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By S. L. Gerhard

In the United States the performance characteristics of permissible explosives are controlled by routine tests, which include firing the explosive into a gallery filled with a methane-air mixture. These tests are made by the staff-of the Explosives Division of the Bureau of Mines and are similar, in general, to those employed in other countries. This control has helped to reduce the frequency of accidents involving the ignition of firedamp by explosives but has not clarified the basic causes of the ignition. To advance this control and to minimize potential hazards further, this fundamental knowledge is needed. Some of the results of recent research on the causes of the ignition are described herein. NATURE OF THE PROBLEM When an explosive ignites firedamp in the gallery tests, the source of the ignition must be one or more of the emissions from the steel borehole. It has been accepted generally that these emissions are (1) particles, (2) the shock wave, and (3) hot gases and flames. Photographs show that the shock wave emerges from the borehole first, followed closely by hot gases. At first the velocities of these are high and approximately equal, but the velocity of the gases decreases more rapidly than that of the shock wave, and by the time the reactions causing the flame are complete the shock wave travels in an otherwise undisturbed medium. The particles are originally enveloped in the hot gases but some soon begin to break through and eventually out-distance the shock wave. The approximate geometry of these emissions about 1 millisecond after the shot is fired is illustrated in figure

Jan 1, 1939

By S. L. Gerhard

In the United States the performance characteristics of permissible explosives are controlled by routine tests, which include firing the explosive into a gallery filled with a methane-air mixture. These tests are made by the staff of the Explosives Division of the Bureau of Mines and, are similar, in general, to those employed in other countries. This control has helped to reduce the frequency of accidents involving the ignition of firedamp by explosives but has not clarified the basic causes, of the ignition. To advance this control and to minimize potential hazards further, this fundamental knowledge is needed. Some of the results of recent research on the causes of the ignition are described herein. NATURE OF THE PROBLEM When an explosive ignites firedamp in the gallery tests, the source of the ignition must be one or more of the emissions from the steel borehole. It has been accepted generally that these emissions are (1) particles, (2) the shock wave, and (3) hot gases and flames. Photographs show that the shock wave emerges from the borehole first, followed closely by hot gases. At first the velocities of these are high and approximately equal, but the velocity of the gases decreases more' rapidly than that of the shock wave, and by the time the reactions causing the flame are complete the shock wave travels in an otherwise undisturbed medium. The particles are originally enveloped in the hot gases but some soon begin to break through and eventually out-distance the shock wave. The approximate geometry of these emissions about I millisecond after the shpt is fired is illustrated in figure

Jan 1, 1939

By C. W. Owings

A few of the more progressive mining companies have taken precautions to safeguard employees or man-trips. Specially constructed men-cars -have been provided with special devices or mechanisms to stop the cars on slopes, if the hoisting cable should break. Cars have been equipped with safety chains to connect and hold them together if a coupling should break. Steel frames covered with heavy wire netting have been placed over cars to reduce injuries to the riders from roof fails on slopes. A safety cable passing from the front car to a point above the cable socket on the slope hoisting cable is used frequently as a precaution in case the socket loosens o the main cable breaks at the socket. Such devices are commendable, but the percentage of man-cars and man-trips protected is relatively small - entirely too small. Man-trips that travel level haulage roads are rarely protected safety devices, and haulage roads are seldom inspected by mine officials to determine the condition of roof and ribs.

