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By Ulrich Maidl, Gustavo Aguiar, Argemiro Ferreira, Marco A. Peixoto Silva, Marc Comulada

"Metro Line 5 in Sao Paulo is being constructed. This lot extends for 4,940 m with twin EPB shield tunnels under a dense and busy urban area, with an excavation diameter of 6.9 m. The tunnels run predominantly in the tertiary soils of Sao Paulo where extensive experience exists from previous EPB shield tunnel projects. However, new experience is being gained in Sao Paulo in shield tunnelling through Saprolite, the weathered product of the underlying Gneiss crystalline basement, through the resulting residual soils and in rock-soil mixed face conditions. Furthermore, experiences in difficult mixed face soil conditions with overconsolidated clay at the face in combination with loose sands at the crown under the groundwater table will be presented. Additionally, the design, operational and controlling approach followed for the shield drive at particular critical cross-sections where the shields were driven close or under buildings. INTRODUCTION Within the framework of Sao Paulo´s metro network expansion, the excavation of the shield tunnels for Metro Sao Paulo Line 5 is currently taking place. The present paper deals with the description of the most relevant features from the construction of the Line 5 – Lot 3 tunnels. The paper presents how particular challenges were dealt maximising potential of EPB shield tunnelling technology. Challenges were posed not only by the difficult boundary conditions of urban shield tunnelling, such as shield drive under buildings, but also by complex geotechnical situations. PROJECT DESCRIPTION The great urban area of São Paulo is one of the biggest cities in the world, with around 20 Million people living in the city and in the suburb area. The city faces great mobility problems and in the last years the government has been investing great amounts on the megacity´s metro expansion. The Line 5 Extension plays an important role to connect the south area to the central area of the city, with a whole extension of 11 kilometres, including 11 new stations. It is estimated that this line will transport almost 900.000 passengers/day. The first stretch of the expansion, Lot 3, consists of two single tunnels, almost 5 kilometres long each, crossing 4 stations. Figure 1 shows details of the Line 5 Expansion."

Jan 1, 2016

"SART technology is a useful tool for improving the economics of gold recovery from certain types of complex gold ores. SART liberates cyanide consumed by base metals such as copper, zinc and nickel, and enables the newly freed cyanide to be recycled to precious metals leaching while producing high-grade base metal sulphide concentrates for sale. The benefits of SART include the reduction in cyanide consumption, avoidance of cyanide destruction costs, minimization of risks of environmental non-compliance due to residues of cyanide destruction reporting to mine effluents, and generation of extra revenue from the sale of base metal concentrates. Concerns with SART typically include uncertainties around capital and operating costs and proper integration of SART into the overall metallurgical flowsheet. This paper presents two case studies addressing these concerns. The first involves actual costs of the full scale SART integrated into a gold heap leach operation and treating up to 500 m3/hr of leach solution at a mine in Mexico. The second involves field pilot testing and a preliminary cost estimate for integrating SART into a silver mine in Peru using Merrill Crowe.INTRODUCTION One of the current trends in the gold industry globally is the increasing importance of complex polymetallic gold deposits as discoveries of large Carlin type gold deposits become increasingly rare (Sceresini, 2005). The presence of cyanide soluble copper and zinc in complex gold deposits necessitates changes in traditional gold extraction metallurgical flowsheets. One of the tools available to the industry to help deal with interferences of cyanide-soluble base metals in gold extraction is the SART (sulphidization-acidification-recycling-thickening) process. SART breaks the weak acid dissociable (WAD) base metal-cyanide complexes, precipitates the metals as high-grade sulphide concentrates and makes the freed cyanide available for recycle. Although SART is a commercially available technology, it is still relatively new to the industry. Fewer than ten (10) full scale plants have been constructed in the past couple of decades. Some of these SART plants are small, most are located at remote sites, and the majority have not operated on a continuous basis. This has resulted in a general lack of information in the industry about the true costs, operability and metallurgical performance of SART. BQE Water has been involved in the design, construction, commissioning and operation of large scale SART plants in Mexico, Turkey and Chile and has conducted field testing programs as part of the technical assessment of SART integration into various metallurgical circuits. Having built and operated numerous plants utilizing selective sulphide precipitation of heavy metals, BQE Water has gained unique insight into the design and control of the sulphidization stage of SART to minimize costs and ensure high efficiency in cyanide recovery."

