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By G Barla

In Europe, a major interest in the infrastructure and tunnelling fields is in the new crossings of Alps in the form of base tunnels, which are important components of the high-speed (for passengers)/high-capacity (for freight) Trans European railway corridors. These tunnels cross the mountain belt at the elevation of the main cities and basins located all around the Alps and are longer (up to 57 km) and deeper (up to 2500 m) than all tunnels constructed in the centuries before. The excavation of the first Alpine railway and road traffi c tunnels could in general be carried out successfully by conventional excavation methods. With the great lengths of the new base tunnels, mechanised excavation by using tunnel boring machines (TBMs) is imperative as it contributes significantly to savings in construction time and costs. Questions are however posed on the adoption of such a systematic tunnel construction method given the severe ground conditions which are some time anticipated along the tunnel alignment, with possible major geological hazards such as water inflow in heterogeneous fractured or karstifi ed rock masses, stress-induced tensile failure of hard rocks, and plastic shear failure and squeezing of weak rocks, etc. This lecture is to briefly review the current state-of-the-art in the understanding and modelling of two such critical hazards as spalling/bursting and squeezing ground behaviour. With the present interest in the design of mechanised tunnelling with TBMs in such conditions, the complex interaction between the rock mass, the tunnel machine and its system components, and the tunnel support is studied in detail by numerical modelling. The research and development efforts presently underway with the intention to provide the designer with a novel three-dimensional (3D) simulator of mechanised tunnel excavation are presented. Case examples are discussed with reference to the Lyon-Turin Base Tunnel design.

Mar 8, 2011

By Margaret V. Doyle, R. W. Powers

INTERNAL friction measurements, carried out as functions of temperature, have been used extensively to obtain data on the mobility of interstitial impurities in the Group V metals, vanadium, colum-bium, and tantalum. For a given frequency of vibration, the internal friction peaks at a temperature which depends principally on the particular metal and interstitial impurity. Relaxation times and corresponding activation energies are determined from a knowledge of such peak temperatures for various vibration frequencies. These experimentally determined relaxation times are related to the average jump frequencies of the interstitial impurity atoms using the model of Snoek1 and can be related to macroscopic diffusion coefficients as shown by Polder.2 In these Group V elements, the impurity whose diffusion rate has been the hardest to pin down by the internal friction technique has been carbon. The experimental difficulties associated with carbon in these metals were not evident in the earliest investigation carried out by Ke on tantalum.3 The carbon peak was thought to occur near 140°C at 1 cps on the basis of the enhancement of the height of this peak measured on specimens which had been coated with colloidal carbon and heated in vacuo at 1200°C. Presumably on the basis of similar evidence, Wert identified a peak also near 140°C at 1 cps in columbium with the diffusion of carbon in that element." Later, the difficulties of admitting carbon into these metals without simultaneously introducing oxygen were pointed out by Ang and Wert- nd by Marx, Baker, and Sivertsen.6 The latter suggested that the peaks attributed to carbon in tantalum and columbium might arise from the presence of traces of oxygen, adventitiously absorbed during the carburization. Such suspicion was confirmed, at least in tantalum, when it was found possible to prepare C-Ta specimens without contamination by oxygen. Specimens sci prepared, aitnough high in carbon content, gave no evidence of a damping peak near 140°C.7 Recently, the authors were able to Show that carbon diffuses in tantalum at a rate only slightly slower than that for nitrogen.8 At 1 cps, the carbon peak lies at 34g °C, only a few degrees above the nitrogen peak at 341 °C. However, the two could be distinguished by a different stability with respect to aging at 400 °C and by a different dependence of peak height on solute concentration. On the basis of this experience with tantalum, it appeared worthwhile to search also for a carbon peak in columbium in the vicinity of the nitrogen peak." In this report, the location of the carbon peak in columbium is made known and its position relative to the nitrogen peak is compared with the authors' previous findings in tantalum. In addition, a second source of internal friction seen only in specimens of very high purity is discussed. Columbium was obtained from the Fansteel Metallurgical Corp. as either 30 or 40 mil diam stock. The manufacturer gives the following analysis as typical of this material: 99.4 pct minimum Cb, 0.10 pct maximum C, 0.5 pct Ta, 0.04 pct Ti, 0.02 pct maximum Si, and 0.01 pct maximum Fe. Wires 13 in. long were degassed near 2200°C for 4 to 16 hr in an ultimate vacuum better than 2.10" mm Hg in an apparatus described previously.8 This treatment reduced the oxygen and nitrogen damping peaks observed in the as-received material to less than 0.0001 in Q-1 above background. The latter value varied somewhat from specimen to specimen in the range 0.0004 to 0.0008, depending chiefly on the wire diameter and the frequency of vibration. The high temperature evacuation left the specimen in a rather soft condition, the Vhn being reduced to 40 from a value near 121 in the as-received conGi~iur~. The gram size was about the diameter of the specimen. After outgassing, specimens were loaded with carbon by absorption of such hydracarbons as methane or ethylene. Carbon was also added to a few speclrnens by heating them at

