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By N. Bazzanella

The hydrogen desorption kinetics of pure and Nb-doped magnesium hydride film samples was investigated by using a Sievert-type apparatus. The overall activation energy and the reaction order controlling desorption are (141±5) kJ mol-1H and n 4 for Mg hydride and (51±5) kJ mol-1H and n 1 for Nb-doped (5% at) Mg hydride indicating that, in the doped sample, hydrogen desorption is controlled by the H migration in transformed h-Mg layers. Structural analysis performed by X-Ray Diffraction (XRD) and Extended X-Ray Absorption Fine Structure spectroscopy (EXAFS) show that the catalytic effect of the Nb dopant is connected with the formation of NbH0.89 nanoclusters dispersed in the Mg hydride matrix. It is suggested that the catalysis process is also connected to the presence of Mg-Nb hydride interfaces where the transfer of H atoms preferentially occurs by connecting h-Mg grains and by the role of the MgH2-NbH0.89 interface as preferential site for the dissociation of the hydride phase.

Jan 1, 2006

By R. E. Johnson, J. E. Dutrizac, B. R. Palmer

Silver sulphide (acanthite) and lead sulphide (galena) dissolve relatively rapidly in FeCl3 media with the formation of elemental sulphur and soluble silver and lead chlorides. Parabolic kinetics are observed, and the leaching rates are controlled by the outward diffusion of the AgCl and PbCl2 reaction products through the constantly thickening elemental sulphur layer formed on the sulphide. Hence, both leaching rates are strongly dependent on those variables which affect the solubility of AgCl or PbCl2 at the reaction interface. The rates therefore increase with increasing temperature and total chloride ion concentration, but decrease in the presence of elevated concentrations of AgCl or PbCl2. By contrast, neither sulphide is significantly attacked by ferric sulphate media, even at high Eh values. Although the reasons for the refractory behaviour of Ag2S in sulphate media remain unknown, the low rate of PbS attack is attributable to the passivating layer of PbSO4 and elemental sulphur formed on the surface of the galena.

Jan 1, 1993

By J. J. Craron

MR. J. J. CRARON: If Ross Weber rings that bell of his, I think I have a few secrets on him that I will tell. It is not such a long time ago when the sales and executive departments of the coal industry were constantly urging the operating department to increase their output, and this cry for increased production resulted in vast development work and increased capacity to the point where the operating departments are today in position to produce coal upon sudden demand far in excess of the ability of their sales departments to dispose of it. So today our ability to produce coal is away ahead of our ability to market it. There are many reasons, of course, for this condition. First, the present economic situation, which has prevented even a normal consumption of coal. Secondly, the over-development and production of every commodity and industry as the result of war time and post-war time prosperity. Thirdly, the inroads made by competitive fields, particularly oil and gas, because of the desire of the public for automatic heat.

Jan 1, 1934

By William P. Blake

The salt-beds at Salton, on the line of the Southern Pacific railway, in San Diego county, California, have been successfully worked for many years by the corporation known as the East Liverpool Salt Co., and the salt has been largely used upon the Pacific coast generally and in the interior. But the industry has lately been destroyed by the overflow from the Colorado river. The salt is dissolved, and the waves of the Salton sea now roll 50 ft. above the site of this once thriving and growing business. The salt-bed was evidently the residual accumulation from the waters of an ancient lake, which I have named Cahuilla, from the name by which a large part of the valley—the home of the Cahuilla tribe of Indians—is known. The deposit covered a comparatively small area in the lowest part of the valley, 280 R. or more below the sea-level. This depressed area is now generally known as the Colorado desert, but has a soil of wonderful fertility wherever water can be had on its surface. The deserted beaches, and the water-lines, only a few feet above tide-level, upon the rocks of the bordering mountains, as well as a great abundance of shells in the soil, all bear decisive testimony to the former occupation of the valley by water. The depression is topographically the northern end of the Gulf of California, from which it is now separated by the delta of the Colorado river, extending practically from the mouth of the Gila river across the valley to the coast mountains on the

