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By Zhang Hanbo, Niu Liping, Zhang Zhiqi, He Jicheng, Dou Zhihe

"Rutile, ilmenite and Al-Ca complex reducer were used to prepare high titanium ferrous alloy by enhanced reduction-SHS method. The effects of the complex reducer compositions and slag types on the enhanced reduction-SHS process were investigated. The high titanium ferrous alloys were characterized by XRD and SEM. The results indicate that the high titanium ferrous alloys consist mainly of TiFe2, AlTi3 and Al2O3. The oxide inclusions exist resulting in directly the high oxygen content and micro-structural defects in the alloys. The titanium and oxygen contents decrease, but the aluminum content in the alloy increases while the mass ratio of calcium in the Al-Ca complex reducers increases. When the mass ratio of Al/Ca in the Al-Ca complex reducer is 6:1, titanium, oxygen and aluminum contents are 63.75%, 3.01% and 10.72% respectively. When the mass ratio of Al/Ca is 5:1 titanium content is 55.00% nearly and aluminum content is higher than 14.00%, but oxygen content is lower than 2.0%.1. IntroductionThe high titanium ferroalloys with 65%~75% titanium have the advantages of low melting point and high titanium content. They are widely used in special steel refining, while they are also a kind of very important quality orientation alloys in the rage of aviation and aerospace. At present, the methods of preparing high titanium ferroalloy include vacuum remelting and thermit reduction. The alloys prepared by the vacuum remelting method have good qualities and low oxygen content, so it is widely used in Russia, Western Europe and other developed countries. In China, there are abundant rutile resources, but waste titanium is lack, therefore, the preparation method is the thermit reduction. But there are many quality defects in the high ferrotitanium alloy, including high oxygen content, unstable quality and so on. In order to improve the qualities of the high titanium ferroalloy, especially to reduce oxygen content, the domestic and overseas have done a lot of further researches. For example, Sichuan E-mei ferroalloy plant and Beijing Nonferrous Metal Research Institute have prepared high titanium ferrous with 73.77% titanium with natural rutile, but the oxygen content is high. Through controlling the quality of raw material, they obtained the better qualities, but the oxygen content is still very high. South Africa Mintek company have prepared high titanium ferrous alloy with low nitrate by plasma heating under the isolation air conditions, but they couldn’t also remove effectively oxygen in the alloy. The oxygen exists in the form of Al2O3 and titanium protoxide. So it can be speculated that except TiO2 not being fully reduced, the no-sufficient alloy-slag separation is the direct reason resulting in high oxygen and poor microstructure. In view of present technical difficulties during preparing high titanium ferroalloy by thermit reduction, this paper proposed a new method of preparing high titanium ferrous with low oxygen by enhanced reduction-SHS with Al-Ca complex reducer. Ca in Al-Ca complex reducer has stronger reductive ability, it can effectively strengthen the reductive degree of TiO2. The slagging agent CaO CaF2 and MgO can effectively reduce the viscosity of Al2O3 slag to improve its liquidities to strengthen alloy-slag separation effects so that to remove inclusions and oxygen. In this paper, effects of slagging agent type on the reduction and the qualities of high-titanium ferroalloy were studied."

Jan 1, 2012

By Stanley Kesler

The first of two initial 650-mw units of the Paradise Steam Station, located on the banks of the Green River in the south-central portion of the western Kentucky coal basin, is scheduled for operation in late fall of 1962. Location of the site is shown on the map of figure 1. This plant will be the eighth, large-capacity,, modern station built by TVA in a series starting with Johnsonville, operated first in 1951. During that period of 10 years,, unit sizes have increased from a capability of 125 mw to 500 mw at the recently completed Widows Creek Unit 7 addition and at Paradise to 650 mw. This new unit will take its place in a power system that serves an area of some 80,000; square miles with a present installed capacity of over 12,000 mw. Upon completion of the Paradise units and other additional hydro and steam units presently under construction, the system capacity will have reached over 15,000 mw. Projected load estimates indicate that this system will provide a margin' of slightly under 10 percent of dependable capacity above peak demand at that tire. One Paradise 650-mw unit at that time will represent approximately 4 percent of the total system installed capacity.