Jan 1, 1958

By H. R. Butler, J. F. Church, A. T. MacGibbon

Introduction Inco is the major North American nickel producer. Initially based in Sudbury, Ontario, its past exploration activity was directed toward finding new nickel deposits. New nickel sulfide discoveries outside Sudbury have included Thompson, Manitoba; Shebandowan, Ontario; and Widgiemooltha in Western Australia as well as a host of nickel laterite deposits. The company is currently diversifying into other commodities, including gold. Inco's exploration department participated in uranium discoveries in Saskatchewan and chromite discoveries at Tiebaghi in New Caledonia. In addition, it found new gold deposits at Lupin, Northwest Territories; Crixas, Brazil; Hoyle Township, Ontario; and Casa Berardi in Quebec. Crixas and Casa Berardi are currently being evaluated by underground exploration. Figure 1 shows some Canadian Shield gold locations where Inco is or was an active participant. Base metal developments Base metal exploration in shield areas has been greatly eased by applying scientific studies. Archean nickel sulfide deposits have been found using komatiitic-flow models (Fardon, 1971). Volcanogenic massive sulfide model has been applied to copper-zinc deposits (Sangster and Scott, 1976). Such deposits were subsequently seen developing on the sea floor through black smokers (Spiess, MacDonald, and Atwater, 1980). Sedimentary processes were recognized early as important in ore formation, particularly in the southern hemisphere (King, 1976). And many ore deposits are now regarded as a simple part of the geological column (Stanton, 1960 and 1972). Petrographic work on alteration patterns in and around ore bodies was used to develop standard porphyry copper models (Lowell and Guilbert, 1970). Epithermal models for precious metals followed. Stratigraphic zonation patterns have been formulated for base metal deposits, including keel facies, ore facies, and cap or distal facies. Gold developments The work on base metal deposits naturally spilled over into precious metal exploration when the gold price was allowed to float on world money markets. Early work on elements associated with gold deposits, especially arsenic, tellurium, selenium, and mercury, pioneered more detailed geochemical work (Bagby and Berger, 1985; and Groves, Ho, and Houstoun, 1984). Geochemical patterns have been recognized around microfine gold deposits. And the study of gold precipitation patterns in modern geothermal systems has helped understand gold deposition. In the late 1960s and early 1970s, it was noticed that numerous Archean banded iron formations contained anomalous gold values. From this and other observations, the syngenetic exhalite gold model has developed. Gold deposits also occur along shears in some plutons such as the Belmoral mine in Quebec. This indicates the importance of epigenetic processes in ore formation. Shield ore settings Initial studies recognized that the major gold camps in the Canadian Shield were mostly in greenstone belts and found along "breaks," especially zones of faulting and sedimentation. Gill (1948) wrote, "Only recently, as a result of detailed mapping, has the importance of major schist zones such as the Larder Lake, Cadillac, Porcupine Creek, and Destor Breaks been recognized. These zones of persistent adjustment mark broad belts favorable for ore occurrence." The importance of shearing in ore location and regional greenstone stratigraphic position close to late sedimentary packages was clearly understood. And structural models have been further developed for some Canadian ore deposits (Hubert, Trudel, and Gelinas, 1984). In the Beardmore-Geraldton camp of northwest Ontario, the importance was soon recognized of fold noses in banded iron formation, as localizers for gold ore. This importance had also been recognized in Western Australia,