Jan 1, 2017

By M. Bélanger, H. -L. Jacob

"The province of Quebec has a strong tradition in industrial minerals. Ten commodities are produced and the annual total shipments have exceeded $600 million in recent years. Quebec is a world renowned producer of chrysotile, titanium slag, graphite, and ilmenite. Quebec is an important North American producer of mica, talc, and peat moss. This paper reviews the main minerals and commodities that have been the object of exploration or development in recent years, namely graphite, wollastonite, dolomite, and silica. Some of the leading projects concerning magnesium minerals and apatite-ilmenite are described. IntroductionQuebec has a strong tradition in industrial minerals. It goes back to the second half of the 19th century when the first graphite and apatite mines in the Gatineau area and asbestos mines in the Eastern Townships were opened. Since then, more than 25 commodities have been produced in Quebec, making industrial minerals an integral part of the Quebec mineral industry. Today, industrial minerals and building materials count for one third of the total mineral production in Quebec.Present industrial mineral production includes 10 commodities (Table 1). In the last five years, the value of industrial mineral shipments has varied between 500 and 700 millions dollars annually, which represents 20% to 25% of Quebec’s total mineral production. For many years, Quebec has been a major producer of chrysotile and titanium slag, the only producer in eastern North America of mica, graphite and ilmenite, and a leading Canadian producer of talc and peat moss. Quebec also produces, mainly for domestic markets, dolomite, limestone, salt and silica.Quebec’s industrial mineral sector has been quite active in the recent years. Exploration by government geologists and companies has led to the outlining of new deposits, some of which are now in production; others are currently being evaluated. Technical and economic studies are also underway to determine the feasibility of various development projects."

Jan 1, 1999

By Ulrich Maidl, Marc Comulada, Janosch Stascheit

"INTRODUCTION Cohesive soils are notorious for causing clogging of the cutter head and the excavation chamber of tunnel boring machines (TBMs). While clogging leads to a drastic reduction in excavation performance, it further induces higher wear of tools and other parts of the cutter head and may even prevent a controlled support of the tunnel face and, thus, lead to face collapse and excess settlements or sinkholes. Employing well-balanced soil conditioning techniques, the clogging tendency can be significantly reduced. The monitoring and control of soil conditioning as well as the timely detection of potential clogging tendencies require a close monitoring of all relevant machine parameters and measurements. To this end, a reliable and powerful Process Controlling software that gathers all machine and process-related information is a prerequisite for successful mitigation of clogging-induced problems. The remainder of this contribution is organized as follows: First, a brief introduction to the Process Controlling system PROCON is given. Afterwards, the mechanisms and mitigation techniques of clogging are discussed. Finally, an example is given how Process Controlling has been employed to soil conditioning in a tunneling project with highly clogging soils.PROCESS CONTROLLING Being both the active part and a huge measuring device, the shield machine represents the core component in mechanized tunneling. This machine comprises a manifold of complex components and devices that require constant supervision and control and, thus, is equipped with a manifold of different sensors that provide a continuous monitoring of the state and condition of the machine (Maidl & Stascheit, 2014). If these data are put into the whole context of the tunneling process, they can provide insight to the assessment and optimization of the performance and to the prediction of potential risks and hazards such as, for example, the tendency of clogging of the cutter head."

