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By P. G. Salom

The manufacture of steel castings has become one of the important industries of the times. The late Mr. Alexander I,. Holley published in 1878, in the Metallurgical Review, an able paper, entitled "Solid Steel Castings," showing how all manner of castings could be made advantageously of steel. Mr. Holley had then but lately returned from the great iron and steel works of Terrenoire, France, which were engaged, I believe, almost exclusively on large castings, of a simple type, for the government,, and were repeating the same operation from day to day. These conditions are, as experience has shown, very different from those of ordinary practice in miscellaneons castings; and Mr. Holley might have been less confident if be had actually gone into the business. More than seven years have passed ; and as yet the magnificent possibilities held forth in his paper have not been realized. There are only six steelcasting establishments in the United States, and their total output of castings is certainly not as much as 20,000 tons per annum, and probably not more than 10,000 tons; whereas it should be over 200,000 tons to supply the needs of the country. A large number of so-called steel castings are made, however, which are nothing more than malleable iron. The best of these castings are made from a superior white pig, as low in silicon and

Jan 1, 1886

By J. J. Daniels

Advances in borehole geophysical research for mineral assaying and remote detection of mineralization away from the borehole are cited. Nuclear activation measurement research has provided accurate in situ assays of economic metals with neutron-gamma activation, using a high resolution intrinsic-germanium detector. Although nuclear activation analysis is the present "best hope" for obtaining in situ assays for some elements, gamma-gamma and magnetic susceptibility measurements can provide accurate assays for lead-zinc and magnetite, respectively. Borehole optical spectroscopy and X-ray fluorescence are being investigated as possible in situ assaying techniques for some minerals. More laboratory and field calibration research is needed before non-linear complex resistivity (NLCR) can be routinely used as a quantitative assaying tool. Field tests have shown that variations in the local geologic environment can affect the quantitative accuracy of assay values from downhole NLCR measurements. Deeply penetrating borehole geophysical methods are increasingly being used for mineral exploration as drilling costs and exploration have increased. Borehole electrical measurements have been shown to be useful for detecting conductive ore bodies that are not intersected by a drill hole. Hole-to-surface resistivity and surface-to-hole time-domain electromagnetics are demonstrated to be particularly effective for defining mineralized zones in a massive sulfide environment. Borehole gravity meters and three-component magnetometers have been developed and should prove useful for defining geologic anomalies away from the drill hole.

Jan 1, 1987

By E. S. Leaver

THE presence of soluble base metals in precious-metal ores usually precludes cyanidation as the best method of treatment. The laboratory experiments described in this paper show the possibility of cyanidation of gold-silver ores containing less than 0.5 per cent, of cyanide-soluble copper and the effect of zinc in the cyanide solution. PART I.-COPPER IN CYANIDATION The proposed process of cyanidation of precious-metal ores containing copper is based on the regeneration of about 80 per cent., of the cyanide used in the dissolution of the copper. The method of regeneration involves a combination of the sulfide and the acid precipitation of the copper and silver. The resultant solution is made alkaline with lime, and the gold is precipitated with zinc dust. Solubility of Copper Minerals in Cyanide Solution In order to determine the solubility of copper minerals, including metallic copper, under the usual conditions for cyanidation, experiments were conducted with synthetic ores. Each ore sample was prepared by mixing the particular pure copper mineral with barren sea sand. Both the mineral and sand were ground to pass 100 mesh before they were thoroughly mixed. The percentage of copper in each head sample was determined by direct assay, excepting the metallic copper sample, which was computed on weights before mixing. Table 1 gives the results.

