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Much interesting data on cemented carbides has been published over a period of years which, when classified and pieced together, gives a clear picture of this special branch of powder metallurgy. This is an attempt to present the essential information in an ordered account.THE HARD CARBIDES-THEIR PROPERTIES AND PREPARATIONThe so-called hard or refractory carbides are the carbides of a number of metals which are grouped together in the Periodic Classification. These metals are in groups IV, V and VI. They are titanium, vanadium, chromium, zirconium, niobium (columbium), molybdenum, hafnium, tantalum and tungsten. These carbides have attracted the attention of chemists because of their remarkable properties. They possess very high melting points, and are rather difficult to prepare in the pure state. Their outstanding propertyis their extreme hardness, which they share with certain other carbides, such as those of silicon and boron. In addition, these compounds possess distinctly metallic properties, such as lustre (in fused specimens) and high thermal conductivities.(l)t They are capable of forming alloys in two ways:1. With metals, particularly those of the iron group. 2. With each other (a case of solid solubility).The constitution of these substances is not that of ordinary salts, which obey the usual valency rules, but must be likened to that of certain intermetallic compounds. Actually they are "interstitial" compounds(2), that is, they are formed from the ordinary metallic lattice by the insertion of the relatively small carbon atoms in the interstices.. The energy required to fill the lattice completely is high, and this explains the difficulty often found in obtaining the exact stoicheiometric compound. Thus the carbides can have a range of composition, and can be considered as solutions of carbon in the respective metals.Physical Properties of the CarbidesThe hardness of these compounds is so great that it is difficult to compare the individual compounds on this basis. Becker(l) gives values on Moh's scale, which are not very accurate and are of no great value. Burden(3) has reproduced a diagram by Hatfield which indicates that the cemented carbides are between 1,400 and 2,000 on the Vickers diamond scale. However, the pure carbides are harder, tungsten carbide being about 2,200. Hoyt(4) describes a method of measuring hardness applicable to powdered specimenswhereby the powder is rubbed on a standard block of cemented tungsten carbide under standard conditions, and the rate of wear is determined. In...

Jan 1, 1942

By Andrzej Tejchman

Calculation of pile foundations should possibly truly reflect its real work, mainly with respect to the value and distribution of settlements, pile internal forces and bending moments within a slab. Many empirical and theoretical methods serving for an assessment of the settlements of pile group overestimate its actual values obtained from field measurements (see Tejchman et al., 2001). In the paper a simple engineering method for calculation of pile foundations is presented. The method takes into account the interaction between the slab and a soil together with the phenomenon of non-uniform deformation of the soil-pile subsoil, particularly under large foundations. In the method the scheme of the slab resting on one-parameter elastic subsoil is assumed. The comparison of the calculation results for existing pile foundation with the field measurements shows good agreement between those values.

Jan 1, 2002

By Gerry Houlahan

The east span of the 3.5 km long SF-Oakland Bay Bridge is supported by different types of foundations along its span. Starting from the west, its first 460 m section comprising twin concrete box-girders is supported by sands and rock on Yerba Buena Island. A 620 m long steel suspension span then bridges a 25 m deep channel that is formed in sediments overlying rock. Twin concrete box girder structures, each 2.4 km long, complete the stretch over the remainder of San Francisco Bay to the engineered earth fill landing at its east end. For most of its length, the Skyway bridges water 3 to 10 m deep over soft surficial Young Bay Mud. The foundation types include spread footings with hold-downs, steel and concrete piles that are set in drilled rock sockets up to 3 m in diameter and 2.5 m diameter steel tubular piles driven to penetrations of up to 100 m. The design and construction-related considerations are presented. The different foundation types, influences of the site geology and earthquake demands on the substructures are discussed. The seismic motions of the bridge superstructures and substructures, as well as the depth-varying soil motions, influenced the foundation design. Together with performance-based design criteria, including post-earthquake footing displacement limits, these seismic demands influenced various aspects of the foundation design, including the use of battered and vertical piles.

