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By Rolf B. Pedersen, Ingunn H. Thorseth, Håkon Dahle, Ingeborg E. Øklandm, Linn M. B. Olsen

Weathering of sulfides and the generation of acid mine drainage (AMD) is a well- known environmental issue in on-land mining. The process can release potentially toxic compounds and heavy metals to the environment and is highly influenced by microbial activity. However, the weathering of sulfides in deep-sea environments is not well studied. In 2014 we therefore deployed two titanium incubators filled with freshly ground pyrite grains into an inactive part of the hydrothermal sulfide mound of Loki´s Castle vent field, aiming to study the in-situ seafloor weathering of the freshly exposed sulfides. Each incubator had five chambers placed in a depth profile, where the upper chamber was exposed to the bottom seawater. After one year of exposure, one incubator was collected and analyzed for weathering features and microbial colonization and community composition. In addition, one sediment core (25 cm deep) was collected from the sulfide mound in close vicinity to the incubators, and another core (45 cm deep) was collected from the (hemi)pelagic sediment just outside the sulfide mound. The cores were analyzed for geochemical composition of the solid material and porewater, and the microbial community composition aiming to define the redox zoning and dominating geomicrobiological processes in the natural deposits, and to unravel how these processes influence the mobility of heavy metals during sulfide weathering. Scanning electron microscopy (SEM) revealed development of Fe-oxyhydroxide weathering rims on the pyrite grains in the incubator chambers. Spalling of the rims on the most weathered grains, exposing fresh pyrite surfaces to oxidation, was commonly observed. The SEM investigation also revealed a positive correlation between weathering degree and microbial community density. Preliminary results from the microbial community analysis show a high relative abundance of putative sulfide oxidizers, suggesting that the community is governing the degradation of pyrite.

Jan 1, 2018

Most publicity about the copper industry nowa- days is focused on the adequacy of ore reserves and on excessive mining capacity. These concerns, stemming from public awareness of actual and poten- tial shortages and oversupplies, relate to production rather than consumption. Perhaps the reason for this one-sided view is that copper is thought of as a commodity which is conspicuously traded in world markets, rather than as one of many industrial materials that serve today's rapidly changing tech- nology. Copper differs from other widely traded com- modities in that its real cost of production has pro- gressively increased since World War II. The reasons for the increase are identifiable by analyzing operations in one of the world's large producing centres, the copper province of Arizona. Another respect in which copper differs from some other com- modities is that increases in demand occur less auto- matically in the case of copper than they tend to in commodities whose consumption is more directly related to population growth. The copper industry's current inability to generate and attract needed investment capital is attributable to these differences between copper and other com- modities; it suggests that the concept of copper purely as a commodity is outdated. The key to the problem is better integration between the activities of copper producers and users. Depending on cir- cumstances, integration takes various forms- for example, investment tied to long-term sales con- tracts between producers in developing countries and consumers overseas; common ownership of pro- ducing and manufacturing facilities in industrialized

Jan 1, 1978

By Hans Lundberg

An electric survey from a 'plane flown over the ground is much faster and cheaper than an electric survey carried out on the ground. The results are obtained as continuous recordings that are resolvable into both a depth expression and a conductivity effect, so that the indications are easier to evaluate, as well as to correlate from one flown line to the other. The prospecting technique adopted in our electric airborne surveys may be brie fly described as follows: A loop of many turns of insulated copper cable is fastened around the fuselage of the 'plane and connected to a generator supplying a few ampere alternating current, usually of a frequency less than 1,000 cycles per second. Just as the current in the primary coil of a common transformer will induce current in the secondary coil when shorted, the alternating magnetic field from this primary current now induces alternating current in electric conductors that happen to be located in the vicinity of the path over which the 'plane is flown. This induced secondary current in each conductive section of the ground causes, in turn, an alternating magnetic field, secondary field, which disturbs or dampens the normal alternating magnetic field from the primary loop flown by the 'plane. These secondary fields are then picked up and recorded by the help of detecting solenoids, amplifiers, and recorders carried in the 'plane. By closer study of such a secondary field it is possible to localize the secondary current causing it and, thereby, the conducting body that contains the secondary current. In the 'plane are continuously recorded, besides the amplitude or intensity of the field, also the phase, which is a measure of how much the recorded secondary field is out of step with the primary field.

