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By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By Zhou Jun

Water-quenched samples were taken from a commercial flash furnace at three levels along its reaction shaft during operation at high feed rate. The samples were subjected to a series of analysis and observation. Such processes of the feed in reaction shaft as oxidation, desulfurization, melting, slag and matte formation and etc., variations of particle size along axial and radical direction of the shaft are investigated. The following smelting mechanism in reaction shaft named as “Multi-particle and multi-phase fusion model” is proposed: (1) Fragmentation and collision of concentrate particles take place simultaneously in reaction shaft with particle size growing up. Collision produces large-size “unit melt” which falls into the reaction layer in the settler bath. (2) In the settler reaction layer below the shaft, weak bath smelting reactions take place among the shaft products, producing final matte and slag which separate into two layers. (3) The processes in the shaft are all progressive along the whole height of the shaft. The predominant reaction in the shaft is oxidation, not reduction.

By E. A. von Hahn, T. R. lngraham

The rates of cementation of pd11 on electropolislzed copper cylinders were studied in aqueous perchloric acid solutions at pdII concentrations from 0.02 to 0.1 mM. The cylinders were rotated at various high speeds to reduce the diffusion layer to a minimum thickness. In 0.1 M HClO4 solutions, the cemented palladium is dense, adherent, and shiny. The rate data indicate that there are two stages in the deposition. In the initial stage, the rate of cementation is first order with respect to the pd11 concentration. The second stage is much slower. The first stage is consistent with rate control by the diffusion of pd11 ions to the copper surface, and/or chemical reaction at the surface, and the second stage is consistent with rate control by the diffusion of copper ions from the cop-per surface through the deposit of cemented palladium, out to the main body of solution. In 0.001 M HClO4 solution, only the first stage is evident and the rate is more rapid than at higher acidities. This rate enhancement is attributed to PdOH+ ions that predominate at low acidity and aye more reactive than unhydrolyzed pdII. The deposit is porous and loose. All of the cemented deposits are Pd-Cu alloys rather than pure palladium. Activation energies are 9.5 kcal per mole in 0.1 M HClO4 and 7.4 kcal per mole in 0.001 M HClO4. CEMENTATION or displacement reactions occur between aqueous solutions of metal salts and immersed metals according to the general equation: where M1 is electrochemically the more noble metal. Although these reactions find considerable application in metals recovery processes (e.g., the cementation of copper192 or gold3), in electrorefining processes (e.g., solution purification before electrolysis4,5), and in plating and metal finishing processes,6 few studies have been made of the kinetics of such reactions.7-9 The rates of cementation reactions will depend on one or more of the following factors: a) chemical reactions at the metal-solution interface; b) ionic transport to or away from the interface;'-' and c) the character and adherence of the cemented deposit on the substrate metal,6a,10 because the deposit will inhibit the rate of transport of dissolving ions (M2m+) into the solution. In this investigation, the kinetics of the early stages of cementation were studied to obtain an understanding of the reaction mechanism under conditions in which the deposit was sufficiently thin that its inhibiting effect could be disregarded. To achieve this, very dilute solutions in Mn+ were used. Cementation rates are often fast in the initial stages and transport-contr01led.9 To find conditions under which transport control would shift to chemical control, very high stirring velocities were used to minimize the diffusion-layer thickness. Of the many possible cementation reaction systems, the palladous perchlorate-copper system was chosen for this investigation because it was believed to involve simple ion-for-ion exchange. In addition, there are no interfering side reactions, such as the reduction of hydrogen ions, and anion effects are usually absent in perchlorate solutions. EXPERIMENTAL Materials. Reagent-grade chemicals and redistilled water were used in all experiments. Palladous perchlorate stock solutions (0.02 M) were prepared by dissolving 99.5 pct Pd sponge (Johnson Matthey and Mallory Ltd.) in concentrated nitric acid, adding concentrated perchloric acid, evaporating twice slowly (to prevent PdO precipitation) to a small volume, and diluting in a volumetric flask. To prevent gradual hydrolysis of PdII, the stock solutions were made 0.4 M in HC104. Tests for pdIV (Ref. 11) and C1- were negative. Copper strips were cut accurately from 0.025-in. electrolytic tough pitch sheet, Sample 1 (Mines Branch stock or Canadian Copper Refineries Ltd., Montreal), or from oxygen-free, high-conductivity sheet, Sample 2 (American Metal Climax O.F.H.C. brand, sold by Utility Brass and Copper Corp., Brooklyn). The strips were annealed for 1 hr at 335°C in a stream of purified nitrogen (Union Carbide, Linde Division) which had

