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By Alden B. Greninger, Victor G. Mooradian

Microscopic examinations of quenched (beta) 60:40 copper-zinc and quenched (beta) 74:26 copper-tin alloys have frequently disclosed long, thin parallel bands or markings within the polyhedral beta grains. Apparently, it has been accepted that these markings are mechanical twin bands, although there is no published account of experimental data that might tend to substantiate this belief for the copper-zinc system, and only meager evidence has been submitted for the copper-tin system. Johnsonl0 commented upon the markings he observed after deforming a quenched brass of 55.6 per cent copper and 44.4 per cent zinc. Clark's papers4 on the heat-treatment of Muntz metal contain many photomicrographs of markings in beta brass; these she referred to as Neumann bands (inasmuch as repolishing and re-etching failed to remove them) and stated that markings present in Muntz metal as quenched were the result of shock imparted during the polishing operation. Van Wert18 first suggested that these parallel markings in quenched beta brass (60:40) might be alpha precipitated along certain crystallographic planes of the matrix lattice. He showed that upon reheating the specimens to temperatures below 800" C., obvious precipitation of alpha within the large beta grains first occurred at the markings. In a discussion of this paper, Phillips stated (pp. 505-507) that in his opinion the markings observed by Van Wert were mechanical twins resulting from contraction strains produced during the quenching operation. In a study of segregate structures in beta copper-tin, Smith17 observed that in the quenched beta phase (containing 74.92 per cent Cu) parallel . bands or markings very similar to those in metastable beta brass could be

Jan 1, 1938

By B. S. Butler

PART I SUMMARY CERTAIN relations between the formation of ore deposits and other geological processes are pretty generally accepted, namely: that many ore deposits are closely associated with igneous activity; that ore deposits accompany certain types of intrusive bodies, notably batholiths and stocks, and that they are concentrated near the tops of such bodies; that igneous activity occurs in belts of strong folding and faulting; that folding and faulting are greatest in basins of extensive sedimentation and least in areas of erosion or slight sedimentation; that areas of erosion or slight sedimentation and of heavy sedimentation persist over long periods and exert a major control over structure, igneous activity, and ore deposition; that cycles of erosion, deposition, folding and faulting, igneous activity, and ore deposition, have been repeated through geologic time resulting in rather definite periods in which metal deposits have formed. In short, ore deposition is but one phase of a series of closely related geological events. It is attempted in this chapter to point out the relations of these interreacting geologic processes to the distribution of ore deposits in the western United States. Three great periods of mineralization are recognized; pre-Cambrian, post-Jurassic, and late Cretaceous-Tertiary. In distribution the deposits of the three periods, with certain exceptions, show a concentration about two large positive areas, the Colorado plateau and the Columbia plateau, which suggests a causal relation. The most general age divisions of the rocks of the Cordilleran region of the United States are (1) pre-Cambrian, and (2) Cambrian and later rocks. The pre-Cambrian rocks are exposed mainly through the Rocky Mountain belt from the Canadian boundary southward to Arizona and westward through Arizona to southern California. They have commonly

