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By S. B. Christy

The practice of the cyanide-process of gold-extraction has brought to light many important contradictions of familiar chemical analogies, which still obscure both the theory and the practice of the art with distinctions subtler and more difficult to make or follow than those which delighted the heart of the old-time metaphysician. Yet Nature herself has drawn these distinctions; and if we hope to succeed in this modern search for the Golden Fleece, we must be able to follow her through the winding labyrinth. There are so many phases of this question that I shall attempt to touch on only one of them at this time, but it is one that lies at the root of many others. In reviewing my paper on " The Solution and Precipitation of Cyanide of Gold,"* Mr. E. B. Wilson contends† that" in the solution of gold by means of alkaline cyanides the various reactions are determined, as to their order and intensity, by the relative position of the elements concerned in the electro-chemical series, or series of voltaic tension." In a modified form this statement is probably true. That is to say, the difference of electrical potential in any closed electrical circuit determines the nature of the reactions which ensue. But the matter is not so simple as Mr. Wilson assumes. Recent investigations show that the order of the metals in the electro-chemical series depends not only on the nature of the elements themselves, but also on the chemical composition of the solution in which they are placed; its degree of concentration; its temperature; and, in the case of gases, on the pressure. Unless all these conditions are taken into account, inferences drawn from the electro-chemical series are likely to prove more

Jan 1, 1901

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Numerous schemes have been proposed in the past to evaluate the shear strength of rock discontinuities based on in situ and laboratory testing. Due to scale effects, in situ testing is the most reliable way to assess the shear strength parameters. However, practical reasons often impede this kind of testing. This is unfortunate because advances in theoretical rock mechanics are still dependant on qualitative experimental works. This paper presents a mobile high capacity shear apparatus developed for in situ direct shear testing of discontinuities along with testing methodology. The apparatus has the advantage of being simple, although of high capacity, and can be moved to different site locations for other tests. The in situ test was performed on a natural rock outcrop of schist with subvertical schistosity. A concrete block 50 x 50 cm with a base layer of high strength mortar was cast on the rock surface. Prior to the test, the concrete block was lifted and repositioned to have an unbonded joint but with interlocking asperities. The shear load was applied perpendicularly to the schistosity direction. The test was conducted in a constant normal load (CNL) condition. Both normal and shear loads were applied manually. The instrumentation consisted of two load cells for shear and normal loading, eight displacement laser extensometers for shear, normal, and lateral displacements and fourteen acoustic emission sensors for monitoring evolution of asperities’ degradation during the test. The friction angle obtained is 72° for the peak and 58° for the residual. The high values of friction angle indicates that first-order roughness and good interlocking of the joint surfaces can result in high shear strength parameter values in a rock generally regarded to have low values.

Jan 1, 2015

By E. P. Whelan

A recent investigation1 into the origin of "ghost boundaries" in dilute Cd-Mg alloys has indicated the persistence of a segregated solidification substructure in spite of a homogenizing treatment designed to remove such segregation. Although no grain growth experiments have been reported on these segregated alloys, the homogenizing treatment used in grain growth studies on other dilute alloys2-7 is similar in

Jan 1, 1968

By Pierre O'Dowd

"The southern Abitibi Belt is the major source of gold in Quebec. Although the northern part of the belt is quickly being developed, the area under study will not be downgraded in the near future because it still contains more than 75% of the known reserves in the belt.Gold is found in a variety of geological environments which are part of a small number of distinct structural patterns. For the exploration geologist, outlining such patterns might be easier and more productive than defining, when it is possible, the exact genetic nature of the gold mineralization.Exploring in the right place has always been one of the main concerns of explorationists. This paper briefly describes the various favourable geological settings, and outlines areas, types of structure and lithologies of high potential for gold exploration in the southern Abitibi Belt.IntroductionThe southern part of the Abitibi Belt is a profilic mining area for precious and base metals (Lulin 1990). Although mineralizing processes and controls of polymetallic deposits are well known and understood (Lydon 1984), almost every gold occurrence is a unique case and numerous models have been proposed (Roberts 1987; Hodgson and McGeehan 1982; Hodgson 1990).This study does not define new genetic models for the formation of gold deposits, neither is it meant to elaborate on the existing ones. A genetic approach, is by definition, theoretical and, to some extent, universal. It helps geologists define types of targets and exploration tools but does not outline or quantify target areas. To tentatively summarize the complexity of a genetic approach, a brief discussion on the various genetic models in vogue in Abitibi and the problems related to their use in exploration can be found at the end of this paper."

