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By N. Wagner, P. den Hoed, J. D. Steenkamp, S. Soqinase

In pyrometallurgical processes, metal oxides are reduced from molten slag through carbothermic reduction. It is of interest to evaluate the reactivity of the carbonaceous materials towards substances such as slag. Characterization techniques such as coal petrography can provide insight into the influence of feed coal properties and how they potentially dictate reductant performance. This study aimed to compare the petrographically determined organic composition of coal to reductant reactivity. Two South African medium-rank C bituminous coals and one anthracite sample were investigated together with high-carbon ferromanganese industrial slag. The reductant reactivity tests were conducted at 1500°C in a muffle furnace to assess the potential of carbonaceous reductant in reacting with the main slag components. SEM-EDS was applied to understand the extent of MnO (and to a lesser extent, SiO2) reduction from the slag. Coal 2, consisting of a greater proportion of vitrinite (59.5 vol% on a mineral matter-free basis and 54.7 vol% including mineral matter) was the most reactive reductant. The anthracite sample, with the highest inert maceral proportions (71.8 vol% including mineral matter and 76.8 vol% on a mineral matter-free basis), was the least reactive reductant.

Feb 6, 2023

By William Petruk

The mineralogy of the primary and oxidized ores from the Malanjkhand porphyry copper deposit in India was studied to determine ore characteristics that affect metallurgy, and to assess applicable processes for recovering the copper. Three mineral assemblages were found. One occurs in primary ore, another in moderately oxidized ore, and a thir:d in intensely oxidized ore. Chalcopyrite, the main mineral in the primary ore, is relatively coarse-grained, with grain size increasing as the ore grade increases. High chalcopyrite liberations should be achieved at a relatively coarse grind, and good chalcopyrite recoveries should be obtained. The chalcopyrite, however, tarnishes readily and oXidizes to chalcocite in a relatively short time (several months). The presence of both the tarnished chalcopyrite and chalcocite may affect chalcopyrite flotation and reduce copper recoveries, The moderately oxidized ore occurs in an oxidized cap immediately above the primary ore, and stockpiled primary ore alters quickly to a moderately oxidized ore. Chalcocite is a major copper-bearing mineral in moderately OXidized ore. The concentrator processing this ore should be capable of handling a chalcocite-rich ore. The intensely OXidized ore contains a wide variety of acid-soluble copper-bearing minerals. Leaching may be required to recover the copper from them.

Jan 1, 1987

By R. Degel

Keywords: Pyrometallurgy, DC furnaces, electric smelter, FeCr, FeNi, FeMn, Si metal, ferro-alloys, platinum production, circular furnace, energy recovery system In 1906, the first submerged-arc furnace was supplied by SMS Siemag. Since then, the division has become established in various industries such as ferro-alloys and non-ferrous metals, and in numerous other special applications. During the evolution of this technology, more efficient units with longer lifetimes were developed. Today, especially the potential of DC-based smelters, raises worldwide attention, with some projects having already started to implement this kind of technology. This paper evaluates SMS Siemag?s general viewpoint regarding the potential application of DC smelter technology and possible options for the ferro-alloy and non-ferrous industry. SMS Siemag is currently executing a FeCr project in Kazakhstan, where four of the world?s largest closed-type DC smelting furnaces, with a power input of 72 MW, will be installed. These furnaces include the latest technological features of modern DC smelters, which are described in this paper. SMS Siemag has started a long-term research and development project allowing a direct comparison of AC versus DC technology on a large scale, using a recently installed 1 MVA test furnace at the IME at the University of Aachen, in Germany. For open-type ferro-alloy and Si-metal furnaces, SMS Siemag has developed an energy recovery system, which is presented in this paper.