Jan 1, 1962

By Charles L. Parsons, R. B. Moore, S. C. Lind, O. C. SCHAEFER

Early in 1912, from information received by the Bureau of Mines, it became evident that quantities of valuable radium-bearing ore from Colorado were being exported for manufacture in foreign coun- trics and that at least part of the manufactured product was being returned to this country and sold at a price entirely incommensurate with that received by the miner and the prospector. Consequently, in line with its efforts to increase efficiency in the mining and treat- ment of mineral resources, the Bureau of Mines undertook an inves- tigation of conditions. Results of this preliminary investigation were published, in the summer of 1913, as Bulletin 70, which gave an out- line of the radium deposits of the West, the conditions of mining, the wastes involved, and the status of the production of radium from its ores. At about this time newspapers and medical journals were publish- ing statements regarding the value of radium in cancer therapy. These reports, although many of them were exaggerated, brought out clearly the remarkable virtue of the gamma rays for the treat- ment of cancer and other malignant growths. In view of the fact that the largest known supplies of radium ore in the world are in the States of Colorado and Utah and on the public lands of the United States, it was deemed highly important for the Bureau of Mines to study the production of radium in detail. Such study, it was hoped, would enable the prospector and miner to obtain a fairer price for the ores and would furnish information necessary in case Congress appropriated funds to develop methods for extracting radium from ore on the public lands under Government supervision, to be supplied at cost to the hospitals of the Army, Navy, and Public Health Service.

Jan 1, 1915

By D. T. Hahn

Adequate and cost effective erosion control is an important component in most plans for reclamation of surface mined land. Despite the fact that much is known about erosion of agricultural lands, insufficient conclusive knowledge is available about erosion of reclaimed surface mined land. Our study was conducted to characterize the erodibility of reclaimed surface mine land relative to unmined cropped land, and to evaluate the accuracy of the universal soil loss equation (USLE) in estimating erosion from reclaimed soils. A rainfall simulator was used to measure runoff and erosion rates from plots at three Indiana surface mines. The relation of erosion of the reclaimed soils was not completely constant with that from the cropped soils. Significant differences in erodibility were observed between reclaimed and nonreclaimed top soils, as well as reclaimed topsoils and reclaimed subsoils.

Jan 1, 2011

By H. J. Conolly

The area around Osisko lake, the Horne mine, and the town of Rouyn, in northwestern Quebec, presents a most interesting structural problem. The present discussion is confined to an area around Osisko lake, about six miles long and three miles wide, shown in Figure 1. The writers are particularly indebted to Mr. Thayer Lindsley, of Ventures Limited, who sponsored the investigation and gave permission to publish this paper. Mr. H. L. Roscoe and Mr. Oliver Hall, of Noranda Mines, Limited, gave every possible assistance; and the Noranda geologists, Mr. H. M. Butterfield, Dr. Peter Priee, and Dr. G. G. Suffel, contributed many data and ideas. It is a pleasure to acknowledge also the fuidance of Dr. W. F. James and Dr. B. S. Buffam and the full use made o their maps and criticism. Dr. M. E. Wilson and Dr. A. Lang, of the Geological Survey of Canada, kindly furnished data on the geology in neighbouring fields. Mr. E. Bailey assisted ably in the field, and Mr. H. F. King kindly reviewed the text. Memoir 166 of the Geological Survey of Canada, The Geology and Ore Deposits of the Roztyn-Harricanaw Region, Quebec, by Cooke, James, and Mawdsley, proved an invaluable source of information. STRATIGRAPHY The following stratigraphie sequence is based in part upon the interpretation of the structure as outlined in this paper:

