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By Ximeng Zhu

The electrochemical behavior of mineral and coal pyrites in stirred and quiescent alkaline boratelsulfate solutions @H 7.9-10.5) have been investigated using cyclic voltammetry. Significant differences in the electrochemical response of these pyrites were observed. At the mineral pyrite surface, three anodic peaks at about -0.8 V, -0.1 V and +0.5 V (SCE) have been detected along with their corresponding reduction peaks. The first two peaks correspond to FeIFeOI) and FeOI)lFe(III) oxidation. The third peak is present for quiescent conditions but disappears as a distinct peak when the electrolyte is stirred. In the upper voltage region +0.30V (SCE), the current increases markedly during stirring and the reactions correspond to the oxidation of pyrite with the formation FeOII) oxides plus elemental sulfur. Also there is evidence that Fe oxy-ions form. Coal pyrites, under rapid sweep conditions display only the first two anodic peaks, the associated reduction peaks and an additional reduction peak corresponding to one or more of the high voltage oxidation products. After prolonged exposure to high potentials, coal pyrite displays reactions similar to those of mineral pyrite but at much higher current densities demonstrating the much higher reactivity of the coal pyrite. The reactivity sequence was Upper Freeport coal pyrite > Pittsburgh coal pyrite > mineral pyrite.

Jan 1, 1991

By Richard R. Walker, John J. Watkins, Allen C. Amos, Matulich. Angelo

THE KIDD CREEK MINE is located within the Abitibi greenstone belt, near its west end, in an area known as the Porcupine mining camp (Fig. 5). The Abitibi belt, long known for its many major gold and base metal deposits, is the largest Archean (early Precambrian) greenstone belt within the Canadian Shield. In the Porcupine area, the greenstone belt is composed principally of Keewatin (older Archean) basic to intermediate volcanics, with subordinate felsic volcanics developed• locally. Greywacke, mainly of volcanic derivation, occurs associated with and overlying these volcanics. Timiskaming (younger Archean) sediments, principally coarse clastics, unconformably overlie the Keewatin volcanics and sediments. The reader is referred to Goodwin and Ridler (1970) •r. for a more comprehensive description of the Abitibi belt.

Jan 1, 1974

By J. P. Gouvea, T. R. Stacey

A research project was carried out on a gold mine in the Vaal River region of South Africa (Witwatersrand Basin) to evaluate the effect of two particular aspects of rockbolt installation – the angle of inclination of the bolt relative to the orientation of the rock surface, and the protruding length of the bolt – on the mine’s gully support system. A keyblock analysis approach indicated that these factors do not have an adverse impact on the stability of the strike gullies. This was confirmed by extensive empirical data collected from the case study mine. While safety is the primary concern, cost saving opportunities can be realized through reconsidering historically inherited support standards that are perceived to be correct and appropriate. The research described in this paper sets forth a practical approach, that is easy to implement and repeatable, to evaluate the role of rockbolts in stoping gullies.

Feb 12, 2024

By A Batnasan, K Haga, A Shibayama, K Higuchi, H Takeuchi

High silica (SiO2), alumina (Al2O3), and phosphorus (P) contents in iron ore adversely affect the quality of iron products. The removal of those impurities from iron ore is an essential point in further iron ore processing. In this paper, the removal of P, SiO2 and Al2O3 impurities from iron ore by alkaline drying followed by reverse cationic flotation is discussed. The reverse cationic flotation experiments are performed using the iron ore samples without and with alkaline drying pretreatment. All other flotation conditions except pulp pH (4–12) and particle size distributions (-45 to -250 μm) are held constant. A typical collector and frother, such as dodecylamine acetate (DAA) and methylisobutylcarbinol (MIBC), are used in the flotation experiments. Alkaline treatment is conducted before flotation using sodium hydroxide at fixed conditions. The impact of alkaline drying on the performance of iron ore flotation is evaluated based on the removal rates of P and SiO2 + Al2O3, iron grade, and iron recovery compared with the iron ore flotation without alkaline drying (direct flotation). X-ray diffraction (XRD) analysis indicates hematite and goethite are the main minerals in the iron ore, which assays 62.8 mass per cent Fe, 0.232 mass per cent P, 7.1 mass per cent SiO2 + Al2O3 (total) determined by X-ray fluorescence analysis (XRF). Results indicate that a combined approach is more effective for removing P and SiO2 + Al2O3 impurities from iron ore than the direct processing technique because the maximum removal rates of P and SiO2 + Al2O3 are 48.2 per cent and 66.5 per cent from the alkaline dried iron ore when 8.4 per cent and 13.1 per cent from the non-alkaline dried iron ore.

