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By H. A. Wriedt

A method of calculating activities in binary systems having miscibility gaps is described. The method, which applies only to the phase in which the gap occurs, is exact when the function defined by the equation varies linearly with composition. Analytical and numerical solutions (as a function of the conjugate phase compositions) are presented for two coefficients A and B from which the thermodynamic activities can be calculated. Deviations from Henry's law, calculable by the method presented, are shown graphically for the particula~ case of the component i at the edge of the miscibility gap more remote .from pure component i. For symmetrical gaps, the deviation from Henry's law at this gap edge becomes smaller as the gap becomes wider, The interrelation of gap location, the direction of departures from Henry's law and the occurrence of maxima and minzma in these departures is discussed in some detail. Values for a and for activity calculated from phase diagrams show fair to excellent agreement with corresponding experimental values in the Al-Zn and CaO-SiO2 systems. WHEN structurally similar phases, B and 6, lie at the sides of a two-phase region in a constitution diagram, it can be assumed that, stably or metast-ably, they will become completely miscible at a higher temperature. The B and 6 phases are particular composition ranges of a single B6 phase region with a miscibility gap. Below, as above, the critical solution temperature, the free energy of formation of the 06 phase is a continuous function of composition through the range of the miscibility gap. It is the purpose of this paper to use this continuous free-energy function in order to develop a simple method for computing the thermodynamic activities in the B6 solution of a binary system. To make these calculations it is assumed that the function ai, familiar from Gibbs-Duhem integrations and defined by the equation

Jan 1, 1962

By James A. Madonna

Several universities and colleges in Australia, Canada and the United States, recognized the need to establish or reorganize geoscience programs at the vocational and two-year technical levels. To accomplish this, a cooperative study with industry in one state or province from each country was initiated. These include Tasmania in Australia, British Columbia in Canada and Alaska in the United States. The objective of this work was to develop a diversified geoscience educational model at the two-year technical, vocational and continuing education level that provides the source from which any nation can draw the proper educational tools to create a new geoscience program, modernize an existing program or strengthen a weak program. More than 100 mineral industry organizations provided information regarding their specific training needs for support personnel. The data gathered have been used to identify training areas for semi-skilled, skilled and technical personnel in geochemical mineral exploration. These included geological, geochemical, environmental and computer skills. With the areas of major educational need defined for geochemical exploration, an educational field skills model was developed for the three levels of training. The international need for a study of this type was recognized as early as 1980, following numerous contacts from domestic and foreign geoscience educators regarding the structure and success of training within the University of Alaska Fairbanks Mining Extension program, located in Fairbanks. Contacts, correspondence and visits included educators from Australia, Brazil, Canada, Mozambique and the conterminous United States. The need was magnified between 1985 and 1989 at the University of Alaska Fairbanks, when an attempt failed at initiating and developing a two-year geoscience vocational-technology program leading to an Associate of Science degree.

Jan 1, 1994

By W. H. Bassett, C. H. Davis

The late J. P. Sparrow, chief operating engineer of the New York Edison CO., carried out a series of practical tests on condenser tubes of several copper alloys and reported on the results to the Association of Edison Illuminating Companies at its meeting in September, 1913. In the preparation of these tubes the senior author had the pleasure of cooperating. Copper-zinc alloys in the proportions of 60-40,70-30,80-20, 90-10, and Admiralty metal, which is in effect 70-30 with 1 per cent. of tin, were tried. Monel metal and several copper-nickel alloys, and 8, 5, and 3 per cent. aluminum bronze were also tried. At the time of this report, the aluminum bronze had been in service for 4 1/2 years and seemed to be giving especially good results but later it began to fail and showed no substantial improvement over Admiralty metal. Monel metal was unsatisfactory and the nickel alloys apparently did not give better service than the Admiralty alloy. Previous to the publication of the report, and after considerable discussion, it was agreed that a test where tubes of different kinds could be under laboratory observation would be advisable, so the apparatus described here was set up in The American Brass Co.'s Waterbury Laboratory. This was fitted with tubes of copper, brass, bronze, nickel silver, cupro-nickel and other alloys, and the test started on Oct. 11, 1912. Salt water from East River, New York harbor, was barrelled and transported to the laboratory for the test. A fresh supply, completely replacing the water in service, was obtained at the end of each six months period. Plan of Procedure In general, the procedure was to inspect the tubes at short intervals and to remove those that had begun to leak. The tubes removed were carefully examined and a photographic and microscopic record of the