Jan 1, 2016

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By T. S. Lundström, B. D. Marjavaara, I. A. S. Larsson

"The flow field in a rotary kiln, used in an iron ore pelletizing process, was investigated using a three-dimensional computational fluid dynamics model. The model is isothermal, downscaled and simplified. The objective was to examine the possibility of capturing the unsteady motion of the flame seen in the real kiln. The results from the simulations were compared with recorded images of the real process. The results demonstrate the possibility of quickly getting an overview of the flow field in the kiln. The main, unsteady behavior of the flame was captured. The model may be used as a tool in the ongoing work of improving and optimizing the pelletizing process.IntroductionThe pelletizing process, in which the crude iron ore from a mine is upgraded into pellets, is a process involving large amounts of hot air flowing in complex geometries. Flow control is a crucial factor in this process to maintain high pellet quality. The rotary kiln is one of the last steps in the pelletizing process, and this is where the pellets are sintered to increase their strength and metallurgical properties. The kiln burner produces a flame that supplies the entire pelletizing process with the necessary heat.Kiln burner flames are large diffusion flames arising from a jet of fuel from the burner issuing into a concentric confining cylinder with a surrounding coflow of air, called secondary air. To enable combustion, the secondary air needs to be entrained into the fuel jet. This mixing of the fuel and air is the slowest step in the combustion process and therefore affects the efficiency of the combustion. The rate of entrainment depends on the momentum ratio between the burner jet and secondary air. The higher the momentum ratio, the faster the entrainment rate and, consequently, the faster is the fuel/air mixing.The kiln of interest in this study differs from kilns used in other industrial processes in both geometry and operating conditions. A distinguishing feature is the large amount of secondary air being induced through the kiln hood and then transported to earlier stages in the process as air or exhaust gas. The secondary air therefore has a substantial momentum, implying that the resulting flow field has a significant impact on the mixing and combustion process in general and the flame shape and stability as well as combustion efficiency in particular. A systematic study of the factors influencing the dynamics of the flow field in the kiln, neglecting the combustion, is therefore justified."

Jan 1, 2016

By M. E. Wilson

"The property of McWatters Gold Mines, Limited, is in the east-central part of Rouyn township and about 6 miles east-southeast of the town of Rouyn. It includes 35 claims, the group of 5, staked originally, and 30 claims acquired in later years. The Rouyn-Val d'Or road and the Noranda Senneterre branch of the Canadian National railway both pass within a few hundred feet of the mine.The group of claims in which the mine occurs was first staked in 1922, but gold was not discovered until August 1932 when a schistose zone including veins of quartz carrying considerable free gold was laid bare in a stripped area in the northeastern part of claim R.11604. Diamond drilling undertaken in 1932, and continued into 1933, shouwd that the gold extended for at least 1,000 feet along the strike. A 3-compartment shaft was sunk to 418 feet in 1933. A mill having a capacity of 50 tons a day was constructed in 1934, and enlarged to 150 tons in 1935. Production began in 1934 and continued without interruption to June 1944. Except for a few diamond drill holes, there have been no operations on the property since that time. The maximum depth of the mine workings is 1,50) feet. A total of 368,013 tons of ore having a value of $3,946,752 and an average grade of $11.04 was mined during the years of operation.GEOLOGYThe ore mined from the property occurred within the south limb of an eastward plunging syncline of volcanics and sediments cut off on the north by the Cadillac-Bouzan Lake fault. Because the rock formations within the syncline have been severed from those outside with which they were originally continuous, their correlation is based almost wholly on lithological similarity. They include an irregular middle zone of conglomerate and greywacke underlain by north and south bands of andesite agglomerate and andesite tuff, in which lenticular bands of pillowed andesite are included."

