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By C. G. Dunn

Many investigations have been made concerning the nature of plastic deformation and recrystallization of metals either in the form of polycrystalline materials or in the form of single crystals. However, similar work on strip materials composed of large grains as thick as the strip and having a high degree of preferred crystal oricntation has not been carried out extensively. Such materials are ideal not only for studying changes in single crystals under conditions where neighboring grains exert their influences but also for obtaining the complete change in orientation of a grain or group of grains during the course of plastic deformation and subsequent recrystallization. It is well known that first-order twins in the form of Neumann bands may be produced during the plastic deformation of ferrite crystals, particularly silicon ferrite crystals.l--3 Furthermore, it is believed that high-stress regions exist in the vicinity of these bands4. and it has been said that these banded regions would be active in recrystallization processes.5 Evidence to that effect in silicon ferrite had already been presented with photomicrographs showing recrystallization among Neumann bands during the early stages of recrystallizati~n.5,6 Similar evidence has been published for nonferrous metals5 Merging of fine parallel deformation bands during annealing to form twin bands of ordinary appearance in alpha brass has been offered not only as evidence of an active role being played by mechanical twins but also as evidence that such twins cxisted prior to recrystalli~ation.5 Proof that such new structures are actually first-order twins, or even twins at all, must be considered inadequate except for those cases where X-ray or optical data have been obtained to confirm the necessary oricntation relationship.7,8 A. B. Greninger has obtained excellent iliustrations of annealing twins in alpha iron.9 Since his material was previously deformed by sharp hammering, a process that generally induces Neumann bands, the existence of twins following annealing might suggest that they grew from mechanical twins. In connection with transformation twins in alpha iron, Greninger reported that grains containing three twin orientations occurred rarely and none occurred with three sets of well-developed bands.9 The work at the Pittsfield Works Laboratory on silicon ferrite in the form of large-grained strip steel deformed a small amount and annealed to partially recrystallize the grains indicates that the deformation and recrystallization processes that lead to annealing twins involvc more complex processes than the formation of Neumann bands and the growth of such bands. Some groups of annealing twins are obtained which contain not only three well-developed twin structures, but also contain more than one order of twins. It is also shown, in one case, that an interrelated group of twins did not arise within one single parent grain and, furthermore, orientations of grains in the group

Jan 1, 1944

By C. G. Dunn

Many investigations have been made concerning the nature of plastic deformation and recrystallization of metals either in the form of polycrystalline materials or in the form of single crystals. However, similar work on strip materials composed of large grains as thick as the strip and having a high degree of preferred crystal oricntation has not been carried out extensively. Such materials are ideal not only for studying changes in single crystals under conditions where neighboring grains exert their influences but also for obtaining the complete change in orientation of a grain or group of grains during the course of plastic deformation and subsequent recrystallization. It is well known that first-order twins in the form of Neumann bands may be produced during the plastic deformation of ferrite crystals, particularly silicon ferrite crystals.l--3 Furthermore, it is believed that high-stress regions exist in the vicinity of these bands4. and it has been said that these banded regions would be active in recrystallization processes.5 Evidence to that effect in silicon ferrite had already been presented with photomicrographs showing recrystallization among Neumann bands during the early stages of recrystallizati~n.5,6 Similar evidence has been published for nonferrous metals5 Merging of fine parallel deformation bands during annealing to form twin bands of ordinary appearance in alpha brass has been offered not only as evidence of an active role being played by mechanical twins but also as evidence that such twins cxisted prior to recrystalli~ation.5 Proof that such new structures are actually first-order twins, or even twins at all, must be considered inadequate except for those cases where X-ray or optical data have been obtained to confirm the necessary oricntation relationship.7,8 A. B. Greninger has obtained excellent iliustrations of annealing twins in alpha iron.9 Since his material was previously deformed by sharp hammering, a process that generally induces Neumann bands, the existence of twins following annealing might suggest that they grew from mechanical twins. In connection with transformation twins in alpha iron, Greninger reported that grains containing three twin orientations occurred rarely and none occurred with three sets of well-developed bands.9 The work at the Pittsfield Works Laboratory on silicon ferrite in the form of large-grained strip steel deformed a small amount and annealed to partially recrystallize the grains indicates that the deformation and recrystallization processes that lead to annealing twins involvc more complex processes than the formation of Neumann bands and the growth of such bands. Some groups of annealing twins are obtained which contain not only three well-developed twin structures, but also contain more than one order of twins. It is also shown, in one case, that an interrelated group of twins did not arise within one single parent grain and, furthermore, orientations of grains in the group