Jan 1, 1967

By Kenneth Gavin

The accurate prediction of the shaft capacity of drives piles in sand continues to present problems for foundation designers. Research in this field has been carried out for many years and has yielded a wide range of design approaches -some of which have been shown by recent experimental work to be based on questionable assumptions. This Paper reviews some of the current popular design methods for piles in sand in the context of recent information obtained from high quality field tests conducted by institutions such as Imperial College London. A database of driven piles in cohesionless soils has been compiled from well documented (and reliable) case histories that have been reported in the literature. The measured shaft capacities of the piles in this database are compared with predictions made by the various methods and an assessment is made of the predictive performance and reliability of each method

Jan 1, 1996

By H. P. Reid

Portland cement is manufactured under either of two general processes, the wet or the dry. The raw materials in general consist of limestone, shells, marl, cement rock, clay, shale, blast-furnace slag, etc., so proportioned that when calcined the desired composition will be obtained. In the wet process the combined raw materials are ground to extreme fineness in the presence of water, to a resulting slurry of from 30 to 50 per cent moisture content. The moisture of the slurry may be reduced by thickening or filtering processes for feed to the cement kiln or the slurry may be fed to the kiln with its full percentage of water. The dry process differs from the wet in that the surface moisture of the raw materials is removed prior to grinding. For the drying of these materials heat is required and in most cases is produced by burning of raw fuel either on grates or stokers before the dryers or in suspension in the form of pulverized coal, oil or gaseous fuel. The power required for making the cement is sometimes purchased from outside sources; sometimes it is generated from the heat in the waste gases leaving the cement kilns, or generated at the plants direct from raw fuel. We have, then, as the possible requirements of fuel in the cement industry: (1) fuel for power generation, (2) fuel for drying raw materials, including coal before pulverizing, and (3) fuel for burning the raw materials to cement clinker. There is no essential difference in quality required in fuel for burning the materials by the wet and,dry processes. Fuel fob Power Generation As there is nothing peculiar to steam generation in a cement mill power plant as compared with other power plants this use classification of such fuel will be found in other reports of the Technical Committee. Fuel for Drying Raw Materials and Coal Any fuels capable of producing moderate temperature gases may be used for drying raw materials. There is no problem of material contamination from fuels at this part of the cement manufacture to be guarded against.

Jan 1, 1932

By Nelson W. Taylor

With the extensive deposits of potash minerals which have been discovered in the southwestern states, and their rapid development, a permanent American supply of potassium compounds is now assured. The 325-year history of the potash industry in this country has been told by H. I. Smith1, of the U.S. Geological Survey, and the more recent activities of the Survey and of American potash companies were described last year by the same author2. In fact, it may be stated that so great is the productive capacity that two mines in New Mexico and one in California are able to supply more than half a million tons of crude and refined salts over and above that produced for agricultural purposes. The era of scarcity has given way to an era of superabundance. This situatiori makes it desirable for the potash producer to look for other applications for his product, and it is with this in mind that the writer presents some information pertaining to present and possible future uses for potassium compounds in the ceramic industry. Ceramic Products Ceramic products are essentially solid materials containing one or more oxides such as SiO2, Al2O3, CaO, MgO, FeO, K2O, Na2O, TiO2, which are the oxides of greatest abundance in the earth's crust. The typical ceramic process is that of firing or burning the batch, and the product may be glassy, crystalline or mixed. In the glassy or vitreous group come glass, porcelain enamel and glazes; in the crystalline group, refractory materials such as silica brick, or chromite or magnesia; and in the mixed group, porcelain, chinaware, stoneware, tile, brick, etc., which contain both a vitreous and a crystalline phase, in variable proportions. The ceramic industry of the United States is a billion dollar industry, and is important not only because of its magnitude but also because of the key position occupied by certain ceramic products in the whole manufacturing structure. From the standpoint of use of potash, the field of refractories is of no great interest, since K2O lowers the melting point of a refractory oxide and

