Search Documents

By E. Posnjak

IT is rather the general belief that acidified solutions of ferrous salts are readily oxidized when in contact with air, and often elaborate pre-cautions are taken to prevent it. This, however, is not the case and several statements may be found in the literature expressing surprise at the extreme slowness with which oxidation takes place when air or oxygen is bubbled through such a solution. Thus C. Baskerville and R. Stevenson1 "observed with surprise" that no. oxidation apparently took place, as shown by titration with 0.5 N KMnO4, when a stream of air was passed for 3 hr. through an acidified solution of ferrous ammonium sulfate or ferrous sulfate. The same authors state that even the presence of salts such as cobalt, chromium, copper, manganese, etc., which usually act as oxygen carriers, had "no effect upon the oxidation as was observed by, passing air for 3 hr. through solutions of Mohr's salt acidified with sulfuric acid." While this statement will be proved further on to be at least partly incorrect the slowness of the oxidation of ferrous salts alone has been previously established by McBain.2. His investigation also showed that the rate of oxidation increases markedly with an increase in the concentration of ferrous sulfate as well as that of oxygen; the concentration of free acid had a comparatively small influence, which in the case of sulfuric acid was to retard slightly the rate of reaction. More recently R. Thomas and E. T. Williams3 investigated the catalytic effect of nitric oxide on the oxidation of ferrous salts, which had been earlier patented by McCulloch.4 They found that the probable mechanism of the catalytic action was the oscillation of the catalyst between two stages of oxidation and its interaction alternately with the oxygen and the ferrous iron.

Jan 1, 1927

Objective: To identify and evaluate a permanent stopping to direct ventilation airflows in large-opening metal/nonmetal mines.

May 1, 2006

By L. R. Shotwell, C. F. Voss, R. J. Bastian

Pacific Northwest Laboratory (PNL) currently supports the U.S. Department of Energy's Office of Civilian Radioactive Waste Management in developing and evaluating analytical methods for assessing the suitability of sites for geologic disposal of high-level radioactive waste. The research includes consideration of hydrological, geomechanical , geochemical , and waste package components and the evaluation of the degree of coupling that can occur between two or more of these components. The PNL effort and those of other research groups investing potential waste sites in the U.S. and abroad are producing a suite of computer codes to analyze the long-term performace of the proposed repository sites. This paper summarizes the ongoing research in rock mechanics at PNL involving flow through jointed rock. The objective of this research is to develop a methodology for modeling the coupled mechanical-hydrological process of flow through joints and then attempt to validate a "simple" model using small -scale laboratory test data as a basis for judging whether the approach has merit. This paper discusses the laboratory tests being conducted to develop s joint behavioral constitutive model for the numerical method under development and the modeling approach being considered.

Jan 1, 1986

By Faruk Oksuz, Clay Haynes, David Egger

The United States Army Corps of Engineers (USACE) has committed to solve a major drainage problem in the suburban Chicago community of Griffith, Indiana. The Cady Marsh Ditch is currently undersized and on occasion spills its banks causing flooding and economic setbacks to the community. Preliminary studies have identified both tunnel and surface solutions as being attractive and viable. The USACE has decided that this project is an opportunity to use the design-build contracting approach to maximize ingenuity in project approach and to allow the market to dictate whether a surface or subsurface solution is most attractive. The tunnel would be over one-mile in length through sands, gravels and clay. Water control will be an issue during tunneling. The paper will explore the contracting approach to the project and the adaptation of Underground Technology Research Council (UTRC) guidelines for underground contracting to a design build project. The roles of Owner, Owner’s consultant, and design-build contractor will be defined as interpreted by the USACE and key contract provisions will be described and contrasted with a traditional design-bid-build approach to tunnel construction.