Jan 1, 1950

By L. Yuan, J. H. Rowland

"In 1995 and 2003, the U.S. Mine Safety and Health Administration (MSHA) conducted surveys to determine the number of atmospheric monitoring systems (AMS) that were being used in underground coal mines in the United States. The survey reports gave data for the different AMS manufacturers, the different types of equipment monitored, and the different types of gas sensors and their locations. Since the last survey in 2003, MSHA has changed the regulation requirements for early fire detection along belt haulage entries. As of Dec. 31, 2009, point-type heat sensors are prohibited for use for an early fire detection system. Instead, carbon monoxide (CO) sensors are now required. This report presents results from a new survey and examines how the regulation changes have had an impact on the use of CO sensors in underground coal mines in the United States. The locations and parameters monitored by AMS and CO systems are also discussed.IntroductionThe last survey conducted by the U.S. Mine Safety and Health Administration (MSHA) on atmospheric monitoring systems used in underground coal mines in the United States was in 2003 (Francart, 2005). A total of 146 active mines were surveyed. The survey report states that since 1995 there had been a steady increase in the use of atmospheric monitoring systems in underground coal mines as the technology of carbon monoxide (CO) sensors was improved by manufacturers. Atmospheric monitoring systems had become more reliable, and some CO sensors could be purchased with the capability to discriminate between the CO produced by a fire versus CO produced by diesel equipment. This increase in reliability had reduced the number of false alarms and the response time. The faster response time to a developing fire allowed miners to take the necessary action to put out the fire or exit the mine.At the time of the last MSHA survey, some mines still used point-type heat sensors to detect the presence of a fire on conveyor belts. This detection method works by measuring the temperature of the air around the sensor. As a fire starts to develop, smoke and hot gases are produced from the combustion process, and the air is heated up. Once the air and gases reach a designated temperature detected by the point-type heat sensor, a fire alarm signal is generated. Studies have shown that the response times for detecting the presence of a fire using CO sensors are much shorter than when using point-type heat sensors (Conti and Litton, 1995)."

Jan 2, 2018

By W. C. Phalan

"Prewar Conditions:Metallic magnesium may be considered a war metal, but a war metal with a future, so far as the industry in the United States is concerned. Its production in the United States prior to 1915, on a commercial scale, was negligible, but imports prior to that year may be taken as a gaze of the demand for the metal. Unfortunately, magnesium was not listed separately by the Department of Commerce prior to the war, among the importations, but was included with other metals, as follows: ""Barium, calcium, magnesium, sodium, and potassium, and alloys of which said metals are the component materials of chief value."" However, the imports of metals enumerated other than magnesium were probably small, so that the importations under the above caption may be considered chiefly metallic magnesium in one form or another and, therefore, is an approximate gage of the demand for the metal in the United States. These imports were as follows:These figures are so close that they give a good idea of the figures for the respective calendar years.Of this prewar use, it has been estimated that about 85 per cent was used annually and in approximately equal quantities in the production of (1) flash-light powder, (2) fire works, (3) aluminum casting work, and (4) nickel and nickel-copper alleys, such as monel metal, etc. The re¬maining 15 per cent was employed for general uses, such as deoxiding brass and other copper alloys in foundry work, and to a small extent in laboratory and research work."

May 1, 1920

The deep seafloor in Papua New Guinea's proposed Exclusive Economic Zone appears to be a gold-rich province in the same sense as the territory above sea level. Two significant sites with polymetallic massive sulphide deposits forming today are known on neovolcanic ridges in the Manus Basin. Their high precious metal contents have led to renewed interest in the issue of exploiting seafloor mineral deposits. The prospects of finding other, possibly larger deposits in the region appear substantial. This paper reviews current data on seafloor deposits in Papua New Guinea (PNG) and raises some issues relating to future commercial exploration and mining of the sea floor. One of the known PNG deposits could become a prime candidate for the trials needed to develop technology, establish costs, and minimise environmental impact.

