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By J. M. Mutamansky

"Coal mine dust research throughout the world has been stimulated by the recognition of its importance in the development of coal miners' diseases, particularly coal workers' pneumoconiosis (CWP). A historical look at the problem and the present state of knowledge in this area of importance to the worldwide coal industry is presented. A summary of progress made in this area is provided and some research ideas for the future are discussed.1. INTRODUCTIONI thank Dr. Yong Won John, President of the Korean Institute of Mineral and Mining Engineers, for his invitation to address the International Symposium on Coal Mining and Safety. This presents me with an interesting opportunity to take a broad look at the research in coal mine dust and where we are going. From this broad perspective, we can all view the progress and problems that are apparent in the present state of knowledge of coal mine dust. One important element in the review of coal mine dust research and its role in miners' diseases is that of its history. The existence of diseases attributed to the mine atmosphere is often traced back to Pliny the younger in the first century A.D. His work on natural history mentioned observed human effects attributed to mine fumes and vapors. However, the subject of the effects of dust in the mine was not mentioned in published literature until 1556 when Agricola discussed the ailments of miners in his day (Seaton 1975).For many centuries, many medical ailments of the lungs were often categorized together and distinct diseases were often not recognized until more modern times. The ability to distinguish different lung diseases was limited until the discovery of X-rays in 1986. Nonetheless, Zenker in 1866 applied the term pneumonokoniosis to any disease where dust gathers in the lymphatic depots of the lungs. This term was changed to pneumoconiosis in 1932. While pneumoconiosis was defined in the 1800s, scant attention was paid to control of miners' diseases until recent decades. The first attempt to control disease through control of the mine atmosphere has been attributed to the South Africans who instituted a silica control in 1910 (Drinker and Hatch 1954)."

Jan 1, 1989

By Cloyd D. McDowell

The Federal coal Mine Health and Safety Act of 1969 has been criticized by those who say it goes too far in controlling the activity of private enterprise and by those who say it does not go far enough in eliminating fatalities and accidents in an accident prone industry. Possibly a better evaluation of this legislation lies somewhere in between. From the viewpoint of the coal industry it can be said that through the efforts of those engaged in mining, both the operator and the miner, the year 1969 marked a record year in mine safety with only 190 fatalities and a frequency of 0.84 per million man hours exposure. This outstanding achievement compared to any previous was the result of a determined effort on the part of a concerned industry to improve its reputation as being the most hazardous industry in the nation. After the effective date of the Act, March 31, 1970, the Bureau of Mines assumed complete control of all safety and health activities of the mining industry. Unfortunately, there was no improvement in the safety record of underground mines in 1970 with the total of 255 fatal injuries and a frequency of 1.04 for the year. The number of fatalities declined to 177 in 1971 but the number of underground coal mines had declined from 5,955 to 2,268 during the two year period. Meanwhile, surface mined coal increased from about 38% of total production in 1969 to over 50% in 1971, keeping the annual production of coal at a normal level but involving fewer men.

Jan 1, 1973

By Bernard MacDonald

Introduction. OF the treatment of the slime-pulp of gold- and silver-ores by cyanidation, agitation is an essential part. When prepared for treatment, this pulp, consisting of ore reduced to such fineness that approximately 80 per cent. of it will pass through a 200-mesh screen, is mixed with a certain proportion of water, carrying in solution the quantity of cyanide (KCN) and other chemicals required. The water-constituent of the pulp thus prepared usually ranges from 1 to 2 parts by weight to 1 of the dry ore. Thus constituted', the pulp is charged into treatment-tanks, the shape and capacity of which vary, according to the quantity of pulp to be treated daily and the method of agitation to be employed. Tanks have no other function in a cyanide-plant than that of being economical and convenient containers or receptacles for holding the pulp, solution, or water used in the operations. It is by agitation that the solids in the pulp charged into the tanks are kept in suspension in, and mixed with, the solution in the proper proportions required for the treatment. If the proper mixture of solution to solids be determined to be 2 to 1 by weight (which is, approximately, 5 to 1 by volume), this proportion should be maintained in every part of the charge ; -that is, each solid particle of the pulp, whether it be of 180- or 400-mesh size, should, be surrounded by five times its own volume of solution throughout the whole period of treatment. The reason is, that the amount of chemicals ascertained to be necessary for dissolving the gold and silver contained in the solids, is held in uniform solution in the water-constituent of the pulp, and, therefore, the determined proportions of solution and solids must be maintained at all times during treat-

