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By Charles H. Eldridge, Robert J. Anderson

When a metal or alloy is poured into a mold, internal stresses are set up by the cont,raction in volume on passing from the liquid state at the temperature of pouring to the solid state at the ordinary temperature. It is assumed by the writers that all castings are internally stressed. That any casting is internally stressed is shown by its warping or distortion on maturing at the ordinary temperature, by warping or cracking on heating, or by cracking or distortion on machining. In the investigation made by the writers, the internal stresses in cast non-ferrous alloys were studied with a view to examining the effects of heat treatment (i.e., simple anneal) on the release of such stresses. Data have been obtained that show quantitatively that internal stresses can be removed by appropriate heat treatment. The investigation was limited to a study of the effect of heat treatment on stress release in cast rings of the 87:7:5:1 copper-tin-zinc-lead alloy. The writers are indebted to E. G. Fahlman for the method used for inducing stress in cast rings; to M. E. Boyd for microscopic examination and for other aid; and to G. B. Dalrymple for the chemical analyses. General Information While casting stresses have been discussed considerably, they have usually been treated in a general way, and so far as the writers know no measurements of the magnitude of internal stresses in castings have been reported. It has been suggested by many investigators, particularly in the case of steel castings, that castings are internally stressed, and that these stresses can be removed by annealing. In a casting, the internal

Jan 1, 1923

By Robert J. Anderson, Charles H. Eldridge

When a metal or alloy is poured into a mold, internal stresses are set up by the cont,raction in volume on passing from the liquid state at the temperature of pouring to the solid state at the ordinary temperature. It is assumed by the writers that all castings are internally stressed. That any casting is internally stressed is shown by its warping or distortion on maturing at the ordinary temperature, by warping or cracking on heating, or by cracking or distortion on machining. In the investigation made by the writers, the internal stresses in cast non-ferrous alloys were studied with a view to examining the effects of heat treatment (i.e., simple anneal) on the release of such stresses. Data have been obtained that show quantitatively that internal stresses can be removed by appropriate heat treatment. The investigation was limited to a study of the effect of heat treatment on stress release in cast rings of the 87:7:5:1 copper-tin-zinc-lead alloy. The writers are indebted to E. G. Fahlman for the method used for inducing stress in cast rings; to M. E. Boyd for microscopic examination and for other aid; and to G. B. Dalrymple for the chemical analyses. General Information While casting stresses have been discussed considerably, they have usually been treated in a general way, and so far as the writers know no measurements of the magnitude of internal stresses in castings have been reported. It has been suggested by many investigators, particularly in the case of steel castings, that castings are internally stressed, and that these stresses can be removed by annealing. In a casting, the internal

Jan 1, 1923

By G. W. Jones

[The determination of the ignition tcqornturc ol" dict:iyl cther and othylene in air ma o;GrT;en rir..ic'r. is dcscribed In thin report J'IF.R mqdo primarily for comparison rritll sinilnr d~ton:in:~tions of ot; cr co~~o~imS-r, in the same apparatus and using the r?.:?.r.~o 1a.borntorg t cchzllique The investigation was conducted at the 2ittsbur;;h Experiment Station of the United States wcau 02 hii2cs vritEl tl~c cooperation of licrclc & Co., Inc.]

Jan 1, 1935

By N Mangadoddy, P Jampana, S Diddi

The study of air-core dynamics in hydrocyclone operation is essential for predicting separation efficiency in mineral processing. Electrical resistance tomography (ERT) allows non-invasive measurements of hydrocyclone internal flow dynamics. Existing regularisation methods such as Gauss-Newton and TV norms rely on optimisation techniques which have very high computational cost for very fine meshes. In contrast, the monotonicity method has much lower computational cost as it does not solve such minimisation problems. In this paper, results from the monotonicity method, Gauss-Newton (GN) (Tikhonov) and Total-Variation (TV) norm-based minimisation methods for estimating the air-core diameter in hydrocyclones are compared. We study these methods on the laboratory hydrocyclone experimental two-phase flow data. The results obtained are validated against High-speed video (HSV) imaging and Computational Fluid Dynamics (CFD) results. The results on different mesh sizes, in particular for very fine meshes with the number of cells ranging from 30 000 to above 100 000 are also investigated. The data used in this study is obtained from ITS Z8000 ERT system. This system does not measure the voltages on the current carrying electrodes. Since these voltage values are required for the monotonicity method, we implement an interpolation method to compute them. The results show that the monotonicity method provides a closer approximation of the interface between air and the water phases.

