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By John C. Stankus

At the 13th Conference on Ground Control in Mining, a paper was presented detailing a successful test in which a new truss system was utilized, in lieu of wood cribs, for tailgate support in the Pittsburgh seam (Stankus et al., 1994). Since that time, additional tests using this same truss system in the Pittsburgh and other seams are now complete. Also, several mines are now using trusses for full panel tailgate support with no cribs. Through an extensive instrumentation program, much data and new information has been gained from these tests and the full panel usage. From this data, not only have new concepts pertaining to tailgate support been developed, but also for headgate, pillar configuration, primary and supplemental support. In this paper, an update will be presented summarizing the results of these various tailgates.

Jan 1, 1995

By M Bannear, C Stanton

Since 2008, Arrium has been developing and commissioning a new low-grade hematite ore benefication plant (or OBP) at its Iron Baron mine site.The Iron Baron mine, which was closed in the 1990s, could not consistently yield the high-grade hematite required for pelletising. However, in todayÆs market, the 12 Mt of waste dumps represent a significant low-grade hematite resource, ideal for benefication.Initially, an internal scoping study and several sampling campaigns were conducted to determine the ability to upgrade the available low-grade dump material to a product suitable for export. Test work was conducted at Mineral Technologies (formerly CPG), and included high intensity magnetic separation, spiralling and jigging. Due to promising results from a wet processing circuit, Arrium engaged Mineral Technologies to design a flow sheet that could provide 1 Mt/a of a mixture of high-grade lump (-32 + 8 mm) and fines (-8 mm) products for export.With construction of the plant completed in late January 2012, Arrium, in conjunction with Mineral Technologies, began two commissioning phases. Each phase ended with a toll gate to prove the plantÆs capacity to reach rate and desired grade. After an initial period of running on water, feed solids were introduced to the plant and troubleshooting of bottlenecks began. The first toll gate, whereby the plant was required to run for 24 hours at an average feed rate of 200 t/h (80 per cent of design rate), was completed on the 1 March 2012. Further troubleshooting and resolving of issues allowed the plant to steadily increase feedrate while maintaining good availability and grade. The second toll gate required the plant to run for 72 hours at an average feed rate of 200 t/h while meeting grade, yield and water consumption targets. Sampling campaigns were conducted during this period to track the performance of key equipment. Completion of the test, and full handover of the plant to Arrium, was completed on the 21 April 2012.Although the formal commissioning phases had been completed, ongoing optimisation of the OBP continued, ensuring that all major equipment was working to produce the optimum yield and grade. Sampling campaigns were conducted on the jigs and spirals, with results and correlations used for operations documentation.Overall, with successful completion of the final acceptance tests, the commissioning of the Iron Baron OBP has been established as a major success achieving all production and quality targets as per the original design intent.This paper will focus on the successful commissioning and ramp-up performance of the plant however reference will also be made to the key development stages involved with the development of the project.CITATION:Stanton, C and Bannear, M, 2013. ArriumÆs Iron Baron hematite beneficiation plant - a success from start to finish, in Proceedings Iron Ore 2013 , pp 547-552 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Christopher Mark

Pillar recovery continues to be one of the more hazardous activities in underground coal mining. Safety requires that the roof above the intersection remain stable until after the pillar has been extracted. Artificial supports (timbers and Mobile Roof Supports) arc essential to roof stability, but so is the final remnant stump or pushout. Traditional mining practices usually called for the complete extraction of the final stump, but the recent trend (both in the U.S. and internationally) seems to be towards mining plans that leave a remnant stump. For this study, a sample of roof control plans from the Mine Health and Safety Administration (MSHA) Coal Districts were analyzed to determine current pillar recovery practices. Both full- and partial- extraction plans were included. Special attention was paid to whether plans require that a final stump be left, and whether requirements regarding the dimensions of the remnant stump are included. Foreign experience with final stumps is also summarized. It seems that the risk of major pillar falls can often be reduced by leaving final stumps that are large enough to protect the intersection, but small enough that they do not inhibit the caving of the gob. Because final stumps are often irregular in shape, a new approach for estimating their strength is described. Analyses were conducted to assess the effect of seam height and depth of cover on the potential variation in the size of remnant stumps.