Apr 1, 1912

By Albert J. Phillips

FOR the most part, recent changes in nonferrous physical metallurgy have been gradual and of a transition nature rather than abrupt modifications of existing methods. Development of new alloys containing vital constituents in what formerly would have been considered minute amounts has necessitated more precise control of metallurgical procedure than ever before. Realization of the remarkable effects of minute amounts of specific foreign elements in many alloys has brought about a revolutionary control in the selection of even the most commonplace raw materials. In addition, recognition of the widespread occurrence of precipitation hardness in metal systems, and the utilization of many of these, has emphasized not only the need for precise temperature control but also the necessity for considering the time factor in its effect upon properties in the treatment of most metals. These needs have caused the development and widespread installation of equipment that permits precision of control undreamed of a generation ago.

Jan 1, 1935

By Brian Hart, Rong Fan, Roger Smart, Andrea Gerson, Ning Xu

A complete strategy has been developed for identification of the reasons for losses in recovery and/or grade, due to changes or complications in mineralogy and in mineral surface conditioning, and their subsequent correction. The sequence of methods starts with comparison of mineral phases between QEMSCAN/MLA (compositional) and Rietveld XRD (crystalline diffraction) with bulk assay reconciliation. This methodology has recently led to identification of unrecognised amorphous content (12-40 wt.%), previously attributed to crystalline phases, in the fine fraction (<35 µm) of some problematic flotation feeds. Attached amorphous silica, talc- and chlorite-like fines have direct influence on the hydrophobic/ hydrophilic ratio on value mineral surfaces adversely affecting flotation. SEM/EDS is used in the backscattered imaging mode to determine possible problems with liberation (e.g. remnant local locking), not detected in standard liberation analysis, resulting in gangue flotation. EDTA extraction is used to assess bulk feed pre-oxidation and sequential oxidation product loading through the circuit. Changes in circuit solutions are assayed with speciation modelling of precipitates and potentially adsorbing species. ToF-SIMS with principal component analysis is then used to correlate surface species with specific minerals and can be used to assess the effectiveness of specific reagents particularly collectors. This approach identifies unwanted activating species and interference with value surfaces by adsorbed hydrophilic ions, precipitates and fine particles. When the interference or ineffective reagents are specifically identified, remedial action can be targeted. This method has identified residual talc-like layers (<10 nm thick) inducing gangue flotation of pyroxene and chromite in PGM flotation. Recent case studies of application of the full methodology to losses of molybdenite at KUCC and to sphalerite activation in the Cu/Pb circuit at Brunswick Mines with remedial action are discussed.

Jan 1, 2014

By Michael G. Mayer

Since its invention in 1859 various designs of lead batteries have evolved to meet commercial needs for traction applications and standby power. In recent years major developments have taken place in lead alloys and the chemistry and mechanical design of industrial lead batteries. These are reviewed in relation to their commercial application together with the new type of maintenance free gas re-combination lead-acid batteries which are opening so many new markets for lead.

Jan 1, 1990

By John L. Mero

"The ocean has served humanity as a source of raw materials for thousands of years, but only on a minimal scale relative to its potential. Exploration programs have shown the ocean to contain a large number of mineral deposits of great extent and attractive grade. Recent research has indicated that a number of these deposits can be economically exploited with present-day technology and that the cost of winning many industrially important minerals from the oceanic deposits is potentially much less than that of winning similar minerals from land deposits. Although the finding of mineral deposits in the sea is a relatively simple matter at the present time, the exploitation of many of these deposits has lagged due to the lack of the availability of specific mining techniques for the individual deposits. Within the past two years, however, several developments have taken place in the design and testing of ocean mining systems in depths of water as great as 12,000 feet which indicate that the problem of mining in the ocean may soon be solved.Within the next decade, the ocean should prove to be a major source of many minerals for society and should come to dominate as a source of such metals as copper, nickel, cobalt, manganese, etc. Within a few years of the initiation of the mining of the deep-sea metalliferous nodules, land sources of such metals as nickel, cobalt, copper, manganese, etc. will be seriously affected and it is conceivable that the present structure of the world mining industry will undergo a substantial change in character."