Jan 1, 1991

By J. P. Myers, A. H. Flagg, E. S. Mardock, J. L. P. Campbell, J. M. Terry

The development process for the use of radioactive tracers as a means of locating zones of permeability is discussed. The general techniques for the safe handling of radioactive materials is given as developed by the Lane-Wells Co. and Well Surveys, Inc. The prob1em and. successes with tracers in waterflood systetns, oil and gas injection profiles, fracture sand tracing, squeeze (ement tracing. lost circulution, and cement top localion are discussed and illustrated. INTRODUCTION The exact location of the permeable zones lying within the productive horizon has been a major problem faced by the petroleum engineer for decades, and it has been a problem which has seldom been solved with certainty. Reservoir engineers usually have to incorporate a question mark in their estimates of future reservoir performance because of blanks in the core data. Although the use of radioactivity or electrical logs for the estimation of porosity has been of great assistance in furnishing a record for the reservoir engineer, this application of logging data has not completely solved the problem. In short, the industry needs an in-situ well surveying method which can locate and estimate the permeability of the zones existing within a given pay section. The initial development work with radioactive tracers has been towards filling the need for permeability information. Progress to date permits the location of permeable zones with a qualitative estimate of their relative importance with respect to permeability. The calibration of the method is still incomplete. but present development work on tracer preparations, borehole effect correction factors, and instrument limitations give a promise of quantitative "permeability profiles" in the near future. The development work on the radioactive tracer method discussed here began several years ago in the laboratories of Well Surveys, Inc., in Tulsa. At the outset of this work, three approaches to the problem were visualized as follows: 1. A fluid carrying a soluble, chemically inert, gamma ray emitting isotope is pumped down the borehole and out into the permeable zones of the formation. The greater gamma activity of the permeable zones thus permits them to be differentiated from the impermeable zones which contain no active tracer. It was found difficult to obtain a tracer material which was chemically inert. Absorption to some degree was noted in all experiments. Also, it proved impossible to hold the tracer near the horehole where it could be logged. 2. A fluid carrying a soluble, gamma ray emitting isotope is pumped down the borehole into the permeable formations. In contrast with proposal 1, above. the tracer is chemically active with the fluids and materials in the pore spaces of the permeable zones. The permeable zones are thus indicated by their higher radioactivity level. The main difficulty in this proposal was finding a tracer material which would not be absorbed by shale as well as in the permeable porosity. Very little field work was done with this system. 3. Radioactive particles suspended within the injection fluid are pumped down the well. As the fluid enters the permeable formations, the radioactive particles are filtered out on borehole wall. The permeable zones are differentiated from the impermeable by the gamma ray activity deposited on the formation wall.

Jan 1, 1956

By K. Mukherjee

A quasi-thermodynamic calculation is presented for estirt~ating vacancy Parameters in fcc metals. For fcc metals the equilibrium vacancy concentration at the melting point can be approximated by a constant mole fraction. The Gibbs free energy of formation of the vacancies can then be expressed as a simple function of the absolute melting temperature alone. From this description the formation energy Ef, the vibrational entropy Sv, and the formation volume of a vacancy can be calculated in terms of known thermodynamic parameters. The calculated values are in good agree-rnent with available experimental results. IT appears that many of the physical parameters associated with lattice defects can be empirically related to thermodynamic melting parameters.'-7 Besides the implicit correlations between melting phenomenon and point defects, the melting temperature itself at atmospheric pressure can be used as a reference temperature for the purpose of comparison of vacancy concentrations in a given crystal class. The concentration at the melting point then corresponds to the maximum vacancy super saturation in the crystalline state at a fixed pressure. For pure fcc metals such as Au, Cu, Al, Ag, Pb, and Pt the mole fraction of vacancies at the melting point8 is of the order of 10*"3 to 10"1. The equation expressing the equilibrium vacancy concentration at the melting point contains three parameters: the formation energy, the vibrational entropy, and the absolute melting temperature, see Eq. [2]. Since these three parameters cover a wide range of values8 in the above-mentioned metals, it can be assumed that in other fcc metals, for which no reliable data are available, the mole fraction of vacancies at the melting point most likely lies in the range 10~3 to lO"4. This is then the basis of the calculations described in this article. Within this range the mixing entropy can be linearized and the vibrational entropy, the formation energy, and the vacancy formation volume can be calculated in terms of known thermodynamic constants. 1} LINEARIZATION OF MIXING ENTROPY The Helmholtz free energy of a crystal containing n vacancies at the melting point can be writteng as where Ef, T,, k, and S, are the formation energy of a vacancy, the absolute melting temperature, Boltz-mann's constant, and the vacancy formation entropy, respectively. After applying Stirling's approximation in Eq. [l] and minimizing with respect to n where (n/N), is the equilibrium vacancy concentration in mole fraction at the melting temperature at 1 atm pressure. If instead of setting (6~/6n) = 0 immediately after Stirling's approximation in Eq. [I], the configurational partition function is simplified, then some useful and significant results can be obtained by utilizing the experimental inforrnation After applying Stirling's approximation and rearranging is plotted as a function of (n/N) in Fig. 1. The points, not all of which are shown, are fitted by a straight line substituting from Eq. [5] into Eq. [I] and minimizing with respect to n combining Eqs. [6] and [2] It must be emphasized that Eq. [7] is only a crude approximation based on an oversimplified model of