Sep 18, 2023

By J M. Shekiro

In the chloride process to manufacture TiO2 pigment, feedstocks containing higher TiO2 contents (high-grade ores or HGOs) are favoured in order to minimise production of undesirable by-products. Most of today’s HGOs are produced through the smelting or reduction and leaching of ilmenite, processes which consume significant energy and/or produce large volumes of non-titanium materials that may have to be landfilled. In order to improve the economic and environmental sustainability of its TiO2 business, the DuPont Company, working with Kobe Steel Ltd, has developed an innovative process called TiRON for making HGO. Using a rotary hearth furnace, the process reduces ilmenite to a high TiO2 slag and metallic iron granules. The TiO2 slag is suitable for TiO2 pigment manufacture, and the iron is suitable for steel making. TiRON can process sand or rock ilmenite of varying compositions and particle sizes. Fossil fuel instead of electricity supplies the energy for the reduction. Dusts and off-spec materials are recycled. These process attributes, together with capital requirements estimated to be significantly lower, give TiRON substantial economic, environmental, and process flexibility advantages over conventional ilmenite upgrading processes. TiRON has been demonstrated at the semi-works scale, and preparations are being made to bring it to the pilot scale.

Oct 5, 2011

By Manis Kumar Jha, D. D. Pathak, Rekha Panda

Platinum Group Metals (PGMs) play a significant role in the manufacturing of catalysts, super alloys, electronics, space materials, biomedical equipments, jewellery, etc. due to their excellent electrical and thermal conductivity as well as chemical resistivity. The rising demand of PGMs in industrial applications and their limited natural resources have laid emphasis on the development of feasible and eco-friendly processes for the extraction of these metals from different sources to meet their future requirements. Present review reports commercial processes based on pyro-/hydro- and hybrid techniques to recover PGMs from various resources. The salient findings on different processes used for recovery of PGMs have been reviewed with respect to various methodologies and objectives.

Mar 1, 2018

By A R. Cruden, M S. Egglseder

The formation of banded iron formation (BIF)-hosted high-grade iron ore deposits in the Hamersley Province, Australia has been debated for decades. Although a structural control on their formation is widely accepted, only the roles of large-scale structures (ie faults and folds) formed by brittle and ductile deformation have been considered to date. However, the deformation of multilayered sequences in the Hamersley Province (ie the Mount Bruce Supergroup), with their contrasting rheological behaviours, creates challenges for understanding the complex structural framework at regional to deposit scales, including the significance for mineralisation and orebody location.Our approach to understanding these complex relationships is based on an established principle of structural geology, which is to extrapolate microscale structures to deposit-scale structures and vice versa, supported by state-of-the-art 3D modelling techniques. Complexly deformed hand samples associated with the Mount Tom Price iron ore deposit (Hamersley Province, operated by Rio Tinto Ltd) have been analysed and visualised with 3D explicit (Move™, Midland Valley Ltd) and implicit modelling software packages (Leapfrog™, AranzGeo Ltd) and supported by microstructural investigations (optical and X-ray microscopy) and fieldwork.Our study shows that the deformation of BIFs in the central Hamersley Province is controlled by microscale chemical processes (ie dissolution precipitation creep) due to rheological differences between iron oxide and chert layers, contrasting fluid flow properties and layer thickness variations. These processes account for the removal of vast amounts of silica, its transportation by diffusion in the presence of a fluid and reprecipitation at low-pressure sites. Consequently, this structural framework was used by different upgrading fluids to form iron orebodies.CITATION:Egglseder, M S and Cruden, A R, 2015. Evolution of a structural framework for high-grade iron ore deposits, in Proceedings Iron Ore 2015, pp 255–262 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By B. Qiu

The large surface ground movements induced by underground mining could threaten the safety of the pipelines laid across the subsidence-prone area. Existing analytical methods for the stress analysis of buried pipeline over mine subsidence area were based on the assumption of ?thin? pipeline, which limited their applicability. This paper presents the improved model with the capability to determine the stress distribution of the ?thick? pipeline. The pipe-soil interaction in this model was also updated to adapt various pipe soil contact conditions. In addition, the time-dependent effects of dynamic subsidence effects were also added to the model. A case of protecting a long section of a buried large-diameter pipeline over two longwall panels in a shallow mine is shown. The stress distribution along the pipeline is determined and the overstressed sections are identified. A partial uncovering plan was developed based on the predicted stress and complicated terrain at the site.