Jan 1, 2005

By L. Cornish, P. A. Olubambi, J. H. Potgieter

Four 22%Cr series duplex stainless steels alloys containing varying nickel contents of approximately 5, 7, 9 and 13% were melted in a vacuum induction furnace, hot rolled, solution annealed and water quenched. Their corrosion behaviour was investigated in sulphuric acid and sodium chloride solutions using a potentiodynamic polarization technique. Increasing nickel contents have appreciable influence on their corrosion behaviour. Polarization curves show similarities in the uniform corrosion behaviour of the alloys in the solutions and a significant difference in their pitting behaviour in chloride environments. Alloy 2209 generally exhibited highest resistance to uniform corrosion while 2213 displayed distinct and best pitting corrosion resistance. Their corrosion behaviour were attributed to the influence of nickel on phase modification, microstructural refinement, and the probably types of films formed in different environments. Keywords: Duplex stainless steel; Nickel; Microstructure; Phase modification; Corrosion

Jan 1, 2006

By Charles H. Minott, Michael J. Markow, Robert D. Wyatt, Fred Moavenzadeh

The substantial investment in tunnels anticipated in the next twenty years has focused new attention on the economics of tunnel construction itself and on some costly problems associated with underground work: the uncertain geologic conditions, the performance and adaptability of men and equipment, and the need for quicker, more efficient excavation methods. There also exists a need to develop better ways of estimating tunnel construction. Inaccuracies in current bid estimates stem from a number of causes, among them (1) the effects of geologic conditions, which are not adequately known prior to construction, (2) the dependence of actual cost on the construction method used and on the interactions among the operations occurring underground, and (3) the reliability of tunneling equipment. Inability to estimate final costs for conventional tunneling more accurately has in turn caused difficulty in gauging the costs and benefits attributable to new tunneling technologies either under development or for which R&D programs are planned. ATTRIBUTES OF THE TUNNEL COST MODEL This paper presents a computer based Tunnel Cost Model (TCM) which quantitatively assesses the uncertainties inherent in underground work, and is detailed enough to aid in preparing estimates or bids. The model employs appropriate techniques of subjective (or "degree of belief") probability and computer simulation of tunnel construction operations to estimate distributions of total tunnel

Jan 1, 1974

By Steve Kral

It seems that mining has been in the doldrums for awhile. Except for gold, metals prices remain depressed. And economic conditions in the United States and around the globe have put governments in a financial bind. This affects new building and infra-structure repairs, which, in turn, have a major impact the building materials industry. Add to that the severe environmental and regulatory restrictions placed on the mining industry in developing new mines and expanding existing ones. It’s enough to make a mining engineer/geologist/metallurgist go sell real estate. So why do those employed in the mining industry stay in the business and remain optimistic? Many of them will say that they have been through down cycles before and know that an upswing is in the offing. They also know that society will always need the commodities they produce. And they love the challenge. The challenge in mining’s case is producing commodities as cheaply as possible, in an environmentally sound manner and improving the quality of life in the communities where they work.

Jan 1, 2003

By G A. Challis, A B. Christiel

Microprobe analyses of electrum grains in some Hauraki Au-Ag deposits indicate that gold fineness is in the range of 500 - 800 (50 - 80 per cent Au), but for most deposits the range is usually narrower than this. The electrums contain minor amounts (<0.8 per cent) of copper, arsenic, antimony, mercury, iron, and sulphur. Platinum and palladium were analysed for but were not detected (detection limit 0.24 per cent for Pt or Pd). For some deposits (eg Waihi), the average fineness values for the analysed electrums correspond fairly well with the electrum fineness determined by assay during the historic mining operations.

Jan 1, 1992

By K. Viking

This article deals with some of the civil engineering related problems to be encountered when offshore wind energy projects transform from prototype offshore wind energy converter farms, developed and installed during the 1990's, to commercial farms that's currently planned to be built. The offshore wind energy converter (OWEC) installations encounter a wide range of problems, only partial of these are geotechnical. In Europe both onshore and offshore wind farms have, from a historical point of view, usually been founded by using the monopole technique, installed with traditional impact hammers, or by using gravitational foundations. However, the rapid development of bigger turbines and larger wind farms, together with increasing considerations of fatigue aspects, has lead to financial benefits of developing and exploring other foundation techniques. This paper reviews some Scandinavian experiences regarding critical components of the design phase in relation to connecting the superstructure to the ground, and some of the main considerations of how the loads applied to the structure are transferred to the surrounding soil. Keywords: Offshore Wind Turbines, Wind Farms, Foundation, Pile, Gravity Structures