Jan 1, 1944

By Y. S. Sun, P. Gao, Y. F. Li, J. W. Yu

"Oolitic hematite ore is one of the most refractory iron ores in the world. It is not feasible to separate iron minerals from raw ore by conventional mineral processing methods. In recent years, a new technology called coal-based reduction followed by magnetic separation has been employed to produce metallic iron powder from oolitic hematite ore effectively. In order to find the nucleation mechanism, a thermodynamic analysis of the carbothermic reduction of oolitic hematite ore was conducted by the HSC 6.0 thermochemical software. The phase transition and microstructure changes during the coal-based reduction were also investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results showed that the iron oxides in the oolitic ore were reduced to metallic iron following the route of Fe2O3–Fe3O4–FeO–Fe in reduction process. The reduction reactions preferentially occur in the high activity regions to form a higher concentration of Fe elements, and then more supersaturated Fe separated out to form new phase nuclei. Under the action of homo-aggregation and principle of minimum free energy, the iron cores continuously absorbed migratory Fe around and grew into quasi-spherical iron particles embedded in slag phase. INTRODUCTION With the rapid increase of steel industry, premium grade iron ore in China has been gradually exhausted, and its supply has become bottleneck for the development of iron and steel industry (Guo et al., 2015). Therefore, it is urgent to exploit the refractory iron ores, such as oolitic hematite ore. Oolitic hematite ore is widely distributes in France, Germany, America, Canada, Pakistan, China, and among other countries (Maynard and Van Houten, 2004; Li et al., 2011). In China, the explored reserve of oolitic hematite ore is 3.72 billion tons, which accounts for approximately 1/9 of total iron ore resources of China (Gao et al, 2016). Oolitic hematite ore possesses complex composition,"

Jan 1, 2018

By Kristineq Pankow

The August 2007 Crandall Canyon mine disaster raised national awareness of mining-induced seismicity (MIS) in Utah as well as general interest in how seismic monitoring might improve mine safety in the region. Unlike the situation in most other mining areas in the U.S., local seismographs in Utah?s Wasatch Plateau (WP) and Book Cliffs (BC) coal fields are an integral part of a modern real-time earthquake information system developed by the University of Utah Seismograph Stations (UUSS) as part of an Advanced National Seismic System. The UUSS earthquake catalog contains a continuous record of MIS at all active mine sites in the WP-BC region since 1978 (more than 18,000 seismic events = M 4.2). We describe characteristics of MIS and current seismic monitoring capabilities in the WP-BC region. We then demonstrate, using MIS from an example Utah coal mine, the ability to refine event locations with estimated absolute errors of ~200 m or less using a combination of (1) a double-difference relocation methodology and (2) ground truth information provided by mine operators. This approach enables sufficient spatial resolution to correlate MIS with mining activities, providing a useful tool to help improve mine safety.

Jan 1, 2008

By S. Downing, T. Grammatikopoulos, N. Hoffmann, C. Gunning

"Most deposits display a high degree of geological and mineralogical complexity that can affect metallurgical processing. Therefore, the proper characterization of the ore and gangue minerals requires a multi disciplinary approach combining geology, mineralogy, geochemistry and processing. However, mineralogy to a large extent informs the metallurgical process. Automated methods can be used throughout the mining chain from advanced exploration through to production.In this presentation we discuss actual case studies where automated mineralogy has been applied in a geometallurgical framework at a pre-feasibility to feasibility level. These include examples from a strongly serpentinized magmatic Ni deposit (Dumont) and a magmatic Cu-Ni deposit (Maturi). Mineral speciation and ratios, e.g., chalcopyrite, cubanite, and pentlandite/pyrrhotite are critical to model the Cu-Ni magmatic deposit. In the serpentinized Ni ore, automated mineralogy is used to speciate the Ni minerals into sulphides, alloys and refractory Ni in the silicate matrix.The mineralogical results are linked to the metallurgical test work in order to model the geometallurgical domains. These case studies will illustrate how mineral quantification and improved understanding of inherent mineralogical parameters in relation to metallurgy reduce technical risk in both exploration and flowsheet development.INTRODUCTIONGeometallurgy is a cross-discipline approach combining geology, metallurgy and mine planning (e.g., Dunham et al., 2011). It is aimed to improve the understanding of geological, mineralogical and metallurgical parameters of an ore. Informational gaps among the different disciplines are often apparent. Automated mineralogy is shown in many studies (e.g., Eppinger et al., 2013, Philander and Rozendaal, 2013) to constitute the link between geology and metallurgy. The geometallurgical approach can provide specific data to geology, mining and mineral processing development and plant operations. The scope of the automated mineralogy is to illustrate how mineral quantification can improve the understanding of inherent mineralogical parameters in relation to metallurgy, and reduce the technical risk in both exploration and flowsheet development."