Jan 1, 1994

By P. R. Sperry, P. A. Beck, Hsun Hu

As described by means of quantitative pole figures, the inside texture of highly rolled aluminum and copper strips may be approximately described by four equivalent ideal orientations near (123) [121]. If rolled in reversed passes, the surface texture of copper is also near (123) [121], that of aluminum is (100) [011]. The inside texture of highly rolled brass is (110) [112]. The surface texture is the same, if rolled in reversed passes. The surface texture of all three metals is related to the inside texture, but asymmetrical, if rolled without reversal between passes. MANY previous investigations dealing with the subject of the present work were reviewed by Wassermann.1 Barrett,2 Brick,3 and Richards.' The recent introduction of quantitative methods for pole figure determination by Decker, Asp, and Harker,5 Schulz5 and others made it possible to reinvestigate some of the finer points which the earlier more qualitative photographic methods left undecided. The rolling textures of silver and of 70-30 cartridge brass have been quite consistently characterized by the ideal orientation of (110) parallel to the plane of rolling and [112] parallel to the rolling direction. On the other hand, it has been recognized by several investigators that certain other face-centered cubic metals, such as copper and aluminum, developed rolling textures rather different from that of brass. These textures have been variously described by the following ideal orientations, singly or in combinations with each other: (110 [112]: (112) [111]; (135) [335]; (135) [211], etc. The discrepancies usually have been attributed to the lack of sharpness in the textures and to the attendant difficulty of associating "ideal orientations" with pole figures showing great scatter of orientations. It seemed desirable to investigate by the new quantitative methods to what extent the apparent lack of sharpness may have been brought about by the qualitative methods used previously, rather than by the textures themselves, and to decide, if possible. between the various ideal orientations which have been proposed. Another problem, not satisfactorily settled by earlier investigations. concerns surface textures in rolled metals. For instance, in rolled aluminum the surface texture in some cases appeared to be similar to the texture inside the sheet, whereas in other cases it was reported to be entirely different.' The conditions under which such differences may have arisen, and the possibility of the occurrence of different surface textures in other face-centered cubic metals do not appear to have been examined in detail. The present work was undertaken to investigate the above questions. Some of the results obtained have been described- riefly. Experimental Procedure Specimen Preparation: In the present investigation 2s aluminum, electrolytic tough-pitch copper, and commercial 70-30 brass were used. These materials were available in the form of cold-drawn rods. 1 in. diam for tough-pitch copper and commercial 70-30 brass and 11/2 in. diam for 2s aluminum. The cold-drawn bars were alternately annealed and rolled 30 pct lengthwise in several cycles until a penultimate thickness of 0.500 in. was reached. The intermediate and the penultimate anneals were carried out for 30 min at 380°C with 2s aluminum, and for 30 min at 550°C with 70-30 brass. For tough-pitch copper, the intermediate anneals were 30 min

Jan 1, 1953

By G. E. McClelland

Introduction Many discoveries have been made during the-past decade of low grade gold-silver deposits in the western US. This has stimulated development of low cost cyanidation procedures for precious metal extraction. Heap leach cyanidation techniques possess considerable potential for application to these low grade ores, small ore bodies, mine strip waste, and tailing materials where fine grinding is not necessary for good extraction. For heap leaching to be successful, these resources must have good permeability to achieve uniform distribution of the cyanide solution throughout the heaps. Some of the most difficult of the gold and silver ores to treat successfully by heap leaching are those containing excessive amounts of clays, or fines generated by crushing. Presence of excessive amounts of slimes, -50 µm (-270 mesh), in the heap leach feed will slow percolation, cause channeling, or produce dormant or unleached areas within the heap. This may result in unreasonably long leaching periods and poor extractions. In extreme cases, the clays or slimes can completely seal the ore heap. This causes the leach solution to run off the sides of the heap rather than penetrate the ore bed. The problem of heap leaching ores with fines can be aggravated while preparing ore heaps because of the natural sorting of coarse and fine material that occurs. This phenomenon results in concentration or ore fines in the center of individual ore piles and concentration of larger rock fragments of the lower slopes and base of the pile. When the individual piles within the heap are leveled off for the installation of the sprinkling system, additional segregation occurs as the fines sift through the coarser ore particles. This results in localized areas or zones with marked differences in permeability. Consequently, the leach solutions follow the course of least resistance. They percolate down through the coarse ore regions and bypass or barely wet areas that contain large amounts of fines or slimes. Effective use of marginal gold and silver resources by heap leaching required development of new methods to achieve more uniform size distribution when preparing ore heaps and better slime control during leaching. Early methods Agglomeration and balling of crushed ore to produce a porous and more uniform feed material for heap leaching is a viable method for treating clayey ores. Researchers from the US Bureau of Mines in Reno, NV began agglomeration pretreatment research in the mid-1970s for applications to and exploitation of these poor percolating feed materials. Little attention had been given to such methods before the Bureau's research. In 1905, T. C. Scrutton developed a unique technique for obtaining rapid vat leaching of a clayey ore where the gold was finely disseminated. His technique consisted of rolling the ore down a chute inclined at 60° to form agglomerates or balls readily permeable by the cyanide solution. However, these agglomerates lacked rigidity. And, to ensure good percolation leaching and washing, they could not be bedded in layers more than 1 m (3 ft) deep. If this depth was exceeded, it is difficult to obtain uniform leaching and washing. This results in reduced gold recovery. Shepard and others in 1937 studied the addition of lime and carbon dioxide or calcium carbonate to gold-bearing tailings to form agglomerates suitable for vat leaching. Satisfactory percolation flow rates were achieved in 90 g (3 oz) scale experiments, but the reagent requirements were cost prohibitive. Agglomeration and pelletizing has been used in other segments of the mineral industry. This technique was first used successfully around 1911 for pelletizing iron ores. Since then, agglomeration