Jan 1, 1938

By T. Sterry Hunt

I have in a previous communication called the attention of the Institute to the geognostical relations of the crystalline iron ores belonging to the Eozoic racks of North America, at which time I noticed (1) those associated with the gneisses of the Laurentian series, (2) those of the crystalline schists of the Huronian, as seen in Northern Michigan and in many localities along the Appalachians; (3) those of Southeastern Missouri associated with petrosilex porphyries and schistose rocks, and presumed to be nearly of the same age with those of the Huronian schists; and (4) the highly titaniferous ores of the Norian or Labradorian series from Essex County, N. Y., and from various parts of Canada. It may here be remarked that, although the presence of titanium is most marked in the Norian ores, this objectionable element is sometimes found in the schistose ores of the Huronian, and to a lesser extent in certain Laurentian magnetites. The ores of each of these geological divisions have their individual peculiarities, which serve to distinguish them to such a degree that the magnetites and specular ores of the Laurentian are as dissimilar to those of the Huronian as are the crystalline silicated rocks of the two series. As it happens that these mineralogical dissimilarities correspond to diflerences in composition and in adaptability to different processes of manufacture, which, in the present condition of the iron industry, are objects of special consideration to metallurgists, it will be seen that these geognostical distinctions become of great practical importance. During the past year I was desired by the Geological Commissioners of Pennsylvania to devote a few weeks to certain geological studies in the eastern part of the State, in the course of which I was enabled to make, with regard to its crystalline iron ores, some observations to which I desire to call the attention of the Institute. I may mention, in passing, that the great South Mountain belt, from the Schuylkill to the Delaware, is composed of Laurentian rocks, in which are found the characteristic ores of the series like those of the Highlands of New Jersey and New York, and of the Adiron-

ZAY JEFFRIES (communication to the Secretary*).-Having seen Mr. Ruder's micrographs of electrolytic iron, I am of the opinion that the tentative explanation offered verbally is correct. Mr. Ruder has informed me that both of the samples were cooled in the furnace. The structures as shown in Figs. Band C resulted from the last cooling through the temperature range near 900° C. Assuming that the rate of cooling through this range was the same in both cases, the differences in struc-ture of the gamma iron in the two samples must have ]:)]-ought about, in some way, the variations in grain size and grain shape shown in Mr. Ruder's micrographs. Even though there is practically no temperature gradient in muffle-furnace treatment during the "soaking" period, during both heating and cooling, there is a temperature gradient. Fig. B should normally have been fine-grained prior to the last cooling, due to the comparatively low maximum temperature to which it was heated (1,000° C.). On cooling through the allotropic change point at 900°, these small gamma grains, iii conjunction with the temperature gradient, should form an ideal condition for germination. Germinant grains should form near the surface of the sample (the-colder portions) and the small gamma grains would be progressively absorbed as they changed into non-gamma iron. The elongated grains in Fig. B, converging toward the axis of the piece of iron, indicate that germinant grains first formed near tine surface and advanced their boundaries toward the interior of the sample. The gamma grains in Fig. C, however, should have been large, prior to the last cooling, due to time high temperature treatment (1,250 to 1,300° C.). In other words, to use one of Prof. Howe's expressions, the crystalline organization should be very complete and the change from gamma to non-gamma iron on cooling would take place reluctantly. This resistance to change from gamma to non-gamma iron would probably be greater in the interior of the large grains than at their boundaries. Non-gamma iron centers or nuclei would probably form at a great many places, at the grain boundaries, thus masking the influence, to a large