Jan 1, 1954

By Mitchell L. Spencer, Viswanathan Panchanathan

"Bonded magnets are important category in permanent magnets. They are made by one of the following processes: compression bonding, injection molding, extrusion, calendering. An overview of the various bonded magnet processes and properties of products made with different magnet materials along with their applications are discussed. The main emphasis will be on the use of bonded NdFeB and ferrite magnets.IntroductionBonded magnets are a major growth area in permanent magnets. Bonded magnets are made by any one of the following processes: Compression bonding; Injection Molding; Extrusion and Calendering [1,2]. Compression and injection molded magnets are rigid magnets. Materials used in calendering process produce flexible magnets. Only the extrusion process makes both rigid and flexible magnets. The binders used for the bonded magnets vary depending on the processes. Thermoset, thermo-plastic and elastomeric binders are respectively used in compression, injection and the calendering process. Extrusion molding uses elastomers or thermo-plastic materials. The most co=on magnetic materials, Ferrite, SmCo, Alnico and NdFeB can be used in any of the above processes either alone or in combination as hybrid magnets. Another material that has been developed for co=ercial application is SmFeN. Making the material has been challenging and it is being used in niche market applications in limited quantitiesIn the extrusion process, a highly loaded compound is used to produce strip or sheet and is continuously extruded through a die. In calendering the granulated compound is rolled to produce a continuous wide sheet. In the compression bonding process a uniaxial pressing force is used. These magnets have higher loading compared to injection molded magnets. In injection molding the material is forced into a mold cavity and has lower loading compared to compression molded magnets [2,3]. Most of the flexible magnets are made using extrusion and calendering processes and the most co=on magnet material is inexpensive ferrite. Flexible magnets have been made using rare earth materials, but on a very limited basis.The major advantages of magnets processed by extrusion and calendering are as follows: inexpensive tooling, automation; practically any 2D geometry; fast production rates; no chipping or breaking; a wide range of properties; on-line magnetization; easy to convert (e.g. cut, punch or shape).Compression bonded magnets are inexpensive to manufacture. They have higher magnetic properties compared to injection molded magnets; however lower than their sintered counterparts. The magnet shape is restricted to simple geometries and they require careful handling. Their isotropic nature allows complex magnetizing patterns."

Jan 1, 2013

By E. G. dos Santos, M. M. Veras, C. H. Sampaio, A. S. Young, R. S. Paranhos, C. O. Petter, A. C. Bastos

"The major challenges of the current mining are the energetic optimization, the lowest water consumption and minimizing environmental impact. One technique that eliminates much of the waste avoiding milling sterile, operating without water and to decrease the generation of waste at the end of the process, must be considered a major innovation. One of the most important developments in these past 10 years in the mining industry was expanding the use of high-tech sensors aimed at pre-concentration of ore. Among the mining areas where this type of technology is booming is the industrial minerals. The most common sensors are color sensors with Charge – Coupled Devices (CCD cameras) allowing through the RGB colorimetric system, the separation of minerals with different hues, and in many cases, a difference in brightness. More recently, the development of the use of dual energy X-ray transmission (DE-XRT) Dual Zone allowed the separation by atomic density of the mineral constituents of the rock. This paper presents a review of these two techniques (CCD and DE – XRT) as well some results showing the use of these two techniques for Earth Rare and Limestone. INTRODUCTION The mining industry is going through one of its biggest technological changes since the industrial revolution by the implementation of new technologies, according to Australian Mining Magazine (2015), whose theme emphasized one of the 10 greatest challenges that mining will face in the coming years. Optimization of the energy matrix in mining is focused on reducing water consumption and minimizing environmental impacts. The implementation of sensor technologies (Sensor-Based Sorting - SBS) allows elimination of mill tailings and permits the mill to operate with reduced use of water or totally eliminate this consumption (Young et al, 2016). According to Jönsson (2014) mining has undergone striking changes with the expansion of sensors of high technologies applied in the pre-concentration of mining ores. These techniques have contributed over the past 10 years in the recapture of mining areas with emphasis on the environment and/or operational optimizations. In line with the requirements of technological innovation, the mining industry is forced to make improvements in gravimetric processes ensuring better levels of Run of Mine ore feed in beneficiation plants. The implementation of automatic sorting, assisted by dual energy x-ray transmission (DE-XRT) sensor technology, or charged coupled device (CCD) image capture camera technology in the feed plant, allows for the selective sorting of individual particles into pre-concentrations (Veras et al, 2016)."