Jan 7, 1986

By Satoshi Honda, Mitsuru Shimizu, Tatsuji Nagao, Motoaki Kurisu, Hirokazu Izumi, Toshinori Takahashi, Hiroyuki Itoi

"1. INTRODUCTION Grade separation of roads and railway tracks is an effective method for solving traffic-related issues in cities. However, in urban areas where the existing traffic infrastructure is already overcrowded, construction of new roads often faces problems especially in the proximity of existing structures. This paper summarizes the construction plan and results of new road tunnel construction in the proximity of the piers of elevated tracks on the Tokaido Shinkansen railway.2. SUMMARY OF CONSTRUCTION AND ISSUES Auxiliary Route No. 26 as specified in the Tokyo urban plan is a project by the Tokyo Metropolitan Government, covering the construction of a new road with a total length of 22.3 km currently on the way to completion. In Shinagawa Ward, Tokyo, Auxiliary Route No. 26 is designed to cross the railway tracks of the Yokosuka Line and the Tokaido Shinkansen Line, so for this project, the East Japan Railway Company (JR East) was commissioned to design and build a road crossing under the railway tracks (Sumiyoshi Underpass). Figures 1 through 3 show a sketch of the Sumiyoshi Underpass. The Sumiyoshi Underpass was planned as a two-lane tunnel for vehicles, which was to cross under the railway tracks of the Yokosuka Line and the Tokaido Shinkansen Line at an angle of 70 degrees. The structure concerned is a single-story single-span box culvert structure with the following dimensions: 11.5 m wide, 7.7 m high and 31.6 m long. The Tokaido Shinkansen Line tracks were constructed on a girder-type elevated bridge built in the 1960s, and the foundation piles of the piers (P7 and P8) in the proximity of this crossing box culvert of RC structure were constructed using an earth drill method. The crossing structure for this project is located extremely close to the piers of the Tokaido Shinkansen railway tracks, with a minimal separation of 0.4 m, and the most significant issue of this project was construction in a manner that would not obstruct the normal operations of the Tokaido Shinkansen (Figure 4). Initially, we considered installing a temporary earth retaining structure in the proximity of the piers, cutting the ground and building an RC box, but concluded that it would be very difficult to apply this method because of probable excessive displacements in the Shinkansen railway piers. That is why we decided on the use of a non-open cut method in order to minimize the impact on the piers."

