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By M. Mentser

The exchange of oxygen between carbon dioxide and carbon monoxide that occurs reversibly on carbon surfaces was studied at temperatures of 750° to 850°C and a pressure of 1 atmosphere. Carbon-14 was used to detect and measure the exchange reaction. The extent of oxygen exchange was a linear function of com- position of the gas mixture, and this relationship was used to evaluate the forward and backward rate constants of the reaction. Equilibrium constants, directly determined for oxygen exchange in this study, agreed well with values in the literature that were derived only by indirect procedures. This result establishes the validity of oxygen exchange in the mechanism of carbon gasification by CO2. Rates of carbon gasification were less than an order of magnitude slower than rates of oxygen exchange. Activation energies for these two processes were 58 and 53 kcal/mole, respectively. The closeness in the activation energies argues against any change in the rate-controlling step over a wide temperature span at atmospheric pressure. The role of CO as a retardant on the CO2-C reaction, and the nature of the carbon-oxygen complex are also discussed in view of the data obtained.

Jan 1, 1973

By J. R. Thoenen

This paper outlines briefly results of seismic measurements recorded in the vicinity of quarry blasting under practical operating conditions. The data cover field work done from January to the middle of August 1930, during which time records were made of 61 blasts in 19 quarries. Of the tests made, one was in biotite-gneiss, two in dolomite, two in a flintlike volcanic complex, three in gabbrodiorite, five in trap rock, and six in limestone. One quarry was in Alabama, two were in South Carolina, two in New York, four in Kentucky, five in Connecticut, and five in Massachusetts. Explosive charges ranged from 0.30 pound to 41,900 pounds, and the method of shooting varied from mud caps through hammer and wagon drill holes to churn drill holes and coyote tunnel shots.

Jan 1, 1937

By M. C. Irani

This study is a survey of supply and demand for minerals, metals, alloys, and compounds used by the chemical industries in the Ohio River Basin (ORB) area of Ohio, Pennsylvania, and West Virginia during 1967. Data for the study were obtained from completed questionnaires received from chemical manufacturers and from interviews with officials of chemical companies and mineral producers and distributors. The information includes kind, quality, quantity, values, sources, specifications, uses, and methods of transportation. Results of the study show that of the total value of mineral materials consumed by the chemical industry, manufacture of inorganic chemicals consumed 46 percent; fertilizers, 22 percent; and soaps and detergents, 19 percent. Fifteen commodities accounted for 91 percent of the total value of mineral materials consumed. Five of these--phosphates, potash, salt, sulfur, and titanium dioxide--accounted for 59 percent of the total.

Jan 1, 1970

Martin Marietta Aluminum, Inc. followed Howmet Aluminum Corp., Revere Copper and Brass, Inc. and Anaconda Co. in lifting August prices of 99.5 percent unalloyed aluminum ingot by 3 cents to 56 cents per pound. Prior to these moves, Kaiser Aluminum and Chemical Corp. raised its June ingot listings by 4 cents to 57 cents and Consolidated Aluminum Corp., 4.5 cents to 57.5 cents. Domestic merchants increased July quotes by slightly more than 1 cent to 51.3-51.8 cents per pound. ARSENIC The Occupational Safety and Health Administration (OSHA) issued new standards, effective August 1, for worker exposure to inorganic arsenic, a toxic substance linked by OSHA to lung and lymphatic cancer. The new standard will limit worker exposure to 10 micrograms per cubic meter of air over an 8-hour period, a drastic reduction from the previous standard of 500 micrograms for a like period. Implementation of the new standards may be the most difficult and costly for copper smelters where arsenic is associated with the copper feed material but problems will also be encountered by producers of arsenic containing products such as for pesticides and herbicides. The new standards allow use of personal protective gear for workers as an interim measure until plant engineering controls can be put into effect.

