Search Documents

By W. W. Adams

[S,1.1.8'"' of explordves -permissible explosivos,21 other high explosives, and black blasting povrder -in the Uni ted States during the caJ.endar yenr 1937 reached a ~ombined total that slightly exceeded the quantity sold in 1936. A larger output was re orted. for permisAiblA and other hig! explosives but asmal-ler for black po~~er. Production of the three classes of explosives totaled 404, 744,294 pounds, more than 3 pel'CGnt over 1336. The total qrumti ty produced included 49,579,441 pounds of perminsibles, 2~8,924,253 pounds of other high ex-plosives, 36,403,950 pounds of black powder in pellet form, and 29,836,65q pounds of bla~k powder in granular form.]

Jan 1, 1938

By Gerhard Derge

The rapidity of oxygen steelmaking has created renewed interesl in the mechanisms and kinetics of the various processes involved. These studies can now be approached with increased confidence because of the more adequate thermodynamics, physical chernislry, and relevant engineering infornzation available. These combine to offer promise of useful control and automation if the details of each specific problem can be sufficiently well-defined. The hot filament microscope provides new insig-hi into many of these problems by direct observation at temperature, allowing the appraisal of the relative importance of thermal gradients, convection, and intermediate phases. All of these have a direct bearing on the overall rates and control of most pyrometallurgical processes. It is one of the special privileges of the Howe Lecturer to become better acquainted with this distinguished man. All of us interested in the metallurgy of iron and steel have developed some sense of his widespread influence by the annual reference to his work in these Memorial Lectures. Each lecturer since 1923 has been able to identify his personal specialty with the broad interests of Professor Howe. This has become even more rewarding with the background information from Professor Gensamer's monograph, "Henry Marion Howe's Contributions to Metallurgy, which brings out his happy combination of intellectual and professional activities. Beyond this, I found my personal bond with Professor Howe in his book on The Metallurgy of Sleel first published in 1891.' After a detailed discussion of the dephosphorizing action of slags, he relates the mineral species identified in the frozen sample to the chemistry of the fused slag with the question, "Is it not most philosophic to hold that these independent entities were wholly integrated in the initial magma; that their presence in it was wholly

Jan 1, 1968

By W. W. Mason

The US began exporting coal in the late 1800s, at first in very small quantities to Canada and, beginning in 1897 and 1898, to the east coast of South America. Shipments to European countries began on a very limited basis in 1902 and these shipments increased gradually until World War I when shipments overseas increased from 7.3 Mt/a to 20 Mt/a. After the war exports dropped as fast as they had increased and, with the exception of exports to Canada, remained at very low levels until just after World War II when the US again emerged as a major coal exporter. World War II left the coal industries of Europe in ruin. As the US was the only country able to supply large quantities of coal at reasonable prices needed for reconstruction of the European economy, the US coal exports overseas expanded rapidly to 38.6 Mt in 1947. Additionally, we shipped 23.8 Mt of coal to Canada in that year for a total export of 62.3 Mt. Unfortunately, that level was not reached again until 1957 when exports reached an all-time high of 69.3 Mt - a high that has not been reached since. Over the years the level of US coal exports has fluctuated fairly widely. Approximately 80-90% of all US coal exports are high quality metallurgical grade coal so our exports level depends directly on world-wide economic conditions and world steel production levels.

Jan 1, 1982

By C. W. Owings, J. J. Forbes

"INTRODUCTION The recent coal-dust explosions in Illinois and Indiana have again brought forcibly to the attention of mining men the fact that mines which liberate little or no methane can have widespread explosions, if dry and dusty conditions exist and if adequate measures are not taken to control the dust hazard by rock dust¬ing or use of water.Even though rock dust has been used more or less extensively for more than 20 years as a means of limiting or preventing coal-mine explosions, many mine operators have requested information on rock dusting and means of allaying coal dust at its source. The purpose of this circular is to summarize available information on these two methods.COAL MINES TO BE ROCK-DUSTEDAll nonanthracite coal mines must be rock-dusted, except those mines or locations in a mine that are too wet or too high in incombustible content to propagate an explosion.Coal dust that contains 20 percent or more moisture may prevent ignition or propagation of an explosion. Such dust can be molded in the hands, and under such condition the roadway would be considered muddy. Mine dust that is only damp is not wet enough to prevent propagation of an explosion. Beads of water standing on accumulations of dust are not indications that the dust is wet. Only those mines or locations in a mine in which the coal dust can be molded in the hand need not be rock-dusted."