Jan 2, 1987

By H. P. Rassbach, E. R. Saunders

MUCH progress has been made in recent years in the theory and practice of making stainless steel. By effective utilization of oxygen for decar-burization and more suitable alloying agents, it has been possible to attain consistent production of very low-carbon stainless steel. In order to facilitate economical production of stainless steels, the Electro Metallurgical Co. has carried out an extended experimental program that has clarified some of the complex interrelations of temperature and composition under decarburizing and reducing conditions. These results'-:' have been founded in large part on small experimental heats, and in order to confirm their validity and significance under commercial conditions, a survey of stainless steel melting practice has been made with the cooperation of stainless steel producers. Conditions required for decarburization and associated oxidation of chromium, manganese, and iron have been fairly well established in relation to the beneficial effect of the highest practicable temperature. The recovery of chromium and manganese from highly oxidized slags by reduction with silicon has been indicated with somewhat less precision and this study has shown significant deviation in large commercial heats from the small experimental heats. In spite of an unsatisfactory degree of accuracy in estimating the conditions affecting reduction of metallic values, it has been possible to calculate a slag weight in reasonably good agreement with the results observed in large heats. While there still is much to be learned about both the qualitative and quantitative aspects of stainless steel melting, this survey has indicated the manner by which the efficiency of the production process may be measured. Oxidation Period In order to establish practices for the recovery of chromium and manganese from the slag the amounts of these metals oxidized should be known. Moreover, since reduction of oxidized chromium and manganese must necessarily be accompanied by similar reduction of iron, knowledge of the total quantity of metallics oxidized is essential. The relations between carbon, chromium, and temperature under oxidizing conditions were developed by Hilty in 1948.' While it had been realized previously that retention of chromium in the metal during carbon oxidation is favored by high temperatures, the Hilty relation provided quantitative information useful for evaluating melting procedures. For example, it was shown that decarburization to moderate carbon levels can be achieved while retaining substantial amounts of chromium. However, in decarburizing to the low-carbon level necessary for producing 0.03 pct maximum carbon stainless steel, very little chromium remains in the bath at the temperatures generally employed. For this reason, Hilty, Healy, and Crafts' later projected an extension of the chromium-carbon relation to the low-chromium region. Although this chromium-carbon-temperature relation defined the composition of a chromium steel bath at the end of the oxidizing period, it did not provide a direct means for estimating the total amount of metallic oxidation occurring during decarburization of a stainless steel heat. This subject was investigated by Crafts and Rassbach³ and, later, by Hilty, Healy, and Crafts" who demonstrated that metallic oxidation is a function of the chromium content of the initial furnace charge, the minimum carbon content attained, and the temperature. It was further demonstrated from data on 1-ton heats that an empirical relationship exists between the ratio of chromium plus manganese to iron in the slag (S) to the corresponding ratio of these components present in the metal bath. The following expression was derived to permit the calculation of the amount of metallics oxidized during decarburization of a given charge: W-2000 (Cr1 + Mn1)-(Cr2 + Mn2) 1 100s/s+1-(Cr3 + Mn2) where W is the pounds of chromium, manganese, and iron oxidized per ton of charge; Cr1, the percentage of chromium in the charge; Mn1, the percentage of manganese in the charge; Cr2, the percentage of chromium in the bath after oxidation; Mn2, the percentage of manganese in the bath after % Cr + % Mn oxidation; and S =%cr+ % Mn/%Fe in the slag after %Fe oxidation. In order to establish whether the slag ratios of commercial heats are consistent with those found in the experimental heats, the slag and metal analyses shown in Table I were evaluated. These data represent samples taken after the oxidation of two 1-ton and seven 15 to 25-ton heats of types 303, 304, and 304L stainless steel made in chromite, acid, and basic hearths. Fig. 1 illustrates that the results for the commercial heats correlate reasonably well with the relationship originally established for experimental 1-ton heats. It will be noted that in the range of metal composition of these heats, the slag values generally lie above the line. As was suggested by

Jan 1, 1954

By G. R. Hopkins

The average quantity of heat needed to refine a barrel of crude oil in 1934 was 638,000 B.t.u., or about as much heat energy as contained in 5 gallons of fuel.oil. Although the total heat utilized in 1934 was slightly above 1933, crude runs to stills increased 4 percent, hence the average requirement per barrel declined from 660,000 B.t.u. in 1933 to 638,000 B.t.u. in 1934 (see fig. 1). The average for 1934 constitutes a new record for firing efficiency, being just under the previous low of 1929. Heat consumption at refineries depends on many factors, of which the trends in yields of gasoline and lubricating oils are probably most important. The yield of gasoline is indicative of activity at cracking plants, which typo of plant utilizes more thou the average amount of heat per gallon of product. The yield of lubricating oils is indicative of the extent to which crude oil is refined; that is, it takes considerably more heat to refine a barrel of crude through lubricating oils than it does to separate only gasoline and kerosene. The yield of gasoline decreased from 43.7 percent in 1933 to 43.4 percent in 1934; on the other hand, the yield of gas oil and fuel oil increased. Although the yield of lubricating oils increased slightly in 1934 the theoretical increase in fuel requirements probably was offset by technical improvements, such as solvent refining. Although no outstanding technical developments of a fuel-saving nature were made in 1934, some progress undoubtedly was recorded. Heat exchangers, an effective fuel-saving device, wore enlarged, and some refiners now take off several cuts before the crude reaches the pipe stills. The total capacity of pipe stills increased 2.5 percent in 1934, and many of the less efficient shell stills were torn out.