Jan 1, 2016

By S. H. Moll, R. E. Ogilvie

The investigation of solid-state diffusion phenomena may lead to much information concerning binary alloys. In particular, a study of the concentration gradients present in multiphase diffusion couples can lead to the determination of the solubility limits of the single-phase fields in the phase diagram. The specific concentration gradient which results from the heat treatment of a diffusion couple depends not only upon the time and temperature of diffusion, but also upon the number of phases existing in equilibrium at the diffusion temperature. Such concentration gradients possess sharp discontinuities whose terminal points correspond to the solubilities existing at the limits of the two-phase field in the phase diagram at the diffusion temperature. In general, there will be a discontinuity in the concentration curve for each two-phase field which exists in the phase diagram between the concentration limits of the couple. A number of investigators have analyzed the gradients present in multiphase diffusion couples. 1-8 The iron-titanium phase diagram exhibits a y loop in the temperature range from 900" to 1400°C, and the limit of the a + y field lies at some composition which is less than 1 wt pct Ti for any temperature. It was felt that a diffusion study could yield values not only for the diffusion coefficients involved, but also for the chemical solubilities in the phase diagram. The concentration gradients were analyzed by an X-ray absorption technique developed by Ogilvie.6 The absorption of a monochromatic X-ray beam is measured in steps parallel to the diffusion direction and the resulting intensity gradients are transformed into concentration gradients by applying the laws of X-ray absorption in a binary system. This technique has been applied by ogilvie6 to the systems Ni-Au, Cu-Au, Fe-Cr, and Ni-Cr; by Gelles7 to the systems Be-Fe, and Be-Ni and by Hilliarde to the system Al-Zn. Linear X-Ray Absorption Analysis—The use of X-ray absorption analysis as a tool for determining concentration gradients arises from the fact that the beam is absorbed according to the quantity and species of elements present in the sample and not according to their state of aggregation. This method is more advantageous than the chemical analysis of machined layers since it is less time consuming and less expensive and can analyze a very small area. IF a homogeneous binary alloy (A + B) is analyzed with two different monochromatic X-ray beams I0(2) and lo(2) the following relation between the transmitted intensities, the intrinsic absorption coefficients of A and B for the two different radiations and the weight fraction of each element may be derived.' In (I/Io) (a+b) xa(u/p)a(2) + xb(u/p)8(2) Eq. [1] is independent of specimen thickness and density, but requires that either element A or B possess an absorption edge between the wavelength limits of the two monochromatic beams. I, is evaluated for each radiation by measuring the transmitted intensity through a varying number of foils of a suitable absorber. A plot of the natural logarithm of the transmitted intensity as a function of the number of foils, when extrapolated to zero foils, yields the value of I,. If a plot of the ratio in Eq. [ I] is calculated as a function of xA, then a master curve results. From

Jan 1, 1960

By R. J. Tailleur, M. Rosenberg

Oil well drilling muds prepared with lubricating aids such as oil, graphite or mica will not produce a sufficiently strong protective lubricant film for the bit bearing surfaces under high load conditions encountered in drilling operations. Consequently, the damage to the bearing surfaces resulting from the absence of such a film frequently results in a shortening of the drill bit life. Several different types of extreme pressure lubricating additives for use in muds have been developed. These arlrlitives are capable of providing a protective lubricating film for bearing surfaces subjected to high load pressures. A modified version of the Timken lubricant tester, an instrument commonly used for testing the extreme pressure lubricating properties of oils, is used for measuring and controlling the lubricating qualities of the mud. Comparison tests made in the laboratory with 55/8-in. tricone bits drilling on steel plates immersed in extreme pressure lubricating muds and conventional muds showed that the bearing life of those bits tested in the lrrbricating mud was three to four times greater than obtained with conventional muds. Drilling tests made with extreme pressure lubricating muds in West Texas increased over-all bit life three to fourfold, reduced drilling torque and wear on drill pipe and drill collars. INTRODUCTION Roller bit cones contain roller, ball and journal-type bearings that are subjected to very heavy loading during drilling operations in which the only lubricant available for these bearings is either water or drilling mud. These bearings must be able to operate satisfac- torily in order for the cutting structures on the surface of the cones to be fully utilized. Frequently, the bearings wear to the point that the cones freeze and the bit must be pulled before the cutting structures on the cones become worn. In some instances the bearings continue to turn with severe wear but the cones, which are held on the bit by the bearings, drop off; and this causes an expensive fishing job. In other instances the bearings wear to the point that the cones pinch in causing an undergauge hole and delays to ream the hole. The advantage of increasing bit bearing life is self-evident. Because of inability to control the internal wear of bits while drilling, it was felt that improvement of the lubricating qualities of the circulating mud would be helpful. However, the often-discussed lubricating property attributed to muds has been a rather vague and intangible one. The literature has implied that the oil-emulsion muds are more effective lubricants than non-emulsion muds. Actually, there has been no direct method of measuring the lubricating property of muds which would indicate that one mud was better than another; there has been no way to determine whether the lubricating property of any mud was adequate. Furthermore, in comparing lubricating properties of muds, two qualities should be considered—the coefficient of friction and the extreme pressure lubricating qualities. For example, graphite can reduce the coefficient of friction, but does not provide a strong enough lubricating film to protect bit bearings subjected to high loads. The primary object of the investigation reported herein was to find a method for prolonging the bearing life of drill bits; and considering the heavy loads used in drilling, it was felt necessary to find both a method of measuring lubricating properties under high load conditions and methods of establishing effective lubrication under these conditions. Extreme pressure lubrication deals with that realm of lubrication where metal surfaces are in rubbing contact with each other under very high pressures. These pressures may be quite high, as for example,

