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By Junji Shibata

Extraction behavior of Ti(IV) and other metal ions, such as Fe(III), Fe(II), Cu(II), Zn(I1) and Co(I1) from acidic solutions like sulphuric acid and hydrochloric acid was studied in order to recover titanium from the waste solution in Ti02 production. Extractant used was tri-alkyl phosphine oxide whose trade name was Cyanex 923. Then, a study was made of the idea of simulating a countercurrent multistage extraction system, using the results of batch extraction. The simulation was camed out on extraction and saipping behavior for a Ti(1V)-H$O,-Cyanex 923 system. From the simulation result., the optimum operating condition of the system was considered.

Jan 1, 1994

By Howard C. Turnage, Dana T. Updyke, Wayne C. Muhler

The objective of this project was to develop technical data and evaluate performance and utility of leaky feeder communications systems currently used in North American underground mines. The desired information was obtained principally through on-site surveys. Altogether, six of the seven mining companies known to be using leaky feeder communications were visited. This report covers the findings of these surveys. In addition, the report provides a brief background summary of mine communications, a technical discussion of leaky feeder systems, and conclusions and recommendations based on the results of the survey.

Jan 6, 1980

By Gregor Mori

Niobium electrolysis has been performed in a NaCl-KCl-NaF-NbCls electrolyte. By means of electrolytic .refining the average valency of the niobium ions was determined as well as the crystallization behaviour. In electrowinning runs the influence of the main parameters such as temperature, RF (mole ratio F/Nb), chemical prereduction, niobium content of the melt and current density has been determined with respect to low specific energy consumption and high purity of the deposit.

Jan 1, 1995

By Slattery T. E

Recent develognents in zinc flotation at the North Broken Hill Limited concentrator are discussed. An outline of the history of zinc flotation and a description of current practice is presented. Installation of on-stream X-ray analysis probes has resulted in inproved metallurgical performance and focussed attention on automatic control. Results are presented of investigations made over the past six years which have led to the formulation of experimental schemes for the automatic control of zinc flotation.

Jan 1, 1983

By K. Nielsen

The paper presents a brief overview of the mineral industry in Norway, followed by a description of the mineral policy and relevant legislation including the roles of the Norwegian Directorate of Mining and Geological Survey of Norway in this context. The discussion then proceeds to describe the land use planning framework on a national, regional and local level, the interaction between land use planning and the Directorate of Mining and the Geological Survey respectively, and how this impacts on the mineral industry and the exploitation of mineral resources. Some recent Norwegian examples of land use planning conflicts are also presented.

Jan 1, 2005

By P. J. Bhonde, R. D. Angal

Conventionally low carbon ferromanganese is manufactured globally by refining high carbon ferromanganese in liquid state. This process is an expensive and lengthy technique. Hence, the present work was undertaken with the objective of understanding the feasibility and kinetics of the solid state refining of ferromanganese. The process involved transformation of carbon rich carbides viz. Mn3C2, Mn7C3 into metal rich carbide i.e. Mn15C4, Mn23C6 by subjecting the alloy powder to a flowing stream of carbon dioxide. Effect of the process governing parameters such as time, temperature, particle size, pressure on the extent of decarburization was studied. Without any loss of manganese in the form of fumes or slag, it was observed that, there was substantial reduction, viz. 65 per cent in the total carbon content, by this technique. Subsequently, the process was investigated to find out the mechanism of carbon removal. Depending upon the temperature and the particle size, it was found that the rate controlling mechanism changes from chemical reaction control to product layer (ash) diffusion control. The activation energy for each of the aforesaid mechanism was computed. The values thus obtained substantiated the aforesaid mechanisms.

Jan 1, 2004

By Donald H. Yardley, A. Aly Selim

Abstract-An economic simulation model was developed to predict the amount of copper recovered from copper oxide deposits, and the cost of producing it as a function of the deposit parameters. The economic simulation model includes programs for fragmentation design and cost, copper extraction, solution distribution and recovery, effluent solution cutoff grade, and financial analysis. Cost and price indices were also developed to evaluate the economic feasibility of in situ leaching operations as a function of their starting date. Application of the models to various hypothetical properties having the same area and different ore thickness shows that the effluent solution cutoff grade does not vary with the ore thickness nor with its grade. The percent of copper recovery is, however, shown to increase with the increase in the ore thickness and is independent of the ore grade. It is also shown that while the profit per unit of extracted copper increases with the increase in ore grade or ore thickness, the rate of return on total investment does not show any correlation.