Jan 1, 2016

By Harry C. Gatos, Frank J. Bachner

It was shown through high-pressure experiments that tin loss by volatilizatim is necessary for the degrada-tion of the superconducting transition temperature of Nb,Sn associated with high-temperature annealing. Crystallochemical analysis of the degraded Nb3Sn showed that it constitutes a new phase with ordered niobium-site vacancies, created by the migration of niobium atoms to vaccnt tin sites. This new phase was found to form when 4 pct Nb-site vacancies were present. It has a transition temperature of 6'K and a lattice parameter of 5.283A. A similar degradation effect was observed in Nb,Al. Its superconducting transition temperature dropped from 16.5" to 8" K following a high-temperature annealing. The superconducting temperature degradation in these 0-tungsten structure compounds is attributed to the disruption of the interchain d bonding by the periodic interruption of the niobium atom chains. By annealing the degraded Nb, Sn at 1000 C in nitrogen its normal superconducting behavior is restored most likely due to the incorporation of nitrogen atoms causing the elimination of the ordered vacancies. HANAK et al.' have observed low superconducting transition-temperature values (T, - 9"K) in some NbsSn samples deposited from the vapor phase. They attributed such low T, values to disorder in the 0-tung-sten structure. Much lower T values (down to 5.6"K) were reported by Reed et al.zC for NbsSn samples annealed at high temperatures. These authors also attributed this degradation effect to disorder (random occupation of the A and B sites by niobium and tin) but pointed out that such disorder could be brought about (by high-temperature treatment) only in samples containing niobium in excess of the stoichiometric composition NbsSn. Both groups reported that the normal superconductivity behavior could be rever-sibly restored by appropriate heat treatment. Courtney et al., also found that degradation in NbsSn requires excess niobium brought about by the loss of tin during the treatment. However, these investigators proposed that the degradation is due to niobium-site vacancies resulting from the migration of the niobium atoms to the vacated tin atom sites. They did not consider the reversibility of the effect. The present study attempts to establish the nature of the above degradation phenomenon. EXPERIMENTAL PROCEDURES All compounds prepared for this investigation were made from the powders or filings of the elements which were intimately mixed, cold-pressed into a cylindrical pellet at approximately 50,000 lb per sq in., and then submitted to the desired heat treatment. The samples annealed under high pressure were placed in a MgO sample container which was mounted in a pyrophyllite tetrahedron designed for a tetra-hedral-anvil press. Details of the experimental arrangement are given elsewhere. This setup allowed heating at 1800°C or above under pressures in excess of 30kbars for 3 hr. The samples annealed in a vacuum were prepared in a high-temperature vacuum furnace which could reach temperatures up to 2400°C under a pressure of 2 x lo-' Torr. For annealing in a reactive atmosphere, a quartz tube was placed in a clamshell furnace and the desired gas ambient passed through the tube. Lattice parameters were determined using a Debye-Scherer 114.6-mm camera. Cohen's method, programmed for the IBM 7094 computer, was used to calculate the lattice parameter from the measured d spacings. X-ray integrated intensity measurements were made on several samples. These samples were ground to -400 mesh and the powder mixed with a solution of collodion in amyl acetate. The mixture was poured into a depression milled in a bakelite disc. When the mixture dried, the surface of the disc was ground flat leaving a diffraction surface defined by the face of the disc. The disc was mounted in a Philips rotating specimen holder which allowed the rotation of the sample in the plane of the diffraction surface and the integrated intensity measured using a scintillation counter and a pulse-height analysis sys-tem. The superconducting transition temperatures were determined by means of self-inductance techniques.' EXPERIMENTAL RESULTS AND DISCUSSION The Role of Tin Loss in the Degradation of Super-conductivity. The loss of tin during high-temperature annealing can be effectively suppressed by annealing under high hydrostatic pressures. Accordingly, a series of experiments were performed under pressures of approximately 30kbars. This pressure was the minimum under which high-temperature experiments could be safely performed in the particular pressure apparatus employed. Experiments were also designed to test high-pressure effects on the superconductivity behavior of NbJSn. The results of the high-pressure annealing experi-ments are summarized in Table I. All samples were prepared as described earlier. They were reacted and homogenized at 1000°C for 24 hr under argon at-

