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By T. Wajima

"A novel carbonaceous immobilizing agent for heavy metal contaminated soil was prepared from rice straw using sulfur immersion and pyrolysis, and the lead immobilization in artificial contaminated soils using sulfur-impregnated carbonaceous material was estimated. The rice straws were cut to 1 cm pieces, and then immersed in 0.1 - 1 M K2S solution for 0 - 24 h to prepare sulfur-immersed materials. The immersed-materials were heated at 400 oC for 1 h in nitrogen gas to produce the sulfur-impregnated carbonaceous material by pyrolysis. The abilities of the product to immobilize lead from aqueous solution were examined to obtain the product with high lead immobilization ability. With increasing K2S concentration, the immobilization ability of the product for lead gradually increases and then above 0.5 M K2S those are almost constant, while 15 min is sufficient for the immersed time to obtain the product with high lead immobilization ability. The product prepared from material immersed in more than 0.5 M K2S solution for less than 15 min has a maximum immobilization ability for lead ion. The lead immobilization using the sulfur-impregnated product is sustainable due to the formation of leadhillite [Pb4SO4(CO3)2(OH)2] and anglesite [PbSO4]. The product can immobilize lead ion in various artificial lead contaminated soils. By mixing artificial lead contaminated soil with the sulfur-impregnated product, the eluted solution became neutral, and the eluted concentrations of lead ion dropped below the Japanese elution standard for soil.INTRODUCTION Soil contamination with heavy metals is a worldwide problem. Accumulation of heavy metals in soils affect soil ecology, agricultural productivity, quality of agricultural products, water resources, and serious health problems for human and animal (Raicevic, et al., 2005). In the United States, for example, approximately 63 % of the sites on the National Priority List (NPL) for the treatment of contaminated soils are contaminated by metals, and lead is the most common metal, found at 15 % of the sites. In Japan, according to a report by the Ministry of Environment, 43 % of the contaminated sites that exceed the environmental quality standards are contaminated by lead compounds. Soil contamination by lead compounds is also prevalent in other developed and developing countries where lead compounds are used extensively in industrial activities without careful contamination management. Lead is a ubiquitous heavy metal pollutant in soils due to their use widely. The primary sources of Pb contamination include industrial activities such as mining, smelting of metals, and the use of Pb-containing products such as paints, lead-acid batteries, bullets, gasoline and pesticides (Cao, et al., 2009). It can damage human nervous (especially children) and reproductive systems (ATSDR, 2007). The high concentration of Pb in the soil poses risks to human and animal health by the leaching of metals from the soil into water and the consumption of edible plants growth in the contaminated soil. Therefore, proper remediation is necessary to reduce metal availability in soil for protecting human health."

Jan 1, 2018

By Daryl R. Tweeton

Bureau of Mines research in in situ uranium leaching includes injection well construction and environmental aspects. Clogging of injection wells is a common problem, and is affected by construction techniques. Part of the clogging can be caused by a low-permeability skin left on the borehole wall if the drilling fluids are not thoroughly flushed out. Certain polymer drilling fluids are less prone to cause clogging than bentonite muds, since a lower solids content can be used. The environmental research primarily involves two contracts. The first describes the environmental impact of in situ leaching and the effect of environmental legislation on leaching; the second describes the cost effectiveness of various methods of restoring ground water quality.

Jan 1, 1978

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By R. L. Teseneer

Pyrite samples from twenty-one locations in the North Carolina Slate Belt were analyzed for cobalt, gold, mercury, and nickel by atomic absorption spectrophotometry. The geographic distribution of relatively high values of certain trace elements in pyrite suggests that, in addition to gold, cobalt and nickel metallogenetic provinces are possible in the slate belt. Northwest trends of province boundaries may be genetically related to subsurface features rather than to surface geology. Within province boundaries gold and nickel exploration programs should be concentrated in areas containing intermediate to mafic tuffs, while cobalt may be more concentrated in argillites and phyllites.