Jan 1, 1936

By I. R. Miller

The purpose of this discussion is to try to offer some suggestions as to how the zinc and lead markets will perform over the balance of the decade, review some of the factors influencing production and come to some conclusions regarding prices. The past 2 years have been simply awful in terms of consumption, prices and overall profitability for the industry. In looking ahead to the year 2,000, it is probably not a bad idea to look back about 20 years to see where we have been and how we got to where we are. Zinc consumption from 1950 to the early 1970's increased steadily and rather nicely at an annual average rate of close to 4.0%. It was starting in the early 1970's that things started to get volatile and at times, difficult for the industry. The general economic boom of the early 70's was marked by annual consumption rates close to 5.0 million tons, a level not seen again for over 10 years. The First Oil shock of 1973-74 was followed by the sharpest consumption drop in memory. In two years, Western World zinc consumption fell 27%. While our chart shows a rather dramatic recovery thereafter, the average annual growth rate since 1970 has only been a rather modest 1.5%.

Jan 1, 1992

By Dion Weatherley, Raúl Castro, Pablo Cid, René Gómez

In underground mining, hang-ups due to coarse fragmentation are frequently observed in drawpoints, drawbells, and ore passes during ore draw. Hang-ups can often require operational interference and hang-up removal activities. Drawpoint and drawbell design has been shown in some studies to influence hang-ups; however, the full extent of this influence remains open to question. In this study, the discrete element method was used to analyze the effect of hang-ups on three distinct drawbell geometries: the Drawer type, Circular type, and El Teniente type. The drawer type was used as the base case given that data was available from a physical model in which hang-ups were studied. The drawer type base case data was then used to calibrate our numerical model. Results show that the El Teniente drawbell geometry sustained 13% more hang-up events as compared with the base case, while the circular drawbell geometry had 16% fewer hang-up events than the base case. From this study, it can be concluded that fewer hang-up events will occur with a rounded drawbell geometry.

Apr 11, 2023

By Simon N. Lekakh, D. G. C. Robertson

A new integrated CFD-combined reactors approach is proposed for the description of processes in metallurgical vessels. CFD simulations were used to obtain the melt flow pattern in the vessels (ladle, tundish, and continuous caster mold). From these simulations, the characteristic curves were derived: (i) the residence time distribution curves (RTD) for flow-through systems (at tundish exit or at dendrite coherency surface in the mold) and (ii) the mixing curves for closed systems (ladle). In the next step, the melt flow was represented in a “combined reactors” system consisting of a combination of unit reactors (Plug Flow, Mixer, and Recirculated Volume). An inverse simulation was used to define the volumes of the reactor units and the melt flow rates between them by fitting to the characteristic curves from both methods (CFD and combined reactors). The suggested approach is demonstrated for multiple designs of Ar-stirred ladles, tundish, and SEN. This methodology can be used to enhance traditional post-processing CFD analysis and also as a tool for on-line process control.

Jan 1, 2014

By Cheryl S. Lim

New technologies such as direct reduction and smelting reduction processes are increasingly being used in iron-making and steel-making in addition to conventional blast furnace technology. Critical parameters for control of these processes include the degree of metallization, degree of pre-reduction, and carbon and silica levels. On-line monitoring of these parameters is difficult because measurements often need to be made on hot ores (at or higher than -1000'C) in circumstances where representative sample streams are not readily accessible. A nuclear analyser has been developed which provides continuous, non¬intrusive, real-time measurements of iron, oxygen, carbon and silicon levels in hot ores undergoing reduction. The analyser has been tested in a plant using a direct smelting process on pre-reduced feed to the smelting vessel-, accuracies of 1% relative, 0.5 w'.96 (25% relative) and 1.0 wt.% (9% relative) were obtained for the degree of pre-reduction, carbon and silica respectively. The underlying method, capabilities and potential applications of the analyser will be discussed.