Jan 1, 2011

By Michael G. Pojar, Peter G. Chamberlain

Solution mining, primarily by heap leaching, has emerged as an important method for mining gold and silver in the United States. Heap leaching offers many economic and environmental advantages over conventional production techniques, in particular for lean ores and old mine waste rock. In order to more effectively pursue research on heap, dump, and in situ solution mining of gold and silver, the Federal Bureau of Mines conducted an extensive survey of leaching practices and problems. This presentation summarizes trends and statistics. Leaching is projected to provide 20 pct of primary mine produced gold and 10 pct of primary silver by the end of 1982. Current leaching practices in the United States are reviewed; operational problems and research programs to alleviate those problems are discussed.

Jan 1, 1981

By Ronald A. Crowson

Detailed stratigraphic studies of the overburden at North Carolina Phosphate Corporation new South Creek Mine have delineated several aquifers and acquicludes within the 30-meter-thick overburden section of late Pleistocene sands and clayey sands. A major aquifer occurs in the 10-meter-thick sequence of shelly sands of the early Pleistocene Croatan Formation. The water-charged Croatan sands thicken into a paleodrainage surface on top of the Pliocene Yorktown Formation, a major aquiclude. A three-phase dewatering program is projected: 1) improve surface drainage around mine perimeter to reduce both flowage into the pit and rainfall recharge; 2) use a wellpoint system to dewater the upper 8 meters; and 3) use recharge wells along the axis of the paleo- drainage to dewater the overburden below 8 meters.

Jan 1, 1983

By L. Zhang, Y. Zhou, H. Wang, C. Mo

Fluorination of magnetite (Fe₃O₄) by NH₄HF₂ was investigated using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), and observing the morphology and phase changes using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffractometry (XRD). The results indicate that fluorination with the involvement of oxygen begins at room temperature, peaks at 178.40C, and is completed at 2000C with the formation of only (NH₄)₃FeF₆. On heating, (NH₄)₃FeF₆ gradually releases NH₄F by the formation of NH₄FeF₄ at 2590C, then (NH₄)0.18FeF₃ at 3270C, and finally FeF₃ with minor FeF₂ at 4000C due to the partial reduction of Fe (III) to Fe (II). At 5500C, FeF₃ is oxidized to FeOF/Fe₂O₃.

Dec 13, 2022

By Brij M. Moudgil

Separation of oil shale from waste material or into high grade and low grade fractions can have a major influence on the economics of the surface (ex-situ) retorting process. Different components of shale rock vary significantly in physical and surface chemical properties such as specific gravity, color, water wettability etc. Various techniques which utilize the difference in one or more of the above propartis have been proposed to preconcentrate the oil shale before retorting. A discussion of the techniques proposed such as gravity separation, sorting and froth flotation is presented.

Jan 1, 1982

In a previous paper the writer dealt -with the jasper bar formations and their relationship to the structural geology of older pre-Cambrian rocks in the goldfields districts of Western Australia (24). He has pointed out in this ahd other papers that jasper bars, or banded iron formations, banded hematite or ,magnetite quartzites, jaspilites and related banded ferruginous or non-ferruginous cherts, occur in abundan'ce in the Older Greenstone Series of Western Australia (22), (24), (26). They are considered to represent special forms of banded ferruginous sediments, and are usually fpund in the field interbedded with more or less metamorphosed pasaltic 01' andesitic lavas and tuffs, now amphibolites, together with occasional thin bands of normal pelitic sediments, which go to make up a large proportion of the Older Greenstones in thfs State (26).Great thicknesses of fiat-bedded ]:landed ferruginous cherts are also found associated with cherty' carbonate rocks; quartzites, shales and thin-bedded dolomite whicIi constit'ute the Nullagine (Pl'oterozoic) system in the northwest of Western Australia. In the Hamersley Range district these banded ferruginous chert beds are the hosts of important deposits of blue amphibole asbestos.In the paper mentioned above brief reference was> made to the importance, of geological structure in relation to economic geology, particularly in the goldfields regions of Western Australia, and it was shown that jasper bars may have an important role in the study of 'the structural geology of many of these regions. Of possibly more immediate economic importance is the part that these rocks play, both directly and indirectly, as host rocks for mineral deposits-the chief of Which are gold, iron ores, blue asbestos, and manganese ores. The blue asbestos bearing banded iron formations mentioned above are confined to the younger pre-Cambrian Nullagine formations. They have been described in detail elsewhere (23). In this paper it is proposed to discuss the economic geology of the jasper bars found in the older pre-Cambrian series.The jasper 'bars have in themselves little or no intrinsic value except perhaps some of the more highly coloured and banded varieties which may be utilised for ornamental and decorative purposes. Probably the best known of such varieties is the so-called "marble bar;" a belt of, strikingly coloured banded chert occurring just south and west of the famous town of that name (see Fig. 1t). This consists of a hard, very fine, even-grained rock with alternate individual stripes varying from the thickness of a sheet of paper up to an inch or more in width, and ranging in colour from clear white to yellow, from various shades of pink to brilliant...