Jan 1, 2003

Henry D. Hibbard, Plainfield, N J. (communication to the Secretary*):—This very interesting history is a valuable addition to our knowledge of the basic process and its introduction to this country. In addition to the attempts noted in the paper which were made here to establish the basic Bessemer process, and the experiment with the Siemens-Martin process at the Otis works, there were others made with the latter-named process at about the same date, all of which failed or, at least, were discontinued. The first attempt which survived was that of Carnegie,

Jan 1, 1911

By Herbert Herman, M. E. Fine

THE first decomposition product of a supersaturated aluminum-rich A1-Ag alloy at low tempera- tures is Guinier-Preston zones.'-, The zones are ideal and each consists of a spherical shaped silver-rich cluster about 16 A in diam syrounded by a silver-poor shell approximately 72A in diam.' The composition of the two regions is not known with certainty., After quenching from the solution anneal, these zones form rapidly on aging at temperatures as low as -30°C.5 The rate of zone formation increases with aging temperature; the activation

Jan 1, 1961

By Jurgens PE Hamman, Faisal Putra, Hadnaltias Alpeki, Willem de Beer

The Deep Ore Zone mine is the third lift of caving at PT Freeport Indonesia’s East Ertsberg Skarn System. An increasing trend in seismicity along the northern boundary of the DOZ cave, as well as the northern fringes of the DOZ production and infrastructure levels, was taken as indicative of an interaction between the approaching DMLZ cave and the DOZ subsidence zone. Seismicity trends and locations indicated a reducing crown pillar and an associated stress increase along these DOZ excavations, as well as the regional area along the DOZ cave boundaries. Although rockbursts were not identified as an immediate hazard, seismic shakedown was a highly probable hazard in the case of remote large (≥3.0) seismic events. An evaluation process, as described in the Canadian Rockburst Support Handbook (1996), was followed to identify and quantify the various parameters that could contribute to a shakedown evaluation. A shakedown assessment, based on the Peak Particle Velocities scaling relation, was conducted to assess the current installed ground support systems along the northern fringes and the fixed facilities of the DOZ mine. The range in ground support systems were mostly due to different geotechnical environments. The load–deformation characteristics of these support systems were evaluated to determine the support capacity and compared to the potential support demand under varying shakedown conditions. Shakedown hazard maps were compiled to indicate the installed ground support system’s vulnerability to seismic shaking. Based on this information, areas were divided into zones indicating whether they were sufficiently supported, additional support was required, access was to be restricted, and / or they were to be abandoned. Mine management utilised these hazard maps to strategize actions for the various operational zones within the DOZ, including the fixed facilities. This paper briefly describes the derivation of the PPV scaling relationship. Seismic and geological data for the DMLZ – DOZ interaction areas were evaluated to determine the likely source of large events. Subsequent larger events and their effects are shown to assess the veracity of the magnitude and PPV estimates, as well as the effectiveness and appropriateness of the ground support systems.

Apr 26, 2022

By Y. J. Wang

The Hardy Cross iterative method is the most popular technique for solving a ventilation network problem with natural air splitting. This method tradition-ally solves each mesh equation by an approximation during each iteration. It is thus interesting from both theoretical and computational viewpoints to be able to solve for an exact solution to the mesh equation. Presented in this paper is an algorithm for computing the exact solution to the mesh equation with a variable fan pressure. The algorithm uses signum functions for air quantities to generate an alternative mesh equation in the form of a quadratic equation, which has two solutions defined by the well-known quadratic formula. The condition that the derivatives of the alternative and the original equations must be the same provides a basis for the correct choice between the two solutions.

Jan 1, 1997

By R. L. Smith, J. L. Rutherford

ALTHOUGH considerable effort has been devoted toward the determination of the mechanical properties of pure metals, it is extremely difficult to compare the results of such work. This is because of differences in method and type of test, grain size, heat treatment, and purity of material. There is very little information on the properties of most of the high melting point reactive metals with purities greater than 99.9 pct. Previous evidence concerning the tensile properties of unalloyed metals show that: body-centered-cubic metals are brittle at low temperatures; face-centered-cubic metals remain ductile; some hexagonal metals remain ductile, others become brittle. It may be that traces of impurities decrease the low temperature ductility of the body-centered-cubic lattice. This would suppose that a body-centered-cubic lattice free from impurities would exhibit nearly the same ductility as a face-centered-cubic structure. The present investigation has been an evaluation of the tensile properties of zone refined iron in order to determine whether higher purity material than that previously evaluated behaves differently. Experimental Procedure In this investigation, high purity iron was zone purified using the floating zone method.' The starting stock was obtained from two sources. The first,

