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By P. Srinivasan

Corrosion is a major operational problem in amine-treating plants causing significant expenditures each year, Corrosion may become more severe when the amine plants contain process contaminants ? namely heat-stable salts. The heat-stable salts enter the plants with feed-gas streams and makeup-solution, and/or are produced within the plants by reactions of alkanolamine and available carboxylic-acid anions, This work investigated interaction corrosion effects that may exist in amine-treating plants containing a mixture of heat-stable salts, The investigation was experimentally carried out in a 5 kmol/m3 monoethanolamine (MEA) solution containing 0,20 mol/mol carbon dioxide (CO2) loading at 80°C under atmospheric pressure using carbon steel 1018, Six heat-stable salts, including formate, oxalate, bicine, acetate, thiosulfate and chloride, were tested with a series of salt combinations, Potentiodynamic Polarization, Tafel Extrapolation, and Cyclic Polarization were used for revealing corrosion behavior, determining corrosion rate, and examining the pitting tendency, respectively, Results show that thiosulfate induces the most corrosive environment when present either individually or in the form of salt mixtures.

Jan 1, 2005

By P. Arz

With a total of five basement levels, ground floor and a further six levels above grade, construction of the Kö-Galerie building, on the Königsallee, in the centre of Düsseldorf, was completed with all the difficulties which accompany property development today in the inner city. To meet the intermediate and final deadlines, ad­vanced building techniques were used. Notable among them are the top/down method for simultaneous construction upwards and downwards from an intermediate level, and the use of pre-fabricated composite columns in drilled shafts for the main load-bearing foundations as well as diaphragm walls designed as permanent structural wall of the basement.

Jan 1, 1989

By C. Gaubert, G. Bourassa

"The construction or rebuild process in the anode baking furnaces has been modeled with the software Rockwell Arena, in order to minimize the process cost and risk. The case study was focused on the sectional rebuild (""on the fly"") that needs a high coordination of the material inventory, the on-site personnel and the construction/production schedule. Multiple entities and resources were allocated for the different part of the process (in-furnace process, prefabrication, materials transportation, etc.). Logic flow charts and VBA macros were used to simulate the space utilization (including cranes utilization) and interaction with production. MS-Excel output files can show user-friendly results."

Jan 1, 2006

By J. M. Mutmansky

A number of previous publications have attempted to provide the practicing ventilation engineer with simple guidelines on the optimal velocity to be used in mine openings. Some of these velocities were meant to be used in metal mining operations and some were meant for coal mining. A careful review of these publications reveals that the optimal velocities were determined based upon assumptions that are not existent today. As a result, they are not suitable for use in a modern coal mine. This paper takes a new look at this problem and determines a statistical relationship for optimal velocity that can be applied under both current and future conditions. The analysis performed here is based upon the determination of the optimal velocity for coal mine entries under variations in power cost, mining cost differential, airway friction factor, time value of money, airway lifespan, and quantity of air carried. A total of 8400 different conditions were analyzed for optimal velocity using computer calculation of the capital and operating cost values. Using the individual values of the optimal velocity derived in the calculations, a linear regression equation was fitted to the data to relate the optimal velocity to the other six variables outlined above. This regression relationship allows the ventilation engineer to make an easy, rapid determination of the optimal velocity.

Jan 1, 1984

By Michael P. Evans

Traditionally in coal processing jigs have been used to clean the coarse coal fraction, the +3/8" or +1/4" material. Today with the advent of modern fine coal jigs in the United States, its place was moved from the coarse to the inter- mediate coal circuit, the 3/8" x 100 mesh. The most economical coarse coal circuit to build and operate is a heavy media bath circuit. The following table summarizes the cost per raw coal ton processed for a coarse coal jig circuit, and a coarse coal heavy media bath circuit. The flowsheets used to compare these two circuits are shown in Figures 1 and 2.