Jan 1, 1943

By T. Celik, B. Genc, C. Musingwini

"Mine planning software continues to be an important factor when it comes to the development of the South African mining industry. To contribute to this development, a new methodology to define and measure mine planning software utilization in the South African coal mining sector within an evolving data-set framework was developed. An initial data-set showing the mine planning software providers, their corresponding software solutions, as well as the software capabilities and information on the number of licences was collected and compiled in 2012 in an online database for software utilized in the South African mining industry. Details of the database development and implementation were published in the Journal of the Southern African Institute of Mining and Metallurgy in 2013. In 2014 the data-set was updated with additional and new information.In this paper, using the 2012 and 2014 time-stamps, a methodology for estimating the software utilization is developed. In this methodology, three variables: commodity, functionality, and time factor are used to define and measure the software utilization in order to ultimately inform decision making strategies for software utilization. Utilization in the coal sector was measured according to six different functionalities, namely Geological Data Management, Geological Modelling and Resource Estimation, Design and Layout, Scheduling, Financial Valuation and Optimization. The methodology is useful for stakeholders reviewing existing software combinations or intending to purchase new software in the near future and wanting to estimate the comparative attractiveness of a certain software package. These stakeholders include mining companies, consulting companies, educational institutions, and software providers. The work presented in this paper is part of a PhD research study in the School of Mining Engineering at the University of the Witwatersrand."

Jan 1, 2016

By C. Orf. Chukabarah

Acoustic pollution (noise) is a significant mine environmental system problem. The U.S. Bureau of Mines (USBM), Environmental Protection Agency (EPA), Department of Labor (DOL) and other researchers have all performed contributory research on noise in mining environments. The present study addressed the problem of unavailability of a computerized, practical, routine, user-friendly, and user-editable, prose-styled application program with which one can determine (a) the noise exposure indices among mine workers, (b) mine system noise exposure level on time-weighted average basis, and (c) predictive relationships among mine workers' age, prior exposure to abnormal noise levels, prior auditory pathologies and the risk/degree of mining-induced hearing impairment. Results showed that such a program ("NEIL") is accomplishable. Additional results revealed that most U.S. mines operate within the statutory noise exposure levels. Furthermore, the mine worker's age was statistically confirmed to be the main predictive risk factor for mining-induced occupational hearing impairment.

Jan 1, 1992

By M. Beth McClenaghan

This paper summarizes diamond exploration techniques used in glaciated terrain, focusing on indicator mineral and geochemical methods applied to glacial sediments. Understanding the ice flow history, depositional history, and stratigraphy of glacial sediments are essential to successful sampling, interpretation and follow-up of indicator mineral and geochemical anomalies related to kimberlites. Kimberlite indicator minerals survive glacial transport over long distances and the relative abundance of each mineral in till is a function of the primary mineralogy of individual kimberlites. Indicator mineral distributions observed at a regional scale define the net effect of glacial dispersal, often along different ice flow directions. Local-scale distributions define individual dispersal trains. The medium sand (0.25 to 0.5 mm) fraction of heavy mineral concentrates prepared from glacial sediment samples is best suited for indicator mineral surveys. The application of till geochemistry to diamond exploration is increasing because it is significantly cheaper than indicator mineral analysis and it can be performed quickly. The <0.063 mm (silt+clay) and 0.5 to 2.0 mm (coarse sand) fractions provide the best geochemical contrast between background and kimberlite-rich till. Kimberlite pathfinder elements that provide good contrast include Ni, Cr, Ba, Co, Sr, Rb, Nb, Mg, Ta, Ca, Fe, K, Ti and REE, the relative importance of which will depend on kimberlite composition as well as that of the surrounding bedrock.

