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By Fu-Shen Zhang, Mengjun Chen, Jianxin Zhu

"In the present study, different types of cathode ray tube (CRT) glasses were examined by sequential extraction combined with TCLP to provide possible explanations for how Pb and Ba leach out from the waste CRT glasses and to give possible reasons for why they leach out. Sequential extraction results showed that Pb and Ba in the CRT glasses dominanfly presented as the residual fraction. The exchangeable fractions of Pb and Ba were extremely low, less than 0.01 % of the total content, but they were higher than those required by the regulation limits, 5 and 100 mg/L for Pb and Ba, respectively. TCLP tests of the original CRT glasses and CRT glasses residues after each step of sequential extraction demonstrated that the extremely high leaching toxicity of CRT glasses mainly caused by its exchangeable and carbonate fractions of Pb and Ba.IntroductionIn recent years, the amount of cathode ray tube (CRT) contained monitors or TV sets in the market were sharply reduced, since they were substituted by novel and better electronic and electric equipments such as LCD and PDP, leaving huge amount of end-of-life CRTs. 50-85% of the total weight of this kind of computer monitor or a TV set is glass[1,2], which was classified to three categories according to their chemical compositions: black & white glass (BW), color panel glass (CP) and color funnel glass (CF)[3]. In order to provide shielding from X-rays generated during the picture projection process, lead, barium and strontium oxides were used in the glass. In general, a color CRT contains 1.6-3.2 kg of lead . Therefore, these glasses have attracted wide and tense attention due to the potential risk to the environment and human health."

Jan 1, 2011

By Gerhard Derge

THE introductory paper1 of this series described the potential behavior of tin in sodium carbonate and bicarbonate solutions whose pH ranged from 8.4 to 11.2 and demonstrated that significant and reproducible results could be obtained by proper attention to experimental technique. In examining the corrosion of tin under such conditions, it is desirable to know the effects of anions, aside from carbonate, that are likely to be present in commercial materials packaged in tin. Therefore, in this paper the potential behavior of tin in carbonate solutions to which sodium fluoride, chloride, bromide, iodide, sulphate, nitrate, monobasic phos-phate, dichromate, perborate and acetate have been added will be described. For most of the additions, solutions containing 0.001 and 0.01 .moles of the added material were studied. The experimental procedure was exactly the same as that described in the first paper; the pH of the electrolyte was controlled by adjusting the ratio of carbonate to bicar-bonate as follows: pH 0.1 M NaHCO3 8.4 2 parts 0.1 M NaHCO3, 1 part 0.1 M Na2CO3 9.5 1 part 0.1 M NaHCO3, 2 parts 0.1 M Na2CO3 10.0 0.1 M Na2CO3 11.2 The reagents used were all of C.P. grade. The anions studied may be divided into three groups: (1) anions that had little or no effect upon the potential curves-sulphate, nitrate, and acetate; (2) those that helped to prevent corrosion at low pH only-fluoride, chloride, bromide, and iodide; (3) those that helped to prevent corrosion at high pH also-phosphate, perborate, and chromate.

Jan 1, 1939

By Mengsu Hu, Yuan Wang, Jonny Rutqvist

Material interfaces and typical boundary conditions are boundaries influencing the existence, uniqueness and stability of numerical solutions of water flow in heterogeneous media. The Numerical Manifold Method (NMM) with a two-cover-meshing system is an ideal method to handle boundaries, considering its flexibility with no need to adjust mathematical nodes onto boundaries, the meshing efficiency, and its integration precision. In this study, we derive and compare two new approaches for boundary constraints, i.e., a discontinuous approach with Lagrange multiplier and a continuous approach with jump function in the frame of NMM. In the discontinuous Lagrange multiplier method (LMM), Dirichlet boundaries or the material interfaces are regarded as discontinuities which are linked by Lagrange multipliers. In the continuous Jump function method (JFM), the material interfaces are regarded as inner interfaces, where the refraction law is realized by constructing jump terms with discontinuity of hydraulic gradient in its normal direction. Both the continuous and discontinuous approaches make full use of the aforementioned advantages of NMM and are established based on a clear physical meaning of water flow by our energy-work seepage model. The newly derived boundary-constraint approaches were coded into an NMM water flow model and tested for precision and efficiency on different simulation examples. We first tested both LMM and JFM for an idealized heterogeneous model, comparing the numerical results with analytical solutions. Then we tested both approaches with a heterogeneous model and compared the results of hydraulic head and specific discharge. We proved that both approaches are very suitable for material boundaries considering the accurate realization of the boundary constraints and the flexibility with no need for mesh-conforming.