Jan 1, 2005

By James J. Brady, Joginder S. Bhore, Robert B. Gordon, Jimmy W. Honeycutt

The authors of this paper have a combined construction experience of 70 years. They have served as engineers and managers on projects throughout the United States and Canada. Approximately 50 shafts have been sunk under their direct and daily participation. Several shafts have been selected from each of their experiences and have been briefly summarized here. SHALLOW SHAFT SINKING Sinking shallow shafts in highly urbanized areas adds an additional set of problems to those encountered in normal sinking operations. During the time between July, 1975 and early 1981, a series of shafts were sunk for The Washington Metropolitan Transit Authority. All of these were located along the "A" line, starting soon after the route departed from its path along Connecticut Avenue, proceeding to Wisconsin Avenue and then along Wisconsin Avenue to the city line at Western Avenue. (See WMATA System Map, Figure 1) The first three shafts were subcontracted from Morrison-Knudsen & Associates, Contract A9a, in July, 1975. They were: Albemarle Street - 27'6" diameter, 78'O" deep Brandywine Street - 30'6" diameter, 88.6' deep Ellicott Street - 33'0" diameter, 110'0" deep

Jan 1, 1985

By H. F. Yancey, E. Zane

"INTRODUCTION The term ""friability"" as applied to coal may be defined as the physical property of coal which expresses its tendency to become reduced in size during handling as a result of such external forces as impact and attrition. Thus friability is a quantitative concept and property, and hence can only be defined in relative terms or in terms of measurement. Methods of measurement are difficult to formulate and apply because coal is anything but homogeneous in physical structure and chemical constitution. aMoreover, friability itself is a composite property obviously dependent upon a group of other specific characteristics such as cleavage, fracture, tenacity, hardness, and elasticity, which vary from coal to coal with change in rank and even between individual coals of the same rank. These characteristics affect the friability values of different coals to varying degrees, but this fact does not impair the usefulness of and the need for friability measurements.The amount of breakage or degradation in size that a coal suffers in mining, preparation, and subsequent handling depends upon its inherent friability and the severity of the handling treatment which it receives from the time it is taken from the bed until it reaches the consumer. The value of the coal to the producer and jobber depends in large measure upon these same factors--friability and severity of treatment—because the larger sizes still command a premium in the ordinary market. Although much has been accomplished by the coal-producing industry in minimizing the breakage of coal in mining and preparation, it is apparent that additional reductions in breakage must await further improvements in design of coal-handling equipment. Such improvements will result from more intensive investigations of the extent of breakage or degradation in size occasioned by specific mining and handling operations and the development and application of standardized methods of evaluating friability.The work described in this report was undertaken to assist in the development of standard methods for evaluating the friability of coal. Specifically, the work deals with a Comparison of the various methods previously proposed for estimating the friability of coal and coal products. This same objective is now being sought at a number of other institutions, both in the United States and Canada, by a committee of the American Society for Testing Materials. It is believed that by providing additional information concerning a property of coal pertinent to its increased usefulness, the work described will supplement and increase the useful of the data which long have been, and still are being, furnished by the bureau of Mines on the composition of coals of the United States."

Jun 1, 1933

The first of this three part series examines he history and some of the properties and characteristics of explosives. Use of explosives is discussed for underground and surface coal operations—the largest consumers in the mining industry. Part two of the series will deal with explosives use in surface and underground hardrock operations. Part three will discuss explosives transportation, storage, handling, and destruction.

Jan 7, 1981

By D. Xie, S. Sun

An overview of recent development of CSIRO?s Multi-Phase reaction models will be presented with examples comparing the calculated physico-chemical properties of metallurgical slags with the existing experimental data. The paper will also outline the development of a kinetically based model for molten bath reactors and its application to submerged combustion of coal in a slag bath as well as the reaction between the slag and injected coal particles. The plume model combines established models for the combustion of pulverized fuel with models for the growth and rise of bubbles from a lance or tuyere. This model predicts the extent of de-volatilization and combustion of the coal in the plume, the utilization of oxygen and the exchange rate of oxygen between the gas and the bath as well as the heat transfer rate between the gas bubbles and the bath. The slag reduction model brings together the recently measured rate data and fundamental understanding of the kinetics of CO-CO2reaction with iron oxide containing slags and predicts the changes resulting from injection of coal particles into molten slags. The top-space model covers reactions between gases and molten droplets in the post-combustion zone, where heat and mass transfer between phases results in higher utilization of the fuel values in the partly oxidized gases and transfer of heat to the molten bath. Keywords: Phase equilibria, viscosity, electrical conductivity, slags, kinetics, reaction rate.

