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By Marcio Toshio Tanaka, Marcelo Breda Mourao, Cyro Takano, Cesar Yuji Narita

"The concerns in questions related to the environmental impact in the steelmaking industries caused mainly on the gas emissions such as the dioxide carbon are due to its raw material such as the coal, a fossil and non renewable resource. The purpose of this paper is to replace from 10% to 50% of the coal used in cokemaking by mixing it with a renewable source (wood charcoal). The powder (- 325 mesh) from both raw materials (coal and wood charcoal) were mixed in order to obtain a briquette that was then heat treated at 1100°C to obtain the biocoke. Results of usual analysis (coke reactivity index, coke strength after reaction and cold crushing strength test) were employed to compare to regular coke briquettes. It was found that biocoke with different amounts of wood charcoal present features enabling it to be used in some ore reductionprocesses.1. IntroductionThe iron and steelmaking industry is a heavy emitter of carbon dioxide; according to the World Steel Association, 6.5% of global emissions of this greenhouse gas is due to the production of ferrous materials [ 1]. This is due to the fact that the fuel and reductant employed in the blast furnace is metallurgical coke, obtained from fossil coal. There are some projects aiming to reduce or even eliminate the emission of fossil GHG in the iron and steelmaking process [2]. Most of them propose the capture and storage of the gas (CCS) [3], a technology not yet proven. Other studies point out that the coke consumption in the blast furnace could be reduced by using high reactivity coke; this could lead to lower temperatures in the thermal reserve zone of the blast furnace and consequently less fuel rate in the furnace.The use of biomass in the iron ore reduction process is known as an environmentally accepted solution, as biomass does not release already fossilized carbon."

Jan 1, 2013

The Metallurgical Development of an Enargite-Bearing Deposit

Sep 13, 2010

By Carl W. Dalrymple

A wide variety of contaminants (heavy metals, suspended solids, colloids, oils, organics) have been successfully removed from wastewater using an electrocoagulation process. An innovative electrocoagulation system is described. This process involves a procedure which subjects dissolved and suspended wastewater contaminants to the simultaneous addition of metal ions in the presence of direct current. During the treatment process Ionic and other charged particles in the wastewater are neutralized with oppositely charged ions generating the coagulation of contaminants: The process Is called CURE, and' presented here with application to wastewaters containing mainly heavy metals.

Jan 1, 1995

By Thomas Kuhn

The detailed investigation of both active and inactive submarine hydrothermal systems has gained tremendous progress during the last decades because of the increasing usage of remotely operated vehicles (ROV) as well as manned submersibles. Special aspects like the targeted sampling of chimney structures and vent fluids as well as the analysis of zonations of near-surface structures like sulfides mounds was only possible with the usage of such vehicles. However, the availability of such vehicles has been very limited because of the few number of deep-water ROVs and manned submersibles which need both a trained crew and a special research vessel. This was especially true for the German science community which did not have such devices at its disposal until recently. With the ROV QUEST 5 which is based at the University of Bremen (c/o. Prof. Dr. G. Wefer, Dr. V. Ratmeyer) this major drawback has now been eliminated.

Jan 1, 2003

By Richard P. Roberts

This paper will discuss the methods for the cooling of aluminum melting furnace? dross .and their impact on the environment. Also discussed will be a case history of an AROS Dross Processor installation, which is designed to maximize the recovery of metal content of the dross in a manner which is not only environmentally cleaner, but which also prepares the output in such a way as to facilitate downstream processes. Handling of the discharged material will be discussed in regards to the recycling of the preserved metal content and deposition of the unusable-materials.

Jan 1, 1992

By C. P. Browning

Copper, as far as we know, was the first metal used by man, and due to the fact that it occurs in many places in the 'native' state, and also to the ease with which it may be shaped, it has played an important part in the evolution of civilization. Copper tools with inscriptions dating back to 6,000 B.C. are known in Egypt, where the metal probably got its start as a useful material in human hands. Just how far back the use of copper in Canada dates is difficult to say, but it was in use by the Indians in the Lake Superior country long before the arrival of the first white man. For many generations the Eskimos also have used copper derived fr0m deposits of the native metal found in the Coronation Gulf district. Due to the metal's many unique qualities, imperishable with age, ancient implements and utensils are apparently as good today as when they were made, having withstood the onslaught of time probably better than objects of any of the other base metals. Copper alloys so well with other metals that today it is second only to iron in its industrial value. Even at the beginning of the eighteenth century the world's production of copper was probably not more than seven thousand tons a year, with Great Britain producing three-fourths of this. One hundred years ago the mines of the United States, Chili, Mexico, Canada, South Africa, Australia, and Tasmania, which now produce about nine-tenths of the copper of the world, were totally undeveloped. Ln 1926 the world production of copper was approximately 1,658,000 tons, which was seventy thousand tons greater than in the preceding year; but growing demand absorbed the increased production, so that the stock of rough copper throughout the world is comparatively small. Of this huge tonnage of the metal, Canada produced four percent, two-thirds of it emanating from British Columbia, nearly one-third from the Province of Ontario, and the balance from Quebec.