Jan 1, 1933

By J. T. Norton, Joseph Gurland

IN spite of the extended use and high state of practical development of the cemented tungsten carbides, the structure of these alloys is still a matter of considerable controversy. The characteristic high rigidity and rupture strength of sintered compacts have been attributed to a continuous skeleton of tungsten carbide grains, formed during the sintering process. This view is based mainly on the work of Dawihl and Hinnuber,1 who reported that a sintered compact of 6 pct Co maintained its shape and some of its strength after the binder was leached out with boiling hydrochloric acid. After leaching, only 0.04 pct Co was reported to remain in the compact. They also showed that the assumed increasing discontinuity of such a skeleton, as the cobalt content is increased, could be made to account for the observed discontinuous increase of the coefficients of thermal expansion, the loss of rigidity, and the impaired cutting performance of alloys of more than 10 pct Co. Contradictory evidence was cited by Sanford and Trent,' who mentioned that a sintered compact was destroyed by reacting the binder with zinc and leaching out the resulting Zn-Co alloy. The skeleton theory also does not account for the observed change of strength of sintered compacts as a function of cobalt content. If the skeleton is responsible for the strength, the latter would be expected to decrease with increasing binder content. Actually, the strength increases and reaches a maximum around 20 pct Co. In addition, tungsten carbide is brittle and undoubtedly very notch sensitive. The highest value found in the literature for the transverse rupture strength of pure tungsten carbide prepared by sintering is 80,000 psi.3 herefore, such a skeleton does not easily account for a rupture-strength value of 300,000 psi and higher, commonly found in sint.ered tungsten carbide-cobalt compacts. In view of the conflicting data present in the literature, experiments were undertaken to determine whether the sintering of tungsten carbide-cobalt alloys leads to the formation of a carbide skeleton or whether the densification behavior and the properties of cemented compacts are consistent with a structure of isolated carbide grains in a matrix of binder metal. The specimens were prepared from powders of commercial grade. Tungsten carbide powder ranged in particle size from 0 to 5x10-4 cm. Mixtures of tungsten carbide and cobalt were ball milled in hexane for 48 hr in tungsten carbide lined mills. After milling, the specimens were pressed in a rectangular die (1x1/4x1/4 in.) at 16 tons per sq in. NO pressing lubricant was used. Sintering of the tungsten carbide-cobalt compacts was carried out in a vertical tube furnace equipped with a dilatometer (Fig. I), by means of which the change of length of the powder compacts could be followed from room temperature to 1500°C. An atmosphere of 20 pct H, 80 pct N was maintained inside the furnace. Decarburization of the samples was prevented by the presence of small rings of graphite inside the furnace tube. The temperature of the sample was measured by a platinum-platinum-rhodium thermocouple, which also was part of a temperature control system able to maintain a constant temperature within ±100C. Pure tungsten carbide compacts were prepared by sintering the carbide without binder or by evaporating the binder from sintered compacts in vacuum at 2000°C. Since complete densification of these samples was not desired, they were sintered only to 60 or 80 pct of the theoretical density of tungsten carbide. The specimens were prepared for metallographic examination by polishing with diamond powders and etching with a 10 pct solution of alkaline potassium ferricyanide. Cobalt etches light yellow and the carbide gray. The amount of porosity is exaggerated since it is difficult to avoid tearing out carbide particles, especially from incompletely sintered samples. Experimental Observations A number of specific experiments were carried out in order to study some particular aspect of the sintering problem. The details of these experiments, together with their results, are as follows: Electrolytic Leaching: The binder was removed by electrolytic leaching from sintered tungsten carbide-cobalt compacts for the purpose of determining the continuity of the carbide phase. The method used was based on the work of Cohen and coworkers4 on the electrolytic extraction of carbides from annealed steels. If the sample is made the anode, using a 10 pct hydrochloric acid solution as the electrolyte, the binder is dissolved, but the rate of solution of tungsten carbide is negligible. A current density of 0.2 amp per sq in. was applied. As shown in Fig.

