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By J. Singh

Recently, a Maryland bank became the overnight owner of a toxic waste site through a foreclosure. The original property owners had operated a crash and garbage business on the site and obtained loans for their business venture through the bank. In 1980, their son purchased the property from his parents with mortgage monies obtained from the bank. Failing to make his loan payments, the son defaulted on the mortgage. The bank foreclosed on the property and eventually purchased the property at a foreclosure sale. Shortly after the bank's purchase of the site, toxic wastes were found on the property--the result of disposing solid wastes on the site for 10 years. The bank declined responsibility for contaminating the site and consequently for its cleanup. The Environmental Protection Agency (EPA) took corrective actions to clean up the site. EPA then handed the bill to the bank, citing the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) of 1980 (more commonly known as "Superfund"). CERCLA imposes liability on the current owners and operators of hazardous waste sites.

Jan 1, 1988

By R. H. Nafziger

A novel process has been developed for preparing directly workable steel ingots from prereduced iron ore pellets by a two-stage process. The pellets are continuously charged into an electric arc furnace, where molten metal is separated from the gangue. The molten metal flows out of this furnace through a hollow nonconsumable graphite electrode immersed in a molten flux in an electroslag furnace. The molten metal solidifies on a continuously withdrawing base plate to form the ingot. A variety of standard carbon and alloy steel ingots . free of porosity , were produced using suitable decarburizers and ferroalloy additions. Some advantages of the two-stage process include: (a) consumable electrode fabrication is eliminated; (b ) no expensive deoxidizers are required; (c ) the uncontaminated electros lap flux can be reused; (d) energy consumption averages 25% less than in a conventional electric arc - electroslag operation ; and (e) the operation is continuous.

Jan 1, 1977

By Peter Zhang, Daniel Su, Bo Hyun Kim

Shale gas wells drilled in longwall chain pillars are influenced by longwall mining. Longwall mining on each side of the chain pillars can create overburden movements and induce deformations in gas well casings. If the deformations result in a casing breach, intrusive shale gas could leak into the longwall mine with serious safety consequences. This study concerns five shale gas wells in the chain pillars between two adjacent longwall panels in the Pittsburgh coal seam under a cover depth of 670 ft and a mining height of 7 ft. The gas wells were constructed with typical casing design, but a casing cementing alternative with uncemented production casings was practiced. Four production casings were uncemented, and one production casing was unintentionally cemented with good quality cement to a 535-ft depth and low-quality cement stringers from a 444- to 535-ft depth. The longwall faces passed by the shale gas wells as each adjacent longwall panel retreated. Production casings were surveyed by a multi-finger caliper after each panel was mined. No deformation was detected in the four uncemented production casings, but small deformations were detected in the partially cemented production casing. The maximum measured deformation in the cemented production casing was 0.05 in. after first panel mining and 0.06 in. after second panel mining. The casing deformations were also predicted by the FLAC3D model set up on site-specific overburden geology. The predicted deformations were in good agreement with the measurements in terms of deformation locations and magnitudes. All five shale gas wells resumed normal production after being temporarily plugged during the period of mine-by. This study provides a successful demonstration of the effectiveness of a casing cementing alternative for decoupling production and intermediate casing, and thus minimizing the influence of longwall mining in the shale gas wells drilled through longwall chain pillars.

Jul 1, 2023

By Ch. -A. Gandin, M. Rappaz

"The grain selection mechanism which occurs during the growth of columnar dendritic structures is routinely used in the investment casting industry to produce directionally solidified (DS) and single crystal turbine blades. However, the evolution of the grain density with increasing distance from the chill has rarely been correlated with the evolution of the grain texture. This contribution presents a three-dimensional (3-D) stochastic modeling approach which permits the computation of grain maps, pole figures and grain density evolutions in DS superalloys. These predictions are compared with measurements resulting from an automatic indexing technique of Electron Back-Scattered diffraction Patterns. This 3-D stochastic model, which applies to uniform temperature situations, has to be extended to the dendritic growth in a thermal gradient. As a preliminary step, a 2-D Cellular Automaton (CA) has been coupled recently to Finite Element (FE) heat flow computations in order to predict the grain structures in complex shape investment cast part. The application of this CAFE model to the investment casting of a turbine blade is presented. Considering these results, the extension of the CAFE algorithm to three dimensions is discussed.INTRODUCTIONThe selection of columnar grains during the directional solidification of alloys plays a key role during the investment casting of directionally solidified (DS) and single crystal (SC) components for aerospace applications [I]. This selection mechanism, leading to a competition of the dendritic network propagation at grain boundaries, has been the subject of many investigations. In particular, the study of Walton and Chalmers [2] is remarkable since it provides a link between the evolutions of the density and of the texture of columnar grains with increasing distance from the mold wall. Since this original work of Walton and Chalmers, two new tools have become available, which enable one to revisit the problem of grain selection in much greater depth. The first one is a fully automatic indexing technique of Electron Back-Scattered diffraction Patterns (EBSPs) [3-6] which directly gives the crystallographic orientation of the solid at any location of the specimen. Pole figures, orientation distributions, misorientations between grains can be visualized very easily with this technique. This information can be directly compared with the results of a second tool: a three-dimensional (3-D) stochastic model (SM) describing the nucleation and growth of grains in a uniform temperature field [6-9]. In order to extend this model to non-uniform temperature situations, a preliminary 2-D model has been developed [10]. It is based on a Cellular Automaton (CA) algorithm coupled with Finite Element (FE) heat flow computations. Since the details of both the automatic indexing technique of EBSPs and the simulation tools have already been published [3-10], only a brief summary is given here."