Jan 1, 1935

As 1979 drew to a close, it was obvious that China would have another good year with output of most industrial products at 3-9% above levels attained in 1978. Most increases were registered on the basis of maximum utilization of existing capacities and nationalization of procedures and methods. There were also distinct improvements in the quality and variety of products. Coal output probably surpassed the 650-Mt level in 1979. Steel output was expected to reach the 35-Mt level, an increase of nearly 10% over 1978. Based on the vast amount of housing and road and project construction, cement production more than likely surpassed 70 Mt. The nonferrous base metal industries improved somewhat in 1978, but actual output levels in recent years may have been a little higher than previously estimated by the outside world. Stagnate world demand slowed growth in the "export metals" sector. Minerals like magnesite and talc were produced at tonnages much larger than previously thought, with gold also falling into this category. Sulfur and pyrite production are still short, although a big pyrite mine was being brought into production. Barite out-put was reportedly up and fluorspar output held its own. Westerners generally concede that difficulties in transportation and power supply are holding back mineral production. Throughout 1979, basic construction continued on the majority of projects started by the Chinese and those few foreign projects contracted before the adjustment of industrial priorities. Foreign Ventures Perspective The foreign connection looms large in China's plan for modernization. In effect, it is an extension of what China wants to do in terms of "walking on two legs"-that is, develop what can be done locally to the fullest extent, then rely on international technology to move into the bigger and more complicated projects. Foreign projects are designed to complement domestic projects rather than replace them. Many foreign projects were started or continued by the Chinese in 1979. Building the necessary infrastructure for the projects is usually a Chinese endeavor and requires Chinese technicians and money. In areas with a strong economic base, this activity proceeds without foreign aid. In other areas, added funds are requested. Foreign funds can come in many forms-equipment technology, low interest loans, equity capital, advance-of-funds on the basis of future delivery in kind, and joint venture money. The Chinese are exploring all these avenues, with the strategy of minimizing foreign exchange needs for individual projects. They feel very uncomfortable with high interest rates, even though interest can be treated as operating ex¬pense rather than capital expense. Then there's the question of rights. Will Chinese sovereignty be affected? Can foreigners own land, in addition

Jan 3, 1980

By T. M. Gurr

In recent years the need for reducing energy costs has led many in search of alternative fuels, examples are gasohol, "cow power", oil shale, biomass, peat and many others. We have been involved with several peat resource evaluations and would like to share with you some of our observations and experiences. We hope our experiences may help you in your evaluation of existing or future projects where peat is considered as an energy resource. The items that we will cover are listed as follows: ? Peat Uses, Occurrences, and Characteristics ? Identifying Exploration Targets ? Peat Exploration ? Peat Prospecting and Reserves Analysis ? Peat Harvesting and Reclamation Assessments ? Summary and Conclusions

Jan 1, 1983

By W. G. Scott

IT IS APPROPRIATE that your Institute should have chosen, for its 1956 Annual General Meeting, the Capital City of a province which is making such rapid advances in mining. The railway industry is proud to be playing an active role in this development, expenditures on equipment and railway construction in the Province of Quebec alone in recent years being in ?excess of a quarter of a billion dollars. In looking up some background material for this address I ran across a definition of a mine by Mark Twain, the great American humorist, which I thought might amuse you. He said that a mine was "a hole in the ground owned by a liar". I am sure that if he were alive to witness the enormous value attached to Canada's mineral resources today he would quickly change his definition. Canada's postwar record of mining development has been staggering in its variety and enormity. Historically, only the ?construction of our transcontinental rail ways outranks the largest of three of these development projects - the aluminum undertaking at Kitimat; the Quebec-Labrador iron ore deposits ; and the petroleum and natural gas developments in Wes tern Canada.

Jan 1, 1956

By C. J. Edmonds, R. Bland, W. C. Ferguson, R. Whitehead

"In 1969, the Environmental Science Division of James F. MacLaren Limited received authorization from The International Nickel Company of Canada, Limited to carry out a water quality monitoring program in the Lake Shebandowan region of Ontario, where a new base metal mining and milling complex was expected to go into operation in 1972. The objective of the program is to establish base-line water quality characteristics. Fully realizing their corporate responsibility to minimize the effects of the proposed activities on the environment, Inco decided that it would be desirable to establish a program by which any change in the quality of environmental waters will be detected before detrimental conditions ensue, permitting prompt corrective measures to be taken. The program has been in progress for over two years. The waters are sampled and analyzed four to six times per year. Sampling stations are located in Lake Shebandowan and on the adjacent Gold Creek - Matawin River system. On-site analyses and measurements are made of flow, dissolved oxygen, temperature and pH. Samples also are collected for later analysis in the laboratory. These samples are analyzed for a wide range of chemical and biological characteristics. The paper discusses the extent of the sampling program, the techniques utilized and the value of such programs in maintaining the quality of the environment."