Jan 1, 1935

By Robinson Irarrazabal, Edison Collinao, Rodrigo de Carvalho, Patricio Davila, Marcelo Tavares

"In recent years, DEM (discrete element method) softwares, along with 3D laser measuring equipment, have become powerful tools to describe mill charge behavior, as well as forces acting on the liners of SAG mills. With the aim of contributing to streamline this application of the advanced technologies ME Elecmetal and Universidade Federal do Rio de Janeiro, UFRJ, proposed a new approach to improve the design of mill liners using elements from mechanistic modeling of grinding. The paper presents a methodology for continuous improvement of liner design, which uses information from the DEM collision energy spectra in the mill discriminated for the different components (ore and steel balls), as well as information on the breakage properties of the ore being ground. From these it proposes the concept of "effective collisions", which corresponds to the collisions that are of sufficient magnitude to cause breakage, thus allowing to discriminate from impacts that do not cause breakage either in a first impact or after repeated loading. It also tracks the collision of steel balls against the shell in order to assess their potential damage to the liners. An industrial case study is presented of a 38’ diameter SAG mill, which was experiencing challenges associated to liner breakage and low efficiency with the old liner design. Through a modification of the liner design, simulations demonstrated the potential benefit associated to reduction in ultraprojection and improvement in mill capacity. Implementation of the new design in the SAG mill was carried out, resulting in increase in daily throughput from 6 to 12%. Further, the time spent in liner change was reduced by 47% given the reduction in the numbers of parts. This operation also benefited from having no stops due to unplanned shutdowns to replace broken tiles. These demonstrate the benefit of coupling advanced computational tools to sound engineering principles in continuous improvement of liners."

Jan 1, 2014

By J. P. Gu, C. Beckermann

"Melt convection and macrosegregation in casting of a large steel ingot is numerically simulated. The simulation is based on a previously developed model for multicomponent steel solidification with melt convection, and involves the solution of fully coupled conservation equations for the transport phenomena in the liquid, mush, and solid. Heat transfer in the mold and insulation materials, as well as the formation of a shrinkage cavity at the top are taken into account. The numerical results show the evolution of the temperature, melt velocity, and species concentration fields during solidification. The predicted variation of the macrosegregation of carbon and sulfur along the vertical centerline is compared with measurements from an industrial steel ingot that was sectioned and analyzed. Although generally good agreement is obtained, the neglect of sedimentation of free equiaxed grains prevents the prediction of the zone of negative macrosegregation observed in the lower part of the ingot. It is also shown that the inclusion of the shrinkage cavity at the top is important in obtaining good agreement between the predictions and measurements.IntroductionMacrosegregation in large steel ingots is one of the most well-known and now classical problems in the field of solidification and casting [1]. Commonly found macrosegregation patterns in steel ingots are a positively segregated zone at the top, negative segregation near the bottom in the equiaxed zone, inverse segregation near the ingot surface, V-segregates along the centerline, and A-segregates in the columnar zone [2, 3]. It is well established that the macroscopic transport of species leading to macrosegregation can occur by a variety of mechanisms, including thermally and solutally driven natural convection of the melt in the mushy zone, flow due to solidification contraction, and the sedimentation of free equiaxed crystals. Fredriksson and coworkers [ 4,5] provide recent overviews of the solidification transport phenomena and macrosegregation in ingot casting."

Jan 1, 1999

By W. Baranek

The paper describes activities undertaken for intensification of copper cathodes production in electro-refining plants of the Polish copper smelters: 'Legnica', `Glogów I' and `Glogów II'. In the 'Legnica' smelter, Outokumpu?Wenmec machine was used for preparation of copper anodes. Intensive studies were conducted in order to optimise copper electro-refining conditions. As the result of them, spacing between the electrodes was reduced to 99 mm, which enabled placing forty-one cathodes in each tank and increasing amperage from 10.8 to 13.0 kA. This modification resulted in the increase of electro-refining capacity to 103,000 tons/y. Intensification of the copper production at `Glogów II' by 18,000 tons/y became possible after development of new electro-refining procedures, including application of a regime of changes in electrolyte level during the cathode cycle, implementation of the changes in location of starting sheets relative to anodes, and in dimensions of the sheets, and modification in the shape of the anodes. Similar works have been performed at `Glogów I', which were concentrated mainly on defining of a new method of anodes preparation, modification of their geometry, determination of optimum current density, composition of a set of inhibitors and of a method of their introducing. The implemented solutions resulted in the increase in electro-refining capacity at `Glogów I' from 207,000 to 240,000 tons/y.