Jan 1, 1967

By Tony Walsh

Australian Stock Exchange Limited (ASX) -ASX is ranked 9th in the Morgan Stanley Capital International (MSCI) Index – only 2.02% of that Index. -1520 companies – 400+ mining & mining exploration. -Over 50% of Australians own shares in ASX listed co.s -Disclosure standards play a vital part in providing investors with confidence, thereby building depth and liquidity in the market.

Jan 1, 2003

By P. Mottahed, E. K. S. Passaris, J. Q. Ran

"The jointed roof of underground mine openings in stratified rock can be analyzed in terms of a voussoir beam. Because of the essential indeterminacy of the structure, previous attempts of theoretically solving the equilibrium equation have been unsuccessful. Numericalanalysisby the finite element method taking the geometrical and joint non-linearity into consideration combined with the experimental method has been adopted to study the performance isopara of the voussoir beam. Deformation and failure mechanism is analyzed in relation to the failure modes. Equations are proposed to estimate the elastic buckling strength and the crushing strength of the voussoir beam and to verify the failure mode of shear sliding. For application of the mechanism of the voussoir beam in mining operations, methods are described to predict the stability of a jointed roof and to design the dimensions of mining openings.IntroductionThe roof stability of an underground mine opening has direct effects on the selection of support methods, opening dimensions and, more importantly, on the safety of mining personnel. The prediction of the roof stability can be of importance in the design of a mining method and in mining operations. The jointed roof of mine openings in stratified rock can be stable under transverse load depending on the roof geometry and properties of the roof material and joints. The stability of this type of roof can be analyzed in terms of a voussoir beam which was introduced by Evans (1941) to study the strength of underground strata. Brady and Brown (1985) analyzed the voussoir beam and suggested that the mechanism of the voussoir beam could be used in the design of underground mine openings in stratified rock instead of the traditional continuous beam theory."

Jan 1, 1993

By D. F. Howarth, F. F. Roxborough

Some important aspects of the design of rock-cutting systems remain relatively unexplored. Two areas of practical significance in this context form the subject of this paper: cutting in jointed or fissured rock, and groove-deepening. A series of controlled laboratory experiments on the performance of disc cutters in jointed rock showed that the spatial and geometrical configuration of jointed rock masses needs to be taken into consideration in the design of mechanized rock excavating systems. One series of experiments showed that, under favourable geometric conditions, the energy required to cut in a jointed rock mass is at least half that required to cut otherwise intact rock. Groove-deepening-the progressive deepening of a groove by successive passes of a cutter-is a potential operational feature with most mechanized rock-excavating systems. Laboratory experiments revealed an important fundamental cycle of events associated with disc cutters when progressively deepening a groove in intact rock. Furthermore, in contrast to pick cutting, groove-deepening by discs is shown to be an efficient operation and one that should not necessarily be avoided. This can be directly attributed to increased interaction between the disc cutters as the result of an increase in magnitude of the lateral forces generated as a groove is deepened.

Jan 1, 1982

By G. B. Misra

Heat transfer in partially wet mine airways has been the subject of study for quite some time. Of the available models some are quite empirical while some involve highly complicated computation. Models developed by Amano, Mizuta and Hiramatsu and Banerjee and Chernyak as well as that modified by Misra were evaluated for prediction of the rise in temperature and humidity (mixing ratio ) of partially wet mine airways at four different levels in the Mosaboni Mine of Hindustan Copper Ltd. Measurements of barometric pressure, virgin-rock temperature and changes in dry- and wet-bulb temperatures along a certain length of airway were made. The rise in dry-bulb temperature and mixing ratio of air over the sections were calculated using the three models. The study reveals that calculated values of temperature and moisture content agree within possible rage of experimental error with all the three models in case of three levels with low wetness factor, but the agreement was poor for the relatively more wet airway on the 30th level. Errors in the estimation of fw to the tune of 0.025 can lead to fair error up to 0.94 K in the estimated temperature while alternative ways of estimating the heat transfer coefficient [] can introduce errors up to 1.45 K.

