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By L. B. Berger

Each winter brings its toll of deaths and serious accidents from the deadly gas, carbon monoxide. Newspapers carry warnings to the public of the dangers of this gas, and frequent now items retort the finding of persons dead or unconscious from the effects of carbon monoxide, yet these accidents continue. Either those warnings are not read, or they are unheeded by people who feel that "It can't happen to me." It can happen to you - carbon monoxide is no respecter of persons, as evidenced by items appearing daily in newspapers all over the country. Carbon monoxide has been a threat to human safety as long as man has used fire to keep himself warm and to cook his food. The burning of any fuel that contains carbon may produce carbon monoxide. This is true of solid fuels such as coal, coke, and wood; of liquid fuels such as oil, gasoline, and kerosene, and of gaseous fuels such as natural or manufactured gas. In the process of combustion the carbon in the fuel unites the chemically with tat oxygen of the air to form carbon dioxide (CO2), however, if the supply of air is not adequate, combustion is incomplete and carbon monoxide (CO) will be formed.

Jan 1, 1943

By J. Chen Kuriyama

One method to store hydrogen effectively involves the use of metal complexes such as the alkali-element aluminum hydrides. The hydriding/dehydriding properties of these materials depend on how to prepare them with different structures and microstructures. The present work focused on a high-energy ball milling technique to produce Ti-doped lithium tetrahydridoaluminate (LiA1H4) and lithium hexahydroalanate (Li3AIH6) powders with nanocrystallites. The phase structures and dehydriding/rehydriding characteristics were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller measurement, thermogravimetry, and differential scanning calorimetry. The mechanism of dehydrogenation and rehydrogenation was also examined by means of X-ray photoelectron spectroscopy (XPS). The results on the relation between the reversible hydrogen storage and catalysis function of the Ti-doped complex hydride indicate that both the homogenous distribution of Ti+AI nanoclusters and the Ti¬catalyst with Ti e> Ti3+ (Ti0/Ti2+/Ti3+) defect sites play important roles in optimizing the reversible hydrogen storage.

Jan 1, 2002

By Joseph Coffman

There are 14 operations that supply 97% of the Market Economy Country (MEC) manganese and contain nearly all of its resources. Six mines account for about 70% of the production and 85% of the resources; there are no known resources that are economically close to those that are currently being mined. Costs (January 1989 dollars) of producing manganese concentrates from the operations evaluated are estimated to range from $ 0.96 to $ 1.86 per long ton unit (ltu or 22.4 lb) of contained manganese. Total MEC demonstrated resources evaluated amount to about 1.2 billion tons of in situ ore containing 474 million tons of manganese. Identified resources amount to about 1.8 billion tons of in situ material. Key results of the study indicate the following: 1. The MEC supply of manganese will be from the currently mined resources well into the next century. 2. Centrally Planned Economy Countries (CPEC's) will be increasingly dependent on MEC manganese ore and concentrate in the future. 3. At the 1976 to 1987 demand increase rate, total MEC resource needed through the year 2000 would be about 282 million tons of in situ material. 4. Transportation and infrastructure support will continue to be major elements of production costs.

Jan 1, 1992

By Olexandr Gydin

The evolution of grain and dislocation structures during cold deformation of the new steel LH800 of Salzgitter AG is investigated in the frame of this work. The main feature of this material is its ability to air-harden by carbon content of about 0.1%. The initial ferrite structure of the metal provides high plasticity at cold deformation and subsequent heat treatment increases tensile strength approximately two times. Described are results of in-situ tensile tests in the SEM. SEM and TEM analysis of grain and dislocation structures evolution in samples, which have been uniaxially deformed to certain strains, are carried out. After statistical evaluation of results the grain elongation against strain is determined. A microstructure of a deep drawn cup is analyzed by means of SEM. A quantitative evaluation of grain elongation on the different cup zones and comparison of these data with prediction results based on tensile tests are carried out.