Jan 1, 2015

By V. Ogarlaci

Over 90% of the Romania's lignite reserve is located in the region of Oltenia, which is why this area is given special attention in the country's coal resources. Because the lignite deposit of Oltenia is comprised of 1-8 exploitable coal layers, their capitalizing calls for urgent arrangements to ensure rational exploitation under conditions of total safety, minimum losses and efficiency. The technology used the coal pits of North-Western Oltenia is the technology of excavation, transport and dumping in a continuous flow by using the complexes of excavation, transport and high-capacity dumping. The theme of this paper is of particular importance because the rhythmic operation in complete safety, is necessary both for sizing and keeping within the bounds of acceptable values, throughout the process of excavation of the geometric elements of the coal faces, marked by: the height of benches, slope angle and width of berms. Geometric dimensions of the benches of the open pits, the height of benches, slope angle and width of berms shall be calculated and shall be based on: the massif structure that forms the benches; physical-mechanical characteristics of rocks from the bench; working conditions, characterized mainly by mining and extraction methods applied; functional parameters of the mechanical equipment used to perform various operations on the coal face etc. For this study it was necessary a broad field for task tracking, measurement, research and design elements of the coal face, for land survey and a desk activity by: processing of topographic data, laboratory analyses on physical and mechanical properties of rocks and numerous specialized studies. In the final part, we bring some contributions to elucidating the issues of special importance for the lignite coal pits of Oltenia, coming up with data, graphics, formulas, solutions and concrete dimensioning of coal faces in terms of using technology in a continuous flow.

Aug 1, 2013

By Hung Tran, Qian Liu, Patrick Andrieux, Dave Counter

Blast damage in open stope mining has been an important concern in controlling ore dilution. Severe damage to the surrounding rock mass can result in the caving of waste rock and/or backfill materials, as well as general instability of the ground. The blast damage study conducted at Kidd Mining Division in 1995 was aimed at measuring the damage zone around blastholes and at identifying other factors which influence the damage. An approach and methodology developed mainly by Blastronics, together with Noranda under a project with the Mining Research Directorate, was adopted for this project. The principle was to combine vibration measurement results with borehole camera observations to derive the blast damage criteria at the specific site. The Holmberg-Persson Equation was used for the regression of near-field vibration data. The damage criteria was examined with both borehole camera observation results and rock elastic and mechanical properties. Details of this methodology, including instrumentation, are reviewed in this paper and an implementation case study of the blast damage evaluation is presented.

Jan 1, 1998

By Robert J. Timko, R. Lincoln Derick

This U.S. Bureau of Mines study examined spontaneous heating episodes in coal mine pillars in an active underground coal mine. The information obtained from these incidents was then analyzed to learn which sampling methods provided the earliest indication of pillar heating. The objective of this study was to discover if the location of future events of pillar spontaneous heating could be inferred from the available information. The spontaneous heating-prone area in this evaluation involved pillars located just in by the mine portals. Several detection methods were used to determine gas levels outside as well as inside the affected pillars. It was hoped that, by incorporating external and internal sampling methods into an organized program, locations undergoing spontaneous heating could be determined more readily. This study found that by drilling small-diameter boreholes into the pillars, then obtaining gas samples from the affected pillars, the ability to locate early spontaneous heating episodes was improved. However, the ability to accurately predict future spontaneous heating events remains in question.