Jan 1, 1967

By M. T. Worley

Joint Development Associates International, Inc. (JDA) began humanitarian relief and community development in Central Asia in1992, following the collapse of the former Soviet Union. Appropriate technology has played an important role in their efforts to assist those segments of society that are most vulnerable to poverty and disease. Three case histories are described to illustrate the successful implementation of simple, but effective technology in community development.

Jan 1, 2004

By Xie Zhang, Jiang Diao, Xiaojun Li, Bing Xie

"Vanadium is widely utilized as an important element to improve the quality of alloyed steels in iron and steel industry. Moreover, the crystallization process of V-containing spinels plays a significant role due to the aim of achieving a fairly larger size of spinel crystals in vanadium extraction. Thus, a comprehensive exploration and discussion on the competitive precipitation and growth of vanadium, chromium and titanium spinel crystals in vanadium slag during a cooling process were carried out in the present study on the basis of a crystallization kinetic model. To be more specific, the abilities of forming crystal, precipitation order and suitable temperature range for crystallization of the three kinds of spinels were discussed with both theoretical and experimental methods.IntroductionVanadium is an important element which is used almost exclusively in ferrous and non-ferrous alloys due to its excellent physical properties such as high tensile strength, hardness, and fatigue resistance [1]. Various kinds of processes of vanadium extraction from V-containing hot metal are available at present. However, only four processes which are the Highveld process (South Africa), the Pan-steel process (China), the NTMK duplex process (Russia) and the New Zealand steel process (New Zealand) take the dominant positions [2, 3]. Although the type of reactor and the initial vanadium content in hot metal are different in these techniques, they share the same principle that vanadium is oxidized by oxygen into vanadium slag."

Jan 1, 2012

By Edward D. Thimons

Several types of inflatable stoppings, developed under Bureau of Mines contract for use as mine air barriers during underground production, have been tested by the Bureau. All of the stoppings tested showed significant internal leakage initially but, in all but one stopping, the leaks were sealed with limited effort The stoppings were tested underground in two western noncoal mines under production conditions. The results from the Colorado molybdenum mine showed the stoppings to be generally unsatisfactory for daily mine usage if they are deployed near blasting areas or in locations where near-perfect air seals are required. They were very susceptible to blast damage and seldom were better than 90 percent efficient as air barriers. However, stoppings tested in the New Mexico uranium mine were located substantially distant from any blasting. Because slight leakage past the stoppings was acceptable, they proved very satisfactory in that application.

Jan 1, 1976

By D. Tang

The froth zone in a flotation cell is recognised as a region which contributes to the overall flotation performance. Froth recovery is a measure of the efficiency with which the froth phase delivers particles arriving at the pulp-froth interface to the concentrate. Poor froth recovery in scavenger stages is generally attributed to poor froth stability. The key indicators of froth performance: froth recovery, entrainment and water recovery were measured in an OK3 pilot cell installed at a zinc concentrator in Australia and supplied with scavenger feed. Cell hydrodynamic and pulp chemical conditions during the operation of the cell were also measured as well as bubble growth across the froth phase. The objective of the work was to assess the impact of a number of commercial frothers on the froth performance in the OK3 cell and assess the suitability of using bubble growth as an indicator of froth stability.