Jan 1, 1979

The Arctic is a region of special economic, geopolitical, research, socio-ethnic, and defense interests of both Russia and other countries of the Arctic zone. Introduction of innovation technologies at ore-processing factories is a direct responsibility of the state and this problem should be solved on the basis of coordination of interests of different stakeholders. The task of elaboration of scientific principles of rational state regulation in the North is very topical. Innovations require considerable investments first of all from private capital. However as an investment object innovations are not attractive for investors as they require large expenditures for long-term projects, and they are connected to high risks because market incentives form striving to get quick profits of private companies and result in a certain behaviour strategy while innovations need ?long money?. Under such conditions without state regulation of investment and innovation activities development of the mining sector in the Arctic practically has no prospects. At innovation development of mining enterprises economic growth is provided at the expense of active state innovation activities. The elaborated strategy of ore-processing enterprises should correspond to the modern paradigm of the ore-processing industry development which is not only for extraction of minerals but also for multi-profile structure having comprehensive use of the resources on the rational basis intended for rational complex utilization of mineral resources of the AZR which by the definition includes maximally full use of the whole aggregate of resources on the economically rational basis with obligatory environmental with resource reproductive and socio-economic functions and deterrents. The main principle of creation of innovation technologies is to obtain more products of higher quality with minimal costs. This allows increasing ?productivity of the resources? several times. This principle makes increasing productivity of the resources the most important and in this case efficiency of use of the resources brings extra profits at the expense of lack of new costs such as payment for protection and utilization of wastes. According to the economic theory only ratio between demand and supply is able to fix optimal proportions in economy and to give necessary signals for investment activities of mining enterprises. In this context market for minerals and increase of mineral resources productivity do not create incentives for investment activities without which neither sustainable economic growth nor solution of macroeconomic tasks are possible. Nevertheless countries should not reject this idea in spite of economic efficiency of the enterprises. Extraction degree of useful components and especially oil in the Arctic zone is one of the lowest in the world. This can lead to crisis of oil industry and other mining sectors. The reason for that is lack of a state policy of realization of innovation technologies in the mining sector in the Arctic.

Jan 1, 2014

By O. M. Popoola, A. P. I. Popoola, D. O. Okanigbe, A. A. Adeleke

The physical, chemical, mineralogical and morphological characteristic of the waste copper smelter dust (CSD) from Palabora Copper (PTY), Limpopo, South Africa, has been reported in the open literature. The bulk of this material falls within the −53 μm particle size fraction with a copper weight percent of 18.02 as determined with the XRF. The high presence of reactive gangue minerals such as mullite (42.97 wt%) and quartz (11.45 wt%) necessitates that the waste CSD be first upgraded of its copper value in the falcon gravity concentrator before subsequent hydrometallurgical treatment. As an initial step, a sample preparation was carried out to make the sample amenable to both real density determination and copper upgrade experiment, thus resulting in 97% of the particles passing the 300 μm sieve aperture (d97 = 300). The laser particle size analyzer (LPSA) was used to analyze the d97 = 300 and the results showed a %change from 90.82% to 95.59%, with a real density of 2.830 for the waste CSD. The result of the copper upgrade showed that test 8 with treatment combination of 80 rpm and 4.5 l/min gave the highest % copper grade of 1.37 which is still less than the %grade of copper in the feed (1.49%). It thus lead to the recommendation that another type of centrifugal separator that will allow the introduction of the feed as slurry so that the pulp density and feed rate can factored into the whole upgrade experiment, consequently reducing the significant amount of losses and the chances of an improved grade and recovery of copper from this waste CSD.

Mar 1, 2018

By J. Trojacek

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20th century. Many uranium deposits were discovered in the territory of the Czech Republic. Over a period of 50 years approximately, 110 000 tons of uranium in concentrate were produced. Different mining methods were developed and used. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere ? Straz pod Ralskem where both mining methods ? the underground mining and the acidic in-situ leaching ? were used. The extensive production of uranium led to widespread environmental impacts and contamination of groundwaters. Over the period of ?chemical? leaching of uranium (ca. 32 years), a total of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approximately 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers an area larger than 27 km2. The influenced volume of groundwater is more than 380 million m3. The total amount of dissolved SO4 2- is about 3.6 million tons. Approximately 0.5 % of the contamination is located in the Turonian aquifer. After 1990, a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. The objectives of the remedial activities are the followings : to restore the aquifer to a condition guaranteeing continuing usability of Turonian water of Northern Bohemia Cretaceous, to decommission boreholes and surface installations and to incorporate the surface of leaching fields into the ecosystems taking into account regional systems of ecological stability and urban plans. Nowadays four main remedial technological installations for reaching of these aims are used - the ?Station for Acid Solutions Liquidation No. One?, the ?Mother liquor reprocessing? station, the ?Neutralization and Decontamination Station NDS 6? and the ?Neutralization and Decontamination Station NDS 10?. Total capacity of this complex is sufficient to reach the target values of remedial parameters in 2037. The remediation action consists of: pumping of residual solution to the surface, separating uranium from the solution and reprocessing contaminants into commercially usable or ecologically storable products. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 1.5 billion EUR.