Jan 1, 2001

By R. E. Whitehead

"The earliest gold-mining operations in Ontario included the Cordova, Deloro, and Sophia mines north of Lake Ontario (see for example, Miller and Knight, 1914). The Cordova deposit, worked intermittently between 1891 and 1940, is reported to have yielded 22 774 oz of gold from 127 670 tons of ore averaging 0.19 oz/ton Au (Gordon et al., 1979). The property remained inactive for many years. In 1988, Gunnar Gold Inc. and Mill City Gold Inc. conducted a drilling program along the main Cordova vein. The present study is based on core from three drill holes through the Cordova gabbro (Fig. 1) and the carbonate alteration zones enveloping the quartz-carbonate veins. The relatively narrow width of the alteration zone and the availability of continuous sections of core provided an opportunity to conduct a compact mineralogical-chemical study of carbonate alteration and its effect on the redistribution of rare earth elements (REEs). Although the Cordova deposit is not of great economic importance, this study has revealed a number of interesting features which are interpreted as resulting from processes that may be applicable to gold-bearing quartz vein deposits elsewhere.The Cordova gabbro is layered in places, varying from fine-to coarse-grained and in color from light gray (feldspathic) to dark gray-green (amphibolitic). However, layering within the section of the gabbro considered here and which hosts the Cordova gold deposit is mainly textural rather than compositional. Samples of unaltered gabbro selected for analyses were medium- to coarse-grained; amphibolitic and anorthositic phases were avoided as being less representative of the general chemical composition of the gabbro.The Cordova intrusion has undergone regional metamorphism and consists dominantly of actinolite and saussuritized plagioclase with smaller amounts of granular clinozoisite and flaky chlorite; minor quartz, ilmenite, titanite, apatite, and calcite are typically present. Some actinolite grains have irregular rims of pleochroic green hornblende that is optically continuous with the actinolite. Both chlorite and clinozoisite occur in two modes. Chlorite occurs as an alteration product of actinolite and as separate grains in the groundmass. Clinozoisite and albite occur together as regional metamorphic alteration products of original plagioclase crystals and as discrete grains in the matrix.The main gold-bearing quartz-carbonate occurrence occupies an easterly trending, steeply southward-dipping carbonatized shear zone up to 15 m wide and 700 m long. The gold occurs principally in irregular lenses and veins of quartz-carbonate up to a foot thick occupying the lower part of the schistose shear zone within the gabbro. This zone consists of chlorite, biotite, and carbonate and is flanked on both sides by chlorite-carbonate schist lacking biotite. The chlorite-carbonate schist in turn grades into regionally metamorphosed actinolite-bearing undeformed gabbro.The dominant sulfide within the quartz-carbonate lenses and in the surrounding schist is pyrite which occurs mainly as small cubes (1 mm to 2 mm) generally making up less than 10% of the rock. Rare blebs of chalcopyrite are present. Magnetite is common throughout the schist."