Jan 1, 1958

By Juan J. Monsalve, Mario Karfakis, AMAN SONI, Nino Ripepi, Jim Hazzard

Pillar collapses are events that due to their severe consequences can be classified as high risk. The design of pillars in underground room-and-pillar operations should migrate to risk-based design approaches. The authors of this work proposed a risk-based pillar design methodology that integrates stochastic discrete element modeling for pillar strength estimation, and stochastic finite volume modeling (FVM) for stress estimation. This paper focuses on the stochastic FVM component for stress estimation. The mining and geomechanical aspects of a case study mine (CSM) are described and pillar stresses are estimated by using three approaches: (1) analytical solutions, (2) 2D finite element modeling, and (3) 3D finite volume modeling. This operation extracts a 30° dipping deposit, which makes current underground stone mine design guidelines inapplicable for this CSM. This work compares results from each stress estimation approach and discusses uses the point estimate method as a simplified stochastic approach to evaluate the effect of rock mass elastic properties variability on pillar stress distribution. Results from this work show that the three estimation approaches lead to different estimations, possibly, due to the wide range of assumptions each estimation approach considers. It was also determined that the horizontal to vertical stress ratio has a significant impact on pillar stress magnitude. Therefore, it is recommended to perform in situ stress measurements, or assume worst-case-scenario values to account and reduce uncertainty due to this parameter. The stochastic stress estimation approach used in this paper provides results that can integrate a risk-based pillar design framework.

Sep 24, 2022

By Donald L. Katz

Charts for predicting the pressure to which natural gases may be expanded without hydrate formation have been prepared for gases of even gravity. Pressure-temperature curves for hydrate formation were established for gases having gravities from 0.6 to 1.0. These curves and the thermal behavior of the gases during free and adiabatic expansion were used to prepare the charts for estimating the permissible expansion of natural gases without hydrate formation. The problem was solved by L. F, Albright, W. T. Boyd, J. J. McKetta, G. Martin, P. Poettman. and A. P. Snyder.-, who are first-year graduate students in the department of Chemical and Metallurgical Engineering at the University of Michigan. This paper is essentially a summary of their results. Prediction of Conditions for Hydrate Formation in Natural Gases Each natural gas under a given pressure will form solid hydrates at a corresponding temperature provided sufficient water is present.1-5 The temperature of natural gases below about 5000 lb. per sq. in. decreases when the gases are expanded freely.6,7 This decrease in temperature may cause the expanding gas to enter the region of temperature and pressure at which hydrates will form' The final pressure to which a natural gas may 'be expanded without hydrate formation depends upon the initial temperature and pressure and the gas composition. This paper presents charts that give the final pressures to which gases of gravity 0.6 to 1.0 at given initial temperatures and pressures may be expanded without formation of hydrate. Hydrate-forming Temperatures and Pressures as a Function OF Gas -Gravity Experimental data of pressure versus temperature at which solid hydrate will form, provided sufficient water is present, are available for a series of gases.2,3 A method of predicting the pressure-temperature curve for a given gas composition has been reported.' The solution to this problem requires that these curves relating pressure to temperature be established for gases of given gravities.

Jan 1, 1945

By L. C. Weiner

For zinc single crystals, xo = 3o, a surface coating raises both the cleavage and yield strengths over a large temperature range. The "brittle temperature," associated with slip after completion of twinning, does not coincide with the point of intersection of the flow and cleavage curves, which is associated with twinning. A surface film has no effect on the brittle temperature, while it lowers the intersection temperature some 20°. For crystals, yn = 83o, a coating decreases the cleavage strength, making it temperature independent, as well as increases the brittle temperature or its equivalent, the intersection temperature, 20°. These observations are described on the basis of a dislocation-pile-up-at-a-barrier model for brittle fracture; in crystals x,, = 3o the number and distribution of twins play a vital role. IN a recent investigation on the effects of solid environments on the brittle fracture of zinc single crystals,' it was demonstrated that the presence of a surface film changes the cleavage strength of these crystals, either increasing or decreasing it, depending on the crystal orientation. An increase in cleavage strength of some 43 per cent was found for coated crystals oriented x, — 3o K = 28",* while a decrease of 48 per cent was observed with crystals X" = y» — 83". Moreover, these effects were found

Jan 1, 1959

By V. B. Chernyavsky, Ladokhin S. V.