Jan 1, 1953

By J. L. Lehman, J. D. Sudbury, J. E. Landers, W. D. Greathouse

A full scale field experiment on cathodic protection of casing answers questions concerning (1) the proper criteria for determining current requirments, (2) the amount of protection provided by different currents, and (3) the transfer of current at the base of the surface pipe. Three dry holes in the Trico pool in Rooks County, Kans., were selected for cathodic protection tests. The three holes were in an area where casing failures opposite the Dakota water sand often accur in less than a year. Examination of the electric togs showed the wells to be similar to other wells in the field where casing in four of seven producing wells has failed. The three holes were cleaned out and cased with 75 joints of new 51/2-in. 14-tb J-55. Each joint was visually inspected and marked before it as run. The casing was bull plugged and floated in the hole 50 that the inside might remain dry and free of excessive attack. Also, if a leak occurred, a pressure increase could be observed on gawge at the surface. Extensive testing was done, including potential profiles, log current-potentid curves and electrode measurements from both surface and downhole connections. Based on these data, a current of 12 amps was applied to one well and 4 amps to mother. The third well was left to corrode. During the two-year period when the casing was in the ground, [he applied current was checked weekly, and reference electrode measurements were made about every two months. Three sets of casing potential profi1e.c were run. When the three strings were pulled, each joint was examined for type of scale formed, presence of sulfate-reducing bacteria, extent of corrosion nttnck and pit depth. Since the pipe was new when run, quantitative determination of the protection provided by current was possible. This is the first concrete field evidence to help resolve the many arguments about the proper method for selecting adequate current for cathodic protection of oilwell (-using. INTRODUCTION A casing string is run when a well is drilled. This pipe is supposed to protect this valuable "hole in the ground" for the life of the well. Often the casing does not last the life of the well; it is with these casing failures that this work is concerned. The cost of repairing a casing failure varies from field to field—from as much as a $30,000 per leak average in California to $5,000 per leak in Kansas. Additional costs other than actual repairs are also important. These include formation damage, lost production, etc. Casing damage caused by internal corrosion is important in some areas. Treatment normally consists of flushing inhibitor down the annulus, but further research is being done on control measures. The test described in this paper is concerned only with external corrosion. The problem of casing failure from external attack has appeared in several areas including western Kansas, California, Montana, Wyoming, Texas, Arkansas and Mississippi. Cathodic protection is currently being used in an attempt to control external corrosion. From reports in the NACE there are thousands of wells currently under cathodic protection. The quantity of current being applied ranges from 27 amps on some deep California wells to a few tenths of an amp being supplied from magnesium anodes on wells in Texas and Kansas. Considerable field and laboratory effort1,9,5,6 was exented on the problem of cathodic prctection of casing, and it became fairly obvious that this method could be used to protect wells. Early workers showed that current applied to a well distributed itself over the length of the casing and was not concentrated on the upper few hundred feet. Basic cathodic protection theory had shown that corrosion attack could be stopped by applying sufficient current. The problem resolved itself, then, into one of trying to decide just how much current was necessary. Various criteria were utilized in installing the many existing cathodic protection installations. These methods included the following. 1. Applying sufficient current to remove the anodic slope as shown by the potential profile." 7. Applying enough current to maintain all areas of the casing at a pipe-to-soil potential of .85 v.' 3. Applying the current indicated by a log current-potential (or E log I) curve." 4. Supplying the current necessary to shift the pipe to-soil potential .3 v." 5. Applying 2 or 3 milliamps of current per sq ft of casing."

By Joël P. T. Kapusta, Romeo U. Pagador, Noparut Wachgama, Chumnoom Khuankla

"Thai Copper Industries (TCI) is a custom copper smelter and refinery in Rayong, Thailand, with an annual capacity of 165,000 tons of cathodes. It employs the El Teniente Technology as the primary smelting reactor to produce white metal from copper concentrates. The white metal is further treated in Hoboken Siphon Converters to produce blister copper then refined in anode furnaces before being cast into anodes for electro-refining in the on-site tankhouse.Thai Copper Industries is the first copper smelter to install and successfully operate on a commercial scale with the Air Liquide Shrouded Injection (ALSI™) Technology in the Hokoben converters with sonic injection of oxygen enriched air and nitrogen for cooling of the injector tip areas. Following commissioning and the establishment of operating practices, the performance of the Hoboken converters with ALSI™ Technology produced outstanding results. The unique combination of an El Teniente and Hoboken siphon converters, both of which are bath smelting operations, offers very high blowing and oxygen efficiencies. As a consequence, reverts recycling was accelerated with minimal build up on the mouth, end-plates or even below the siphon that is typical in Hoboken converters.These outstanding results in the Hoboken Siphon Converters with ALSI™ Technology helped the TCI Plant reach a production of about 75% of its capacity within four months despite the fact that the TCI staff is quite young and its converter know-how and experience are not yet fully developed."

Jan 1, 2009

By M. Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

Jan 1, 2005

By Tatsuro Ariyama, Michitaka Sato, Atsushi Sakai, Sumiyuki Kishimoto, Ryota Murai

"In order to achieve high pulverized coal injection operation in a blast furnace, optimization of the injection lance arrangement was carried out using an experimental furnace and mathematical models. To increase the injection rate of pulverized coal, it is required to raise the combustion efficiency of pulverized coal. It became clear that multi-point injection and the lance arrangement to avoid interference among the coal streams injected were so effective in increasing combustion efficiency. With these findings, the eccentric double lance arrangement has been newly developed.At NKK, Fukuyama No.4 Blast Furnace, after the improvement of the lance arrangement, the maximum injection rate reached up to 230 kg/thm and an average monthly record of 218 kg/thm was successfully achieved.IntroductionFrom the viewpoints of reducing the production cost of pig iron and prolonging coke oven life, high pulverized coal injection over 200 kglthm is actively pursued by ironmaking industries[1-2].Coal particles injected into the blast furnace are consumed by combustion in the raceway and also in-furnace reaction like solution-loss reaction (C + CO2 = 2CO). The amount of coal consumed by the latter process is determined by the carbon balance in the blast furnace and there is a limit. Therefore, to increase the injection rate, it is desirable to improve the combustion efficiency in the raceway. For these purposes, the optimization of the lance arrangement was examined by a hot model and mathematical models."