Jan 1, 2001

By John T. Galey

Production of crude oil for 1940 in southwestern Pennsylvania was off nearly 70,000 bbl., largely as a result of the great number oi abandonments, together with the lack of extension of the Washington and Green County pools. Oil wells completed numbered 51, which is 26 more than last year, but the total initial production of 259 bbl. is only 18 bbl. greater than in 1939. There was an increase of 72 over last year for a total of 209f gas wells. However, 68 7 dry holes were drilled, which is 40 more than a year ago. Thus, 328f wells were drilled during the year, and rigs are erected or drilling is progressing on 59 t more. Shallow Development Oil.—Butler County led in number of oil wells completed, with a total of 27 for an initial production of only 69 bbl. Washington County, with 12 new oil wells, one of which made 40 bbl. from the Fifth sand in S. Franklin township, has 95 bbl., while in Allegheny County 9 wells gave an initial of 86 bbl. for the highest Per well average in the area. This initial was given a considerable boost by one 35-bbl and another 2;-bbl. well in West Deer township, where the Fourth sand produced at 1840 feet. Greene County had only one oil well completed during 1940, and Washington County had 12. The subnormal totals for these counties may be explained by the higher cost of completions and the declining price of crude. The first price change in crude during the year occurred on May 22, when a 25 cut was made. A second 25 cut was made July 12, and was followed by a 156 cut on .Aug. 28. This price held until Nov. 12, when there was a restoration of 156. On Dec. 17 a second 156 increase was put into effect, bringing the price to $I.So per barrel. Gas The large increase in the number of gas wells completed may be attributed to three factors; namely, the recently discovered production possibilities of moderately deep, hitherto little tested horizons, together with increased demand and price. The latter has been made possible by a recent decision of the court, which ruled restraining the public service Commision's prohibition of a raise in the minimum monthly charge to small consumers by one of the major gas companies. A portion of the revenue derived in this manner is being passed along to the producer in the form of higher prices in the field. This higher field rate will remain in effect until a new ruling is made, when it will be reduced in proportion to the reduction of the monthly minimum charge. In an effort to extend the chambers Dam Fifth sand oil pool southwest from Amwell township, Washington County, several wells have been drilled. One of these, in Morris township, washington County, had an initial of 3.2 million cu. ft. open flow from the Big Injun sand. This indicates an entirely new productive area for the latter horizon. Allegheny County had one spectacular well in South Fayette township-—at a depth of about 2500 ft. a 4-million-CU. ft.

Jan 1, 1941

By John T. Galey

Production of crude oil for 1940 in southwestern Pennsylvania was off nearly 70,000 bbl., largely as a result of the great number oi abandonments, together with the lack of extension of the Washington and Green County pools. Oil wells completed numbered 51, which is 26 more than last year, but the total initial production of 259 bbl. is only 18 bbl. greater than in 1939. There was an increase of 72 over last year for a total of 209f gas wells. However, 68 7 dry holes were drilled, which is 40 more than a year ago. Thus, 328f wells were drilled during the year, and rigs are erected or drilling is progressing on 59 t more. Shallow Development Oil.—Butler County led in number of oil wells completed, with a total of 27 for an initial production of only 69 bbl. Washington County, with 12 new oil wells, one of which made 40 bbl. from the Fifth sand in S. Franklin township, has 95 bbl., while in Allegheny County 9 wells gave an initial of 86 bbl. for the highest Per well average in the area. This initial was given a considerable boost by one 35-bbl and another 2;-bbl. well in West Deer township, where the Fourth sand produced at 1840 feet. Greene County had only one oil well completed during 1940, and Washington County had 12. The subnormal totals for these counties may be explained by the higher cost of completions and the declining price of crude. The first price change in crude during the year occurred on May 22, when a 25 cut was made. A second 25 cut was made July 12, and was followed by a 156 cut on .Aug. 28. This price held until Nov. 12, when there was a restoration of 156. On Dec. 17 a second 156 increase was put into effect, bringing the price to $I.So per barrel. Gas The large increase in the number of gas wells completed may be attributed to three factors; namely, the recently discovered production possibilities of moderately deep, hitherto little tested horizons, together with increased demand and price. The latter has been made possible by a recent decision of the court, which ruled restraining the public service Commision's prohibition of a raise in the minimum monthly charge to small consumers by one of the major gas companies. A portion of the revenue derived in this manner is being passed along to the producer in the form of higher prices in the field. This higher field rate will remain in effect until a new ruling is made, when it will be reduced in proportion to the reduction of the monthly minimum charge. In an effort to extend the chambers Dam Fifth sand oil pool southwest from Amwell township, Washington County, several wells have been drilled. One of these, in Morris township, washington County, had an initial of 3.2 million cu. ft. open flow from the Big Injun sand. This indicates an entirely new productive area for the latter horizon. Allegheny County had one spectacular well in South Fayette township-—at a depth of about 2500 ft. a 4-million-CU. ft.