Jan 1, 1908

By H. R. Manouchehri

"In all electrical beneficiation methods, the difference in electro-physical properties of the contributed mineral particles, essentially frictional charge, electrical conductivity and dielectric constant properties are exploited to achieve separation. The composition of the raw material determines what kind of either corona charging, conductive induction, or triboelectric separation method should be employed. The process is versatile and is influenced by different parameters related to mineral characteristics, surrounding ambient conditions and electrical and mechanical attributions of the separating device. Electrical separation is surface based beneficiation method which is mainly affected by the surface and surface changes of the minerals. Therefore, it is essential to understand how the electrophysical properties of the minerals can be changed/modified. During electrical/electrostatic separation process, both charge magnitude and its polarity that developed on the particles and therefore, their electrical beneficiation potential is essentially defined by surface phenomena. Therefore, it is essential to understand how the main electro-physical parameters can be changed/modified with applied surface treatment/pretreatment methods to promote separation. Surface treatment of minerals is carried out by different means, including chemical conditioning, irradiation, thermal treatment, etc. This paper discusses and analyze the electrical separation process, electrophysical properties of the minerals with special focus on the effect of surface pretreatment/treatment methods to affect electrical beneficiation potential of the minerals. The surface treatment methods vary in a wide range from simple surface cleaning to more complicated chemical conditioning and doping. The knowledge of the solid-state physics and chemistry leads to improve the beneficiation potential of different mineral systems by choosing suitable treatment method(s). Despite the complexity and multiplicity of the charging mechanisms, difficulties in separating fines it seems to be beneficial make our attempts to further investigate and develop the process as dry, low cost beneficiation process, especially nowadays when environmental concerns, as well as energy and water consumptions are main concerns for mining industry."

Jan 1, 2018

By Fred C. Dobbs

To effectively manage the potential environmental impacts of deep-sea mining of manganese nodules, we need to know substantially more about the effects of sediment redeposition on abyssal communities and the time scales of recovery from such effects. As an initial step towards a predictive understanding of mining impacts on abyssal benthos, we are conducting a series of biological studies within the framework of the Benthic Impact Experiment (BIE). Mining operations will cause resuspension of sediments across extensive areas of the abyssal Pacific Ocean. The resultant plumes likely will produce redeposition layers, ranging from a few sediment grains in thickness to > 1 cm, over thousands of square kilometers of the seafloor. The impact of such redeposition on abyssal benthic communities is exceedingly difficult to predict. While there has been speculation that redeposition of 1 mm or less will exert deleterious effects, there has been very little testing, and the BIE will provide the first in situ test of redeposition impacts. In a series of cruises before and after controlled resedimentation, we are collecting biological samples to determine the undisturbed state of the ecosystem, the immediate effects of disturbance, and the time-course of recovery resulting from quantified levels of resedimentation.

Jan 1, 1992

By B. A. Watters, G. A. Parslow, F. H. Mcdougall

Carbonate-rich rocks occur at several localities within the Flin Flon volcanic sequence of the eastern Amisk Lake area. The rocks occur in two areas: as a group of small occurrences on islands within Amisk Lake and as two much larger linear belts running parallel to the regional structure east of Amisk Lake. Mineralogically, the rocks consist of talc and Ca-poor ankerite with occasional graphite. Segregation of these minerals and colour variation impart a well-defined planar fabric to the rocks and where the units are fairly continuous (e.g. Mosher Lake), their trend and attitude suggests a concordant relationship to the volcanics. Major and trace analysis of22 samples confirms the presence of two types, with one type being represented in each of the two areas. Most of the elements studied can be used to characterize the two groups, but three elements in particular give a clear separation: Mg, AI and Ni. Recalculation of the major element analyses, on a water and carbonate-f ree basis, indicates that one group (large concordant bodies with high MgO, high Ni and low AI20.J is altered ultrabasic material of peridotitic or dunitic composition. Because no relict igneous material is observed, and the contacts are apparently very sharp, it is possible that the hydration-carbonization process occurred simultaneously with intrusion, .in a closed system. The other group (small occurrences with relatively low MgO, low Ni and high AI203J represents alteration of basaltic rocks. AIthough some analyses suggest the introduction of calcium, as carbonate, along with the volatiles, the major oxides have remained remarkably stable during the alteration process(es).