Aug 24, 2022

By Guo Chang Jiang

In order to improve the IIAZ toughness of X-60 pipe steel, the intragranular ferrite plate (IFP) technology was used. The characteristics of IFP is claimed to be much fine ferrite plates appear inside the original austenite grains. By means of suitable Re, Zr, Ti additions in a bath with a higher initial oxygen potential, a good control of the peak temperature and the cooling rate during welding simulation, one can get a %IFP in volume over 50%, and the toughness gets up from 55 J to 160 J. It was found that the inclusions most effective in nucleating IFP are some deformable complex silicates which either entrap Re, Zr, Ti oxides or contain these elements. The greater the number of the evenly distributed and effectively nucleating inclusions, the more the %IFP in volume, and the finer the microstructure of the HAZ, so the better the relevant toughness. Generally, these silicates bahave as fine spheres along a line. The present authors revealed that these fine spheres result from the remelting of the shuttle- like silicates due to heating in the process of welding simulation. These silicates used to get a higher sulphur capacity, so MnS deposits might be observed on the periphery of the silicates. IFP was proved to be directly rooted in the [Mn] depleting zone which locates beside MnS deposits.

Jan 1, 1997

By F. S. Hoseinian, K. Filho, D. Deglon, T. Souza, M. Safari

"This paper investigates the reverse flotation of hematite in three laboratory flotation cells with very different contacting environments. The main objectives are to investigate the recovery of coarse quartz by flotation and fine hematite by entrainment. The laboratory flotation cells used were the mechanical, oscillating grid and pneumatic cells. The effect of froth height and solid concentration were investigated in the mechanical and pneumatic cells. The effect of impeller speed and energy input were investigated in the mechanical and oscillating grid cells. Froth height results show that coarse quartz particle recovery decreases almost linearly with increasing froth height due to increased detachment of coarse quartz particles in the froth. Fine hematite particle recovery also decreases almost linearly with increasing froth height due to decreased water recovery and associated entrainment. Agitation/energy input results show that coarse quartz particle recovery increases with increasing impeller speed to an optimum, after which this decreases dramatically. The increase is due to improved gas dispersion, generation of smaller bubbles and increased bubble-particle collision and attachment. The decrease is due to significantly increased bubble-particle detachment at higher impeller speeds. The recovery of coarse quartz particles in the OGC is higher than that in the mechanical cell with an optimum at a much lower energy input. Solids concentration results show that both mass recovery and water recovery increase with increasing solid concentrations. The pneumatic cell achieves higher mass recoveries and lower water recoveries than those in the mechanical cell at equivalent solids concentrations and operating conditions. INTRODUCTIONFlotation is a selective process for separating different minerals from each other. The flotation separation efficiency depends on the recoveries of the mineral species by both true flotation and entrainment (Neethling and Cilliers 2009; Wang et al. 2015). Both chemical variables and hydrodynamic conditions within the flotation cell affect the recovery and selectivity of the flotation process. Cationic reverse flotation of hematite is a common method for selective separation of quartz from iron ores to produce pellet feed. The presence of coarse quartz particles in the tailings and fine hematite particles in the concentrate are two major challenges in the reverse flotation of hematite (Vieira and Peres 2007)."