Jan 1, 1929

By Henry Faul

MEASUREMENT of radioactivity of rocks and ores has developed into a complete method of geophysical exploration. The problem falls into three natural categories: (I) surface radiation measurement in the field and underground; (2) radioactivity logging of drillholes; and (3) laboratory analysis of samples. Portable counters are used in the field for tracing radioactive formations and for quantitative estimates of radioactive content of surface rock. Wartime advances in battery design make it possible to construct small precision counters that can be carried easily. Even the smallest conventional diamond drillholes can be logged, and actual content of the radioactive element can be measured. The exact grade of very thin active layers or veins can be estimated only approximately. Samples may be analyzed for their alpha, beta or gamma activity, and beta assaying is the best suited to rapid routine operation. Simple calibration with standard samples is sufficient for rough work, but a density correction is necessary when greater precision is required. Samples with high emanating power should be fixed and stored for three weeks to reestablish the radium-radon equilibrium prior to precision assaying. Carnotite can be fixed by sintering or molding with plastics. Among the important new developments, a low-voltage Geiger tube has been designed recently, and crystal scintillation counters hold great promise for high-efficiency gamma-ray measurement.

Jan 1, 1947

By M Brewster

Goldfields Abosso Goldfields Limited (AGL) is a Ghanaian registered company that owns and operates the Damang Gold Mine. Gold Fields Ghana Holdings Limited holds a 71.1 per cent interest in AGL. The Damang concession held by Gold Fields Ghana Holdings Limited covers a total area of 271 km2 located 40 km north of the town of Tarkwa in the south-western part of Ghana. Gold Fields as a company registered on the New York Stock Exchange is legally obliged to be SOX (Sarbanes-Oxley). Sarbanes-Oxley Section 404 (SOX404) is on management assessment of internal controls. The Mineral Resource Management (MRM) function of AGL manages three Prospecting Licenses and two mining licences. At least ten pits/prospects are scattered along the two limbs of the Damang Anticline and have two main types of mineralisation notably Paleoplacer and Hydrothermal. Thus SOX404 procedures are put in place to treat each mineralisation type in the best way for reliable resource outputs and estimates. Generating auditable resources for AGL is a prime but most important function of MRM. Thus important checks are built and designed to ensure that all relevant geological and geostatistical inputs conform to procedures outlined under SOX404 requirements. More importantly sign offs are designed to ensure that technical personnel involved in all aspects of resource and reserve generation are satisfied and can be held accountable.

Jan 1, 2007

By Henry Howland

INTRODUCTION DURING the last decade no topic has created more interest or received more thought among blast-furnace men than colic. One reason for this is, undoubtedly, the remarkable increase in the use of byproduct coke. Formerly our coke was made at a distance from the furnaces and by a distinct organization. There was little cooperation or development possible under these conditions. Today the situation is greatly changed. Much of our coke is made by the organization operating the furnaces and the coke oven is operated with the primary object of obtaining the best results in the blast furnace. The effect of changing the method of coke manufacture, even in some minor detail, is often felt almost immediately at the blast furnace. There naturally results one of the most valuable assets of the byproduct coke oven, -i.e., the possibility of increased blast-furnace efficiency clue to close observance and correct operation of the ovens. The results are evident, but it often is difficult correctly to account for them. In attacking the solution of a problem of as much importance as why one coke is better than another, there are facts which should be kept clearly in mind The author hopes, in this paper, to bring out some points relative to the use of carbon in the blast furnace which will be of value in solving this question.

Jan 3, 1916

By P. Bhakta

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment leaching procedure to increase the recovery of gold from arsenopyrite (FeAsS) ores. The best solution compositions for arsenopyrite dissolution were determined using cyclic voltammetry and chronocoulometry. Initial arsenopyrite dissolution occurred at -0.20 V versus standard hydrogen electrode (SHE) in a sodium hydroxide (Na0H) solution. Leaching of a high-grade arsenopyritic ore containing, in percent, 28.2 As, 25.3 Fe, 19.9 total S, and 1.0 Sb and, in troy ounces per short ton, 1.6 Au and 5.5 Ag resulted in >90 pct As extraction at 1000 C, 40 psig O2,4 h, and 2M NaOH solution in a 2-L autoclave. Cyanidation of the leach residues resulted in 90 to 93 pct Au and 60 to 80 pct Ag extractions, compared with only 5 and 15 pct, respectively, without the pretreatment. The procedure was further tested by leaching a low-grade gold ore and a bulk sulfide flotation concentrate prepared from it. Cyanidation of the leach residues resulted in 70 pct Au and 31 pct Ag extraction. The NaOH leachate was partially regenerated by precipitating the arsenate as calcium arsenate [Ca3As04)2] and the sulfate as barium sulfate (BaS04).

