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By Lara de Assis Moreira, Vinicius Thiago Lecco Rampinelli

The energy efficiency of reheating furnaces is a continuous challenge, as these equipment consume a representative portion of the total fuel of an integrated steel plant. Therefore, any investigation and implementation which brings improvement in this figure become an important issue for the mill competitiveness. In the case of production delays due to external factors (the condition addressed in this work), whether predicted or unforeseen, the slabs remain inside the furnace with high temperatures in order to avoid production delay during the production restart, elevating the specific consumption and scale formation. This work increased the energy efficiency of the two ArcelorMittal Tubarão’s walking beam reheating furnaces, by reducing the consumption of mixed gas during production delays (either scheduled or not) lasting less than 3 hours. The objectives were achieved through improvements, among them, tuning of Level 2 automation system parameters, automatization of procedures and operational training. The work resulted in a 34.4% fuel gas consumption reduction during the delays.

Oct 1, 2019

By H. N. Hickey

Wildcat drilling operations in Montana during 1933 did not yield any discoveries of oil or gas that were of major importance. There was comparatively little drilling in the older proven fields, as most of the interest was centered in the Cut Bank field, where 44 wells were completed. The total number of wells completed in the state during the year was 79, of which 62 were productive of either oil or gas.

Jan 1, 1934

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By John Hoelle

Coal mines in southern West Virginia, south-western Virginia and eastern Kentucky have experienced coal bumps at least since 1933. Most of the bumps have occurred due to high cover, strong roof and floor strata and stress concentrations due to the mining sequence. A longwall mine in eastern Kentucky first experienced coal bumps on the tailgate side of the longwall face in 1989. The bumps continued until 1996. The bumps were the result of: Thick overburden up to 2200 feet Strong roof and floor (strata strengths up to 25,600 psi UCS and elasticity modulus up to 4,800,000 psi Previous over-mining in places Sandstone channels Not all characteristics occurred simultaneously. The bumps produced seismic events recorded up to 4.3 (Richter scale magnitude), and damaged pillars that were up to 147 by 152 feet in size.

Jan 1, 2008

By Richard E. Ellwanger

Methods of utilizing flocculants as settling and filter aids for mineral processing slurries are reviewed. Broad chemical classifications and techniques for proper dilution, multiple addition, and combination treatments are discussed. A variety of custom built and commercially available systems for make up and delivery of flocculants to the application points are in use through- out the mining industry. Those concepts which, in the author's opinion, are particularly important to the successful make up and use of flocculants are presented in relationship to the available make up and feed systems. Actual industrial applications are included in the presentation.

Jan 1, 1980

By Jack A. Kanz, Samuel R. Shortes, E. C. Wurst

Zinc diffusion into GaAs from the vapor phase through reactively sputtered SiO, films Izas been inrestigated for various zinc pressures at 1000"C. Diffusions were carried out in evacuated quartz ampules with elemental zinc and with various Zn-Ga alloys. Sputtered films have proved effective in lowering surface concentrations and preventing surface deterioration during diffusion. Approxin.ate complenzentary error-function impurity distributions were found when surface concentrations were reduced to approximately 3 -—4 x 10" atoms cm'3 or less with dilute zinc sources or by diffusion through SiO, films. Zinc difhsions in GaAs tlzrough SiO, films produced more planar diffusion fronts than were observed with uncoated zuafers under identical conditions. A) Surface Deterioration During Diffusion. Device technolorn-- in compound semiconductors has been hampered by several difficult problems not normally encountered with silicon and germanium. 111-V and 11-VI compound semiconductors generally have volatile constituents at temperatures used for diffusion. To achieve specific junction depths in reasonable lengths of time, or to obtain particular impurity distributions and doping levels, it is often necessary to use temperatures which cause surface deterioration and erosion of the wafer. The resultant surfaces are generally unsuitable for devices. The type and extent of surface damage depends to varying degrees on the particular environment of diffusion and on the particular impurity in question. The most common type of deterioration results from simple dissociation of the gallium and the arsenic during diffusin.' The deterioration process is significantly enhanced by thermal gradients in the diffusion zone, usually resulting in vapor transport and condensation at the cooler portion of the system. The resulting damage sometimes appears as a general haziness over the surface or an array of pyramidal etch pits characteristic of the particular orientation. Occasionally, erosion of the surface occurs uniformly over the wafer so that surface loss is not readily apparent. Workers in GaAs usually resort to the sealed-ampule type of diffusion system3"5 rather than the more conventional open system used for silicon and germanium. Another type of deterioration results from direct interaction of the impurity with the surface. The form of deterioration may vary from surface alloying, as in the case of zinc, to direct chemical attack and vapor transport of the reaction products, as in the case of sulfur. Surface alloying with zinc occurs at higher temperatures and source vapor pressures.4 The process is largely controlled by the amount of free gallium on the surface of the wafer in equilibrium with the arsenic lost to the system. The group-VI elements, sulfur, selenium, and tellurium, are commonly used donor impurities for gallium arsenide. These elements are characterized by high vapor pressures and high chemical