Jan 1, 1995

By Brian P. Stapleton, Bill M. Stewart, Joel R. Warneke, Curtis C. Clark

Of the 28 accident/injury classifications listed by the Mine Safety and Health Administration, handling materials is second only to roof falls in terms of generating the highest number of reportable accidents in active underground coal mines. Two materials-handling activities that cause numerous injuries each year are the categories of ‘handling supplies or material, load and unload’ and ‘moving power cables.’ Mechanization and mine worker activity training are two methods that can aid in preventing these injuries. This paper describes three mechanical methods – the mobile manipulator, the in-mine hoist, and a cable-handling system - being developed and tested at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health. Two of the devices are specifically designed for loading, unloading, and moving supplies and materials, and the third device is for handling trailing cables in the confined spaces of coal mines. Also described are safety solutions developed for underground coal mines geared to showing miners safe and unsafe ways of performing various materials-handling tasks.

Jan 1, 2005

By Duk-Won Park

A vast majority of the operating longwall sections use shield-type face supports to provide ground control in the United States. As a co-operative research program between the University of Alabama (UA) and Jim Walter Resources, Inc.(JWR), a joint research program is underway to study interaction of shields with surrounding rock masses. A series of analyses on the response of shields are performed using monitored data at a longwall face in a deep coal mine. In this paper, various effects of parameters, such as leg pressure, setting load, developing load, maximum loading rate, pressure in capsule, and convergence between canopy and base, are discussed and recommended as stability indices. A microcomputer program is being developed for instantaneous interpretation of the shield monitored data, and for giving warnings of potential problems. The preliminary results define the effects of the setting load, developing load, and rate of developing load or leg closure rate. The objective of the study is to understand the shield characteristics and their interaction with surrounding strata in real time, then develop a reliable program for maintaining longwall stability.

Jan 1, 1992

Horizontal stress is an important factor that contributes to roof failure during a long wall entry development, especially when the immediate roof is weak. In this study, the effects of the three factors, the stress angle between the maximum horizontal stress and entry development, the stress ratio of the maximum to the minimum horizontal stresses, and the sequence of entry development, on the stress distributions in the weak immediate roof of a three-entry system are analyzed using the finite element method, when the horizontal stress is fixed. The results have confirmed that the stress angle has a significant influence on the stress distributions. Generally, the three-entry system is in the worst stress condition when the angle is about 60°_75°. The stress ratio has little effect on the roof stresses. In addition, the sequence of entry development has also little effect on the roof stress for the specific case analyzed.

Jan 1, 1999

By Terrence M. Carroll, Chu E. Ho

"A pile installation and load testing program on driven tapered piles was undertaken at John F. Kennedy International Airport in New York City for the extension of the existing Terminal 4. As part of the program, dynamic testing by means of the Pile Driving Analyzer (PDA) was performed on several preliminary test piles as well as production piles. The results of the dynamic tests and subsequent static load tests were reviewed to develop an understanding of the pile-soil response of a tapered pile during driving and after setup. Pile setup occurred as a result of increase in shaft resistance with virtually no increase in toe resistance. More than 150 tons of additional capacity was gained after the setup time.The capacities measured during driving from the PDA are typically used as the basis for determining the pile driving set criteria, with the required initial driving capacities determined largely by the contractor’s experience. An improved appreciation of the setup phenomenon is required to better refine the driving criteria at the end of initial driving such that the required ultimate capacities can be obtained, with reasonable confidence, after a period of setup.This paper presents interpretation of pile-soil behavior from Case Pile Wave Analysis Program (CAPWAP) analyses and discusses the mechanism of increased capacity as a result of setup effects. Time-dependent capacity gain as a result of setup effects should be based on the extrapolation of the shaft resistance component rather than the total pile capacity as is commonly practiced. Prediction of pile performance using this approach was in good agreement with observed static and dynamic load test results.IntroductionTapered piles have been adopted for various projects at John F. Kennedy International Airport (JFKIA) since the late 1940’s. Initially timber piles were used exclusively, with steel Monotube piles being used from at least the 1980’s (Horvath and Trochalides, 2004). The steel Tapertube pile was developed in the mid-1990’s and has commonly been used in recent construction (Brusey and Yin, 2008). The Tapertube piles used for this project consisted of a 25 foot long tapered section that was 8 inches in diameter at the tip and 18 inches in diameter at the top. An 18 inch diameter straight pipe was welded above the tapered section."