Jan 1, 2009

By T. B. M. Himawan

In this study, effect of thiosulphate and oxidation using oxygen were studied in arseno copper ore flotation. Single mineral study of chalcopyrite and tennantite in regard to the aforementioned techniques was also studied. Zeta potential, XPS, contact angle and floatability of single minerals were conducted for each treatment to understand the mechanism. It was revealed that the separation is best conducted in alkaline condition at where there will be interaction between thiosulphate and the mineral surface as well as the formation of hydroxide species in the oxidation using oxygen. From zeta potential of both thiosulphate and oxidation conditioning, it can be found that the reactivity of tennantite is much higher rather than chalcopyrite resulting higher rate of depression on both techniques as shown from contact angle and floatability of each mineral after treatment. XPS spectra confirmed qualitatively and quantitatively the existence of species responsible for the depression of each conditioning techniques. As for the copper ore flotation test, it is the oxidation using oxygen provides best performance after 60 minutes of oxidation. Keywords: tennantite, chalcopyrite, arseno copper ore A, thiosulphate, oxidation using oxygen

Sep 1, 2012

By M Haest, O Dominguez, D Mittrup

Technological innovations and emerging analytical capabilities are transforming the way drill samples are analysed, with real-time mineralogical analysis made possible. In addition, new business/technical requirements are challenging long standing processes to incorporate more sources of information during planning in order to improve compliance to plan during mining and processing. Unfortunately, the new sources of information that are added do not always have adequate protocols in place to ensure quality data is collected.Spectral data covering the visible – near – short wave – midwave – longwave range are routinely collected by the Geoscience and Exploration department at BHP Billiton Iron Ore for accurate mineralogical identification. These data are used for geological interpretations (logging and modelling) and prediction of physical variables (metallurgical and geotechnical properties).This paper introduces how sampling and quality assurance / quality control concepts have been applied in the spectral data process. The described routine for sampling, data collection/management and reconciliation has been developed to track system precision and accurately and consistently ensure the data is of high quality before it is used across the mining chain.CITATION:Mittrup, D, Dominguez, O and Haest, M, 2017. A new approach to implement quality assurance and quality control to technological innovations – quality of spectral data capture and processes in the minerals industry, in Proceedings Eighth World Conference on Sampling and Blending , pp 265–270 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By D. Milne, P. Germain, G. Sauriol

"The practical determination of optimum stope geometry has, until recently, been an art relying primarily on experience at a given operation. Due to the complex and variable nature of rock masses in situ, stopes are often designed either very conservatively, resulting in excess development, or non-conservative resulting in excessive dilution and, in some cases, in loss of ore reserves.The Geomechanics group of the Mining Technology Division, Centre de Recherche Noranda, uses a combination numerical modelling and empirical design techniques to optimize allowable stope geometries. The above methodology allows the optim ization of stope geometry for varying rockmass classifications within an operation or between different operations. Such techniques require the development of a thorough geotechnical database at each operation and are best used when calibrated to the specific operation through back analysis.This paper discusses the above optimization techniques in light of specific examples from the Noranda Group. The design methods, limitations and results are discussed.INTRODUCTIONMine design has traditionally referred to production planning, general facility layout, (i.e. ore passes, crusher stations, main haulage drifts, etc.) and ventilation design. The dimensioning and sequencing of the stopes and pillars, however, has been almost solely based on trial and error and precedent practice.More recently, numerical stress analysis has received much more attention as part of the design process. It is common now at many operations to look at the effect of proposed stope layouts and sequences on stress redistribution through the surrounding mine workings. Through calibration of actual stope and pillar behaviour in situ, one can then relate the model predictions to support requirements, safety problems, etc."

