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By Melvin H. Miles

"Considerable research has been conducted on the anodic oxidation of methanol in fuel cells. The electrochemical reduction of carbon dioxide in aqueous solutions to form methanol is the same reaction in reverse, i.e. CO2 + 6 H+ + 6 e- ? CH3OH + H2O. The same catalysts and conditions may operate for both reaction directions. This carbon dioxide reduction reaction, however, must be able to compete with the electrochemical reduction of water to form hydrogen gas. Thermodynamically, the reduction of CO2 to form CH3OH is slightly more favorable than the reduction of water. The use of nearly neutral electrolytes rather than acidic electrolytes makes the reduction of CO2 kinetically more favorable. The thermodynamics of various reaction steps are presented. Similarities exist with the electrochemical reduction of CO2 and the green-plant photosynthesis process that converts CO2 to carbohydrates.IntroductionVirtually all of the oxygen in the earth’s atmosphere is of biological origin having been generated by green-plant photosynthesis from water and carbon dioxide [1]. The net reaction can be represented byCO2 + H2O ? O2 + [CH2O] (carbohydrates, etc.) (1)Chlorophyll and enzymes promote this reaction, and the energy required comes from sunlight. The actual photosynthesis process is a complex multistage reaction and requires 469 kJ mol-1 of energy supplied by the sun. Isotope tracer experiments using 18O have shown that both the oxygen atoms in the O2 molecule originate from H2O, whereas oxygen atoms in the carbohydrates come from CO2 [1]. The total amount of water on the earth is split by photosynthesis and reconstituted by respiration and combustion once every 2 million years or so. The photosynthetically generated oxygen gas temporarily enters the atmosphere and is recycled about once every 2000 years [1]. The carbon dioxide is partly recycled in the atmosphere and oceans after an average residence time of 300 years and is partly fixed by precipitation of CaCO3 and other carbonate minerals [1]."

Jan 1, 2008

By R Marchant, D Willingham

"Predictive maintenance (also known as PHM or equipment ‘health monitoring’) refers to the intelligent monitoring of equipment to avoid future equipment failures. In contrast to conventional preventive maintenance, the maintenance schedule is not determined by a prescribed timeline; instead, it is determined by analytic algorithms, such as machine learning, using data collected from equipment sensors and/or via simulation.Predictive maintenance offers the following benefits for operators and equipment manufacturers:reduction of equipment downtime by identifying issues before failure, thereby enabling convenient scheduling of equipment service and extending equipment lifetimeautomatic determination of the root cause of the failure, enabling appropriate service to be performed without utilising resources to determine a diagnosis avoidance of costs of unnecessary maintenance and unexpected failures improved safety and product quality.Algorithms and data are critical to predictive maintenance success. Sensor data preprocessing is performed using advanced statistical and signal processing techniques. In the case that data isn’t available for the full range of operating modes, operating scenarios can be simulated. Machine learning techniques are then used to estimate equipment health. Once tested, predictive maintenance algorithms may be operationalised in an IT environment such as a server or cloud. Alternatively, algorithms may be implemented in an embedded system directly on the equipment, allowing for faster response times and significantly reducing the amount of data sent over the network.In this paper, we use both historical and simulated data of the plant under various modes of operation including run to failure, and we then leverage machine learning techniques in MATLAB to estimate degradation and remaining useful life. This technique, of combining both simulation models and machine learning, in the areas of predictive maintenance and equipment health monitoring has been adopted by Safran, makers of aircraft jet engines, since 2007. They now have over 160 modules developed (Lacaille and Aurelie, 2015).Citation:Willingham, D and Marchant, R, 2016. Predictive Maintenance Using Simulation and Machine Learning, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 279–284 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By Paulo von Krüger

This paper deals with the cell design and operation of a tin electrorefining 1:5 pilot plant. The purpose of the work was the fitting of the basic parameters to be used in a full-scale tankhouse from a major Brazilian tin producer. The main specific difference was the use of permanent stainless steel cathodes instead of conventional tin starting sheets. The results of both product quality and operating parameters are discussed.

