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The reported values of the standard reduction potentials of the Au(NH3)2+/Au(0) and Au(S2O3)23-/Au(0) couples are reviewed to emphasise the experimental difficulties associated with the measurement of reliable values for these quantities. The standard reduction potential for Ag(I)/Ag(0) in ammonia and thiosulphate solutions measured at ionic strength 0.1 and 25oCis used to predict the following relevant stability constants () for gold complexes based on the linear free energy correlations: Au(NH3)2+2 = 1013, Au(S2O3)23-2 = 1024 and Au(NH3)43+4 = 1033. The equilibrium constant ( 10-11) for the reaction Au(S2O3)23- + 2NH3 = Au(NH3)2+ + 2S2O32- based on these stability constants is in reasonable agreement with the measured value (10-9) based on potentiometric and spectroscopic data when excess ammonia was added to a solution of Na3Au(S2O3)2. This also indicates that the stability constant of Au(NH3)2+ is 9 to11 orders of magnitude less than that of Au(S2O3)23-. Relevant species distribution and Eh-pH diagrams based on the revised data are presented.

Jan 1, 2003

By C. H. Gerould

I would like to take a moment to consider our polystyrene-silica replica technique, which was developed at the Dow Chemical Co. and which was mentioned in the paper just given by Mr. Thielsch. He stated that he feared that our replica technique would cause difficulty due to deformation of the metal as a result of the application of pressure during the molding process. We at the Dow have never had any reason to suspect that any deformation of the metal was occurring during the molding process. Our procedure has been to heat the polystyrene to a temperature of 160°C. before applying any pressure, at which temperature the polystyrene is a viscous liquid. By so doing the pressure of the polystyrene against the metal is essentially hydraulic and is therefore applied equally in all directions, which we feel should not cause deformation. Our work using this replica technique has brought forth several indications that deformation of the specimen is negligible. These indications are: I. Direct comparisons have been made between the light and electron microscopes when studying a specific spot on a metal surface. These "same spot" studies were obtained by first taking micrographs at high magnification, with a light microscope, of a specific structure that could be readily recog-

Jan 1, 1947

By M. Bourassa, R. del Villar, S. St. Arnaud, J. Valenzuela

"Autogenous grinding is used quite frequently for mineral comminution as a result of its lower capital and operating costs. However, it is more difficult to control than conventional grinding, particularly when the autogenous or semiautogenous mill is the only comminution stage (i.e. no secondary grinding is available). Analysis of the control strategy used then becomes extremely important, a task that is greatly simplified by the use of an empirical dynamic simulator:This paper presents the methodology used in the development and the calibration of such a simulator for the autogenous grinding circuit of an iron are concentrator: The various steps are described: industrial data acquisition, preliminary treatment of the gathered information. and empirical modelling of the process. Finally, both the actual and the proposed control strategies are compared using simulation results.This exercise has shown that the variability of some of the controlled variables could be reduced through a better handling of the water addition and the use of filters on some of the signals used for control purposes. The reduction in variability of critical variables, such as power draw, would allow their average value to be increased without the risk of exceeding their safety values. Some advanced control techniques were also tested, with interesting results."

Jan 1, 1995

By G. R. St. Pierre, L. M. Adelsberg, R. Speiser

OXIDE platelets have been observed'-3 in oxidized tantalum adjacent to the metal-oxide interface, Fig. 1. The origin and identity of the platelets are important with respect to the proposal of an acceptable mechanism of tantalum oxidation. At reaction temperatures below 750°C, it has been established that the platelets

Jan 1, 1967

By William Cochran

Data on the cost and quantity available were developed for rutile (TiO2), which is potentially recoverable as a byproduct at sand-washing plants in the Southeastern States of Alabama, Georgia, North Carolina, and South Carolina. Baaed on 1969 production data, an estimated 4,300 tons of rutile could be recovered annually from plants that process more than 25,000 tons of sand per year. Rutile prices at which this resource would be available ranged upward from $262 per ton, compared with the current market value of $185 per ton.