Jan 1, 2018

The La Colosa, Colombia porphyry gold deposit is currently in the pre-feasibility stage. This large deposit has many types of gold mineralization: native gold, electrum, and tellurides. These variations in the gold mineralization lead to variability in the gold recovery. The final process flowsheet may include gravity concentration with cyanide leaching. Metallurgical testwork is utilized to identify the zones of ore that may be problematic to recover. To help select the samples that represent the fluctuating variability zones, geometallurgical models are constructed using mineralogy and geology data. These zones are then wireframed and compared to the geological and structural models for spatial correlation. Samples for the variability testwork will be selected from these different zones to identify and analyse the effect the different gold mineralization types have on the recovery. By using geometallurgy to aid in the sample selection for metallurgical testwork, the variability in the ore body can be understood and constrained to aid in process optimization.

Feb 27, 2013

By Manuel Sanchez, Marcial Medina, Matt Hurley, Hugo Granados, Pramod Kumar, Raj Rajamani, Jose A. Delgadillo

"Large-diameter ball mills have traditionally used steel liners—steel being a highly durable material that can be shaped into any desired geometry, among which the double-wave has been the preferred design. Such a design produces a purely cascading charge motion, which is ideal for the shearing action needed to produce a finer product. Today, however, rubber liners, which have been in existence for over forty years, are now preferred over traditional steel, largely because they weigh less and are easier to maintain. In this paper, we show the operating data from the Hudbay Minerals’ Constancia Mine, wherein the liners on a 26-by-40-foot mill were changed from conventional steel liners to PolyStl™ liners. It is then shown that this change reduced the amount of energy consumed whilst being able to maintain previous grind and throughput levels. The design is verified via discrete element simulations.IntroductionThe Constancia Mine (“Our Business: Peru,” 2016) is located in the southeastern Andes of Peru, at an elevation of approximately 4,200 m. It can be accessed via the CU-126 road, about 95 km from the town of Espinar in Espinar Province. The mine also contains both the Constancia and Pampacancha deposits in the Province of Chumbivilcas. Hudbay Minerals, Inc. acquired the mine in 2011, through the purchase of Norsemont Mining, Inc. and currently retains sole ownership of the property. Production of the Constancia Mine began in 2014, with commercial production levels being achieved in April 2015.The Constancia and Pampacancha deposits primarily include hypogene, supergene, and skarn ores. The Mine’s main products, however, are copper concentrate, with silver contents, and molybdenum concentrate. These mineral reserves are expected to last approximately 22 years. Constancia’s open-pit mine supplies a processing plant that is designed for 81,900 metric tons per day of throughput. Average annual copper production is estimated to be 82,000 mT (contained metal in concentrate). Actual plant production can be found in Table 1."

Jan 1, 2017

By Kent Phillips, Meredith Scaggs-Witte, Emily Sarver, Cigden Keles

"After nearly four decades of decline, the prevalence of coal workers’ pneumoconiosis (CWP, or black lung) in the United States has been on the rise since the mid-1990s (Laney et al., 2014; Laney et al., 2010; Suarthana et al., 2011; Pollock et al., 2010; Antao et al., 2005; Blackley et al., 2016). Particularly alarming is the number of cases of rapidly progressive disease such as progressive massive fibrosis (PMF) (Pollock et al., 2010; Antao et al., 2005; Blackley et al., 2016; Laney et al., 2017). A recent study by Laney et al. (2017) observed 192 U.S. coal miners participating in the Coal Workers’ Health Surveillance Program (CWHSP) who had been diagnosed with PMF since 2000. Of the 163 (85 percent) that had a normal radiograph on file to use as a baseline, 27 (17 percent) of these individuals had progressed from a normal radiograph to PMF diagnosis in less than 10 years. Moreover, 162 (84 percent) of the individuals in that study worked in Kentucky, West Virginia or Virginia, and 169 (88 percent) had only ever mined underground. Blackley et al. (2016) also reported on a group of 60 PMF cases that were discovered by a single black lung clinic in eastern Kentucky. Since seeking care at such clinics and participation in the CWHSP are voluntary, and could be influenced by a number of factors, there has been some concern that these reports may overestimate the degree of resurgence in severe disease (i.e., versus disease that was previously under-reported). Even so, they highlight a critical need to better understand the cause(s) of disease development and progression — such that effective interventions can be devised.The notable uptick in CWP and PMF rates among miners in central Appalachia has led to this region being called a hot spot for disease (Pollock et al., 2010; Antao et al., 2005; Blackley et al., 2014; Laney et al., 2017). While the geographic clustering has been well documented (Pollock et al., 2010; Antao et al., 2005; Wade et al., 2011; Wang et al., 2013), the root cause is still unknown. Leading hypotheses have focused on the relative amount of rock being cut along with coal in many central Appalachian mines, as there has been a tendency to mine increasingly thinner coal seams over the past couple of decades (Laney et al., 2010; Schatzel, 2009). This shift has likely been accompanied by changes in specific dust exposure factors, such as increased abundance of particularly harmful dust constituents (e.g., silica or silicates) or increased frequency of harmful exposures (e.g., due to work in more risky environments) (Pollock et al., 2010; Blackley et al., 2016; Cohen et al., 2016; Douglas et al., 1986)."