Jan 1, 1987

By A. E. Gorum, I. Cornet

Fatigrle of ionic crystals has been studied primarily in magnesinm oxide. under cyclic stress dislocations move irrreversibly; they multiply; slip bands form and grow; cracks mucleate and propagnte, and failure occurs. The use of ionic crystals such as MgO is advantageorus in such investigations because they are optically transparent. Individual dislocation Intersections with {100} surfaces may be observed with a standard microscope, using etch-pit techniques. Slip, deformation, crack .formation, and fracture in MgO crystals under cyclic stress are compared with cotrresponditzg processes in metals. ThE effect of cyclic loading in metals has been studied for many years. The appearance of slip lines is readily observed and the ensuing fracture may also be seen. From these observations it is possible to predict the behavior of a material and make an educated guess as to what is happening internally, but the actual changes taking place within the structure are not readily apparent. If one could obtain a material in which the individual glide components could be observed, it would be invaluable in determining the actual slip distribution resulting from cyclic loading as well as the distribution of slip in the neighborhood of a growing crack. Such a material is magnesium oxide. Dislocation arrays may be observed by means of etch pits

Jan 1, 1961

By Woodcock JT

This paper reviews the chemistry of flotation pulps with the aim of gaining a better understanding of the effect of chemical environment in flotation and ap- plying the knowledge to improving the con- trol of reagent additions. Theories of flotation are considered briefly, but they are only of limited help in specifying an appropriate chemical environment and in establishing control techniques. The chemical nature of flotation pulps is reviewed. Four distinct phases are present - solids, an aqueous liquor con- taining many dissolved reactive sub- stances, organic liquids, and gases. All of these vary in many ways and interact with each other. It has now been estab- lished that there are many previously- unsuspected materials present in plant pulps that can or might affect flotation. Concentration profiles of selected para- meters in operating plants are given to show some typical changes that occur. Recent advances in collector chemistry, especially that of xanthate and related species, are reviewed. Modes of decompo- sition and/or formation in pulps of xan- thate, dixanthogen, perxanthate, xanthyl thiosulphate, and monothiocarbonate are reviewed, and their W absorption spectra are compared. Some relevant information on dithiophosphates, mercaptobenzothia- zole, and thionocarbamate is summarized, and some speculative comments are made about reactions of these collectors.

Jan 1, 1984

By Ishijima Y, Goto T

Displacement Discontinuity Method (DDM), which was originally developed by Crouch,S.L., is a powerful tool to calculate mechanical disturbances due to tabular excavations. Three topics on DDM applications to strata control problems in Japanese deep coal mines are described. First, is numerical simulation of microseismicity induced by longwall mining in Horonai Coal Mine. Microseismicity in the mine had been monitored by a mine-wide seismic ar- ray. Location of microseismic events and in- tensity of seismicity were well simulated. In the simulation procedure based on DDM, first, zones where a failure condition is satisfied by the advance of mining are detected. Then, the seismic moments, which indicate the inten- sity of seismicity, at the failure zones are evaluated. Second, is prediction of the shaft damage due to mining in Sumitomo Akabira Colliery. In this mine, the limit angle of the shaft pillar was changed from 600 to 800 to increase the amount of minable coal volume without increas- ing mining depth. Displacement of the shaft axis has been measured to assess the damage due to mining around the shaft pillar. In the calculation based on DDM, a fault intersecting the shaft and the ground surface are con- sidered. Observed and predicted displacement of the shaft axis agreed well.