Jan 1, 1927

By Wyborn L, Giddings J. W, Plumb K. A

The McArthur, Balma (new name) and Habgood Groups are thick (up to 4.5 km) correlative sequences of shallow water evaporitic carbonates, mudstones and sandstones that are exposed largely within the Batten, and southern and northern Walker Fault Zones (Batten and Walker Troughs) of the McArthur Basin respectively. Recent re-mapping of the Walker Fault Zone has provided data for refined stratigraphic correlations between these groups. Two significant hiatuses are now recognised within the Balma Group (base of Vaughton Siltstone and base of Yarrawirrie Formation) and these may represent tectonically-generated sequence boundaries which may correlate with similar local hiatuses within the McArthur Group such as at the base of the Teena Dolomite and Lynott Formation respectively.

Jan 1, 1994

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By S. E. Khalafalla

In support of its goal to maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines has investigated a novel hydrometallurgical system with sulfur dioxide. Differential leaching with dissolved SO2 of manganese, nickel, and cobalt from their hydrous oxides was found to be very rapid and efficient--almost instantaneous and quantitative. In this method a given weight of mixed oxides previously ground to minus 200-mesh is slurried with a leach solution containing a specified quantity of dissolved SO2 for 10 minutes at room temperature and ambient pressure. An empirical leaching parameter, R, is defined as the ratio of the number of SO2 moles in the leaching solution to the weight of the metal oxide charge. Plots of the variation of metal extraction with the ratio R generate a series of sigmoidal-shaped curves, each of which is characteristic of a specific metal extraction. A threshold value of R is required to initiate the leaching of a given metal from the mixed oxides. Once this threshold is reached, the metal recovery can increase to more than 95 pct in very short times. For increasing values of R, the extractability of various metals by SO2 follows the order: Mn > Ni > Co >> Fe, Al, Cu. Differences in the threshold R values permit a variety of metal separations to be made simply by adjusting the quantity of SO2 in the contacting solution. Success in this leaching system depends upon comminuting the sea nodules to less than 0.149 mm (100-mesh). Above this critical size, leaching is slowed due to the inaccessibility of inner particle reacting groups to the SO2 leaching agent. This results in nonselective extraction and less extraction of preferred metal values. At or below 0.149 mm, leaching by SO, is possible with all its attributes of selectivity, sensitivity, and rapidity. Leaching with HC1 solutions of the same pH level as dissolved SO2 yielded mixed, slow, and incomplete metal extractions. This observation rules out any interpretation based on hydrogen ion as the leaching agent. The leaching curves resemble the complexometric titration curves of heavy metals with specific coordination species.

Jan 1, 1981

By Gregory M. Molinda

Coalbed discontinuities historically have been hazardous to mining as well as obstructions to efficient production. An effective means of mapping these features is needed in order to plan safe and efficient mine development. This Bureau of Mines report discusses the use of surface seismic techniques for this purpose. At a southwestern Pennsylvania mine, a system of coalbed discontinu-ities (paleochannels) was accurately mapped by the Bureau of Mines using borehole log methods and underground observation. This site was chosen to test the value of a high-resolution surface seismic reflection on technique for coalbed mapping. A statistical study performed at this mine indicated that the probability of accurately delineating this paleochannel system with conventional borehole methods was remote. A total of 1.47 miles of high-resolution seismic survey, comprised of four seismic profiles, was conducted in known and suspected coalbed discontinuity areas. Several test holes were drilled on the seismic lines in order to evaluate the interpretations. It was found, based on these and other existing boreholes, that it is possible to predict these dis-continuities. Paleochannel washouts were correctly predicted in several instances but in other instances were either incorrectly predicted or not predicted in areas of known discontinuities.

Jan 1, 1988

By R Robinson

Modem occupational health practice can be described as the fitting of work to the individual and each individual to his job; perhaps a non-traditional way to view occupational health. This two-component description is achieved through the development of programs to implement and monitor specific job procedures, from the monitoring of unwanted exposures to contaminants to the auditing of mine sites. This paper is about such programs. Some attempt must be made to evaluate the effectiveness of the program and several performance indicators which are intended to measure the effectiveness of such a program are offered.