Jan 1, 1989

By A. J. Monhemius

"This paper reviews the history of modern iron-control processes in hydrometallurgy. Attention is paid to processes developed in the electrolytic zinc industry for removal of iron from zinc sulfate leach liquors and the problems faced by the industry in the safe disposal of the iron residues produced by these processes. Past lessons learned are projected onto current efforts to develop hydrometallurgical processes for treatment of copper sulfide concentrates. It is argued that any attempt to create a “hydrometallurgical copper smelter” will fail, unless methods are developed that can recover iron in a form that can be directly used by the steel or pigment industries.RÉSUMÉ Cet article passe en revue l’histoire des procédés modernes de contrôle du fer en hydrométallurgie. Il accordera une attention particulière aux procédés développés dans l’industrie du zinc électrolytique pour l’élimination du fer dans les liqueurs lixiviantes de sulfate de zinc anhydre, ainsi qu’aux problèmes rencontrés par l’industrie en termes d’élimination sans danger des résidus ferreux générés par ces procédés. En projetant les leçons tirées du passé sur les efforts actuels, on pourra développer des procédés hydrométallurgiques pour le traitement de concentrés de sulfure de cuivre. Beaucoup prétendent que toute tentative de créer une « fonderie de cuivre hydrométallurgique » échouera à moins de développer des méthodes permettant de récupérer le fer sous une forme pouvant directement être utilisée par les industries sidérurgique ou des pigmentsINTRODUCTIONThis paper resulted from an invitation to the author from the CIM’s Historical Metallurgy Committee to give a presentation on the early developments of iron control in hydrometallurgy. This was to take the form of a plenary lecture at the 4th Symposium on Iron Control in Hydrometallurgy, which formed part of the 28th International Mineral Processing Congress, held in Quebec City in September 2016.I was naturally flattered that the invitation was to give the lecture at an IMPC, the prestigious conference series that has been held since the 1950s. That this particular IMPC was to include the 4th Symposium on Iron Control in Hydrometallurgy, a conference series held only every 10 years, made the invitation even more appealing and appropriate. This was because I had been co-chairman of the First Symposium on Iron Control, together with my erstwhile colleague, John Dutrizac, which was held 30 years ago in Toronto."

Jan 1, 2017

By D. Sediako

Excessive residual stress in Al engine blocks may result in cylinder distortion which reduces engine operating efficiency. As such, neutron diffraction was used to measure residual strain along the Fe liners and Al, in the hoop, radial and axial orientations with respect to the cylinder axis, at the cylinder interbore region. Residual stresses were subsequently calculated using generalized Hooke's law and related to the microstructure along the cylinder bridge. The results suggest that the residual stresses in the Al interbore region are tensile and increased with depth in the axial direction of the cylinder. The increase in residual stress at the bottom of the cylinder coincides with a finer and more uniform microstructure in this region of the cylinder. The refinement in microstructure at the bottom of the cylinder likely increased alloy strength, thereby decreasing this section's susceptibility to distortion. This study successfully quantified the residual stress profiles in a heat treated engine block and related the stress profiles to an as-cast engine block.

Jan 1, 2011

By Art Frye, Lee Pratt, Gaichang Zhao, Greg Newman

This paper will discuss the Wight Pit wall slash at the Mount Polley open-pit copper-gold mine that scavenged a high grade block of ore from two double-benches of the pit wall. The Wight Pit orebody, discovered in 2003, is located in the Northeast of the property with the southeast pit wall approximately 50m (165ft) from the edge of Polley Lake. In early 2009, the Wight Pit was nearing completion while an estimated 150,000 tonnes (165,000 tons) of ore averaging a grade of 1.4% copper remained just inside the southeast pit wall. The ore block started 24m (78ft) above the pit floor and extended up another 48m (157ft) with a 70o plane defining the back of the block.

