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By Florian Kongoli

While calcium ferrite slags have been successfully used in continuous copper converting for the last 30 years, ferrous calcium silicate slag was proposed about 8 years ago as an additional alternative for copper smelting. Although both slags are normal extensions of each other their phase relations have not been completely clarified. In this paper the liquidus relations of both slags have been quantified at various areas that cover both of them. The existing experimental data have been first reviewed and discussed in relation to the solidification procedure. An original physical model is then used to predict various diagrams of the liquidus surface of both slags. It is shown that the ternary liquidus diagrams normally used for FeOx-SiO2-CaO system are not suitable for industrial slags. The new model diagrams of Fe/CaO versus SiO2 and Fe/SiO2 versus CaO as well as Fe/CaO versus Temperature and Fe/SiO2 versus temperature are proven to be much more convenient for ferrite and ferrous calcium silicate slags. Based on these diagrams the effect of SiO2 and CaO on the melting temperature is quantified. The effect of Cu2O is also quantified through the model. Some Fe/CaO versus Cu2O and Fe/SiO2versus CaO at various copper contents are predicted and the results show good agreement with the experimental data. It is also shown that in the presence of liquid copper, Cu2O is dissolved in the slag depending on the oxidation degree of the system and might lower the liquidus temperature. Some discussions are also presented taking into account plant observations and important conclusions are drawn for copper smelting and converting

Jan 1, 2006

The Dizon open pit mine of Benguet Corporation in western Central Luzon, Philippines has yielded some 182 000 t copper, and about 26 000 kg gold and 48 000 kg silver as by products since it started operation in November 1979. The 140 million tonne orebody is associated with a small quartz diorite porphyry stock emplaced in volcanic rocks on the basal slope of a stratovolcano complex as stockworks, fracture fillings and disseminated sulphide mineralization averaging 0.43% Cu, 0.93 g/t Au and 2.5 g/t Ag. Intense hydrothermal alteration accompanied the mineralization that developed fairly distinct mineral assemblages within and around the intrusive. Post-ore volcanic activity later gave birth to an upward-flaring diatreme which broke out south of and adjacent to the orebody and partially destroying it. Subsequent volcanic activity buried the mineralized area along with the rest of the stratovolcano's surrounding slopes under a thick deposit of pyroclastic and laharic debris. Erosion eventually removed the volcanic cappings over Dizon and also exposed the quartz diorite porphyry stock which might have resulted in the truncation of a sizeable section of the Dizon deposit. The chain of stratovolcanoes that comprise southeastern Zambales range hugging the southeastern edge of the Zambales ophiolite is part of a west-facing volcanic arc that extends for some 300 km along the western margin of central and southern Luzon whose development has been correlated to the subduction in the Manila Trench located off the west coast of Luzon. Prominent WNW-trending lineaments that cut across the ophiolite appear to be splays of the Philippine Fault whose intersection with the Mt. Pinatubo stratovolcano complex might have localized the emplacement of a number of intermediate stocks along with the gold-rich porphyry copper mineralizations associated with some of them.