Aug 1, 2013

By L A. Balzan, F Nieuwenhuys

GEOSCAN on belt analysers have been widely utilised in iron ore for nearly two decades. Since the first installations in 2003, the availability of accurate and reliable grade data has become standardised across iron ore mines in the Northern Cape in South Africa, where various streams are monitored continuously to ensure the optimal functioning of plants. Assmang Khumani has been at the forefront of technology adoption, and has implemented 19 GEOSCANs at various locations throughout the plant, monitoring run-of-mine, stockyard feed, beneficiation plant feeds, and products. Over the years, collaborative advances in the technology have allowed for numerous benefits and gains to be made. In recent times, there has been a concerted effort on the development of analysis for phosphorus in the material flows, and based on Scantech’s experience in the phosphate industry, this element has now been calibrated to achieve statistically acceptable and repeatable accuracies for real time analysis of this element on many of Khumani’s GEOSCAN analysers. This paper provides an overview of GEOSCAN use at Khumani, while focusing on the development of phosphorus analysis. A case study of analysis results is presented for a range of analysers that have been calibrated for this element, as well as a discussion on the benefits obtained as a result of this analysis.

Nov 8, 2021

By Doris Hiam-Gálvez

El presente trabajo describe las últimas tecnologías que mejoran la minería en América Latina y la eficacia en el procesamiento del mineral. Así también se revisa el modo innovador de energía a través de la fundición de sales con energía solar, particularmente en regiones desérticas de América del Sur. Cada tecnología ofrece mejoras sustanciales en eficiencia, capital, y costos operativos y contribuye a la reducción el impactom ambiental de las operaciones mineras.

Feb 1, 2012

By P. Plante

Contaminated neutral drainage (CND) is characterized by the presence of metal concentrations above regulatory requirements at circumneutral pH in mine drainage. The generation of CND by tailings and waste rocks is a growing concern for the mining industry due to increasingly restrictive regulatory requirements. Difficulties in CND prediction arise from the low oxidation rates of sulfide minerals and from the metal retention potential within the wastes. In fact, sorption phenomena may induce an important delay in the development of CND. For now, it is not possible to adequately consider this delay using the prediction tools developed for acid-mine drainage, such as humidity cells, columns and lysimeters. This work aims to present the new approaches currently under study for CND prediction, particularly the use of a chelating agent in kinetic tests. The main challenge of CND prediction is to quantify the metal retention potential of mine wastes, especially when sorption phenomena are involved in metal retention. Three approaches are currently used to overcome this difficulty. Firstly, the sorption potential is estimated using batch sorption studies. The second approach consists of artificially saturating the sorption potential of the mine waste by contact with a contaminated leachate in sorption-enabling conditions until saturation of the retention potential. These approaches both require that the possible metals involved in CND are known (as well as their chemical speciation) prior to the tests, which require an exhaustive material characterization. Although the two methods enable a qualitative estimation of the retention potential of mine wastes, their results are difficult to scale up from the laboratory to the field since some important parameters are not taken into account. A third proposed approach consists of inhibiting metal sorption at the source using chelating agents. The hypothesis is that chelating the metals immediately upon their release from the oxidation of sulfide minerals will inhibit all geochemical interactions (sorption, complexation, secondary mineral precipitation, ion exchange, etc.) between the metal and its environment. The ideal chelating agent will inhibit geochemical interactions after metal release in the drainage waters without having any impact on the sulfide oxidation and acid neutralisation rates. These approaches were tested over a waste rock sample that is known to naturally generate CND after a few decades of weathering. Results show that kinetic testing (weathering cell, ± 70 g samples) using a chelating agent (EDTA) in the leaching water renders higher metal concentrations in the leachates than a control sample without EDTA, suggesting that sorption (and possibly other geochemical interactions) is inhibited. These results suggest that the combination of these approaches can be efficiently used for more precise CND prediction from mine wastes. Future work will be done using the chelating agent approach over larger scale tests such as columns (± 80 kg samples) and field cells (± 100 tons) in order to propose an integrated approach for CND prediction.