Jan 1, 1983

By Akira Kaneda

Mitsubishi continuous process employs an electric furnace for settling matte from slag. Electrodes are immersed into the slag layer in the slag-cleaning furnace and the temperature of the melt is maintained at a predetermined level by Joule's heat. Electrodes are immersed to the depth where the current of each electrode is kept at a set value, and they are raised or lowered automatically to compensate for the deviation from it. Because electric resistance of the bath is varied with the matte level in the furnace and the composition and temperature of the slag, the immersion depth of the electrodes is affected by them. Therefore by monitoring the immersion depth and its change with time, abnormal situations in the furnace, such a~ rise of matte level or local abnormal state of melt, can be detected. In this paper, relations between state of the furnace and electrode behavior are discussed based on the plant data, and then a new and simple monitoring method of the condition of the furnace is proposed.

Jan 1, 2001

By John L. H. Patterson

Handheld XRF has become the favorite way of measuring the content and identity of alloys in the field. This is because of the very portable nature of the instrumentation and its simple operation. However, these analyzers have been unable to determine the concentration of the light elements like Mg and Si due to the very low energy of the x-rays produced by these elements. In the past accessories such as vacuum and He flush have given some analyzers the ability to determine these light elements with modest detection limits. The introduction of the Silicon Drift Detector (SDD) into this class of instrumentation has added a new level of analysis capability to portable XRF instrumentation. X-ray fluorescence is achieved by exciting a sample with a beam of x-rays, which in recent portable equipment are generated by a small tube. This results in the emission of characteristic x-rays from the sample under test. By measuring the energy of each x-ray it is possible to determine what element generated it. By counting the number of x-rays at each energy it is possible to determine the concentration of each element. The detection limit for each element is dependent upon the number of x-rays which reach the detector. As the number of x-rays increases the detection limit will improve. One of the major factors in an x-ray reaching the detector is the energy of the x-ray. As the energy of an x-ray increases the probability of that x-ray reaching the detector increases. The energy of an x-ray is inversely proportional to the atomic number (AN) of the element generating the x-ray. For example, an iron x-ray (AN=26) is 6.40 keV while an aluminum x-ray (AN=13) is 1.49 keV. As the energy decreases, the detection of the x-ray becomes less and less probable because the x-ray may be absorbed by the windows which are part of the instrument and detector or the air in the path between the sample and detector. In SiPIN based portable XRF analyzers, the lowest element which is detected with acceptable detection limits is normally considered to be Ti (AN=22). The detection limits for 60 second measurements on typical SiPIN XRF analyzer are given in Table I. Thus, portable analyzers have not been useful for measurement of aluminum and titanium alloys as major components of these alloys are Mg (AN=12), Al (AN=13) and Si (AN=14).

Jan 1, 2009

By J. Duby

"A description is given of a series of tests performed to determine the comparative effects which dynamic and static straining, in compression, have on the physical strength properties of mild steel and an aluminum alloy. The dynamic deformation was imposed during the passage of single stress pulses of about 100 micro-second duration. These pulses were recorded with strain gauges mounted near both ends of the specimen. The resulting records were analysed using a simple wave theory; there from the dynamic stress-strain curves for the respective metals were deter-mined and were then compared with the static stress-strain relation. The respective hardnesses of the metals after deformation are evaluates by means of static stress-strain curves in compression. The micro-structures of the metals before and after deformation are also shown. It is observed that dynamic de-formation considerably modifies the rate of strain hardening. This modified hardening appears to be persistent. The observed differences in physical strength properties and micro-structures are discussed in the light of the accepted dislocation theory for metals."

Jan 1, 1960

By S. Chander

A mineral or metallurgical process uses various inputs, such as ores, energy and other raw materials, to make different products that fulfill societal needs. The processing of raw materials has changed in recent years due to the increased complexity of processing low-grade ores, intensifying competitiveness and greater constraints. For process improvement, various plant optimization and process modifications must be conducted under environmental, social, political and economic constraints. Processing research and education's success in meeting the process industry's future needs depends on an adequate balance between micro- and macro-engineering approaches. In its simplest form, macro-engineering is concerned with the "big picture," while micro-engineering requires looking at a subset of the process. So macro-engineering may be defined as an investigation of the larger or "whole" system to achieve the desired goals. And micro-engineering may be viewed as a quantitative investigation of a subset of the process, to determine cause-and-effect relationships within the subset. Two different approaches might be used in macro-engineering analysis. In one, the big picture may be viewed without a detailed knowledge of the subunits. With this approach, statistical tools are used to relate input and output parameters. Also, actual plant data or analog models might be used to obtain the desired information. The usefulness of such an approach increases with problem complexity. To attain the desired goals using the second, "model-based," approach, a detailed knowledge of the subunits is often useful and their interactions may be considered. In complex process analysis, the first of these approaches is more useful since less information is needed. However, it is also less exact and more likely to fail if there are significant changes in conditions and interactions. The second approach, on the other hand, is more exact, with greater predictive ability within the narrow subset being considered. Consequently, it is difficult and costly to conduct.