Jan 1, 1992

By W. B. Xie

The hardening behaviour and microstructure evolution of Cu-30Ni-30Mn alloys aged at 350 °C has been investigated utilizing optical microscope, scanning electron microscope, transmission electron microscopy and Vickers hardness tester. The results show that the discontinuous precipitation of NiMn phase results in a remarkably hardening effect in Cu-30Ni-30Mn alloy during aging at 350 °C. The maximum hardness (~494HV) is attained in the sample after aged for 48 h. The NiMn precipitates are ordered and have a face-centered tetragonal structure. The coherent orientation relationship between the NiMn precipitates and Cu matrix is (220)Matrix // (220)P, [1-1-2]Matrix // [1-1-2]P. In addition, there is a linear relationship between hardness and volume fraction of the discontinuous precipitation, which indicates that the hardness increment of Cu-Ni-Mn alloys aged at 350 °C is attributed to the microstructure characteristics of discontinuous precipitation. The high strength of discontinuous precipitation colony is caused by the formation of nanoscale NiMn precipitates with a lamellar structure in discontinuous precipitation. INTRODUCTION Cu-Ni-Mn alloys are attractive candidates for oil drilling, aerospace and energy applications due to their high elasticity, high strength and excellent corrosion resistance (Sun et al., 2009; Liu, Yang, Xia, Jiang, & Gui, 2016). The high strength of the Cu-Ni-Mn alloys is mainly attributed to the precipitation of NiMn phase (Shapiro, Tyler, & Lanam, 1974; Xie et al., 2015). The uniformly dispersed nanoprecipitates formed by continuous precipitation can impede dislocation movement, and thereby lead to a significant improvement in strength of traditional precipitation-strengthened alloys. However, it is reported that there are two precipitation types observed in Cu-Ni-Mn alloys, namely, continuous precipitation and discontinuous precipitation (Shapiro et al., 1974). The discontinuous cellular colony with a lamellar structure nucleates at grain boundaries, and progressively grows inward the grain on the process of discontinuous precipitation (Ng, Bettles, & Muddle, 2011). It is found that the discontinuous precipitation can occur in many Cu-based alloys, such as Cu-Ni- Mn alloy (Shapiro et al., 1974), Cu-Be alloy (Monzen, Hasegawa, & Watanabe, 2010) and Cu-Ni-Sn alloy (Zhao, & Notis, 1998). Many studies consider that the discontinuous precipitation results in a detrimental effect on hardness and strength, and the discontinuous precipitation occurring during aging treatment should be suppressed (Markandeya, Nagarjuna, & Sarma, 2004; Semboshi, Sato, Iwase, & Takasugi, 2016). The mechanical properties can also be improved by discontinuous precipitation in AZ91 magnesium alloy (Tamura, Kida, Suzuki, & Soda, 2009) and AM30 magnesium alloy (Saikawa et al., 2012). Jun (2017) found that the reduced interlamellar spacing of precipitate fibers in discontinuous cellular colony leads to a significant increase in hardness. Indeed, the strengthening contribution of discontinuous precipitation is similar to that of continuous precipitation in Cu-20Ni-20Mn alloy. Discontinuous precipitation of NiMn phase can provide a significant strengthening effect in Cu-Ni-Mn alloys.

Jan 1, 2019

By Susan M. Moore

According to the Mine Safety and Health Administration (MSHA) injury database, 227 knee injuries were reported in underground coal mining in 2007 [ 1]. Low-seam coal mines are those with extremely low working heights (<42?). Gallagher et. al [2] found that the average cost per knee injury in low-seam coal operations was $13,121.29. Thus, it can be estimated that the financial burden of knee injuries was nearly three million dollars in 2007. Pressure applied to the knee while kneeling and crawling is likely a risk factor. Typically, mine workers utilize kneepads to better distribute the pressures at the knee; however, their ability to reduce the stresses at the knee is unknown. The objective of this study was to determine the pressure applied to the knee during static postures used in low-seam mining while not wearing kneepads and while wearing two kneepads commonly used in the industry (one articulated and one non-articulated).

Jan 1, 2009

By F. Keller, E. H. Dix, R. W. Graham

Aluminum alloys containing relatively small amounts of magnesium and silicon are of commercial interest because they are readily workable in the annealed form and may be hardened and strengthened by suitable heat treatment. An intermediate temper can be produced in these alloys by quenching after a Solution heat treatment and the alloy in this condition can be formed easily. Artificial aging is required to obtain the maximum mechanical properties but this aging does not cause distortion nor require elaborate heat-treating equipment. The hardening of the alloys after quenching is attributable in part to the retention of the compound Mg²Si in solid solution, while the maximum hardness obtained by subsequent artificial aging is attributed to the fact that the solid solubility of the compound Mg²Si in aluminum decreases with decreasing temperature. Considering the importance of aluminum alloys susceptible to heat treatment, it is surprising how few fundamental investigations have been carried out on the aluminum-magnesium silicide alloys. This paper deals principally with the solid solubility relations of the compound Mg2Si in aluminum and is the sixth paper of a series1 from the laboratories of the Aluminum Co. of America reporting the results of investigations of equilibrium relations in aluminum-base alloys made from high-purity aluminum."