Jan 1, 2011

By P. G. Claridge, G. P. Holmes, M. A. Redfearn

"IntroductionThe purpose of this chapter is to describe current practices in operation and maintenance of flotation circuits in Canadian mineral processing plants. The chapter consists of five sections covering description of equipment, typical flow diagrams, operating practice, instrumentation and maintenance. The approach to this subject matter is intended to be practical in nature, hence no deeply technical treatment of flotation theory will be included.Flotation is an extremely common method of beneficiation of ores. Reasons are the relatively low cost of flotation compared to many other processes, the wide range of minerals to which flotation may be applied and the high efficiency of separation which can usually be achieved. The flotation process as we know it today has been developed within this century and it has had a major impact on the mining industry. While flotation is commonly considered to be important because it provides a relatively simple method of separating minerals in complex ores, the availability of flotation has also made a multitude of mineral deposits in Canada into economically viable mining operations because it allowed production of a concentrate of valuable minerals from the ore. These concentrates could then be transported from geographically remote locations to centraHzed plants for further processing, although the existence of the remote and perhaps small ore body alone would not have justified installation of metallurgical processing plants on site and the grade of ore would not have justified direct shipment of ore.Some of the more common minerals concentrated by flotation are sulphides of copper, nickel, cobalt, iron, zinc, molybdenum, lead and arsenic, as well as non-sulphides such as sodium chloride, potassium chloride, phosphates, silicates, chromite, fluorite, limestone and coal. Precious metals are also recovered by flotation, generally in association with another sulphide mineral."

Jan 1, 1989

By Y Zhang, Z Zhao

The green production of the steelmaking process has urgent requirements for fluorine-free fluxes. In this article, a new solid waste-based slagging flux was applied in the external dephosphorisation test of low silicon hot metal to replace the traditional fluorite-lime dephosphorisation slag. The results showed that under laboratory conditions, the new flux was utilised for smelting low-silicon molten iron with a phosphorus content of 0.10~0.13 wt per cent, the temperature of the molten iron was 1350°C and the slag amount was controlled at 2 per cent. Within ten minutes of smelting, the dephosphorisation rate of the molten iron reached more than 50 per cent. When making slag with new flux, the slag melting time was about 40 seconds and the P2O5 content in the final slag was higher than 8 wt per cent. In the industrial test of a 150 t molten iron ladle, under the same molten iron conditions, an out-of-furnace dephosphorisation test was conducted in the Kambara Reactor (KR) process. The flux material consumption per ton of steel was 8~10 kg. Within 15 minutes of smelting, the dephosphorisation rate of the molten iron was about 30 per cent. During flux slag making, the slag melting time was about three minutes and the P2O5 content in the final slag was higher than 6 wt per cent. This new solid waste-based flux has significant cost advantages and outof- furnace dephosphorisation effects and is expected to become the benchmark for a new generation of fluorine-free steelmaking fluxes.

Aug 21, 2024

By D Shuen, R Sales, D La Rosa

Semi-autogenous grinding (SAG) mill control is complex and depends on many dynamic process variables. Good control strategies ensure that a mill is operating as close to optimal as possible, resulting in significant economic benefits to an operation. Pueblo Viejo, a gold mine in the Dominican Republic, has been actively improving their control strategies since start-up in 2012, and one of these initiatives was to install an acoustic monitoring system on the SAG mill. The data from the system is used to optimise the mill’s performance by limiting the time the mill is either running too quiet or too loud. The lower limit is an indication that the charge in the mill is too high for efficient breakage or that the mill speed is too low and grinding media are not striking the toe of the charge. Conversely, when the acoustic emissions from the mill are too high, this can indicate that the balls are striking above the toe of the charge, resulting in inefficient grinding and excessive liner and lifter wear. Adjusting mill operating conditions to keep acoustic emissions in the ‘sweet spot’ between these limits results in more efficient grinding.Pueblo Viejo installed a Metso SmartEar™ to monitor the acoustic emissions of their SAG mill in January 2013. This system has been installed on many mills around the world and is specifically designed for optimising SAG mill control. One system output is the impact counter which measures steel-on-steel impacts on the mill shell. The impact counter uses both frequency and time domain analysis to approximate the number of ball impacts per minute. This method of analysis excludes parts of the sound signal not associated with steel-on-steel impacts and gives an accurate measure of this critical control parameter. After the acoustic system was installed, Pueblo Viejo collected data to determine the upper and lower limits for the impact count variable. The live data is available to the mill operators and it is used as one of the key operating variables to control the mill.Through continuous improvement and the use of advanced technologies like SmartEar™, Pueblo Viejo are improving the control and operation of their SAG mill, resulting in reduced liner wear, more efficient mill performance and optimised energy consumption. This paper discusses the installation of the system, and the measureable benefits obtained by using acoustic monitoring to control their SAG mill.CITATION:Shuen, D, Sales, R, Wortley, M and La Rosa, D, 2014. The benefits of using SmartEar™at Pueblo Viejo, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 297–304 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By R. L. Zick