Jan 1, 1978

By A. S. Adams

A GLANCE at the list of papers1 that have been published since 1920 on the general subject of flotation suggests the variety of ideas that exist regarding the underlying cause of the phenomenon. Among these ideas, we find several coherent theories, but none that adequately and completely explain the phenomenon. Ralston2 and Bains3 suggested an electrical theory which has to do with the attachment of mineral particles to a bubble by the attraction of unlike electrical charges. This theory has its root in the fact that a bubble of air in pure water is electrified in such a way that the surface is negatively charged while the body of the water is positively charged. This result, which was first discussed by Helmholtz, also obtains when the water contains anything except a high concentration of hydrogen ions, or ions which are trivalent or tetravalent. The theory also holds that the mineral particles have positive charges on their surfaces, and so there is attachment between bubble surface and mineral particles by the old law of electrostatics, which states that unlike charges attract.

Jan 1, 1928

Copper cyanide is a common component of cyanide-treatable precious metal ores. The copper concentration in production heaps can be predicted from laboratory column tests, but the exact correlation is not necessarily intuitive. Generally, heap leach operators like to keep copper concentrations in solution below 300?500 ppm and may note problems with gold recovery and cyanide consumption when copper concentrations exceed this amount. There are several methods of copper removal from cyanide solutions including ion exchange; direct electrowinning; acidification, volatilization, and recovery (AVR); and sulphide precipitation such as the sulphidization, acidification, recycling, and thickening (SART) process. SART involves acidification with addition of soluble sulphide, separation of the resulting copper sulphide precipitate, and addition of lime to re-establish alkalinity prior to returning the solution to the leaching process, recovering both copper and cyanide as valuable products. In principle SART is very simple. Yet some SART plants that have been built may have been unnecessarily complex. This paper explores the basics of SART and makes the case for a simple plant design as applied to the heap leaching circuit.

Jan 1, 2012

By J. W. Axelson

CRUSHING has always been a major operation in the chemical and metallurgical industries, yet little is known about the theory of crushing, and today, the design of crushers is still based almost entirely on empirical knowledge and accumulated practical experience. In view of the increasing national need for the economic working of poorer grades of ores, the lack of a fundamental under- standing of this unit operation hardly presents a satisfactory situation. Basic investigations of crushing have been concerned mainly with three phases of the problem, 1-the mechanism of the fracture process itself, 2- the particle size distribution of the crushed product, and 3-the relationship between the energy input and the amount of new surface produced. Probably adequate information on these phases will be required for a comprehensive understanding of the process of crushing. A bibliography covering these phases will be given as well as a review of the work done in recent years at the University of Minnesota on the relationship between the energy input for crushing and the amount of new surface produced.

Jan 12, 1951

By M Kizil

Mining Engineering Degree programs have traditionally had a practical emphasis and have been highly vocational in nature. However, over the years, there has been an increasing attention to the more scientific aspects of the discipline. More recently, the professional institutions, the industry and the community at large have placed increasing emphasis on the broader aspects of the professions: management, finance, humanity, environment and social issues. Notwithstanding this, there has been a continuing emphasis on the practicalities, and most Mining Engineering programs are still strongly vocational in nature. But employers of new graduates complain about the graduatesÆ lack of practicality and readiness for employment æat the sharp endÆ on the mine site.This paper briefly describes some of the more recent developments in the Mining Engineering Degree program at the University of Queensland that attempt to address the problem. Particular attention is paid to alternative learning programs, including applications of virtual reality, practical experience at the University Experimental Mine (UQEM), and the Undergraduate Site Learning Program (USLP).

Jan 1, 2002

Blasting is known to be both an important and an easily quantified cost factor in rock breaking operations. However, the indirect costs and benefits of the blasting operation are not easily determined due to the irreversibility of the mechanisms involved and the multiplicity of influencing factors. A general conceptual model showing the relationship between blasting and mining costs is well known, but serious attempts to address the critical real relationships have all floundered on the fact that not enough is yet known about either detonation physics or blasting effects. This can only be remedied to the extent that blasting instrumentation enables researchers to pin down not only the relationship between the detonation process and its impact on a particular environment, but also the downhill costs of handling the rock, repairing any damage and building in "Safety Factors" to provide for imponderables. It is vital to standaraize on specifications for instrumentation and measurement techniques and there is a need to review what has been achieved in blasting expertise so as to focus on the most fruitful paths for future work.