Jan 5, 2018

By J. D. Grozier, W. W. Mullins, H. W. Paxton

The morphology of the nucleation and growth of austenite into high-purity iron in NH3-H2, gas mixtzires has been studied. The growth rate of an austenitic rim (planar interface) from scratched surfaces of- polycrystalline iron specimens was determined as a function of temperature and percent NH3 and found to he in reasonahle agreement with growth-rate calculations based on a model which assumes the diffusion of nitrogen to he the rate-controlling step. Under certain conditions, austenite pew as platelets; growth rates of these along the surface of single crystals were found to he dependent on surface preparation, orientation, THE development of microstructures can conveniently be thought of in terms of nucleation and growth. The complex topic of nucleation in solid-solid transformations will not be discussed at length, although a few qualitative experiments were performed. Growth is determined by the mobility of the various possible interfaces under the available driving forces in a particular situation. In homophase transformations, it has been clearly demonstrated that the mobility is very sensitive to small amounts of impurities, to the kind of impurity, and to the orientation relations across the boundary.' A degree of quantitative knowledge has temperature and percent NH3. On electropolished surfaces with a (110) pole, the maximum growth rate of platelets was determined and found to be in agreement within a factor of 2 to 3 with theoretical calculations of the edgewise growth rate of a platelet. The calculations are based on a model which assumes that the diffusion of nitrogen in the ferrite in front of the moving curved attstenitic interface at the tip of the platelet is the rate-controlling step. The growth direction on the surface of the single crystal and resztlting habit plane of the platelets were determined and found not to he unique but to vary systematically with the pole of the surface. been obtained. In the case of heterophase transformations, which are significantly more complicated to treat, a comparison of theoretical and experimental studies often shows rather poor agreement.'-' The main purpose of the experiments discussed below was to obtain additional quantitative data on crystallographic effects on boundary mobility in a system which was otherwise as simple as possible, viz. the growth of iron-nitrogen austenite into fer-rite. In the course of the experiments, it became necessary to re-examine the theory for the growth of Widmanstatten plates, especially the influence of anisotropic interfacial free energy. Some other minor experiments in the Fe-N system were performed, and are described briefly. EXPERIMENTAL METHODS A) Material Preparation. The floating zone purified iron used for this investigation was supplied by Battelle Memorial Institute. The nominal composi-

Jan 1, 1965

By J. D. Miller, C. L. Lin

In general, x-ray computed tomographic (CT) techniques are able to provide 3D images of the internal structure of opaque materials in a nondestructive manner. The unique cone beam geometry allows acquisition of all 2D projections with only one rotation of the sample thus providing for fast data acquisition and better x-ray utilization, as a complete 2-D detector array receives the cone-shaped flux of rays. Thus, an isotropic 3D volume can be reconstructed without the mechanical translation and the stacking of sequential slices as is the case for more conventional CT scanners. In this regard, a state-of-theart, custom designed x-ray microtomography facility to provide very detailed 3D spatial analysis of multiphase particles has been installed and is in operation at the University of Utah. The reconstructed 3D tomographic volume allows for an adjustable spatial resolution from 5 to 20 microns for sample dimensions from 10 to 40 mm in diameter, respectively. For example, a packed bed of coal particles is shown below in which different crystalline froms of pyrite are distinguished in 3D.