Jan 1, 2003

By H. Bernier

The Noranda Inc., CCR Division, copper refinery located in Montreal-East, Québec, Canada, has expanded over the years to reach a capacity of 410,000 metric tons of cathode production per year. The expansion process resulted in nine, parallel, 200 m. long bays each equipped with its overhead cranes and manually operated washing machines. Anode scrap washing and piling was done manually. The mechanization of the tank house involved the elimination of 18 cells at one end of each of the bays in order to install transfer conveyors where anode scrap and cathode loads are deposited by the bay cranes. The cathode loads are brought by new transverse cranes to new machines where cathodes are washed, piled in predetermined bundle weights, check weighed, strapped then shipped in trucks or railroad cars. Suspension bars are automatically removed, stacked in magazines and sent back to the starting sheet machines. Anode scrap loads are brought to machines located near the anode furnaces where they are washed and piled in bundles for easy charging. The mechanization has eliminated numerous hazardous jobs and has realized a reduction of 0.2 man-hours/ton. After these modifications, the refinery production capacity now stands at 370,000 metric tons per year.

Jan 1, 1987

By M. Paymardi, A. Foroutan, T. P. Oladele, M. Abbaszadeh

"Reducing the amount of zinc and iron in lead concentrate is one of the important aspects of processing in lead and zinc flotation plants which results in improvement of lead concentrate quality and prevents zinc loss. In mineral flotation industries, lignin sulfonates are known for their depressant properties for both non-metallic and sulfide minerals such as pyrite and pyrrhotite.This paper investigates the effect of lignin sulfonate on flotation of galena, sphalerite and pyrite in sulfidic lead and zinc bearing ores. Batch flotation tests were carried out on a high pre-activated zinc samples. The feed contains 0.9% lead, 2.3% zinc and 7.5% iron. The dosage of all reagents such as sodium cyanide, zinc sulfate, ethyl xanthate and methyl isobutyl carbinol (MIBC) were kept constant for lead flotation step except calcium lignin sulfonate (CLS) that was varied between 0 and 80 gr/ton.Results for lead rougher concentrate showed that the grade of lead increased by 2.7% while the recovery decreased around 4 % at the highest dosage of CLS. Furthermore, zinc recovery decreased by 6.3% with no significant change in grade. Iron recovery in lead rougher concentrate decreased by 2.3 % while the grade changed around 1%. In sphalerite flotation step, CLS dosage was changed in the range of 0 to 80 gr/ton while the dosage of other reagents such as copper sulfate, lime, amil xanthate and MIBC were kept constant. In this step, no decreasing in grade and recovery of zinc was observed, while iron recovery decreased. It was suggested that CLS has a depression effect on sphalerite in conjunction with other zinc depressants such as zinc sulfate and sodium cyanide. CLS was further used in plant with non-pre-activated zinc minerals. Similar trends were observed in plant.INTRODUCTIONlead-zinc sulfide minerals play an important role in the production of lead and zinc metals in the mineral processing industry (Luo, Feng et al. 2016). Due to complexity of the lead-zinc ores mineralogy, in some situations, their flotation properties vary significantly from one deposit to another one even in itself (Bulatovic 2007)."

Jan 1, 2018

"WELFARE…Welfare endeavor in connection with both the metal and the coal mines of Utah has shown gratifying progress during recent years and both the operators and their employees are deserving of much credit for the efforts put forth to better living, working, educational and receational conditions in most of the mining camps of the state.In the older metal mining camps of Utah, where the towns are incorporated and independent of the mining properties operating in the vicinity, less opportunity is pre¬sented for the companies to exercise efforts looking towards improved welfare conditions than is the case of camps located on company ground and under the full control of operators.Even in such camps, however, as illustrated in Bingham, the companies can do much to better welfare conditions. In this camp the Utah Copper Company has spent $800,000 since 1 920 in the erection of modern brick cottages, apartment houses and the Gemmell Memorial Club. The cottages and apartments have every convenience to be found in up-to-date city homes. The Gemmell Memorial Club, erected and equipped at a cost of $1 75,000, was provided by the company for the benefit of the Utah Copper Company employees living in the canyon and has been made the recreational center for the camp."

