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By D R. van der Meulen, P Ande, D J. Lunt

Pressure hydrometallurgy is becoming an increasingly common unit operation in the treatment of gold and base metal ores and concentrates. The design of an adequate and appropriate pilot-scale testwork program is, therefore, essential in order to minimise the risks associated with developing a project in which autoclaves form a key part of the operation. This paper identifies the approaches that have been taken in the piloting of oxidative and pressure acid leach operations. Particular emphasis is placed on the determination of scale-up ratios between the pilot and commercial plants and the pilot-plant run durations. The issues, both metallurgical and project-specific, that can impact these key parameters are reviewed.

Jan 1, 2004

The short review of hydrogeologic conditions in the three Polish coal basins have been presented as the background for the prevention measures against water inrushes being underta- ken in coal mines. The Polish mine safety regulations concerning water inrush prevention have been discussed, namely: - classification of sources of the potential water inrushes, - levels of water inrush risk and conditions of mining operation in the mines facing particular risk levels, - determination of the -di.mens.ons.of protecting pillars to prevent water inrush to mines, protection of surface water reservoirs and their earth embankments in regions submitted to mining deformations. Three examples of coal mining being carried out under water bodies have been presented.

Jan 1, 1988

By G. Brooks, M. Hamed, S. Nightingale, K. Coley

The Marangoni effect plays a significant role in slag line corrosion of refractories. Previous experimental studies for various refractory /slag systems and mathematical models are reviewed and show that Marangoni flow is important in slag line corrosion under static conditions. Recent work by the authors is presented which also shows significant slag-line corrosion of MgO refractory in SiO2-CaO-FeOx-MgO slag. The rate of attack of the MgO was marginally slower in the case of slags containing alumina. A semi-empirical model developed by Hrma based on mass transfer control described reasonably well the observed progression of corrosion with time. Further work is proposed to evaluate this model.

Jan 1, 2004

Equilibrium in the reaction H2(g) + [%0] (in liquid copper) = H2O (g) was investigated at temperatures between 1200 -and 1350°C with p(H2Oj/p(H2) ratios between 1 to 15. A semi-microbalance was used for direct measurement of dissolved oxygen in molten copper. Oxygen was found to obey Henry's law under the experimental conditions used. The standard free-energy change for the above reaction is given by Equation 1where 1 weight per cent solution is the standard state for dissolved oxygen.For the dissolution of oxygen in copper according to 1/2 O2(g) = [%0] (liq. Cu), the standard free energychange is given byEquation 2.

Jan 1, 1973

By G. P. Salas

I.- In order to keep pace feeding its fast growing population, Mexico with only about 20% of its surface suitable for intensive agriculture, will need the application of modern foodgrowing techniques. To assure greater crop yields it will be necessary to apply more fertilizers than used at present (yearly average of 29 Kgs/hectare)** For its fertilizers production Mexico still depends mostly on imports of phosphate concentrates from Florida, U.S.A., Morocco and Spain. To reduce or eliminate this dependence on foreign providers, the Consejo de Recursos Minerales -a Federal Government exploration Institute- started in 1974 an exhaustive exploration program for phosphate deposits more amenable to commercial exploitation than the phosphatic limestones contained within the La Caja Formation of Upper Jurassic, found along the Sierra Madre Oriental. After studying literature on the origin and deposition of marine phosphate and visits to deposits in Florida, U.S.A., the Baja California peninsula was selected as most favorable for starting this program because of its geologic and sedimentary history and also for its geographic location, where the cold California and warm Counterequatorial currents meet. Exploration activities executed by FORNOS, S. A. (1956) led to the disco very of low grade phosphate (3 to 5% P2O5) in the recent beach sands along the Bahia de Magdalena (Fig. # 1). In his doctoral thesis Bruno D'Anglejan Chatillon (1965) reports the presence of nodular phosphate on the continental shelf, between Isla Margarita and the Vizcaino peninsula. He estimated reserves of up to 1.5 million tons. A Mexican-American marine exploration company attempted in 1966 the evaluation of this deposit with negative results.