Jan 1, 1987

By J. S. Kennedy, A. A. Lerew, C. M. Judson, G. L. Simard

DITHIOPHOSPHATE collectors are commonly used in the flotation of sulphide minerals. Studies of the interaction of a typical dithiophosphate collector with galena surfaces have been previously reported from. these laboratories." These fundamental studies were carried out by employing phosphorus labeled radioactive dithiophosphate. Radioactivity determinations then could be used to measure readily and accurately the small concentrations of dithiophosphate that, are present under conditions of flotation processes. Measurements were made on ground mineral, determining the amount sorbed indirectly from the concentrations in solution; and studies were also made with single crystals, determining the amount sorbed directly by counting the crystal surface. The rates, isotherms and reversibility characteristics of dithiophosphate sorption, the competition between phosphate and dithiophosphate for the mineral surface, and the exchange of sorbed dithiophosphate with dissolved dithiophosphate were studied. These studies have now been extended by sorption measurements in flotations with a Fagergren, machine. For this work, the selective flotation of galena and sphalerite from quartz was chosen, using ammonium di-(sec-butyl) dithiophosphate as. the collector, sodium cyanide as depressant for sphalerite, and copper sulphate as an activator for sphalerite. While the selective flotation of galena and sphalerite using a single dithiophosphate collector is not typical of flotation practice (two different collectors are generally used), it was found that a reasonably good separation could be obtained by using zinc sulphate with the sodium cyanide in the galena flotation and by cleaning the sphalerite concentrate or by carrying out the sphalerite. flotation in an alkaline medium. Data of practical importance on the distribution of collector between the concentrates, tailings, and solutions were obtained, particularly with regard to the effect of copper sulphate and sodium cyanide. In addition to the. selective flotation of galena and sphalerite from quartz, single flotations of galena-quartz and sphalerite-quartz mixtures were carried out, along with blank flotations on quartz alone. The present paper describes the results of these experiments. As in previous papers, the term sorption is used to designate uptake of collector by the mineral, without implication as to the nature of the processes involved. Experimental Materials: The mineral system was a ground synthetic mixture of galena, sphalerite, and quartz. The galena was from Galena, Kans., and contained 75 pct lead (theoretical 85.6 pct Pb for PbS); the sphalerite, from Ottowa County, Okla., contained 63 pct zinc (theoretical 67.2 pet Zn for ZnS) ; and the quartz from Klondike, Mo., analyzed as 99.97 pet SiO2. Sulphur labeled radioactive di-(sec-butyl) dithiophosphate was prepared from S82 supplied by the Oak Ridge National Laboratory on allocation from the U. S. Atomic Energy Commission. The synthesis consisted of precipitating barium sulphate, reducing the barium sulphate to barium sulphide, acidifying to form hydrogen sulphide, and oxidizing the hydrogen sulphide with iodine to elemental sulphur.

Jan 1, 1952

By Matthias Neuenschwander, Andreas Theiler, Patrick Steinle, John Singer, Martin Vogel, Diego Martini, Ömer Ündül, Markus Weh

"Quartz Dust is a major health hazard in underground works, wherever the ground contains quartz and depending on the chosen method of excavation. A research project initiated by the Swiss Tunnelling Society and realized by the Swiss Federal Institut of Technology, Zurich, established a correlation between the potential of quartz dust generation during excavation and well known geotechnical characteristics – the Cerchar Abrasivity Index CAI and the Uniaxial Compressive Strength UCS - of ten typical Swiss rocks. The results are at the center of a new guideline by the Swiss Society of Engineers and Architects on the requirements for early project stages regarding ventilation and logistics in function of the quartz dust related risk of the expected ground type of the project. The approach presented could be applied worldwide, contributing to more effective health protection as well as to better cost stability in underground works. CONTEXT Respirable quartz dust (aerodynamic diameter of particles < 10 micron) is universally recognized as a major workplace health hazard. Chronic bronchitis, silicosis and lung cancer can be caused by excessive exposure to quartz dust, as has been proved by many medical studies. Therefore, the legislations of many nations specify a maximum workplace concentration (Maximale Arbeitsplatzkonzentration MAK, Occupational Exposure Level OEL). In Switzerland, for example, the Threshold Limit Value TLV for respirable Quartz or Crystalline Silica imposed by the Federal Committee on Exposure Levels (Grenzwertkommission) is 0.15mg/m3 air. Some nations refrain from establishing a OEL because of the carcinogenic nature of quartz."