Equipment and continuous casting technology for the production of small diameter copper rods and tubes are described. Industrial copper wastes, such as scrap and shavings, were used as the charge. An electron-beam installation for rod and tube production includes a crucible with an electromagnetic stirring system and a pouring hole in its bottom, a bottomless mold, .and a special cooling system, which includes an oil and water cooling devices. For the first time in the electron-beam technology, rods of 8 mm and 14 mm diameter mm tubes of 14 mm external diameter and 7 mm internal diameter were produced through continuous casting by pulling them out of the vacuum chamder into the atmosphere with depressurizing the vacuum chamber. The production capacity of a single strand continuous casting machine was 200 mm/tnin for rod casting and 150 mm/min for tube casting.

Jan 1, 2000

By J. G. Giddings, R. Kobayashi

Residual viscosity, the ViSCOSitY at a given pressure and temperature minus the dilute gas viscosity at the same temperature, has been found to be independent of temperature for pure components and mixtures for simple molecules and light hydrocarbons. The residual viscosities for methane, ethane, propane and four mixtures were correlated as a function of reduced density and molecular weight. INTRODUCTION Earlier efforts in correlating the viscosity of light hydrocarbons and associated gases under pressure, primarily by some form of the corresponding states principle, have been reported elsewhere.7 The formal theory of corresponding states principle for viscosity from non-equilibrium statistical mechanical arguments for simple molecules has been developed by Helfand and Rice.13 The most serious obstacle to the development of a generalized corresponding states representation of viscosity data, even for simple molecules, has been the limited quantity of precise viscosity data of pure components and mixtures over a wide range of pressure and temperature conditions. Viscosity data on light hydrocarbons have recently been contributed by several laboratories.2,6,8,23,25,26 In the study of the viscosity of nitrogen, Michels and Gibson" observed that the viscosities of nitrogen as a function of density gave parallel isotherms. The same behavior has since been reported for other gases.".= The observed behavior indicates that the residual viscosity or the viscosity at a given pressure and temperature minus the dilute gas viscosity at the same temperature is a unique function of the density. Abas-Zade,1 Michels and Botzen,18 and Michels, Bot-Zen, Friedman and Sengers,19 observed similar behavior for thermal conductivity, the residual thermal conductivity being defined in a manner parallel to that of residual viscosity. Thodos and co-workers 4,15,24 applied the residual viscosity concept to the viscosity of pure monatomic and diatomic gases. Ellington and co-workers10,25 made the residual viscosity vs density plots for ethane and propane, but omitted the region below a residual viscosity of 15 micropoise and showed a systematic separation of the ethane isotherms in the low density region. Eakin correlated the residual viscosity of methane, ethane, propane and n-butane empirically as a function of density and molecular weight: Carmichael and Sage6 recently presented ethane residual viscosity vs density values in the gaseous liquid, and near critical regions as a single univariant function of density. Flynn, Hanks, Lemaire and ROSS" have contributed extremely accurate viscosity data to confirm that the residual viscosity concept is essentially correct, but may not be accurate within 0.1 per cent of the viscosity value for the gaseous state- The recent studies by Giddings12 indicate that the residual viscosity of methane, propane and each of four methane-propane mixtures are unique functions of density Over the temperature and the density ranges studied.

Jan 1, 1965

By G. P. O’Malley, A. N. Nikoloski

One of the most promising options for extraction of copper from low-grade chalcopyrite ores by heap leaching, however, chalcopyrite is refractory and suffers slow leaching kinetics and poor overall extraction due to formation of a passivation layer on the particles. The solution composition is believed to strongly affect the formation of this layer. This paper examines the effects of the major cationic species of Fe3+/2+, Mg2+, Cu2+, and Al3+ and the anionic SO42− species in acidic ferric sulfate media with a composition simulating recycle heap leach conditions. It was found that altering the sulfate, iron or aluminium concentration had significant effect on the copper extraction, the concentration of copper slightly influenced the extraction, and the amount of magnesium had no appreciable effect. Also, iron and aluminium caused a change in the sulfate concentration, and the sulfate ions had the greatest influence on the extraction of copper under recycle leach conditions