Jan 1, 1978

By R. W. Smith

A number of investigators have studied the electrokinetic potential (?) of kaolinite as a function of pH. (1,2,3,4,5) These investigators all agree that the ? is negative except at quite acid pH values. The actual shapes of the curves reported by the several authors vary considerably. In spite of the general negative character of kaolinite the mineral has a rather high anion exchange capacity. (6,7,8) The cation exchange capacity is the lowest for the clay minerals. (6) It has been shown that anionic surfactants adsorb readily onto the mineral even up to neutrality, often in quantities exceeding the reported anion exchange capacity. (7,8) At least part of the anionic adsorption should be onto positive edge sites thought to exist on the mineral. (9,10) In the present study ? of kaolinite was measured as a function of pH using both the streaming potential (sp) and microelectrophoresis (m.e.p.) methods. In addition ? was measured at various pH values as functions of sodium dodecyl sulfate (SDS) and trimethyldodecylammonium chloride (TMDAC) concentrations. In some experiments decyl alcohol (DA) was added.

Jan 1, 1968

By E. Marcotte

"Technology developments and improvements are imperative to maintain a viable mineral processing industry. In order to achieve optimum implementation of technology in processing plants, safety conscious and efficient work forces are required. Effective management methods are required to prevent employee injuries, equipment or environmental damage and process losses. Good leadership also provides for employees to perform their work in the safest and most efficient manners to attain optimum recoveries of the valuable minerals and produce high quality mill products. Equipment and processes must be designed, operated and maintained as required to assure safe and efficient mineral processing.INTRODUCTIONThe Canadian mining industry must contend with many challenges to attain and maintain a competitive position in today's global market. Canadian Mineral Processors play a vital role in meeting the challenges and achieving optimum mineral productivity.Ongoing technology developments and improvements continue to be imperative to maintain a viable mineral processing industry. The efficient implementation of technology developments requires a safety conscious, skillful and productive work force.In addition to technical and human resources, challenges may also include governments, labour unions or environmental advocates who at times may appear to be misguided or unrealistic. Canadian Mineral Processors must not allow themselves to be overwhelmed by these apparent obstacles but must use their demonstrated ingenuity to achieve successful solutions.It should be recognized that the majority of the Canadian work force are, in fact, a potentially talented and skillful people with ambitions to excel. As leaders of people, we must provide the methodology, incentive and direction that will allow our work forces to realize their ambitions. If the potentials of our work forces are not recognized and leadership is not properly exercised much loss will occur. That is, safe effective and efficient work will not be achieved."

Jan 1, 1993

By Charles G. Yale

A few years ago somebody connected with one of those self-constituted bodies of unofficial character, like a Chamber of Commerce, Board of Trade, or State Development Board, started a catch-phrase referring to California as a The Land of Sunshine, Fruit, and Flowers," and the railroad magazines and folders keep it steadily in use, working day and night. Yet it altogether ignores the substance which brought the State into the Union, which peopled it, and which made it famous thronghout the world. You ladies and gentlemen who have come from what wc here call "the East," have in your own States, no matter which one, sunshine, fruit, and flowers. But your Eastern States, having these things as we do, have not the gold that we do. Therefore, the old designation of " The Golden State," applied to California, should be revived, as being the most distinctive term. It is worthy of remembrance, too, that during the dark days of the civil war this State handed over $172,000,000 in yellow gold, and saved the credit of the nation. Gold-mining has been carried on in California since '' The days of old, The days of gold, The days of '49," and it still continues. Since that historic year, and up to the end of 1910, the State has produced, in gold alone, $1,530,214,468. Since 1792 the entire United States production of gold has been $3,261,573,500, so that the single State of California has, in that period, produced within $201,144,564 of one-half of all the gold from Alaska, Arizona, Colorado, Idaho, Montana, Nevada, New Mexico, Oregon, South Dakota, Utah, Washington, and the Southern and scattering States. In other words, all the other 25 States of the United States combined