Jan 1, 2001

By S. J. Gerdemann

The U.S. Bureau of Mines is studying the kinetics of wet oxidation of sphalerite concen- trate (ZnS) as a possible process for a gravity-pressurized reactor (GPR). At tempera- tures in excess of 200' C, a sphalerite water slurry will react with 0, to form zinc sul- fate (ZnSO,). However, the pressure required to keep the water from boiling at these temperatures has kept this reaction from becoming a viable continuous process. The GPR can easily obtain the high pressures required for this reaction. The reaction rate is complicated by the solubility of 0, in water and the further oxidation of ZnSO, to insoluble zinc oxysulfate (Zn4(OH),S04.4H20). The effects of pressure, temperature, and particle size on the rate of reaction were investigated. Reaction rate was found to be limited by the amount of oxygen in solution. However, at 250" C and 1500 psia, over 90 pct of the zinc was solubilized in less than an hour. The conditions for maxi- mizing the Zn++ in solution, while minimizing oxysulfate formation, are discussed.

Jan 1, 1993

By J. H. Maysilles

The Bureau of Mines is conducting research on various technologies to recover alumina from domestic resources for feedstock to existing aluminum smelting capacity as a means to reduce dependence on imported bauxite, which represents 93 pct of U.S. aluminum requirements. One of the more promising technologies being investigated is the hydrochloric acid leaching of kaolinitic clay. In the hydrochloric acid leaching technology, alumina is recovered from iron-free aluminum chloride leach liquor and separated from impurity elements by sparging the liquor with HC1 gas to crystallize aluminum chloride hexahydrate (ACH). A large-scale crystallizer with a 336-gallon usable volume was constructed and operated to obtain engineering and design data for potential scale up and to demonstrate the ability of the technology to produce specification grade alumina. Test campaigns involving about 1,400 hours of operation were completed. ACH meeting all chemical purity requirements could not be produced by a single crystallization, but was produced by recrystallizing the product from the calcined kaolin clay leach liquor. Product crystals with a size distribution of more than 80 pct plus 100 mesh and 65 pct plus 65 mesh were made at a rate of 10 pounds of ACH/(hr)(ft3). The zirconium tube heat exchanger used to maintain constant process temperature operated with an over-all heat transfer coefficient of 420 to 500 BTU/(hr)(ft2)(°F).

Jan 1, 1981

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By Paulo Masiero

Sintered titanium carbide has been extensively used since the early 1980s for demanding wear-resistant applications and, in particular, in environments characterized by high temperature and oxidation. Thanks to its physical characteristics, especially its low density, titanium carbide (TiC) has been successfully applied in the manufacture of cassette guide rollers for hot steel rolling. However, the peculiar characteristics of the sintered Ti carbides make it difficult their redressing and hence this has always represented the limit for a more extensive application. Very often iron based alloys are preferred even if, in general, they are less cost effective just because they are easier to be redressed by turning. The availability of a simple, compact, fully automatic and reasonably priced CNC machine; specialized in the grinding of guide rollers and able to operate accurately and efficiently -both in contour and in plunge- can definitively solve TiC’s redressing problems and render its use even more widespread and attractive.

Oct 30, 2017

By K. K. Kelley

The first bulletin (245)3 in this series, which appeared in 1932, summarized the entropy values then available for the elements and inorganic compounds, results being listed for some 150 substances. In the interim advances in the realms of spectroscopy applicable to the determination of thermodynamic properties and in the development of methods of calculation therefrom have added many highly accurate values. Moreover, through the efforts of Prof. W. M. Latimer (286) and his coworkers, satisfactory entropy values are now available for all but a few of the common inorganic ions in aqueous solution. At the same time rapid progress has continued in the study of low-temperature heat capacities in several laboratories, In addition, compilation and correlation of data pertaining to vapor pressures (247), thermodynamic properties of carbonates (258), thermodynamic properties of sulfur and its inorganic compounds (250), and the thermodynamic properties of metal carbides and nitrides (251), which were published as members of this series, have yielded many values. As a result, over 500 usable entropy values for inorganic substances may now be tabulated. This bulletin originally was planned as a second revision of the first member of this series, the first revision (249) having appeared in 1936; however, because of requests for the explanatory section of the first bulletin from those teaching thermodynamics, it was decided to com¬bine the information in the first bulletin and its revision with the data that have appeared since 1935 and to repeat the explanatory material in somewhat more detail. The purpose of this bulletin is therefore to give the available values of the entropies at 298.1° K. of the elements and inorganic compounds, together with enough explanation of the methods employed in calculating entropies to make the results comprehensible.