Jan 6, 1917

By Nelson W. Taylor

With the extensive deposits of potash minerals which have been discovered in the southwestern states, and their rapid development, a permanent American supply of potassium compounds is now assured. The 325-year history of the potash industry in this country has been told by H. I. Smith1, of the U.S. Geological Survey, and the more recent activities of the Survey and of American potash companies were described last year by the same author2. In fact, it may be stated that so great is the productive capacity that two mines in New Mexico and one in California are able to supply more than half a million tons of crude and refined salts over and above that produced for agricultural purposes. The era of scarcity has given way to an era of superabundance. This situatiori makes it desirable for the potash producer to look for other applications for his product, and it is with this in mind that the writer presents some information pertaining to present and possible future uses for potassium compounds in the ceramic industry. Ceramic Products Ceramic products are essentially solid materials containing one or more oxides such as SiO2, Al2O3, CaO, MgO, FeO, K2O, Na2O, TiO2, which are the oxides of greatest abundance in the earth's crust. The typical ceramic process is that of firing or burning the batch, and the product may be glassy, crystalline or mixed. In the glassy or vitreous group come glass, porcelain enamel and glazes; in the crystalline group, refractory materials such as silica brick, or chromite or magnesia; and in the mixed group, porcelain, chinaware, stoneware, tile, brick, etc., which contain both a vitreous and a crystalline phase, in variable proportions. The ceramic industry of the United States is a billion dollar industry, and is important not only because of its magnitude but also because of the key position occupied by certain ceramic products in the whole manufacturing structure. From the standpoint of use of potash, the field of refractories is of no great interest, since K2O lowers the melting point of a refractory oxide and

Jan 1, 1938

By R. L. Skaggs, R. A. Molsberger

DARKEN1 has pointed out that in most binary liquid metal systems the thermodynamic behavior is relatively simple in the terminal regions. Between the terminal regions. the thermodynamic behavior is more complex. To describe this behavior. he has defined the stability and the excess stability as shown: Qualitatively, an inflection in the free energy of mixing curve results in a change in sign, from positive to negative, of the stability function and is associated with a phase separation. Conversely, a large, positive stability over a narrow composition range is indicative of compound formation. Darken has shown a number of binary systems where the excess stability is constant in the terminal regions and varies sharply in between. The work described in this communication was undertaken to study the variation of stability and excess stability in a binary system as a function of temperature. In addition, this work provides means for the direct comparison of previously existing equilibrium (activity) and calorimetric (molar heat of mixing) data on the Hg-Sn system. Hildebrand2 measured the vapor pressure of mercury over Hg-Sn alloys at 595°K. Calorimetric studies were made by Kawakami3 at 523°K and by Kleppa4 at 423°K. In this work, the equilibrium vapor pressure of mercury was measured over a series of Hg-Sn alloys at 453" and 503°K by use of fused salt manometer with one arm exposed to mercury vapor. Deflections of the fused salt manometer were balanced by argon pressure on the other arm. Argon pressure was subsequently measured with a dibutyl phthalate manometer. Tin activities were determined by graphical integration of the Gibbs-Duhem equation making use of the familiar Darken5 a function. The activities of mercury and tin showed positive deviation from Raoult's law at 453 and 503°K as Hildebrand observed at 595 K. In Fig. 1 are plotted log activity of mercury and tin vs reciprocal temperature. The plot contains activities obtained from calorimetric studies. Hult-gren6 has calculated activities from Kleppa's4 data, and Kubaschewski7 has similarly treated Kawakami's7 data. Presumably. in each case a regular solution was assumed. For regions where a two-phase field

Jan 1, 1970

By R. W. Raymond

The " law of the apex," with its vague and impracticable " extra-lateral rights," is defended—if it is defended at all— on the ground that it is required by the peculiar conditions of the mineral deposits or of the mining industry in those States and Territories in which it is operative. As I have repeatedly attempted to show, in papers read before the Institute, and most recently in an article on " The Relation of the Mining Law of the United States to the Davelopment of its Mineral Resources," published in Mr. Rothwell's Mineral Industry for 1894, there is now (whatever may have been the case formerly) no peculiarity of conditions in the regions referred to which warrants the subjection of their mining industry to a burden so vexatious and injurious as this law imposes. I have called attention to the absolute freedom from expensive litigations over mining titles enjoyed by all other States in the Union and all other regions in the world where the absurd extra-lateral right does not exist.

Jan 1, 1896

By Holliday RJ

The Imperial Smelting Furnace (ISF) was developed in Britain during the 1950's as a process which could produce zinc from a blast furnace. Since then it has evolved into an efficient means of producing zinc and lead from lower grade raw materials, both of primary and secondary origin. These changes have been in response to the need to improve the cost competitive position of the ISF in a climate of decreasing metal prices. The improvements at the Cockle Creek smelter of Sulphide Corporation Pty Limited have resulted from work undertaken in four main areas: 1. Changes in plant design and operating practice to give more stable furnace operation. 2. Improvements to the quality of sinter being charged to the furnace. 3. Improved monitoring of process variables and the formulation of control strategies based on the improved data. 4. Increased understanding of the processes occuring within the furnace shaft to allow predictive modelling to be undertaken. Work in these areas is still progressing but the work to date has resulted in a significant improvement in the production rate and efficiency of operation.