Aug 1, 2013

By Warren D. Longwill

The Bureau of Mines inventoried Federal lands in the State of Oregon and classified them in detail, section by section, according to their availability for mineral exploration and development as affected by legal status and agency management practices. The Bureau determined areas of the State having past mineral production and/or known metallic mineral resources and areas favorable for coal, oil, gas, and geothermal resources, and prepared maps that spatially compare the availability of Federal mineral land with these mineral areas to demonstrate the extent of restrictions to mineral entry. Oregon contains 62.1 million acres, of which 33.9 million acres or 55% is Federal mineral land. About 2.3 million acres of Federal land is favorable for selected metallic mineral deposits, of which 64% is available, 13% is restricted, and 23% is unavailable. Of the 21.1 million acres of Federal leasable land favorable for oil and gas, 68% is available, 11 % is restricted, and 21 % is unavailable. Of the 146,720 acres favorable for coal, approximately 71% is available, 13% is restricted, and 16% is unavailable. Federal leasable land favorable for geothermal resources amounts to 458,968 acres, of which 42% is available, 34% is restricted, and 24% is unavailable.

Jan 1, 1988

By S. L. Pohlman

Physical characteristics of possible importance in the acid leaching of Chrysocolla have been evaluated. Surface area studies and pore size distribution indicate: 1) a large surface area (350 m /gm); 2) an average pore size of 13 or 16 Å , depending upon use of the adsorption, or desorption, branch of the Type IV isotherm in the evaluation; ) the presence of a significant fraction of pores of size less than 15 Å determined by the accumulation surface area method. The initial structure is micro- crystalline on the basis of x-ray powder patterns; the silica leach residue is amorphous and has only 24 m2 /gm surface area, and loses integrity when dry. However, readsorption of copper onto the wet leach residue gives a product with integrity and 100 m2 /gm surface area. Visual observation of the leach residues supports evidence of a non-protective diffusion mechanism of leaching which is well correlated by the shrinking core model previously presented.

Jan 1, 1976

By Ben DiFiore, Richard DePew, Nate Long, Adrian Naranjo-Castillo, Chris Petta, Robert Auber

The Walworth Run stream was brick-culverted in the 1800s, converting it to a 16-ft diameter sewer. This Cuyahoga River tributary contributed to the infamous burning river that became the catalyst for USA’s environmental movement. The NEORSD has been working hard to reduce CSOs here, most recently by diverting Walworth Run’s 882 MGD of flow to the new Westerly Tunnel. This had to consider structure age/size, alluvial/glaciolacustrine deposits (requiring several ground support systems, groundwater control), and maintenance of massive flows. This paper examines challenges identified during design that supported the contractor in development of a risk-mitigating plan, culminating to successful implementation.

Dec 1, 2022

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015

Study on Desulfurisation and Deashing for Medium-High Sulfur Coal Using Shaking Table As important coal resources, medium- high sulfur accounts for a significant part of the coal reserve in China. The environmental regulations and fuel standard requires sulfur and ash to be removed before it is used, so as to save energy and decrease the emission. Therefore, the effective desulfurisation and deashing technologies are urgent needed. However, due to the local characteristics of the coal, specific technology with optimum operation parameters is required to develop for different local coal. Qinglong is a district of Guizhou Province, which has large medium to high sulfur contained coal reserve. In this paper, medium-high sulfur coal is sampled from Qinglong, Guizhou province. Some basic characteristics such as the mineralogical composition of the coal rock, the monomer existing state and the granulometric composition are determined by X-ray diffraction quantitative analysis and polarisation microscope analysis respectively. Adopting the classified feed method, shaking table tests show that the feed pulp concentration is 20 per cent, the stroke is 13mm, the frequency of the stroke is 380 per min, the cross slope is 3¦ and the volume of wash water is 5.2 L per min. Under such condition, aggregate processed coal yield is 72.87 per cent and sulfur content decrease to 1.31 per cent With shaking table technology of 'First stage rough and intermediate further fine benefication', the yield of concentrate coal increased from 72.87 per cent to 81.21 per cent, while the sulfur content reduced to 1.35 per cent.