May 1, 2002

By A M. Goodwin

Detailed stratigraphic studies in the Birch-Uchi Lakes area have shown that the volcanic components are arranged in superimposed sequences, or cycles. Each cycle displays a progression from predominantly mafic effusives below to predominantly felsic extrusives above. Sedimentary rocks are preferentially associated with the felsic extrusives. Two volcanic cycles are represented. The average stratigraphic thickness of the volcanic rocks present is 31,000 feet. The original volcanic pile was probably in the order of 40,000 feet thick. The present lithologic composition is estimated to be: mafic volcanic rocks, 60 per cent; felsic volcanic rocks, 27 per cent; sedimentary rocks, 10 per cent; and others, 3 per cent. Gold occurrences are preferentially distributed with respect to the volcanic succession. Of fifty recorded occurrences, thirty-nine are located in the upper felsic division of the lower volcanic cycle; forty are associated with closely interbanded daciterhyolite pyroclastic rocks, andesitic lavas and siliceous sediments. The gold-bearing quartz veins either lie at the contacts of enclosing lithologic units or occupy cross-cutting fractures in one or more adjacent units.

Jan 1, 1965

By H. J. McQueen

Pyro-reduction of ores to metal products developed markedly through the industrial revolution into the great depression. Nineteenth century resource and environmental sustainability were haphazardly improved by many process changes, although the motivation was primarily reduction in labor, feed stocks and fuel. Some notable achievements were coke and hot air for blast furnaces (later from waste heat stoves), puddling of wrought iron and steel ingot production with convertors advancing into oxygen use and continuous slab, billet and strip casting. Although advances in one sector were often counteracted by fall-backs in others, there was progress in that the resource consumption and pollution per unit of production was decreased. Improvements in the 2 decades following WW2 were mixed but popular notice of environmental hazards forced governments to legislate pollution controls and initiate steps in resource conservation. The energy crisis of the 1970’s saw an industrial energy-saving campaign and legislation of technology assessment procedures. Up until mid 18th Century, the training of iron masters depended on apprenticeship with some formalized knowledge from medieval books such as those of Biringuccio (1540) and Agricola (1556). The advances were very slow partly due to absence of scientific concepts of the smelting process. Nevertheless, some iron masters succeeded in improving the process and described procedures to instruct others. With the surge of steam power and the reverberatory puddling process for ductile wrought iron (WI), machinery changed from wood (iron strap reinforced) to WI machinery. With the clarification of the reduction and oxidation mechanisms by Cavendish and Lavoisier (~1780), productivity in iron production surged. The mechanical testing and microscopy of Kirkaldy (1862) spurred understanding of processing and properties of WI and steel. The various forms of C in steels were determined by chemists at the end of the 19th Century. It also became possible to control metal and slag chemistry in the open hearth furnace. But understanding of the transformations during heat treatment of steel only came in the first decades of the 20th Century.