Jan 1, 1994

By D. A. Horne, V. R. Daiga

Certain steel mill wastes contain significant amounts of zinc oxide due to the use of galvanized scrap during the steel making process. Typically electric arc furnace (EAF), and basic oxygen process (BOP) flue dusts contain 20 to 30% zinc oxide and 40 to 50% iron oxides, along with smaller quantities of lead and cadmium. These materials can be recovered from the flue dusts by using a proven rotary hearth furnace (RHF) process. By-products of the recycling operation include a crude zinc oxide fume, which is captured in a baghouse filtering system, and sponge iron that may be recycled into the steel making operation. Crude zinc oxide properties plus the operating experience from two commercial RHF installations utilizing MR&E's DRyIron™ Process will be presented.

Jan 1, 2000

By T. I. Urbancic, C-I. Trifu

"ABSTRACTSeveral case studies are presented on the use of seismic techniques to map active structures, evaluate changes in stress levels, and identify the conditions leading to large magnitude seismic events and the generation of rock-bursts in Canadian mines. The results suggest that microseismicity can be used to identify the orientation of active fractures; define regions of relatively high and low stress, and those most likely to host a rockburst; determine the role of local stress on observed shear failures; and identify the path of stress transfer associated with the remote triggering of rockbursts. Additionally, the conditions leading to rock-bursts can be characterized by a significant increase in the clustering of microseismic events along the fault plane orientation of an impending event, and an increase in the effective stress levels. It is concluded that the analysis of microseismicity provides the means for remotely monitoring rock mass behaviour as a result of mining."

Jan 1, 1997

By Barun Gorain, Aparup Chattopadhyay

"Many double refractory gold deposits are characterized by the dominance of ""invisible gold"" (sub-microscopic gold) as solid solution or as colloidal-sized particles in different sulfides and other phases. These deposits are mainly composed of silicates and carbonates with moderate clay and mica content and with minor amount of sulfides and organic carbonaceous matters. The presence of highly preg-robbing and finely disseminated carbonaceous matter adversely affects gold recovery in leach circuits. Characterization of carbonaceous matters, commonly known as TCM and quantification of gold associated within these carbonaceous matters along with different sulfide and oxide phases is highly complex and challenging. Studies were initiated on various complex ore deposits and also on samples representing various process streams. This paper presents the development of a systematic approach to gold deportment studies using state-of-the-art mineralogy characterization techniques for quantification of invisible and visible metal contents in various species. The relevance of this mineralogy characterization to metallurgy will also be discussed in this paper."

Jan 1, 2014

By P. K. Rozakeas

It has been experimentally demonstrated that the application of electrokinetic techniques in the continuous flow of coal-water suspensions within a helical anode-cathode pipe geometry effectively causes a significant reduction in the wall shear stress. This reduction in the frictional force at the cathodic pipe wall surface is attributed to a decrease in the concentration of coal particles in this flow region caused by the migration of negatively charged coal particles towards the anodic surface(s). The disadvantage of flow-intrusive geometries is the reduction in effective flow area as well as an increase in frictional surface area caused by the placement of the anode(s) within the flow region. Experimental data is presented for a non-intrusive helical anode-cathode geometry embedded in the pipe wall which shows that a reduction in pumping energy of approximately an order of magnitude is possible. A sample of sub-bituminous black coal fines having a mean particle size of approximately 17 microns was used to prepare coal-water suspensions with a solids concentration of 50%(w/w). The practical and economic implications of this work relate to an enhanced method of long distance transportation of slurries in pipes as well as an alternative technique for continuously separating solid-liquid suspensions.

Jan 1, 2014

By A. W. Bryson, K. C. Lenthall

"With the growth in the use of cobalt in industry, interest in its extraction and recovery has increased. With this increased interest comes the need for a fundamental knowledge of the processes involved in the recovery of cobalt metal. This paper examines the effects of cobalt concentration, catholyte pH, operating temperature and current density on cobalt electrowinning with respect to the current efficiency, cell potential and nature of the cobalt deposit. It is found that the cobalt concentration and catholyte pH affect the current efficiency, while current density and temperature affect the cell potential and thus the specific power consumption. Pitting on the deposit is affected by the catholyte pH and the operating temperature. Furthermore, the effect of feed flow-rate on catholyte pH, and thus current efficiency, is investigated. A model to predict the cell performance, which includes the flux of hydrogen ions through the diaphragm, is proposed.IntroductionCobalt metal is a silvery transitional metal found between nickel and iron on the periodic table. Due to its resistance to corrosion and other properties under high temperatures and its good work-hardening characteristics, it is favoured in alloys used in high temperature applications. These include aerospace, aircraft and high speed tools. Other applications include its use as a colourant in glass and ceramics, a drying agent in paints, a nutrient for livestock, a catalyst in the petroleum industry and, in the medical field, in prosthetics and radiology.The main deposits of cobalt are found in Central Africa, specifically Zaire and Zambia, although deposits also occur in Morocco, Canada and Australia. The cobalt is generally associated with other transitional metals including nickel, iron and copper. It is generally extracted by hydrometallurgical means and recovered from solution by electrowinning or hydrogen reduction. Little data [1-2] exists in literature on the electrowinning of cobalt from aqueous solutions. This paper investigates the effects of various operating conditions on the current efficiency, cell potential and deposit nature under continuous operation."

