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By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

An evaluation was made of the wear and performance characteristics of liter bars, and the cost-life effectiveness of backing materials for rotary-mil liners. In a large run-of-mine mil in which the liter bars were mounted on grid liners of austenitic manganese steel (AMS), the liners had an average life that was five to six times that of equivalent unprotected liners. For a single mil, this is equivalent to annual savings in the cost of materials of up to R320 000, and to a downtime of 100 hours. Of the five materials tested in a large pebble mil grinding quartzitic ore, AMS grids and 'white iron' blocks performed best on a cost-life basis, with possibly improved performance from a real white cast iron. (The 'white iron' was shown by microstructural analysis to contain flake raphite and pearlite, being in reality a grey cast iron.) The high-chromium white iron had by far the longest predicted life, with mild steel a surprising second. Rubber was shown to last well in this type of mil. The wear rates of liners change during their lifetimes. The protective effect of liter bars was clearly illustrated by the reduction of over 40 per cent in the wear rates of the liners when the lifter bars were renewed to a height of 80 mm from a fully worn height of 35 mm.

Jan 1, 1991

By Yong Hack Lee

Electric Arc Furnace (EAF) dust is generated when scraps are treated in the electric arc furnace and usually classified as hazardous industrial waste in most countries. EAF dust usually contains 15 to 25% of zinc and 3% of lead. It is usually treated in rotary kiln (Waelz process) or landfilled after a solidification and stabilization treatment. Numerous methods have been proposed as the EAF dust treatment technology, but few of them are in operation as a commercial scale except the Waelz process. Korea Zinc performed a plant test in which 600 tons of EAF dust was treated using TSL (Top Submerged Lance) technology. The TSL technology is a low cost, proven technology for processing zinc-bearing residues. The EAF dust was first de-chlorinated and fed to the TSL furnace. Finally, clean slag satisfying toxicity criteria was generated and valuable metals such as zinc and lead were recovered as fume oxide. The fume oxide was de-halogenated by sodium carbonate and sent to zinc refinery to recover zinc and lead. The recovery of zinc and lead was 90% and 93%, respectively. Most of the dioxin in the EAF dust was discomposed so dioxin less than the Korean regulation limit was detected in the offgas, which proves that the TSL technology is the best solution to treat EAF dust.

Jan 1, 2006

By Ken J. Richards

Industries dependent on pyrometallurgical processing generally find themselves facing a common set of problems, namely, serious environmental restrictions, heavy capital requirements for new facilities and for plant modernization, the certainty of rapidly escalating fuel costs, and the uncertainty of fuel availability. To remain competitive, it has become clear to industry that a new dimension of attention must be given to assuring the maximum performance from plant facilities already in place and from those that are built in the future. In the last decade or so, in response to these needs, there has been an acceleration in the development of new pyrometallurgical process concepts. Their application, though spotty, is increasing. A common factor in this developing base of technology is the need for effective process control. Digital control is an indispensable element of meeting the challenge. We cannot make the point, however, by looking to a general survey of instrumental control of pyrometallurgical processes. Computer control is in its awkward adolescence. Its application is so new that only isolated applications can highlight the trends. For this reason, the authors have chosen to focus on the nonferrous smelting industry to illustrate the status of pyrometallurgical processing and control. We believe this approach will best meet the interests of most readers of this edition and the background of the authors.

Jan 1, 1979

By John A. Shuster

INTRODUCTION Controlled ground freezing for mining and construction applications has been in use for over a century. Despite the great technological evolution which has occurred during this period, ground freezing is still used on projects today with much the same basic technology as that used originally over 100 years ago. Major developments have occurred in the separate fields of frozen soil mechanics, refrigeration, and heat transfer analysis. However, except for a few projects in Europe and Asia, these developments have not been combined to upgrade ground freezing techniques to their potential level. In view of this situation, it is believed desirable to examine the art of ground freezing in light of recent technical developments, together with highlights on some of the apparent advantages, disadvantages and economics of the various alternative approaches. The purpose of this paper is to attempt such an examination, with particular emphasis on the practical application of presently available technology. GENERAL ADVANTAGES AND DISADVANTAGES Ground freezing may be used in any soil or rock formation, regardless of structure, grain size or permeability; however, it is best suited to soft ground rather than rock conditions. Freezing may be used for any size, shape or depth of excavation and the same physical plant can be used from job to job despite wide variation in these factors.