Jan 1, 2012

By P Ridley

EnergyAustralia’s Sydney Central Business District (CBD) cable tunnel network will form a loop 6.2 km in length. The 3.2 km long, 3.5 m, diameter city east cable tunnel (CECT) currently in design, will complete the loop in 2014. This paper discusses the ventilation design of the CECT, considering operation for four functions:1. normal (unmanned),2. access (manned),3. purge, and4. emergency fire modes.The dominant design criterion which determines the required ventilation capacity for CECT is the specification of an upper air temperature limits of 35°C (dry bulb) and 24°C (wet bulb) for manned access, during all ambient weather conditions and cable heating loads. Simplistic static heat transfer analyses do not yield a sufficiently accurate calculation of tunnel air temperature and humidity to provide a safe and yet economical design. The primary refinement in the analysis discussed in this paper is associated with modelling of the system’s dynamic behaviour.Our means of analysis is through a thermo-fluid-dynamic simulation of the interactions between the diurnally and seasonally varying loads (cable heat generation, ambient air conditions and groundwater inflow), tunnel airflow and the resulting tunnel air temperature and humidity. These simulations are validated using experimental data from the existing city south and city west cable tunnels.Fire life safety scenarios are also analysed and discussed in association with the ventilation design. Ventilation strategies are developed for dealing with such emergency fire situations.The understanding and insight provided by the work offers the ability to optimise ventilation plant provisions in future cable tunnels, particularly long and high energy density tunnels.

Mar 8, 2011

By Robert M. Doerr

Isothermal oxidation kinetics were determined for three grades of Ni and for 99.99 percent Co in Ca and in air from 800° to 1,200° C. The oxidation reactions followed approximately the parabolic rate law. For 99.99 percent Ni in 02 at 1,200° C, the parabolic rate constant was 2 mg cm-2 hr-2. For 99.99 percent Co in dry air, the constant ranged from 1 mg cm-2 hr-2 at 800° C to 18 mg cm-2 hr-2 at 1,200° C; for 99.99 percent Co in 02 the constant was 2 mg cm -2 hr-2 at 800° C and 10 mg cm-2 hr-2 at 1,000° C. For 99 percent Ni in dry air, the constant ranged from 0.2 mg cm 2 hr-2 at 800° C to 3 mg cm 2 hr-2 at 1,200° C. By X-ray diffraction measurements, only divalent oxides were found in the scales. Volumetric and quartz-helix gravimetric methods were used. The volumetric apparatus was designed to permit less stringent restrictions on the corrosion specimens; it was also more convenient to use. The agreement between the weight gain determined gravimetrically and the 02 consumption determined volumetrically was not good enough for direct comparison of gravimetric and volumetric results.

Jan 1, 1963

By P. J. Noakes

Remote and isolated, located in a frigid, hostile environment, the Black Angel mine in Greenland had to create a warm social environment which would help attract and retain a stable work force of miners and support staff. The high cost of personnel turnover plagues many mines and, when the mine is inside the Arctic Circle, accessible by helicopters which are highly vulnerable to unpredictable weather conditions during the long, dark winters, the potential costs of personnel turnover become critical factors in the success or failure of the mining venture. Manpower planning should start from the date the engineers begin the technical design of the new mine. The plan should include provisions not only to ensure an adequate, skilled work force, but also to ensure a stable work force of people who are happy enough in the mining environment to want to remain, take their vacation and return to work at the mine. The skilled work force was assured with training courses of four months, designed to produce highly specialized underground workers from unskilled Danes and Greenlanders supported by trained Swedish and other Scandinavian miners. The stable social unit was assured by plans the primary attribute of which had to be flexibility. The accommodation changed from shared accommodation with communal washroom facilities to single accommodation with private washroom facilities. A recreational director was hired to help the workers make use of elaborate recreational facilities. A closed-circuit TV and radio system was installed to operate as a private broadcasting system using taped programs originally broadcast on European TV networks or developed by the mine personnel themselves. The liquor rules were changed and the mine manager became a licensed innkeeper responsible for the orderly operation of the Black Angel Bar in accordance with the Danish laws governing the services of a public bar. The result is a relatively stable work force. Some 35% of the people have more than two years&apos; service with the company, Greenex A/S, and some 62% complete 10 months of service.