Jan 1, 1994

By H. Kenworthy

The purpose of the study described in this publication is to develop methods for recovering simple master alloys or single metal components from discarded and scrapped S-816 alloy, The Bureau of Mines started this investigation late in 1955 after the need became apparent for a method of reclaiming high-temperature alloys from an ever-increasing accumulation of rejected and wornout jet engine turbine buckets. Laboratory studies showed the following: (1) Pyrometallurgical separations are not selective enough, (2) several methods can be used for effective chemical dissolution of the major constituents of the alloy, (3) a master alloy or complex salts of cobalt and nickel can be separated, (4) chromium, contaminated by several other metals, may be segregated, and (5) more time and effort need to be expended in separating the minor constituents and improving the purity of the major metals removed. Difficult and incomplete chemical separations were attributed to the complexity of alloy composition, as were the long tedious chemical analyses o' products. For determination of several of the metallic components, standard methods of separation and routine analytical procedures had to be considerably modified to achieve satisfactory results. The overall technical problems involved in separating S-816 components do not appear to be insurmountable; however, refinement of several of the methods used in this investigation is desirable.

Jan 1, 1961

By James R. Boyle

The mining methods and practices used at the Young zinc mine, American Zinc Co. of Tennessee, have resulted in a low-cost, high-yield operation. Zinc ore (sphalerite) occurs in limestone-dolomite beds of the Kingsport Formation and is mined by modified room and pillar method. Utilizing trackless mining equipment which incorporates a high degree of flexibility, this operation has had a steady increase in productivity.

Jan 1, 1965

By R. I. Iacobescu, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, P. Knops

In this work, we explore a novel mineral processing approach using carbon dioxide to promote mineral alterations that lead to improved extractability of nickel from olivine ((Mg,Fe)2SiO4). The precept is that by altering the morphology and the mineralogy of the ore via mineral carbonation, the comminution requirements and the acid consumption during hydrometallurgical processing can be reduced. Furthermore, carbonation pre-treatment can lead to mineral liberation and concentration of metals in physically separable phases. In a first processing step, olivine is fully carbonated at high CO2 partial pressures (35 bar) and optimal temperature (200 °C) with the addition of pH buffering agents. This leads to a powdery product containing high carbonate content. The main products of the carbonation reaction include amorphous colloidal silica, chromium-rich metallic particles, and iron-substituted magnesite ((Mg1- x,Fex)CO3). Carbonated olivine was subsequently leached using an array of inorganic and organic acids to test their leaching efficiency. Compared to leaching from untreated olivine, the percentage of nickel extracted from carbonated olivine by acid leaching was significantly increased. It is anticipated that the mineral carbonation pre-treatment approach may also be applicable to other ultrabasic and lateritic ores.

Jan 1, 2014

By G. M. Ross, J. A. Scott, C. A. Laamanen, H. Shang

"Indirect recovery and use of waste heat contained in smelter off-gas is proposed to expand regions available for year-round, on-site production of micro-algae–sourced biodiesel, a fuel that could be used in underground machinery. A dynamic model of an off-gas heat exchanger describes capture and distribution of heat into open, external, rectangular micro-algae ponds. Smelter off-gas contains sufficient energy to maintain large-scale micro-algae cultivation pond temperatures above 15°C, even with winter ambient temperatures below –15°C. Results highlight opportunities that could lie in tapping these heat resources to produce renewable biofuels on-site and sequester CO2 while leaving the industrial process unaffected.RÉSUMÉ On propose la récupération et l’utilisation indirectes de la chaleur résiduelle contenue dans les dégagements gazeux des fonderies pour développer les régions se prêtant à une production toute l’année durant et sur place de biodiesel à partir de micro-algues, carburant dont on pourrait se servir pour le matériel d’exploitation souterraine. Un modèle dynamique d’échangeur de chaleur contenue dans les dégagements gazeux décrit le captage et la distribution de la chaleur dans des bassins rectangulaires ouverts de micro-algues en extérieur. Les dégagements gazeux des fonderies contiennent suffisamment d’énergie pour maintenir les températures des grands bassins de culture de micro-algues au-delà de 15°C, même avec des températures ambiantes en hiver inférieures à –15°C. Ces résultats soulignent les possibilités que pourrait offrir l’exploitation de ces sources de chaleur pour la production de biocarburants renouvelables sur place et pour la séquestration de CO2 sans que cela n’ait d’incidence sur le procédé industriel.INTRODUCTIONMicro-algae that grow in water can efficiently convertsolar energy and carbon dioxide into biomass. This biomass can be up to 50% oils (lipids), which can be extracted and converted into biodiesel through transesterification (Demirbas, 2008). Compared to terrestrial plants that produce similar oils (e.g., jatropha, soybean, and rapeseed), micro-algae represent an order of magnitude increase in areal productivity, do not require arable land, and can be continuously harvested (Rawat, Ranjith Kumar, Mutanda, & Bux, 2013). The potential advantages through the production of biodiesel from micro-algae also include sequestration of carbon dioxide, reduced reliance on fossil fuels, and the co-production of other value-added bioproducts."