Jan 1, 1978

By James Westfield

A brief résumé follows of recent activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction of injuries at coal mines: 1. The Federal Mine Safety Code for Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consulting with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous-coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior on October 8, 1953, after further consultations with representatives of management and mine workers and was incorporated by reference in the 1952 and subsequent bituminous-coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. Federal coal-mine inspectors also had temporary authority to close mines found to be imminently dangerous, but such authority (under Executive Order 9728) was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1958

By Jr. Frank Parrish

This report describes the performance of 17 selected water-injection projects producing from Pennsylvanian-and Permian-age reservoirs. Illustrations depict reservoir structure and thickness, and production and injection history. A selected bibliography of publications pertaining to area oil recovery and geology is included. Tabulations of field and reservoir data reveal marked differences in the projects. Increased oil recovery resulted from injecting water in most cases; however, seven projects recovered less oil than the operators anticipated. Oil recovery by water injection ranged from 0.2 to 262 bbl per acre ft, or 0.1 to 22.5 pct of the initial stock-tank oil in place. Major reasons suggested for poor performance include: (1) Adverse directional horizontal permeability, (2) channeling of injected water through fractures or zones of high permeability, and (3) lack of containment of injected water. One 330-foot-deep project is among the first successful shallow water-floods in north Texas. Another project is the first successful Canyon sand-stone waterflood reported in the area. Previous gas injection in two Cisco sandstone projects did not prevent the reservoirs from responding favorably to waterflooding.

Jan 1, 1965

By Henry H. Ginsberg

The Federal Bureau of Mines made pilot plant investigations of the process requirements necessary to produce heavy fuel oil by the liquid-phase hydrogenation of bituminous coal. The investigation was carried out in three separate series of experiments. The first series studied the effect of temperature and contact time on product distribution at 3,500 p.s.i.g. and 420° to 480° C. in the presence of 0.1 wt.-pct../ stannous sulfide plus 0.05 wt.-pct. iodoform based on gross coal. As a result of increased contact times and temperatures, the conversion-6/ and yield of hydrocarbon gas increased, the viscosity of product oil decreased, and elimination of oxygen, nitrogen, and sulfur from coal increased. The yield of oil did not indicate any definite trend with changes in temperature and contact time. The yield of oil ranged from 76 to 85 pct. for Pittsburgh coal and from 60 to 85 pct. for Rock Springs coal. Asphaltenes in the product oil ranged from 17 to 38 pct. of the total oil for Pittsburgh coal and from 12 to 22 pct. for Rock Springs coal. Fuel oils meeting Bunker C or American Society for Testing Materials (ASTM) Grade 6 specifications were produced with Rock Springs coal at 0.2- to 1.0-hr. contact time and 440° to 480° C. and with Pittsburgh coal at 0.3- to 1.0-hr. contact time and 420° to 460° C. In the second series of experiments tin, nickel, iron, and zinc were evaluated as catalysts for the hydrogenation of Rock Springs coal to heavy fuel oil at 3,500 p.s.i.g. and 460° C. Using the apparent conversion of coal as criterion of catalyst activity, at a contact time of 0.45 hr. tin was the most effective catalyst; nickel and iron were nearly as effective, but the use of zinc resulted in much lower conversion. When the contact time was increased to 0.80 hr., the apparent conversion of coal was essentially the same for each of the catalysts. When the yield of oil boiling below 3550 C. was used as criterion of catalyst activity, at 0.45 hr. the order of activity was tin, iron, nickel, and zinc; at 0.80 hr. tin was far superior and the others were essentially equal. The product oils contained from 8 to 20 pct. asphaltenes.

Jan 1, 1960

By R. R. Faddick

A mineral slurry data hank has been compiled, containing slurry pipelining data on sixteen ores, concentrates, and tailings. The data bank it in the form of a computer print-out all they necessary system constants and headloss data for each mineral commodity. The purpose of the data bank was to assist in the development of a universal head loss correlation for mineral slurries, if such a thing exists. Present headloss correlations were tested and found to be inconsistent for the various mineral slurries. Consequently, a different approach was taken, that of compiling a library or Stanton diagrams relating friction factor and Reynolds numbers for a given slurry in a given pipe diameter. The advantages of the diagrams arc demonstrated and discussed. While this correlation shows excellent potential, it is necessary that additional work, both theoretical and experimental, be performed. In addition, two equations are given from which a design velocity may be obtained to minimize deposition or formation of bedload. The equations are based on data taken from the mineral slurry data bank.