Jan 1, 1912

By Fred Beasley

METALLURGISTS have, in the past ten years, overcome many difficulties of high zinc in lead blast-furnace slags. This problem was brought to the front at the close of the late war, by the price obtained for lead and the high cost of labor, fuel, and flux. The Port Pirie plant of the Broken Hill Associated Smelters, Australia, early in 1919 had increased the zinc oxide in its blast-furnace slags from 13.5 to 20 per cent., at the same time reducing the iron oxide in the slag from 33.5 to 25.6 per cent. These results were obtained by the following proceduret the addition of granulated slag to the roaster charge, 10 to 12 per cent., improved conditions of the crushing and mixing and roasting of the constituents of the sinter. By experiments and improve-ments the practice at this plant has developed a normal slag that carries 22 per cent. zinc oxide, and at times runs as high as 33 per cent. zinc oxide, with only slight furnace trouble. The granulated slag is used not, only as a diluent to the sulfur in the roaster charge, but also on account of its value as a slag-forming material and on account of the physical properties it imparts to the finished sinter. The ore is mixed with flux and given a double roast. All the first roasting is by sintering with the Dwight & Lloyd machines. The final roasting is performed partly by Dwight & Lloyd machines and partly by H. & H. pots. The charge to the blast furnaces consists chiefly of the final sinter, slag shells, siliceous and non-bearing sulfur, lead ores. High blast and ore columns are the practice. The greatest care is taken to obtain in the final sinter as low a sulfur content as possible.

Jan 2, 1925

By R. H. Merrill, D. W. Wisecarver

The paper "Design of Surface and Near-Surface Construction in Rock" by Deere, Hendron, Jr., Patton, and Cording discloses a principal difference between civil and mining engineering as applied to openings in rock. Generally, the civil engineer considers an opening as an asset, where a mining engineer finds that most of his openings are a liability. The openings, or rock surfaces, treated in the paper by Deere and coauthors are designed for lasting stability and the foundations for dams, the diversion tunnels, abutments, and surface excavations are expected to be stable for long periods or provide continuous access and other useful purposes. Except for those openings used for the transportation of men, materials, ore, and for ventilation, the mining engineer finds that his underground openings serve no useful purpose once the mineralized rock has been removed. Usually, these openings create problems such as reduced ventilation efficiency, added requirements for scaling, sealing, and other tasks necessary to maintain or isolate the openings. The surface openings and mine plants present another liability to the mining engineer. After the product has been removed from the earth, the abandoned pits or strips, tailing ponds, dumps, and buildings sometimes become hazardous, unsightly, or occupy surface areas that could be used for other purposes. As a general rule, the various disciplines involved in rock mechanics have different objectives and uses for openings; however, the basic concepts regarding the design or control of openings in rock are similar for each discipline. The review by Deere and his coauthors contains examples of the duplications in this technology, and, in particular, the common approaches used by civil and mining engineers. Therefore, both the review paper and this report consider the problems that are common to most of

Jan 1, 1967

By Thomas Frost

In this time of market globalization, many industrial companies are including detailed arbitration clauses in their international contracts, in order to avoid the potential costs, delays, and uncertainties of litigation in foreign courts. Arbitration is less expensive and more flexible, procedurally, than court proceedings, and arbitral awards enjoy much greater international recognition than judgments of national courts. More than 134 countries have signed the 1958 United Nations Convention on the Recognition and Enforcement of Foreign Arbitral Awards, known as the "New York Convention", which facilitates the enforcement of arbitral awards internationally. There are several other similar arbitration conventions that provide for the enforcement of cross-border arbitral awards. Additionally, arbitral awards are not subject to appeal, whereas judgments of national courts are routinely subjected to a lengthy appeals process, and there are very few viable bases to challenge arbitral awards. This discussion will review key considerations in drafting arbitration clauses, including choice of law and choice of forum considerations; issues surrounding the selection of arbitrators; the discovery process; presentation of evidence; and enforcement of arbitral awards.

Jan 1, 2006

By Frederik P. Agterberg

Mineral exploration consists of the acquisition of data and their interpretation to ascertain the presence or absence of uncertain events. In general, the amount of uncertainty decreases during exploration when targets become increasingly well defined. Decisions on further exploration and whether or not mining should be commenced are based on new information using both objective facts and subjective reasoning. Computers play an important role during all stages of exploration. Three recent books (References 1-3) on decision-making in exploration and mineral-resources evaluation provide additional background supplementing the papers in this volume and articles in scientific journals or other conference proceedings (e.g., References 4 and 5) dealing with the subject. Other new developments to be considered are that microcomputers are becoming increasingly important in the earth sciences (Reference 6), and so are applications of artificial intelligence (Reference 7). Microcomputer- based technology allows rapid communication between field parties and main office. Expert systems are becoming increasingly sophisticated aids for mineral exploration an can now contain objective rules based on statistical theory (Reference 8).