Jan 1, 1978

By Heine Kenworthy

"INTRODUCTION In 1930 the Shenandoah-Dives Mining Co. near Silverton, Colo., put into operation a newly erected, 300-ton selective flotation plant to mill complex ores from its nearby mine. The operation was a steady producer and was enlarged to treat 600 to 800 tons a day. In 1942 the company opened and started milling an area in the mine containing semioxidized ore. The valuable mineral content of this ore was considerably higher than in, the straight sulfide ore previously handled alone. The mixture of clean sulfide and semi-oxidized ore was difficult to treat; consequently, tailing losses, especially with respect to lead, were high. A few years later, in order to study the possibilities of obtaining higher recoveries by a modification of the mill flow sheet, a 1,200-pound sample of mill, feed, taken over a period of several days by the company, was submitted to the Mississippi Valley Experiment Sta¬tion for testing-. Although this sample proved to contain more than twice as much lead as the average yearly mill feed, the same problem of recovering the oxidized values was present.A résumé of the ore-dressing treatment used in the Shenandoah-Dives mill follows. After crushing, the ore passes through a ball mill, the minus 5-mesh discharge of which is distributed to three tables. A finished lead concentrate is made on the tables, and the table tailing goes to the classifier which is in closed circuit with the ball mill. The classifier overflow is treated -by flotation to obtain a bulk sulfide concentrate at a relatively coarse size. The bulk concentrate is thickened and reground to about 95 percent minus 325-mesh before flotation treatment to separate a lead-copper and a zinc concentrate. A typical monthly average showed that the table concentrate contained about 45 percent lead, 1 percent copper, 4 percent zinc, 12 ounces of gold, and 40 ounces of silver; that the lead flotation concentrate contained '35 percent load, 6 percent copper, 7 percent zinc, 3.5 ounces of gold, and 50 ounces of silver; and that the zinc flotation concentrate contained 2 percent lead, 0.5 percent copper, 60 percent zinc, 0.15 ounces of gold, and 4 ounces of silver. Recoveries in salable products were roughly b5 percent of the lead, 70 percent of the copper, 45 percent of the zinc, 85 percent of the gold, and b5 percent of the silver."

May 1, 1948

By W. A. Grosh

The Piquette Mining and Milling Co, operates a zinc mine and concentrating mill in the Upper Mississippi Valley zinc-lead district near Tennyson, Wis. The principal ore mineral is zinc sulfide, which occurs in limestones and dolomites of the Decorah formation. Exploration in the district is by churn drilling from the surface. An adit at the base of the ore zone provides access to the mine. A room-and- pillar mining method with irregular pillars is used. Drilling is done with Jumbo-mounted drills. The broken ore is loaded by crawler-mounted front-end loaders into diesel-powered trucks for haulage direct to the mill.

Jan 1, 1959

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

"Contained in this chapter is a listing of the publications and reference books which have come about as a result of respirable dust research performed by faculty, staff and graduate students in the Generic Mineral Technology Center for Respirable Dust at The Pennsylvania State University, West Virginia University, University of Minnesota, Massachusetts Institute of Technology, and Michigan Technological University. These publications have appeared in scientific journals, proceedings of the national and international symposiums, and professional meetings. Complete citations of the publications can be found in Volumes 3 through 6 and Volume 8 of this series. The agenda of the last annual GMTC seminar, held at West Virginia University on February 1 - 2, 1988, follows. The project presentations are organized under the five research areas. All projects currently active were presented to the Advisory Committee. New project submissions were not. The authors were allotted thirteen (13) minutes for their presentations; the remainder of the twenty (20) minutes allotted for each project was used for introductions, transitions, and questioning by the Advisory Committee. Each author used a standard format for presentation of his/her materials for review; handout materials were distributed to the Advisory Committee for reference. Opening remarks were made by Dr. Richard Bajura of West Virginia University and Dean Robert L. Frantz and Dr. Raja V. Ramani of The Pennsylvania State University.The Generic Mineral Technology Center for Respirable Dust is funded by the U.S. Bureau of Mines through the Mining and Mineral Resources Research Institute Program. The opinions and conclusions expressed in these papers are those of the authors alone and do not represent the opinions of the Generic Mineral Technology"

Aug 31, 1989