Jan 1, 1996

By D Stow, M Edmondson

Lemington coal mine is operating in an environmentally sensitive area in the Hunter Valley, NSW, Australia. Late in 1999 the southern pit was developed using a series of box cut blasts. After the initial development the area would have been free dug due to the soft, well-jointed nature of the deposit. However, it was decided to trial drill and blast to determine if shovel productivity could be improved to enable an overall mining cost reduction. The initial trial blast results were less than satisfactory with both environmental issues occurring and the desired shovel productivity not being achieved. An audit of the blasts indicated that wet ground and the presence of soft clay inter-bedded with harder rock caused the poor blast results. Also, water-affected explosive product combined with explosive energy loss into soft ground led to flat spots and tight digging in the hard band areas, resulting in the lower dig rates. Lemington Mine and Orica Explosives developed a plan to match the rock with the appropriate explosive type and energy. This resulted in a number of blasts over a six-month period using a new non fuming explosive product, æNovaliteÆ. The results have been excellent with the environmental issues being totally resolved and dig rates improved, enabling reductions in mining costs. This has allowed the mine to continue with their exemplary record of environmental management whilst achieving operational efficiencies.

Jan 1, 2001

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

BHP World Minerals (BHP) commenced development of the Cannington exploration decline in 1993 using Peabody Resources LimitedÆs Mining Services Division (PRL) as the contractor. Approval was given in 1996 to complete the mine development and bring the mine into production in 1997. The total mine development at Cannington by PRL has included 14 km of headings, 1040 m of shaft sinking for ventilation and ore hoisting and 990 m of raise boring for ore passes and vent rises. Hard money schedule of rates contracts were used for mine development from 1993 until early-1997. This took the mine development down to 570 m below the surface and developed six levels. Because of significant risks, the final phase of the mine development was completed in 1997 under a partnering agreement. This paper examines the factors considered in making the change to partnering, the issues involved in negotiating the partnering agreement to complete the Cannington mine development and the outcomes of the agreement.

Jan 1, 1998

By D. G. Westlake

THE structure observed in thin foils by transmission electron microscopy is not necessarily representative of the initial bulk material. We have shown that hydrogen, originally present in a specimen of vanadium, niobium, or tantalum, can be concentrated by the thinning operation used to prepare foils from the bulk materials.' These foils exhibited domain walls indicative of a tetragonal distortion of the bcc unit cells, probably caused by ordering of the hydrogen in preferred interstitial sites. We believe this ordering does not occur at room temperature in the bulk material which contains less than 1 at. pct H. In a continued effort to prepare metal foils whose hydrogen concentrations remain constant during preparation, we have developed some new chemical and electrothinning techniques for vanadium. Each of the procedures presented in Table I produced foils that were thin enough for transmission electron microscopy. The experiments described below were performed to test the effect of each thinning procedure on hydro-

Jan 1, 1968

By J McQuie

The concentrator at WMCÆs Leinster Nickel Operation has operated with flash flotation in the grinding circuit since the early 1990s. There has always been a positive correlation between flash flotation Ni recovery and overall Ni recovery û however this relationship could be explained by differences in the ore, rather than by the action of the Flash flotation cell in reducing overgrinding of Ni. In July 2003, refurbishment within the plant made it necessary to operate the concentrator for a period with the flash flotation cells off. The resulting data set provided evidence that flash flotation in the grinding circuit changes the size distribution of Ni to reduce the amount of slow-floating fine (-7 ¦m) Ni produced. Ni recoveries in the finer size fractions were similar with flash flotation on or off û but because less fine Ni is produced when the flash flotation cells are operated, overall Ni recovery improved.