Jan 1, 1964

By J. M. Mwase

The platinum group metal (PGM) industry is currently reliant on the crush-mill-float-smelt-refine route to process PGM ores. However, there are many instances where this route would not be feasible. An alternative process route has been developed which involves heap bioleaching to extract base metals followed by heap reclamation and a water wash step, leading into heap cyanide leaching to extract precious metals. This process was evaluated through test work on samples of Platreef ore using laboratory scale columns. After 304 days 75% Ni and 93% Cu were extracted in the bioleach experiment at 65°C, and after 60 days 58% Pt, 99% Pd and 90% Au in the follow-up cyanide leach experiment at 50°C. A preliminary process flow sheet has been developed around this. Analysis via a mineral liberation analyser showed that the remaining Pt was in the form of the mineral sperrylite, which appeared to be slow leaching in cyanide in comparison to the other mineral types. Analysis of cyanide effluent solution showed high levels of thiocyanate, which present an environmental risk for disposal and high consumption of cyanide. Further studies to develop the process for commercial application in the South African PGM industry are outlined.

Jan 1, 2014

By P. Chris Pistorius, Johannes Sono, Rossouw Sono, J. J. Kobus

Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. These differences were highlighted when a plant which processes titaniferous magnetite had to change to different coal types after decades of operation. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. Direct reduction was evaluated by isothermal experiments using a packed bed of ore and coal, measuring the off-gas composition to determine reaction rates and departure from equilibrium. These indicated reduction to be under mixed control, and quite sensitive to temperature (confirming that the coal reactivity is of importance). An aspect of electrical smelting was assessed by determining dissolution rates of the coal in molten iron at 1550°C. Dissolution rates did correlate with differences in coal structure, as determined by X-ray diffraction, with the more ordered ("more crystalline") coal dissolving faster. The conclusion is that the coal which is more reactive during direct reduction is less reactive during dissolution. However, it is concluded that controlling the temperature during direct reduction offers a feasible method to reconcile the two process steps.

Jan 1, 2003

By Wenbing Guo

Strip pillar mining method is one of the most important techniques for mining subsidence control in China. Mining depth is one of the most important factors that affect subsidence in strip pillar mining method. Six numerical simulation models were set up in this paper to simulate surface subsidence of strip pillar mining at different mining depths. The mining depth in these models ranged from 300 to 800 m. The simulated results were compared and analyzed. The results showed that the subsidence factor of strip pillar mining is related to mining depth. While other things being equal, the subsidence factor of strip pillar mining increases logarithmically with increase in mining depth. Their quantitative relationship was established based on the simulated results.