Jan 1, 1925

By R. W. Stahl, H. E. Sanford, J. B. Benson

"As movement or transportation of coal is second only in importance to actual mining, and as the latter is wholly dependent on the former, the efficiency of the haulage system often determines the efficiency of the entire plant. Safe or accident-free transportation is essential, also, because no attempt is made to divorce safety and efficiency, it being realized that they are inseparable.Most of the Ruhr mines were opened decades ago, and many features that were considered up-to-date then are now obsolete. Progress in developing haulage systems has been slow, chiefly because it would be very costly to change many to accomodate more modern equipment. These systems are being altered or modernized slowly, as capital permits. The only revolutionary changes that have been made in mine haulage are the use of larger locomo¬tives and cars, in the movement of shuttle cars, and in the adoption of skip hoisting. Most Ruhr shafts, however, will not accomodate large cars, the secondary roadways are too narrow for large locomotives, and the coal is too soft to permit skip hoisting because degradation would be too great. Therefore, notable advances have been made only at newer plants, where allowances have been made for modern equipment.The shafts are deep (average 2,300 feet) and of comparatively small diameter. The small bore was designed to reduce costs of sinking and lining. Generally, the shafts are lined throughout with masonry; however, most of the buntons and guides are wooden.The hoisting engines arc installed in masonry structures, and where more than one hoist is used they are placed on opposite sides of the shaft to eliminate as much noise as possible (fig. 1). This arrangement also prevents an engineer from acting on any signals except those transmitted to him. A few hoisting engines are mounted in the headframes (fig. 2). The hoisting engines are equipped with overwind, overspeed, and auxiliary braking devices, which are tested frequently and kept operative at all times. The signal code is displayed in view of the engineer, and a light or dial indicator informs him of the cage's position in the shaft. Many hoists are equipped with re¬cording devices, which show on a continuous chart the speed of hoisting as well as any delays throughout the 24-hour period.A Koepe system of winding is in general use because of the depth of shafts (fig. 3). With this system, a single rope passes over a single-groove, large-diameter sheave attached to the motive power, and the ends of the rope, after passing over the head sheaves, are attached to the cages. A flat tail rope suspended in the shaft and connected to the bottom of the cages serves to balance the system. Both steam and electric engines are used to activate the hoisting system, end the engines are capable of moving at least a 50-percent overload.The ropes are necessarily of large diameter (2-1/2 inches and greater), and flexibility decreases as rope diameter increases. To overcome the unwieldiness .of large-diameter ropes as shafts become deeper, a four-rope system is being tried at one mine (fig.4). In this system the load is equalized between four ropes which permits much smaller ropes to be used. All hoist ropes are inspected daily and discarded after 2 years service unless special permission for longer service is granted by the Mine Inspectorate, and then only after thorough visual and electromagnetic inspection."

Jan 1, 1950

By J. J. Fallon

The subject is "Mergers, Acquisitions and Divestitures in Industrial Minerals, but my remarks could also be applied to new product development, resource development and other new business development activities. At the kernel of the subject is due diligence in major decision-making, that is, where major money amounts and a large corporate commitment are at stake. The "due diligence" means how carefully we do our homework before making the decision. The homework or feasibility study addresses different parts of the decision. In the industrial minerals business the study seeks to uncover the pros and cons in: o The mineral reserves, quantity, quality, mineability, access, etc. o The environmental impact of mining, processing and transporting. o The economics of operations. o Financial aspects o Legal aspects o Many other aspects o And -oh yes! the marketing aspects.