Jan 1, 1925

By G. X. Du

Reaction kinetics of serpentine and hydrochloric acid is theoretical basis for optimizing reaction process conditions of serpentine and hydrochloric acid. Kinetics of serpentine and hydrochloric acid was studied in this paper. The results indicated that apparent reaction order to hydrochloric acid was two and reaction kinetic equation could be expressed as: 2HClHCl,ddtckct-=·. The diffusion rates of hydrogen ions in liquid film on surface of serpentine particle and in amorphous silica layer generated in the reaction and chemical reaction velocity during the reaction had important effects on to-tal reaction velocity. And chemical reaction velocity had the most significant influence. The relation of conversion rate of magnesia xMgO with reaction time could be expressed as: 1(1)xkt--=·.

Jan 1, 2014

By D. B. Dow

"In the natural-gas Gasoline industry, the methods used in determining the amount of gasoline in natural gas are many and varied; they include the specific-gravity test, laboratory tests involving absorption, charge in volume of the gas or in the absorption medium, absorption in charcoal with subsequent distillation, compression of the gas which results in the condensation of the gasoline, and the absorption of the gasoline vapors in an absorption oil, from which the gasoline is distilled and measured. Each of these various tests has advantages, and disadvantages. It is however, conceded in the industry that the tests in which the gasoline is obtained and measured as such are the more reliable.This paper deals with certain factors which should be considered in making absorption tests using ""mineral seal oil"" as an absorbent; this method of testing is widely used not only in the field, but in control work in absorption gasoline plants where the gasoline content of the intake and discharge gas is determined daily. In control work it is frequently found that the plant produces more gasoline than the tests show, which gives the plant the appearance of making more gasoline than is actually present in the gas treated, or in other words operating at more than one hundred per cent efficiency. Obviously then, the tests as made in these cases are in error, and in hope of correcting some of these variances, the following factors have been studied at the U. S. Bureau of Mines petroleum station at Bartlesville, Oklahoma."

Aug 1, 1920

By P R. Botha

Mining has played a significant role in human development and without the mining sector, society would not enjoy a large number of the benefits that it does today. However, mining has also carried with it some important lessons, which remain the source of ongoing learning. One of these lessons is the poor closure or abandonment of mines, worldwide. This has in many cases resulted in large tracts of unproductive land, representing a source of environmental pollution and a safety hazard to the community. Frequently associated with this is a legacy of mining communities having fallen into economic and social decline, beyond mine closure.Due to this legacy, governments, society and the mining sector pay far greater attention to mine closure planning today, than was done in the past. Typically closure planning has focused on the engineering aspects of a mine, namely decommissioning of the workings and plant; dismantling of unusable infrastructure; and rehabilitation of disturbed land. These are important aspects of closure but a more holistic, long-term approach is required which encompasses environmental and social aspects and aims to leave a positive legacy behind.In planning for a mine closure scenario with a lasting positive legacy, it is critical that the broader receiving environments (social, economic, physical and biological) within which a mine is located, define and drive the closure plan and the mine planning as a whole. This ensures that the broader environment influences mine closure, as opposed to looking at how a closed mine will impact on the environment. The ultimate aim is to first understand the broader environment and then to fit the closure of a mine into it. The earlier this approach is followed in the life of a mine, the greater the operational time frame available, and hence a better chance is presented for planning and managing a mine towards the desired, tested and agreed post closure scenario. Within this broad context, there is tremendous scope to achieve successful mine closure. However, it is critical to note that mine closure is not the sole responsibility of the mining companies, and neither is it possible for said mining companies to achieve mining closure alone. This concerted effort requires a multi-stakeholder approach in which partnerships are created and risks, responsibilities and opportunities are shared and managed. To achieve sustainable closure, a multi-stakeholder approach based on an initial forward-looking closure vision is required. This approach provides an early basis for consideration of alternative land uses and economic options from which specific actions to achieve the preferred option can be defined. The Anglo American plc Mine Closure Toolbox has been formulated and developed around this concept. The Toolbox aims to expand mine closure planning - from financial provisioning for rehabilitation and physical closure, to planning for sustainability beyond mine closure and leaving behind a positive legacy.This paper focuses on the business case for mine closure planning and provides an overview of the Anglo American plc (AAplc) Mine Closure Toolbox.CITATION:Botha, P R, 2012. The business case for mine closure planning and an overview of Anglo AmericanÆs mine closure toolbox approach, in Proceedings Life-of-Mine 2012 , pp 7-10 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By K. Adham