Jan 1, 1990

By Pollard D. M

Chalcopyrite samples from two different localities were leached in oxygenated mixed chloride-sulphate lixivants at elevated temperatures and atmospheric pressure. The oxidation of chalcopyrite was found to follow predominantly linear kinetics. The slope of the major region was dependent on stirring rate, oxygen flowrate and chloride concentration while only slightly dependent on the surface area of the sample leached. This region was found to predominate only at low temperatures. The oxidised chalcopyrite releases cuprous and ferric ions into solutions. Chloride ions complex these dissolved ions to effectively move the equilibrium of the leaching reaction to the right. When the level of chloride in solution was below 6 g/l, the unstable cuprous ions were found to reprecipitate with sulphur as covellite. When no chloride was present and the lixivant was a solution of sulphuric acid then ferric sulphates precipitated. The overall leaching reaction occurring in the leaching system is: CuFeS2 + 5H+ + 1.25 02 = Cu 2+ + Fe 3+ + 2S¦ + 2.5H20

Jan 1, 1987

By Robert S. Nichols

Fording Coal Limited's mine in the Rocky Mountains near Elkford, B.C. has produced 21.8 million clean tonnes of metallurgical coal from 1971 to 1980, inclusive. This production has come from several pit areas and required the removal of 149.1 million bank cubic meters of waste rock and overburden by truck-shovel and dragline operations. Waste dumps from 30m to 200m in height have been successfully constructed on natural slopes, generally between 10° and 26°. Design considerations for the dumps include foundation and soil conditions, natural slope angles and containment of weak overburden or rehandle materials. Dump control is maintained by monitoring the crest and the face of an active dump area. Crest movement is measured by extensometers locally termed "Spoil Monitors". When crest movement rates progressively increase above normal, dumping operations are temporarily relocated. Some unstable conditions and mass failures have occurred as the result of natural foundation slopes being in excess of 26°, failure of weak water saturated foundation soils or weak material being placed on the dump.

Jan 1, 1983

Spatial continuity as described by a variogram is a reflection of the underlying mineralisation/geology. Modelling of the spatial continuity (variogram) must account for both the quantitative data (ie sample grades), on which the variogram calculations are based, and the qualitative information as provided by the geological interpretation. An understanding of the geology and the variogram interpretation tie together the sample values and allow us to go beyond the actual data (Journel, 1995). Variography makes geology transportable and allows the geological interpolations to be channelled downstream into mine planning, ultimately affecting the economic decisions surrounding a deposit. As such the process of variography and resource modelling is critical. Thus consistent expert decisions need to be made which force geologists to have a closer look at the available information and the geological interpretations. The aim of this paper is to provide an overview of the latest developments in visualising variography and to demonstrate their usefulness in decisions regarding the spatial continuity of mineralisation. New ideas concerning potential future developments in visualising and modelling spatial continuity through variography are introduced.

Jan 1, 1996

By H. O. Hofman

With the exception of the exhaustive paper on the Father de Smet mill, by its designer, Mr. A. J. Bowie, Jr. (Bans., x. 87), nothing, so far as the writer is aware, has as yet appeared on the stamp-mills of the Black Hills of Dakota, although they have been steady producers for the last ten years. Within the small area of about 6000 by 1600 feet, $2,271,341.14 was produced in 1887† from rock averaging $4 per ton in free gold. I. The Ores. Character of the Ores.—The gold of the district is found in quartz and pyrites finely distributed through vast bodies of mica- and amphibole-schists, argillites and phyllites, and also impregnating the schists themselves. The " Belt," embracing the section of Lead City, Terraville and Central City, is the only part worked at present. The principal associated mineral is iron pyrites, with some arsenopyrite and chalcopyrite, garnet and asbestos. The ores from open cuts and upper levels are more free-milling. than those from underground workings below water-line. Hence

Jan 1, 1889

By P. Lausch, Z. X. He, J. F. Archibald

"Documented underground fill failures have resulted because of the lack of adequate knowledge concerning fill strength and other physical parameters, as well as to a lack of consistent quality of fill materials being used by operators. On the basis of literature review and correspondence with backfill operators at 18 mines throughout the province of Ontario, non-systematic quality control procedures have been shown to exist, both within different levels of single operations and between separate mining operations, which act to provide inferior engineered fill materials and erratic application response in situ.Assessment of existing procedures set by mine operators for determining backfill physical parameters, and recommendation of optimum fill material testing and manufacturing guidelines are presented in this paper.A series of standard fill characterization test procedures are recommended to provide substantial, though not comprehensive, fill behaviour review. The purpose of these recommendations is to propose industry standards for backfill quality review. Data acquired could be utilized for fill design functions and as a means of comparing fill quality parameters between sites in a regular and more systematic fashion than is presently done."