Jan 1, 1990

By Pengfu Tan

Converter slag chemistry control has played an important role in optimizing converter operations. A thermodynamic model of copper P-S converter has been developed to predict the behavior of magnetite in the converter slag. Predictions of bath temperature, slag and matte compositions, and magnetite content in the slag have been validated by industrial data. The effects of fluxing strategy, returns and skim charges, oxygen enrichment, and temperature on the magnetite formation in the slag have been predicted and discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2005

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

By Y S. Zhang

Natural phenomena and human engineering construction activities had great influence on the geosciences space. Natural disasters, particularly mine disaster and other geological disasters happened frequently, which brought great losses both in people’s lives and economics, therefore, to explore the essential causes and mechanisms of disaster by some useful approaches is the most important step in mine disaster prevention. In a variety of methods, building an aground-underground seamlessly integrated model, and then analysing the formation and development mechanism of mining disaster based on this model is a useful way. In this paper, we studied an aground-underground seamlessly Integrated modelling method, and correspondingly given an aground-underground seamlessly integrated 3D spatial model, CSG+CD-TIN+GTP-TTS, by which we can carry out analysis of surface subsidence and underground laneway distortion efficiently, finally preliminary applications verified the effectiveness of this method.

Nov 22, 2011

By Charles Camsell

At the last annual meeting of this Institute the programme very properly was drawn up and carried out with the special object of calling attention to the Dominion's position and problems with regard to fuel supplies. That subject, always one of serious concern, was a source of considerable anxiety twelve months ago. It is still so, but in a decidedly less degree than at that time. So far as the immediate fuel situation is concerned our anxieties have been relieved. And I think we can safely say that such a consciousness of our difficulties and determination to overcome them, has been developed in the minds of our people that there will be no slackening of the offensive until a final solution is reached. In selecting a subject of major importance for the present occasion I have felt free to digress from the pressing problems of last year and to go back, for a starting point, to the presidential address of two years ago .. I do not, however, wish to enter the controversy that has developed as a result of that address, though in spite of my own failure to amass a fortune from participation in certain mining ventures, I am decidedly inclined to the optimistic view that Dr. Corless presented of the future of our mining industry. You will perhaps have observed that in its general wording the title of my paper bears a marked resemblance to that of that address. This simila1ity of titles is not accidental. It is intentional on my part.

Jan 1, 1924

By Ross I. Kelly

Carbonate rocks are widespread throughout Ontario and provide raw material for more uses than perhaps any other rock type. The principal carbonate rocks that are used by industry in Ontario are Paleozoic era limestone and dolostone. Limestone is a sedimentary rock that is composed mainly of the mineral calcite (CaCO,) while dolostone, also a sedimentary rock, is composed mostly of dolomite [CaMg (CO,),l. The majority of the province's limestone and dolostone extraction occurs from Paleozoic era rocks located in southern Ontario. Calcite and dolomite are also found in Precambrian marbles, calcite veins and carbonatites, however, utilization of these rocks by industry has been less common. Calcite and dolomite-rich rocks are utilized for a wide variety of uses including raw materials for cement and lime manufacture, chemical and metallurgical stone, fillers and construction aggregates (Derry, Michener, Booth and Wahl and OGS 1989a). For some uses chemical and physical requirements are very important. In the manufacture of glass, for instance, the chemical requirements of source materials are very important and very stringent. In other uses physical criteria such as whiteness may be more important. Although carbonate rocks are quite plentiful within the province, deposits that contain high concentrations of calcite or dolomite are somewhat limited. For that reason, this paper focuses on deposits that are known to, or may contain, a high percentage of calcite and/or dolomite. The paper emphasizes potential sedimentary limestone and dolostone resources, as these are the carbonate rocks most commonly utilized by industry in Ontario.