Jan 1, 1984

By J. A. Pusateri, M. A. Orehoski, N. R. Arant

Plant studies on commercial-size ingots and laboratory experiments with induction furnace heats have demonstrated that the major source of ingot cracks is associated with two conditions arising during top-pouring practice: 1—solidification during pouring, and 2—turbulence created by the impact of the stream. Methods of controlling the two factors were effective in eliminating or significantly reducing ingot cracks. BECAUSE the process of removing surface defects from hot-rolled product is so costly, the steel industry is striving constantly to develop methods of preventing, or at least decreasing, the occurrence of surface defects. Investigations have revealed steel-making and processing variables related to major surface defects, and controlling these variables has led to improvements in surface quality. However, the fundamental causes of major surface defects, such as ingot cracks, have not been determined; consequently such defects persist. At the Research and Development Laboratory of the United States Steel Corp. in Pittsburgh, a seam research program was initiated to determine the fundamental causes of certain major defects. As a part of the program, ingot cracks in killed, finegrained C1020 steel were selected for study. A cost survey indicated that, of the steels produced in sizable tonnages, carbon steels in the range of 0.18 to 0.23 pct C content require the most conditioning. Since this is particularly true of C1020, any im-provement of surface quality that might be effected from the study would be beneficial. Also, since the frequency of ingot cracks is exceedingly high for this grade, the steel would provide an excellent opportunity for a thorough study of the ingot-crack-ing problem. Why steels in this carbon range tend to exhibit more ingot cracks than do other steels was not considered in the investigation; the mechanism of ingot-crack formation was of paramount importance. Also, only the top-pouring practice was considered in the investigation, because this pouring procedure is used more extensively than others. In this study, ingot cracks are defined. as deep surface defects that sometimes are observed in an ingot prior to rolling but usually are observed during the initial stages of rolling on the primary mills. These defects may occur at any angle to the rolling direction but are most prominent in the transverse or nearly transverse direction. The appearance of ingot cracks on the rolled product varies with respect to their angle of formation and with the extent of rolling after their first occurrence. Ingot cracks are also termed "deep seams," "arrowheads," "irregular cracks," and "transverse cracks." Fig. 1 shows ingot cracks in a rolled bloom. This report summarizes: l—the exploratory investigation of commercial-size ingots; 2—the labor-atory investigations related to determining the source of ingot cracks and developing corrective methods; and 3—the plant evaluations of laboratory methods of decreasing ingot cracks. Exploration of lngot Cracks in Commercial Ingots Materials and Experimental Work: At the Du-quesne Works of the United States Steel Corp., five heats of killed, fine-grained C1020 steel were selected for the exploratory phase of the seam-research program. The heats were made by open-hearth practices that are considered most conducive to good surface quality. They were top-poured into 22x25 in. big-end-up hot-topped molds. One as-cast ingot and four other ingots rolled to the following cross-sectional sizes were set aside from each heat: 16x20 in.; 9 1/2x10 in.; 5x5 in.; and 2x2 in. The processing of the heats, from the time of charging in the open hearth furnaces to the end of the rolling operation on the primary mill, was observed carefully and recorded. The cast ingot and the four rolled ingots from each heat were examined for surface defects. The cast ingots were split longitudinally near the vertical center plane to expose the ingot structure beneath badly cracked regions. Also, a series of transverse sections was cut at about 1 in. intervals in a badly cracked area of one ingot. All sections were ground, polished, examined by sulphur printing and deep etching, and photographed. The rolled ingots