Jan 1, 1992

By Lawrence W. Aldrich

At the San Francisco meeting of the Institute last year, I presented, through the courtesy of Dr. James Douglas, some results of experiments on the roasting and leaching of concentrator tailings. After it became apparent that flotation rather than leaching was clearly the better method of handling the particular problem under consideration, before dismantling the experimental equipment, some data were secured on roasting and leaching the concentrate itself in competition with smelting. Some of the results obtained are given in the following paper and they are of particular interest at this time in view of the large quantities of flotation concentrates with their somewhat difficult smelting characteristics now being produced. A complete wet processt consists of roasting and leaching the calcines in dilute sulphuric acid produced from the roaster gases, roasting the residue with salt and leaching with dilute tower liquors (the well-known Longmaid-Henderson process) and recovering the copper, silver and gold by cementation or electrolysis or a combination of both. It is evident, however, that the residue from the first leaching, carrying about 20 per cent. of the copper and all of the silver and gold, can be smelted if preferable. In considering the application of the scheme to individual cases, it must be remembered that freight plays a large part in any reduction process wherein smelting is not conducted at the mouth of the mine, and that it is not practicable today to build small smelting plants for individual operations, The experiments may be grouped under four main heads: Roasting, leaching, chloridizing residue, and recovery of copper from solutions. The products of two concentrators were used: The Nacozari concentrates were the product of a large modern mill not using flotation, the copper mineral being largely chalcopyrite; and the Tyrone concentrates, the product of an experimental mill including flotation, the copper mineral being chiefly chalcocite. Typical analyses are given in Table 1. Fig. 1 shows screen analyses of calcines obtained by dead roasting the

Jan 1, 1917

By William L. Fink, E. H. Dix, L. A. Willey

The results of a preliminary investigation of the aluminum-iron-manganese system showed that small amounts of iron (0.10 per cent) substantially reduce the solid solubility of manganese in aluminum. This is clearly shown in the photomicrographs of three alloys, Figs. 1 to 3. Fig. 1, of an alloy containing 1.04 per cent manganese after a heat treatment at 626° C. for 45 hr., shows only solid solution. This alloy contained less than 0.008 per cent iron. Fig. 2 shows the abundance of a constituent (which undoubtedly contains aluminum, manganese and iron) in an alloy containing 1.00 per cent manganese and 0.11 percent iron after a solution heat treatment at 625" C. for 63 hr. For comparison, Fig. 3 is included to show the relatively small amount of constituent (FeA13) in a similarly heat-treated aluminum alloy containing 0.10 per cent iron but no manganese. These data necessitated a reconsideration of the binary aluminum-manganese diagram that was previously presented,' inasmuch as the alloys used in that work contained from 0.02 to 0.05 per cent iron. This paper is the fourteenth of a series from the Research Laboratories of the Aluminum Company of America reporting the results of investigations of equilibrium relations in aluminum-base alloys of high purity. The purpose was to determine the phase relations in aluminum with aluminum-manganese alloys containing the smallest amount of iron that could be realized with the purest material available at the present time (less than 0.01 per cent iron). Since the previous publication from these laboratories, five investigations of the aluminum-manganese system have been reported. Krings and Ostmannz assigned the formula MnA14 to the compound at the aluminum end of the syst,em, and found a eutectic between this compound and aluminum at 649" C. and 3 per cent manganese.