Jan 1, 1972

By F. S. Wartman

This paper gives an account of the production of ductile-grade titanium powder in 100-pound batches by reduction of purified titanic Chloride with magnesium, grinding, leaching, and magnetic-separation of the reaction product. Apparatus, technique, and methods of controlling product quality are described and some data on operating costs are given.

Jan 1, 1949

By Keith L. Harris

Real2 gross national product (GNP) grew at a seasonally adjusted annual rate of 1.3% in the fourth quarter and at 2.5% for all of 1986, according to the most recent Department of Commerce estimates table 1). The 1986 GNP growth was the lowest since the recession in 1982, and was slightly below the estimate published in the last issue of Minerals and Materials. Barriers to greater economic growth in 1986 included the Federal budget deficit, the trade deficit, reduced energy-sector investment because of low oil prices, and uncertainty over changes in the Federal tax code.3 Major sectors of the economy responsible for the fourth-quarter growth included real Government purchases of goods and services, up $19.9 billion from the third-quarter level; real net exports, up $12.2 billion; real residential investment, up $3.0 billion; and nonresidential fixed investment, up $1.5 billion. The increase in Government purchases of goods and services was attributed to the S25.1 billion rise in net purchases of farm products by the Commodity Credit Corp-oration. Real personal consumption expenditures and inventory investment declined, however. Personal consumption expenditures declined primarily because of reduced motor vehicle purchases. Despite only modest growth during the fourth quarter, the economy improved significantly because of the narrowing of the trade deficit and growing employment (table 2) while maintaining low unemployment and inflation rates. Business sounded an optimistic note, with planned increases in current-dollar capital spending of 0.9% for 1987 compared with a 1.7% decrease in 1986. While it is primarily the nonmanufacturing industries that expect to increase investment from 1986 levels, some manufacturing industries are increasing investment by significant percentages as well, notably the steelmaking and nonferrous metals industries (table 3).

Jan 1, 1987

By Jasinder S. Jaspal

Most of the underground coal in the United States is mined via room-and-pillar mining methods with continuous miners. These machines operate intermittently because they have to wait for shuttle cars to interchange positions. To overcome this discontinuity in shuttle car haulage and to realize the full production potential of continuous miners, the U.S. Bureau of Mines developed a multiple-unit continuous haulage (MUCH) system through a research contract with Jeffrey Mining Machinery Div. (JMMD). The MUCH system consists of 12 rubber-tired vehicles and a bridge conveyor. The rubber-tired vehicles are connected by a unique mechanical linkage system to form a 250-ft train. The mechanical linkage permits the vehicles to track-retrack the preceding vehicle in both inby and outby directions. The cut coal cascades from one vehicle to another until it is discharged on the section conveyor belt. The MUCH system provides continuous haulage to the continuous miner. The MUCH system was initially surface tested by JMMD. Subsequent extensive testing was conducted by the Bureau at its test facilities at Bruceton, P A. Deficiencies found during testing were corrected. This report summarizes initial tests by JMMD and subsequent extensive tests and evaluation by the Bureau.

Jan 1, 1989

By Albert L. Toenges

[sing tho ppsf; few Yomn t!le:.c. hcs beer. p. trqnd away frorn locomotive haulwe of cop2 frorn tile losdiw point to tho prop,nration plant of bitu~i- nnus-cod strip mlncc to a;~to~lzcd. h,71Jlr.:~. The qrostion has arisen rrhethcr this is alwqvs econ~nicd, rxcl the purpcrse or' tnf s investigation is to de- termine, if possible, the econonic limlt for ~~torieod had.we. sing tho ppsf; few Yomn t!le:.c. hcs beer. p. trqnd away frorn locomotive haulwe of cop2 frorn tile losdiw point to tho prop,nration plant of bitu~i- nnus-cod strip mlncc to a;~to~lzcd. h,71Jlr.:~. The qrostion has arisen rrhethcr this is alwqvs econ~nicd, rxcl the purpcrse or' tnf s investigation is to de- termine, if possible, the econonic limlt for ~~torieod had.we.]