By L. C. IlsLey

"There is an old saying that ""It is too late to lock the stable after the horse is stolen"". Is not this just what is being done by many mine operators today when it comes to buying safe electrical equipment for gaseous and dusty coal mines?The ""open type"" of electrical equipment or even the ""half safe"" type represents the unlocked stable. After the mine disaster, and after men have lost their lives, the lock is put on - that is, safer equipment is installed.For example, an open type of electric coal drill was used in a gaseous mine in West Virginia, This was the probable cause of the death of 27 men. A half safe type of electric coal-cutting machine was used in a gaseous mine in Pennsylvania. This was likely the cause of the death of 36 men. An unapproved, unsafe type of flame safety lamp was used in a gaseous and dusty mine in Utah. This was the all¬eged cause of the death of 171 men. All three disasters happened within the last six months, and seem to have been avoidable if proper equipment had been used.It is understood that more rigid requirements will be enforced in West Virginia. The committee of State mine inspectors made definite recommendation for im¬proving the conditions in the given mine in Pennsylvania. The Industrial Commission of Utah have already issued new orders which will remedy the use of unsafe lamps in that State.These acts and recommendation are all good and will help prevent accidents in those States in the future. Is it not a pity that such recommendations and order were not made a little earlier before the tell of life had been exacted? Is it not a pity that other States will not take these lessons to heart and safeguard their mines before and not after disasters take place?Electric current can cause accidents in five general ways as follows: (1) By shock to persons; (2) by igniting powder; (3) by igniting gas; (4) by igniting coal dust; and (5) by setting fire to inflammable material such as timber and coal. A great many accidents from these causes are preventable if proper care is taken. Most of the accidents caused by sparks and flashes from electrical apparatus would not take place if approved electrical equipment was used. By approved equipment, the writer means equipment that has been tested and formally approved by the Bureau of Mines. So far as known, up to the present time, no disasters have been caused by sparks or flashes from equipment having the Bureau's approval."

Jul 1, 1924

By Richard Curtis

Optimum Colliery is presently experiencing a shortfall of stripping capacity in order to meet its production requirements. Due to the long dragline procurement times, several alternative stripping methods were evaluated in order to alleviate this shortfall in the interim period. Based on the experience gained at the mine. The writer will discuss some of the important factors which influence dragline performance and show how these factors may by used in a theoretical approach to analyse various dragline applications.

Jan 1, 1990

By A. K. Bhasin

The movement of solid particles in a liquid represents an area of interest in many fields of science and technology. Knowledge of the behavior and characteristics of solid-liquid suspensions is of great importance to many areas of mineral processing. In order to characterize a solid-liquid system, the following factors must usually be considered: a) density of the liquid b) rheological properties of the liquid c) density of the solid particle d) size and shape of the solid particle e) volume fraction of solid particles f) relative motion of solid particles and liquid phase Other variables such as the effect of the containing vessel walls, Brownian movement, inter-particle friction, fluid slip and electrostatic effects, are important in special circumstances. Thus it is evident that a complete theoretical treatment is not possible covering all situations. Studies of the kinematic behavior of solid particles in a liquid have been approached by two methods: 1) Assessing the movement of a single particle and extrapolating to a multi-particle system; 2) Modifying the continuum mechanics of single-phase liquids in such a way as to account for the presence of solid particles. The first approach in general utilizes the method of particle mechanics. Extension to a multi-particle system gives rise to very complicated mathematical computation. The creeping motion equations do, however, furnish a practical, useful basis for achieving a uniform treatment and a better understanding of the phenomena. This approach is useful in the study of sedimentation and hindered settling processes.

Jan 1, 1971

By F. Dingwu

The latest technology and novel equipments in kaolin processing industry in China are described in this paper. Some typical experimental results are presented, which include laboratory-, pilot-or commercial-scale tests. The characteristics of kaolin processing technology are summarized, and the developing trends are indicated.