Jan 1, 1955

By C Muñoz, N Ortega, J Vergara, D Avilés

Mass blasts have been the subject of extensive studies because of their potential benefits in mining operations. However, it has not been possible to advance due to the paradigm that states that the blasts near the designed final wall or to critical structures have to be low tonnage. Another reason is the absence of specialised simulation programs to more precisely determine the influence of the energy released by blasting to the rock mass. There are some studies that demonstrate the possibility of massive blasting that maintain the design of the final slope (Farias and Santander, 2014). It should be noted that these studies develop the concept that the size of the blast should not increase the peak vibration in the rock mass.The study was carried out in partnership with Los Colorados Mining Company. Analysis, reconciliation and wall control for two types of blasts were performed:blasting production: approximately 850 000 t, with special wall control considerationsblasting of approximately 950 000 t over the entire width of the bench.Monitoring systems were used in the near field and far field using examination of holes in order to obtain information to assess the impact on the rock mass and then to compare these to conventional blasting combining production and contour blasting.The results show that for a large blasted volume, production and/or those generated from toe to crest on the bench did not produce more impact in the rock mass than the conventional blasting.The conclusions drawn from this study are:an improvement in the excavation rate of 7500 t/h that is higher than the maximum rates normally obtainedthe peak vibrations of the P wave generated by both blasts did not exceed the peak particle velocity criteria (Vergara and Muñoz, 2014)holes examination indicating no difference in their entire length, in pre- and post-blast reviewover US$2 000 000 savings generated in the year (estimated by the client) (Avilés, 2014).CITATION:Vergara, J, Muñoz, C, Ortega, N and Avilés, D, 2015. Benefits related to applications of a mass blast in open cut mining, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 625–632 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Ricardo Melamed

Metallic mercury has been extensively used for gold recovery. Although the solubility and mobility of metallic mercury is low, this metal can undergo many transformations, leading to mercury contamination in humans. The complexity of Hg chemistry in the environment reflects its different possible oxidation states and species, with different physical-chemical properties. The interaction of Hg in the terrestrial system, as well as in the aquatic environment, is important to understand the mercury cycle. This paper reports data on the adsorption of Hg onto an Oxisol soil. Results show that the interaction of Hg(II) at the soil-solution interface depends strongly on ligand concentration in solution, which can affect Hg mobility. The presence of the chloride anion in solution increases the mobility of Hg(II) through the soil, due to a relative lower affmity of mercury chloride at the oxide surface. In the absence of chloride, Hg(II) form strong complexes with the surface, and its adsorption behaviour is similar to the adsorption of other hydrolizable cations.

Jan 1, 1996

By Maurice Cook

NORMALLY the grain size of cold-rolled and annealed copper sheet is of the order of 0.02 to 0.06 mm., and 0.1 min., for example, would, for many purposes, he regarded as undesirably large. The occurrence of very large grain sizes in a few isolated cases of copper sheet led the authors to inquire into the causes giving rise to such unusual results. During the course of this work a very large number of experiments have been carried out to determine the effect of varying the conditions of the final and penultimate rolling and annealing operations, as well as of earlier rolling and annealing treatments. A correspondingly large number of observations have been made, but within the space of one paper it is possible only to outline relatively briefly what appear to be the more important of these experiments and observations. The presentation of the results does not follow chronologically the order in which the experiments were carried out and they have been rearranged for the sake of simplicity. In recent years a considerable amount of work has been done in connection with the recrystallization and grain growth in metals and alloys that take place on annealing, and a number of generalizations have been reached. It is known that the crystal size in wrought material in the annealed condition depends on a number of factors, including the time and temperature of the annealing operations and the nature and amount of cold-work to which the material has been subjected. Results, however, that are not covered by these generalizations can be obtained, which, in some instances, may even appear to he contradictory to them. According to these generalizations gradual changes in grain size are effected by progressive variation of the factors involved in annealing or cold-working. The work recorded in the present paper, however, relates to the development of grain sizes which are far beyond those normally encountered in ordinary annealing operations and far in excess of grain sizes which, according to ordinary standards, would be classified as coarse or large.

Jan 1, 1938

By Joseph A. Sutton

The prospect of utilizing bacteria in mining and metallurgical processes introduces a new and challenging area of investigation. Elements of bacteriology and metallurgy are discussed in connection with possible areas where biological science might be applied in extractive metallurgy. Bacteria may prove important in the selective separation of metals from ores and metallurgical solutions, the production of sulfur from gypsum or pyrites, and the production of sulfuric acid from elemental sulfur. A series of reports concerning the experimental applications of bacteria on minerals and metallic ores will follow this paper. For several years the Bureau of Mines has been investigating the action of bacteria in the oxidation of sulfide minerals and their potential uses in metallurgical processes. Primary attention has been given to the possible utilization of certain strains of autotrophic bacteria that live in industrial leaching solutions or fractures of mineral outcrops. The purpose of this paper is to acquaint the mining and metallurgical engineer with micro-organisms and some of their possible applications in the field of extractive metallurgy.