Jan 1, 1933

By R. Rosenblum, J. Y. Kim, D. Shink, K. G. Stowe

"A small scale continuous flotation cell was designed and constructed at the Noranda Technology Centre to develop a mobile testing flotation circuit located next to the production circuit. This mobile small scale flotation pilot plant can easily and economically be set up at any circuit in a mill and used to evaluate and predict plant performance against a given flotation condition. The main feature of the cell, beside the provisions of automatic pulp level and feed rate control, is to provide a reduced surface to volume ratio approaching to that of an industrial machine.This paper describes the basic design and the results of various testwork carried out to date including aeration, conditioning, reagents, recirculation, flotation gas, etc. are presented in comparison with the plant production results. INTRODUCTIONStudy of the behaviour of an ore during concentration by flotation process starts, in general, with a series of tests in laboratory cells. Given the discontinuous nature of these tests, the information obtained by such a study is somewhat limited. It has long been recognized that laboratory test results are not always reproducible in pilot plant tests and subsequently, the pilot plant results do not always predict plant performance. The differences are often blamed on batch vs continuous operations, grinding media, size distribution, aging (oxidation), water quality, equipment, operator's skills, etc."

Jan 1, 1992

By R. G. Jurd

This paper considers the introduction of large-scale longwall mining into South African coal mining, instead of the conventional mechanized bord-and-plllar mining that is widely practised at present. The two methods are compared, and longwall mining is found to have the advantage in several respects in some seams. The most cogent reasons for the introduction of the longwall method In some seams are associated with safety strata control and increased labour costs.

Jan 1, 1978

By J. R. Pacheco

Paranapanema group has decided to implement the business system SAP R/3 in all companies of the group in order to replace all current applications. This project has taken nine months to be completed. This paper describes the phases of this implementation, with focus on the Plant Maintenance component. In addition, it gives an idea of the effort required to implement SAP R/3 on an organization the size of Paranapanema group.

Jan 1, 2007

By Orville R. Lyons

THE Russellton preparation plant of Republic Steel Corp., located north of Pittsburgh, Pa., prepares 395x0-in. Thick-Freeport coal by means of a 13-ft 6-in. diam Chance cone and 16 No. 7 Deister tables. The plant feed ranges between 370 and 410 tons per hr, of which approximately 31 pct is 1/4xO-in. size, and the plant reject ranges between 14 and 16 pct of the feed.

Jan 6, 1953

By G. Taylor, S. Bounds, G. Moran, M. Cross, K. Pericleous

"A variety of interacting complex phenomena takes place during the casting of metallic components. Here molten metal is poured into a mould cavity where it flows, cools, solidifies and then deforms in its solid state. As the metal cools, thermal gradients will promote thermal convection which will redistribute the heat around the component (usually from feeders or risers) towards the solidification front and mushy zone. Also, as the evolving solid regions of the cast component deform they will form gap at the cast-mould interface. This gap may change the rate of solidification in certain parts the casting, hence affecting the manner in which the cast component solidifies. Interaction between a cast component and its surrounding mould will also govern stress magnitudes in both the cast and mould - these may lead to defects such as cracks.This paper presents a multiphysics modelling approach to this complex process. Emphasis will be placed on the interacting phenomena taking place during the process and the modelling strategy used. Comparisons with plant data are also be given."

Jan 1, 1999

By G. H. Martindill

Complex chemical and physical changes occurring during carbonization result in a heterogeneous system composed of gaseous, liquid, and solid phases, whose relative proportions and chemical compositions change constantly as temperature increases. Studies in which the participating variables are isolated and controlled should be useful in formulating the mechanism of coal carbonization. The most characteristic property of a coking coal is its ability to form a plastic mass at a certain stage of the carbonization process. During this period it is believed that fluidity of the coal influences the properties of the resultant coke. This report gives results of an investigation by the Federal Bureau of Mines of the influence of the maximum fluidity attained by the charge on the physical quality of the coke or char produced. As a first approach to the problem, researchers investigated high-melting-point pitches, which are relatively simple carbonaceous materials. The plastic properties of these pitches, prepared specially for this work, varied greatly; their fluidities, as measured by the Gieseler plastometer, covered most of the fluidity range characteristic of coking coals. Blending these pitches with increasing pro-portions of fine coke progressively reduced their fluidities. Coal-pitch and coal-coke blends also were treated; their fluidities were varied by changing their blending ratios. The various blends were carbonized in a small-scale carbonizer and the resistance of the carbonized residue (char) to abrasion was determined in a small-scale tumbler test, using the Roga drum.