Jan 1, 1972

By D. A. Karvonen

In 1970, the Government of Saskatchewan instituted a program aimed at resolving the dilemma of excess productive capacity over the market demand which existed for potash produced in Saskatchewan. The two primary elements of the program were prorationing of potash production to market demand and a minimum selling price. The paper reviews the factors, both local and international in nature that led to the introduction of the program. The licensing mechanics and the operation of the program, along with the changes that have been introduced in two and one-half years of operation, are discussed. Attention is given to the results of the controls as they affect the industry and the province. Also discussed is the outlook for Saskatchewan potash in world markets.

Jan 1, 1973

By Akira Nishikawa

During the twentieth century, the copper smelting industry achieved dramatic expansion corresponding to the vast growth of global economy. This was largely due to innovations in pyro-metallurgical processes, such as autogenous smelting and continuous smelting and converting technologies. However, as copper production capacity increased, its impact on the environment also could not be ignored, and thus with increasing global environmental awareness, many smelting operations either had to renew or rebuild their facilities. In addition to these changes, in places like Japan and Europe, with scarce primary resources, the treatment and recovery of metals from a variety of items such as car shredder dust, used electrical appliances and electronic devices, on top of scraps traditionally treated, is having a profound effect on the reduction of waste and the preservation of primary resources. Thus compared to the days when copper smelting focused on the environmental control in order to break with "Smoke Stack Industry", copper smelting today is making an important contribution to the sustainable development of human society.

Jan 1, 2003

By Akira Nishikawa

During the twentieth century the copper smelting industry achieved dramatic expansion corresponding to the vast growth of global economy. This was largely due to innovations in pyro-metallurgical processes, such as autogenous smelting and continuous smelting and converting technologies. However, as copper production capacity increased, its impact on the environment also could not be ignored, and thus with increasing global environmental awareness, many smelting operations either had to renew or rebuild their facilities. In addition to these changes, in places like Japan and Europe, with scarce primary resources, the treatment and recovery of metals from a variety of items such as car shredder dust, used electrical appliances and electronic devices, on top of scraps traditionally treated, is having a profound effect on the reduction of waste and the preservation of primary resources. Thus compared to the days when copper smelting focused on the environmental control in order to break with "Smoke Stack Industry", copper smelting today is making an important contribution to the sustainable development of human society.

Jan 1, 2003

By C Parihar, R Garg, A Bhandari, S Bhandari

Blasting can impact the efficiency of entire downstream mining operation. Individual technology solutions for blasting have been available in the industry for many years but all of them only cater for certain aspects of blasting. Many of them are based on individual research and/or experiences. Some of the available software solutions are not suitable to be used in the field as that they need advanced skills or tools. Also, most do not take technology advancements like mobility, advanced data analytics, web solutions and integration into consideration. Hence, no technology platform is currently present in the industry that addresses all potential needs a blaster may need in an integrated manner.This paper presents an integrated solution that takes care of all aspects of blasting – design blasts according to mine plan; collect data after drilling has been carried out (as there is often difference in designed and actual drilled hole locations in the field); predict blast results in terms of fragmentation, flyrock, ground and air vibrations, wave front reinforcement and flyrock distance; and after assessment, allows changes in charging, delay timing and sequence. The technology solution is a secure, cloud-hosted, web-based software-as-a-service solution that can be accessed from anywhere. Also it has a mobile app, which is available for both Android and iPhone/iPad. The mobile app is also integrated with the web-based solution using application programming interface calls to the central data repository.Case studies for two limestone mines are presented where this solution is being used in its initial format. This software platform enabled analysis of the outcome from a previous blast pattern and then subsequently allowed optimisation of blasting operations based on historical data. Uses of this platform have resulted in improved key performance indicators in these two limestone mines. The mobile app as part of this platform enables extensive field blast data capture and analysis and also various predictions before a blast. Data collected include blast parameters, individual hole charging, initiation pattern, videos, photographs and vibration records for analysis/reporting. The key features of the solution are a blast designer, a detailed blast data collection/analysis and a series of environmental predictors. These predictors give blast results in terms of fragmentation, flyrock, ground and air vibrations and wave front reinforcement and take remedial steps before blasting to optimise and control adverse environmental impact. Many features, such as fragmentation predictor and mobility solution, are completely unique features that are not available elsewhere in such a field personnel-friendly manner.CITATION:Bhandari, S, Parihar, C, Garg, R and Bhandari, A, 2015. An integrated technology solution for optimised and environmentally-controlled blasts, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 393–400 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By R. K. Singhal

In an underground coal mining environment, a frictional ignition may be defined as the ignition of an explosive air/ methane/coal dust mixture by mining machinery. As the use of power loading equipment has become more widespread, frictional ignition incidents have increased. There have been many fatalities and injuries from this cause including the death of eleven miners in Sydney coalfield of Nova Scotia, Canada in 1979. This paper reports on the findings of a preliminary study carried out under the auspices of the Coal Research Laboratories, Department of Energy, Mines and Resources Canada. The objective of this study has been to identify a Longwall face cutting system that is inherently safer than the conventional shearer loaders used in Nova Scotia.