Jun 1, 1947

By W. R. Crane

The effect of mining in the red-ore mines of the Birmingham district has been observed for some time, but, except in a few localities, little difficulty has been experienced from disturbance of cover. Cave-ins near the outcrop and fracturing of the surface at greater distances are the most pronounced manifestations of disturbance, while limited areas at points distant from the outcrop and under greater depth of cover have actually subsided. were it not that the orebed is overlain by one or more water-bearing formations, the fracturing or settlement of the surface would not be serious; but because of these formations, fracturing of the top rock may in itself be of sufficient importance to warrant the adoption of protective measures. Further, the collapse of pillars over a wide area may develop squeezes that, if not controlled, may jeopardize the integrity of the mines and necessitate a change in development, from slopes to vertical shafts, at a much earlier period than is now contemplated. Drainsge in these mines has been discussed in papers on mining practice,' but the fact that water, varying from 0.16 to 3.46 and averaging 1.43 times the amount of ore mined, has to be pumped from the mines daily, indicates the importance of the problem and the advisability of making a thorough investigation of the source of mine water, its mode of entry into the mines, its effect upon mining conditions, and consideration of means of improving the conditions.

Jan 1, 1927

By S. Y. B. Subbarao, K. Ravindranath

Lead and Zinc concentrates are being recovered at Rajpura- Dariba (Distt. Rajsamand, Rajasthan, India) from a complex multi metal sulphide deposit since 1984 by selective flotation employing a large number of reagents. The cost of concentrates' production has been high. Due to the increased availability of concentrates world over and to be competitive, it is necessary to reduce cost of production. An effort has been made by the R.D. Department of Hindustan Zinc Limited to bring down the cost by resorting to production of Bulk Pb + Zn concentrate with enough Ag to make it attractive to the smelters. This paper gives an account of open cycle testing and locked cycle testing in the Dowa Continous Mini Flotation unit. The metallurgical data generated in the mini flotation unit indicate the possibility of obtaining smelter-acceptable bulk concentrates containing Pb+Zn 45%, Ag 400 ppm and graphite carbon about 3%. An in-plant trial in the 3000 TPD concentrator indicated that there would be savings through dispensing with and reduction in some reagents, lower power requirement, etc. Also, a substantial increase in revenue is expected due to higher recoveries by resorting to bulk concentrate production as against individual concentrates.

Jan 1, 1995

By Collin Stewart, Greg Hunt, Christopher Mark

Bowie Resources maintains one of the most pro-active ground control programs in the U.S. mining industry today. Its guiding philosophy is that everyone in the organization, from the miners at the face all the way through the top management, are involved in ground control. Some of the unique elements of the Bowie ground control program include: • Roof bolt operators log the stratigraphy of test holes in nearly every cut. These “lith-graphs” are used by section foremen to determine the need for additional roof support, and they are entered into the geologic data base for use in geologic modeling and mapping. • Underground core drilling is conducted to obtain data for CMRR and stability maps. • Weekly “Quality” meetings, involving mine management and technical staff, are held to ensure that ground control information is integrated into production operations. The paper will describe the program in detail, discussing the involvement of roof bolters, section foremen, surveyors, technical staff, and production managers. It will also show how the program has contributed to the mine planning process. Case histories of successful ground control interventions will be discussed.

By M. Al-Hilal, G. Rajja, A. Al-Ali, Y. Jubeli

Abstract -A radiometric survey was carried out over clastic sediments in the immediate vicinity of some phosphatic sediments of Cretaceous age in the Wadi Qasser Al-Hallabat basin of central Syria. The objective was to explore for uranium and to define its dispersion pattern. This was based on ground radiometric surveys and geological studies. All ground surveys (using radon emanometry, track etching, gamma-ray survey and geochemistry) gave similar results, outlining the locations of the radioactive phosphatic formations in the basin, and indicating the dispersion pattern of uranium in the clastic sediments in the surrounding area. The dispersal of uranium from upper Cretaceous phosphatic formation occurs by mechanical weathering and chemical leaching by oxidizing surface waters. A rough estimate is that about one-third of the original uranium content of the Cretaceous sediments has been dispersed. Mechanical erosion is responsible for the main part of this released uranium, which now occurs in Recent sediments. However, the occurrences of spotty secondary U mineralization indicates that another small part of the available uranium must have been chemically leached out by the prevailing oxidizing waters, forming minor surficial minerals.