Jan 1, 1973

By C. H. Attwood

Introduction In presenting this paper on the water-power resources of the Province of Manitoba, it was considered that a brief resume of the power resources of Canada, of the power already developed, and its utilization in the industries 9f the country, would be of particular interest in showing the rapid progress that has already been made. Amongst Canada's national assets, water power occupies a foremost place because of the facilities it provides for the development of her other great natural resources. The rapid development of the mining, pulp and paper, and general manufacturing industries, and the concomitant growth in urbanization, with its numerous demands for domestic, commercial, and municipal service power, have combined to stimulate hydraulic development to a point surpassing even the most sanguine predictions of a few years ago. With the bringing into operation during 1928 of hydraulic turbines aggregating over 550,300 h.p., and of a further 378,400 h.p. in 1929, Canada's total hydraulic development at the end of 1929 amounted to over 5,700,000 h.p., and in this year, 1930, the active construction in hydro-electric plants throughout the country totals in excess of 1,600,000 h .p.

Jan 1, 1930

By Nick Karl, David Wilburn

"The mission of the U.S. Geological Survey (USGS) National Minerals Information Center (NMIC) is to collect, analyze and disseminate information on the domestic and international supply of and demand for minerals and mineral materials essential to the U.S. economy and national security. Understanding mineral exploration activities and trends assists government policy makers, minerals industry decision makers and research entities in identifying where future sources of mineral supply are likely to be discovered, the amount and type of these resources and factors that may affect exploration and development.This review summarizes significant exploration trends related to active sites and budgets, mineral commodities and regional factors for the years 2001-2015. Data were compiled by specialists in the USGS-NMIC, and reported annually in the USGS-NMIC Minerals Yearbook series and in the May issue of Mining Engineering magazine. External data for these analyses were derived from industry sources, published literature, and SNL Metals & Mining, an offering of S&P Global Market Intelligence (New York, NY).The USGS-NMIC compiled exploration site data for more than 80 mineral commodities, focusing on base metals, diamond and precious metals. More than $138 billion constant U.S. dollars were budgeted by the minerals industry from 2001 through 2015 to explore more than 16,000 mineral deposits globally (SNL Metals & Mining, 2016a). Annual analyses identified where mineral exploration took place by principal commodity target, ranked the magnitude of activity in each region, identified the factors that most affected changes in exploration activity and highlighted developments that led to changes in global supply or increased diversity of supply to the United States. Geographic classifications noted in this report were Africa, Australia, Canada, China, Latin America, Pacific, Russia, United States and Rest of the World."

Apr 1, 2017

By V M. Silva, P A. A Martins, V O. Matthew, A L. S Fonseca, E B. Cunha, A J. D Ferrari, E M. S Silva, A C. Silva, D R. T Vilela

The Anglo American phosphate mine is located in the Brazilian state of Goiás and possesses one of Brazil’s most important phosphate rock deposits, with the site being the country’s second largest producer of phosphate rock concentrate. Despite the site having been in operation since 1979, the mining team only started using explosives in 2004 when rocks with greater hardness started to appear in the mine’s geological profile. Rock excavation was previously performed mechanically. Until 2013, only rocks with high hardness were blasted, this following the standard drilling grid that was defined in 2004 without any changes in the blast parameters. The aim of this paper is to show how fragmentation optimisation has yielded positive results at all stages of the production chain, from the mine to the mill passing through an impact hammer crusher, a rod mill and ball mill, operating in close circuit with hydrocyclones.While incorporating the mine to mill holistic approach during the operational integration, the focus was on defining the blasting domains and respective optimal fragmentation and measuring the benefits of blasting in terms of reduction in energy and grinding media consumed in the comminution processes. In the first stage, the blasting team made changes to the blasting parameters and assessed the effects of these changes on fragmentation using computer software and on-site measurements. This generated a database that made it possible to divide the mine into blasting domains. For the second stage, teams from the plant, geology, mine planning and operation departments jointly made comparisons between the performance when processing stockpiles, which only included high hardness blasted ore (20–30 per cent of blasted ore). Changing the drilling grid’s size from 3.0 m × 3.8 m to 2.0 m × 2.6 m for high hardness rock with the presence of silicates resulted in a 40 per cent reduction in the P80 for the blasted material (from 459 to 278 mm), while changing the grid from 3.0 m × 3.8 m to 2.6 m × 3.2 m for high hardness rock without the presence of silicates generated a reduction of 25 per cent (from 270 to 204 mm). There were gains observed from the measurements at the mineral processing plant in terms of specific energy spent on comminution and on the consumption of grinding bodies in the rod mill. There was a measured reduction of circulating load during secondary grinding and a reduction in slime generation.CITATION:Silva, A C, Martins, P A A, Silva, E M S, Fonseca, A L S, Ferrari, A J D, Cunha, E B, Silva, V M, Matthew, V O and Vilela, D R T, 2015. Fragmentation optimisation – adopting mine to mill for reducing costs and increasing productivity, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 363–368 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By C. A. Fisher