The High Density Sludge Process was originally developed by Bethlehem Steel Corporation for use on acid mine drainage and diluted waste pickle liquor discharges requiring continuous chemical treatment systems. This work began in the early 1970s and was first put into practical use around 1973. To date there are approximately 15 operating systems which have been installed on mine drainage in the United States, and another 10 systems worldwide. Dense Sludge is an innovative and improved method for treating acidic metal bearing streams in a manner which minimizes the volumetric generation of sludge for disposal. The technology utilizes a sludge recycle process which forms particles that have a low affinity for water, unlike conventional metal hydroxide solids which contain tightly bound interstitial waters. Typical acid mine drainage streams contain high sulfate concentrations which combine with calcium ions in lime based treatment systems to form gypsum crystals. The physical form of this gypsum is radically altered when the Dense Sludge process is utilized compared to the form generated in conventional lime treatment systems. The characteristics of the metals particles are also changed in this process, as the metal hydroxides are converted to metal oxides. Slides No. 1 and No.2 show scanning electron micrographs of conventional and densified sludges illustrating these differences. The magnification used was 300X. The dense sludge particles settle faster, dewater more readily, are more easily pumped, and hold much less water than conventional precipitates. In some cases, because the metal content of the sludge is more concentrated, it can be economically recovered.

Jan 1, 1998

By R. K. Young

Producing a sound plant design for a major project requires hundreds of engineers and many drawings. Economical accomplishment of this task is based upon careful and orderly organization of the design team so that at all times there is a complete and workable staff but at no time a surplus of costly talent. This paper will describe the various stages in the development of plant design which normally follow the laboratory and pilot plant investigations discussed in other papers today. An outline of the procedures used in the assembling of a project design group, within an established engineering organization will be presented. Actual procedures may vary according to the size and character of the plant, the special requirements of the owner, and the make-up of the engineering organization performing the design, but most of the points covered will be found to be basic to any plant design project.

Jan 1, 1960

By Malcolm D. Flavel

Recent research into the mechanisms of crushing processes has led to the establishment of new criteria for the effective design and operation of comminution plants. This paper reviews this work and gives examples of the productivity gains and cost benefits that have been achieved in the practical application of these findings.

Jan 1, 1988

By Charles Zdazinsky

Many blasting applications in the mining industry demand that the hard rock being blasted remains structurally competent. For example, pre-splitting is a common technique to reduce fracturing, and operators of dimension stone quarries use this blasting method to eliminate overbreak. When pre-split design parameters are not applied correctly, there will be a redistribution of stresses within the rock, resulting in Blast Induced Rock Damage (BID). Advances in geophysical technology are enabling blast technicians to monitor BID and then use the results to correctly design their blasts.