Jan 1, 1998

By Eugene N. Cameron

Pegmatites occur in abundance in certain areas of South West Africa and in adjacent parts of northern Cape Province in the Union of South Africa. Some of the pegmatite deposits were prospected before World War I, and intermittent mining was done during the period between the two World Wars. The deposits of the Jooste lithium mines became an important source of lepidolite, and beryl, columbite-tantalite, wolframite, and other minerals were produced. Since World War I1 prospecting and mining have been carried on vigorously, with the result that South West Africa produced nearly 3000 tons of beryl during 1949 through 1953, together with more than 40,000 tons of lithium minerals, chiefly lepidolite and petalite. Small amounts of tantalite, columbite, and other minerals have also been produced during the postwar period. Most of this mineral production has come from two pegmatite areas roughly outlined in Fig. 1. One is the Karibib-Omaruru area of north central South West Africa. The second is the northeastern part of the Orange River pegmatite area, which extends into adjacent parts of Namaqualand, in northern Cape Province of the Union of South Africa

Sep 1, 1955

By Richard Deakin

This case study describes aspects of the design of bridge foundations using 320mm diameter steel tube piles in the vicinity of Montréal, Canada. In this area, these piles are a very commonly used and cost effective solution for deep foundations. Typically they are driven through thick Champlain Sea Clay to bear onto stiff, strong rock. However, in some locations there is a layer of glacial till between the base of the clay and the rock which cannot always be fully penetrated by the piles. There is currently little published information, about the bearing capacity of these piles in the local till, and this paper presents and discusses some pile-test data from a recent project. The nature of the glacial deposits in the study area is presented using information gained from published geological data, the project ground investigations and site observations. The design approach and assumptions are discussed, together with the aims and outcomes of preliminary field driving trials and pile tests. The paper then discusses the results of dynamic tests undertaken on production piles. Bearing capacity factors are back analysed from the dynamic test results and compared against values assumed within the design. Observations are made that designers of future foundations in similar conditions may find informative.

Jan 1, 2011

By James G. Crawford

Correlation Of water with its reservoir zone or formation has been one of the applications of oil-field water analysis of greatest direct value to the petroleum engineer. The water in each producing zone tends to have diagnostic characteristics by which it can be distinguished from every other water above or below that zone in that immediate vicinity. Representative analyses of oil-field waters from producing oil and gas fields in the Rocky Mountain region are included, and the diagnostic characteristics are discussed briefly. It is concluded that the generally dilute nature of Rocky Mountain oilfield waters is a result of dilution by meteoric waters, and that there is no relationship between presence or absence of commercial oil and the character of water in a structure. Introduction The study of waters associated With oil and gas began more than 50 years ago and has been well recognized by operators, engineers, and geologists for about 30 years. It appears unnecessary at this time to recite the history of oil-field water analysis; suffice to say that it has proved its worth many times to the production engineer suddenly confronted with water problems in producing oil and gas wells. Chemists and geologists have studied the possible origin of these waters and as Yet the subject is unsolved in many important phases. There are both local and regional problems connected with the explanation of concentrations and character- istics peculiar to each field, each subsurface zone and each province. Criteria useful in postulating the Occurrence of oil Or gas in One province completely fail when applied to another, and data carefully prepared and analyzed from one field may be actually misleading when applied to another. Correlation of water with its reservoir zone or formation has been one of the applications of oil-field water analysis of greatest direct value to the engineer. The concentrations and characteristics of the waters are essential to the engineers and geologists making interpretations of electric logs in this region. The behavior of water under conditions of reservoir temperature and pressure is dependent to a great degree upon its concentration and characteristics, and thus important to the reservoir engineer. With the advent of secondary recovery methods in the Rocky Mountain region the characteristics and treatment of water will become increasingly important. Premises upon which Correlation Is Based A brief review of the geochemical history of oil-field waters will suffice to present the premises upon which correlations of the waters are based. Sedimentary rocks which are now stratified were first sediments in seas, lakes and streams. These sediments were filled interstitially with connate water. With burial the sediments were compressed arid consolidated, integrated and indurated into bed rock and much of the connate water was dispelled. Following the formation of bed rock the strata were sub-