Jan 1, 1985

By Michael M. Hamilton

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied a 37,542-acre portion of the 57,002-acre Riordan?s Well Wilderness Study Area (NV-040-166) in order to evaluate its mineral resources. The area studied is located in Nye County, NV, about 60 miles southwest of Ely, NV. Subeconomic mineral resources of limestone and sand and gravel were identified in the study area. The Troy and Irwin mining districts, 4 miles to the west, were active between 1868 and 1963, producing small amounts of gold, silver, lead, and tungsten from mines well outside the study area. Except for minor prospecting activity, most mining activity in the study area has been since 1980, consisting of claim locations and geochemical surveys.

Jan 1, 1987

By M Araos, I Onederra

A novel explosive formulation that substitutes the use of ammonium nitrate (AN) with hydrogen peroxide (HP) as the main oxidising agent has been developed and tested as part of an Australian Coal Industry Research Program (ACARP) project. The main objective was to provide a step-change solution that has the potential to completely eliminate NOx fumes in blasting. The development of this HP/fuel-based explosive started with a comprehensive detonation characterisation program, consisting of unconfined velocity of detonation (VOD) measurements of samples at different diameters, densities and void sensitisation techniques. VOD results showed that the HP/fuel-based explosive mixtures behaved similarly to non-ideal commercial explosives; in that way mixtures could be tailored to achieve specific detonation performance targets. The next stage of testing in this development involved preliminary confined tests to evaluate the rock breakage potential of the HP/fuel-based explosive mixtures. Fully instrumented single-hole tests were conducted in a limestone quarry. Results from these preliminary trials confirmed the rock breakage performance of HP/fuel-based explosive mixtures. The confined VOD measured in one of the tests was 5100 m/s in a 102 mm diameter blasthole at a density of 0.96 g/ml. The corresponding borehole pressure measurement of this HP charge was 2.61 GPa with a detonation temperature of 2921&#176;C. Based on near-field accelerations, both HP and ANFO charges displayed similar attenuation characteristics in the test conditions. Post-blast observations indicated that the breakage performance of the HP mixtures clearly reflected the in-hole detonation performance measurements obtained, confirming the ability of these explosive mixtures to both fragment and effectively displace the rock mass under evaluation. Further research work continues with the future commissioning of a prototype mixing and delivery unit, the successful completion and analysis of data from multiple-hole trials, and further characterisation work associated with product stability, reliability and performance under different geotechnical conditions.CITATION:Onederra, I and Araos, M, 2015. Detonation and breakage performance of a hydrogen peroxide-based explosive formulation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 565–574 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner (SPL), obtained at the end of the pots life contains a small amount of cyanide and fluoride which present environmental problems. SPL became a listed hazardous waste under RCRA (K088) in July, 1990. One of the possible uses of spent potliner is as a substitute for Calcium Fluoride (CaF2) as a fluidizer in iron-and steel making and in the glass industry. A low viscosity and a low melting point are prime requirements for accomplishing the above. In the present study, viscosity measurements were performed. Effect of various additives, such as sand, limestone, dicalcium silicate dust, and MgO baghouse dust on the viscosity of SPL was studied. The results showed that with the addition of sand and limestone, very high fluidity of SPL melt can be obtained at significantly low temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 1999