Jan 1, 2005

By P. E. Hildebrand, S. W. Mao, C. N. Crain

Hydrologic and economic criteria figure in many obvious ways in water resources development, but they are rarely linked quantitatively, and most of the applications are pertinent only to the case in point. In the preparation of a regional plan for the massive program of groundwater development in the Punjab, situations have arisen where the choice among two or more alternatives was made by analyzing the economic implications of critical hydrologic parameters. Two of these situations which are of more or less general interest are described herein. The first involves basic development policy, i.e., the question of whether groundwater development should be based on the demand of the economy, or the conservation concept of safe yield. The analysis demonstrated that mining of groundwater is clearly indicated for areas where alternative supplies are unavailable. The second problem involves integrating hydrologic data into an economic model to determine optimum well design. From an analysis of all pertinent factors, a simple nomograph was derived for determining well specifications on site during construction. The nomograph can be modified for use in any alluvial terrain. In the Northern Zone of the Indus Plains —the region known as the Punjab- Pakistan is proceeding with integrated development of water and land resources on a scale never before contemplated. The heart of the development plan is a massive program of groundwater development to supplement canal irrigation supplies and to provide drainage relief to the irrigated lands. By the close of 1966 about 2500 high-capacity wells were in operation and furnishing the water supply and drainage requirements for nearly two million irrigated acres. The development plan calls for the construction of a total of nearly 30,000 wells with an aggregate capacity of 120,000 cfs by 1980. This is part of an integrated program eventually affecting over 20 million acres of irrigated lands. [This development program is administered by the West Pakistan Water and Power Development Authority (WAPDA) for which the firm of Tipton and Kalm-bach, Inc. serves as regional planning consultant for the Northern Zone. The material presented herein is derived from planning studies which have been made in connection with the preparation of a regional development plan for the Northern zone.] Pakistan is proceeding with this large-scale development of land and water resources at a time when she is at the threshold of an almost calamitous population growth. Furthermore, she is attempting this development at a time when most of her usable land is already occupied and her food demands exceed current production. Here in the Northern Zone is one of the largest continuous areas of irrigated land in the world, easily irrigated, with a warm, dry climate and ample potential supplies of surface water and groundwater. Except for an abundance of land and labor, other primary resources are lacking or in very limited supply. The agriculture sector so dominates the economy that only by means of an effective development of the agricultural resources can other sectors grow and contribute to a viable economy. Because of inadequate irrigation, farming here has not effectively participated in the twentieth century revolution in agriculture, and only by means of massive development of potential supplies can Pakistan catch up. Capital for any kind of mass development must come from the outside. But the overriding restraint to development of the land and labor resources is the availability of water. ECONOMICS OF DEVELOPMENT The decision-making process in planning regional development becomes increasingly complex as the various sectors of the economy become more highly developed. Where, as in this case, one sector dominates the economy and its development can be considered the key to development of other sectors, the decision-making process is simplified and it is easier to identify alternatives and to trace the prob-

Jan 1, 1970

By Prashant Dixit, Akhil Singh, Asim Kumar Mukherjee, Sudipta Patra, Veerendra Singh

Phosphorous is an undesired element present in iron ore used in the steel making process. It leads to an increase in overall production cost as well as deteriorated steel quality. The desired phosphorus content in iron ores used in steel making is < 0.1%. Numerous beneficiation studies are mentioned in the literature; however, there is no commercial scale technology established to beneficiate high phosphorous iron. The major phosphorous bearing minerals are apatite (Ca5(PO4)(Cl/F/OH), wavellite (Al3(PO4)2(OH)3·5(H2O)), senegalite (Al2(PO4)(OH)3(H2O), barrandite ((Fe,Al)PO4·2H2O), etc. Ultrafine grinding is required to liberate phosphorous minerals from iron ore minerals and subsequently subject it to flotation, acid leaching, and bioprocessing. The selective flotation of iron ore could successfully reduce the phosphorous content from 0.82% to < 0.20% with the combination of grinding, magnetic separation, and carbothermic reduction. Acid leaching processes are also able to remove ~80% (0.85%→0.16%) of phosphorus; however, these are relatively costly and complex processes. The mechanism of bio-extraction for phosphorous removal is reported as one of the most successful processes. This process is capable of removing more than 80% of the total phosphorous and significantly reducing the phosphorous content from 1.06% to 0.16%. The main disadvantage of this process is that it occurs at a much slower pace. In today’s scenario, ultrafine grinding followed by froth flotation seems to be the most feasible solution for the beneficiation of high phosphorous iron ore in which the concentrate obtained can be utilized for pellet making and ultimately used for steel making processes. Development of additives for leaching, roasting, and bioprocessing can be explored further to make these processes more effective and economically viable.