Jan 1, 2016

By G. Upadhya

Considerable success has been achieved recently in modeling microstructural evolution during solidification of castings bthrough the coupling of macroscopic heat transfer with microscopic solidification kinetics models. However, a complete model for simulation of solidification in complex shaped castings involves: (i) the description of fluid flow, during and after mold filling, coupled with (ii) heat transfer to the mold and surroundings by use of a macro model, followed by (iii) a description of subsequent solidification of liquid metal by use of a micro model for solidification of the alloy under consideration. This paper describes the coupling of solidification kinetics model to a 3D, transient, fully coupled fluid flow and heat transfer model. Coupling between the macremicro models is achieved by using the latent heat method. Micro models for the eutectics of gray, white and ductile iron are discussed. This coupled code has been used for predicting the thermal history and microstructural data for shaped castings. Various applications of the model, including prediction of shrinkage defects, grain density contours, and graylwhite transition region in the casting, are presented for a relatively complex casting geometry.

Jan 1, 1992

By P. Berendsen

The tectonic and sedimentary environment of the Central North American Rift System (CNARS) provides all excellent setting for major mineral deposits. Major north-northeast-trending high-angle normal or reverse faults and northwest-trending transcurrent fault systems may exercise control over ore forming processes. Gabbro and basalt are the dominant igneous rock types. Carbonatite and kimberlite occur in Nebraska and Kansas. Concentrations of Cu. Ni, Co, Ti, Au. Ag and PG-minerals are known to occur in this setting. Arkosic sandstone, siltstone, shale, and minor carbonate units occur on top of the rift basalts and in flunking basins where they may reach thicknesses of 10 km (6 miles). The potential, for stratiform or unconformity-related metalliferous deposits must be considered. The rift as a whole remains, however, largely unexplored.

Jan 1, 1990

By M. H. Caron

D. C. Ralston—The fact that none of the organizations that have worked on these ammoniacal leaching processes have contributed discussion of Mr. Caron&apos;s papers today is a matter of some disappointment. Adaptations, modifications and improvements have been made by several organizations or individuals and to complete the record I want to document a number of them. The Nicaro Nickel Co. operated a Government owned plant at Nicaro, Oriente, Cuba, during the past war. A report on the project was written for Reconstruction Finance Corp. and is in the document file collected by the Office of Technical Services, Commerce Department and filed with the Library of Congress, where it can be consulted or bibliofilm or photostat copies obtained by asking for copies of PB 97271. Nicaro Nickel Co. has obtained a series of U.S. Patents, my list (probably incomplete) of which bears the following numbers: 2,400,098; 2,400,114; 2,400,115; 2,400,461; 2,400,612; 2,458,902 and 2,473,795. International Nickel Co. has also studied the problem and U.S. Patent 2,478,942 shows that some of the complications involving occasional low extractions have been unraveled. Forward, Samis, and Kudryk, of the University of British Columbia, have also published a study of copper-nickel sulphide concentrate.&apos; Others are interested and it is evident that this type of hydrometallurgy is likely to find a happy application in the not-too-far distant future. Caron&apos;s two papers practically amount to a summation of his life&apos;s work on the important subject of nickeliferous iron ores and the American Institute of Mining and Metallurgical Engineers is fortunate to have been chosen the medium of publication. M. Rey—The ammonia leaching process has been the subject of certain studies in New Caledonia, but at the present time, the conditions are not very favorable to its adoption. The process is a combination of a thermal and a hydrometallurgical process. As a result, the first costs and the operative costs are rather high. To counteract this unfavorable situation, it would be necessary to make a very high extraction. But unfortunately, the process is delicate and in spite of all of Caron&apos;s valuable work, there are still many unknown factors. It is difficult to obtain regularly a high extraction, exceeding 75 to 80 pct. It would be interesting to have the opinion of Inter-national Nickel on the process and to know what the Dutch are doing in Celebes. M. H. Caron (author&apos;s reply)—I am quite familiar with the different types of nickel and cobalt ores as found on New Caledonia, and it may be pointed out that the Celebes ores are quite the same in their properties. Their behavior when treating the ores by the ammonia-leaching process is also alike and in my opinion, there is no reason why a high extraction of the New Caledonian ores could not be obtained if the process is properly applied. For the sake of completeness I may add that one of my patents has not been discussed in the papers. This patent deals particularly with the treatment of serpentine nickel ores. (Netherlands No. 62693 40a, French No. 965.786 April 21. 1948. and Cuban No. 13.625 Jan. 1950.)