THE Salt Creek Oil Field of Wyoming occupies a unique position among the major oil fields of this country. Many years before the beginning of actual production in this area, in 1911, it had attracted country-wide attention as a district holding oil possi¬bilities. Even foreign capital, mainly French and Belgian, had sought out this district as having oil values and spent many thousands of dollars 'in an effort to acquire property rights' in this field which was very largely located on the public domain. Owing to inadequate laws governing the acquisition of oil lands on the Federal domain and a careless practice having grown up among oil land locators of that time, a complicated title situation quickly developed in Salt Creek. This condition of uncertain titles together with the isolation of the field from industrial centers were doubtless the two most potent factors in retarding its early development. After actual production began in 1911 governmental regulations, suits between the government, and the locator, disputed ownerships between locators and claim and counterclaim continued to retard the field's development. It is believed that the title situation in the Salt Creek Field, where potential values of such magnitudes were involved, was responsible more than any other factor for the ultimate passage of the government leasing act in 1920 affecting all oil lands on the Federal domain.

Jan 1, 1925

By S. Nakamura, M. Takaoka, Y. Mizuno, T. Kusakabe

"Mercury is produced as a byproduct from gold mines and, historically, has been transferred to recyclers and used for various industrial processes and products. However, under the Minamata Convention on Mercury, adopted in 2013,the intentional use of mercury in processes or products will be minimized in the world. Surplus elemental mercury should be treated as a hazardous waste and consequently, should be converted to a more stable chemical form for long-term storage or permanent disposal. A stabilization method has been developed to react mercury and sulfur using a planetary ball mill. The planetary ball mill can produce high-energy conditions and enable samples to react within a short period of time. A series of tests has been conducted to confirm that mercury sulfide can be produced using a bench scale machine with 2400 mL pot. Under a suitable experimental condition with 25 mm ball diameter, 30%of ball filling rate and 1.05 of molar ratio of S/Hg, a powdered mercury sulfide product was successfully obtained in 60 minutes. The leach ability and atmospheric emission from the product was extremely low. This stabilization method would contribute to an environmentally sound mercury management strategy for the gold industry.INTRODUCTIONDue to its unique physical and chemical properties, mercury has numerous applications, including in industry and medicine. However, mercury and its compounds are highly toxic. For example, in Japan, methyl mercury in waste water caused Minamata disease in the 1950s, which affected large numbers of people (Minamata Disease Municipal Museum, 2001). In recent years, environmental pollution caused by emissions and releases of mercury into the atmosphere, waterbody and land by various emission sources such as coal fire plants, artisanal and small-scale gold mining (ASGM), non-ferrous metal industries, waste incinerations etc. has also become a significant problem. To protect human health and the environment from anthropogenic emissions and releases of mercury and its compounds, the Minamata Convention on Mercury was adopted in 2013(UNEP, 2013)Because ground gold ore typically contains mercury at 0 to 100 ppm, mercury is often produced as a byproduct from gold mines (UNEP, 2016). In gold mining operations, mercury can be released from the ore by roasting or by leaching in cyanide solutions and recovery onto activated carbon. According to Yanget al. (2016), 85.1%of mercury in a concentrate was vaporized during a roasting process. Both processes finally discharge elemental mercury as a byproduct. In the USA, more than 100 ton of mercury was discharged from large-scale and industrial gold mining (Miller, 2004)."