Jan 1, 1931

By P. S. Miller, S. H. Ash

EXTENSIVE and diversified resources justify large populations and great industries. To carry on the business of commerce and meet the demands of large populations, the utilization of tunnels in some form for transportation purposes constitutes an important link in modern civilization. The driving of tunnels has been appropriated by the tunneling branch of the heavy-construction industry, and the progressive steps taken by modern tunnel builders were not even dreamed of 50 years ago. Great strides have been made toward more rapid progress in tunneling in the United States during the past 10 years. Tunneling consists of a definite cycle of operations developed from ideas that are crystallized and translated into action programs through various engineering phases that begin with the first preliminary survey and do not end until the job is completed. Once the line of the bore is established and a time set for the completion of the work, the face must advance according to estimates prepared before the work commences. This schedule must be followed in regular sequence from the moment the drills start against a new face of rock until they are ready again to drill the succeeding face, constituting a round.1 Mining is largely tunneling carried on under conditions often more inherently hazardous than actual tunnel construction, but for various reasons1 tunneling is more hazardous than mining in any branch of the mineral industry, On the other hand, obstacles are sometimes encountered in heavy-construction tunneling projects that when met in mining enterprises do not offer comparable tasks to avoid or overcome them. One of these is the existence of water under high pressures. In mining enterprises, various alternatives offer a solution in driving a tunnel, even to the extent of its discontinuance or the abandonment of the mine, but a "construction" tunnel usually must go forward because some important project depends largely if not entirely upon it. This paper describes an unusual method of driving a water-supply tunnel through rock carrying water under pressures and conditions that did not permit the use of ordinary tunneling methods. THE DELAWARE AQUEDUCT The new Delaware aqueduct is a Manhattan project of some magnitude; when completed, it will contain what probably will be, for some time to come, the longest tunnel in the world. Various features in its construction are currently described in the trade journals of the construction industry, and informative engineering details are given in the Delaware Water Supply News, published twice a month by the Board of Water Supply of the City of New York. Work was begun on this project on March 24, 1937. The tunnel will convey water from reservoirs at the headwaters of the Delaware River to the City of New York.

Jan 1, 1942

The problems associated with the processing of the Tilden ore are very much representative of the problems encountered in plants processing fine grained magnetic and nonmagnetic iron ores. I would like to comment on some of the problems mentioned in Dr. Nummela&apos;spaper and add to his list of research opportunities in the processing of iron ores. Grinding, the most important step in the processing of fine grained iron ores, is synonymous with liberation. One grinds to separate discrete grains of minerals from the gangue. By convention- al grinding in tumbling mills, mostly random size reduction is achieved with relatively little preferential liberation of minerals. Not only are discrete particles broken that should not be broken, but damage is done to the mineral surfaces. The combination of over- grinding and surface damage shows up in lower recovery figures and higher grinding costs. What is obviously needed is a better comminution process that is more discriminating and that would permit liberating mineral particles at the coarsest possible size with a minimum production of fines. Laboratory attempts at such preferential grinding have been quite successful, but technological difficulties have unfortunately prevented its use. Impact grinding is a good example of a new comminution process that has not been accepted because of equipment problems. Either these problems have to be solved or new comminution systems have to be developed to reduce grinding costs and improve liberation. In his paper Dr. Nummela mentions the change in the primary mill throughput that occurs during the winter months. Seasonal changes in the operation of the grinding circuit and other unit operations have been observed in many plants, and many explanations for this phenomenon have been advanced. The fact is that we do not fully