Jan 1, 2017

By Lendall P. Warriner, Blandford C. Burgess

Jasper County lies just north of the geographical center of Georgia, bounded on the west and north by the Ocmulgee River. The county seat, Monticello, is approximately 65 miles east-southeast of Atlanta and 40 miles north of Macon. It is served by the Macon-Athens branch of the Central of Georgia Railway Co. and by five paved highways converging from adjoining county seats. Farming and lumbering are the principal local occupations. About half the county is covered with pine and mixed hardwoods; a large part of the forested land is owned by the Soil Conservation Service of the Department of Agriculture in its Piedmont Land Utilization Project. The topography is one of gently rolling field and forest with occasional hills rising 100 ft or: more above the creek beds. Though annual rainfall is in the neighborhood of 60 in., most of it falls in torrential downpours of short duration which tend rapidly to erode the red soil and convert the country roads to greasy tracks of red mud.

Jan 1, 1949

By Xun Luo, Yi Duan

A field trial of by distributed optical fiber sensing (DOFS) technique was conducted at a longwall coal mine in Australia. This investigation was designed to assess the applicability of DOFS for microseismic monitoring in mining. The experiments used commercially available optic fiber cables, geophones and associated data acquisition instruments – a fiber interrogator and a seismic recorder. The fiber cable was deployed in a 300m deep hole and in trenches of approximately 3.5 km long on the ground surface around and across the longwall panel being mined. The results obtained from the experiments have shown that DOFS is able to acquire microseismic data with quality that is comparable to geophones. It has been proven that DOFS can achieve higher spatial resolution for seismicity sensing and higher accuracy for locating events than a geophone network. These characteristics are particularly useful for using DOFS to monitor ground vibrations associated with ground caving processes and rock fracturing events induced by mining and civil engineering. It was also found that far more additional seismic events were recorded by the fibers than by the geophones. Automated data discrimination and processing methods must be developed in order to utilize DOFS for real-time applications.

Apr 26, 2022

By Petr Dvorak, Jana Selucka, Hong Vu, Petra Starkova, Tomas Frydl

Waste, generated during high pressure leaching of lateritic nickel ores, contains about 50% of iron in form of magnetite but high chromium content ( *3%) does not allow its extensive utilization as the raw material for pig iron production in blast furnace. The chromium removal from the waste was carried out by two methods: (1) oxidative alkali roasting with NaOH and/or Na2CO3, followed by water leaching and (2) oxidative leaching in KOH sub-molten salts solutions. The results show that about 90.1% of Cr was removed when the waste was roasted at 900 °C for 3 h with 33.1 wt% of NaOH. The removal of 88.2% of Cr was achieved if the waste was roasted at 900 °C for 3 h with 40 wt% of Na2CO3. The sodium content in the water-leached residues was reduced from 5% to about 0.5% by reaction with CaO in aqueous solutions at 80 °C for 2 h. About 70% of Cr was removed if the waste was leached at 190 °C in 73 wt% KOH for 8 h.

Mar 1, 2017

By Felipe Darabas Rzatki

Polyether ether ketone (PEEK) is a high performance thermoplastic often selected for high temperature tribological applications under chemically aggressive environments. The present work evaluate the tribological behavior of a high performance PEEK composite under ambient and high temperature (30 and 80°C, respectively). The atmosphere was also varied (air or tetrafluorethane). An AMTI tribometer equipped with a hermetic chamber and a heating system was used to carry out sliding tests of PEEK cylinders on 304 stainless steel polished discs (Sq < 10 nm) with reciprocating movement and 175 N normal force. Surfaces roughness analyses were performed with a white light interferometer. As expected, there was a strong influence of temperature on the tribological behavior of the samples tested in ambient atmosphere (25% decrease in friction coefficient associated with a 100% increase in wear rate). On the other hand, samples tested in tetrafluorethane atmosphere showed no significant friction temperature dependence.