Jan 1, 1997

By David Scott

WHEN mining operations were first instituted in the mines of the Miami Copper Co., at Miami, Ariz., the relatively hard character of the ground in the western section of the property made it seem advisable to use a wide shrinkage stope and pillar system. The system as finally evolved was applied to the mining of 2,300,000 tons of ore by the use of stopes and pillars each 50 ft. in width. Development, mining and extraction of this reserve has been continuously in progress since 1910, and the final stages of extraction are now reached. A complete survey of all phases of this system can therefore be made. Modification in working methods was obviously necessary, and the system to be described is believed to be typical of the best features. DEVELOPMENT The preliminary work had three main objectives: The opening of a haulage level, the construction of a drawing-off level, and the driving of sublevels for use in stoping. In addition to these, some extra sublevel drifting was necessary to determine exactly the boundaries of the orebody, the general outline having been determined by churn drilling. This development was based on the requirements of stopes 50 ft. wide, with pillars 50 ft. wide between each stope. The length of these units varied from 200 to 500 ft.

Jan 6, 1916

By J. Partinen

Drying is a unit process which has numerous applications in metallurgical process industry. Kumera Technology Center, being a worldwide equipment and process supplier, has developed sophisticated solutions for both direct and indirect drying. In conventional direct drum drying, the energy is taken from combustion of fossil fuels, requiring energy input and emitting considerable amount of off gases. In modem copper smelters, thermal energy from the off gases is recovered in waste heat boilers making the steam available. Using that steam as the energy source for concentrate drying, the total volume of off gases can be considerably reduced and releasing of harmful combustion gases into the atmosphere can be avoided. Kumera Technology Center has recently developed and promotes a new steam drying process for drying of copper concentrates. In the development of the new dryer, Kumera's approach has been to combine the best properties of both the steam dryers and the drum dryers. In the design special attention has been paid to overcome problems of excessive wear and clogging and to reduce the required maintenance operations. In this paper the environmental issues and energy consumption related to both direct and indirect drying processes are discussed. The estimated operation costs and emission levels are compared, based on calculations and the data collected from industry. Finally, the development project of the Kumera Steam Dryer is briefly reviewed

Jan 1, 1999

By P. Bhakta

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment leaching procedure to increase the recovery of gold from arsenopyrite (FeAsS) ores. The best solution compositions for arsenopyrite dissolution were determined using cyclic voltammetry and chronocoulometry. Initial arsenopyrite dissolution occurred at -0.20 V versus standard hydrogen electrode (SHE) in a sodium hydroxide (Na0H) solution. Leaching of a high-grade arsenopyritic ore containing, in percent, 28.2 As, 25.3 Fe, 19.9 total S, and 1.0 Sb and, in troy ounces per short ton, 1.6 Au and 5.5 Ag resulted in >90 pct As extraction at 1000 C, 40 psig O2,4 h, and 2M NaOH solution in a 2-L autoclave. Cyanidation of the leach residues resulted in 90 to 93 pct Au and 60 to 80 pct Ag extractions, compared with only 5 and 15 pct, respectively, without the pretreatment. The procedure was further tested by leaching a low-grade gold ore and a bulk sulfide flotation concentrate prepared from it. Cyanidation of the leach residues resulted in 70 pct Au and 31 pct Ag extraction. The NaOH leachate was partially regenerated by precipitating the arsenate as calcium arsenate [Ca3As04)2] and the sulfate as barium sulfate (BaS04).

Jan 1, 1989

By Vidalinc, Raffoux

Longwall faces producing in the order of 20,000 tons per day of raw coal are presently running in the Houilleres du Bassin de Lorraine of Charbonnages de France. Production levels of twice that level pose some technical and economic problems of coal cutting, ventilation, coal and equipment transportation in the.face and from the face to the sur- face. The peak productions of the equipment in use today, the results of trials with new equipment, the utili- sation of forecasting models (some in the form of software), allow us to fo- resee feasable technical solutions to these problems. They will first be considered in the best possible context (thick- ness, dip, non gassy, soft coal, good strata, no faults). This will give. the necessary conditions to reach daily output'of that level. A sensitivity analysis of these- figures to the effective natural con- ditions will then be undertaken and the implication of such a project on health and safety (dust, climate ...) will be carefully considered. A concise technical and econo- mical approach will permit us to fore- cast the economical interferences of such production units and specially the consequences of sudden variations of the output (downtimes, failures, etc). From this investigation, goals for technological development and re- search areas will be outlined to be able to reach this production target in the XXIst century.

Jan 1, 1988

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services."

Jan 1, 2003

By Dairo E. Chaverra, Carlos Argumedo‑Jimenez, Oscar J. Restrepo‑Baena

This paper presents the results obtained by processing a gold and silver telluride mineral concentrate from a mine in Colombia. An acid wash, also known as acidification, was carried out, followed by oxidation with nitric acid as a pretreatment. Cyanidations of the pretreatment residues were carried out and the results were compared with results from cyanidations of base materials. The removal of carbonates in the acidification, a tellurium extraction close to 90% during the pretreatment, and a 30% improvement in the gold recovery compared to the conventional process were achieved.