Jan 1, 2004

By Anthony D. Barley

Over 60,000 multiple anchors have been used internationally since their introduction in the early 1990s, including 1000 in the United States. The multiple anchor system comprises a "multiple" of "unit" anchors installed within a single borehole - each unit anchor being staggered within the borehole length to mobilize its own capacity independently of the other unit anchors. These systems offer higher capacity than conventional anchors with identical bond lengths due to superior load transfer efficiency. The use of higher capacity anchors may allow reduction in the number of anchors required on a project, which results in time and cost benefits to the anchor installer, contractor, and the owner. Fully removable temporary multiple anchors are available, and have been used with consistent success. Three case histories are discussed highlighting the use of these systems

Jan 1, 2002

A commonplace, sometimes overlooked or taken for granted, article of everyday existence is the tin can. Produced from thin gauge low carbon steel, and commonly coated with a mere 60 millionths of an inch of pure tin, the product is however strong and corrosion resistant. Tin-plate serves a myriad of purposes-the most important being to meet the requirements of the canning industry. Australia's newest steel product, tin-plate, was first produced on a commercial scale during the early part of August, 1957. The commissioning of the Hot Dip Tinning Plant (Fig. 1) of The Broken Hill Proprietary Co. Ltd. at Port Kembla, marked the culmination of a proposal dating back to 1939, the advent of World War II having caused its deferment to the present time.Cornish tin is known to have been exported as early as 300 B.C. to Syria and tinned vessels existed even in the year A.D. 23. The tin coating of plate could be described as an ancient art, believed to have had its origin in Bohemia in the thirteenth century. During the next 450 years, the process spread through Saxony to Pontypool in Monmouthshire, but it was a further half century before any measure of success was obtained.Perhaps the two greatest milestones in tin-plate manufacture were the rolling of iron plates first carried out in 1728, thereby outmoding the hammer formed sheet, and more recently, the development of the electro-deposition process. By the nineteenth century, several important changes had arisen; namely, the substitution of steam for water power, coke for charcoal in the production of the base metal, and...

Jan 1, 1958

By J. G. Eacott

This paper reviews the role of oxygen potential and the advances that have been made in the application of tonnage oxygen in copper smelting. Brief reference is made to reaction kinetics before attention is turned to the thermodynamic considerations in copper melting to illustrate the importance of oxygen and. oxygen potential in the component parts of the overall smelting process. The chemical potential diagram for the Cu-Fe-S-O-Si02 system is used to elucidate the difference b etween the conventional matte smelting process and the modern continuous processes. A progressive oxidation scale' is constructed to show the common elements which exist, and the matte grades produced, during the smelting of concentrates to blister copper in commercially available copper smelting processes and those under development. The common route in producing blister copper from molten mattes, regardless of process, is illustrated on the Cu-Fe-S equilibrium phase diagram. The essential features of oxygen enrichment, in terms of its effect on combustion conditions (i.e. oxidation of fuel and sulphide minerals) and the heat balance are outlined. The benefits of oxygen enrichment are listed. The influence of tonnage oxygen and its effect on productivity, fuel savings, gas volume and strength in various copper melting processes are examined as a state-of-the-art review. Reference is made to the economics of tonnage oxygen utilization.

Jan 1, 1983

An optical computing system was used to determine spacings and frequencies in geological fabrics and engineering joint fabrics.Three-dimensional arrays of joints were plotted on an equal-area net. Directions in which true spacings are seen were determined from these plots. Photographs taken along these directions were used for optical computing.