Aug 1, 2013

By Thomas Mütze, Frank van der Meer, Gunnar Kretschmar

"The air classification of moist bulk materials is addressed in the literature insufficiently. Therefore a feasibility study investigated the influence of feed moisture on the separation efficiency expecting a reduction with higher moisture content in the feed. Two iron ore samples were characterized in terms of the nature of bonding of moisture as well as its effect on the agglomerate strength. The classification tests themselves were conducted with two dynamic laboratory air classifiers at cut sizes from 45 to 110 µm and a moisture of the feed material between 0 to 10 wt.-%. The quality of classification was assessed by split factor, cut size, separation efficiency, moisture of both products, as well as the yield of the fines as product fraction in a corresponding processing plant. An initial approach was found for a technological implementation: A sufficient drying of a moist feed can be realized simultaneously to the pneumatic transport inside the classifiers. In the present case the drying effect and dispersion intensity was sufficient to provide good separation results up to 3 wt.-% feed moisture. An additional drying step was necessary beyond 3 wt.-%.INTRODUCTIONSpecific information about the influence of moisture in air classifiers is very rare. Mostly only dry products are processed and/or drying prior to classification is recommended. Apart from the specific influence of the feed moisture a lot of literature can be found regarding air classification itself. Altogether air classification can be divided into several sub-process (Leschonski, 1977):- dosage of the feed material,- dispersing the solid feed material into a gas stream,- feeding the dispersed material into the classification zone by pneumatic conveying,- separation of coarse and fine particles, and- separation of fine particles from gas.For wet feed particles also drying plays an important role. Interesting for the present investigation are the humidity of the feed and its influence on the single sub-processes."

Jan 1, 2016

By G. A. Calboreanu

The deterioration rate of any metal or alloy is increased in a erosion-corrosion application because the passivated surface layer is removed by the solid particles contained in the pumping fluid and the material surface becomes corrosion active again. Numerous attempts were made to engineer a stainless steel with higher hardness and unaffected corrosion performance. Alloys of special interest in such an area are the duplex stainless steels particularly the CD4MCu material which has the capability of being hardened due to its ferrite-austenite microstructure. Unfortunately, the CD4MCu with higher hardness comprises different intermetallic compounds which will increase the corrosion rate. The paper is analyzing the erosion-corrosion performance of a new type CD4MCu with 32% higher hardness and superior wear performance. The corrosion performance of this new alloy is better than the corrosion performance of the common CD4MCu material which the industry could supply. The corrosion effectiveness was evaluated with the Huey test, the potentio-dynamic anodic polarization test and the weight loss test whereas the erosion resistance was established with a low stress ball-on-disk type apparatus. The Wilfley hard CD4MCu material had 39% lower weight loss and 32% smaller volume loss than the common CD4MCu alloy The hardness range of the centrifugal pump parts poured and processed with the Wilfley hard CD4MCu is 320-350 HBN versus 250-255 HBN hardness of the common CD4MCu. After approximately 18 months of experimentation and field testing it was clearly established that the life time of the Wilfley hard CD4MCu is higher than the common CD4MCu and consequently centrifugal pumps were supplied to different customers in North and South America. India and more recently Australia. Sincere thanks to all the A.R. Wlifley & Sons Inc. and Western Foundries Inc. employees who supported and help to implement this work. special thanks to George Wilfley. Dave Cobb. Bill Becker Sr. and Wayne Taylor

Jan 1, 1997

By D. S. Davies

Further development of the Nitric-Sulfuric Leach (NSL) process has led to an improved design of the leach and nitric acid recovery steps. NO produced in the leach step is reacted with oxygen, regenerating N02, which is sparged directly into the leach reactor. Leaching is simplified to two steps and the nitric acid plant is replaced with an oxidation recycle gas sys-tem. Laboratory work substantiated the concept and led to selection of operating conditions. The lab work also pointed to improved process control compared to use of nitric acid as the sole oxidant. Recovery of copper from purified pregnant liquor is modified to use air agitation electrowinning improving cathode quality and lowering tankhouse costs. Economic evaluation shows reduction of capital requirements from $2400/AT to $2000/AT in 1978 dollars for 50,000 TPY of copper production.