Jan 1, 2007

By E. C. Wright

FOR many years the cost of making pig iron and steel in the Birmingham district has been about the lowest in the United States. The close proximity of the important raw materials such as coal, iron ore, limestone, and the large available scrap supply made it possible to assemble all of the important ingredients necessary for steel-making with only nominal costs for transportation. Both iron ore and coal were being mined in this district at one time for about $1 per ton from underground operations. At that time mining wages were low everywhere and the labor rate in the South was considerably below that of other mining districts. This situation persisted until the emergence of labor unions as an economic and political force, emigation of southern labor to northern plants, and continued growth of industry in the South in the years following the depression of 1932. Since that time union organizing of miners and steel workers throughout the nation has increased labor costs in mining and steelmaking. This influence has been felt particularly in underground mining operations since the proportion of labor cost to total cost is still high. The previous advantage in basic labor rate in the South has been almost entirely eliminated by the equalization of labor rates in basic industries by national unions.

Jan 12, 1950

By R J. Wood

Raise drilling (or raise boring) is not a new technology or methodology. The first raise drilling machine was developed by The Robbins Company (TRC) of the USA in 1962. TRC manufactured the first tunnel boring machine (TBM) in 1952 and Jim Robbins, the founder of the company wanted to ‘turn the TBM concept on its head’ so to speak.Many improvements have ensued in the 50 years since the first machine. Such improvements include advances in the drill rod and thread design, cutters and reaming heads. Raise boring would not have been possible without the development of the tungsten carbide insert cutters and there have been big advances in both the carbide technology and in the mechanical design of the cutters.Over time mines have developed deeper with a greater use of diesel equipment resulting in greater ventilation requirements. This in turn means larger and deeper ventilation shafts. There have also been improvements in directional drilling techniques. This all combines with the need and ability to construct larger shafts using the safe method of raise drilling. With suitable geotechnical conditions the RBR900VF is capable of drilling shafts to a diameter and depth of greater than 8 m and 2000 m respectively. Greater diameters are possible over shorter lengths with suitable ground conditions.The RBR900VF was designed and manufactured to specifications developed by Macmahon. This machine has the greatest thrust and torque capability of any machine in the world. It enables cutters to be more heavily loaded in the larger diameter heads and this is essential for efficient rock excavation. Additional features of the new machine include minimal manual handling to provide a safer working environment and higher strength steel for the drill rods providing additional safety margin.CITATION:Wood, R J, 2014. A revolution in raise boring – the development of the RBR900VF, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 171–178 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By John O. Atkins

[Experiments were conducted by the Bureau of Mines on five types of simuated lunar rock (dacite, tholeiitic basalt, vesicular basalt, pumice, and uluth Gabbro) to study the effects of various simulated lunar environments n their strength and deformational properties. Specimens were tested in an ltrahigh vacuum (UHV) system at pressures ranging from atmospheric down to 0-11 torr and at temperatures of -130°, 20°, and 135° C. All tests were onducted with a servocontrolled testing machine. Rock specimens tested at 0° C in UHV exhibited significantly higher compressive strength and Young's odulus than those tested at 20° C in atmospheric pressure. The magnitudes f increase are related to the porosities and permeabilities of the rock pecimens; high porosity and permeability allow better outgassing and thus nprove surface cleanliness in UHV. The compressive strength generally ncreases but Young's modulus decreases as test environments change from 20° C i UHV to 135° C in UHV. No significant difference was observed in the iysical properties measured at 20° C in LTV and -130° C in UHV. Anisotropy i strength and Young's modulus exist both in UHV and at atmospheric condi¬'.ons with the same symmetry pattern. The orientations of the principal axes iy, however, change from the atmospheric to UHV condition. The results idicate that rock fragmentation in lunar environment will require more ergy than that at 20° C in atomospheric pressure.]