Jan 1, 2023

By D. A. Cowen

Toll and custom treatment of base metal concentrates have been performed for decades as mines and concentrators are developed distant from capital and, energy-intensive smelting and refining facilities. Commercial treatment terms have been developed and refined for over a century, and are negotiated taking into account a complex array of quality and economic factors. Treatment of third-party concentrates in the South African platinum industry is a comparatively recent development, brought about by the opening up of mineral rights and operations being developed that are smaller than the critical size required to sustain capitalization of smelting or refining plant. Published commercial terms have not been demonstrated to reflect the complexities and subtleties of base metal concentrate markets. This paper outlines some key elements and parameter ranges of base metal concentrate treatment contracts, and applies similar principles to typical Merensky and UG2 platinum group element (PGE) concentrates to determine potential value distribution between the mining and treatment parties in tolling arrangements.

Jan 1, 2012

Based on the idea to copy crystallisation and precipitation phenomena occurring in nature, a new technology was developed allowing the preparation of metastable, mineral forming solutions. If these solutions are brought into soil or rock formations, directed precipitation of slightly soluble minerals takes place. Immobilisation of dissolved heavy metals as well as overlaying of reactive mineral surfaces with insoluble minerals can be achieved. It is possible to prepare solutions leading to the formation of gypsum, BaSO4, CaCO3, Ca(OH)2, Al(OH)3 or Fe(OH)3. The successful large-scale application of BaSO4 forming solutions was demonstrated in the former uranium mine Koenigstein of Wismut GmbH, (Germany).

Jan 1, 2003

By S. Kmet, A. Nguyen-Van, H. J. Schulze

The P/B collision and attachment interactions in fine particle flotation have been quantitatively analyzed. New models for attachment probability and kinetics of ‘true flotation’ have been developed. The results are given for both a single bubble and a bubble swarm. The mechanism of the attachment event is also examined. It is shown that (i) impact collision mechanism and rolling mechanism can be ignored in actual fine particle flotation and sliding mechanism is of importance for attachment of particle onto the bubble surface (ii) the attachment probability of fine particles is independent of bubble size and determined by the kinetic measure induction time of hydrophobicity. The theoretical predictions are also compared with the experimental data.

Jan 1, 1995

By Mourad Aissa

From our previous work (Gardner, Aissa, and Verghese, 1982) on determining the residence time distribution of ball mi 11s from radiotracer data taken in closed-circuit operation without interruption of the process, it occurred to us that the data taken for this purpose also contained information on the breakage rates of all the sizes present. It is the purpose of the present work to evaluate methods to obtain breakage rates from this data. A numerical solution for the impulse injection and subsequent detection of radiotracer in a closed-circuit linear comminution process is developed and used with typical breakage parameters, residence time distribution, and classifier functions to study and evaluate these methods.

Jan 1, 1984

By I. Tsolas

Sustainable development is becoming increasingly more important for the mining industry and therefore mining companies should be able to measure their progress towards sustainability. Greek Public Power Corporation (PPC) S.A. is a company which produces lignite in open cast mines in Western Macedonia and in Peloponnesos. The present paper uses operational data kindly offered by PPC S.A. to derive sustainability indicators by means of Data Envelopment Analysis for three large scale lignite open cast mines of PPC (i.e. Main Field, Kardia Field and South Field mines). It also examines three environmental parameters related to the contribution of these mines to sustainable development; namely, the annually produced volume of waste masses, the annually produced quantity of ash from the lignite combustion and the annual volume of pumped water. The calculated sustainability indicators were keeping constantly better during the last years of the different periods for each one of mines studied here, showing that the mines met their goals from both economic and environmental aspects during the last years of their operational periods studied. The contribution of open cast lignite mines studied here to sustainable development can be monitored by the derived indicators analyzing annual mine operational data. The derived indicators can serve as tools to detect where improvements can be made, though another potential use of these indicators can also be during the preparation of feasibility studies or environmental impact studies using necessary benchmarking data.

Jan 1, 2007