May 28, 2024

By C. Wert, D. Keefer

The results of this study indicate that sudden increases in aging temperature lead to reversion phenmena in carbon in the a, iron system. These phenomena are thought to be associated with the dissolution of carbide precipitates. Reversion is studied with respect to three variables: 1) Specimen grain size, 2) the initial amount of carbon in solution, and 3) difference between initial and final aging temperature. It is found that of these variables the initial carbon concentration has the greatest effect on reversion. THE solid solution of carbon in n iron has been the subject of numerous investigations throughout the past few years. Despite the great amount of effort which has been put forth toward understanding this system, however, there persist a number of interesting aspects of the system which are open to further research&apos; Studies Of the precipitate which forms as a result of aging a supersaturated solution of carbon in a, iron appear to be particularly interesting. The present work is an attempt to determine certain

Jan 1, 1960

By S. A Weigand, J. W. Bolton

Production of sound bronze castings is a matter of great practical interest to users and manufacturers of high-grade non-ferrous engineering specialties. Although there has been much excellent research in this field, there still remains some confusion regarding the fundamental principles underlying production of really sound bronze. The literature of the past 20 years on this subject indicates that the prevailing opinion of metallurgists and foundrymen has been that unsoundness in bronze is due generally to oxidation. The following references are typical. Review of Literature Carpenter and Edwards1 state that when gun metal is melted the alloy dissolves gas, the amount increasing with rise in temperature and duration of the melting. The solubility of the gas diminishes during the fall in temperature and it escapes through the liquid metal. At the moment of incipient solidification there is an evolution of gas. Sperry2 says that by using charcoal a reducing atmosphere is supplied whereby oxidation is prevented, and this also prevents gases from coming in contact with the metal. Logan3 says that many of the troubles that occur in non-ferrous castings are the direct result of one thing—oxidized material. He mentions how readily copper absorbs oxygen when molten, but does not mention the harmful effects of reducing conditions as observed in overpoled copper. Guillemin and Delachana14 investigated the gases occluded in bronze and found that the better bronzes contained mostly hydrogen while the poorer ones had a larger proportion of carbon monoxide and carbon dioxide.

Jan 1, 1929

By J. W. Bolton, S. A. Weigand

Production of sound bronze castings is a matter of great practical interest to users and manufacturers of high-grade non-ferrous engineering specialties. Although there has been much excellent research in this field, there still remains some confusion regarding the fundamental principles underlying production of really sound bronze. The literature of the past 20 years on this subject indicates that the prevailing opinion of metallurgists and foundrymen has been that unsoundness in bronze is due generally to oxidation. The following references are typical. Review of Literature Carpenter and Edwards1 state that when gun metal is melted the alloy dissolves gas, the amount increasing with rise in temperature and duration of the melting. The solubility of the gas diminishes during the fall in temperature and it escapes through the liquid metal. At the moment of incipient solidification there is an evolution of gas. Sperry2 says that by using charcoal a reducing atmosphere is supplied whereby oxidation is prevented, and this also prevents gases from coming in contact with the metal. Logan3 says that many of the troubles that occur in non-ferrous castings are the direct result of one thing—oxidized material. He mentions how readily copper absorbs oxygen when molten, but does not mention the harmful effects of reducing conditions as observed in overpoled copper. Guillemin and Delachana14 investigated the gases occluded in bronze and found that the better bronzes contained mostly hydrogen while the poorer ones had a larger proportion of carbon monoxide and carbon dioxide.