Jul 31, 2018

By John Anawati

Bauxite residue is an environmentally unfriendly byproduct of alumina manufacturing, produced worldwide in large quantities. This material contains 50– 100 ppm of scandium, a critical material for the production of stronger, weldable, corrosion resistant, and heat tolerant aluminum products. Aircraft manufacturers are particularly interested in Al–Sc alloys because of its ability to form weldable alloys that could potentially reduce aircraft weight by 15–20%. Because of its abundance and low cost, bauxite residue has the potential to be used as an efficient feedstock for valorization processes to recover its scandium content, while in turn degrading this problematic waste. In this project, we developed an efficient process to recover scandium and rare earth elements from a Canadian bauxite residue with high extraction yields, using industrially scalable and economical techniques. The process employs a modified version of sulfuric acid leaching and subsequent impurity removal by selective precipitation. This article outlines the current progress and design rationale in the development and optimization of this innovative and sustainable recovery process.

By Duclerc Fernandes Parra, Vijaya Kumar Rangari, Washington Luiz Oliani, Danilo Marin Fermino, Ademar Benevolo Lugao, Nilton Lincopan, Luiz Gustavo Hiroki Komatsu

Polyethylene is widely used for packing applications. Different grades of polyethylene, LLDPE and LDPE play a major role in the film blowing industry. The use of nanoclay in polymer matrices (non-polar) requires the use of a compatibilizer agent, ethylene graft maleic anhydride copolymer (PE-g-MA), which acts as a bridge for nanoclay-matrix-interaction. In our study, blown films of LLDPE, LDPE, and their blends were produced using a twin screw extruder. The combination of PEs as matrix, montmorillonite (MMT) and silver nanoparticles (AgNPs) intended to improve mechanical and thermal properties. Nanocomposites films with 1 wt% of montmorillonite and 0.5–1.0 wt% silver nanoparticles were prepared by blow extrusion and evaluated. Nanoclay intercalation/exfoliation degree was investigated by X-ray diffraction spectroscopy (XRD) and scanning electron microscopy (SEM). Mechanical and thermal properties were evaluated. The results showed optimum dispersion at intercalation/exfoliation levels for polyethylene nanocomposite (PENC), slight increasing in mechanical and especially improvement in thermal properties.

Mar 1, 2017

By John Vynne, John Hutchings

There have been a number of recent technological advances in instrumentation for blasthole drills, and more specifically in drill monitoring and HPGPS guidance systems. Likewise, great strides have been made in the development of drill and blast software systems which are user friendly, while providing far greater capability to accurately design and monitor drill and blast patterns.

Jan 1, 2011

By Shiwei Sun, Hongxu Li, Xiangxin Hao, Xie Yang

"Environmental impact assessment of copper metallurgical processes will soon become a compulsory activity in the future. The goal of this work is to analyses the copper metallurgical processes including pyro-metallurgy and hydrometallurgy based on the life cycle assessment method implemented in GaBi software. The evaluation indicators such as global warming potential (GWP), acidification potential (AP), photochemical ozone creation potential (POCP) and human toxic potential (HTP) are taken into account. The results show that the major environmental impact phase in pyro-metallurgy derives from beneficiation because of the largest material and energy consumption. It is also shown that copper hydrometallurgy has significantly lower environmental impact than pyro-metallurgy. Based on the evaluation results, some corresponding optimization methods are recommended to reduce environmental impact.IntroductionCopper is an important metal in modem society due to its wide variety of uses, including electrical wiring, heat exchangers, piping and roof construction and increasingly consumer electronics. Demand for copper has increased dramatically over the past decades, driving production rates almost exponentially. Annual production of copper was estimated to be 20 million tonnes in 2012 with Chinese production at about 6.06 million ton in 2012P1. The production process of copper has environment impacts that often go unnoticed by the producer. Higher production, coupled with declining ore grades, is placing increasing pressure on the natural environment.Sound environmental management helps producers improve their manufacturing technique. LCA is a well-established tool for assessing environmental impact potential and can be readily adapted to map impact potential over time, which can be used to quantify the environment impacts of a product or a process [21. This is achieved by creating an inventory of all the energy and material flows used in the process's life cycle. The results of an LCA can be used to improve the operation of a process so that they have less impact on the environment."