Jan 1, 1989

By Sidney H. Loram

As the work carried on by this Company, of which the writer has been in charge for the past two years, is somewhat unique, the following account of it may be of interest, and, on that account, is offered to the Institute without any attempt to claim this practice as the best. Mines. The mines supplying ore to the Company arc situated in three groups: the Guanaco field,.about 80 miles N.E. of the port of Taltal (lat. 25" S., long. 70" 30' W. of Greenwich); the Sierra Overa, about 63 miles S.W. of Taltal; and Paranao, about 42 miles due N. of Taltal (12 miles N. of the small town of Paposo, once famous for its copper-output). Guanaco. This field lies in the center of an absolutely waterless mountainous desert, where not a sign of vegetation can be found for miles. The dryness is such that ivory and horn crack and open, while raw-hide must be used in place of leather, which -would become worthless in a very short time. Water is brought about 21 miles by piping from the Cordillera, but only in small quantities, and costs in the Guanaco $7 (= $1.78 gold) per cubic meter. All supplies and food are sent from the port of Taltal, which in turn draws its supplies from the south of Chile, the

Jan 1, 1900

By Vidalinc, Raffoux

Longwall faces producing in the order of 20,000 tons per day of raw coal are presently running in the Houilleres du Bassin de Lorraine of Charbonnages de France. Production levels of twice that level pose some technical and economic problems of coal cutting, ventilation, coal and equipment transportation in the.face and from the face to the sur- face. The peak productions of the equipment in use today, the results of trials with new equipment, the utili- sation of forecasting models (some in the form of software), allow us to fo- resee feasable technical solutions to these problems. They will first be considered in the best possible context (thick- ness, dip, non gassy, soft coal, good strata, no faults). This will give. the necessary conditions to reach daily output'of that level. A sensitivity analysis of these- figures to the effective natural con- ditions will then be undertaken and the implication of such a project on health and safety (dust, climate ...) will be carefully considered. A concise technical and econo- mical approach will permit us to fore- cast the economical interferences of such production units and specially the consequences of sudden variations of the output (downtimes, failures, etc). From this investigation, goals for technological development and re- search areas will be outlined to be able to reach this production target in the XXIst century.

Jan 1, 1988

By Pilkington T, Noy A

The Yallourn North Extension (YNX) open cut mine ceased mining operations in early 1989. YNX may be used again for coal supply at the discretion of the Coal Corporation Of Victoria (CCV); this has resulted in the need for interim rehabilitation of the site which may last many years, or indeed, permanently.The site has suffered substantial surface erosion over the years with large areas of bare clay and coal batters remaining exposed. The first priority is to reduce the quantity and improve the quality of stormwater runoff from the site. This is best achieved by appropriate revegetation and the use of existing landform depressions as silt trap/wetland areas. Proposed rehabilitation needed to take into account the sensitive fire safety of the open cut and the option to re-open the mine if CCV deems appropriate.The authors detail the factors involved in the rehabilitation proposal and the multi-disciplinary approach to planning including engineers, scientists, a forester, landscape architects and community input. The rehabilitation design included early consideration of land use and ongoing maintenance issues linked to water quality improvement factors including vegetation. Engineering input was required for reshaping and clay covering exposed coal batters and the design of silt traps which will revert to wetlands in future. The integration of each discipline has produced a rehabilitation design pleasing to both the SECV and community alike.