Jan 1, 2017

By H. Fujihara, K. Uesugi, H. Toda, A. Takeuchi, K. Shimizu

"Hydrogen is trapped at a variety of microstructures, for example grain boundaries, dislocations and particles. It is thought that hydrogen trapped at trapping sites is redistributed to the other sites under loading and then brittle fracture occurs with hydrogen accumulation. In order to understand hydrogen embrittlement behavior, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, changes in hydrogen distribution are observed under stress using Kelvin force microscopy (KFM) that can visualize hydrogen concentration distribution on material surface at high resolution. Spot-like hydrogen enriched regions are observed on the surface of a material. In addition, hydrogen depleted regions are observed around those enriched regions, and the appearance of hydrogen trap due to particles existing near the material surface is revealed. On the other hand, hydrogen trapped at grain boundary can be visualized. From in this result, it was suggested that crystallographic factors influence hydrogen accumulation. The relationship between initiation and propagation of intergranular crack and hydrogen accumulation under stress will be discussed.INTRODUCTIONHydrogen present in a metal sometimes has significant effects on various properties. Hydrogen in a metal is trapped at a variety of microstructure, for example dislocations and grain boundaries. Grain boundaries, dislocations and micro pores are the major trap sites in aluminum alloys. Some researchers considered that hydrogen redistribution and accumulation between these trap sites in a material with loading plays an important role in the brittle fracture behavior. In general, in intergranular fracture and quasi-cleavage fracture, the hydrogen trapped at grain boundaries and dislocations contributes to fracture behavior, respectively. Recently some researchers have shown that the ductile fracture in aluminum alloys is resulted from growth and coalescence of hydrogen micro pores. Analysis using first principles calculation indicates that intergranular fracture occurs when hydrogen concentration reaches 20 atom H/nm2ongrain boundary. From this report, it is considered that hydrogen redistributed during deformation accumulates locally in order to cause hydrogen brittle fracture. In order to understand hydrogen embrittlement, it is necessary to investigate the time evolution behavior of hydrogen accumulation at each trap site. In the present study, we evaluate the relationship between hydrogen accumulation behavior and fracture behavior in Al-Zn-Mg based alloys. In-situ observation was made by combining the tensile test with Kelvin force microscope (KFM) that can visualize the hydrogen concentration distribution on the material surface with high resolution. We also investigate the relationship between hydrogen distribution behavior and crystal orientation."

Jan 1, 2018

By Y. H. Liu

Several foaming aluminum samples of different density were prepared in a semi?industrial scale experimental system, Their properties such as the energy absorption characteristics, mechanical properties, heat conductivity and acoustical properties were measured. The results showed that the foaming aluminum with a density of 0.5 to 0.6 g/em3J has the best energy absorption and this makes it suitable as the ensuring bar of the automobiles and also as a cushion material for the engine. The foaming aluminum with a density of 0.25 to 0.4 g/em3 has the best acoustical properties and heat conductivity resistance, which is suitable for the door filling material, the ceiling and the partition or the car engine.

Jan 1, 2003

By Lakshman D. Jayaweera

Today's rapidly developing and changing technologies and industrial products and practices frequently carry with them the increased generation of materials that, if improperly dealt with, can threaten both public health and the environment. Mercury is an element that poses great problems in the many forms in which it is to be found in the mineral processing industry. These forms are often contained in hazardous wastes and residues which may be unstable, and in which the contained mercury has value. This paper presents some of the stabilisation and recovery methods which are based on hydrometallurgical techniques and thermodynamic stability considerations.

Jan 1, 1994

By Arthur A. Center

HIGH GRADE zinc stocks were reported short early in 1943, but not Prime Western. Maximum production of High Grade was expected to be reached before the middle of the year, and demands of new brass mills were to take all of the increase. In February three premiums (A, B, C) of 2 3/4c. per lb. of zinc in ore were announced to encourage production from high-cost mines, the number of premiums being in proportion to estimates of ore-production costs.

Jan 1, 1944

By I. U. Onyenanu, C. E. Ilochonwu, E. I. Nwonye, C. O. Nwajagu

This work shows how pure silica was derived directly from rice husks ash (RHA) in different temperatures for reduction to Silicon (Si). The processes to form Si materials are usually complex, costly and energy-intensive. The silica in the ash undergoes structural transformations depending on the conditions of combustion. A high purity silica was produced at 650oC after burning the rice husk (RH) for up to 7 hours. The purity of the silica was determined by dissolving the RHA with alkali solution to form sodium silicate solution of pH 11.0. This was added to hydrochloric acid of pH 1.5 which lowered the pH of the solution to 4.0 to form silica gels. The silica gels produced were washed and dried to powder and then characterized using XRD and EDX techniques. This study was done to reduce energy waste and environmental pollution in Nigeria as silica is used to develop many materials.

Jan 1, 2015