Jan 1, 1974

By N. N. Breyer

A specially built "hard" tensile machine with characteristics permitting the precise detertnination of the drop of the load at the yield point has been used to study the magnitude of the yield-point phenotnenon in prestrained martensitic 4340 steel. A new phenonzenon, the appearance of a secondary yield point, has been observed by holding the specimen at constant strain in the plastic region. Furthermore, it has been found that a series of yield-point drops could be introduced by successive constant strain holds in the plastic region. The isothermal kinetics of the development of the secondary yielding point lave been studied at four temperatures: 24° 0° -18°, and -79°C. From the results of the kinetic investigation, equations for the In a previous investigation1 it was shown that, contrary to generally held opinion, steels of medium carbon content, such as 4340, 4140, and 86B30, in the as-quenched martensitic condition, can be cold-drawn through a die with reductions in area of up to 10 pct without cracking. Tensile specimens of 4340 machined from bars quenched and prestrained in this manner exhibited tensile strengths of about 400,000 psi coupled with 30 pct reductions in area. In addition, it was found that each sample of such steels exhibited a yield point in the quenched, cold-drawn condition. Since these studies were conducted on a commercial hydraulic testing machine of a type which is not well-suited to detailed study of yield-point behavior, it was decided to study this phenomenon more thoroughly on a rigid straining machine. In this new investigation, use of such a "hard" machine not only allowed study of the magnitude of the yield-point drop but also revealed a new phenomenon—secondary yielding of the martensite introduced by stopping crosshead motion after plastic deformation of the sample had begun. The present paper is a report of these findings. MATERIALS AND PROCESSING The material used was a commercial 4340 steel of the composition shown below: 0.41 0.80 0.013 0.019 0.31 0.85 1.76 0.28 1 0.42 0.77 0.015 0.024 0.30 0.84 1.69 0.28 0.08 2 1 = Ladle analysis. 2 = Laboratory analysis. Bars of this steel were processed in the following way: 1) machined to predetermined diameters; 2) austenitized at 870°C for 1 1/2 hr; 3) oil-quenched; 4) cooled to -115°C for 1/2 hr; onset and increase in magnitude of the secondary yielding in this temperature region have been found to fit the relationship ?Ys = Atn where ?Ys is the magnitude of the secondary yield Point in psi, t is the time in seconds, and A and n are parameter characteris-tics of the material. Although the occurrence of the primary and secondary yield points could be rationalized qualitatively on the basis of stress-induced ordering of carbon atoms in the stress fields of dislocations, as postulated in an earlier paper, the kinetics of the secondary-yield-point development were interpreted to indicate that the ordering involves more than just single jumps of carbon atoms from high-energy to neighboring low-energy sites. 5) pickled and lime-coated; 6) drawn through a carbide die. The predetermined diameters were chosen so that drawing through the same die gave the various reductions desired. Tensile specimens of 0.252 in. diam with a 1 1/4 in. gage length were then prepared from the drawn bars and tested. In order to study the stress-strain behavior at the yield point in detail, a rigid tensile machine with a high spring constant was constructed. Columns of large cross section (relative to the specimen cross section) constituted the machine frame. A dc motor was used to drive a screw via a gear reducing train and a "crane" thrust bearing. In this relatively simple device small deformations could be observed un-blurred by the slow response and lower spring constant inherent in hydraulic machines.' A strain-gage dynamometer permitted load changes as small as 8 lb to be read. RESULTS Tensile test samples machined from bars in the as-quenched condition with no subsequent drawing and samples from bars with 3.8 pct reduction after quenching gave stress-strain curves typified by those shown in Figs. I and 2. The time lapse between predrawing and tensile testing varied but usually ranged between 3 to 6 days at room temperature. The strain rate during testing was 0.003 in. per in. per min. The as-quenched curve is seen to have a broad serrated maximum whereas the stress on the specimen prestrained 3.8 pct rose linearly to point A, Fig. 2, fell abruptly to B, and then gradually to C. The abrupt drop to B was accompanied by evidence of incipient necking. The drop of the stress at the yield point in the prestrained samples (A to B in Fig. 2) changed with the percent prestrain, as illustrated on Fig. 3. Although the tensile strength increased continuously with the amount of previous cold drawing, the magnitude of the yield point drop first increased—up to about 6 pct prior reduction—and then decreased. Specimens from bars predrawn more than 8 pct broke in a brittle fashion in the elastic portion of the stress-strain curve.

Jan 1, 1967

By Carl S. Westerberg

1,. C. McCABE*-—An increased derliand for coal in the west is to be expected because of the growth in population and industry during the past ten years. The author calls attention to the increased mechanical cleaning of Utah coal between 1938, when no cleaning was being done, and 194.7, when more than 24 pct of the production was cleaned. This is essentially the Period of most rapid growth of the Pacific Coast. area altliough the growth and, no doubt, the general trends in coal production and cleaning continued at a less accelerated rate during 1948. The Pacific southwest increased 37 pct in population between 1940 and 191.7 while the United States showed only a 7 pct increase in the same period. it has been estimated that there will be an additional 15 pct increase in population between 1947 and 1950. The conclusion that more coal and more mechanicak cleaning capacity will be required appears to be well founded. Mr. Westerberg discusses the cco- nomic advantages of coal cleaning reflected in freight savings, in lower cost per million Btu, and lowered ash and sulphur content. In view of the limited occurrence of coking coals in the west it would be interesting to know whether significant beneficiation in coking strength can be expected from mechanical cleaning of Utah coals. This has been demonstrated for some eastern and midwestern coals. One can readily agree to the desirability of recovering the fine coal that has heretofore been lost in washery slurry. The very cheapness of coal has Iridered