Jan 1, 1981

By D. J. Scarpato

"Slope construction in shale can present some interesting challenges for geotechnical design engineers and contractors alike. There are challenges that can be expected and designed-for; however, all too frequently, such challenges manifest themselves as “surprises” in the field. Common constructability challenges can include those such as drill hole deviation during drilling for controlled blasting; and, excavation slope instability arising from inconsistent perimeter control drilling. Drill hole deviation results from the cumulative effects from both drilling mechanics and rock mass conditions. Once a hole has initiated the deviation trajectory, it is difficult to rectify drill steel position. Although such challenges are not necessarily unique to shale, they are often exacerbated by weak, weathered and transversely isotropic nature of bedrock conditions. All too often, the working assumption is that shale is “soft” and easily excavatable; however, this blanket assumption can prove to be costly. This paper is intended to provide design professionals and contractors with the practical considerations needed to avoid the “surprises” associated with drill hole deviation, and minimize the potential for costly claims.INTRODUCTIONFor all the slopes that have been excavated worldwide, and for such advancements in excavation technology and field characterization, one might be tempted to believe that the industry almost has slope development down to a science. This is frequently not the case, especially for weak/weathered and anisotropic bedrock. Excavation contractors are still pushed to the limits of what their technology can achieve, and engineers are all too often called to the field during construction, to make potentially risky onthe- fly decisions relative to excavatability, short and long-term slope stability, and project safety. Although there have been a host of other research papers and journal articles that have been written on the subject of deviation over the past 30 years (Brown, Geen, Sinha, 1981), the problems associated with drill hole deviation are still all too frequent. This fact is especially true for civil engineering surface excavations in bedrock."

Jan 1, 2015

By Taylor K. Kruger, A. H. Basson , S. Fataar

The mining industry remains heavily reliant on mineworkers, whose working conditions are typically more arduous than in most industries. With recent technological developments in mining and other industries focusing on the digitalisation of workspaces, mineworker safety should be at the forefront of the digital transformation. Underground mines should be viewed – and developed – as human cyber-physical systems, where digital technologies are integrated with human roles to enhance safety and coordination. Contributing to this vision, this paper presents a set of functional requirements to guide the development of human cyber-physical systems that improve the safety of mineworkers in underground mines. The formulation of the functional requirements is informed by an analysis of the current context of underground mines and an exploration of opportunities for improved human-system integration within such environments. The functional requirements are related to the real underground mining context through an illustrative example, which demonstrates how a human cyber-physical system could monitor mineworker and environment states, perform predictive safety analyses, and coordinate operations. The proposed functional requirements serve as a starting point for the development of human cyber-physical systems within complex underground mining environments; however, further research (supported by real case studies) is required to refine and obtain specific target values for the functional requirements, and to formulate accompanying performance requirements.

Jul 3, 2026

By N. A. Gjostein

From their study of the anisotropy of grain boundary mobility in aluminum, the authors conclude that tilt boundaries have a higher mobility than twist boundaries because the atomic misfit at the pure-twist boundary is relatively small compared to the misfit at a tilt boundary for a given amount of misorientation. If this is true, then one would expect a twist boundary to have a lower grain boundary energy than the corresponding tilt boundary. Fig. 6, taken from the work of Gjostein and Rhines,10 shows that this is indeed the case for [001]-cu tilt and twist boundaries in the high-angle region, thus lending support to the authors' conclusion.

Jan 1, 1968

As world demand for various minerals increases the mining industry in its endeavour to satisfy this demand will, eventually,look to the extraction of orebodies which previously may have been uneconomical to mine. These orebodies may be of two types. Firstly, new low grade orebodies and secondly, remnant sections of previously mined orebodies. Some of the factors relative to remnant mining operations are discussed and the potent- ial of remnant mining in providing an important contribution to future world metal production is considered.

Jan 1, 1975

By J. H. Venter

The accuracy of estimation from samples of ore in bulk By J. H. Venter Published in the Journal April 1972. ERRATA: Equation (1) should read... Equation (3) should read .... line following "Duscussion" Delete" .... Insert... above "References" "Discussion". Replace .... tenth DISCUSSION M. DA VID Professor Venter has proposed a formula to compute the variance of the estimated grade of a lot of broken ore, and interesting comments on the relevance of the formula and suggestions for developments are made by P. R. Janisch.

Jan 4, 1972

By Orvar Nyquist, Klaus W. K. Lange, John Chipman

Liquid Fe-C-Si alloys containing 0 to 12 pet Si and up to 4 pet C were equilibrated with carburizing gases at 1550°C. Two to 5 alloys simultaneously were held in close proximity for 5 to 7 hr to establish uniform carbon activity in the group. Analysis of the data gives the activity coefficient of carbon as a function of the mole fractions of carbon and silicon, Fig. 7. Values of the interaction coefficients at infinite dilution are

Jan 1, 1962

By Smitham J. B

A selection of Australian washed coal samples was examined to determine the effect of sample hydrophobicity (rank) and particle size on froth stability in the flotation process. The results indicate distinct rank-based variations in froth volume and stability for flotation tests conducted without the use of collector, over a series of particle size distributions.High-rank coals showed a greater tendency to generate stable, high-volume froths than coals of lower rank. Implications for circuit design and operation are outlined.