Jan 1, 2001

By Yongjun Xian

The release of fluid inclusions has a strong potential for the unintentional activation of pyrite during flotation. The present study aims to characterize fluid inclusions in a natural pure pyrite. The results indicate that a certain amount of fluid inclusions exist in the pyrite. The fluid inclusions assume a variety of shapes, including long strips, oval shapes and irregular shapes, with sizes that range from a few microns to dozens of microns. From the EDS results of hollow positions that resulted from the fracture of the fluid inclusions on the pyrite surface, certain amounts of Al, Cr, C, O, Ag and Cu were clearly detected; these elements were not detected in FeS2 pyrite itself. The contents of the inclusions were released into solution when the sample was subjected to a grinding process. Under experimental conditions of 2 g of pyrite cleaned in 40 mL of pure deionized water under an inert atmosphere, the concentrations of Cu, Fe, Cl- and SO4 2- released from the inclusions reached concentrations of 3.29 × 10-6, 32.52 × 10-6, 51.57 × 10-6 and 75.90 × 10-6 mol/L, respectively. These values are significantly greater than those from the experimental nonoxidative and oxidative dissolution of the pyrite. The fluid inclusions of pyrite were, therefore, concluded to represent the dominant sources of Cu, Fe, Cl- and SO4 2- in the aqueous solution. The present investigation provides a new understanding of the source of the unavoidable metal ions in the pulp and may benefit understanding of the flotation theory and environmental geochemistry.

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

8. Field Demonstration of the Remote Mine Sealing System in a Coal Mine 8. 1 Selection of Field Test Site Eastern Associated Coal Corporation (EACC) offered its Federal No. 1 coal mine in Grant Town, West Virginia as the site for field testing of the remote sealing system. The choice of Federal No. 1 mine was particularly appropriate as the first attempt at fire control by remote sealing was done in this mine in 1963. EACC provided the men and equipment required for much of the initial preparation. Considerable assistance, advice, and background on coal mining technology was given by Mr. William Laird, Vice President for Research and Development, EACC, and by Mr. Lawrence Jackson, Resident Engineer at the Federal No. 1 mine. District 3 USBM office, the West Virginia Bureau of Mines, the Technical Support Group of the USBM, and Local 4047 of the United Mine Workers of America also cooperated. 8.2 Preparation of Field Test Site 8.2. 1 Underground Site Preparation The underground site chosen for the field testing was in a non-working portion of the mine within a few hundred feet of the main haulage road, as shown in Figure 80. Known as "Seven Switch, " this area was a 20 minute walk or 5 minute "jeep" trip from the man-trip shaft. Ten years having passed since this area was actively worked, considerable effort was required for gob clearing, roof bolting, rock dusting, and rejuvenating the track from the haulage road to the test area. Three primary borehole locations were chosen for the test program. Borehole No. 1 was in a straight passageway

Jan 1, 1973

By Howard W. Dubois, Charles T. Mixer

Only within the past few years have chemists recognized the importance of the fact, that comparatively large amounts of phosphorus may occur in the siliceous residue left from the acid treatment of iron-ores. We know of one case in which an ore contained about three times as much phosphorus in the insoluble, as in the soluble, form. It was disposed of at a premium, as an exceptionally high-grade Bessemer ore containing 0.010 per cent. of soluble phosphorus, while the insoluble phosphorus brought the total amount up to 0.040 per cent. The magnetite and specular hematite of the Lake Superior districts and the fine ores of the Mesabi range, as a rule, contain very small amounts of insoluble phosphorus. But the mining of the soft hematites and the progressive lowering of the phosphorus-limit in a strictly Bessemer ore, have combined to make the determination of insoluble phosphorus one of the routine-requirements in all analyses of Bessemer ores. The insoluble phosphorus is understood to be that pbosphorus which cannot be extracted by boiling hydrochloric acid of 1.1 specific gravity. The time given for the extraction of the soluble phosphorus will vary, of course, according to the nature of the ore. In ordinary practice the boiling is continued until the residue is white or only very slightly tinged with ferric oxide. This ordinarily takes from half an hour to an hour. The prolonged boiling of ores known to contain considerable quantities of insoluble phosphorus has failed to extract any appreciable amount of additional phosphorus. Very fine grinding and subseqnent sifting through bolting-cloth has not increased the extraction. These statements represent the re-