Jan 1, 1993

By Nuno Cruz

"The concrete overbreak estimation for bored piles provides the quantification of the shaft’s expansion beyond its theoretical volume. There are stability analysis methods that can be employed before and after concrete pour but as for the moment of decision, during pile cast, the most common method still consists in measuring the rising of the concrete level in order to compare its poured volume with the theoretical pile section volume. This is a determinant parameter to monitor, not only because it assesses the bored shaft stability but also because it represents a direct cost. When analyzing the estimation methods commonly applied on-site it becomes evident that these are often affected by human errors that lead to misleading results. The objective of this paper is to identify those errors and discuss a subject which is usually overlooked. As a general conclusion, it was ascertained that most errors derive from inaccurate volumetric data, working procedures and gauging equipment. By acknowledging these widespread practices deep foundations contractors will be in a better position to make informed decisions on how to correct and improve bored pile stability.GENERALBackgroundWhen executing bored piles, the estimation of its concrete overbreak allows a swift appraisal of the excavation stability during the drilling process. This is simply obtained from the proportion of the poured volume of concrete over the drilled shaft theoretical volume, as shown in equation [1].Where CO = concrete overbreak percentage, Vc = volume of poured concrete, Vr = pile’s theoretical volume. This calculation not only provides a general idea of the shaft’s expansion from its theoretical volume, but also the outline of the excavated column’s geometry. For the latter, the outline will be as accurate as the number of measurements taken for each partial known volume of poured concrete. This means that for each load placed inside the excavation there is a corresponding rising of the concrete level. The profile of the definite pile is then plotted (see Fig. 1) and allows inferring about how stable remained the shaft walls up to the moment of casting.The technological developments in this area have provided other methods for determining pile stability before and after pile cast, such as ultrasonic echo sensing, cross-hole sonic logging or thermal integrity profiling systems. Notwithstanding, concrete overbreak assessment remains as common practice and confers the advantage of providing stability information during the process of pile casting."

Jan 1, 2017

By R. D. Nelson

The purpose of this technical note is to briefly present some data on a phenomenon—recrystallization with concurrent deformation—that has been found to occur in a plutonium. This phenomenon is unusual because a plutonium is considered brittle, not easily deformed, and not easily recrystallized; the a phase is simple monoclinic having 8 atoms per unit cell and it is stable below about 115°C. The properties of the recrystallized metal were different from the as-cast metal. Even though a plutonium is difficult to deform, Ianniello successfully rolled it' and he also observed some recrystallization at 120°C.2 Pavlick and Hanson3 detected some recovery at 109°C but they observed no recrystallization. Gardner4 and Bronisz5 studied the compression properties up to 100°C but they did not report having seen recrystallization. In the present deformation studies of electrorefined plutonium pronounced recrystallization took place concurrently with plastic deformation in compression between 24" and 115°C. The metal contained less than 300 ppm total impurities with the major impurities being 100 ppm Am, 30 ppm C, 40 ppm W, and 25 ppm U; all other impurities totaled less than 100 ppm. The compression specimens were machined to dimensions of 1.2 cm long and 0.8 cm diam from as-cast rods having a density of 19.65 g per cu cm. They were heated to the test temperature in a high-temperature silicone fluid that was evacuated to 10-4 Torr. With this procedure the specimens oxidized a negligible amount, and the temperature was maintained within ±0.2°C for times up to 3 weeks. Deformation and recrystallization

Jan 1, 1969

By Pengfu Tan

Lead blast-furnace bullion cools to near its freezing point in an operation known as copper drossing or hot drossing usually contains 0.02-0.06% copper. The removal of this copper is usually carried out in a batch operation known as sulfur drossing. Sulfur is stirred into the bullion at temperatures near its freezing point, and the dross of copper and lead sulfides that floats to the surface is skimmed off manually. A thermodynamic model has been developed to simulate the copper drossing. The phase diagram of Pb-Cu-S system has been calculated, and the effects of the process parameters, such as temperature, copper content, and sulfur content, on the drossing process have been simulated and discussed.

Jan 1, 2006