Jan 1, 2015

By Hendon G. W, Carr F, Jiang Y

A vast majority of the operating longwall sections use shield-type face supports to provide ground control in the United States. As a co-operative research program between the University of Alabama (UA) and Jim Walter Resources, Inc.(JWR), a joint research program is underway to study interaction of shields with surrounding rock masses. A series of analyses on the response of shields are performed using monitored data at a longwall face in a deep coal mine. In this paper, various effects of parameters, such as leg pressure, setting load, developing load, maximum loading rate, pressure in capsule, and convergence between canopy and base, are discussed and recommended as stability indices. A microcomputer program is being developed for instantaneous interpretation of the shield monitored data, and for giving warnings of potential problems. The preliminary results define the effects of the setting load, developing load, and rate of developing load or leg closure rate. The objective of the study is to understand the shield characteristics and their interaction with surrounding strata in real time, then develop a reliable program for maintaining longwall stability.

Jan 1, 1992

By Yuhua Pan

Generic mathematical models have been developed for simulating heat transfer in two types of slag resistance heating electric furnaces for sulphide smelting: i) six-electrode-in-line rectangular furnaces and ii) three-electrode circular furnaces. The models are based on three-dimensional steady-state heat transfer of conduction, convection and radiation. Solidification of liquid slag into solid slag by water-cooling units, for use as freeze lining of furnace walls, is also considered in the models. The developed models are capable of providing predictions with reasonable accuracy for electric furnaces on 1) temperatures in slag, matte, cooling water, freeze lining and other solid regions as well as temperatures at various fluid/solid interfaces, 2) freeze lining thickness, 3) furnace smelting rate and 4) furnace heat loss rate. These computer models are built into executable application programs that are very efficient, with execution time less than one second, and can be easily portable to most computing platforms. This paper describes, as an example, the modelling results on heat transfer in six-electrode furnaces. The major modelling results show that in six-electrode furnaces uniform electric power inputs to the electrodes likely lead to low temperature regions close to slag and matte tapping ends of the furnaces, and the power input and the formation of air gaps between freeze lining and cooling units have significant influences on the thickness of freeze lining maintained by the cooling units.

Jan 1, 2006

By V. Tsukerman, Ivanovam L.

"The potential of hydrocarbon resources in the Arctic oil and gas provinces is enormous. Oil, gas and condensate constitute the basis of mineral resource base of the shelf zone of the Russian Arctic; summary volume of hydrocarbons exceeds 100 billion tons of conventional fuel. Only in the Shtockman gas condensate field in the Barents Sea explored balance reserves equal to 3.2 trillion m3 of gas. It is necessary to establish a special regime of nature management in the Arctic. Environmentally oriented economic activities should be more actively stimulated. The Energy Strategy plans that starting from 2010 in the Barents and Pechora Seas up to 10 million tons of oil and 50 billion m3 of gas will be extracted, reaching the level of 30 million tons of oil and 130 billion m3 of gas in 2020. This task cannot be solved without intensification of geological exploration on the continental shelf. IntroductionThe elaborated strategy of mining enterprises should correspond to the modern paradigm of mining industry development which is not only for extraction of minerals but also for multi-profile structure having comprehensive use of the resources on the rational basis intended for rational complex utilization of mineral resources of the Arctic zone of Russia which by the definition includes maximally full use of the whole aggregate of resources on the economically rational basis with obligatory environmental with resource reproductive and socio-economic functions and deterrents"