Jan 1, 1898

By H. G. Mosenthal

In any mining enterprise, the extraction of the ore from the orebody is of vital importance. This activity is stoping. The gold mines of the Witwatersrand and its extensions in the Klerksdorp, Welkom, and Evander areas form the most extensive goldfield in the world. This address reviews stoping technology and improvements in this technology since the end of the Second World War. Although the reefs that make up the Witwatersrand orebody are uniquely extensive, they are not suited to mechanized mining. This is due to a number of factors such as the depth of the orebody, its narrowness, and the hardness and abrasiveness of the quartzite forming the orebody. The most notable improvements in stoping technology have been brought about because of our beter understanding of rock-engineering problems. This has resulted in beter layouts, stoping geometry, systems of aleviating rock stresses, and support systems. It has enabled the industry, at ever-greater mining depths, to maintain and even increase productivity. These improvements, based on rock engineering, have significantly reduced the accidents due to rockbursts. There are many diferences between today's stoping and that practised forty years ago. Panels are shorter, concentrated mining has superseded bench mining, and the support systems are certainly better. Yet the face scraper is still used extensively, as are pneumatic rock drills. Some innovative stoping systems that have given rise to improved productivity are discussed. Explosives technology has shown spectacular advances during the period under review. Sadly, our local industry has had little to do with this research and development, but has been most adaptive in using the new products on offer.

Jan 1, 1990

By Marwan M. Mohammed, Hani S. Mitri, Wilfrid Comeaul, Baoyao Tang

In many parts of the world, rockbursts have become a major problem of mining at depth. As orebodies are being mined deeper, rockburst phenomena have become familiar to deep hard rock mines. Rockbursts are generally characterised by sudden release of energy in a volume of highly stressed rock, which can cause local violent failure of the rock mass around the opening. One method of controlling these failures is to precondition the rock mass by detonating fully confined explosive charges at the appropriate locations. This method known as destress blasting, was first tried in the deep South African gold mines (Roux et al., 1957), and was widely used later in Canada, United States, France, Poland and Japan.

Jan 1, 1999

By R. W. Fountain, W. D. Forgeng

A new constitutional diagram is presented for the cobalt-rich end of the cobalt-titaniurn system. The modifications result from the presence of a new, intermediate, fcc phase, ?, the existence and homogeneity limits of which were established by metallo-graphic and X-ray studies of alloys containing from about 3 to 30 pct Ti. The precipitation of the ? phase from supersaturated solid solution was studied by hardness and electrical resistivity measzsrements, and two distinct stages in the process were observed. COBALT forms the base for a number of precipitation -hardenable alloy systems which may be divided into two distinct categories of practical interest, a) those hardened by intermetallic compounds and b) those hardened by carbide formation. The precipitation of intermetallic compounds from solid solution in cobalt-rich alloys has, however, received very little attention. Although the phase diagrams for some binary systems capable of precipitation have been determined,' there is an almost complete lack of data on the property changes associated with the precipitation, and even less information on the kinetics of the reactions or morphology of the products. More information is available on the precipitation of carbides because of the practical significance in superalloys. A survey of cobalt binary phase diagrams suggested that the cobalt-titanium alloys might provide interesting and useful precipitation-hardenable alloys. The equilibrium diagram as proposed by Wallbaum2 is shown in Fig. 1. Köster and wagner3 have indicated that the maximum solubility of titanium in cobalt is about 10 pct at the eutectic temperature (1135oC), and this decreases to about 7.2 pct at room temperature. The temperature of the allotropic transformation in cobalt is lowered by the addition of titanium, about 5 pct being sufficient to retain the high-temperature fcc modification to room temperature. Wallbaum and Witte 4,5 have indicated that the precipitating phase in alloys containing up to about 29 pct Ti is Co2Ti, a hexagonal Laves phase of the MgNi, type. With slightly higher titanium contents, they also report a cubic modification of Co2Ti of the MgCu2-type Laves phase. Duwez and Taylor6 confirmed the existence of the hexagonal (MgNi2) modification but not the cubic (MgCuz) modification of Co2Ti and suggested that existence of the cubic form may have resulted from impurities in Wallbaum's alloys. In their work on Laves-type phases, Elliott and Rostoker 7 reported the cubic modification of Co,Ti, but did not confirm the existence of the hexagonal modification. However, Dwight8 in a discussion of the work of Eliott and Rostoker again showed the existence of both modifications of Co2Ti, a result which was confirmed at that time by Elliott and Rostoker. As a result of a study on the iron-cobalt-titanium system, Köster and Gellers suggested the existence of a Co3Ti phase isomorphous with Fe3Ti. Witte and Wallbaum,' however, established the fact that no compound, Fe3Ti, exists in the iron-titanium system, and in a later publication, wallbaum2 stated that Kitster and Geller's reasoning was not valid, and no compound, Co3Ti, exists. This conclusion was later acknowledged by Köster.10 Preliminary experiments by the present authors to determine the precipitation-hardening characteristics of the cobalt-rich, cobalt-titanium alloys re-