Jan 1, 1951

By Qian Xu, Xionggang Lu, Xingli Zou, Zhongfu Zhou, Shuhua Geng, Hongwei Cheng

Herein we report an electrochemical route from oxides (SiO2, TiO2)/sulfide (MoS2)/carbon mixture precursors to Mo-Si-Ti-C composites in molten salt. The electrochemical process was carried out in molten CaCl2 at 800 °C with a potential of 3.1 V, and a graphite-based anode was used in the electroreduction process. The reaction mechanism and the influences of the stoichiometry of the initial mixture precursor on the morphology and phase composition of the final products were investigated. It has been found that Mo5Si3/MoSi2/Mo3Si/Mo, Mo5Si3/MoSi2/Mo2C/SiC, and Mo5Si3/Mo2C/Ti3SiC2/TiC/Mo composites can be electrosynthesized directly from their oxides/sulfide/carbon mixture. The preliminary experimental results suggest that the electroreduction process can be used for the controllable electrolytic production of alloys/carbide-containing composites from oxides/sulfides/carbon precursors.

Jan 1, 2016

By Magnus Gynnemo

The primary purposes of drilling and blasting in hard rocks is to fracture solid rock and prepare it for excavation and subsequent transport to the crushing plant. Using explosives in excavation operations without counting for the geology gives no consideration to the quality of the macadam product or the excess production of waste material (fines).

Jan 1, 1997

The use of systematic review methods, derived from System Safety approaches used in the North American nuclear power industry, have become an accepted approach for seeking "approval" for new coal mining equipment and operational changes in NSW. Based on risk analysis, they provide a valuable and needed framework for the reduction of losses related to people, equipment and production.

Jan 1, 1991

By C. J. Weiss

"A commercially available Through-the-Earth (TTE) communications system was evaluated at an underground coal mine in eastern Kentucky. This field study was conducted as part of a larger multi-site evaluation of available TTE systems to determine their operational sensitivity. Field testing is being performed along with simulation techniques developed for geophysical surveys. The results of the field test will additionally be used to determine the applicability of these simulation techniques to TTE communications. The mine detailed in this paper was idled at the time of the study, which provided the nearest practical representation of a post-event mine shutdown. For this study, the three following communication modes were tested: surface-to-underground, underground-to-surface and surface-to-surface. Standard deployments of the TTE system using the manufacturer’s recommended procedures were able to achieve clear communications between underground and surface locations. Other arrangements of the units yielded intriguing results, some of which were predicted by computer simulations, others were unexpected. Future experimentation is planned to further evaluate the observed phenomena. INTRODUCTION The ability to establish effective communication between surface and underground personnel after a mine event is essential for both mine evacuation and mine rescue efforts. Current communication technology is reliant on physical infrastructure, such as antennas, cables, and repeaters, located throughout the mine. Such systems are easily disabled during a mine event because of their vulnerability to physical damage. A true emergency communications system would have the ability to function regardless of a mine’s physical state. Through-the-Earth (TTE) wireless communications technology has the potential to provide such a tool. Wireless TTE communications are exceptionally challenging because electromagnetic (EM), or radio, signals are subject to drastic attenuation as they travel through solid strata. In addition to attenuation, EM wave propagation is directly affected by the physical and petrographic characteristics, mineral compositions, metamorphic properties, and the degree of water infiltrations in the strata [1-5]. These strata characteristics are unique to each mine thus making the design of an effective, universally deployable, and reliable TTE communications system very difficult. At present, TTE technology is in the preliminary stages of practical deployment with only a few permissible TTE systems commercially available."