Jan 1, 2011

By R. M. Graves, C. B. McKenzie, D. Barbour, D. W. Desnoyers

"Abstract -The prospective Tulks volcanic belt hosts five significant massive sulfide deposits, Tulks Prospect, Tulks East, Jack's Pond, Daniel's Pond and Victoria Mine, as well as numerous showings and indications throughout its 70 km outcrop length. Regionally, the 498 Ma sequence consists dominantly of felsic pyroclastic rocks and flows with interbedded mafic volcanic units and fine­ grained sediments, commonly graphitic. Contemporaneous granitoid rocks occur in the south half of the belt. Rocks usually display a strong NE-SW, steeply dipping, penetrative foliation and other shear-related high-strain fabrics. Facing directions are normally northwest, although there is local evidence of folding. Sulfide bodies and their alteration systems are deformed and shape-modified in the style of ambient strain.The Tulks, Tulks East and Jack's Pond prospects appear to occupy a similar stratigraphic level, on or near the contact between a thick felsic pile and an overlying broad, conductive package of graphitic sedimentary rocks. AU are pyritic deposits with well-developed footwall alteration systems. The Tulks prospect comprises four polymetallic lenses totalling 750 000 t. Three lenses constituting more than 6 000 000 t of sulfide mineralization are indicated at Tulks East but only the 210 000 t ""B"" lens contains significant base metals. Jack's Pond consists of a very extensive, zoned alteration complex in which four lenses of massive to semi-rnassive pyrite + chalcopyrite are known.The central part of the system, characterized by Mg chlorite and carbonate, is enveloped by pervasive sericitization and capped by intensely silicified and pyritized volcanics. The sulfide lenses are interpreted as part of the footwall zone and are beneath that part of the system most likely to host polymetallic massive sulfides.Daniel's Pond differs from the other prospects in such fundamental ways as metal content, associated alteration and structural setting. The deposit comprises strongly tectonized, Ag-rich, Zn-Pb mineralization distinguished by a pronounced Ba-As-Sb signature. Mineralization is confined to a narrow, north-south high-strain zone which separates unstrained mafic volcanic rocks to the east from well-foliated felsic rocks. The deposit Jacks an extensive alteration halo and at its north end is associated with a lens of barren, undeformed massive pyrite.The Victoria Mine deposit, the most cupriferous of the five, is related to a moderately dipping structure that separates well-foliated Tulks volcanic rocks from an overlying, Jess deformed volcanic­ sedimentary sequence that may be as young as 462 Ma. The structure is also the locus of black chlorite, dolomite and quartz alteration. Structurally remobilized precursor sulfide mineralization is one possible source for the deposit."

Jan 1, 1993

By I Jabou, D G. Blazak, L C. S Hogarth

The R70 test is a good indicator of coal reactivity to oxygen and is commonly used to provide a rating of propensity for self-heating. Tests performed by The University of Queensland Spontaneous Combustion Testing Laboratory have resulted in the development of a large database that shows the impact of coal quality on this parameter. From these results it is possible to infer an R70 value, which can be used to gain an appreciation of the intrinsic coal reactivity before it is even tested. However, any interpretation of R70 values must consider the influences of coal rank, mineral matter and moisture content to provide a better understanding of the spontaneous combustion risk of a particular coal.

Jan 1, 2005

By R. H. Sprute

The Bureau of Mines conducted a feasibility study and designed an operational system for consolidating waste coal sludge in a 110-acre pond by applying direct current between buried and floating electrodes. Consolidation would reduce the sludge to half its present volume, there-by extending the working life of the pond as well as creating a safe, stable impoundment. The project was conducted by the Bureau under an agreement with the Washington Irrigation and Development Co. (WIDCO), located near Centralia, WA. Part 1 of this report, published as Report of Investigation 8666 in 1982, covers the results of laboratory tests at the Bureau's Spokane Research Center and of a small-scale field test at WIDeO's coal preparation plant. Test results show the process is efficient and cost-effective when power is applied at low current density. Part 2 (this paper) describes a detailed design for an electrokinetic system to dewater WIDCO's 110-acre pond with a 27.4-acre electrode array. Densification of the inactive sludge pond will require 3.6 yr of treatment for a total cost of $1,450,000. The study and design are site specific, but design procedures and analyses are sufficiently detailed to serve as a guide for applying the process to any sludge pond.

Jan 1, 1988