Jan 1, 1988

By F. L. Bosqui, A. D. Wilkinson

EVEN though the world has not been crying for more copper for the last three or four years there has been some important mill and smelter construction. Discovery and development of large new high-grade copper deposits in Africa has led to the construction of extensive reduction facilities there, prominent among which is the concentrator and smelter of the Rhokana Corporation at N'Kana. Northern Rhodesia. The 3000-ton concentrator adjoins the central shaft. A little over half a mile to the southeast, at an altitude of 40,010 ft., is the smelter, designed on the site by 1. H. Wynne. It is arranged primarily to treat N'Kana copper concentrates, but can also handle concentrates and direct-smelting ore from outside sources. Excavations were started late in 1930; concrete was first poured on Jan. 6. 1931; and the first blister cop¬per was cast on March 1.9, 1932, less than fifteen months later. During this period, which included several months of heavy tropical rains, some 10,000 cu. yd. of concrete was poured and 41000 tons of structural steel erected under the supervision of construction engineer, A. Ek, with a labor force of 60 to 30 Europeans and about 300 natives. The steelwork was fabricated by Head Wrightson & Co. in England, and the boiler plant equipment furnished and erected by the International Combustion Co. Ltd.

Jan 1, 1934

By Josh Calnan, Zach Agioutantis, Daykin Schnell

Damage complaints are a common occurrence related to blasting activities, specifically when blasting operations occur near residential areas. These complaints are often associated with ground vibrations from blasting. It is important for blasters and engineers to understand the potential for ground vibrations to damage residential structures to properly design blasts and appropriately address any damage complaints that arise. A review of the most recent studies of blast vibration damage thresholds for residential structures is conducted to provide a baseline understanding of blast damage potential and mechanisms. Gaps in research and understanding blast vibration damage potential are identified. Research in further understanding damage potential is presented and focuses on studying the impact of high-range ground vibrations generated from full-scale, nearfield ground vibrations from blasting on a residential structure. Specific impacts of the high-range ground vibrations reviewed as part of this research include damage to the block wall basement, global strain, rotational forces, crack generation, and crack extension in a residential structure. Planning and methodology for intentional full-scale, nearfield blasting at a limestone quarry within close proximity to a residential structure owned by the quarry are presented. Conclusions discuss the objectives and optimized layout of the ongoing data collection for the proposed research and analysis. Future potential work related to further understanding blast damage mechanisms and thresholds are also discussed.

Jan 26, 2026

By J. -G. Swanson

Dust control in longwall coal mining depends primarily on the prevention of dust at the source and secondarily on the suppression of airborne dust. One of the primary methods for the prevention of dust is the wetting of the coal face prior to extraction, which can be achieved with water spray systems installed on the shield supports. The spray droplets must travel across the airway to the longwall face, where high ventilation air speeds can entrain water droplets and prevent them from reaching the face thus minimizing the dust control at the source. Through an evaluation of spray plume characteristics in a wind tunnel, the droplet size and droplet drift behavior was determined. This drift behavior was examined by evaluating the spray plume concentration drop and the droplet size shift near the nozzle exit at varying air speeds. Based on these evaluations, CFD modeling was applied to simulate the spray behavior for varying geometries. These results led to the selection of appropriate spray nozzles capable of carrying water droplets to the face at higher air speeds, resulting in an adequate wetting of the coal face and reduced dust generation.

Jan 1, 2012

Provide the technology to remotely reset circuit breakers on continuous mining machines used in extended cuts.

Jan 1, 1994

By M. E. Hinkle

Concentrations of He, CO2, and O2 in soil gases were measured regularly for more than a year at a site near Golden, Colorado. Samples were collected from a hollow probe at 0.75-m depth and from a plastic hemisphere on the ground surface. Soil temperature, air temperature, percent humidity, And barometric pressure were also measured. Soil moisture was measured only indirectly as amount of rain or snowfall. Higher concentrations of CO2 in both the 0.75-m and surface samples correlated with higher soil and air temperatures, which suggests that CO2 was produced by bacteria. Lower concentrations of helium in both the 0.75-m and surface samples correlated with higher soil and air temperatures. Rain and snowfall appear to affect helium concentrations. Carbon dioxide concentrations were lowest when snow lay on the ground for extended periods of time. No correlation was seen between barometric pressure or percent humidity and concentrations of He, CO2, or O2 at 0.75-m depth or at the ground surface. No correlation, either positive or negative, was seen between concentrations of CO2 and O2.

Jan 1, 1988

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016