Jan 1, 2003

By Z X. Zhang

In sublevel caving mines, eyebrow break usually gives rise to lower ore recovery and worse safety in the field. Eyebrow break is caused mainly by two tensile stress waves: one from the front surface of a blasting ring, and the other from the roof of the drift. In order to reduce the two waves and finally to reduce eyebrow break at Malmberget mine, we employed two methods: (1) cartridge charge, and (2) double-primers in each blasthole. The two methods were tested in one ore body called ViRi. A total of 10 rings with the cartridge charge and 25 rings with the double-primers were blasted. At the same time a total of 34 ordinary rings were blasted in the same ore body. The result shows that the eyebrow break is 3.0 m for the ordinary rings, 2.3 m for the cartridge charge rings, and 2.1 m for the double-primer rings, respectively. In addition, the ore recovery for the double-primer rings is increased by 3% on the level of ViRi930, compared with that for the ordinary rings.

Jan 1, 2011

By S R. Grano, M Vera

This paper deals with two separate case studies investigating the froth phase performance and characterisation of two industrial rougher/ scavenger flotation circuits. Froth phase performance was quantified using a mass balance approach to estimate froth zone recovery. Measured characteristics of the froth phase included frother solution concentration determined by gas chromatography, and the time taken for an equilibrium froth sample to decay to one-half of its original froth height. The latter measurement is referred to as the æfroth half-lifeÆ and is strongly linked to froth stability. Special methods and techniques developed to preserve frother in solution and to measure froth half-life are briefly described. The frother type in the first case study was a mixture of straight and branched alcohols, whilst the frother type in the second case study was a mixture of alcohols, aldehydes and triethoxybutane. The first case study focussed on a flotation circuit treating a low-grade ore containing only a small fraction of floatable copper sulfide minerals, while the second case study focussed on a flotation circuit treating a higher grade complex sulfide ore containing significant quantities of chalcopyrite, galena, sphalerite and pyrite. It was found that froth zone recovery of valuable mineral generally decreased down-the-bank of the two industrial rougher/scavenger circuits. Moreover, decreases in froth zone recovery significantly limit the overall cell recovery of valuable mineral achievable from the plant scavenger cells. However, the decrease in froth zone recovery could not be linked to the removal of frother from the pulp solution to the concentrate product in the preceding rougher flotation stages. Measurements of residual frother in solution suggested that, approximately, only five to ten per cent of the added frother was removed into the rougher/scavenger concentrate, with the remainder appearing in the scavenger tailings. This finding suggested there was apparently adequate frother in solution in the scavenger stages.

Jan 1, 2005

By Yukihito Sasaki

Sumitomo Metal Mining Co. Ltd. planned an expansion program for the Toyo smelter and refinery in order to increase the production capacity of electrolytic copper to 450,000 tpy in 2007. Regarding the flash smelting furnace, a drastic increase in the average concentrate smelting capacity from 2,300 tpd to 3,950 tpd was required to achieve the plan. It was necessary to examine the performance of the Sumitomo concentrate burner when the feed rate was considerably increased. The authors developed a mathematical model to describe the combustion phenomena in the Toyo flash smelting furnace. This model was developed incorporating the fluid flow, heat and mass transfer, and chemical reactions of the copper concentrate and ancillary fuel. The copper concentrate was considered to mainly comprise chalcopyrite (CuFeS2). The reaction of CuFeS2 was assumed to consist of two steps, namely, the decomposition of CuFeS2 and the oxidation of the resulting pyrrhotite (FeS) and sulfur (S). The combustion phenomena in the furnace at the increased feed rate were predicted using this model. It was found that the Sumitomo burner was capable of enhancing the smelting capacity. This is attributed to the wide dispersion of the concentrate particles caused by an increase in the particle mass and a long residence time in the reaction shaft; this is due to the low temperature of the reaction air. However nonuniformity of the reaction in the reaction shaft was enhanced with the increased feed rate. In order to improve the nonuniformity of the reaction, an increase in oil-burner oxygen and an enlargement of the diameter of the dispersing cone were useful. By combining the expertise of the Toyo smelter staff and the calculation results, the concentrate smelting capacity of the Toyo smelter has been stably increased to 3,600 tpd thus far, and further improvements of the smelting performance are still being carried out.