Jan 1, 1995

By G. Sommer, R. P. Chaix, G. T. W. Ormrod

Recent developments in the instrumentation and automation of uranium-processing plants by G. SOMMER, Ing. (Grad.) (Visitor), G. T. W. ORMROD (Visitor), and R. P. CHAIX, B.Sc. (Visitor) The paper discusses work at the National Institute for Metallurgy on the evaluation of measuring techniques for the automatic control of free acid in leaching. of the ratio of ferric to ferrous ion in leaching, of pH in liquid-liquid extraction. and of uranium in loaded solvent. Commercially available instruments. and the modifications that have been made to adapt them to South African uranium plants, are also described.

By Donald W. Ross

"INTRODUCTION Sponge iron has been made commercially since 1912 at a Swedish ceramic plant; and the product, known as Swedish disk—type sagger sponge iron, has an excellent reputation as a superior furnace feed wherever high—grade steels are made. The general procedure for making brickyard sponge iron was described frequently in Swedish technical journals prior to 1932 and at that time consisted in filling clay refractory containers, called saggers, with a super-concentrate of Gellivare magnetite plus the necessary amount of solid reducing agent and desulfurizer and then firing in a Hoffmann ring furnace, as used in the ceramic industry.The early Swedish publications describe two types of brickyard sponge iron: (1) An inferior high-sulfur product obtained by mixing the ore and reducing agent, and (2) a high-grade low-sulfur product in the form of coherent disks 7 to 9 inches in diameter and 1 to 1-1/2 inches thick made by the saggers with alternate layers of solid-fuel reducr and of uniaxed ore."

Sep 1, 1945

By T. L. Joseph, G. Bitsianes

THE layered structure of partially reduced iron ore was described in a previous paper.' Reduction by hydrogen was found to take place at well-defined interfaces between layers of the solid phases. In the present investigation, a detailed study was made of the wiistite phase that had formed during the partial reduction of a cylindrical compact of chemically pure hematite. An unusually wide band of wiistite permitted a rather detailed study of this phase. The specimen was made from Baker's C.P. hematite in the form of a cylinder 1.5 cm in diameter and 1.8 cm long. A dense ore structure with about 6 pct porosity was attained by heating the specimen in air at 1100°C for 3 hr. To confine reduction to the top surface, a ceramic coating was applied to the bottom and sides of the cylindrical compact. The specimen was then partially reduced in hydrogen at 850°C and subjected to a coordinated sequence of macro-, micro-, and X-ray examinations. A section of the partially reduced cylinder is shown in the macrograph, Fig. 1. Four layers consisting of metallic iron, wustite, magnetite, and unreduced hematite are clearly shown. The effort to force reduction to proceed downward in topochemi-cal fashion was only partly successful, as some reduction occurred along one side and bottom of the cylinder. A rather wide layer of dark wustite phase had formed, however, and permitted sampling for X-ray studies as indicated. To supplement previous work and to study the wustite layer in more detail, ten separate layers were removed for X-ray examination. Broad and diffuse patterns were obtained with the as-filed powders, especially with those of iron and wiistite, and the condition indicated a cold-working and variable composition effect within the respective layers. This condition was corrected by annealing the entire series of powders at an appropriate temperature. For the annealing treatment, the ten powder samples were wrapped in silver foil, sealed under vacuum in small quartz tubes, and heated at 750°C for 16 hr. The specimens were then drastically quenched in cold water to preserve the annealed condition. These annealed specimens were X-rayed in turn and the compiled patterns are shown in Fig. 2. The standard patterns for iron and its oxides have been interjected at appropriate positions for purposes of comparison and phase identification. All of the patterns obtained were clearcut and concise so that positive identifications could be made for all of the phases. The outermost layers A, B, and C were composed almost entirely of iron with a small amount of wiistite being detectable at the X-ray limit of phase detection. Layer D from the iron-wustite interface showed both of these phases. The next four layers E, F, G, and H were all in the dark phase band which had been tentatively identified as wustite by the macroexamination, Fig. 1. The diffraction data with their single-phase patterns of wiistite for these layers checked the visual evidence. Continuing the X-ray analyses after layer H, the macrograph (Fig. 1) shows that layer I came largely from the magnetite zone but included some fringes of the wiistite-magnetite interface. The diffraction pattern for the sample confirmed this observation. Layer J came from the unreduced core of the specimen and its diffraction pattern indicated a preponderance of hematite phase. The reduction behavior of synthetic compacts has thus been found to be similar to natural dense iron ore. The previous results were supplemented with measurements of the diffraction films and calculations of the respective unit parameters. These X-ray data are summarized in Table I and offer some interesting correlations as to the compositions of the various phases undergoing reduction. The iron layers that were analyzed gave lattice parameters close to that of pure iron at 2.8664A. Evidently this iron was present in layers A through D as a pure phase with little or no oxygen dissolved in its lattice. With the wiistite layers an entirely different situation prevailed in that there was a definite and