Jan 1, 2007

By L. L. Chasko

A mine fire is one of the most challenging safety issues facing a mine operator and can occur at any location underground. The National Institute for Occupational Safety and Health (NIOSH) and the Twentymile Coal Mine, Colorado, conducted in-mine experiments to determine the capability of high-expansion foam for addressing underground fires. The tests were conducted in sloping entries with high-capacity diesel-powered foam generators. The following results were observed: a well-designed, maintained, and properly operated high-expansion foam generator can propagate a foam plug hundreds of feet in steep upward sloping (20 pct) multiple entries against a ventilation pressure; stoppings and partitions designed to contain the foam plug in upward sloping entries must be substantially constructed; and the predicted quantity of foam concentrate can be significantly less than the actual amount used due to foam losses, such as bubble breakage on dry surfaces. This paper describes the production of high-expansion firefighting foam and discusses the in-mine experimental tests and results. DISCLAIMER: The findings and conclusions in this report are those of the author(s) and do not necessarily represent the views of the National Institute for Occupational Safety and Health.

Jan 1, 2009

By R. M. Waterstrat, B. N. Das, Paul A. Beck

The central region of the Ti-Mn system was studied by means of x-ray diffraction and metallography. The following intermediate phases were found: an MgZn2-type Laves phase having a wide range of homogeneity, the p-phase of unknozvn structure, and the + -phase with a large tetragonal unit cell, stable at 930°C and lower temperatuves. MaYKUTH, Ogden, and jaffee1 determined the soh-inh bility limits of manganese in and titanium. They also confirmed the structure of the intermediate phase TiMn2 which was previously identified as a Laves phase of the MgZn2 type.2 In the equiatomic region they found an additional intermediate phase, y, which presumably formed by a peritectic reaction at approximately 1200°C. This last observation was disputed by Rostoker, Elliott, and McPhers0n,3 who reported the formation of TiMn by a peritectoid reaction between 900" and 1000° C, but found no evidence of any intermediate phase other than the Laves phase at higher temperatures. Elliott and Rostoker4 reported furthermore that the X-ray diffraction pattern of TiMn could be identified as that of a o phase, although their data were not consistent with this inter~retation. Margolin and Ence6 presented X-ray diffraction data for the and TiMn, phases, and obtained metallographic indications for the existence of additional intermediate phases. They concluded from metallographic observations that two Laves phases are formed, separated by another phase, designated as &. A phase diagram for the Mn-Ti system has recently been published by Savitskii and Kopetskii,' which shows considerable disagreement with the work of Hellawell and Hume-Rothery,' in particular with regard to the terminal solid solutions based on the allotropes of manganese. The present investigation was undertaken primarily to clarify the phase relationships in the equiatomic region of the Ti-Mn system. The metals used in preparing the alloy specimens Were iodide titanium and electrolytic manganese, the latter having a nominal purity of approximately 99.9 pet. The electrolytic manganese was covered with a thick coating of a brown manganese oxide which was reduced by heating the manganese flakes for several hours at a temperature of 1100°C in an atmosphere of dry hydrogen. Three alloys, see Table I, were made using sponge titanium and manganese not treated in hydrogen. The alloys were prepared by arc-melting in an atmosphere of helium or argon. The composition of each alloy was calculated by assuming that the entire weight loss during melting was due to evaporation of manganese. Subsequent chemical analysis of certain alloys indicated that the compositions calculated in this manner were usually correct within 1.4 pct, as shown in Table I. All alloy specimens were wrapped in molybdenum foil before sealing them in silica tubes containing argon at a pressure of 1 atm at the annealing temperature. After quenching in cold water, the alloy specimens were bright and clean, with no evidence of any surface reaction. The alloys listed in Table I were examined metallographically, using an etchant consisting of 20 pet HNO3, 20 pet HF, and 60 pet Glycerine. powder for X-ray diffraction examination was prepared by crushing a portion of each annealed alloy