Jan 1, 2014

By X. -P. Zhang, L. N. Y. Wong

Shale gas exploitation initiated in North America has rapidly extended worldwide. Hydraulic fracturing is an emerging field technique for stimulating the gas reservoir. The study of cracking processes, particularly crack coalescence, is vital for a successful hydraulic fracturing to enhance the gas exploitation. Experimental studies have observed that the size effects of the constituent particles are significant on the cracking behavior of the rock specimens. To further investigate the size effects, the bonded-particle model (BPM), which is based on the discrete element method (DEM), is adopted in the present research. In flaw-containing specimens, by varying the crack resolution (?= a/2R), which is the ratio of half flaw length (a) to particle size (2R), the size effects on cracking behavior under compressive loading are studied. By keeping the flaw length constant, the particle size is varied independently in the BPM analysis. Decreasing the crack resolution increases the first crack initiation stress, but it has no obvious effects on the uniaxial compressive strength. The trajectories of the first cracks and secondary cracks hence generated have a higher resolution and are well-defined in those specimens possessing a higher crack resolution. On the contrary, in lower crack resolution specimens, the macroscopic first cracks appear to be wider and less continuous. These findings from numerical simulation clearly demonstrate particle size effects on cracking behavior. Special attention should be paid to these effects in future numerical study using the bonded particle model.

Jan 1, 2015

By A Nixon

The Australian mining industry has changed dramatically over the past 20 years in terms of mining methods, mining equipment and human resource policies. The industryÆs approach to safety and health in terms of attitudes, style of legislation, and risk management techniques has also changed significantly. These changes have had and continue to have major impacts on the design of underground mine ventilation systems. In some areas, trends are clearly emerging. In other areas, mine ventilation planning remains very æreactiveÆ and is performing poorly in terms of providing a safe and healthy work environment at a reasonable cost. New concepts involving the role of ramps and shafts, the provision of refrigerated air, æventilation on demandÆ and newe gress and entrapment approaches are likely to be incorporated into mine planning and operating practices over the next ten years. This paper discusses these and other trends and identifies some likely future developments in the area of hardrock mine ventilation.

Jan 1, 2005

In situ mining is no longer a "last ditch" approach for recovery of uranium, but a proven and competitive method of exploiting sedimentary deposits. Today, in any feasibility study of uranium properties, the project manager would be prudent to compare the economics of in situ methods with conventional surface and underground techniques. In this comparison of in situ and open-pit mining, John J. Borkert and Carl E. Gerity of Occidental Minerals Corp., evaluated a group of hypothetical uranium deposits using the three most sensitive depositional characteristics of depth, size, and grade. Their conclusion: in situ is generally the better method to maximize total net profits and return on investment. At uranium values of $40 per pound, their analysis found open-pit mining to he unprofitable, generally, when stripping ratios were greater than 30:1, the deposit grade-thickness (GT) was 0.5 or less, or the ratio of depth to GT was greater than 200.

Jan 10, 1978

By Thomas J. Ferree

The principle mineral concentration practices today can be divided into three basic process categories: magnetic separation, flotation and gravity separation. The basic processes have been in use for many years with only limited changes occurring in equipment design or process technique. In general, equipment and process techniques have been altered only after a need for change has developed. With exceptions for changes necessitated by new environmental laws, most equipment and process improvements have evolved in accordance with the desire to concentrate larger quantities of material at lower costs. The basic result has been the development of larger capacity equipment, to wit: larger flotation cells, larger blast furnaces, larger haulage equipment and larger chemical process equipment. However, there has been practically no changes in the size of spirals, tables, jigs, or-within limits- magnetic separators. (The exception being high-intensity magnetic separators). Consequently, a "new" device has entered the scene which may fill a void in the gravity separation field. It is called a Reichert cone concentrator.

Jan 3, 1973

By E S. Bernard

Steel fibre reinforced shotcrete (SFRS) is increasingly being used as ground support in both civil and mining applications. In recent years, methods of assessing the performance of SFRS have been developed. These include the beam test such as that prescribed by ASTM C-1018 and the panel test prescribed in the EFNARC European Shotcreting Standard. The panel test has gained popularity in recent times due to the two-way action modelled in the test. However, some difficulties have been noticed. Shear failures sometimes occur and there appears to be a rather high degree of variability in the panel test results. A new method of testing panels has been proposed. A circular panel supported on three symmetrically arranged points has been assessed at the University of Western Sydney. This paper describes the new test which may be the basis of a new specification for the testing of toughness of SFRS and summarises research work which has been carried out to-date.