Jan 1, 1941

In this paper, uniaxial compression tests were conducted on intact rocks and broken rocks that were reinforced by grouting, and the effects of grouting on the strength of broken rocks were analyzed. The results show that after grouting reinforcement, the bearing capacity of broken rocks with different lithologies increased, and their uniaxial compressive strength recovered by approximately 6%–16%. The results indicated that the stronger the rock, the smaller the strength recovery of the consolidated body formed after grouting. At the same time, using borehole camera observation and deep overburden strata separations, the fracture development characteristics of surrounding rocks of the gob-side retained entry were analyzed and divided into different regions. On this basis, a guided grouting method was proposed; that is, shallow hole grouting was first used in the plastic zone of the broken surrounding rocks to form the isolation layer, and then deep grouting holes were arranged in the elastic-plastic zone of the transition zone to guide the slurry flow to the shallow unfilled zone. Therefore, the broken surrounding rocks were reinforced into an integrated body and selfbearing capacity improved.

Jul 28, 2020

By H. J. Sutherland

This paper reviews the results of the subsidence research prop ram at Sandia National Laboratories. The manuscript highlights the following: the application of empirical methods (profile functions) to the subsidence above longwall panels in the U.S.; the use of the "rubble model" to describe the behavior of broken strata as it distends when it falls to the Mine floor (or top of the rubble pile) and then is subsequently compacted as it is loaded by overlying elements of strata; and, the application of physical modeling techniques (centrifuge simulations) and numerical techniques to study the failure mechanisms in highly structured stratigraphy. The capabilities of the latter two are illustrated ')y comparing their predictions to the results of a field case that has complicated stratigraphy.

Jan 1, 1982

By Andrew P. Jarosz

The present computerized mine planning systems use CAD-like and Data Base Management System (DBMS) environments for the handling of numerical, textural, and graphical data. These two environments are usually integrated, that the data provided by the DBMS are linked to any graphical element rendered by the CAD system. The subsidence monitoring, analysis and prediction process should be integrated with the mine design process. It should allow for the assessment of impacts of mining on surface, surface utilities, and structures. It should also provide for the measures to control mining, that will create only acceptable levels of negative impacts on the surface. The common data base, and graphical capabilities of the CAD interface, may be used with great advantage for both systems. The findings of the subsidence engineering modulus should be directly incorporated into the mine design system, and vice versa. In this paper the author suggests guidelines for the development of the comprehensive computer system, able not only to predict the vertical and horizontal components of the ground movement, but also assess the induced surface damages, and costs related to subsidence prevention and compensation.

Jan 1, 1995

By Val Ness, Leonard Harris

Mentoring is defined as close counseling by an experienced and objective advisor within the industry. It is one aspect of attracting the best candidates into the minerals industry, holding their interest, and encouraging stable career growth. By encouraging proper mentoring practices, we foster strong careers, we transmit important wisdom to the next generation, we fortify the industry with better talent, and we encourage the best possible advocates for the minerals industry. This paper illustrates the consequences of poor mentoring, offers an example of positive mentoring practice at the college or university level, reviews some guidelines for stable and fruitful mentoring, and proposes a plan to spread appropriate mentoring practices. Authors' note: The use of masculine pronouns is for convenience and simplicity only. Our best engineers and managers come from both genders, and the authors intend no slight to either one.

Jan 1, 2001

By Lulie H. Crump

Salient information on reserves, production, and consumption of fuels and energy by State is summarized in this Bureau of Mines publication. Reserve and production data are shown for each of the fossil fuels (coal, crude oil, natural gas liquids, and natural gas) and for uranium. The consumption data of each of the major consuming sectors (household-commercial, industrial, transportation, electric power, and miscellaneous) are broken down by energy source (coal, petroleum, natural gas, hydropower, and nuclear). In addition, total energy consumption in the Nation in 1974 is compared with consumption in 1973 and 1975 (preliminary data).