Jan 1, 1972

By P. S. Roller

P. S. ROLLER,* College Park, Md.-The author introduces the idea of a grind limit, or lower size limit of the particles formed directly by grinding, and this is stipulated to be 0.70 micron. I wonder where all the particles come from that lie between the resolving power of the microscope and 0.7 micron, which are seen under a microscope in examining a sample of grind? There is also introduced the idea of excess fines; this is all right in itself but the author's quantitative definition seems to be virtually impossible to justify, and, moreover, is obscure. Just why E, the excess fines, should be defined as the distance between an F line and a [?] line is hard to follow, and just where the distance should be measured does not appear to be stated, as it should be since the F and [?] lines intersect and the distance between will depend upon where that distance is measured. The basis of the presentation is the relation of log weight against log size that was "discovered" by Schuhmann. While this relation is implied to fit, the only evidence that I can see is a slightly irregular line in Fig. I between 2 per cent and 18 per cent by weight and then a precipitous drop at 18 per cent away from any sort of straight line. Some of the conclusions are rather startling. It is stated that E, the excess fines, remains constant for all the comminution products of any particular material, except that it may decrease for some coarse crusher products. No reason is given for this assertion. One would, on the contrary, expect that excess fines, if such a concept is permissible, would generally vary with different conditions instead of being constant. Again, "as much net energy is required to reduce a ton of quartz to particles of the grind-limit diameter (namely, of course, 0.7 micron) by grinding as is required to melt the quartz," This would require many data to prove, but no proof is given; any considera¬tion would reveal the impossibility of such a result. Still further, ore samples "ground to widely different sizes, and with different circulating loads and different size distributions or product, show the same production of new surface area per revolution of the mill, when this grind limit is used." This statement is confuted by ordinary experience, which teaches that grinding efficiency varies generally with the condition of material. For example, the cushioning effect of fines is widely accepted, while the inefficiency of a ball mill when the feed is too coarse is also well known. R. SCHUHMANN, JR.,* Cambridge, Mass.¬Contrary to Mr. Bond's stand, there is a great deal of miscellaneous experimental evidence that comminution does not stop at around 0.7 micron, nor does it cease consuming energy at that point. Comminution is in fact recognized as an important method of producing colloids.5 Mechanical comminution methods were used by von Weimarn6 to produce colloidal dispersions of a variety of solids, including the minerals chalcocite, galena, hematite, stibnite. Utzino7 gives average particle sizes ranging from 0.02 to 0.09 micron for colloids produced by mechanical comminution of several crystalline solids. Andreasen and Berg8 have ground

Jan 1, 1941

By K. Aoki, Y. Mito, S. Shirasagi

The authors developed the TBM Excavation Control System (the TBM Navigator), in order to realize the advanced observational construction. During the excavation using this system, the rock strength value is immediately calculated from the TBM driving data as an index of rock properties, and the drill energy coefficient is also calculated from the drill logging data that is carried out using the probe hole ahead of the tunnel face. In this study, a new, geostatistical simulation-based method is proposed for the automatic prediction of the rock properties ahead of the tunnel face with good precision, using both the drill logging data and the TBM driving data. The applicability of this method is validated through the prediction at the actual tunnel excavation that passes through the faults. Les auteurs ont mis au point un Système de Contrôle de forage avec la machine à pleine section (Navigateur de la machine à pleine section), en vue de réaliser un système de surveillance plus efficace. Avec ce système, la résistance de la roche est immédiatement calculée, au cours du forage, à partir des données de conduite de la machine, comme indice des propriétés de la roche, et le coefficient d'énergie de la foreuse est également calculé à partir des données de log de forage collectées dans un trou de sonde foré dans le front de taille. Dans cette étude, on propose une nouvelle méthode basée sur la simulation géostatistique qui permet de prévoir d’une manière automatique, des propriétés de roches se trouvant derrière le front de taille avec une précision satisfaisante, à l’aide des données de log de forage et celles de conduite de la machine à pleine section. Cette méthode s’est avérée suffisamment précise au cours du forage d’un tunnel réel qui traversait une zone de failles. Die Autoren entwickelten das TBM Ausschachtungssteuerungssystem (den TBM Navigator), um noch besser überwachte Bauarbeiten zu ermöglichen. Unter Einsatz dieses Systems wird die Gesteinsfestigkeit während der Ausschachtungsarbeiten unmittelbar aus den TBM Antriebsdaten als ein Index für die Gesteinseigenschaften berechnet. Gleichzeitig wird auch der Bohrenergiekoeffizient aus den Bohrlogdaten berechnet, die an Hand der Probebohrung am Stirnende des Tunnels erhalten wurden. In der vorliegenden Studie wurde ein neuartiges, auf geostatistischen Methoden basierendes Verfahren für die automatische und angemessen genaue Vorhersage der Gesteinseigenschaften am Stirnende des Tunnels vorgeschlagen, für das sowohl die Bohrlogdaten als auch die TBM Antriebsdaten verwendet werden. Die Anwendbarkeit dieser Methode wird durch die Vorhersage bei einer tatsächlichen, durch Verwerfungen verlaufenden Tunnelausschachtung bewiesen.