Jan 1, 2008

By J. Petersen, T. Moyo, J. Dinga

The leaching of chalcopyrite in ferric sulfate media is notorious for its slow and inhibited kinetics. Different methods have been proposed to improve the kinetics, including the use of organic compounds as additives to the leaching media. In this study, the enhancing effect of methanol, ethanol, 1-propanol, and 2-propanol on the leaching of chalcopyrite in aerated acid ferric sulfate solutions using different reactor systems was investigated. The results revealed a clear improvement of copper dissolution by methanol and 1-propanol relative to tests with no additives under similar conditions. Operating a continuous-flow mini-column reactor yields surprisingly good results, potentially related to the maintaining of a consistent leaching micro-environment on the mineral surface. Scanning electron microscopy studies showed that the alcohols result in the removal of surface deposits formed during the anodic dissolution, potentially thus facilitating improved cathodic reduction of the ferric ion to drive the anodic dissolution.

Jan 1, 2023

By B. Qiu, Y. Luo

Longwall and/or room-and-pillar mining operations in multiple coal seams may not only induce subsurface and surface subsidence but also cause interactions between these mined coal seams. The interaction might destabilize underground mine structures and subsequently induce additional strata movements. Mathematical models to use the predicted subsurface deformations to assess the interactions and the consequences have been developed. The models are incorporated into a computer program, CISPM-MS, for predicting the final surface movements and deformations, as well as the mining interactions associated with multiseam coal mining operations. It predicts final surface movements and deformations caused by the individual mining operations and by the interactive effects. The program can also be used to assess mine structural stability in multiseam mining operations. The paper presents the developed interaction models and their application in surface subsidence prediction caused by multiseam mining operations. A case study involving mining in two coal seams, using longwall and room-and-pillar mining methods, respectively, will be used to validate the program.

Jan 1, 2013

By T. G. Sitharam, Resmi Sebastian

"Wave propagation studies across jointed rocks have significance in the fields of rock mechanics and geophysics. The passage of a seismic wave induces strains in rocks and often, these strains are of low magnitudes except at the vicinity of source. These low magnitude strains are generally in the elastic range and hence elastic constants necessary for the design and analysis of strength of rock mass, can be derived from wave velocities. Measurement of travel time velocities and measurement of resonance frequencies are the two methods usually adopted for obtaining wave propagation velocities.Resonant column apparatus measures wave velocities from the resonant frequencies obtained during testing. Depending on the type vibration applied, torsional or flexural, shear and compression wave velocities are secured. By varying the amplitude of vibrations applied, various strain levels can be introduced and corresponding resonant frequencies and wave velocities can be calculated. The resonant column experiments were performed on a model material, hardened Plaster of Paris (POP) samples, in laboratory. The paper explains the preparation of samples and the working mechanism of resonant column apparatus along with the estimation of wave velocity from resonant frequency. The numerical simulation of resonant column apparatus using distinct element method and its validation with the experimental results are presented in the paper.A distinct element code is usually used to simulate the movement of materials with intersecting discontinuities. Finite rotations and displacements of individual blocks representing the material are permitted and new contacts between the blocks are identified as the calculation progresses. Three dimensional Distinct Element Code (3DEC), the software intended for the numerical simulation of rock engineering projects, can well simulate the behavior of jointed rocks under static and dynamic loading conditions. The numerical simulation of resonant column apparatus has been performed with 3DEC considering its efficiency in modeling jointed rocks.The numerical modeling of the resonant column apparatus with application of torsional and flexural vibrations to the sample is elaborated in the paper. The response of samples to a range of frequencies is obtained and the frequency that induces maximum displacement in the sample is measured as the resonant frequency, for any particular strain level. The displacements measured at various points of the sample during application of vibrations are compared and presented. The numerical modeling of resonant column apparatus with an intact sample (without joint) and a sample with a joint incorporated are explained at a particular strain level. The resonant frequencies obtained from laboratory experiments and numerical simulations are compared and illustrated. It has been found that resonant frequencies obtained using numerical and laboratory experiments are in good comparison and can be extended for various strain levels and sample conditions."