Jan 1, 1977

By Gergely Markos

Uranium mill tailings represent a potential threat to the human habitat by containing large amounts of radioactive and chemically toxic substances in high concentrations. These: undesired components enter the human habitat in various pathways such as by erosion and water or air transport. The main objective of this investigation was to evaluate the actual movement and model the potential movement of contaminants by seepage of water from the tailings into the subtailings soil. This report represents various models of the movement of contaminants using both theoretical approaches and empirical evaluation of data available from other investigations. The data consist of field measurements and laboratory determi¬nations of major and trace cations, the dominant anions, pH, and Eh of moist solids, extracts, and waters from the tailings and surroundings. Evaluation and interpre¬tation of data were accomplished by using Eh-pH diagrams, various statistical methods and the WATEQFC computer program. Data analyses show that the critical area of investigating movement- is the interfaces between tailings and the external environment. The chemical differences at interfaces seem to result in a sink system for contaminants. The tailings-soil¬-water system shows extreme complexities because of chemical and physical hetero¬geneity of the system preventing the use of a single comprehensive model to represent real conditions. The validity of the simplifying assumption used has been shown and increasing complexity has been built into the models. Analogs of these models can be used for evaluation of similar systems.

Jan 1, 1981

By W. B. Wise, H. D. Attra, W. M. Black

The purpose of this paper is to illustrate a comparatively new approach for solving a problem that has plagued oil producers for many years—how to make the most money with available field production capacity. In a very basic operation such as a top-allowable one-well field, a computer and staff of engineers are not required to determine that the best operation is to produce that well at its maximum for as long a time as it will produce. However, as the problem becomes more complex and the number of wells and number of reservoirs increase, it probably will be a wise choice to devote some engineering thought and calculation time to determine the best way to operate that field on both an ultimate and day-to-day basis. Continued developments in the field broadly referred to as "operations research" have led to a number of useful engineering analyses for optimizing field operational problems. One of these techniques, termed linear programing, is parlicularly interesting because of its potential applications to the study of complex oilfield operating problems. Linear programing is concerned with the problem of planning a complex set of interde~endenl activities in the best possible (optimal) fashion. A field application of linear programing is being used to maximize daily income from a multi-reservoir producing operation. The initial results of this study indicate that the linear programing technique (I) can be applied effectively to field problems, (2) can be used to detect unsuspected avenues for improving operations and (3) can effect a significantly improved means of controlling field operations through the use of the highspeed computer. INTRODUCTION The usual approach for studying complex field operational problems has been to look in detail at several basic plans suggested by judgement and experience and, then, to choose the best plan from those investigated. This approach is entirely satisfactory provided: (1) that judgment and experience alone will reliably pick the best or near the best program as one of the plans to be investigated; and (2), and most important, that the factors which control field production will not change. This paper deals with the large group of field operations which are at least one-step removed from a satisfactory solution using the conventional method of analysis. Problems such as pipeline- and gathering-system design, transportation studies, large field development projects and multi-reservoir producing operations fall in this latter category. To find the best program for handling these problems when the best program is not obvious, a complete optimization study is required, and high-speed computers are required to continually update the program once it is selected. Operations of this type have an extremely large number of possible solutions. However, only one will result in maximum economic return and, more important, this one program must be re-evaluated and adjusted constantly to accomodate such changing field factors as the number of producing days, the price of crude, the discovery of new reserves, declining reservoir pressure with subsequent decline in production and a host of other factors which characterize specific operations. One of the most widely used, direct methods of optimization is a numerical procedure termed "linear programing", which is designed to investigate systematically each of the possible solutions involved in a given problem, determining rapidly and uniquely the optimum answer. As implied by the name, linear programing requires that all field variables be either defined or expressed in a series of interdependent linear equalities or inequalities. These relationships are solved simultaneously, using a form of matrix solutions to determine the optimum values for each producing variable that will maximize net profits. The solution techniques used in a recent field case study is termed the "simplex method" and is discussed in full detail in Ref. 1.