Jan 1, 1961

By Sebastien Flament

More and more Hot Strip Mills are facing defects on their products that lead to a rejection of complete product batches by their customers. Several of those defects are induced by excessive work roll degradation. This paper is focussed on the understanding of work roll corrosion and oxidation mechanisms in a hot strip mill. Several laboratory trials (Hot rolling simulator, cyclic oxidation) have highlighted important factors influencing corrosion of work rolls as well as helping the understandings of oxidation of a work roll in the roll bite and along the roll circumference in a stand. The attention is focussed on several elements present in water used in HSM for direct roll cooling (e.g. chloride, bactericides, sulphates, phosphates) and their effect on roll surface degradation. The second part of this paper is focused on the understanding of work roll oxidation along the roll circumference. The effects of roll composition, roll temperature, water composition and water temperature have been studied in order to understand the oxidation/corrosion mechanisms in a HSM.

Aug 16, 2017

By K J. Lownie, T Rafferty

The in situ testing of mine ventilation fan systems has been a contentious issue for many years. Site testing was generally undertaken by adapting standards that were developed for the laboratory testing of fans using standardised airways. The deficiencies inherent in this practice have been widely recognised by informed practitioners, and this led to the first stand-alone document specifically intended for the in situ testing of large fans (ISO 5802:2001 Industrial fans - Performance testing in situ).This paper describes the structure of the International Standards organisation and the processes that are followed in the course of preparing such a standard.The application of ISO 5802:2001 is briefly outlined together with how test data is assessed for compliance with the suppliers guarantee. This paper must be read in conjunction with ISO 5801:2007, ISO 5802:2001 and ISO 13348:2007.CITATION:Lownie, K J and Rafferty, T, 2013. A review of ISO 5802:2001 industrial fans - performance testing i n situ, in Proceedings The Australian Mine Ventilation Conference , pp 149-154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By Thomas J. O'Keefe, Pu Yu, George Houlachi, Xuewen Tang

"Impedance measurements were used to investigate the electrochemical characteristics of acidic zinc sulphate electrolytes containing Sb3+, gelatin and their mixtures. The data were correlated with cyclic voltammetry curves made using synthetic as well as industrial electrolytes. The cyclic voltammetry results were similar to those obtained in previous studies in that antimony caused a depolarizing effect while gelatin gave an increase in the potential for zinc nucleation on an aluminum substrate.The electrochemical impedance spectroscopy (ElS) evaluations were conducted on electrodeposited zinc at three overpotential values. The potentials were chosen to represent various current density regions in the zinc polarization curves. The antimony and gelatin gave characteristic impedance plots which correlated with expected behavior, particularly current efficiency. Both antimony and glue appear to modify the intermediate zinc reaction sequence, but in different ways. The data strongly suggest that film formation and stability are major factors in the zinc ion reduction mechanism.IntroductionThe zinc electrodeposition process is sensitive to the presence of a variety of organic and inorganic chemical species in the electrolyte [I]. Such components can produce either beneficial or harmful effects, depending on their relative concentrations and electrochemical behavior. Extensive investigations have been made to gain a better understanding of the changes occurring during zinc deposition in the presence of such additives. Techniques employed include microscopy, x-ray diffraction, dynamic voitammetry, current imd energy efficiency studies [2-5]. Ultimately, the objectives are to identify the factors which most affect the efficiency of the process and to provide a means to effectively control them.One of the most harmful impurities is antimony, which can be detrimental when present at concentrations as low as 10 to 20 parts per billion. Dramatic changes in zinc polarization behavior, deposition structure and current efficiency have been observed with antimony in the electrolyte. Antimony appears to lower the hydrogen overpotential by hydride formation or a similar catalytic mechanism, which allows an increase in localized corrosion and zinc dissolution [6-8]."

Jan 1, 1997