"Fluidized beds are utilized in a wide range of high-temperature applications throughout the metals and materials industry. Their main advantage is the fast and uniform heat and mass transfer between the hot combustion gases and the particulate solid feed. A further benefit can be the lowering of the processing plant's energy consumption, through heat recovery from the fluid bed processes used for solids heating. Here, the enhanced energy efficiency of fluidized systems is investigated and the modeling results are discussed for three configurations: the flash tube, the single bubbling bed and the multi-stage fluid bed. Key thermal design aspects of each system are identified based on results from process simulations, in order to benchmark their main operating features and overall energy efficiency. Suitability and applicability of each configuration is also discussed based on a number of process and material property considerations.IntroductionCombustion based heating of particulate solids is commonly done using three different types of fluidized beds. The flash tube (FT) is similar to a hot pneumatic transport system. The single-stage fluidized bed (FB) typically uses in-bed combustion. The multi-stage fluidized bed (MSFB) can have two or more stages stacked into a tower.Flash tube (FT) suspends the incoming solid charge in a high-velocity stream of hot combustion gases. To maintain the solids suspension in the FT, two parameters are required: high velocity for elutriation of the particles and adequate solid-to-gas ratio for avoiding high pressure drops and solids drop-out [l].The fluid bed (FB) works at much lower velocities than the flash tube. Therefore, most of the solids are not conveyed in the gas stream, but are only suspended in a liquid-like manner. At minimum fluidization velocity (Umr), the gas flow exerts just enough force on the solids to keep them suspended in place [2].Multi-stage fluid bed (MSFB) heats up the solids as they are transferred from an upper bed level to a lower one, counter-current to the rising flow of hot gases generated at the lowest stage. As the temperature and volumetric flow of the gases decrease from bottom to the top stage, smaller bed diameters can be used in the energy recovery stages [3]."

Jan 1, 2014

By M. G. Premo

The McKinley Mine is located in the northwest New Mexico, in McKinley County, approximately 25 miles from Gallup. The mine is operated by The Pittsburg & Midway Coal Mining Co. (P&M), a wholly owned subsidiary of the Chevron Corporation. P&M is headquartered in Englewood, Colorado. Since the McKinley Mine began operations in 1962 a total of 83,391,000 metric tons of coal have been sold through 1990. The 1991 production was approximately 5.000.000 metric tons. The mine operations are contained on a 109.000 square kilometers lease area of which 44.000 square kilometers are on the Navajo Nation. The present customer base consists of four utilities and one industrial account, all of which are located in Arizona. The utility customers are the Arizona Public Service Co. Cholla Station at Joseph City, The Salt River Project. Coronado Generating Station near Joseph City, and The Tucson Electric Company, Irvington Generating Station in Tucson. The industrial customer is the Stone Container Corporation, Snowflake Paper Mill.

Jan 1, 1992

By R. Padilla

A thermogravimetric study has been conducted to follow the decomposition and volatilization of arsenic from enargite concentrate in nitrogen and slightly oxidizing atmospheres. Temperature has a large effect on the rate of volatilization of arsenic. Fractional volatilization of arsenic as high as 98% were obtained in less than 60 min at 650°C in nitrogen atmosphere, while in slightly oxidizing atmosphere the same volatilization could be achieved in 30 min. It was found that arsenic volatilizes as sulfide in nitrogen atmosphere and as 4xture of sulfide and oxide in atmospheres containing 1% oxygen. By using the pore blocking and the first order kinetic models, apparent activation energies of 213 and 200 kJ/mol for the temperature range of 780 - 900 K and 205 and 184 kJ/mol for the temperature range of 900 - 985 K were determined for enargite and copper concentrate, respectively.