Jan 1, 2017

By A. W. Khair, M. Ahmad, L. D. Gehl

"This paper presents an analysis of the dynamics of bit wear on the productivity of the continuous miners. Two field surveys have been carried out. The first survey was to assess the impact of bit wear on productivity and production cost. The second survey was to study the wear characteristics of the cutting tool (i.e. magnitude, forms, and mechanisms of bit wear). Primary factors affecting bit wear is identified and laboratory experiments were carried out to study the effects of some of these primary factors on wear in detail. Results indicate that bit wear has a significant effect on the productivity of the continuous miners. Furthermore under the severe geologic conditions (i.e. cutting rock partings and roof and floor rocks) bit wear not only hampers the productivity, but also increases the production cost due to a higher number of bit consumption. This study also indicated that bit wear accelerates beyond 20% of the conical height loss which corresponds to 7% of the weight loss. This increase rate of wear is an indicative of higher abrasion between bit body and cutting material, resulting in a more dusty environment.IntroductionThe high demand for coal production has increased the need for mechanized coal cutting in underground coal mines. Continuous miners have been used in the United States of America for nearly four decades and now presently more than 2000 are in operation. Almost half of the underground coal production of the country is by continuous miners. Today, competition in the coal industry has increased, due mainly to market conditions and legal restrictions, thus placing an emphasis on production, efficiency, and safety. The use of continuous miners has resulted in the generation of respirable coal dust which causes black lung in mine workers. On the other hand, bit wear presents a serious problem as it affects productivity and economy.Much research in the put has been done on energy requirements and mechanism of energy dissipation for ideal rock fragmentation in the cutting process. Recently, dust hazards in underground coal mines as a result of coal cutting has been a great concern to mining engineers as well as environmentalist of the country. In past, much emphasize has been given to fragmentation mechanics (Khair et al, 1989), dust generation due to regrinding (Khair and Xu, 1991) and dust generation due to bit wear (Khair, Xu. and Ahmad, 1992). These studies concluded that dust concentration increased considerably after a bit weight loss of 7% and thereafter the bit should be replaced. Thus, legal restriction by the Mine Health and Safety Administration for the respirable dust concentration in underground might be a factor deciding the level or rate of production using continuous miners. While efforts in research are on reducing dust generation, it is also important and relevant to study bit wear in more detail.Bit wear is affected by three major groups of parameters: (1) machine operating parameters, (2) insitu conditions and (3) properties of rock. Again, past studies have shown that depth of cut, material of tool, position of water jet and velocity of the rotating drum are very important machine operating parameters. The content of the rock/coal material is important as bit wear is usually due to abrasion or adhesion. Diffusive wear becomes dominant only when the temperature exceeds the sensitive range i.e critical temperature. Mechanical tools have indicated that a rise in temperature is a function of drum velocity, properties of cutting material (rock or coal) and properties of tool. Bit wear due to chemical reaction and oxidation art almost negligible in coal cutting."

Nov 1, 1995

By Robert E. Murray

The title of my paper, "A Company's Response to Federal Coal Leasing," brings to mind a picture of a dog chasing its tail. This is what the coal industry, has been doing since the Federal coal leasing moratorium went into effect in 1971. We've gone around in many circles, but we are only very slowly, if at all, getting closer to catching our tails, i.e., efficient, economical, and rational Federal coal leasing. My companies, The North American Coal Corporation and its four Subsidiaries, The Falkirk and Western Plains Mining Companies and The Coteau and Missouri Valley Properties Companies, together hold in excess of 4.5 billion tons of lignite reserves in North Dakota. Some of our North Dakota properties are substantially interspersed with Federal coal, with the government holding title to the minerals in every other section. This checkerboard pattern of Federal ownership has made it difficult to develop and market some of our reserves, and, as a result, it has become imperative that we be familiar with and active in the Federal Coal Leasing Program.