Jan 1, 1992

By W. H. Durrell

DISCOVERY of large iron ore deposits in New Quebec and Labrador is, undoubtedly, one of the outstanding mining events of the twentieth century. To give an idea of size, the present concession is almost equivalent to a strip a mile wide around the earth at the equator. Importance of this iron ore area can best be appreciated by comparison to the famous Mesabi Range. On Mesabi, the area of favorable rock is 110 miles long and from 1 to 5 miles wide, with a, productive zone about 70 miles long. On the con- cessions the area of favorable rock in the Labrador Trough is 225 miles long and from 10 to 60 miles wide. In Quebec-Labrador, exploration already discloses that the productive zone is 90 miles long, with good chances of being extended at both ends. The Mesabi is covered generally by thick over- burden, and the iron ore deposits were found by T- test-pitting and systematic test-drilling. In Labrador and Quebec, most ore has been developed from a few surface deposits, and when it is considered that at least 95 pct of the area is covered by over- burden, and that there remains thousands of square miles of favorable territory still to be explored, it can be seen that the possibilities for developing additional ore are tremendous.

Jan 4, 1954

By R. A. Guidotti

The Federal Bureau of Mines has studied the reaction of oxides of columbium, vanadium, and tantalum with ammonia in vertical, gas-solids reactors at temperatures ranging from 300° to 1,300° C with the goal of preparing nitride intermediates for subsequent preparation of the metals by a thermal-decomposition step. The best nitride conversions were obtained in nonmetal reactors. With Cb205, V2O3, and V205 , low-temperature maxima in reaction rates occurred at 800°,800°, and 450° C, respectively, during oxynitride formation (in A1203) at 1 atm of pure ammonia. Conversion of the oxynitride, in a second step, to the mononitride was optimum at 1,200° C for columbium and 1,050° C for vanadium. In the case of Ta205, the rate of reaction to form Ta3N5 (in a single step) was highest at 900° C, where the presence of up to 5 percent methane was found to be beneficial; improved results were obtained by conducting the nitriding in a rotary kiln. Optimum space velocities (in the vertical Al203 reactor) ranged from 5,280 hr-1 for Cba205 to 7,950 hr-1 for V203. Oxide particle size had little effect upon reaction rates. Under fully optimized conditions, products containing less than 1 percent oxygen were readily obtained in under 6 hours.

Jan 1, 1975

By A. E. Halim, J. F. Brune

The 2006 Sago, Darby, and Aracoma mine disasters in the United States (US) forced the US government to implement the 2006 MINER Act and additional regulations that require all US underground coal mines to install and maintain refuge chambers to manage entrapment emergencies, in particular, fires and explosions. However, there is a debate on whether barricading in refuge chambers is a good strategy to survive such emergencies. Australian coal mines are not required to use refuge chambers and, instead, have adopted a strategy that focuses on instructing and training miners to self-escape to the surface. This paper analyzes merits and problems of using refuge chambers and self-escape to the surface to manage emergencies in fires or explosions in an underground coal mine. The authors found that the use of refuge chambers may not be the best strategy during extensive fires or when multiple explosions happen. In these situations, mine rescuers are unlikely able to extract miners who are sheltered in chambers and conversely, self-escape may save more lives than sheltering. Chances for successful self-escape are further improved by regular, externally assessed training such as Level 1 Emergency Exercises required in the Australian State of Queensland. These exercises put pressure on mine operators to ensure and maintain the effectiveness of their emergency management system.