Jan 1, 1949

By D. Newman

An underground limestone quarry, developed in the 1940's, transitioned from a surface quarry to an underground room-and-pillar operation. The quarry expanded to a second underground level when the reserves on the first level reached the property boundaries. The historical basis for the sill pillar thickness between the first and second level, pillar dimensions, and mining height was lost during the course of several changes in ownership. When reserves on the second level reached a five-year life, and plans were initiated for a third level, quarry management embarked upon a thorough evaluation of i. current ground control practices for the support of the immediate roof, ii. roof support in the declines between the surface, Level 1, and Level II, iii. pillar centers and pillar safety factors, iv. pillar alignment between levels, v. mining height within a level, and vi. the locations of declines to access future reserves on level three. The evaluation began with detailed mapping of the location and orientation of calcite veins, joints, fractures, and ground conditions in the immediate roof of Level II. The orientation and location of calcite veins, joints, and fractures on Level II were compared with similar mapping on Level 1, completed in the 1970's to establish whether these features were continuous and would be expected to affect conditions on Level III. Rock strength, physical properties, and fracture spacing were obtained from two (2) diamond core holes drilled from Level I to Level II and two (2) holes drilled from Level II to define the vertical extent of future reserves on Level III. The effort to characterize geological conditions was expanded to a rock mechanics investigation of the: i. performance of the current roof support, ii. optimization of roof and rib scaling, iii. calculation of safety factors for 416 pillars on Level II, iv. evaluation of future pillar centers and mining height within a level based upon pillar strength and pillar geometry, v. development of beam safety factors for the immediate roof on Level II, vi. identification of the most suitable strata for the roof in the future level three, and vii. use of LAMODEL to develop a large numerical model of overburden, inter-level, and total stress on the pillars in levels one and Level II with a stress "footprint" on the proposed level three. The characterization of engineering parameters and geological conditions resulted in changes to the: ? active operations in Level II regarding scaling ? equipment and scaling practices, ? pillar centers, ? mining height, ? raising the immediate roof horizon to avoid ? laminated strata in the current roof, and ? a change in rock bolts from a friction based system ? to active tensioned rebar. The planning and design of level three is ongoing and relies heavily upon the geological and engineering investigations conducted during the past year and one-half.

Jan 1, 2001

By S Henderson, J V. Lawless

The worldwide association of low-sulfidation epithermal gold mineralisation, bimodal rhyolitic-basaltic volcanism and rifting is confirmed in New Zealand. In the currently productive Coromandel epithermal-gold province reported Ar-Ar dating of adularia from low sulfidation deposits falls into two groups at 6 and 7 Ma. Bimodal rhyolitic-basaltic volcanism has been reported to be K-Ar dated at 9 to 7 Ma and 6 to 5.5 Ma. Epithermal gold mineralisation in Northland is spatially associated with bimodal basaltic-rhyolitic volcanism, with rifting cogenetic with that in the CVZ. The Taupo Volcanic zone (TVZ) is sufficiently young that the presence of a segmented rift with recent bimodal rhyolitic-basaltic volcanism can be genetically associated with epithermal gold mineralisation, which occurs as both fossil occurrences and in active geothermal fields. This reinforces the known potential prospectiveness of the Coromandel area and increases that of Northland and the Taupo Volcanic Zone.

Jan 1, 2005

By Xuehui Li, Xinshuai Shi, Jun Wang, Jianguo Ning, Shang Yang, Zhaohui Zhang

Pressure relief is an important step in preventing and controlling rock burst disasters. Hydraulic slotting has emerged as a strategy for pressure relief and energy release in roadway surrounding rock. There is no qualitative description for the response relationship between hydraulic slotting parameters and the degree of pressure and energy release in a roadway, which is a scientific problem. In this paper, theoretical analysis, numerical simulation, and on-site industrial practice were comprehensively used. First, a structural model for the pressure relief and energy release of coal by hydraulic slotting in a deep roadway was established, and the pressure relief and energy release principle by hydraulic slotting was revealed. The principles and methods for determining hydraulic slotting parameters in the roadway were proposed. Three evaluation indices for the pressure relief and energy release effect of coal after hydraulic slotting were proposed, namely, the stress ratio of coal, elastic energy density ratio of coal, and displacement rate of the roadway rib. According to the evaluation indices, the degree of pressure relief and energy release was divided into three levels: reverse pressurization, full pressure relief, and transitional pressure relief. Then, a FLAC3D numerical model was constructed, the levels of pressure relief and energy release under different hydraulic slotting parameters were analyzed, and the optimal slotting parameters were determined. Finally, on-site industrial practices were carried out in Panel 7312 of the Xinhe Coal Mine. An effect test showed that the effect of pressure relief and energy release was remarkable after hydraulic slotting was adopted on the roadway surrounding rock, which can effectively reduce the risk of rock bursts. These research results can further improve hydraulic slotting technology systems and provide a theoretical basis and technical reference for the stability control of deep roadway surrounding rock.