Nov 8, 2023

By M. R. Lastra

Island Copper Mine began gold recovery Tom molybdenum sulfide concentrates in April, 1985. Plant design capacity is 20 tons of molybdenum concentrate per day. The molybdenum concentrate is produced in a conventional copper/molybdenum flotation circuit by selective copper depression. After thickening, the molybdenum concentrate is leached with cyanide solution in a series of five leaching tanks. The leached concentrate is then filtered and soluble gold values recovered on activated carbon with a six column adsorption circuit. The gold leach extraction is approximately 80 percent with a gold adsorption on activated carbon of 97 percent.

Jan 1, 1986

By Carl L. Morris

This short dissertation concerning "what the client expects from the engineer" is directed mainly at the design and construction of metallic ore concentration or beneficiation plants. However, practically the same conditions apply to the design and construction of cement and lime manufacturing facilities, with the exception that the latter facilities reflect the client's and engineer's concepts of customer service and in some cases reflect promotional considerations for the product manufactured and distributed. The client expects his engineering contractor to contribute in an efficient, cooperative, and economical manner current industry-wide know-how and experience to the specific project under consideration through the client's organization

Jan 1, 1969

By John C. Cook

This was a study to identify and evaluate known technologies employing electromagnetic resonance phenomena in solid minerals for their identification and assaying, particularly assay logging of exploratory boreholes. A comprehensive literature search and study revealed some little known NMR (nuclear magnetic resonance) techniques developed by Professor G. J. Béné's group at the University of Geneva, Switzerland. These are suitable for use in weak, inhomogeneous magnetic fields. Laboratory NMR tests of numerous U.S. ore minerals showed good identifying signals from phosphates, fluorspar, bauxite, oil shale, and spodumene (lithium) ores, but not from the copper, lead, antimony or manganese ores tested. Use of EPR "signatures" for such ores is suggested. A conceptual design for an NMR assay logging system is proposed.

Jan 1, 1978

By David A. Hart, Barry P. Osborn, Richard J. Totty, Ana T. Carvalho, Max B. Elliott

This paper addresses the experience designing and installing bored piles for the King’s Cross area. This includes continuous flight auger and rotary bored piles, with a range of diameters between 600 mm and 1200 mm, reaching a maximum depth of 56 m below ground level. Existing Network Rail Thameslink twin bored running tunnels are located directly beneath the subject plots. These tunnels have an external diameter of 6.6 m and the crowns of the tunnels are very shallow, in some cases just 10 m below the existing ground level. Some plots needed piles to be installed in close proximity to the tunnels, which required additional control measures and contingency plans. Pile verticality was monitored as the tip of each pile advanced and in-tunnel monitoring readings were verified and are presented. Lessons learned from designing, installing and testing the piles and monitoring the tunnels are addressed in this paper.

May 1, 2022

By M. M. Rajkovich, J. J. Zaluski, S. J. Gardner

The telephone rings at 3:20 a.m. and an exasperated voice on the other end says, “There’s been a mine explosion at Mine No. 5 and we have not heard from three units of men!” Twenty-three minutes later, the phone rings again and another panicked voice says, “There’s something wrong at the slurry impoundment, the pool level has just dropped five feet and we’re trying to figure out what’s wrong!” Thirty minutes later, the mobile phone rings and an excited security guard says, “We have reports of thick black water running down both the right fork and left fork of Straight Creek and both seem to be rising in the banks!” As if this isn’t enough excitement, the mobile phone rings again and a stressed company official says, “I just heard a report that black slurry is running out of the portals of XYZ Company No. 2 Mine, which is adjacent to our No. 5 Mine!” Is this all some kind of dream or nightmare? More importantly, however, if this could happen, what on earth do you do? Although we all like to think that “It can’t happen to me,” we all must admit that mine explosions do happen, slurry impoundments can rupture and creeks can flood with black water causing damage to others, including competitors. Your response must be quick, cool-headed, calculated and effective. This paper will examine the issues, concerns and ramifications of this hypothetical “disaster” and then present a systematic crisis management response. While each situation is different, there are general guidelines for forming an effective plan of action.

Jan 1, 2003

By John H. Soulé

"INTRODUCTION Spodumene and lepidolite were shipped from the Harding pegmatite deposit, Taos County, N. Mex., in the period from 1930 to 1930. Tantalum minerals were noted as early as 1924 and described in 1931 3/ but no tantalum ore was shipped until 1942. The deposit was mapped and studied by geologists of the Federal Geological Survey and engineers of the Bureau of Mines late in 1942 and early in 1943, and a Bureau of Minus exploratory project was carried out in 1943. 4/ Thu following report presents the results of that project.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Minos has as its primary objective the more effective utilization of our mineral resources to the end that they make the greates possible contribution to national security and economy. It i the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lovell B. Moor, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallugiical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, Assistant Director."