Jan 1, 2003

By Bukeikhanov D. G, Syedin V. F, Sagyngaliyev K. S

The present paper describes a method of simulating deposits of com- posite structure by means of computers. The method employs mathematical tech- niques to study the openworks zone formation dynamics in open-pit mines with any mode of the works front ad- vance as well as to determine, on oriented graphs,the optimal direction of openworks expansion.

Jan 1, 1977

By W. S. Anderson

The use of flexible liners for support of underground openings has been investigated by the Bureau of Mines. This report presents installation procedures and instrumentation results of a full-scale flexible liner field installation in the Burgin mine. The flexible liner is a part of the mine support system and has provided maintenance-free support for 22 months

Jan 1, 1975

By Peter H. Toepfer

Hydraulically emplaced, classified mill sands long have been used for stope fill. Entrained water drains rapidly from this type of fill through openings between the sand grains. Slimes are removed to facilitate drainage of the water, thereby lowering dangerous hydrostatic pressures in the fill. Use of unclassified mill tailing as practiced at the Dayrock mine is a recent development and represents a fundamentally different approach to the problems of inhibiting the development of hydrostatic pressures within the stope fill. At the. Dayrock mine, mill tailing is used to form a densely packed fill of sand and slime particles relatively impervious to additional water.

Jan 1, 1952

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By A. F. Otero

During the electrowinning (EW) of copper significant quantities of highly toxic vapors (acid mist) are produced due to the liberation of oxygen at the cathodes. Acid mist affects the health of operators, the environment and plant infrastructure. Acid mist can be decreased to acceptable levels by a combination of physical means (e.g. ventilation, plastic spheres over electrolyte) and chemical surfactants that decrease the surface tension of the electrolyte, modifying the way oxygen bubbles burst at the surface of the electrolyte. However, only few chemical surfactants are compatible with electrolytic applications, and they are not always used due to their high costs. This paper describes the application of a novel surfactant of natural origin (commercial name Mistop®) to suppress acid mist in copper EW process. Mistop® contains triterpenic saponins derived from the Chilean quillaja tree Quillaja saponaria Molina. The product is non-toxic, and poses no risks to the environment or to EW operators. Mistop® was tested at a laboratory, pilot plant and industrial scale in the world?s largest copper EW production plant at Radomiro Tomic (RT), CODELCO, Chile. At a Mistop® dosage of 8-9 ppm, acid mist decreased below the value accepted by Chilean regulations (< 0.5 mg/m3). At this dosage, Mistop® represents and economical alternative to chemical surfactants, and it is currently industrially used at RT.

Jan 1, 2003

By Stephen R. Pogorski, Nicholas Busigin, Colin R. Phillips

The movement of radon away from its source in porous media is determined by two key parameters: the fraction of the total radon formed which enters the intergranular pore spaces, termed the emanation coefficient, and the transport processes which exist in these pores such as diffusion and convection. The first parameter, the emanation coefficient, is of primary importance since it is a measure of the actual amount of radon which is free to migrate within the media. The effects of particle size and radium concentration on the emanation coefficient were examined using a quartz-pebble conglomerate ore from the Elliot Lake mining district of Ontario. It was found that the smallest particle size examined (<74 µm) had the highest radium concentration and contributed the most to the radon emanation. A one-to-one correspondence between radium concentrations for the various particle size fractions and radon emanation was not observed. Samples were examined using scanning electron microscopy and very small particulates were observed to be present on the particle surfaces. When these very small particulates were removed from the host particle surfaces by rinsing, the radon emanation decreased by a factor of 17. This result indicates that most of the emanation comes from the very small particles. The effect of moisture on the emanation coefficient was examined qualitatively and a trend of increased radon release with moisture content was noted.

Jan 1, 1981

By Larry G. Stolarczyk

1.0 FRAMEWORK FOR COMPARISON This document describes the decision factors that bear on the selection of the modulation process for the wireless underground medium frequency (MF) communication system. The selected modulation process must satisfy the Bureau of Mines stated objective of improving general communications within an underground mine. The improvement being sought includes the development of a wireless communication technology of measurable benefit to both mine safety and mine productivity. The improvement will allow wireless communications paths to exist between roving miners. The wireless communication paths will also be made compatible with the existing underground telephone system to extend paging and voice communication throughout the underground mine. The new wireless equipment will include man-pack, vehicular, repeater, and base station transceivers. Repeaters and base stations will feature coupling networks for interfacing with the existing telephone circuits. Frequency modulation (FM) and single sideband (SSB) modulation processes are analyzed in view of the special conditions associated with underground mining. Of primary importance is the tremendous electrical noise generated in an operating mine that could adversely affect communications quality. High noise coupled with high attenuation rate of near field signals forces the communication system to be inherently short range. Fortunately, near field signals can propagate over great distances on underground wires and cables. The framework for comparison is generated by presenting all factors that