Jan 1, 1962

By S. J. Rothman, L. T. Lloyd

S. J. Rothman and L. T. Lloyd (Argonne National Laboratory)— Hagel's paperz0 discusses the question of the mechanism for self-diffusion in bcc transition metals. Recent work21"23 has led us to agree with him in reabandoning the ring mechanism in favor of a defect mechanism, most likely vacancies. On the other hand, we think that Hagel's attempt to group together all self-diffusion in bcc transition metals is wrong. We prefer the scheme of Peart, Graham, and omlin," who separate them into two groups. One group contains the anomalously behaved metals P titanium,', y uranium, and perhaps zirconim.' The other group contains a iron," this alloy was held at 1800°C for 2 hr before quenching, its structure was all a. B. C. Giessen, I. Rump, and N. J. Grant (Authors' reply)—We very much appreciate the discussion by Deardorff and Kato regarding the a to /3 transformation temperature of hafnium. In the W-Hf program, as well as in a current study of the system Cr-Hf, standard precautions were exercised against contamination, including vacua of less than 10"5 mm Hg and a weight control check of all specimens to insure an impurity rise of less than 100 ppm. Following receipt of the above discussion, a revision was made in the annealing process. Arc-cast specimens were etched with a 10 pct HF-90 pct HNO solution until 1 mm of surface, including a possible oxide film, was removed. Annealing was done in a hafnium container which provided a long diffusion path for gaseous contaminants. Finally, the heat treating time was shortened. Structural changes were noted to occur quite slowly. A 99.5 at. pct Hf alloy showed 70 pct /3 after 30 min at 1700°C and was 100 pct /3 after 10 min at 1715°C. After 24 hr at 1740C, the alloy was found to be 10 pct/3. This change is due to contamination; it was estimated that it corresponds to an increase of 60°C in the transformation temperature over a 24 hr period. The corresponding change in 30 rnin would be slight. Using the same hafnium as in the above publication, and three new alloys at 98, 99, and 99.5 at. pct Hf, the transformation temperature was indicated to be 1715" 15°C. Since this hafnium contained 4.4 at. pct Zr, a correction of 40 5C, based on an assumed approximately linear transformation temperature curve, must be made for pure hafnium. This yields a value of 1755 20°C in good agreement with Deardorff and Kato's value. Because the slope of the boundary is small, this permits a good extrapolation, and we regard the W-Hf alloys as well suited to check the Hf transformation temperature. niobirn,'' and molybdenum,22 whose activation energies correlate with the melting temperature and whose Do values follow Zener's predictions.28 We have no quarrel with Hagel's placing chromium into the second group; we disagree with his interpreting our data to make uranium fit into that group. Hagel considers that the measurements of self-diffusion in uranium below about 950°C represent combined volume and grain boundary diffusion. This contention is based on the curvature of the penetration plot for our 891°C run,4 which also has a nearly straight line plot of log c vs x. Hagel has extrapolated these characteristics to our 803.5C run and fitted his Arrhenius plot for self-diffusion in y uranium to our four highest temperature points only. We think this is wrong for the following reasons.

Jan 1, 1963

By H. J. Sandri

In the spring of 1991, Western Aggregates, Inc. began operating the newest expanded shale lightweight aggregate operation in North America. The operation is located in Jefferson County, Colorado, just south of Boulder, at the sight of the former Ideal Basic Industries ("Idealite") lightweight aggregate plant, which was decommissioned in 1975. The "new" facility has been built to principally serve the Denver and Front Range markets, as well as ship products into other locations in Colorado, Wyoming, New Mexico, Kansas and Nebraska. Western Aggregates is a wholly-owned subsidiary of Inco U.S., a subsidiary of Inco Limited of Toronto, Canada. Inco Limited is the free world's largest producer of nickel and is a leading producer of copper, cobalt, gold, silver, and platinum group metals, high nickel and super alloys, and specialized engineered products. Inco is constantly seeking new mining related investments that leverage off its mining and processing skills and that meet corporate fmancial objectives. Construction materials are an area presently being pursued by Inco. The basic 'building blocks' of society, from a construction perspective, are sand and gravel, stone, and aggregates. To the vast majority of people these are natural products that are mined, quarried or dredged, and other than washing, screening and crushing, are generally used in their primary form. While these materials vary from quartzite river rock, to calcified limestone, to hard basalt, they are generally classified as "heavy" aggregates. There are, however, other types of aggregates that do not fall under the "heavy" classification, but are used in general construction activities just the same.