By A. L. Johnson

In this Bureau of Mines report, time-resolved infrared emission spectra and corresponding pressure and temperature histories are reported for large-scale propagations of CH4-air, CH4-air-N2, and CH4-air-CF3Br ignitions in a 12-ft-diam sphere. Absolute spectral radiances were obtained throughout combustion over the 1.6- to 4.8-gym range, and the radiance growth patterns for the H20 (2.5-µm) bands are presented as a function of methane stoichiometry and diluent concentration. Flame temperatures were determined from the C02-band emissions, which approximated unit emissivity shortly after ignition. Burning velocities are also given for some of the test-mixture compositions. Measured flame temperatures were in excellent to fair agreement with theoretical adiabatic values for the CH.-air and CH4-air-N2 mixtures; the best agreement was for the stoichiometric CH4-air mixture. The CH4-air-CF3Br mixtures with =2 pct CF3Br gave poor agreement with theory. The measured temperatures were significantly lower during the early stage of combustion; furthermore, the later stage of combustion was uninhibited and yielded unexpectedly high pressures. Supplemental data from a 2-ft-diam sphere at various initial pressures confirmed that the CF3Br inhibition effectiveness decreases with increased pressure. The possible effects of buoyancy, turbulence, and changing kinetics are discussed.

Jan 1, 1977

By Hugh K. Taylor

"With some justification, people have long complained about the indefinition of ore reserves. Perhaps they were led to expect too much; from former and easier definition practices in the once common underground mines with exposed and available assets, where the obsolete term 'ore in sight' was at least partly literal. But such mines have become rarer, and their underground development less affordable. For most projects, valuations and its definitions have thus been advanced from actual to prospective mines, leaving a very wide gulf between 'what is there' and 'what may happen to it'. This brings the double challenges of reduced geological and technical assurance and the protraction of economic uncertainties.This paper avoids the popular field of regional resources, being confined to what may possibly be mined within single or closely grouped deposits. For these, many estimates of tonnage and grade must be made, defined and declared long before assessment of feasibility; and the uncertainties of the latter make it an unsound base for defining the earlier quantities. Despite the best of intentions, implied or inferred promises may proveimpossible to honour.A simpler framework of definitions is suggested, to some extent reverting to an earlier dependence on supporting work rather than on opinions of economic assurance or future events that are more properly the functions of production and cash flow schedules."

Jan 1, 1994

By C. A. Hansen

Page Introduction............................206 Power Characteristics in Zinc Sulfate Electrolysis........... 207 Current Efficiency......................... 207 Corrosion Rates..........................216 Voltage Required by the Zinc Cell..................219 Power Requirements of the Zinc Cell ................221 Impurities in Zinc Electrolyte.....................222 Non-cumulative Impurities.....................223 Cumulative Impurities ....................226 Impurities in General........................228 Temperature and the Stability of the Zinc Cell..............229 Practical Expedients for Control of the Zinc Cell...........234 Acknowledgments...........................234 Appendix................................235 Discussion...................:.......... - 236 Introduction It has been the experience of the writer, during some five years' work with electrolytic zinc, that the zinc cell is perhaps more sensitive to impurities in the electrolyte than the analytical methods as yet developed for the chemical identification and determination of these impurities; but that, when proper purification methods have been applied to a given solution, the behavior of the cell is quite independent of the original sources from which the zinc sulfate has been derived. It has also appeared that the behavior of the zinc cell is the best and surest check on the correctness and thoroughness of the purification methods used, because it indicates the presence of both current impurities and cumulative impurities derived from the leaching of the ore; it also indicates whether these impurities are current or cumulative, at least in so far as they are of serious importance commercially.

Jan 1, 1919

By R. G. Darmody

Longwall coal mining in southern Illinois occurs beneath some of the best agricultural land in the U.S. This region is characterized by highly productive, nearly level, and somewhat poorly drained soils. Subsidence from longwall mining causes changes in surface topography which alters surface and subsurface hydrology. These changes can adversely affect agricultural land by creating wet or ponded areas that can be deleterious to crop production. While most subsided areas show little impact from subsidence, some areas experience total crop failure. Coal companies are required by law to mitigate subsidence damage to cropland. The objective of this study was to test the effectiveness of mitigation in restoring grain yields to their pre-mined levels. The research was conducted on sites selected to represent conventional mitigation techniques on the predominate soils in the area. Corn (Zea mays L.) and soybean [Glycine max.(L.) Merr] yields in 1988, 1989, 1990, and 1991 from mitigated areas were compared to yields from nearby undisturbed areas. There was no significant (a=0.05) difference in soybean yields averaged over the four years. Average corn yields, however, were significantly lower than reference areas. The impact of subsidence and mitigation is variable and site specific. Results were also related to weather. In wet years, yields in mitigated areas tended to be depressed. This research demonstrated that mitigation of subsidence damage can be successful.