Jan 1, 1938

Air pollution control regulation$ already implemented or being considered for implementation require substantial investment of capital to remove the sulfur oxides from copper, lead, and zinc smelter gases. There will be an attendant increase in production costs and possibly an associated increase in the price of these metals to the consumer. The total investment and any resultant metal price increase will depend upon the control regulations that ultimately will be adopted by the individual States. Controversy has arisen between the metals industry and governmental control agencies regarding the status of stack gas desulfurization technology and the ability of industry to control sulfur oxide emissions to the degree proposed by some of the more stringent regulations currently under consideration. This paper evaluates the problems involved in achieving various degrees of control over smelter sulfur oxide emissions and the technology available to accomplish the task of assuring clean air. The estimated cost of compliance is reviewed for the copper, zinc, and lead industries, but principal at tent ion is given to the copper situation.

Jan 1, 1971

By R. F. Zaffarano

Data presented on the physical characteristics of the reservoir oil, Aneth field, represent the initial phase of a study of Paradox basin reservoir oils being made by petroleum engineers of the Federal Bureau of Mines, Petroleum Research Center, Laramie, Wyo. The purpose of the study is to determine the original reservoir-oil characteristics in several important new discoveries in the Paradox Basin and to investigate correlations between the properties of these reservoir oils and structural or areal position within the basin, If migration is limited and oil accumulates near its source, then it seems probable that few differences should be found in the composition and characteristics of reservoir oils occurring in given age rocks and within the confines of a geological basin. Within these limits, conditions that effected the formation of oil and its transfer from parent to storage rocks probably were rather uniform in an area the size of most of our geological basins. However, if oils should migrate considerable distances, it seems logical to expect that the relative quantities of gas and liquid components may differ in traps occurring along the direction of migration, corresponding with the theory of differential entrapment (5).4/

Jan 1, 1959

By Albert L. Toenges, Frank A. Jones

"INTRODUCTION The introduction of mechanized pining in coal mines, which has speeded loading, has emphasized the importance of efficient underground transportation systems. The purpose of this investigation is to study and analyze various systems now in use, and to derive conclusions therefrom. This report may be helpful to operators who are planning new systems of transportation or who are revising present systems to increase their efficiency. This paper is the first of a series on this subject and describes some systems of transportation utilizing rail haulage.ACKNOWLEDGMENTThe information used in preparing this report was obtained through the courtesy and cooperation of the officials of the companies whose mines wore studied. The descriptions of the transportation systems at the mines included herein have been checked for accuracy, and publication of the data has been approved by the executives of the several operating companies."

Jun 1, 1940

Anaconda Aluminum Co. began production from a new 60,000-ton-per-year potline at Sebree, KY, which brings the total capacity of the plant to 180,000 tons per year. A strike by workers at Alcan Aluminium Corp. primary aluminum smelters at Arvida, Que., Isle Maligne, Que., and Beauharnois, Que. shut down the plants and the company announced force majeure on part of its ingot supply commitments. Kaiser Aluminum and Chemical Corp. announced plans to increase its price for primary aluminum from 60.0 cents per pound to 63.0 cents per pound effective July 1.