Jan 1, 1992

By C. B. Ndimande, C. Ntsele, M. Lisso, L. Arlow

"In the processing of UG2 platinum ore, stirred milling technologies are dominating regrind applications that require grinding the particles to P80s’ in the region of 45 µm. For this application stirred mills are 30–40% more energy efficient and require a smaller foot print compared to traditional tumbling mills. In this work a study was carried out using a batch pin mill and three scales of Stirred Media Detritors. A laboratory scale pin mill, a pilot scale Stirred Media Detritor with an installed power of 18.5 KW and two industrial scale Stirred Media Detritors in continuous operation, with an installed power of 355 KW and 1,100 KW were used. The industrial scale SMDs were in the secondary grinding section of a mill floatmill float (MF2) UG2 processing plants. The tests were focused on assessing the effect of feed rate and percent solids on power consumption and product fineness at lab scale, floatation response of the SMD product at pilot scale and on an industrial scale, the effect of feed rate on energy consumption and product fineness. The measurements obtained were feed flow rates, mill power and from the samples cut, particle size distribution of both feed and product. Specific energy was observed to increase with increasing percent solids over the 30wt% to 80wt% studied. Floatation response tests of the pilot scale SMD products show improvement in grade. Specific energy and reduction rations are observed to decrease with an increase in feed rate.INTRODUCTIONThe purpose of comminution in most mineral processing applications is to liberate the valuable minerals from gangue so that they can be recovered in subsequent separation stages. Most precious and base metal plants treat low grade fine-grained ores which require a higher degree of size reduction to yield the necessary degree of liberation (Partyka & Yan, 2007). Many authors have shown that the relationship between product size and grinding energy consumption is exponential, the finer the product from the comminution device, the higher the energy consumption (Gao & Weller 1993; Napier-Munn, Morell, Morrison & Kojovic, 1996; Jankovic, Valery & La Rosa, 2003). The suggested reason for this kind of relationship is that smaller particles have fewer flaws and higher strength than larger particles. Particles with fewer flaws and higher strength require higher energy for breakage to occur. One of the challenges most plants face is that of efficient energy utilisation in the liberation of the mineral from these complex ores. Conventional tumbling mills are not energy efficient in fine and ultra-fine grinding applications because some of the energy is spent on moving the charge and does not go directly into breakage. Stirred mills have been found to be about 30% to 40% more efficient and require a smaller foot print compared to traditional tumbling mills for regrind applications that require product size with P80s’ in the sub 45 µm regions (Radziszewski & Allen, 2013). Stirred mills are able to produce fine product because they can achieve a high number of stress events per unit time and volume compared to tumbling mills (Kwade, 1999a). To minimise energy usage without compromising product quality, the mining industry has adopted stirred milling technologies for fine and ultra-fine grinding (Radziszewski & Allen 2014; Kwade, 1999b). The south Africa platinum group metal (PGM) industry alone had over 40 stirred media mills installed by 2011 (Rule, 2011). Of that 40, 13 were in the ultra-fine grinding (UFG) application and the rest in main stream inert grinding (MIG)."