Jan 1, 2006

By Ho E

Analyses of several nickel mattes from around the world show a significant variation in their copper content. Typically, matte contains an alloy, heazlewoodite and a copper sulphide phase. The various commercial methods of processing these mattes are reviewed and some of the fundamental factors which determine the choice of leaching system are discussed. Electrochemical studies on pure heazlewoodite and millerite in sulphate and chloride media are compared which show that nickel sulphides react via a series of nickel deficient sulphides and exhibit passivation as nickel is removed. Differences in the electrochemical behaviour of nickel sulphides in chloride media are attributed to greater crystallinity of sulphur and less formation of'NiS2. The electrochemistry of mattes differs because of the presence of alloy and copper. Copper in the matte modifies the potential for alloy dissolution and the rate of anodic dissolution of nickel. At elevated temperatures, Cu(II) in solution exchanges with NiS and completes the leaching of nickel at relatively low potentials without significant oxidation of sulphur to sulphate. It is concluded that there are fundamental advantages to leaching nickel matte in chloride media using Cu(II)/Clz as the oxidant.

Jan 1, 1996

By Edward W. Parker

At the Cleveland meeting of the Institute, October, 1912, I had occasion to call attention to the general though erroneous impression that the principal mining activities of the United States lie west of the 100th meridian of longitude. Few, I believe, realize that the States east of the Mississippi river, which comprise only 28.8 per cent. of the total area of the United States, exclusive of Alaska, contribute about two-thirds of the total mineral production, computing by values. In 1910 the percentage of the production credited to the Eastern States was 67; in 1911 it was 65. When I have, with becoming modesty, ventured to speak of these comparisons, I have usually been met with the rejoinder, " But you include coal." I surely do, for whereas coal (m petroleum, as natural gas, as limestone) is not in the strictly technical definition of the word, a " mineral," it is legally mineral, is certainly a mineral substance, and contributes by far the largest tonnage and approximately one-third of the total value of all mineral products. The production of coal-mines in 1911 weighed approximately 500,000,000 tons. In 1912 it exceeded that record by nearly, if not quite, 50,000,000 tons. According to H. D. McCaskey, of the U. S. Geological Survey, the total weight of all the metallic ores mined in the United States in 1911 was 105,000,000 tons (a little more than one-fifth that of coal). In 1910 Mr. Lindgren estimated the total weight of all metallic ores at 120,000,000 tons. The products of the quarries, clay-pits, oil-wells, phosphate-mines, and other non-metallic products, taken all together, did not in 1911 weigh in excess of 300,000,000 tons, so that the output of coal exceeds by 25 per cent. the combined tonnage of all other mineral products. The coal-mines give to

Jan 1, 1914

By M. Remillard, M. Garon, M. Thérien, D. Hodouin

"Nineteen streams in the copper and zinc flotation units of the concentrator of the Matagami division of Noranda Inc. have been sampled for particle size distributions chemical assays, and gold and silver contents in each particle size interval. The data are upgraded by the mass balance package BILMAT. These results, in conjunction with microprobe analyses, are used to quantify the silver losses in the copper clean¬ing flotation stages and to determine how overall silver and three silver-bearing minerals are recovered in the plant final products.RESUME Dix-neuf produits des circuits de flottation du cuivre et du zinc de la division Matagami de Noranda Inc. ont été échantillonnés pour leur distribution granulométrique, analyses chimiques et le contenu d'argent et d'or des fractions granulométriques. Le bilan métallurgique a été obtenu à l'aide du programme BILMAT. Ces résultats couples avec une etude minéralogique à la microsonde sont utilises pour quantifier les pertes argentifères aux diverses étapes de nettoyage du circuit de cuivre et pour de¬terminer la repartition de l'argent et des trois minéraux argentifères dans les produitsfinals de l'usine.INTRODUCTION The Matagami division of NORANDA INC. produces copper and zinc concentrates from a sulphide ore which contains a small amount of gold (0.34 g/t) and silver (20 g/t). Only a small part of the silver (~-30%) is presently recovered in the copper concentrate. The objective of this study is to evaluate the metallurgical behaviour of silver, and secondarily of gold, in the flotation circuit for a possible increase of its recovery in the copper concentrate to improve its economic value. For that purpose it is worthwhile to study the minerals which bear silver and to determine the critical flotation stages where they are lost in the tails. The methodology proposed here is based on a coupling of a mineralogical study and a detailed mass balance calculation in the flotation circuit."