Jan 1, 1929

By T. A. Read, H. K. Birnbaum

Deformation of AuCd alloys having the 8 (orthorhombic) and (3" (tetragonal) structures occurs by the stress induced motion of twin boutdaries. A restoring force acts on displaced twin boutdaries as a result of internal energy increases in the volume through which the boundaries are displaced. The phenomonology of the twin boundary motion is described and a mechanism for twin boundary motion and the restoring force is proposed. A time-dependent stabilization behavior of the twin boundaries, which is observed after the twins are formed by the diffusionless phase transformations, is described. THE AuCd 8 phase (ordered bcc structure) exhibits a transformation to a phase having an orthorhombic structure, 8&apos; (space group D&apos;), for compositions in the vicinity of 47.5 at. pct Cd and to a phase having a tetragonal structure, 8" (point group 4/m, m,m), for compositions in the vicinity 50.0 at. pct Cd. Both transformations are diffusionless, occur on cooling at 60" and 30OC, respectively, and are crystallo-graphically reversible.&apos; They are accompanied by an inhomogeneous deformation which was observed to be twinning in the low-temperature phase. 3&apos;4 The transformations may occur by a "single interface" or by "multiple interfaces."5&apos;6 In the "single interface" transformation, the twinned product phase consisted of two twin orientations as shown in Fig. 1. In the multiple interface transformation the product phase contained "domains" each of which contained two twin orientations, Fig. 2. Deformation of specimens containing transformation twins was achieved by motion of the twin boundaries. Releasing the applied stress resulted in the displaced twin boundaries returning towards their initial positions. This "pseudo-elastic" behavior of the boundaries varied with time after the formation of the twin boundaries by the transformation.

Jan 1, 1961

By William Kendall

INTRODUCTION Stillwater Mining Company, with its two underground, hard rock mines in South Central Montana, is the largest primary producer of palladium and platinum in the Western Hemisphere. Platinum Group Metals (PGMs) are mined from a specific zone within the Stillwater Complex, a layered mafic/ultramafic igneous intrusion, named as the J-M Reef. Over much of the J-M Reef, the economically minable, mineralized horizon is contained at typical horizontal widths of 6.5 ft to 8 ft wide. This feature of narrow mining widths has made it challenging to safely and effectively mine these areas of the J-M Reef using mechanized cut and fill and sublevel sill development mining methods. Mechanization of most or all of the steps of the mining process is important to Stillwater in the continuous pursuit of high standards in safety and health. Mechanized bolting within the J-M Reef ore production headings is an important piece of reaching these objectives. In general, metal/non-metal mining requires varied mining techniques, as compared to more traditional bedded mineral/resource deposits. Narrow vein mining is a selective mining technique that generates a minimal amount of waste material while obtaining the more valuable ore deposits. Drilling and bolting in narrow vein mining has traditionally been performed with air-powered, hand-held ?jackleg? equipment because mechanized equipment is, typically, too large for the selective narrow vein techniques. In addition, traditional hand-held pneumatic equipment provides significant flexibility for small-opening, narrow-vein developments, reducing waste rock handling and improving ore recovery management. The hand-held equipment is also relatively inexpensive to purchase. Due to its simplicity, it is also relatively easy to train operators to use hand-held equipment. Hand-held equipment has been routinely used to safely install ground support and to develop production faces in hard rock mines for many years. Although it is effective, the hand-held equipment requires operator exposure to certain inherent hazardous conditions in the active face/development mine areas. These include falling rock, tripping hazards, bending/twisting/lifting hazards, high noise levels, and chemical fumes from the hammer exhaust. Based on health and safety statistics from the Stillwater mines, operation of the rotary-percussive hand-held equipment adversely affects the long-term health of the operator?continual jackleg operation frequently results in long term damage to hearing, shoulders, arm and wrist joints, and back injuries. This reduces the quality of life for the operator and also results in higher personnel turnover rates for the mining company.

Jan 1, 2014

By Peter Loehr

Full-face tunnelling machines were introduced into German coal mines 12 years ago. It was aimed to utilize these highly efficient systems to drive mine tunnels in rock so that the large demand for development work in some mines could be met. A characteristic feature of coal deposits in Germany - and particularly in the Ruhr Area - is a thick overburden strata. Access is therefore only possible through vertical shafts. A network of horizontal drivages leading from these shafts open the deposits between the different mine levels. The hardcoal-bearing formations are multi-folded and heavily tectonically stressed. Apart from a few extensive fault zones there are many single faults of different natures in the carboniferous strata. During the course of decades coal mining has penetrated to ever increasing depths. Nowadays coal is mined from depths of between 600 m and 1,200 m. The effects of ground pressure in connection with extremely varying rock strengths and high temperatures are particular difficulties which have to be overcome during drivage work. The first full-face tunnelling machines to be applied in the mines had originally bee deigned and developed for tunnelling projects. Not only the machines themselves, but also the back-up equipment had to be adapted to meet the special demands of German coal mines.

Jan 1, 1983