Jan 1, 1970

By Robin P. Gardner

The mechanistic approach to comminution consisting of incorporating particulate breakage functions into a suitable population balance equation has been developed by a number of researchers over the past decade or so. (1) To date this approach has been developed and demonstrated primarily for batch-operated, laboratory or small-scale ball mills. However, since industrial mills are mostly quite large and operated in the continuous mode; suitable population balance models and methods for obtaining the necessary breakage and other model parameters must be developed. This paper describes and investigates a radioisotope tracer technique for this purpose, Population balance models previously developed(2,3) are adapted for this study.

Jan 1, 1974

By Barton J. Suchomel

Introduction Despite perennial economic turbulence, Argentina continues to push ahead with efforts to develop its fledgling hardrock mining industry. The country lacks the infrastructure and mining history of neighboring Chile, but contains vast areas of great resource potential. The eastern slope of the Andean Cordillera in west-northwest Argentina is a relatively little-explored region offering geology highly conducive to the occurrence of base and precious metals deposits. Past exploration has concentrated on locating and evaluating porphyry copper-molybdenum (Cu-Mo) type occurrences. Comparatively little attention has been given to precious metals potential. An interesting and important group of base and precious metals prospects in northwestern Argentina occurs within and adjacent to the Upper Miocene Farallon Negro volcanic complex in Catamarca province. The volcanic complex contains numerous base and precious metals vein occurrences, high gold porphyry copper prospects, and possible disseminated gold targets that have attracted relatively minor attention in the past. Various geologic aspects of the region have been reported by several workers (Llambias, 1970, 1972; Caelles et al, 1971; and Sillitoe, 1973). Regional geology The Farallon Negro volcanic complex is located within the Sierras Pampeanas morphostructural province about 200 km (125 miles) east of the main Andean Cordillera (Fig. 1). The Sierras Pampeanas is characterized by north-south-trending basin and range topography that developed during the Miocene and Pliocene. Uplifted blocks are composed mainly of lower Paleozoic metasediments and granitoid plutonic rocks unconformably overlain by Tertiary redbeds and minor carbonates. A consistent landward migration of volcanic and intrusive ac¬tivity occurred in this region of the Andes from the early Mesozoic through the mid-Tertiary. An eastward extension of magmatism during the Miocene and Pliocene resulted in the formation of the Farallon Negro volcanic center. Volcanism at Farallon Negro ini-

Jan 8, 1988

By Virgil A. Marple

The primary purpose of this contract was to evaluate methods and techniques by which the size distribution acid concentration of mining-related dusts can be measured. One result has been the development of a portable, battery-operated optical particle counter/ multi-channel analyzer system which can he used to determine the size distribution and concentration of mining aerosols. One important aspect of this program has been the development of a calibration technique which relates the output of the optical particle counter to the penetration of the particles through an impactor: This results in a calibration curve in terms of the aerodynamic or Stokes' diameter or the aerosol particles. Using this technique, calibrations were performed on coal, silica, Arizona road dust, potash, and rock dust (corer ore) aerosols. Another task of this program was the calibration and evaluation of the GCA respirible dust monitors (RMD) 101-1 and 301. The results of evaluation showed that the instruments were within the manufacturer's specification of ±25% of the true mass concentration up to about 15 mg/m , if the dust particles were in a size range from about 0.7 to 10 µm aerodynamic diameter. Particles smaller tan about 0.7 µm were not collected by the instrument and particles larger than about 10 µm were lose in the inlet. Other tasks included performing field studies in cooperative research programs with the Bureau of Mines personnel, development of a portable polystyrene latex generator for use in optical particle counter calibrations in the field. The incorporation of impactor classification devices on the inlets of aerosol mass measuring instruments to give mass size distributions, and a study of the density of coal particles as a function of the particle size.

Jan 1, 1977

By B. Samanta

This paper investigates the performance of the neural network technique in a placer deposit situated at the Nome district in Alaska. Initially a single neural network model was constructed to estimate the gold grade. However, at a later stage, an ensemble model consisting of multiple networks was also constructed via the Adaboost algorithm. The reason behind the use of the ensemble model of the Adaboost algorithm was to examine if the ensemble model provided superior performance to the single neural network. As indicated by other studies, Adaboost did not have a better performance than a single neural network in this specific application. This may be due to the high noise inherent in the gold data used in this project. Consequently R2 values of gold prediction are also poor for both the single and multiple networks.

Jan 1, 2005