Jan 1, 1989

By Greg Joachims

Composition of salt in the Permian Flowerpot Shale in northwest Oklahoma suggests that the salt in this formation was deposited in the early phase of solar evaporation. Brine produced through natural dissolution of the subsurface salt has netted very pure brines, with relatively low concentrations of magnesium salts that should result from late-stage precipitation of salt deposits from sea water. Over the last 100 years, extensive studies of sea- water evaporites, in relation to brine density, have been a topic of discussion. The development of evaporation models has facilitated the increased production and purity of solar salt (salt produced through evaporation of brine by the sun's energy). Conversely, this information can be utilized to gain an understanding of how rock-salt formations were precipitated from sea water by analyzing the elemental constituents of the rock salt and of the resulting brine. By evaluation of well-documented, phase-curve tables of sea-water evaporation, a basic theory can be formulated on how the Flowerpot salt unit was formed.

Jan 1, 1999

By P. Seppanen

Cemented fill was first introduced at the Keretti mine in 1952, but entailed high cement costs, the need for stope preparation, slimes handling, clean-up and maintenance, increased mine dewatering, segregation of fill and long setting times. In the 1970s research began into the use of iron blast-furnace slag as a binding agent and by 1989 Pyhasalmi, Vihanti, Keretti, Vammala and Enonkoski had saved US $11 000 000 by using slag binders instead of cement. Viscaria in Sweden and Tara in Ireland also use slag as 90-100% of total binder, although their backfilling methods vary. The main area of interest in slag research is determining the activation methods for initiating the binding reactions; it is also important to achieve other characteristics such as resistance to corrosion by sulphuric ion. New backfilling techniques developed during the 1980s included the use of high-density cemented tailings fill at Vammala and porous cemented rockfill at Enonkoski and Viscaria. Future developments focus on concepts such as integration of mining and milling with backfilling and the achievement of total underground disposal of wastes

Dec 1, 1995

By W. D. Gould, . W. Koren, P. Bedard, P .. B. Marchant

Ammonia and nitrate in metallurgical operations arise from several sources: (1) the use of ammonium nitrate based explosives, e.g. ANFO; (2) the use of cyanide for gold extraction which is degraded to ammonia by most cyanide destruction techniques; and (3) the use of nitrogenous reagents in the mill for neutralisation, flotation and extraction. The concentrations of ammonia and nitrate in effluents vary from 10-50 ppm and 25-300 ppm respectjvely. A number of environmental problems are associated with both ammonia and nitrate. Both of these forms of nitrogen can contribute to the eutrophication of receiving waters. Ammonia and organic nitrogen can also cause high dissolved oxygen demands in receiving waters. Ammonia is also toxic to fish, particularly at elevated pH values. Several methods are in use for the removal of ammonia and nitrate from municipal wastewater, industrial effluents and agricultural runoff. To date, no treatment systems have been developed specifically for the removal of nitrogen from mine and mill effluents. This paper will report on some removal techniques that have been tested using actual and synthetic mine effluents.

Jan 1, 1993

New Zealand's Land and Income Tax Act 1954 contains unique incentives for companies engaged in mining certain specified minerals or petroleum. Sections 152 and 153 provide for the taxable income of such companies to be based not on profits made but on dividends paid to shareholders. A significant saving in tax results, particularly where profits are not distributed: but the Act attempts to ensure that undistributed profits are used for further mineral exploration and development. To encourage investment in the mining industry, persons taking up shares in a company mining for the specified minerals or petroleum are entitled to a one-third deduction in respect of monies paid on the shares and used by the company for its purposes; and company shareholders may make loans to the company and write-off such loans for tax purposes to an amount of up to half their taxable income. Maximum utilisation of the tax incentives calls for careful consideration as to whether a mining or petroleum company should be financed by way of loan capital or share capital.