Jan 1, 1979

By Wenhua Wan, Jan M. Mutmansky

Many concerns have been expressed worldwide regarding the use of diesel equipment in underground mines due to the potential health risks associated with diesel particulate matter (DPM). In assessing the risk to the health of miners and designing control strategies for DPM, it is important to know the concentration of DPM in the working areas of a mine. In some mines, significant stratification occurs due to the characteristics of the diesel exhaust, affecting exposure and the ability to measure DPM concentrations accurately. This study outlines some of the concentration profile data obtained during sampling at three mines where diesels were employed. Mine #1 (a gold mine) employed large openings in which a diesel-powered roof bolter was used. Mines #2 and #3 are both room-and-pillar operations with varying conditions. Mine #2 is an experimental mine where two stationary diesels were utilized for sampling purposes, while Mine #3 is a traditional evaporite operation using two mobile diesel vehicles for section haulage. These field studies indicated that some level of stratification occurred in all the mines, but the stratification was not as pronounced in the case of Mine #2 due to the complex pattern of exhaust emissions generated by the vehicles. The stratification seemed to depend on the distance from the vehicle, the mine air velocity, whether the vehicles were moving or stationary, and whether the exhaust was diluted by equipment design features. The concentration of DPM was generally higher at samplers located near the roof and lower at samplers located near the floor. However, this was not found in all cases. This paper provides conclusions on how knowledge of stratification patterns can be utilized in sampling and control of DPM in mine atmospheres.

Jan 1, 1997

By Klaus Schwerdtfeger

The rate of formation of silicon monoxide from silica spheres has been measured at 1500°C in H2, H2-H2O, H2-He, H2-Ar, and CO-CO2 gas mixtures. Indications are that in the hydrogen-containing gases the reaction rate is mainly determined by convective diffz~sion. In the CO-CO2 mixtures the rate approches a constant value which is independent of sphere diometer (and gas velocity). This suggests that a surface reaction becomes rate controlling in CO-CO2 gas. WHENEVER silica is exposed at elevated temperature to a strongly reducing atmosphere there occurs, inevitably, a volatilization of silica by the formation of gaseous silicon monoxide. Because of the importance of this reaction in metallurgical processes and laboratory experiments, its kinetics were studied in the present work. EXPERIMENTAL The spheres made of vitreous silica were suspended by a molybdenum wire in the hot zone of a gas-tight high-purity recrystallized alumina furnace tube of 3.1 cm internal diam and 100 cm length. Molybdenum wire resistance heating was used. A purified H2, H2-H2O, H2-He, H2-Ar, or CO-CO2 gas mixture was passed through the tube, from top to bottom. The amount of silicon monoxide formed was determined by weighing the silica balls before and after the experiments. The silica balls were made from commercially available translucent fused quartz glass. In experiments with hydrogen-containing gases the silica stayed vitreous during the experiment, whereas in experiments with CO-CO2 mixtures, which were performed over longer times, the balls were always crystallized to cristobalite (as determined by X-ray examination) at the surface. Constant-pressure head capillary flowmeters were used to control the composition of H2-He, H2-Ar, and CO-CO2 gas mixtures. The oxygen and water vapor were removed from the gases containing hydrogen by passage through columns containing platinized asbestos (450°C) and an-hydrone. The CO was purified from O2 and CO2 by passing it through activated copper (200°C) and through ascarite. The H2-H2O gas mixtures were prepared by passing purified Hz through a mixture of oxalic acid dihydrate and anhydrous oxalic acid held at a constant temperature in a water bath. The equilibrium water vapor pressures of oxalic acid dihydrate-anhydrous oxalic acid mixtures were taken from the available data.1 The furnace system was checked for sufficient gas tightness at regular intervals. As an additional check, the H2O and CO2 contents were measured in the exit gas and were found to agree closely with the metered contents when H2-H2O or CO-CO2 mixtures were used. When purified H2 was used, H2O pressures found in the exit gas were always below 0.1 mm Hg. These contents originate either from an incomplete reoxidation of silicon monoxide in the cold part of the furnace or from small leaks which cannot be avoided. If the latter is the case, such small uncontrolled H2O contents decrease the partial pressure of SiO in equilibrium with SiO2 by less than about 7 pct, which is considered small in comparison to other experimental uncertainties. The temperature of the furnace was controlled automatically in the usual manner. The reported temperature was measured with a Pl-Pt/l0pct Rh thermocouple and was accurate to ± 5°C. TRANSPORT-CONTROL LED RATE OF REDUCTION The gaseous convective diffusion from the surface of a sphere can be predicted from the semiempirical relationship obtained by Ranz and Marshall2 in a study of the evaporation of water and benzene drops in air. The following equation applies:

Jan 1, 1967