Jan 1, 2015

By Ronald S. Conti

This is the fourth and final article in a series that discusses underground fire-fighting preparedness. As with the previous three articles, it is based on interviews with 214 miners at 7 underground coal mines (referred to as Mines ?A? through ?G?) conducted by researchers of the National Institute for Occupational Safety and Health?s(NIOSH) Pittsburgh Research Center[Vaught et al. 1996]. The first article presented an overview of the study conducted by NIOSH on mine fire response preparedness and provided a general perspective on underground mine fires. The second article discussed miners? preparedness to evacuate a fire and their experience with incipient fires. The third article described miners? experiences in fighting underground mine fires and presented their perceptions of training and readiness for fire-fighting. This final article in the series offers suggestions to improve mine fire-fighting preparedness.

Jan 1, 1997

By Yoshio Nakano

Keywords: Tannin gel, Palladium, Separation, Redox We have developed the novel recovery system of palladium from wastes, which is simple and generates little secondary waste in comparison with the conventional recovery processes, using tannin gel particles synthesized from condensed-tannin molecules. Pd is adsorbed onto the tannin gel particles through inner-sphere redox reaction mechanism: two-electron transfer from tannin gel to Pd(II) species, accompanied by ligand exchange between chloropalladium(II) complexes and tannin molecules. In addition, we propose the separation system of Pd and Au from Pd-Au mixture, which is feasible due to the difference in oxidization and reduction potential between Pd and Au species: PdCl3(H2O)? and PdCl42? are less adsorbable than Pd species containing fewer Cl, such as PdCl2(H2O)2 and PdCl (H2O)3+, while such a distinct difference between Au species is not observed.

Jan 1, 2005

By N. A. D. Parlee, N. M. El Tayeb

Fe-V alloys with small percentages of vanadium show no deviations from Sieverts&apos; Law up to P~, = 1 atm in the 1600º to 1750ºC region. At somewhat under 8 pct V and up to at least 20pct V, at 1604" and 1661 °C, nitrogen absorption follows Sieverts&apos; Law at low Pn2 values, but deviates from this law beyond critical values of pn2, due to formation of a nitrzde phase of approximately VN composition. The behavior below these solubility limits can be described at all temperatures by the equations: RAO and parlee1 suggested that the nitrogen absorption curve for liquid iron alloys takes the general form shown in Fig. 1 when an alloy nitride precipitate is formed. They showed that the precipitation of 6 titanium nitride from liquid Fe-Ti alloys follows this general scheme and dealt with the general theory involved. Recently, Evans and Pehlke2 reported their research on the precipitation of aluminum nitride from liquid Fe-A1 alloys. Fountain and Chipman&apos;s recent paper3 on the precipitation of boron nitride from solid solution contains a fine example of the analogous behavior which they have been studying in the solid state. Researches on the absorption of nitrogen by liquid Fe-V alloys have been described by various authors.1,4-7 Most of this work has been confined to fairly low vanadium concentrations and rather high temperatures because of difficulties variously described as, formation of surface scums, bridging, and so forth. This behavior and the rough thermo- dynamic calculations made by chipman,8 over eleven years ago, indicated that excessively high vanadium concentrations should not be required for vanadium nitride precipitation. It seemed desirable to look for and study this precipitation in order to fill out the thermodynamically interesting nitrogen absorption data on these alloys. EXPERIMENTAL METHOD The general method used was essentially the same as employed by Rao and parlee,1 in which a Sieverts type of apparatus was used and the precipitation of the nitride detected by the "break-point" in the Sieverts&apos; Law line, and by the visual observation of the formation of the new phase on the surface of the melt. There were, however, a few differences in apparatus and technique as described below. The oil manometer used by Rao and parlee&apos; to measure low partial pressures of nitrogen was not employed. The present authors sought to avoid as much as possible the exposure of the liquid alloy to low total pressures of gas during the 6 to 10 hr long runs because of the heavy iron evaporation-loss errors involved. This was achieved, partly by keeping evacuation times to a minimum with fast pumping but largely by the use of two burettes, one for argon and one for nitrogen, and using them to equilibrate the alloy with mixtures of argon and nitrogen rather than nitrogen alone. Each run involved a careful sequence of operations. After melting, de-