Sep 20, 2023

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By James J. Broderick

In the production of Pig Iron - Limestone, Coke and Iron Ore pellets are changed to the blast furnace and reacted at approximately 2,800 degrees F. The resultant products are molten iron and a molten slag - not unlike lava. The molten slag stream is channeled into open pits, cooled with water, crushed and sized for various industrial applications. The production of steel from pig iron in open hearth, B0P, BOF and electric furnaces results in somewhat similar slags: but since free lime is normally the flux, the resultant slags are not satisfactory for use in cement pastes. When exposed to water, the lime slakes, expands by 250% and ruptures the concrete. Thus, the slag discussed first is Blast Furnace Slag composed of 30 to 40% Silica (SiO2) Alumina (AL202) 7 to 16% Lime (CaO) 32 to 45% and Magnesia (MgO) 5 to 15%. The oxides do not exist as free oxides but rather as silicates and alumino silicates which are chemicall inert. Since transportation costs limit the area of use, blast furnace slag can only be found in concrete products produced within 60 to 100 miles of a blast furnace operation. Even within these areas where slag is in heavy supply, quite often the use of slag is minimal for concrete aggregate and the major outlet is road base.

Jan 1, 1985

By Anne Kathrine Kalager

"Stretching from Norway’s capital, Oslo, to the city of Ski, a new railway line is under construction with a 20 km long hard rock tunnel. This is a major project with high demands regarding quality, cost and schedule. In addition, restrictions concerning locations close to sensitive urban infrastructure require execution with the highest level of precision and expertise. The new double track railway line forms an important part of the intercity rail development southwards from the capital and includes the longest railway tunnel to date in the Nordic countries. With its novel methods and solutions, this project offers a model for future railway project developments in the region. This paper provides general pertinent details and facts relating to this current railway project and includes a description of the project with information relating to concept and design of the tunnels, geological conditions, particular challenges, selected tunneling techniques and contracting strategies. THE FOLLO LINE PROJECT The Follo Line is a new 22 km long double track railway line under construction between Oslo Central Station and the city of Ski. The project is divided into four subprojects, as shown in figure 1. The main part of the project consists of a 20 km long hard-rock tunnel, which will be the longest railway tunnel in the Nordic countries to date.The Østfold Line is the existing double-track railway line running between Oslo Central Station and Ski serving 12 local stations. The new Follo Line will offer a direct service, without stops, between Oslo Central Station and Ski and reduce the travel time from 22 minutes to 11 minutes. After completion of the Follo Line, these two railway lines will, in combination, more than double the capacity for train transport in the region south-east of Oslo."

Jan 1, 2016

"Sedimented hydrothermal precipitates of silica, now fine-grained quartz, are described from a Pb-Zn-bearing vein system. Their discrimination from the wall-accreted fine-grained quartz that is common in the shallow parts of epithermal systems is discussed. Local fine-grained (<0.3 mm) quartz accumulations occur in a suite of veins with otherwise normal drusiform and crustified infills. This sediment may fill the vein above chokes in steep segments (axial plugs), or form continuous layers within the footwall material where the vein is inclined at low to moderate angles. Pads of fine-grained sediment are deposited on the upwards-facing surfaces of wall-rock clasts and of drusiform crystals growing from the vein walls. The asymmetry of these deposits differentiates them from the more common symmetrical, crustified walllining deposits of fine-grained quartz and opaline silica, and requires a gravity-controlled, sedimentary depositional mechanism.Thin section examination shows that much of the fine-grained quartz is present as elongate prisms. The prism habit was present soon after deposition, but it is not possible to identify unequivocally the original sedimented grains. Sedimentation of vein- and wall-rock-derived detritus is also recognized. Deposition of the fine-grained sediment accompanies normal in situ drusiform growth of quartz and other vein minerals. The mammilated and spherulitic textures associated with accretion of amorphous quartz are entirely absent from the Tyndrum veins with sedimented materials. The literature on modern hydrothermal waters and physical chemistry of silica precipitation shows that precipitates of silica suspended in hydrothermal fluids are amorphous and derived from colloidal silica. It is argued that much of the suspended silica was present as quartz at the time of deposition or was converted from amorphous silica almost immediately after deposition.Hydrothermal sediments and their distribution potentially provide information on flow directions and velocity in veins. Plugs of sediment obstruct vertical flow and lead to local flows with large horizontal components. It is shown that sedimentation features occur in other deposits and can involve other minerals. If the features seen here can be scaled up to the size of major veins, they may result in up and downdip variations in mineral assemblages and abundances, which may affect grade."