?It is not the strongest of the species that survives, nor the most intelligent. It is the one that is most adaptable to change.? Charles Darwin. Canada?s mining and exploration companies have evolved over the past century from essentially a pick-and-shovel industry to a high-tech industrial sector. This evolution has occurred in fits and starts, and has been driven by the shifting environment of economic, technical and social opportunities and pressures in Canada. As labour costs have gone up, and labour availability has gone down, the industry has evolved more efficient processes. As mineral prices have increased or fallen, the industry has evolved either by expanding or shrinking production, or by changing processes to adapt to the newly prevailing conditions. As stringent environmental protection legislation has been implemented, the industry has adapted accordingly, and has substantially changed its mindset to incorporate sustainability into its way of doing business. These changes have occurred over a number of decades, and have usually occurred as the industry?s reluctant response to pressures it couldn?t evade. This model mirrors the classical paradigm of natural selection where evolution is driven by pressures external to the organism (or organization) ? change occurs to the degree necessary for survival and prosperity, but generally no further. In recent years a new paradigm has started to come into play in Canadian mining and exploration. Rather than only a reactive response to the external economic, social and technical factors, groups within the mining community are becoming proactive in developing strategies for future adaptive change. Instead of each against the other, they are developing more sophisticated paradigms where they can both compete against (such as in marketing) and cooperate with (such as for tech development) their fellow organizations. Most importantly, they are seeing individual and national advantage in a collaborative Canadian approach to address the advantages of overseas competitors who often have lower labour costs, lesser environmental standards, or more accessible markets and transportation. This has translated into large-scale mining community support for the Canada Mining Innovation Council, and its programs in exploration, mining, processing, HR development, energy and environmental stewardship. This new paradigm is adaptive to the current environment but is substantially different from the older way of doing business in two major ways ? it is based on a collaborative approach to competitive advantage, and it is highly proactive rather than reactive. All the programs have their priorities determined principally by the mining and exploration companies, whose first obligation is to determine the long-term research priorities of the industry as a whole, rather than for their individual companies. Only after industry consensus on priorities does the research community become engaged in the implementation of specific projects to address those identified priorities. A goal of the program is to effectively create a virtual mining research laboratory, by engaging all the major research centres in the country. This approach is being actively adopted by much of the Canadian mining community, and argues well for the adaptability and long-term survival of mining in Canada.

Aug 1, 2013

By Dalton. J. L., H. P. Dibbs

An account is given of investigations into the application of two neutron methods to the on-line analysis of slurries. One deals with the application of the neutron moisture gauge principle to the determination of the water content of iron oxide slurries, and the other with the application of gamma radiation from thermal-neutron-capture to the determination of the composition of aqueous slurries of iron oxide, copper oxide, zinc oxide and sulphur. Linear relationships were found between the composition of the slurry and the neutron count-rate in the first study, and between the slurry composition and the prompt-gamma-ray count-rate in the second study. A mathematical relationship has also been developed which relates changes in the prompt-gamma-ray counts from hydrogen to changes in slurry composition.

Jan 1, 1973

By Michael Gauna, Christopher Mark

"Underground coal mining in the U.S. is conducted in numerous regions where previous workings exist above and/or below an actively mined seam. Miners know that overlying or underlying fully extracted coal areas, also known as gob regions, can result in abutment stresses that affect the active mining. If there was no full extraction, and the past mining consists entirely of intact pillars, the stresses on the active seam are usually minimal. However, experience has shown that in some situations there has been sufficient yielding in overlying or underlying pillar systems to cause stress transfer to the adjoining larger pillars or barriers, which in turn, transfer significant stresses onto the workings of the active seam. In other words, the overlying or underlying pillar system behaves as a ""pseudo gob."" The presence of a pseudo gob is often unexpected, and the consequences can be severe. This paper presents several case histories, summarized briefly below, that illustrate pseudo gob phenomenon:• Pillar rib degradation at a West Virginia mine at 1100-foot (335 m) depth that contributed to a rib roll fatality.• Pillar rib deterioration at a Western Kentucky mine at 570-foot (175 m) depth that required pillar size adjustment and installation of supplemental bolting.• Roof deterioration at an eastern Kentucky mine at 1300- foot ( 400 m) depth that stopped mine advance and required redirecting the section development.• Coal burst on development at an eastern Kentucky mine at 1700-foot (520 m) depth that had no nearby pillar recovery.• Coal burst on development at a West Virginia mine at the relatively shallow depth of 1100 feet (335 m) that also had no nearby pillar recovery.The paper provides guidance so that when an operation encounters a potential pseudo gob stress interaction the hazard can be mitigated based on an understanding of the mechanism encountered.INTRODUCTIONThe U.S. underground coal mining industry has conducted mining in multiple seam environments, where the active mining has underlying or overlying old workings at varying interburden distances, throughout its history. Often no serious consequences arise from the multiple seam mining. However, sometime mines have been confronted with hazards from underlying or overlying workings that include localized roof and rib failure, pillar system failures through propagating roof falls and floor heave, and also pillar bursts."