Jan 1, 1960

By C. A. Zapffe

BOTH the foundryman and the theoretical metallurgist are now generally agreed that the anomalous "rising" or "bleeding" of certain ferrous castings of killed metal is primarily attributable to hydrogen. How and why the phenomenon occurs, however, have not been made clear. The following discussion is intended to harmonize foundry experience with metallurgical theory so that the foundryman may possibly improve his ability to prognosticate whether a certain casting may bleed or not. BLEEDING, RISING, AND PIPING The "rising" to be discussed here is not to be confused with the action in rimming ingots as a result of the carbon-oxygen reaction, although a conclusion will be drawn that may apply to the art of controlling the rimming action. Only killed metal is considered, which includes both steels and irons. In Fig. I, three killed, chill-cast ingots are shown: a porous ingot whose evolution of gas during late stages of solidification has ejected metal through the top; an ingot in which moderate gas evolution during solidification has lifted the mushy central metal, i.e., it has "risen"; and, third, a sound ingot with good piping characteristics. The first type is referred to as "bleeding," and generally infers that a solid skin had first formed through which the liquid metal later erupted. There is no fundamental distinction between bleeding and rising in reference to killed metal.* POROSITY Hydrogen appears as a cause of bleeding because the gas evolution simultaneously leaves a porosity of a type traceable to hydrogen. Twenty years ago, Melmoth1 noted that killed steel that rose unexpectedly in the mold, if returned while liquid to the furnace and heated further under a reducing lime slag, would again rise in the mold; but that if the ingot were allowed to solidify and was then remelted no rising occurred. A critical quantity of the responsible gas is therefore removed by the rising action. Melmoth associated rising with high silicon (0.7 to 0.9 per cent) and concluded that silicon increased gas absorption. Because silicon is a strong deoxidizer, oxygen must, therefore, be eliminated from consideration of the three common gases in steel-oxygen, nitrogen, and hydrogen. Butterworth2 later decided that pinhole porosity was caused by gases dissolved in the metal and that hydrogen was obtained from steam in the mold. Allen's classical work on copper castings,3 soon followed by

Jan 1, 1942

Many industries base their decisions on the assaying of tiny analytical sub-samples. The problem is that most of the time several sampling and sub-sampling stages are required before the laboratory provides its ultimate assays using advanced chemical and physical methods of analysis. As long as each sampling and sub-sampling stage is the object of due diligence using the Theory of Sampling it is likely that the integrity of the sought after information has not been altered and the generated database is still capable to fulfil its informative mission. Unfortunately, more often than not, unawareness of the basic properties of heterogeneous materials combined with the unawareness of stringent requirements listed in the theory of sampling, lead to the conclusion that massive discrepancies may be observed between the expensive outcome of a long chain of sampling and analytical custody, and reality. There are no areas that are more vulnerable to such misfortune than sampling and assaying for trace amounts of constituents of interest in the environment, in high purity materials, in precious metals exploration, food chain, chemicals and pharmaceutical products. Without the preventive suggestions of the theory of sampling serious difficulties may arise when making Gaussian approximations or even log-normal manipulations in the subsequent interpretations. A complementary understanding of Poisson processes injected in the theory of sampling may greatly help the practitioner understand structural sampling problems and prevent unfortunate mistakes from being repeated over and over until a crisis is reached. This paper presents an overview of the theoretical, practical and economic difficulties often vastly underestimated in the search for quantifying trace amounts of valuable or unwelcome components.