Jan 1, 1950

By Lawson F

The leaching behaviour of BHAS copper matte in oxygenated acidic sulphate chloride solutions at 85¦C has been studied using samples containing 34% copper, 41% lead and 12% sulphur. Copper sulphide in the matte, essentially Cu2S was found to leach in two distinct stages. Similar to the behaviour of pure chalcocite, copper dissolution in the first stage was affected by the availability of oxygen in solution. The presence of chloride ions in the leachant was essential if there was to be any leaching in the second stage (which usually commenced after about 40% of the copper had been taken into solution). Lead sulphide in the matte was oxidised to lead sulphate and formed a shell around the partially leached matte particles. Electrochemical studies showed that this lead sulphate and/or sulphur produced during leaching can form a passivating layer around the copper sulphide. However, this layer was disrupted when chloride ions were present. A Plackett-Burman analysis was used to determine the species in the recycled leach solution that affect the leaching of copper. Under the experimental conditions used, in the first stage the rate of copper dissolution was influenced by the concentrations of sulphuric acid, Zn(II), Cu(II), Fe(III) and Cd(II). In the second stage, the rate was futher modified by the concentrations of Cl(I) and As(V) ions. In solutions of low acidity and high As(V) concentration, insoluble copper arsenate formed which coated the partially leached matte particles and acted as a barrier to futher reaction.

Jan 1, 1989

By H. A. Davies

DURING a current program of research on the structure and properties of liquid sodium alloys, the need arose for information on the solubilities as a function of temperature of several B subgroup metals in liquid sodium. In the absence of reliable information in the literature for several of these systems, par- ticularly at temperatures in the range 100° to 300°C, an apparatus was constructed to determine solubilities by a direct melt-sampling technique, followed by wet-chemical analysis for both sodium and the solute metal. The details of the technique have been described previously.' The solubility of indium in liquid sodium was determined at eight temperatures in the range 100° to 270°C. The solubility as a function of temperature is shown on Fig. 1; this represents the liquidus line over this composition range. A cooling curve was plotted after the completion of the sampling and an arrest was observed at 94.9°C which must be interpreted as being the result of a eutectic reaction. By extrapolation of the liquidus to this temperature, the eutectic composition was estimated to be about 0.25 at. pct In. The present estimate of the eutectic temperature and composition are in good agreement with the values of 96.0° to 96.2°C and between 0.28 and 0.45 at. pct In, respectively, which were reported by Heycock and Neville.2 However, no further information on the liquidus of this system at the sodium-rich end could be found in the literature for comparison. One compound: NaIn, has been reported in this sys-

Jan 1, 1968

By W. P. Staunton, K. Jones

INTRODUCTION The increased activity in the Aus­tralian gold industry over the last decade has resulted in a concomitant increase in the use of sodium cyanide, with a projected consumption of 80,000 tonnes in 1991. Growing environmental awareness by government, industry and the public has generated increased interest in the fate of cyanide near gold mine tailings dams and has highlighted the lack of basic knowledge in the area, particularly for Australian conditions. In 1989 the Chemistry Centre (W.A,) commenced a' project, under the auspices of the Australian Mineral Industries Research Association entitled "Fate of cyanide in the Enviroment Near Mine Tailings" to investigate some of the issues arising from the management of tailings containing cyanide, The project, which has been supported by thirteen companies has three broad aims:

Jan 1, 1991

By Lars Thomassen, Ernest Kirkendall, Clair Upthegrove

THE amount of research done in the last few years on the subject of diffusion in solid metals is significant of the importance of this problem. To review the literature dealing with diffusion is unnecessary here. Desch1 in 1912 reviewed the work that had been done on diffusion in solids and gave a bibliography of the literature published before that time. Mehl's paper in 19362 is an excellent review of diffusion in metals and contains a large bibliography. Of importance also for its review and bibliography is an article by A. I. Krynitsky.3 While considerable material has appeared in the literature on diffusion in brass, the amount of information is not great compared to that pertaining to some of the other alloys. Most of the information published is of a qualitative nature; that which is quantitative varies considerably. Thus the quantitative determination of the rates of diffusion of copper and zinc in alpha brass by a new method appeared worth while. In the present investigation the rate of diffusion of zinc in approximately the same composition alpha brass has been determined at three temperatures. PROCEDURE The method used consisted of plating copper on a beta brass, heating it to allow diffusion to take place, and measuring the concentration of copper by determining the lattice constant of the alloy. This method is unique in that it uses a beta brass of such a composition that at the temperature at which diffusion takes place the beta brass is saturated with copper. Thus, while the beta brass supplies the zinc, no diffusion takes