Jan 1, 1941

The status of utilization of copper ore resources, and the application and development of biohydrometallury technology in the world is reviewed. Based on the characterization of Zambia?s copper resources, biohydrometallurgy technology is shown to be a practical approach to extract and utilize the enormous low grade copper resource, such as ore tailings and low grade copper ore in this country. Through the cooperation of CSU, China and MMMD, Zambia, ?CNMC-CSU Demonstration Base of Biohydrometallurgy Technology in Zambia? was launched and several biohydrometallurgy plants are being constructed. This indicates that the biohdyrometallurgy technology would be applied soon in Zambia and in the whole Africa. Biohydrometallurgy technology stands as an efficient alternative to the traditional pyrometallurgy process and it can be the key to unlock mineral resources value. Keywords: biohydrometallurgy, low grade copper ore, Zambia, Central South University

Sep 1, 2012

Although few people know of it, Woodlark Island produced a relatively large quantity of gold in a short period at the turn of the century. Deaths of miners, enticement to richer fields elsewhere, and world wars have contributed to the abandonment of these gold fields to their present obscurity. In the mining boom, companies were formed, amalgamated and bought-out in a flurry of activity but present records are incomplete. The main sources of information are annual reports of the Department of Land Surveys and Mines in Papua, a few geologists' publications (notably Pinder,1901; Stanley, 1912, 1923; Trail,1967) and a variety of unpublished data. The first traces of gold in New Guinea were'found by Saavedra in 1528. The first gold in Papua was found near Port Moresby in 1878. The next discovery was at Sudest Island in 1888 followed by Misima Island in 1889 and Woodlark Island in 1894. By 1910 the "Murua Goldfield" (Woodlark Island) had contributed over 43% of the total gold yield of the Territory of Papua.

Jan 1, 1987

By Francisco A. Fonseca

The Carajás Hills are in Brazil's Eastern Amazon, between the Araguaia and Xingu rivers, and parallels 5° and 7° Latitude South. A location map is given in Fig. 1. It is an area of low mountains (maximum altitude 900 meters), covered by the Amazon rain forest. Annual average temperature is 25°C, ranging from 31°C (maximum) to 19°C (minimum). Annual rainfall averages 2,000mm. Although it rains throughout the whole year, heavy rains occur from December through March. At the beginning of the 20's, Brazilian explorationists made brief geological descriptions of the area. Due to the thick soil, scarce fresh rock outcrops and the tropical forest covering a completely unpopulated area, detailed geological studies were difficult and reconnaissance expeditions were limited to the river margins.

Jan 1, 1982

By Daniel Rodríguez Hoyle

El presente texto señala una breve reseña histórica sobre el cobre, producción, exportación, consumo, reservas y su expansión mundial en el Perú durante los últimos cinco años.

Jan 1, 1968

By Luis A. Mejia

El presente texto evalúa la utilización del Método de Elementos Discretos (DEM) en el estudio de la propagación y coalescencia de fracturas en taludes de gran altura, asi como el entendimiento del mecanismo de ruptura tipo Step-Path en macizos rocosos fracturados. La metodología se realiza en dos etapas: la primera comprende el estudio de los procesos de propagación y coalescencia de fracturas en muestras pequeñas y la segunda, señala la extrapolación para el modelamiento de macizos rocosos fracturados. La ventaja que ofrece dicho método estriba en la comprensión de este mecanismo de ruptura, que puede ser mejorado, conforme se optimize la determinación de los micro-parámetros de las partículas y de las fracturas modeladas.

Sep 12, 2011

By R. H. Thurston

Jan 1, 1879