Jan 1, 1986

By V. Steinbach

Non-renewable mineral raw materials are grouped into three categories to investigate ways leading to sustainable use of natural resources: 1.) metallic resources, 2.) non-metallic resources with the exception of the fertilizer minerals, and 3) the fertilizer minerals for the nutrients nitrogen (N), potassium (K), and phosphorous (P). With the exception of minerals in Group 3 which are essential for plant growth, mankind does not need raw materials as such, only the intrinsic property of a material that fulfils a useful function. This is especially true for non-metallic materials. Metallic resources have the best chance to become renewable if one makes optimal use of the resources of the man-made technosphere. For the fertilizer elements K and N there does not exist a problem, because sea water or air respectively provide an inexhaustible source for them. This does not apply to P however. So P is serving as one of our apposite case studies for solving sustainability challenges. For all the challenges along the road from a non-sustainable to a sustainable resource economy technology can be envisioned to come to the rescue provided conditions that are considered to be essential for sustainable use for all natural resources-- affordable renewable energy and human ingenuity to find new solutions for functions, to optimize processes and to minimize losses-- are satisfied.

Jan 1, 2011

Following the preparation of tantalum oxide and carbide (1) an investigation of the details relating to the production of tantalum metal powder was planned. From the literature (2) it was evident that tantalum could be produced either by reduction of potassium tantalum fluoride with an alkali metal or by electrolysis of a fused salt mixture containing a tantalum compound. The latter method appeared to be the more suitable and, as there was considerable divergence of opinion in the literature as to the nature of the reactions involved, it was decided to study the electrolytic process. The ultimate aim in any case was to produce tantalum pOWder for use in an investigation of the problems relating to the preparation of consolidated tantalum.FACTORS GOVERNING ELECTROLYSISAfter a few preliminary exploratory electrolyses several factors which needed amplification were revealed. These will be mentioned before the details of the electrolysis experiments are given.COMPOSITION OF THE BATHWithout the knowledge gained in the preliminary experiments it would be thought that the best material for the bath would be that one which underwent electrolytic decomposition. Consider what at first appeared the most likely - namely - potassium tantalum fluoride. The melting point of K2TaF7 was determined to be 630°C with volatilization and decomposition taking place at that temperature so that it would not have been very satisfactory.

Jan 1, 1946

By Francis S. Kendorski

Underground stone mines tier construction aggregates and industrial minerals are being planned in increasing numbers throughout the United States. At the middle of the last century (1950s) underground stone mines were much more common, and characteristically had no thorough site characterization other than proving reserves and trial-and-error planning. Ground control employed was minimal. Consequently, there was a tendency to conduct minimal pre-mining studies. However, the deposits that lend themselves to little site characterization and minimal ground control are few today, with the best being mined out. Failures of a number of underground stone or similar mines from that era are more common than realized, Underground stone mines almost always use some combinations of square or rectangular pillars, sized to support the overburden load, and spaced to allow the use of larger, more-efficient equipment. Heights are controlled by the available stone quality, interbeds of waste, or technological or safety considerations. Prior to committing to a specific mine plan with subsequent significant capital investment, and prior to having available the wealth of knowledge and experience gained once mining underground, a safe and workable mine layout must he achieved. Early attention to the several different rock units involved (roof, mine level. floor) and their strength as a rock mass with the inherent discontinuities, will allow first approximations of acceptable mine geometries and sequencing.

Jan 1, 2000