Jan 1, 2014

By Yuanbo Zhang, Zijian Su, Bingbing Liu, Guanghui Li, Jicheng Liu, Manman Lu, Tao Jiang

Blast furnace slag (BFS), one kind of typical solid waste in the steel industry, was used as structural materials to synthesize NaNO3/BFS composite phase change materials (C-PCMs) by mixing and sintering method. NaNO3 in the composites functioned as phase change materials (PCMs) and BFS as structural skeleton to maintain a stable external form. In this study, the prepared C-PCMs could remain in the solid state without salt leakage even if operating temperature exceeded the melting temperature of NaNO3. The composition and structure of BFS and the prepared composites were characterized by XRD, FTIR, SEM and TG-DSC analyses. The results showed that NaNO3 was well incorporated in the pores of BFS. The melting temperature and latent heat of the final composites were 300.5 °C and 65.53 J/g, respectively. The product also had good thermal storage performance and durability even after 100 thermal cycles. The energy density of the product was calculated as high as 468.03 J/g for an temperature range of 50–400 °C.

Mar 1, 2018

By J. C. DeSantis

Thin, highly reflective rhodium films with metal compositions greater than 98% (elemental -weight percentage) have been deposited by chemical vapor deposition using Rh(allyl)3 (ally1 = q3-C3H5) in the presence of a hydrogen plasma. Uniform, crystalline films that adhere well to several types of substrates result from depositions at temperatures as low as 150°C. Depositions using H2 (no plasma), or an argon plasma yields material that is amorphous, contains a significant amount (>14%) of residual carbon, and has a dramatically slower growth rate. The composition of these materials does not vary significantly from that of the materials obtained from the in vacuo thermal deposition with Rh(allyl)3.

Jan 1, 1992

"A fire design innovation of the concrete lining of the Ohio River Bridges East End Crossing Tunnel has been developed. As a result from a fire suppression and tunnel ventilation system, the project design Heat Release Rate (HRR) was able to be constrained from 300 MW to about 50 MW. With this reduced HRR, concrete lining without passive fire protection may be acceptable, if the tunnel concrete lining will not result in explosive spalling during the designed fire event. Concrete explosive spalling test was proposed to verify this assumption. Since no standard concrete fire explosive spalling testing procedure exists, a project specific testing procedure was developed and fire tests conducted. From fire test results, it is concluded that the proposed tunnel concrete lining, in conjunction with the proposed fire suppressing and ventilation system, will not experience explosive spalling and does not require a passive fire protection system. INTRODUCTION The Ohio River Bridge East End Crossing Tunnel is part of a Public Private Partnership project, which connects transportation network between Louisville, Kentucky and southern Indiana. Located in Louisville, Kentucky, the twin-tube highway tunnel provides northbound and southbound lanes of the Kentucky approach to a new bridge across the Ohio River. Tunnel lengths are approximately 1,675-ft and 1,685 for the northbound tube and the southbound tube, respectively. Connected by two cross-passages, both tubes have a roadway width of 40-ft, for 3-lane traffic, and a vertical clearance of 26.5-ft.The Tunnel was constructed by drill and blast method with shotcrete and rock dowels as initial ground supports. The final tunnel lining consists of 16 inches cast-in-place concrete lining and 20 inches invert slab, with a waterproofing system around the tunnel perimeter. Two (2) tunnel side drains and one (1) invert drain were provided for each tube. This paper describes the rational in assessing fire design requirements of the tunnel final concrete lining, to answer the question whether a passive fire protection system is needed or not."

Jan 1, 2016