Jan 1, 1999

Scientific elite of the Minerals Beneficiation Div. assembled in Denver, Colo., September 17 to 20 to commemorate the 50th Anniversary of Froth Flotation in the United States of America. In his warm address of welcome at the opening luncheon, John W. Vanderwilt, President, Colorado School of Mines, recalled his experience in Bonanza which coincided with the early days of flotation. In those years the scientific and engineering aspects of the process which we know today were little understood and operating the flotation circuit was considered an "art." Luncheon Chairman H. L. McNeill caught the flavor of the old days in an anecdote which recalled the mill nightmares to many present with the agonized words, "Oh God, what's happened to the concentrate now!" It was an appropriate gesture when he called the names of some of the flotation greats for presentation to the assembly; and many an "artist" there was among them!

Jan 10, 1961

By Chappell BW

A zone of northwest trending dykes extends for over 600 km in the hinterland from Cairns to Mackay. In sate regions the zone is up to 120 km wide. Figure 1 shows their approximate extent, compiled from published regional maps and from specific studies in more limited areas : Palm Islands, Cardwell Ranges, Jourama Falls, Townsville area and Burdekin Delta. The context of the dyke swarm is the Tasman Orogenic Zone, the region of Eastern Australia conprised of Palaeozoic metamorphic, sedimentary, volcanic and plutonic rocks which has experienced a complex history and evolution. In the Whitsunday region, the Tam-an Zone also involves Cretaceous volcanism and plutonism. Geological relationships indicated a wide span of ages for the intrusions in the dyke, swarm zone. They intrude a range of volcanic and sedimentary rocks, and in some areas plutonic rocks. Older dykes, apparently part of the same regional swarm are intruded by sate of the granites.

Jan 1, 1987

By T. W. Healy, P. Somasundaran, K. Ananthpadmanabhan

Hydrolyzable surfactants such as fatty acids and amines undergo, in addition to micellisation and precipitation, various associative interactions in aqueous solutions to form ionomolecular complexes such as acid-soap, dimers, etc., depending upon the solution conditions such as pH. The interaction of these collector species with the mineral surface and with other dissolved species in solution will play a significant role in determining the interfacial processes such as adsorption and flotation. Marked differences in the hydrophobicity imparted to the mineral surface depending upon the solution conditions such as pH can be attributed to possible differences in surface activities of the foregoing complexes. This aspect of solution chemistry of flotation system is discussed here for two widely used collectors, namely, oleic acid and dodecylamine. Equilibrium species distribution diagrams, based on the available literature data and on estimates of energy of interactions between molecules, have been obtained for oleic acid and dodecylamine solutions.

Jan 1, 1980

By W. C. Lacy

A WIDE variety of metalliferous deposits in Peru shows a close and consistent relationship to intrusive and extrusive igneous rdcks. This relationship furnishes a clue to the comp(osition of ore-bearing fluids and to the timing in separation of these fluids from differentiation magma Conclusions presented here are based on ten years' study of a large number of metalliferous deposits in Peru. The most important of these areas are shown in Fig. 1. The structural relationship of meta1 mineralization to the intrusive series and of the members of the series to each other can be illustrated by three examples: I The well described Cerro de Pasco (Ref. 1, p. 160) sulfide mass shown in Fig. 2 is localized along the ' eastern contact of an agglomerate-filled crater. Quartz-monzonite porphyry and related intrusive breccias, which in places border the pyrite mass On west, are replaced by the pyrite and cut by later transverse vein structures. Late unmineralized but

Jan 1, 1958

By Edward W. Parker

If one is to place any credence at all in the reports published in the daily press, the subject of conservation has been a very lively topic of conversation during the past 60 days, and it does not appear that the temperature of the summer months has been in any way moderated by the discussion. It is a subject in which we are all vitally interested and to which, so far as our mineral resources are concerned, both the Institute and the Geological Survey have liberally contributed. The report of the National Conservation Commission, appointed by President Roosevelt, contains a series of papers on the conservation of mineral resources, all of which were prepared by members of the Geological Survey and were compiled largely from information previously collected by that Federal bureau in the performance of its regular duties. It is not the purpose of this paper to reiterate in extenso any of the material already published. The contributions of the Survey offcials to the Corn-

Jan 1, 1910