Dec 1, 1946

By A. K. Kelly

Potash was first discovered in Saskatchewan in 1943 but its continuous extraction did not begin until 1962. In the years since then, potash has played an important role in the economic and political life of the province. And, as is well-known, the most eventful time in the life of the industry occurred in 1975 when the Government of Saskatchewan decided to become a major participant in potash production. To understand that decision, however, requires an understanding of the economic development of Saskatchewan and of relations between the industry and the government prior to 1975. This year, Saskatchewan celebrates its 75th year as a province. For most of those years, we have been an agrarian economy and society, dependent on exports of cereal grains, mostly wheat, for a livelihood. Even today, agriculture accounts for about 25% of the province's Gross Domestic Product (Economic Review, 1979, p. 7) and difficulties in agriculture spread rapidly to the rest of the provincial economy. The difficulties and risks that go hand in hand with being a "one crop" economy were known as long ago as 1920 but were not fully appreciated until the combination of depression and drought in the 1930's turned the prairie grain- belt into a dustbowl. Some idea of the severity of the depression is revealed by the following data: in 1928, Saskatchewan produced 321 million bushels of wheat. By 1931, the total fell to 132 million bushels and, in 1937, to a mere 37 million bushels. The value of agricultural products sold off farms fell from $273,000,000 in 1928 to a meagre $51,000,000 in 1937. The impact of such a fall of agricultural incomes was catastrophic since about 70% of the population of some 921,000 persons lived in rural, agriculture-dependent areas (Britnel.1, 1939, p. 14).

Jan 1, 1980

By A Riles

"Three issues of relevance in a modern tailings storage facility (TSF) are:geotechnical stabilitymanaging acid rock drainage (ARD) from pyritic tailingsmanaging the tailings from cyanidation of gold ores. Drawing on examples from both copper porphyry flotation and sulfide-hosted gold ores, this paper demonstrates that giving some weight and importance to the process tails properties upfront can influence the flow sheet and not only improve tailings management effectiveness but also impact positively on economics. In the case of a typical copper porphyry ore with moderate pyrite content, the rougher tail in a conventional high pH selective flotation step is usually classified as potentially acid generating (PAG). To avoid the generation of ARD within the tailings and the requirement for a costly plastic lining, subaqueous deposition is recommended, which in turn has negative implications for tailings stability, consolidation and closure. Adopting a neutral pH rougher stage rejects silicate gangue but recovers pyritic material to the cleaners for a subsequent selective flotation stage, often after regrinding. This effectively quarantines the PAG pyritic material in a much lower volume cleaner tail, which can then be appropriately encapsulated within a larger non-lined flotation tails facility. It also facilitates cyanide leaching of the cleaner tail for gold recovery, with the encapsulated tailings facility being suitable for cyanidation tails storage. A case study from Europe is examined. For gold ores where the gold is sulfide-hosted, but not refractory, a flotation route with cyanidation of the concentrate can similarly produce the majority of tailings as a benign flotation tail and again quarantine the low volume concentrate leach tail in a small encapsulated cell with appropriate residual cyanide management measures applied. Overall economics for intensive leaching of a low volume concentrate stream can also be surprisingly positive. A feasibility study design example of the process and TSF is presented. CITATION: Riles, A, 2016. An Integrated Approach to Optimising All Concentrator Products, Including Tailings, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 341–346 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By Gopalakrishna M. Rao

"Several industrial and government laboratories are of the opinion that solar--cell technology will grow into a billion-dollar industry by the year 2000, especially if oil prices rise again. Of the variety of materials that have been investigated as the major component of photovoltaic systems, silicon appears to have an outstanding advantage. The cost factor is the primary importance in photovoltaic development, since the technology to make silicon cells of acceptable efficiency and life time has existed since the early stage of the space program. Electrometallurgy is one of the low--cost processes for the production of silicon, since it allows direct, single-stage production from some abundant, inexpensive source materials such as silica and fluorosilicates. Among several systems, two are given particular attention, using inorganic baths with Si0 2 or K2SiF6 as the source of silicon respectively. They appear capable of development to commercial production. Conceptual designs of a commercial--scale cell for silicon production at temperatures above its melting point, and of a pilot' plant for plating silicon from an all-fluoride bath are presented. Energy ProspectsThe major changes in the world energy since the first energy crisis in 1970 have impacted on our community. When oil was $40 a barrel in the mid-1970s, we became obsessed with the energy conservation and a search for alternate energies. Even though the crude oil fell below $15 a barrel during the last several years, our energy security fears continue to haunt us. This time it is not the scarcity, but the abundance of foreign oil and the decline in the domestic production.The prospects of energy depends on the demand and supply of energy. These, in turn, depend on future energy prices, which are linked to economic factors, political events, and unforeseen circumstances. Although no one can predict the future with certainty, three energy consumption patterns used by the Ford Foundation are as shown in Fig. 1."

Jan 1, 1988