Jan 1, 1978

By I. Raposo, I. Moreno-Ventas, A. Palma, M. J. Díaz, M. Vázquez

The oxidative degradation kinetics of chalcopyrite have been studied by thermogravimetric analysis (TGA). The obtained data are necessary for the kinetic description of the flash fusion process, which can contribute to the optimization of the smelting process in copper extractive metallurgy. Activation energy (Ea) evolutions of the involved processes have been determined by several isoconversional methods; in this sense, the chalcopyrite oxidation processes could be adequately described, among studied models (E1641–16, Ozawa–Flynn–Wall, Kissinger–Akahira–Sunose and Friedman), by the Kissinger–Akahira– Sunose kinetic model. Using this method, Ea and A values are found to be very dependent on the conversion. Under lower conversion levels, higher Ea and A values have been calculated with respect to that found for medium and higher conversion levels.

By Akio Ohta

The Hyuga smelter has been producing ferronickel by a rotary kiln-electric furnace process in Miyazaki, Japan. Several approaches to improve our operation have decreased the electrical energy consumption. A new process was developed to decrease the cost of energy even further. Oil and technical oxygen are injected through lances to heat up the calcined ores (calcine) instead of the electric power. Main problems during the development of the process were the short life of the water-cooled lances, the check on security of the safety system and the eruption of combustion gases through the calcine bed. These problems have now been overcome successfully, and stable operation can be maintained. The addition of 1 Litre of heavy oil per tonne of ore can save the electrical energy requirement by 8.6 kwh per tonne of ore. The new process has resulted in a reduction of the electrical energy consumption by more than 10 percent

Jan 1, 1992

By Jian-guang Yang, Lei Jie, Si-yao Peng, Jian-ying Yang

A new membrane electrolysis process for bismuth recovery from bismuthinite concentrate was introduced. Under the conditions of temperature 70 degrees C, acidity 3 mol/L, solid liquid ratio 1:4 and 1.1 times stoichiometry sodium chlorate dosage for 1.5 h oxidation leaching, more than 98.5% bismuth can be leached from bismuthinite concentrate. The resultant leach solution was subjected to membrane electrolysis. Under the conditions of NaCl concentration 300 g/L and pH 7 in anolyte, bismuth ions concentration 80 g/L and HCl concentration 3 mol/L in catholyte, heteropole distance 6 cm, temperature 40 degrees C and current density 200 A/m2, a flat deposited bismuth plate can be obtained after 24 h electrolysis, and the bismuth purity was more than 99%. The current efficiency of cathode was 97.88%. Chemical component analysis results showed that the average convert efficiency of the sodium chlorate was 52.77% and the average oxidizing efficiency of chloride ion was 69.78%, and the resultant anolyte generated in anode compartment could be fully reused as oxidant for leaching bismuthinite concentrate again.

Mar 1, 2017

By John W. Taber

Discovery of these unusual fluorite deposits was brought to the attention of the Bureau of Mines late in 1951, shortly after the first locations were made. A brief investigation of the deposits by the Bureau revealed seven principal outcrops of fluorite in two areas. The smallest outcrop continuously exposes massive fluorite over an area 25 by 55 feet; the largest outcrop is a similar exposure 180 by 240 feet. The deposits appear to be sharp-walled, low-angle-, tabular ore bodies in granite and are at least 10 feet thick. The Bureau investigation of the deposits included bulldozer strip-trenching, drilling and blasting rock cuts, and channel sampling across three of the largest outcrops. This sampling indicated an average grade of 97.2 percent CaF2 and 1.44 percent SiO2. Preliminary metallurgical tests on the ore indicate that it can be concentrated to acid-grade specifications by simple gravity methods. One laboratory test recovered 78.4 percent of the fluorite in a product containing 98.7 percent CaF2, 0.25 percent SiO2, and 0.10 percent Fe2O3.

Jan 1, 1952

By Stanley W. Ivosevic

The South-Central Osa Peninsula produced around 30,000 kg (100,000 troy oz) of gold since prehistoric times. Gold freed by erosion from quartz lodes in the Mesozoic Nicoya ophiolite complex was reconcentrated through three generations of Quaternary sedimentary deposits. Resultant gold placers grade upward from 1 g/m3 (0.03 troy oz/m3) and are of moderate size.