Jan 1, 1982

By J P. van Dyk

A new crude ilmenite beneficiation process was recently proposed that allowed for the preparation of a smelter grade ilmenite from ilmenite with elevated chromium content. Magnetising roasting was not utilised in the process. As part of this circuit an ilmenite low susceptible reject stream was produced that had a low magnetic susceptibility. In this article a magnetising roasting process was investigated to beneficiate this material. Tests were conducted on material produced by pilot scale simulations on a typical South African East Coast heavy mineral reserve. The results obtained were compared to those published in literature for crude ilmenite. The small-scale experiments were used to define approximate operational limits for the oxidising roasting of a low susceptible ilmenite low susceptible reject stream, although industrial roasting conditions may differ significantly from those obtained in laboratory units. In a next phase these results will be confirmed on pilot plant scale.

Jan 1, 2001

By Jérôme Girard, Shiu Kam, Sue Longo

"Historically, tailings management in a northern climate has involved the deposition of tailings into the Tailings Management Area (TMA) as conventional slurry. This type of system is obviously viable but presents challenges that are difficult to manage as circumstances change over the life of mine. These issues can include:? Increases in mill throughput, and? Life of the TMA for the life of mine.This case study will present how thickened, high-density, non-segregating tailings are used as an alternative to conventional slurry disposal to achieve greater storage capacity and enhanced environmental performance for a gold tailings facility in a northern climate. This paper will focus on how this change in deposition strategy accommodated the increased throughput of the mill and the increased life of mine. Specifically, the paper will discuss the addition and integration of new processes to the exiting mill system to accommodate the tailings management issues. It will highlight the challenges from laboratory testing to pre-feasibility to the engineered design of the thickened tailings system implemented at Musselwhite Mine.BACKGROUNDGoldcorp Canada’s Musselwhite Mine, in Northwestern Ontario (120 km north of Pickle Lake), is an underground gold mining operation that began production in 1997. The current mill throughput is about 4000 tpd (1.4 Mtpa). Gold extraction is based on a CIP process with cyanide destruction.The existing tailings management area (TMA) is located about 2 km southwest of the mill complex. The TMA is contained by high ground to the north and to the west and flanged by a moraine ridge along the south side. A number of dams have been constructed along this ridge. The dams were first built in 1996 and subsequently raised in 2000 and again in 2005. Excess tailings pond water is discharged to a polishing pond then released to the environment via a wetland.The TMA was originally designed to contain 13.7 Mt of tailings under a ponded surface for closure. The water cover was to inhibit adverse long-term environmental effects because the tailings contain pyrrhotite and other sulphide-bearing minerals that are potentially acid generating. The design was modified during Stage 3 Construction in 2005 to expand the storage capacity to 17.3 Mt (Golder, 2005). As of end of 2009, over 16 Mt of tailings had been deposited in the TMA. The slurried tailings were historically deposited at 50% solids."

Jan 1, 2011

By Dawei Yu, Kinnor Chattopadhyay

In the nickel industry, molten slags produced from a Pierce-Smith converter contain significant amounts of valuable metals in the forms of oxides and physically entrained matte droplets. A slag cleaning step, which takes places in an electrical slag-cleaning furnace, is therefore required to recover the valuable metals as a common practice. Utilization of a waste material from aluminum industry (i.e. spent potlining) as a flux to improve the slag cleaning in terms of both the metal recovery and the operation efficiency was studied by simulation with FactSage program. Results show that the addition of SPL could substantially reduce the slag viscosity due to its fluoride values, thus accelerating the settling of matte droplets. The carbon value in the SPL could also help increase the metal recovery by reducing the valuable metal oxides followed by settling.