Jan 1, 1963

By M. Amani, A. Akbarinasab, M. Bazmandeh

The fourth iron ore production plant at Golgohar mining and industrial company consists a ball mill and wet medium intensity magnetic separators (3500 Guss). The ball mill product applies directly into MIMS and the MIMS concentrate directly transfers to the low intensity magnet separators (LIMS). The thickener is used for dewatering of MIMS and LIMS tailings. By sampling from streams of ball mill and separators, it was defined that the grade and iron recovery were 60% and 80% respectively while they would be 66% and 90% respectively based on the designing documentation. The average of P80 in the ball mill was 342 micron in a month that is coarser than optimized value. This problem was related to unsuitable operation of grinding. For optimization of grinding efficiency, the amount of charge volume was investigated as a variable. The measurements illustrated 32% charge volume. For increasing grinding efficiency, the charge volume was increased 1% and 1.6% in two stages. The results showed ball mill power draw average reached from 3650 kw to 4120 kw and the average P80 reached to 329 micron. All of parameters calculated about 35 day before and after change. Average of Ball mill feed iron ore grade before and after change was 49.24% and 50.32% respectively. This change caused an increase in efficiency of MIMS, where the enrichment ratio and concentrate grade increased 2% and 1.9% respectively. For increasing the iron grade of the MIMS concentrate; the orifice of the tail flow exit pipe changed from 4 inch to 6 inch and the concentrate grade increased 2%.

Jan 1, 2014

By Dario Bernabe

This paper evaluates four open pit mine scheduling programs recently developed and compares them in order to determine if significant differences exist among them. The same input data, which consist of a 3-D block model, an economic set of parameters, and the initial surface topography for a operating copper mine in Southern Peru, was used to test each technique.

Aug 25, 2002

The introduction of cement into underground backfilling at The Zinc Corporation, Limited and New Broken Hill Consolidated Limited mines to improve mining efficiencies gave rise to several major problems, the magnitude of which had not been anticipated. These problems were 1. A loss of recovery in the milling circuit due to the presence of cement 2. The presence of cement-rich slime layers on the surface of the fills 3. The introduction of a safety hazard due to the slippery nature of the surface of cemented fills 4. The deposition of cemented slimes on the levels and in underground sumps and dams. The loss of revenue due to decreased metal recoveries considerably offset the gains from increased stoping efficiencies and the use of cement was substantially reduced while, (a) the Metallurgical. Department attempted to identify the chemical nature of the problem and overcome it, and (b) the Mining Department investigated methods of reducing cement contamination of the ore stream. As a part of this investigation the Mining Department added polymeric flocculants to the cemented fill pulp. Testwork was carried out in the following steps 1. The available Alfloc polymers were screened to determine which was the most effective and what was its optimum dosage rate. 2. This polymer was used in the laboratory to determine the reduction of surface slime, clarity of water, and effects on strength and percolation of fill. 3. Fills were placed underground to substan- tiate the laboratory work. /+. The polymer was then added to all cemented fills going underground to study its effect over a long term. The use of flocculants not only improved the distribution of cement in the body of the fill, but also the distribution of the fines fraction of the filling material, practically eliminated slippery surfaces and improved the clarity of the drainage water. Flocculant is now added to all cemented fills and restrictions on the use of cement are gradually being lifted.