Jan 1, 2016

Face and pillar bursts, bumps and bounces are violent failures that occur in underground coal mines in response to a complicated interplay of face and pillar geometry, seam depth, coal properties and interactions between roof, seam and floor strata. Additional complications arise from the presence of gas, mainly methane, and associated pressure and flow that vary with time and are further influenced by the rate of face advance. Where gas plays a dominant role, the term outburst is often used; where stress concentration is primary, terms such as burst, bump or bounce may be used. Hargraves [1983] presents an often cited review of outburst phenomena with emphasis on Australian conditions. Beamish and Crosdale [1998] indicate outbursts have occurred for over a hundred years and present tabulations of outburst numbers in major coal basins throughout the world. A central consideration is the rate of depressurization that occurs in the course of mining. Outbursts are not limited to coal seams and adjacent strata; they also occur in salt and potash mines [Molinda et al 1988]. Stress concentration and gas pressure act in consort, so the combined action is important to understanding the mechanics of bursts or outbursts and to the development of measures to reduce the associated hazard. Gas flow is a complicated phenomenon associated with diffusion of gas from micro-pores and the flow of gas along cleats. Laboratory measurements indicate both are dependent on stress and pressure [Harpalani and Ouyang 1998]. Moreover, gas permeability in porous media is often many times water permeability [Klinkenberg 1941]. However, there is also evidence that gas and water permeability are similar at elevated stress and follow Darcy?s law [Dabous et al]. Gas flow is also of importance to mine ventilation. Price et al [1973] in cooperation with personnel of the former U.S. Bureau of Mines developed finite difference models to estimate methane emission in mines in the Pocahontas No. 3 and Pittsburg seams using a premining pressure of 4.69 MPa (680 psi) and Darcy's law implying laminar flow. However, the effects of stress were not taken into account. In this regard, mine measurements of permeability are usually based on Darcy?s law [Peide 1990]. Early models of gas flow with stress effects were one-dimensional in space and time (x,t) and were developed with the goal of estimating the gas pressure profile from the face into the seam as time passed [Schlanger and Paterson 1987, Zou and Yu, 1999]. A zone of high permeability adjacent to the mining face was recognized in these early models. Later models based on the popular finite element method allowed two spatial dimensions (x,y) and variation in time (t) and for coal seam heterogeneity [Tang et al, 2002]. Zhu et al [2007] formulated a set of nonlinear equations involving a complicated stress-pressure-permeability relationship for application to coal seam gas flow and concluded the coupling was important but failure of coal should also be considered. Wold et al [2008] used a hybrid finite difference - finite element model interleaved with a reservoir simulation model to study outbursts based on extensive mine and laboratory measurements. An important feature of the modeling was the use of spatially variable material properties and Monte Carlo simulation to obtain quantitative estimates of outburst conditions and probabilities. Connell [2009] used the same reservoir simulation model as Wold but used the popular finite difference code FLAC3D for hydro-mechanical responses to evaluate two permeability relationships, one depending on porosity and the other on stress, and concluded that permeability changes with gas production were more complex than computed by either permeability model. Gadde [2010] in an integrated laboratory and field study of coal pillar strength explored the effect of spatial variability and concluded that design based on average strength was acceptable in some circumstances, although gas pressure was not an issue. Liu et al [2011] also applied a FLAC code to analyze two-dimensional gas flow and deformation of layered but homogeneous strata in a Chinese coal mine using a strain-softening model and concluded that damage and gas pressure were important to strata safety relative to the case without gas.

Feb 27, 2013

By D. S. Cronan

Pitcairn Island, the last remaining British Colony in the Pacific Ocean, falls in the S.E. Pacific. Its location, on top of a hotspot volcano, suggests the presence of submarine hydrothermal deposits in its EEZ. Such environments are known to contain hydrothermal mineral deposits, as in the case of Loihi submarine volcano near Hawaii, and Macdonald and Teahitia-Mehitia seamounts in the South Pacific. The hydrothermal deposits in these areas are formed as a result of the interaction of seawater with hot volcanic rock, producing a hydrothermal fractionation sequence comprising sulphides of Fe, Cu and Zn, oxides and silicates of Fe and oxides of Mn. In 1988, a GLORIA survey from the RRS Charles Darwin confirmed the existence of recent volcanism within the Pitcairn Island EEZ. A later bathymetric and sampling survey by the FS Sonne of the region round Pitcaim Island revealed submarine volcanoes approximately 80 km ESE of the island. Hydrothermal mineral deposits were recovered from them, and comprise finely laminated crusts of Fe oxides containing up to 50% Fe, and laminated hydrothermal Mn crusts up to 5 cm thick. Both morphologically and chemically the latter are similar to those from mid-ocean ridge and island arc settings, containing up to 50% Mn, associated with sulphides, and represent first discovery of such deposits associated with mid-plate "hotspot" volcanoes. Massive sulphide deposits are thought to occur within the volcanic pile.