Jan 1, 1955

CARL HENRICH (communication to the Secretary*).-I have read with much interest the discussions of my paper by Messrs. A. S. Dwight, E. P. Mathewson, Win. B. Boggs, Jos. W. Richards, and W. C. Smith. Mr. Dwight's acknowledgment that he always-in lead smelting¬obtained better results by figuring A1203 as an acid in his slags, I may take as a confirmation of my views, notwithstanding his later conversion by, the late T. S. Austin to the latter's empirical view and way of neglecting the consideration of A1203 altogether in the composition of slags-letting the slags "dissolve" in Al203. I have a strong suspicion that Mr. Austin, in a large custom smelting plant at El Paso, has been able to keep the alumina percentage of his slags sufficiently low, not to give him much trouble, although I have also a suspicion that his furnace foreman may have had a somewhat differing opinion of the practical working of the "dissolving" theory,, whenever its applicability was tested to its limits. That Austin should have conceived the notion that the Ca of CaF2 would enter into a slag as CaO, seems hardly in accord with the recognized ability of that late metallurgist. It is a well-recognized fact that even small amounts of CaF2 will reduce the viscosity of a slag; but I did not think anyone ever had an idea that CaF2, in some mysterious way, parted with its F and coupled itself with 0 to satisfy a craving for CaO on the part of 802-least of all in a lead furnace. The "dissolving" theory for CaF2 was doubtless appropriate, and an improvement on figuring the Ca of CaF2 as CaO to satisfy the demand of Si02 for RO bases. However, I cannot understand the rationality of extending this "dissolving" theory to A1203 and to ZnO. It would be interesting to have more specific data from Mr. Mathewson in regard to the actual composition-analyses-of the slags made, when he had these unusually high alumina slags in Colorado. We "old" smelters all know that within certain limits, usually found out by rather tough experience, we could safely "disregard" A1203. In fact, I believe, we never really analyzed for alumina, except in slag analyses, when we

Jan 6, 1917

By Wilford L. Stork

Certain influences of oxygen on iron have been known for many years and it has always been considered one of the worst enemies of the iron and steel founders. Nobody had a good word for it, hence little was done to make use of this oxygen. In all the fields of foundry practice, the desideratum was "melt without oxidation of the metal." In the consideration of the influence of oxygen on cast iron, we must not confuse this condition with oxidized iron caused by poor melting conditions, due to a high bed, heavy charges, low coke ratio, excessive melting rate, high blast, or poor charging. It is admitted that oxygen absorbed by iron melted under these conditions has a deleterious effect on the properties of the iron. The writer has had experience both in the melting under such poor conditions and in remedying these bad conditions and considers the product far inferior to iron melted under normal conditions. As stated by Dr. Richard Moldenke,l such iron has a higher melting point and high combined carbon, is sluggish, and contains slags and oxides in solution in the liquid, causing slag inclusions and gas occlusions, 'thus producing defective castings. This oxidized condition cannot be counteracted or removed by any of the known deoxidizers; it can be remedied only by proper melting conditions. Such iron is redly burned, whereas the iron considered in this paper was melted under normal conditions with moderate blast, correct bed height, light charges of iron, and low coke consumption and is not in this category at all. In 1914, the late J. E. Johnson, Jr., startled the metallurgists of the . world when he published his results on the advantages of oxygen on cast iron.2 His work is so convincing and so logical, in spite of the common and well-established notions on the subject, that nobody has been able to refute a single argument. Such an eminent authority on iron and steel metallurgy as Prof. H. M. Howe has accepted the work in all its details in his latest book.3 The work of J. E. Johnson, Jr., has revolutionized the metallurgy of cast iron and it seems apparent that all future work must include an oxygen determination just as we include silicon, sul-

Jan 1, 1920