Jan 1, 1997

By Hillary W. St. Clair

In a previous report 1/the author showed that the essential information from particle size analyses of grinding mill products can be represented by three or four parameters derived from the first four moments of the particle size data. These parameters may be used in gamma or beta distribution functions to estimate the weight fraction in any given size range. Moment analysis was used to study the progressive changes that take place in particle size distribution when a homogeneous isotropic mineral such as quartz is reduced in size by impact crushing. 2/ This report briefly reviews the essential features of moment analysis and describes extension of this method to size reduction by ball mill grinding.

Jan 1, 1972

By A Golsby

Both primary and secondary ventilation is important in underground mining. Secondary ventilation refers to the provision of ventilation to development ends, stopes and services facilities, which constitute secondary circuits tapped off the primary circuit or main through flow of air.An unbalanced primary and secondary combination can cause re-circulation, which is inefficient and potentially hazardous. These inefficiencies extend into operational and other considerations, such as power.Most cost justification analysis covers capital and physical consumables. These analyses are often not comprehensive or holistic. This case study is an example of ‘how to holistically justify’ a secondary ventilation circuit and optimise it to meet all stakeholder needs.This paper particularly addresses the following:how to account for all stakeholders in a secondary ventilation cost justificationthe secondary ventilation componentsthe cost justification outcomes and how to measure themsome of the sensitivitiesthe stakeholdershow to present the justification to meet the stakeholder needssecondary ventilation cost justification.CITATION:Golsby, A, 2015. Secondary ventilation as a value proposition – a case study, in Proceedings The Australian Mine Ventilation Conference, pp 49–54 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By I Jabou, D G. Blazak, L C. S Hogarth

The R70 test is a good indicator of coal reactivity to oxygen and is commonly used to provide a rating of propensity for self-heating. Tests performed by The University of Queensland Spontaneous Combustion Testing Laboratory have resulted in the development of a large database that shows the impact of coal quality on this parameter. From these results it is possible to infer an R70 value, which can be used to gain an appreciation of the intrinsic coal reactivity before it is even tested. However, any interpretation of R70 values must consider the influences of coal rank, mineral matter and moisture content to provide a better understanding of the spontaneous combustion risk of a particular coal.

Jan 1, 2005

By S. Goodman

Successful exploration for and exploitation of a mineral deposit requires an accurate understanding of the deposit architecture in 3D, and of the development of the mineralizing system through time, which requires a thorough comprehension of the structural framework of the deposit. The integration of geological, geophysical and geochemical datasets to arrive at a 4D structural framework is well-established and has been successfully applied by SRK Consulting in projects from deposit to regional scale. In some cases, we can go beyond this, applying the SEEBASETM technique, which utilizes a ?bottom-up? approach to basin analysis. SRK?s approach primarily relies on the interpretation of magnetic and gravity data, calibrated with many other datasets including mapped geology, topography, event histories, wells/drillholes and seismic data. The SEEBASETM model is a culmination of this data integration and is produced through an iterative process of structural interpretation and geophysical modeling, where an interpretation of basement composition and 4D structure is used to constrain depth-to-basement geophysical modeling, and the modeled depths are then used in conjunction with the structural interpretation to constrain contouring of the basement topography. The result is a rigorously calibrated, 3D view of the basement surface, which can be used to understand the basement and basin architecture, and thus serves as a predictive exploration model. This technique, which was developed for use in the petroleum industry, is now finding success as a predictive tool in mineral exploration.