Jan 1, 2015

By Carole L. B. Mitchell

The increased use of micropiles and soil nailing presents a growing database of verification and sacrificial load test data. In Washington State, the use of micropiles is becoming common, and soil nails are now almost as widely used as tiebacks; yet the state of the practice in understanding load transfer rates has not improved. This research compiles load test data for micropiles and soil nails from Shannon & Wilson?s records in the Puget Sound region of Washington. Ultimate and maximum load transfer rates for design are correlated to geologic units and soil types found in the region. Variables such as pressure versus tremie grouting, hole diameter, soil density/consistency, and the presence of groundwater are compared to load transfer rates for similar geologic units and soil types. Results are also compared to published PTI, AASHTO, and FHWA guidelines. Our results indicate that published ranges may be conservative for some soil types in the Puget Sound region, especially for micropiles. Performing verification tests to failure instead of typical verification or performance tests is needed to improve correlations and provide less conservative design load transfer rates.

Jan 1, 2006

By J. E. Udd, L. B. Geller

"Responding to requests by the Canadian mining industry and the mine regulatory authorities, the Canada Centre for Mineral and Energy Technology (CANMET) undertook a major research project on evaluation of wire rope testing in 1986. The objectives were to document, analyze, and clarify - in basic operational terms the reasons for ongoing mine shaft wire rope failures that occur despite mandatory non-destructive testing (NDT) with electromagnetic (EM) instruments on a routine basis.The project's investigative scope and depth was unprecedented. It could not have been successfully completed without the wholehearted cooperation of industry, research organizations, and mine-inspectorates at both national and international levels.The project's goals were attained. II was shown that, at present, the problem areas in Canada are oj a human , rather than of a hardware-related nature. Consequently, the principal recommendations are concerned with a more widespread, more uniform and thorough operator training and certification process at industrial and regulatory levels. Secondary suggestions concern areas of hardware-related improvements.In this paper an up-to-date general overview is given of the major project results. A n extensive reference list is also provided of papers that contain all relevant documentation in detail."

Jan 1, 1992

By Robert M. Hopkins, Craig C. Monahan

A corrosion survey was performed on ten selected H-piles which support a reinforced concrete wharf located at Trepassey, Newfoundland. Approximately 900 thickness measurements were taken at twelve different locations in each off our zones on the steel piles: the splash (atmospheric) zone, the intertidal zone, the low tide zone and the submerged zone. Results show that over the 2o-year life of the wharf, corrosion has been most severe in the splash, low tide and submerged zones with average corrosion rates for the flanges of 6.95, 9.45 and 6.86 mils per year (mpy}, respectively, and average corrosion rates for the webs of 5.13, 4.12 and 3.45 mpy, respectively. Minimal attack was found in the intertidal zone where the average corrosion rate was only 1.66 mpy on the flanges and 1.37 mpy on the webs. Such a pattern of attack is frequently observed f or steel piles partly submerged in seawater. The abnormally low corrosion rate associated with the intertidal zone is generally explained as being due to cathodic protection induced by the high corrosion rate in the adjacent low tide zone. Analysis of the corrosion data obtained for the Trepassey wharf would suggest that this explanation might be incorrect. An alternate hypothesis has been brought forward which better accounts for the extremely low corrosion rate observed in the intertidal zones of these piles.

Jan 1, 1990

By Lin Daoyi

In this paper, we have adopted the high pressure jet-grouting curtains to seal the sea-water, and to consolidate the wall of the well for deep foundation diteh, make a pladge of building and construction of deep foundation was primarily on progress without water. This paper, we have been given a test for pumping water under mainly the circumtances of sealing condition and to report in advance the capacity of seawater seeping into the gam curtains in the process of building and construction of deep foundation.

Jan 1, 1991