Jan 1, 2016

By J. A. Bustnes

The present work deals with kinetic studies of the reduction of molybdenum- and tungsten oxides by hydrogen. The experimental method used was therrnogravimetry under isothermal as well as non-isothermal conditions. The non-isothermal kinetics in the case of the reduction of MOO, to Moo2 has been modeled considering surface reaction as rate- controlling. In the case of the reduction of W02 to W a model was developed on the basis of the movement of the reaction front. The activation energies calculated on the basis of the models were in good agreement with those derived from isothermal experiments.

Jan 1, 1994

By Richard L. Ashbrook, John F. Wallace

Several high-temperature eutectics of cobalt and nickel alloys were modified by small additions of selected elements. Thes-e alloys were compared to unmodified melts for microstructural variations. A few modified compositions were selected on the basis of structure and their tensile and stress-rupture behavior determined. The results of stress-rupture tests in air at 1800 F and room-temperature tensile tests of four high-temperature eutectics showed modification capable of producing substantial improvements in properties. The microstructures were altered and mechanical properties improved by: a.) dispersing a subordinate phase more uniformly throughout the matrix; b) replacing large continuous -network or platelike constituents with small equiaxed discontinuous phases; and c) by forming new, finely divided phases. tHE term "modification" is most commonly used to describe the refinement in microstructure of the Al-Si eutectic that occurs as a result of rapid cooling from the melt or on slow cooling after treatment with small amounts of sodium.1 "Modification" has also been used to describe the change from flake to spheroidal graphite in the austenite-graphite eutectic of cast iron.2 This change of graphite shape is accomplished by small additions of cerium or magnesium.3 Other systems have also been shown to be capable of modification, for example: Pb-Sn by copper;4 Al-Cu by sodium;5 Al-Mn by sodium;5 and Pb-Sb by aluminum.5 Although modification of Al-Si alloys and cast irons is usually accompanied by improved mechanical properties, a general definition of modification has been suggested to include the effect of small quantities of impurity elements on the microstructures of all eutectic alloys, regardless of the effect on the mechanical properties.6 In this paper, the term "modification" is employed in a broad sense to include the formation of third phases or even the supplanting of one of the binary eutectic phases by a third phase. The mechanism of modification, as for any solidification phenomenon, must be considered primarily in terms of nucleation and growth. Although both nuclea-tion and growth mechanisms are required to explain all the phenomena observed in connection with the solidification of modified eutectics, various investigators have usually favored one or the other.7"16 It has been shown that modification of a binary eutectic can be effected by addition of a solute element that has greatly different distribution coefficients or k values in the two phases of the eutectic. Under these conditions, differences in the temperatures at the solid-liquid interfaces of the two phases retard the growth of one phase with respect to the other.4 It has also been shown that increased undercooling favors a transition from a rodlike eutectic to a globular eutectic.17 A mechanism proposed for the transition from lamellar to rodlike eutectics depends on the concept of constitutional super cooling.18 The modification of eutectic alloys may be of interest for high-temperature service as well as at room temperature. Although "high-temperature eutectic alloys" may appear to be a contradiction in terms, many eutectic systems, including those studied in this work, have melting points in excess of 2400°F. One of the mechanisms by which high-temperature alloys are strengthened is dispersion of a relatively brittle phase such as an oxide, carbide, or an inter-metallic compound throughout a ductile matrix. For a given volume fraction of dispersed phase, strength is increased by decreasing the size and spacing of the dispersed particles.19&apos;20 Furthermore, room-temperature ductility may also be increased by changing the shape of a brittle dispersed phase from platelike to equiaxed or spheroidal.8 Overaging and redissolving of the secondary phase limit the maximum temperature to which precipitation-hardened alloys can be used. However, in a binary eutectic system, both phases coexist up to the melting point. Although all eutectic structures are not completely stable,21 a dispersion-hardened cast high-temperature alloy might result if a fine distribution of one of the eutectic phases could be obtained during solidification. An additional reason for interest in eutectic alloys is their excellent castability.22 Since eutectic alloys, like pure metals, freeze at a single temperature rather than over a range of temperatures, their castability is superior to solid-solution alloys with long liquidus to solidus ranges. The purpose of this research was to study the effects of small solute additions on the microstructure and mechanical properties of a number of high-melting-point eutectic compositions.

Jan 1, 1967