Jan 1, 1938

By Y. Luo

Based on the concept of slope stability analysis, a formula for determining an important parameter required in the mathematical model for the prediction of mining subsidence in hilly terrain has been proposed. The slope geometry and soil physical and mechanical properties of the surface natural slope can all be considered in the formula. Incorporation of this new formula into an existing mathematical model provides an integrated approach in studying ground movement in hilly regions.

Jan 1, 1998

By V. I. Ryaboy, V. P. Kretov, S. E. Levkovets, I. V. Ryaboy

"Using the flotation of a gold-containing ore from a deposit in Kazakhstan as an example, we have conducted a study designing dialkyldithiophosphate collectors, in addition to xanthates, for the flotation of hard-toenrich gold-containing ores to increase gold recovery.The increased flotational ability of the dialkyldithiophosphates was determined by their surface activity at the liquid-gas interface and their hydrophobic ability, the changing of which allowed us to control the collecting power and selective ability of the dialkyldithiophosphates. The studying of the surface activity of aqueous solutions was done using the stalagmometric method and the evaluation of the hydrophobic ability was done in percentage of the relative value of the zinc ion binding in the solution in standard conditions.Studying the influence of surface activity in our designed dialkyldithiophosphate collectors, with their close hydrophobic ability, showed that even with a small increase in surface activity in their aqueous solutions, gold recovery increased by 2-3% in laboratory conditions. Using this enabled us first to apply the dialkyldithiophosphate collector BTF-161 at a plant in Kazakhstan, and then to introduce the specially designed dialkyldithiophosphate collector BTF-163, which has been in use since. Further study of dialkyldithiophosphate activity based on this concept showed us that for the range of short-chain dialkyldithiophosphate collectors with a chain length of up to ?5, the effectiveness of ore processing became lower the higher their surface activity got, with relatively small differences in their hydrophobic ability. For long-chain dialkyldithiophosphates with a chain length of over ?5, ore processing effectiveness increased with the increase of their hydrophobic ability.Based on these studies, a new effective dialkyldithiophosphate collector, BTF-1517, was designed. Using this reagent in continuous gold recovery tests allowed us to reach an 84.21% recovery with a concentrate quality of 15.66 g/t, while using the applied collector BTF-163 in similar conditions led to the recovery of 82.87% with a concentrate quality of 15.65%. As a result, the Kazakhstan processing plant decided to conduct industrial tests with the BTF-1517 collector."

Jan 1, 2018

By A. B. Kinzel

Since the exposition of the behavior of certain iron alloys by Sykesl involving the existence of an austenite loop and the discovery of such a loop in the chrome-iron system by Bain,2 there has been much conjecture both on his part and on the part of metallurgists in general as to the exact shape and location of this loop. In previous work commercial steel has been used and the microscope has been employed to locate the critical points so that the position of the loop has been quite approximate. Numerous attempts have been made to measure the critical points of the carbon-free alloys but all of these for one reason or another have failed. A satisfactory method for studying these phenomena is presented here. MateRial The first difficulty in this study was to obtain pure chromium-iron alloys. This has been overcome by melting in a vacuum electrolytic iron and chromium analyzing 99.84 Cr, Fe and C. A pure magnesite crucible was used and the melt allowed to solidify in the crucible. A typical analysis is chromium, 10.10 per cent., carbon, 0.006 per cent., silicon and manganese nil. To overcome the problem presented by segregation, ingots were made into wire 0.04 in. in diameter. This was accomplished by hand-forging the ingots into rods, using an oxyhydrogen flame for heating, in order to avoid carbon. Subsequently the rods were swaged to wire, the heating being carried out in hydrogen. Thus local segregation was eliminated although differences in analysis between portions 50 ft. apart were noted. An electric-resistance method was first tried to determine the critical points, but due to the physical defects in the wire this failed. Bain had previously shown the presence or absence of critical points in a qualitative way by observing the sag in a catenary. The author has devised the following method which gives an accurate determination of the critical points from expansion-temperature curves of suspended wire, a special telescopic dilatometer being used for the purpose.