During the latter part of 1937 consideration was given to the construction of a; local smelting plant for producing blister copper. Previously copper concentrates had been shipped to the United States of America. The proposition had the advantages of a saving in cost of realization, quicker financial return and reduced dependence on overseas shipping.The smelter was designed by the existing staff, who had difficulty in obtaining data on small plants, particularly on the reverberatory furnace. Construction was started in March, 1938, and the reverberatory was blown in on January 16th, 1939. One roaster had been operating for several weeks prior to this date.While results and operating technique on this new departure in small-scale smelting are barely beyond the experimental stage, it is felt that the experience gained to this time should be recorded to help fill the obvious gap in published information covering plants of this type.At present there are three copper smelters operating in Australia; the other two plants are equipped with blast furnaces.LOCATIONThe new smelter is situated in a position convenient to the concentrator and to the power plant. The site is traversed on two sides by a brick flue, from an old smelter plant, which connects with a 250-ft. stack. This stack and portion of the old flue are used in connection with the...

Jan 1, 1939

By Lucas Lopes da Costa

In this work, a natural foam extracted from the Amazon buriti palm tree is investigated as possible substitute for synthetic foams. The basic physical and mechanical properties of this biofoam were evaluated. Its sponge-like structure was characterized by the amount of pores and morphological aspects. It was found that the buriti biofoam displays a very low density of the order of 0.1 g/cm3 with a relatively good compressive strength. This would be suitable for several engineering applications and as a new material with the potential for replacing currently applied synthetic polymeric foams.

Jan 1, 2010

By R. Balia

The upper part of the "Contatto Ovest" orebody, at the San Giovanni Pb-Zn sulphur mine (Sardinia, Italy), is mined by a sublevel caving method. With increasing mining depth, a progressive caving of the hanging wall and discontinuous subsidence occurs. The orebody, which is located very close to the contact between the Cambrian limestones and the Silurian shales, strikes NE-SW for more than 100 m and dips 75-80' NW. The limestone footwall is massive and strong while the hanging-wall consists of very weak shales. The mine considered is located near a town so that the observed subsidence effects must be taken into account for both stability of the nearby railway and houses and morphological and environmental impact. A limiting equilibrium analysis to predict the progress of hanging wall failure with increasing mining depth was used. A suitable computer program was developed for solving the model by a iterative procedure. The progressive hanging wall caving and its consequent superficial effects were predicted perfectly by means of the computer program used and later confirmed by a geophysical test (seismic tomography). Our study ends with a further analysis, carried out using the same procedure, which allows to have a different geometrical situation with the presence of a pillar to protect the mill area.

Jan 1, 1990

By A Priatna, H Rumbino, T Casten

This paper discusses the progress of the Deep Mill Level Zone (DMLZ) mine from the pre-feasibility study completed in 2005, through commencement of development access in 2008, completion of the feasibility in 2010 and cave initiation in late 2015. This fourth lift of caving in the East Ertsberg Skarn System (EESS) is located 500 m below the currently producing Deep Ore Zone (DOZ) mine and represents approximately half a billion tonnes of ore and around 1900 planned drawpoints, scheduled to be mined at a peak of 80 000 t/d.The paper reviews the mine design, access requirements, planned footprint sequence and major fixed facility installations such as ventilation, oreflow and shops. A discussion of the preproduction development and construction activities and some of the critical technical challenges overcome during this time frame are addressed, as well as the cave initiation process undertaken in late 2015 and the ramp-up of production and progression of caving.CITATION:Casten, T, Priatna, A and Rumbino, H, 2016. Deep Mill Level Zone – from feasibility to production, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 635–644 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Kung-Lee Wang

SUSTAINED growth characterized the U.S. economy in 1964. Many new peaks were achieved in production, sales, employment, employee earnings, and business profits. At the end of 1964, the economy had experienced 4 years of uninterrupted expansion, and the greatest net gains in output for all postwar cyclical advances had been registered. There were no indications of the various weaknesses which have previously characterized advanced stages of business expansion. Both gross national product (GNP) and national income were 6.7 percent higher than in 1963. In 1964 GNP totaled $628.7 billion, a gain of $39.2 billion over the 1963 figure. On an overall basis, prices rose 1.75 percent in 1964. The real volume of output of goods and services (GNP in constant dollars) increased by 5.0 percent ill 1964; this was more than the 3.8-percent gain in 1963 but less than the 6.6 percent gain in 1962. The 1964 output gain also exceeded the average 3.7 percent annual increase for the postwar period. Congress authorized a two-stage tax reduction designed to further stimulate economic growth and employment. The tax cut favorably affected the 1964 economy in the following ways: By helping to boost personal income, corporate profits, and industrial production; by accelerating the pace of consumer spending and business capital expansion; and by increasing employment, thereby reducing unemployment to 5 percent. Three major problems remained unsolved. These were unemployment of 3.7 million persons, poverty conditions among more