Jan 1, 1979

By W. E. Cassan, W. L. Eaton, James Westfield, W. M. Romisher, Karl Hughes, S. H. Ash

"INTRODUCTION Funds were made available to the Bureau of Mines, United States Department of the Interior, for anthracite investigations during the fiscal year ended June 30, 1945. One of the approved projects was to conduct inquiries and scientific and technologic investigations having a bearing on the anthradite mine-flood problem. The investigative work done from July 1,1944, to June 30, 1946, is described in previous reports (5, 8, 10, 24, 28). 6/Purpose of Report The purpose of this report is to describe the investigative work conucted by the Anthracite Food-Prevention Section, Safety Branch, Bureau of Mines, during the period July 1, 1946, to June 30, 1947,Scope of WorkInvestigative work during the fiscal year ended June 30, 1947, was conducted under the direction of D. Harrington, chief, Health and Safety Division, and S. H. Ash, chief, Safety Branch, Bureau of Mines, Washington, D. C.The broad objective of the investigative work was to obtain factual day on: 1. Anthracite reserves of Pennsylvania.2. Underground water pools.3. Barrier pillars.4. The ""buried valley"" of the Susquehanna River.5. Infiltration of surface water into underground mine workings.The above-mentioned investigations are being continued during the fiscal year July 1, 1947, to Juno 30, 1948.In addition to the investigative work covered in this report, Ash end Eaton presented a paper on barrier pillars, which proposes a method for designing barrier pillars and has been Published by the American Institute of Mining and Metallurgical Engineers (5);"

Apr 1, 1948

By David J. Kusler

The Bureau of Mines reviewed current technology in the refractories consuming industries and evaluated the impact of changes in technology on the supply and demand of refractories. Literature was searched and contacts were made with leading consumers and producers of refractories. The distribution of refractories by value of shipments to users was surveyed. The report shows that the percentage distribution of refractories sales to the consuming industries has remained essentially constant during the last decade but that substantial changes have occurred in the relative distribution of types of refractories. The trend in pyroprocessing technology in recent years has been toward higher temperatures, which require more costly refractories. This fact is reflected in the impressive gain in the dollar value of refractories sales, which in 1968 was about one-third greater than in 1960, and the rapid growth of refractories based on high-alumina, magnesia, zirconia, carbon, and other materials, at the expense of fire clay, silica, and chrome- based refractories. An appendix to the report contains refractories value and shipment data tabulated in a manner by which trends in the distribution of refractory types can be observed from 1955 to 1968. In addition, unit values are presented on a per-ton basis for comparison.

Jan 1, 1970

Norton Co., the world's largest producer of abrasives, is enlarging its proppant operation. Proppants are strong chemical particles used to wedge open rock formations in deep oil wells, thereby increasing the well flow rate, sometimes as much as tenfold. Norton" aluminum oxide-based proppant is rapidly displacing less durable materials. The company is building the world's largest proppant plant in Fort Smith, AR. ALUMINUM--See also REFRACTORIES The price of primary aluminum ingot was increased by several producers in July. Kaiser Aluminum & Chemical Corp., and Revere Copper & Brass Inc. increased the price of primary aluminum to 63.0 cents per pound, effective July I. Reynolds Metal s Co., Anaconda Aluminum Co., Howmet Aluminum Corp., and Marti n Marietta Aluminum Inc. increased the price of 99.5% primary aluminum ingot to 63.0 cents per pound, effective July 5, The Aluminum Company of America increased the price of aluminum ingot to 62.5 cents per pound, effective July 9. The range of prices at the end of the month was 58.5 to 63.0 cents per pound.

Jan 1, 1979

By Richard D. Miller

This Bureau of Mines publication contains analyses and related source data for 224 natural as samples from 18 States. Of the total, 191 sam¬ples were collected during calendar year 1981. The remaining 33 samples were collected during previous years, but releases, granting permission to publish were not received until 1981. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by the mass spectrometer and special helium apparatus described previously (1-2).3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the general public. Twenty-five publications have presented the results of 12,827 gas analyses made prior to 1981. The first three bulletins (1-3) contain analyses and related data on 5,218 gas samples collected from 1917 through 1960; these bulletins have been supplemented annually by information circulars (4-17, 19-24) containing 7,609 analyses of samples collected since 1960.

Jan 1, 1982