Jan 1, 1986

By J. Golamnejad

This paper attempts to model long-term production scheduling problems by chance constrained binary integer programming in a stochastic environment. This stochastic model is set up to account for ore block grade uncertainty. The probability distribution function of grade in each block is used as a stochastic input to the optimization model. This distribution function in each block should be determined using a Geostatistical Simulation approach. The deterministic equivalents of these chance constraints are then achieved, which are in the form of nonlinear in binary variables. A confidence level at which it is desired that the uncertain constraints holds, is specified in each scheduling period. Rather than the previous risk-based model, this formulation will yield schedules with a high chance of achieving planned production targets while maximizes the expectation of net present value and minimizing the variance function simultaneously. Using this method, the grade uncertainty is integrated explicitly into the optimization process.

Jan 1, 2006

By Research Staff ? Verde Copper Mines

FLOTATION is now commonly practiced in alkaline ore pulps, yet little is known regarding the action of the alkaline solutions on the ore particles beyond the fact that films of oxidized material form. We wish to chronicle our discovery of the presence of soluble reducing agents in alkaline ore pulps of the United Verde, and present some data on lime consumption. During the grinding and flotation of a pyritic ore containing small amounts of ferrous sulfate and other soluble salts, an excess of lime was added to precipitate the salts, and filtered samples of the solution were titrated with standard permanganate solution. Even in pulps of high causticity an appreciable permanganate titration was always obtained, in spite of the fact that the solutions were shown to contain little iron. Investigation of the cause brought about the discovery of several previously unsuspected compounds in flotation pulps made from pyritic ore. Not only the reducing agents present had to be identified, but also the amount of dissolved oxygen, and a survey was finally made of the free oxygen content and reducing agents of the mill pulp in the concentrating mill at Clarkdale. A great many. compounds might form, caused by oxidation of pyrite or other metal sulfides or by reaction between a lime solution and pyrite. The most probable compounds considered were calcium sulfides, polysulfides, thiosulfates, and polythionates. Later it was discovered in the literature that in alkaline pulp polythionates do not exist and if introduced are decomposed into sulfites and thiosulfates.1 Any precipitated sulfur is changed by alkali into thiosulfate and polysulfide. Sulfites and sulfides react to form thiosulfate, so that in the end it is possible to have in an alkaline solution only thiosulfate and an excess either of sulfide or sulfite. Confirmatory tests were made and it was finally established that the alkaline mill pulps made from the United Verde ore contained

Jan 1, 1929

The coal resources of the Singleton- Muswellbrook area of New South Wales are of major importance to Australia, and are likely to play a significant role in meeting the expanding demands for energy in many countries of the world. Coal resources of 45 thousand million tonnes of which 15 thousand million tonnes lie at a depth of less than 200m have been estimated. The history of coal mining in the area commenced in the mid 1800's and has been one of fluctuations in production but of rapid expansion in more recent years. It is destined to become the largest coal producing area in New South Wales. Coal is being won from the area by strip mining, open pit mining and by underground means. The techniques involved are described. The area is well endowed with infra- structure such as modern towns, railways, road- ways and access to port facilities. Production of both coking coal and steaming coal is expected to rise significantly within the next 25 years. A large proportion of the State's anticipated increased production to between 117 and 177 million tonnes by the year 2000 is likely to come from this area.

Jan 1, 1979