By W. L. Cornell

Bulk sulfide concentrate produced from Missouri Pb ore concentrator tailings must be reground to liberate sulfide values for subsequent sepa-ration. Studies to determine grinding parameters for optimum liberation were carried out using optical microscopy coupled with image analysis. The major sulfide phases present in the ground mineral particulates are marca-site, pyrite, sphalerite, galena, chalcopyrite, siegenite. and bravoite. Results showed that the base metal minerals were liberated by grinding to 74 micrometers (200 mesh), but the siegenite and bravoite required grinding to 20 micrometers or less to achieve liberation. Both the experimental method and results are presented.

Jan 1, 1987

By A. B. Cecala

Video technology coupled with data logging exposure monitors have been used to evaluate worker exposure to different types of contaminants. However, previous application of this technology used a stationary video camera to record the worker?s activity while the worker wore some type of contaminant monitor. These techniques are not applicable to mobile workers in the mining industry because of their need to move around the operation while performing their duties and tasks. The Helmet-CAM is a recently developed exposure assessment tool that integrates a person-wearable video recorder with a data logging dust monitor that are worn by a miner in a backpack, safety belt, or safety vest to identify areas or job tasks of elevated exposure. After a miner performs his or her job while wearing the unit, the video and dust exposure data files are downloaded to a computer and then merged together through a NIOSH-developed computer software program called EVADE (Enhanced Video Analysis of Dust Exposure). By providing synchronized playback of the merged video footage and dust exposure data, the EVADE software allows for the assessment and identification of key work areas and processes, as well as work tasks that significantly impact a worker?s personal respirable dust exposure. The Helmet-CAM technology has been tested at a number of metal/nonmetal mining operations and has proven to be a very valuable assessment tool. Mining companies wishing to use this technique can purchase a commercially available video camera and an instantaneous dust monitor to obtain the necessary data, and the NIOSH-developed EVADE software will be available for download at no cost on the NIOSH website.

Feb 27, 2013

By Elmer Palmer

As part of the Goldcorp Inc growth plan Minera Peñasquito SA de CV has developed its polymetallic deposit with a large ?state of the art? concentrator to process lead and zinc ores. The plant consists of two grinding lines including 38ft diameter SAG mills and 24ft diameter ball mills. During mid to late 2009 concentrator commissioning activities commenced. First concentrates were produced in October 2009 and now the plant is meeting its design basis of 65,000 mtpd per line. This paper describes the design and operational experience to date for its grinding circuit design, together with the recently commissioned HPGR crushing circuit.

Jan 1, 2012

By W. Dziurzynski, S. Nawrat, A. Krach

The paper presents research on the influence of the goaf methane inflow on a fire. The problem was investigated by a computer simulation of a fire developing in a goaf. A relevant mathematical model of the fire was selected, which considered both burning of coal and methane. The combustion process is very sensitive on the oxygen and methane concentrations, which was indicated on graphs of the fire temperature evolution. Examples of computer simulation for various location of the fire were considerd. Analysys of results confirms the influence of the content of the goaf methane on development of fires.

Jan 1, 2003

By F. Siciliano, D. Bai, S. Yue, A. M. Elwazri

The influence of niobium addition and very low temperature (`cool&apos;) deformation on the microstructure and properties of low carbon microalloyed steels was investigated. In this work, the specimens were heated at 1200°C and held at this temperature for 20 minutes. Some specimens were aged at 400°C for times ranging from 10 minutes to 10 hours followed by air-cooling. Others were subjected to deformation at 400°C (`cool deformation&apos;) prior to aging. It was observed that the proportion of acicular ferrite was increased as the amount of Nb was increased. It was found that cool deformation increased both yield and tensile strengths significantly compared to that of the aged only specimens.

Jan 1, 2005

By G. Russo

During the construction of the S.Martin La Porte access adit, 9m in diameter, extreme squeezing conditions occurred while crossing Carboniferous schistose formations, with diametric convergence up to 2m. Back-analysis of monitoring results shows that an acceptable simulation of the observed excavation behaviour can be derived using a combined analytical and numerical approach, with simple elasto-plastic laws but a progressive reduction of residual parameters and a relevant increase of dilatancy.

May 1, 2009