Jan 1, 1973

By R. S. James, S. P. Goff, A. E. Armitage

"Oxide-facies banded iron formation in the Third Portage Lake area is hosted by ultramafic and calc-alkaline volcanic rocks and related sedimentary rocks of the Archean (2.8 Ga) Woodburn Lake Group, 80 km north of Baker Lake. These rocks record at least two phases of metamorphism/ metasomatism. Greenschist facies metamorphism, in the temperature range of 370°C to 520°C and at pressures above 2.3 kbar, has affected all rocks on a regional scale. Later mineralization and alteration of banded iron formation (BIF) and associated volcanic rocks resulted from metasomatic fluids which carried Mg, K, Ca, S, As, Cu and Au. These fluids were confined to ductile to brittle, cross-cutting and layer-parallel micro-shears developed in the thickened hinge region of a shallow plunging recumbent fold. Metasomatic reactions yielded cummingtonite + biotite-bearing assemblages which are associated with strongly mineralized iron formation. Pyrrhotite is the dominant sulfide phase and occurs within ductily deformed iron formation where it pervasively replaces magnetite. Minor fine-grained chalcopyrite and arsenopyrite generally occur as inclusions within pyrrhotite and recrystallized magnetite, and rarely as individual grains. Pyrite is restricted to brittlely deformed iron formation, and to the contact between iron formation and altered ultramafic rocks, where it is associated with quartz veins. Pyrite typically replaces pyrrhotite. Native gold is associated with both pyrrhotite and pyrite, but higher gold concentrations are associated with pyrite. Grunerite/Ca-amphibole + stilpnomelane and sparse pyrrhotite and pyrite characterize weakly mineralized iron formation. Within adjacent ultramafic rocks, metasomatic reactions yielded assemblages of interlayered Ca-amphibole + biotite, and talc + Ca-amphibole + carbonate + biotite. K-Ar geochronology on metasomatic biotite from mineralized BIF yielded a 1791 ± 32 Ma age.An epigenetic model is favored for the emplacement of gold. The age of the gold mineralization in the Third Portage Lake area is uncertain, but may be Proterozoic based on the preliminary isotopic age and by analogy with Proterozoic gold deposits elsewhere in this part of the Churchill Structural Province. Copyright"

Jan 1, 1996

By C. Allen, H. Zhang, L. Falk

Shock loss occurs when there is a change in the area of a drift or airflow direction. These shock losses accumulate throughout the ventilation system and will increase the mine resistance as underground development deepens or becomes more complex. Hence, shock losses should be carefully considered when establishing the resistance through a series of branches as they can be a significant contributor to the estimated mine resistance. Using computer software to simulate a ventilation system is common but applying reasonable shock loss factors in the software is not a simple or direct process. Determining shock loss values includes the consideration of historical measurements, application of factors and formulas from literature based on the geometry and complexity of junctions, and the geometry variation at different locations. For example, the shock loss at the bottom of a ventilation raise can consist of a 90° bend and a sudden area change. This paper presents an approach for estimating shock loss factors near raise junctions using computational fluid dynamics (CFD). Current and future work will also be compared with field measurements. Results from this approach are compared with software defaults as well as classical techniques in published literature and standards.

Sep 1, 2024

By Emma Arakelova

An increase in concentration of a Zn-containing volatile complex for synthesis of ZnO films was investigated when processing their target by ultraviolet radiation emitted by mercury lamp. The experiments were carried out using a flow-type quartz reactor. ZnO tableted target was preliminarily irradiated during 2 to 7 hours. H2O2 (98%) vapor at 25Pa passed through the reactor with ZnO target at 373K. As substrate material, five subsequent quartz cylinders were used at 423K. The experiment lasts 4 hours. H2O2 decomposition on ZnO surface was accompanied by formation of a Zn-containing volatile complex which passed in gas phase and decomposed on the substrates with isolation of final ZnO. The concentration of the Zn-containing volatile complex (N) in gas phase increases with UV pre-irradiation time (t) (without irradiation N = 1.05 1011 particles/cm3; after t=2 hours, N = 5.19 1011 particles/cm3, after t=4 hours, N = 9.95 1011 particles/cm3; after t=7 hours, N = 1.86 1012 particles/cm3.

Jan 1, 2006