Jan 1, 1971

By G. S. Dobby, N. J. Contini, S. W. Wilson

Scale-up and simulation of flotation columns requires construction of mathematical models which employ, as a minimum, rate constants for quantifying particle recovery in the collection zone as well as split factors for quantifying froth zone performance. To date, measurement of these rate parameters has proven to be difficult, due to the interdependent nature of the collection and froth zones. This paper describes a technique for making these measurements. The method requires recovery data from two modes of operation: countercurrent and cocurrent. In cocurrent flow slurry is fed at the bottom of the column and tailings are withdrawn a short distance below the froth interface. Countercurrent mode is conventional operation. The critical difference is that particles which are dropped out of the froth in cocurrent mode are immediately lost to tailings, while in countercurrent mode the particles are subjected to recollection. Fitting of the measured recoveries to the equations that describe flotation in the two modes yields rate constant or recovery values for both the collection and the froth zones.

Jan 1, 1988

By J. C. Taylor, J. A. Davis

"Existing environmental, health and safety regulations have forced pyrometallurgical facilities worldwide to drastically change some of their traditional methods of operation. In extreme cases, a number of facilities have been closed due to their inability to conform to these existing regulations. Tougher future legislation and government policy will lead to more stringent regulations and enforcement policies. The efficient control of smelter secondary emissions will, therefore, become critical to successful smelter operation.Much attention has been paid to the smelter primary process off-gas systems, including the development of new process designs to reduce the number of uncontrolled transfer operations. However, even the most modem smelter design requires control of its secondary contaminant sources, which mayor may not be directly related to the process operation.This paper discusses some of the potential secondary emissions encountered in many of the present process technologies. A few of the emission sources presented are only periodic in nature, such as those caused by maintenance procedures, but which have the capability of forcing smelter shut-down because of their direct impact on worker health and safety. The paper deals with a variety of topics relating to the efficient control, maintenance and monitoring of secondary emissions in copper, nickel, aluminum, magnesium and lead smelters, as well as in iron foundries and steel making facilities. Examples of the typical problems encountered in each of the above process operations are presented, including fume control at furnace tapping and slagging locations, metal transfer stations, tapping launders, and ladle transfer operations. The parameters for the most efficient design of fume capture systems, problems encountered with the handling and clean-up of certain collected emissions, and examples of successful solutions in particular operations are discussed."

Jan 1, 1994

By Behdeen Oraee-Mirzamani

Since the advent of New Austrian Tunneling Method (NATM), shotcrete as a primary means of support in tunnels has been widely applied. It?s most important features are durability, speed of application and cost effectiveness. This paper introduces some tables that provide guidelines for the thickness of shotcrete required in some common situations of mine roadways. In order to devise such tables, two different arch sections, together with three different overburden types, were considered. Geotechnical parameters such as apparent cohesion and angle of internal friction of surrounding rocks were chosen, based on the five-category classification of Bieniawski. Two K0 factors (the ratio of horizontal stress to vertical stress) and an average rock density were utilized. Using numerical methods, 60 models were then devised in this way. By applying interaction diagrams of axial force and the bending moment for different thicknesses of shotcrete, appropriate shotcrete thickness for these models were calculated. The results of this research, as well as the methodology applied, can be used in mining roadway support design and all types of civil engineering tunnels.

Jan 1, 2011

By Robert W. Hyers

Electromagnetic levitation has proven important in a wide range of experiments, all affected by fluid flow. For some experiments such as viscosity measurements, only whether the flow is laminar or turbulent must be established. For other experiments, however, quantitative assessments of velocity, shear stress, or shear strain rate are required. In most cases it is difficult or impossible to measure the internal flow in levitated droplets directly. The samples are usually small, opaque, reactive, high-temperature, metastable, or all of these. Furthermore, recirculating flow limits the utility of tracking surface particles, since they collect in stagnation points ratherthan following the flow. Most research groups have chosen mathematical modeling to assess the internal flow in levitated droplets. A variety of analytical and numerical methods have been applied, including both laminar flow and various turbulence models. A number of these models are reviewed and their impact on different containerless experiments is assessed. Much of the research reviewed here was performed by alumni of Professor Julian Szekely, and by others using similar methods.

Jan 1, 2006