Jan 1, 1992

By G. Harper

The Windy Craggy polymetallic massive sulphide deposit is located in the extreme northwest corner of British Columbia 40 miles west of the Haines Highway, 90 miles northwest of the port of Haines Alaska. The physical setting is mountainous country but with few peaks rising above 2,000 metres elevation, in contrast to the spectacular mountainous terrain to the north and south in Kluane and Glacier Bay Parks respectively. Valleys are classically U-shaped with incised V-shaped bottoms. The upper portions are still occupied by glaciers, which in the Windy Craggy area are documented as retreating at a rapid rate -in the case of the Tats Glacier of the order of 1% of its mass per year. The outcrops around Windy Craggy show a north-easterly dipping sequence of Mesozoic limey sediments and volcanics being the western limb of a north northwesterly trending syncline. Northeasterly cross folding provides a few complications. The flanks of the syncline have been buttressed by intrusive bodies of granitic affinity.

Jan 1, 1991

By Jose Carlos D'Abreu, Edelink Efrain Tinoco Falero, Mauricio Marcos Otaviano

The production and consumption of Direct Reduced Iron (DRI) are continuously increasing, as a consequence of the impact of shale gas extraction technology on the Natural Gas (NG) market. Considering this context, DRI may improve the Blast Furnace (BF), Electric arc Furnace (EAF) and LD converter ’s productivities and consequently their competitiveness. In this work the results of a cooperative research conducted by PUC-Rio University and a Brazilian mining company are presented. Laboratory-scale simulation tests, using DR commercial pellets and typical industrial operational parameters of a benchmarked DR shaft furnace, were conducted and planned using statistical and factorial analysis. In the simulated experiments, the following three regions of the DR shaft furnace were considered: Reduction Zone (RZ), Transition Zone (TZ) and Cooling Zone (CZ). Three stages were considered in the research development: (i) the reactions and equations concerning pellet metallization and Carbon precipitation were analyzed; (ii) experiments focused on the de finition of the carburization kinetic equations occurring in the Transition and Cooling zones, and finally, (iii) aimed to develop the “METCARB” model, a computational program conceived to simulate mathe- matically the metallization and carbonization reactions along the height of the furnace. In conclusion, a comparison is made with industrial results in order to validate the resulting “METCARB” model.

Mar 1, 2018

By L Sandery, S Light

Within 22 months of commencing decline development, the Prominent Hill Ankata Underground Project achieved its full production rate of 1.2 Mt/a.In 2010 construction of the Ankata Underground Project was approved. Decline development commenced in November 2010 and the turnout for the first sublevel was reached by August 2011. The first stoping ore was produced in the first quarter of 2012 and production was successfully ramped up to full production during the third quarter of 2012.Diamond drilling commenced in October 2011 and was conducted concurrently with the underground development. This presented challenges as mining and production targets had to be balanced with underground exploration activities. To achieve production on schedule, without adversely affecting the diamond drilling program and future development, meticulous and adaptive planning techniques were required. This included involvement from engineers, geologists, underground operators and underground diamond drillers.The granularity of these planning techniques allowed the management and prioritisation of development and diamond drilling down to an almost hourly basis. A constant flow of information from drill assay results was fed back into the planning systems. This resulted in a constantly evolving mine plan as the orebody was further refined. High priority areas were identified and targeted to allow continued development and a successful rapid ramp up to full production.CITATION:Sandery, L and Light, S, 2014. Managing the diamond drilling interactions in commissioning the Ankata underground mine, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 75–80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By M. I. Sherman, J. D. H. Strickland