Jan 1, 1980

By Cameron Dunn, Callum Fryer, Carmen Hu, Craig Sewell, Peter Stakne, Andrew Raine

The Woodsmith Project is located in north-eastern England within the North York Moors National Park. The strata contains the world’s largest known high-grade Polyhalite resource of around 2.66 billion tonnes. The Project was initiated by York Potash Limited (YPL), a subsidiary of Sirius Minerals plc., but in March 2020, a takeover was completed by Anglo American, one of the largest mining companies in the world. Polyhalite is an evaporite mineral and contains essential nutrients required for plant growth. The Polyhalite will be extracted via two deep mine shafts and transported underground from the mine site to a Materials Handling Facility on a Mineral Transport System (MTS), which comprises a high-capacity conveyor belt system located within a 4.9 m ID tunnel. In 2018, STRABAG were awarded with the design and construction of the MTS tunnel and associated infrastructure, including the high-capacity conveyor system. The scope of work consists of 300 m of open cut, 100 m SCL tunnel, 36.5 km TBM drive (originally anticipated as three separate TBM drives) along with a network of underground caverns at the Woodsmith Mine. The construction of two 380 m deep intermediate access shafts was later awarded as Amendments to the Contract. The tunnel is constructed using a Herrenknecht Single Shield TBM. As a result of how the various elements of the project have developed over time, the first TBM drive has been extended to ~29 km making it the worlds longest single heading TBM Tunnel when complete. The option of completing the entire tunnel length with a single heading TBM drive is currently being assessed by Anglo American and STRABAG. This unprecedented tunnel length requires two intermediate shafts to provide essential access and services, the first intermediate shaft is at Lockwood beck (LWB) and the second is at Ladycross (LDX). The LWB shaft has been constructed utilising the innovative Blind Boring technique never used before in the UK. This paper will explain the methodology and technical risk management associated with this technique. The authors believe that the collaborative approach between all contract partners is and continues to be the important contributor for the success of this project.

Jun 13, 2023

By Donald F. Reed

In its program of investigation of deposits of strategic minerals, the Bureau of Mines did some development drilling from October 1247 to March 1948 at the Pickering Creek deposits, Charter County, Pa., in an endeavor to find an additional source of supply of lead and zinc. Lead mining in Pickering Creek Valley showed great activity from 1851 to 1855; but after this period mining gradually declined until 1870 when all mines were. One small mine did some work from 1917 to 1920. The ores were sulfides of lead and zinc, which were partly oxidized from the surface to the 20-foot level. As zinc was penalized at the reduction works, the ore was sorted at the mine and the zinc discarded. The Wheatley and Chester County veins contained the beet ore bodies in the district. These converging veins are 2 to 5 feet wide. To cut the veins below the old mine working' the Bureau of Mines diamond-drilled eight holes aggregating 2,820 feet. No significant lead-zinc mineralization was found.

Jan 1, 1949

By Glenn E. Hoffman

Relax: the world today is not running short of many mineral commodities, even though prices are spiraling upward. Einstein?s observation still holds true that everything is still relative, as long as one can pass on the incremental costs of production to the consumer. However, a strong consensus exists among many of the companies comprising the minerals processing industry that it is becoming increasingly difficult to find the easy-to-mine, high-quality resources that make juicy profit margins, which shareholders like. For the most part, the resource cherries have all been picked, and established mineral processing companies that are exhausting their reserves, or in the process of looking to add reserves so as to create longevity for their company, have no recourse but to look long and hard at what were once considered the dregs of the earth. Even end users, such as steel companies, are now looking to become ?miners,? to establish captive iron ore resources. Owning a captive resource facilitates a dependable supply of feed materials, which translates into effective cost control and a guarantee for a thriving sustainable business in the future.

Jan 1, 2012

By Brian Lewis, Reinhold Daykin Schnell

Blasting is the primary and most effective method for breaking and moving material at most mine sites. The blast design is often adjusted in efforts to optimize the effectiveness of the blasts’ explosive energy while minimizing costs. When adjusting blast design parameters, it is important to adjust one parameter at a time, observing and analyzing the potential effects of the change on the overall blast performance.

Feb 6, 2023