May 1, 2003

By Yang Xianwan, Zhu Xiaoyun, Guo Zhongcheng, Zheng Yanping, Zhai Dacheng

"Corrosion resistance of RE-Ni-W-P-SiC composite coating and 3 l6L stainless steel in corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations by means of immersion methods and anodic polarization curves obtained by DHZ-1 electrochemical synthetic tester and HDV-7 transistor constant potentiometer. Immersion experiment results show that corrosion rate of RE-Ni-W-P-SiC composite coating as-deposited in HCl solutions increases with the rise of HCl concentrations, on the contrary, the corrosion rate of the composite coating after heat treatment decreases with increasing the HCl concentrations the corrosion rates of the coatings as-deposited and after heat treatment in H2SO4 and H3PO4 solutions respectively decrease with the rise.of H2SO4 and H3PO4 concentrations the corrosion rate of the deposit as-deposited in FeC13 solutions decreases with increasing FeC13 concentrations, while the rate of the composite coating after heat treatment increases .with the rise of FeC13 concentrations.In addition, the corrosion rate of 3 l 6L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations increases with rising of concentrations. Furthermore, the corrosion rate of 316L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions respectively is much greater than that of the RE-Ni-W-P-SiC composite coating as-deposited and after heat treatment in the same corrosion media.1. IntroductionAll the materials and their products, when processed, stored and used, it is inevitable that the corrosion, wear, fatigue and crack occur owing to the actions of surroundings. Those early failure and abrasion, through all kinds of departments and profession that corrosion consumes one percent of tens of the steel products of the whole world; and two or four percent of the GDP is lost because of the corrosion."

Jan 1, 2000

By Nathalie Neveux

For the first time, dehydrated ferrous sulfate was successfully used for the dry synthesis of potassium ferrate. In addition, ferrate ion is stabilized as a solid solution where hexavalent iron is partially substituted by S(V1) leading to a sulfato-ferrate having the following formula K2(Fe,S)04. This substance has an efficient life time of about six months. Ferrate ion is a powerful oxidant ( EO = 2.2V ), a bactericidal agent and possesses coagulant, flocculant properties. Its reduction generates nascent oxygen, hydroxyl groups and Fe(OH)3. Alkali metal ferrate is probably the future global agent for water treatment. Applications of this material in the field of urban and industrial effluents treatment have been investigated. Heavy metals cations such as Cu, Cd, Mn, Ni, Pb, Zn, ... were successfully removed. The results of sulfato-ferrate use for cyanide destruction, decrease in COD, soil, discoloration of pulp and paper effluents will be summarized.

Jan 1, 1999

By Matthew Blecha

The Tribag copper deposit is one of the rare examples of mineralized breccias in the Canadian Shield. The breccia is a pipe-like body, and consists of granitic, diabasic and volcanic fragments embedded in a vuggy, quartz-carbonate matrix. The mineralization is essentially chalcopyrite and pyrite, with minor molybdenite, sphalerite, galena and other sulphides. The main ore zone is saddle-like in shape, and is enveloped in a zone of chloritization, sericitization and clay-mineral alteration. It is suggested that the breccia is of the diatreme type. Introduction T HIS paper is based on eighteen months of field work, including surface and underground geological mapping and core logging, and on the survey of relevant literature. No significant amount of laboratory work has been done as yet. Location and Access The Tribag Batchawana property is located 40 miles north of Sault Ste. Marie, Ontario, about 10 miles east of Lake Superior. A 17-mile, all-weather road connects the property to the Trans-Canada highway to the south, and 4 miles of a 12-mile road remain to be completed to link it to the Algoma Central Railway to the northeast.

Jan 1, 1965

By W. -D. Schneider, B. Schwab

Like all metals, zinc can be recycled theoretically without end. To demonstrate environmentally friendly use of zinc, it is necessary to increase the recycling rate. In this regard, the Imperial Smelting Process developed in the forties and fifties in the United Kingdom has become more and more important. This unique process combined with a sinter plant, hot briquetting, and direct injection through the ISP furnace tuyeres offers ideal possibilities to recycle all kinds of zinc and lead bearing materials. Possible secondary materials include Electric Arc Furnace (EAF) dust, zinc-containing sludges and even zinc/carbon batteries. This high temperature process also destroys all organic materials, like dioxin, and can be seen as a sink for many harmful substances.

Jan 1, 2000