Jan 1, 2007

By Markus A. Reuter, Bernardete Castro, Antoinette van Schaik, Han Remmerswaal

This paper describes the inseparable relation between product design, liberation, and metallurgical recovery in the optimisation of the recycling of passenger vehicles. This is illustrated by the use of an optimisation model that uses among others a material combination matrix based on metallurgical process data, which depicts the consequences of the quality of intermediate recycling products on the metallurgical material recovery and final alloy metal quality. Various simulations will illustrate the effect of changes in product design and hence liberation on the recycling of end-of-life vehicles. Although this paper focuses on cars, the discussion is equally valid for any end-of-life product. Calibration of the model will be discussed with reference to experiments carried out in order to study the optimal recovery of aluminium applications used in passenger vehicles.

Jan 1, 2003

By J. W. Martin, L. K. Singhal

Grain boundary M23CB precipitates have been shown to form by a process involving the migration of an austenite grain boundary, and each plate of precipitate is in parallel orientation with one of the austenite grains constituting the boundary. The carbide distribution and morphology appear to be sensitive to grain boundary mis orientation. Some areas of austenite grain bowzdary permit the development of an array of M,C, particles, some of which are in parallel orientation with one grain and some with the other grain constituting the boundary. Massive carbide at grain boundary triple points is also shown to be in parallel orientation with one constituent grain. PREFERENTIAL precipitation during aging of carbides of the type (Fe,Cr)23C6, usually written MZ3C6, in grain boundaries of quenched austenitic stainless steels has been widely recognized. M23C6 has a complex cubic crystal structure&apos; which contains ninety-two metal atoms and twenty-four carbon atoms per unit cell. Less energy is involved in forming grain boundary precipitates than in the formation of intragranular precipitates, and the process is further enhanced by the accelerated diffusion rates in the boundaries and by the probability of segregation of chromium atoms and carbon atoms to the region of the grain boundaries during prior solution heat treatment in order to reduce lattice strain. Early electron micrographic studies2, 3 involving either extraction replica or normal replica techniques established the geometric or dendritic form of the carbide particles, although this approach led to dis- pute as to whether the particles grew within the plane of the boundary or grew into the matrix.4-6 More recent thin-foil studies&apos; have claimed to identify a discontinuous precipitation process involving M23C6 at grain boundaries, and the object of the present work was to attempt to clarify the situation using modern electron micrographic and diffraction techniques. 1) EXPERIMENTAL 1.1) Material. The steel selected for this work had a base composition of 24 pct Ni-25 pct Cr-3 pct Ti and contained about 0.04 pct C. The full analysis if given in Table I. This alloy was in the form of strip which had been hot- and cold-rolled to a thickness of 0.6 mm. 1.2) Heat Treatment. Specimens 4 cm long by 1 cm wide were solution-heat-treated for 3 hr in argon at 1150°C, followed by water-quenching. Specimens were subsequently aged in vacuo at 750°C for periods up to 500 hr. 1.3) Preparation of Electron Microscope Specimens. The heat-treated strips were cut bv spark machining into discs of 3 mm diam and 0.6 mm thickness. he-discs were dished on both sides using an electrolytic jet of 15 pct HCl electrolyte at 80 v. Final electro-polishing of the discs was carried out using 10 pct perchloric acid, 20 pct glycerol, and 70 pct ethanol at 10 v. The current density was kept below 300 ma. cm"2 by cooling the electrolyte to 0" to 5°C. As soon as a small hole appeared, the electropolishing was stopped and the specimen was quickly washed with ethanol.

Jan 1, 1969