USE of a hydrometallurgical approach to the oxidation of sulfide ores and extraction of metals therefrom may have advantages over the more common smelting techniques when a low grade deposit is difficult to concentrate or the subsequent separation of metals, coexisting in the ore, is laborious by any known smelting operation. For economic reasons, the most promising oxidants are either atmospheric oxygen or electric power. The use of oxygen, or air under pressure, has recently been revised. Pyrrhotite has been converted to iron oxide and elementary sulfur' and a variety of sulfides have been treated by Forward and co-workers.2-4 Generally sulfate is the end form of the sulfur but with galena in an acid medium, elementary sulfur can be formed." For economic reasons chlorine and ferric iron salts are about the only possible alternatives to the atmosphere as oxidizing agents for base metal sulfides. If aqueous solutions of chlorine or ferric iron are employed, the reduction products can be oxidized electrolytically in situ and used again, thus acting as catalysts for electric power as oxidant. The use of ferric salts for this purpose is established hydrometallurgical practicea but, although chlorine gas has been employed in the dry state at an elevated temperature, its use in aqueous solution at or near room temperature has not found favor. The reaction of chlorine water with the soluble sulfide ion has been studied by several workers,7-9 and both sulfate and elemental sulfur are found as end products, the latter being favored by the presence of a low concentration of oxidant relative to that of sulfide in solutions of about pH 9 to 10. Of direct bearing on the work in hand are an early American patent" and a recent Austrian patent." The former advocates stirring powdered ore with an aqueous solution of ferric chloride chlorine oxides and chlorine. In the latter it is claimed that both metal and sulfur can be obtained by electrolysis, in a diaphragm cell, of a metal ore slurry in brine. Details in these patents are scant and no data or explanation is given for the mechanism of the reaction which, in the Austrian work, is attributed to the (unlikely) action of nascent chlorine at the anode surface. No mention is made of possible differences in behaviour between various ores. Apparatus A complication encountered when working with chlorine water is that a serious loss of chlorine occurs by gas partitioning unless an enclosed system is used and any air space in the apparatus is kept very small and constant. Arrangements were made, therefore, to take out samples for analysis without letting air into the system to replace the liquid removed. For convenience in studying a heterogeneous reaction the apparatus was so designed that a reproducible controlled stirring rate could be maintained and the ratio of surface area of ore to volume of solution was approximately constant throughout any experiment. The apparatus used is shown in Fig. 1. The ground ore was placed in the horizontal cylindrical vessel, A, of about 1 liter capacity, heated by a constant temperature circulating bath pumping water through the concentric jacket, B. By adding chro-mate to this water, an ultraviolet radiation filter effectively surrounded the reaction vessel, greatly reducing any possible photochemical decomposition of chlorine solutions. Stirring was effected by glass paddles, C, attached by an axle to a magnet which was rotated by another powerful Alnico magnet, D, outside the glass end, this magnet being itself rotated by an electric motor electronically controlled to constant speed. Speed could be varied from about 150 to 900 rpm and was measured and held to within 1 pct of a given value. The end of the reaction vessel remote from the stirring magnet was closed by another one-ended glass cylinder, E, connected by thin polyethylene bellows, F, clamped by screw clamps and watertight rubber gaskets to the main vessel. Through E, a glass electrode and calomel electrode projected into the solution and a hypodermic syringe pierced a small bung and allowed acid or alkaline to be added to maintain a constant pH. By pushing the fully extended bellows until the two cylinders touched, from 50 to 100 ml of solution could be forced out through a sintered disk into the three-way tap system, G, either to waste (for flushing purposes) or up into a 10 ml burette where the solution could subsequently be measured out for analysis. The ore samples were introduced at H, the tube being stoppered by a thermometer of —1 to +52ºC range, graduated to 0.1°C intervals. To prevent ore from being ground in the end bearings of the stirrer these bearings were pro-

Jan 1, 1958