Jan 1, 2009

By Henry Mulryan

Diatoms are microscopic aquatic plants of the order Bacillariaceae. They are unicellular plants with skelctons made up of amorphous opaline silica. The skeletons show highly ornate, complicated geometrical designs. Diatoms live in water virtually everywhere. They are found in clean sea water, brackish water, and fresh-water lakes and ponds. When conditions are right, diatoms propagate by subdivision in huge numbers. Alkalinity, temperature, and the presence of high concentrations of silica in the water largely control diatom life. When the diatoms die the skeletons drop to the bottom of their habitat to form oozes of varying thicknesses. Diatomites Diatomite, or diatomaceous earth, is composed essentially of the siliceous remains of the diatoms, although other organic skeletons are also present, especially in sea-water deposits where radiolaria, sponges and silico-flagellates are common. Impurities are generally carbonaceous material, fine-grained silt, volcanic ash and dust, and occasional coarse grains of sand. Diatomites are marine, brackish, or fresh-water, depending upon types of diatoms and their method of deposition. Diatoms More than 8000 species of diatoms have been named and classified. Some are definitely classified as to their habitat; some are so well recognized as to their living conditions that they can be stated to be diagnostic types, and when encountered in a deposit determine the origin of the deposit. Some of the commoner types of diatoms found in the freshwater diatomites on the Pacific Coast are: Cymbella lanceolata Agardh Fragilaria virescens Ralfs Encyonema prostratum Ralfs Diatoma vulgare Dory Surirella biseriata Brebison Eunotia major Ehrenberg Amphipleura pellucida Kützing Stictodiscus niagarac Ehrenberg Gomphonema geminatum Lynberg Melosira granulata Ehrenberg Epithemia turgida Kützing

Jan 1, 1942

By Henry Mulryan

Diatoms are microscopic aquatic plants of the order Bacillariaceae. They are unicellular plants with skelctons made up of amorphous opaline silica. The skeletons show highly ornate, complicated geometrical designs. Diatoms live in water virtually everywhere. They are found in clean sea water, brackish water, and fresh-water lakes and ponds. When conditions are right, diatoms propagate by subdivision in huge numbers. Alkalinity, temperature, and the presence of high concentrations of silica in the water largely control diatom life. When the diatoms die the skeletons drop to the bottom of their habitat to form oozes of varying thicknesses. Diatomites Diatomite, or diatomaceous earth, is composed essentially of the siliceous remains of the diatoms, although other organic skeletons are also present, especially in sea-water deposits where radiolaria, sponges and silico-flagellates are common. Impurities are generally carbonaceous material, fine-grained silt, volcanic ash and dust, and occasional coarse grains of sand. Diatomites are marine, brackish, or fresh-water, depending upon types of diatoms and their method of deposition. Diatoms More than 8000 species of diatoms have been named and classified. Some are definitely classified as to their habitat; some are so well recognized as to their living conditions that they can be stated to be diagnostic types, and when encountered in a deposit determine the origin of the deposit. Some of the commoner types of diatoms found in the freshwater diatomites on the Pacific Coast are: Cymbella lanceolata Agardh Fragilaria virescens Ralfs Encyonema prostratum Ralfs Diatoma vulgare Dory Surirella biseriata Brebison Eunotia major Ehrenberg Amphipleura pellucida Kützing Stictodiscus niagarac Ehrenberg Gomphonema geminatum Lynberg Melosira granulata Ehrenberg Epithemia turgida Kützing

Jan 1, 1942