Jan 1, 2015

By S France

The Waterview Connection will complete a strategic Auckland motorway route linking the south, west and north. The project will comprise 2.5 km of ‘undrained’ driven tunnels and 900 m of drained cut-and-cover tunnel and portals.The project is aligned beneath a stream valley of Oakley Creek incised through alluvium and in places overlain by landfill, between Mt Albert volcano and a ridge formed in alternating sandstones and siltstones. The hydrogeology of the area is complex with perched aquifers in compressible soils, cascading water levels in fractured rock aquifers, and discontinuous higher permeability units resulting in artesian water levels and groundwater springs.Numerical groundwater modelling was undertaken to assess the potential effects of tunnel construction and long-term operation on the groundwater system; the magnitude and extent of changes in groundwater level and the resulting potential for settlement, buoyancy effects, contaminant migration and adverse effects on creek base flow. Modelling also provides inputs to tunnel design such as groundwater seepage volumes and water pressures.The driven tunnel will be ‘undrained’ long-term so potential effects on the groundwater system are limited to short-term dewatering during construction. Significant project time and cost savings can be made if the portal areas are permanently ‘drained’, but this means potential effects are greatest in the long term condition.This paper summarises the investigations, implications of the complex hydrogeological setting on tunnel design and environmental assessments, and groundwater modelling undertaken during the planning stage of this project. The groundwater modelling has been used to incorporate mitigation options in tunnel design and construction sequencing; a comprehensive monitoring program will be used to trigger appropriate responses should effects differ from those predicted.

Mar 8, 2011

By N. H. J. Freire, D. Majuste

In this paper, the effects of some organic compounds on the current efficiency, cell voltage and specific energy consumption during nickel electrowinning, and on the deposit features (morphology, crystallographic orientation and nanohardness) were described. The organics tested here (extractant, diluent, flocculant, lubricating oil and acid mist suppressant) are currently used in industrial plants. The results indicated that only the flocculant and acid mist suppressant exhibit relevant negative impacts on the current efficiency and energy consumption. The current efficiency dropped from 93.6 % (organic-free solutions) to 86.0 % and to 92.8% in electrolytes containing 100 mg.L-1 of acid mist suppressant and flocculant, respectively. At this concentration, their addition to the electrolyte led to increases of the specific energy consumption in the order of 18 % (acid mist supressant) and 2 % (flocculant). Cyclic voltammetry showed that Ni nucleation occurs at more negative potentials at 50 and 100 mg.L-1 of these organics in the electrolyte, thus indicating an inhibition of the deposition process. The deposit quality decreased at the higher concentration of all organics, when more hydrogen pitting was observed. The acid mist suppressant caused delamination of the Ni deposit at 50 and 100 mg.L-1. The addition of 100 mg.L-1 of flocculant and acid mist suppressant to the electrolyte increased the nanohardness of the deposit around 31 and 72%, respectively. The increase in Ni deposit hardness may lead to a decrease in the material ductility, thereby affecting the stripping and cutting of Ni sheets. Our findings may be helpful since strong adverse effect of some organics that may be present in the electrolyte were identified, thus the industry can control and optimize the organic´s dosage in the corresponding operations.

Jan 1, 2016

By H. E. Perlee

Autoignition temperatures and limits of flammability of nine halogenated hydrocarbons in atmospheres of air, oxygen, and nitrogen tetroxide were measured in a modified standard autoignition apparatus and limit-of-flammability apparatus previously developed at the Bureau of Nines. Of the nine halogenated hydrocarbons investigates--bromochloromethane, bromotrifluoromethane, bromochlorodifluoromethane, 1,1,2-trichlorotrifluoroethane, 1-bromo-l-chloro-2,2,2-trifluoroethane, dibromodifluoromethane, l,2-dibromo-1,1,2,2-tetrafluoro-ethane, 1,1,1,3,3-pentachlorotrifluoropropane, and l-bromo-2,4-dichloro-1,1,2, 3,3,4-hexafluorobutane--two formed flammable mixtures with nitrogen tetroxide and six with oxygen; none formed flammable mixtures with air. Three of the halogenated hydrocarbons formed no flammable zones with any of the three oxidizing atmospheres. For those halogenated hydrocarbons that supported combustion in oxygen atmospheres, explosion pressures developed during constant-volume burning of mixtures near the middle of the flammable zone were observed to range from about 6 psig for dibromodifluoromethane to 158 psig for 1-bromo-1-chloro-2,2,2-trifluoroethane. In all cases, the calculated burning velocities of these mixtures were less than 8 in/sec.

Jan 1, 1966