Jan 1, 1960

By A Hekmat, R Castro, A Casali, R Gómez

Block caving is the most economic underground methods for excavating massive orebodies, due to the high productivity and low production costs. The success of block caving operations depends on the fragmentation and draw control as large blocks decrease the equipment efficiency, inhibit the material flow and may lead to expensive secondary blasting. Even though ore handling system design, as well as overall economic results, both critically rely on secondary fragmentation, this parameter continues to be one of the least understood issues in the caving operations.This research focuses on the experimental study of secondary fragmentation, considering the impact of vertical pressures and material flow. Experiments using a load-haul-dump extraction system were conducted under laboratory conditions to quantify the influence of pressure and particle size on secondary fragmentation. Results demonstrate that increasing the vertical pressure (simulating deeper conditions) leads to higher fragmentation (smaller particle size) and greater fines generation during draw. The experimental results were applied to calibrate the developed mathematical model based on kinetic matrix. The acceptable accordance between the comminution model results and the reality showed that this method is convenient in predicting the secondary fragmentation in block caving.CITATION:Castro, R, Gómez, R, Casali, A and Hekmat, A, 2016. Experimental and comminution model framework for secondary fragmentation prediction in block caving, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 175–182 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Robert H. Carpenter

Abstract, Syngenetic uranium in pre metamorphic Idaho Springs volcanics and sediments probably, was mobilized during metamorphism (1.7 b.y.) and partly retained along unconformities. Precambrian Silver Plume intrusives (1.4 b.y.) and Pikes Peak granite (1.0 b.y.) may have mobilized uranium from the craton and. Idaho Springs metamorphics to concentrate it in cauldron sites in migmatites, pegmatites, alaskite, disseminations and greissen. Tertiary intrusives also may have upgraded uranium by anatexis, leaching and differentiation. Tertiary vein and shear zone uranium mineralization may have-been-derived from underlying magma sources, leached from Idaho Springs metamorphics and from syngenetic leaching of overlying sediments and introduced by deep hydrothermal convection systems.

Jan 1, 1979

By Gifford E. White

Explanations of the basic procedure for making earth-conductivity studies by the Eltran method have already appeared in several placeS. 1,2,3 In its essentials, this method consists of applying step functions of voltage to one pair of earth grounds and measuring the transient potential resulting at a separate pair of ground points. As previously pointed out,' the transient potential resulting from a suddenly applied steady voltage is the indicia1 transfer function of Carson1 6 which has been extensively studied in network theory. The discussion here, with one special exception, will ignore the problem of how the physical configuration of the earth affects the transient response voltage; it appears that this phase of the problem has been solved in only a few special cases having any direct bearing on the prospecting problem. Entirely distinct from the potential-theory aspect of the conductivity problem is the interesting material that can be had from studying the well-known network relations between cause and effect in linear circuits, and thus deducing criteria for the application of the several experimental methods available. To do this, only one assumption need be made about the nature of the earth. The earth is to be considered a linear conductor within the tolerance of ordinary measurements. The discussion will be restricted to collinear electrode configuration like that of Fig. I, since this is the only type of spread practical for use with driving currents that vary with time. Here one pair of grounds carries the driving current, and in line with these and external to them is a RECORDING Fair of potential probes. The problem will be to consider the relation between the different voltages appearing between the potential circuit terminals when various types of driving voltage sources are inserted in the current circuit. Suppose that the grounding points G, and G2 make good contact with the earth, and that a battery of sufficient voltage to produce one ampere of direct current is introduced into the current circuit by the closing of a switch. The potential transient response to such a voltage can be measured by taking an oscillogram at the potential Directors terminals, giving the time function that has been called A(l).4 This time function has been solved for analytically in the case of a homogeneous earth,"' and the

Jan 1, 1946