Jan 1, 1965

By Woodcock J. T

When an aqueous suspension of pyrite and a manganese ore reacts with oxygen, manganese is dissolved by the ferrous sulphate and sulphuric acid produced in situ by oxidation of pyrite. In the absence of added acid, the optimum conditions are: a molecularratio of Mn02/FeS2 of about 1·0, a temperature of about 1400 C., and an oxygen pressure between 25 and 90 lb./sq. in. Under these conditions, complete extraction of manganese is obtained in six hours leaching. An addition of sulphuric acid enables an Mn02/FeS2 ratio of 2·0 to be used successfully.Manganous sulphate decreases in solubility with increase in temperature above 1000 C., but even when the solubility limit is reached during leaching, reaction to form MnS04 still proceeds, and on cooling the MnS04 redissolves.INTRODUCTIONMany manganese deposits contain secondary manganese oxide minerals which are difficult to concentrate. Considerable attention has therefore been given to their hydrometallurgical treatment. In most manganese oxide minerals, the manganese is quadrivalent and must be reduced to the divalent state for dissolution. Reduction and dissolution can be accomplished in a number of ways, one method being to use aqueous ferrous sulphate solutions.A possible source of ferrous sulphate is pyrite as it is known that ferrous ion is an intermediate product in the aqueous oxidation of pyrite. It was therefore thought possible, that by heating an aqueous suspension of manganese oxide and pyrite with oxygen, the ferrous sulphate and sulphuric acid formed from pyrite would provide the necessary leaching reagents for manganese in situ. There are certain advantages in producing ferrous ion in situ...

Jan 1, 1958

By C. F. Weinaug, R. W. Farley, J. F. Wolfe

A rapid, accurate method for predicting the dew points of gas condensate systems and their subsequent normal and retrograde phase behavior with pressure decline has been developed. The method predicts dewpoint pressure, volume percent liquid, condensate content of produced gas, and the liquid and gas compositions at pressures below the dewpoint pressure. Use of a modified form of the BWR equation of state, which was established by regression calculations on experimental data from several gas condensates, provides depletion behavior predictions that are significantly improved over predictions using K-values based on convergence pressures and Standing's correlation for density. INTRODUCTION Prediction of complex hydrocarbon-mixture thermodynamics is fundamental to reservoir and gas process engineering. In particular, accurate descriptions of phase behavior are needed to plan production operations for gas-condensate reservoirs. Although analysis of reservoir behavior during producing and cycling operations can be made for simple reservoir models, extensions of these studies to more complex reservoir systems are still difficult, both with regard to numerical techniques and the phase behavior of the fluids. This report presents a mathematical method for handling the complex phase relationships encountered in retrograde condensates; it represents an advance in reservoir behavior technology in that it will aid the development of closed-form mathematical representations of total production systems. A typical phase diagram for a complex hydrocarbon mixture is shown in Fig. 1. When the reservoir temperature T, is higher than the critical temperature Tc, and lower than the critical-condensation temperature Tct' the mixture is a gas condensate. Decreasing the pressure on a condensate while maintaining nearly constant temperature will result in two phases forming at the dew point. Further decrease in pressure will cause additional liquids to be formed. This phenomenon is called retrograde condensation. As pressure continues to decrease, normal phase behavior regions are encountered (liquid vaporizes as the pressure decreases) until the low-pressure dew point is encountered. When a gas-condensate reservoir is produced, gas is withdrawn and the volume of fluids in the reservoir remains nearly constant as the pressure declines. Heavier components tend to accumulate in the liquid phase as a result of retrograde condensation, while lighter components tend to concentrate in the vapor phase. Thus, as the gas is produced the composition of the gas and the condensate

Jan 1, 1970