Sep 13, 2010

By R. J. Hickson

From 1993 through 1999, Cyprus Amax Minerals successfully completed eight major construction projects around the world. Six greenfield mines were brought into production, an ongoing operation was completely modernized and an environmental issue was appropriately remediated. The projects stretched over three continents: from arctic Russia to the Atacama Desert, from sea level to an elevation of 4,900 m (16,00Oft), from city suburbs to remote wilderness and from a low of US$130 million to more than US$ 1billion. The operations included open-pit and underground mines, mill and leach facilities and involved gold, copper, molybdenum and coal. The diversity of these projects inspired Cyprus Amax to create a "best-practices” project-management protocol to steer corporate expansion in the new millennium. This paper summarizes these best practices, while highlighting the project-management pirfalls to avoid.

Jan 1, 2000

By Maria Flessas, Justin Ray, Danielle Steinmetz, Brian Zuckerman

"The Ventura County Medical Center Hospital Replacement Wing project consists of the construction of a 2- to 3-story building with a basement encompassing the entire footprint and two corridors connecting the new hospital wing to existing buildings. The site is located in the Ventura Basin where strong ground shaking has been observed during moderate to large earthquakes on nearby faults. The upper 90 feet of the soil consists of loose to medium dense finegrained sands and low plasticity silts that are potentially susceptible to liquefaction, seismic densification, and hydroconsolidation. Ground settlement associated with a large seismic event on a nearby fault is estimated at 20 to 26 inches. To account for the anticipated ground settlement, auger pressure grouted (APG) piles gaining support below the potentially liquefiable soil were selected for the support of the proposed structure. Challenges for pile design included the anticipated earthquake-induced ground settlement, high downdrag loads, low soil lateral capacity during strong ground shaking, and the effect of pile installation on the performance of the existing adjacent buildings and the installed shoring system. The replacement hospital is supported on over 600 APG piles, with lengths varying between 120 and 140 feet. Axial pile capacities were verified with an extensive indicator pile installation program and dynamic pile load testing.INTRODUCTIONThe Hospital Replacement Wing (HRW) project is at the Ventura County Medical Center (VCMC) in Ventura County, Southern California (Figure 1). The VCMC consists of three interconnected hospital buildings (Buildings 303, 304, and Fainer Building), the Medical Laboratory/Cafeteria Building, two mental health buildings, a medical office building, an emergency generator building, and surface parking lots. The HRW is near the center of the campus, adjacent to several existing buildings.The HRW is a 2- to 3-story structure, with a 15- to 20-foot-deep basement beneath the entire 95,000-square-foot building footprint. The HRW project includes a Loading Dock, a four-level corridor to the Fainer Building (Fainer connector), and a two-level corridor to the Medical Laboratory/Cafeteria Building (Café connector). The corridors are structurally separated from the existing buildings. Typical dead plus live load column loads for the HRW range from about 635 kips to 935 kips and total loads range from about 860 kips to 1,295 kips."

Jan 1, 2016

Generation and Attachment of Submicron Size Bubbles to Colloidal Solids

Sep 13, 2010

By K. Cole, D. Mesa, P. R. Brito-Parada, M. R. van Heerden

Turbulence in stirred tank flotation vessels determines the bulk transport of particles and has an important role in particle-bubble collisions necessary for attachment. Positron emission particle tracking (PEPT) produces quantitative measurements of the kinematic motion of different particle classes inside flotation vessels. This paper presents flow profiles of the vessel, residence time distributions, flow profiles through the mesh and macroturbulent kinetic energy distributions as experienced by valuable (hydrophobic) mineral particles in a laboratory scale flotation vessel. The results highlight the impact of the rotor-stator design and a retrofit mesh modification at the upper part of the vessel which improve recovery by decreasing turbulence in the quiescent zone and at the interface. Keywords: Flotation machines, turbulence, PEPT

Jan 1, 2020