Jan 1, 1997

Laboratory tests were conducted in a full-scale continuous miner test gallery to evaluate resulting dust levels for changes in face airflow, spray water quantity and pressure, and mining height. The minimum and maximum values tested for each parameter were as follows: airflows between 1.42 and 6.14 m3/sec, water flows between 56.8 and 132.5 lpm, nozzles pressures between 413 and 1379 kPa, and mining heights between 1.52 and 2.74 m. Each of these parameters were evaluated for four common spray system designs. Respirable dust samples were collected in the operator's cab on the miner and in the immediate return. Second-order polynomial models were used to represent expected dust levels and multiple stepwise regression was used to identify significant control parameters for inclusion in the models. Separate models were developed for dust levels at the operator and return locations and for each individual spray system. Interaction between control parameters and curvature effects were found in most models. The analysis indicated that at the operator location, airflow and mining height had the most significant impact on respirable dust levels. In the return, airflow and water pressure were typically the most significant parameters. The models developed for each spray system design can be used by mine operators to guide application of control parameters for a variety of operating conditions and mining heights.

Jan 1, 1994

By B Belle

"Mines around the world are inherently and operationally diverse. Current methodologies for the design of mine ventilation and cooling infrastructure involve controlling major safety and health hazards. Globally, it can be estimated that mine ventilation systems from various commoditiescirculate over 150 000 m3/s of exhaust air through shafts. Additionally, over 2 000 000 workersare transported every day through shafts in labour-intensive mining countries like China, India,Southern Africa, and the Americas. A key objective of this paper is to share experiences and provide a case for the revision of ætime-honouredÆ ventilation design parameters based on a benchmarking exercise on design exhaust shaft velocity from various global operations (gold, diamond, platinum, coal and base metals). An active fi eld observation on exhaust shaft velocity has indicated that, regardless of the commodity or continent where the mine operates, almost all life-of-mine (LOM) design parameters provided are in the same range of 20 m/s to 22 m/s, which is not convincing considering signifi cant variations exist in shaft depths, geography, commodity, operating and capital costs. From a due diligence perspective, there are no documented views that are available on the most widely used design exhaust air velocity. Based on the global exhaust shaft velocity data, it is noted that a significant portion of shaft velocities are outside the current design velocity of 20 m/s (some operating up to 30 m/s) and other signifi cant portions of the exhaust shafts operate in the critical velocity range. In the case of Australian coal mines, limited data suggests that none of the mines have ever reached the LOM design exhaust shaft velocity. It is self-evident that when the shafts are not operating at their design quantities either the mine system resistance is low or the ventilation and main fan is operating ineffi ciently. The most common reasons given for not reviewing the shaft system were, ætime-honouredÆ design parameter are being used and cannot be changed, mine fan pressure limits, possible fan blade damage, possible spontaneous combustion risks, leakage or simply did not consider such a possibility. In conclusion, the study has reiterated the historic lessons that a safe and expensive airway should not be utilised uneconomically by circulating too litt le air through it."

Jun 1, 2012

By Jack C. White

The purpose of this Bureau of Mines research was to determine the technical feasibility of direct sulfuric acid digestion of Florida land-pebble phosphate matrix. Preliminary tests in a continuous digestion circuit showed that 92 to 96 percent of the P2O5 contained in the matrix was extracted, while the P.05 concentration in the product acid ranged from 21 to 30 percent. The waste filter cake contained about 1 percent P205 and up to 18 percent water. These sandy compact filter cakes, comprised mostly of quartz and gypsum, appeared to be suitable for backfilling and reclamation of mined lands.

Jan 1, 1975

By M Spiteri, S Woth, J Caratti, K Henley

Blasting is an essentially violent process aimed to disrupt and loosen rock for productive excavation and downstream processing. Dilution of the orebody to some extent is the inevitable result, particularly in narrow vein gold mines. A small change in gold recovery is usually a strong lever on revenue generation. As a result blast designs are carefully engineered to both minimise and control the direction of rock movement. Traditionally blast designs in gold mines have used the minimum powder factor that will still permit rock excavation. This now conflicts with the recent industry trend to optimise the total process flowsheet from the mine to the mill. Numerous mines have achieved success in reducing total mining cost by increasing powder factors. Not only is explosive energy cheaper than mechanical comminution energy requirements, the increased blasting effect may deliver benefits across all downstream processes of digging, hauling, crushing and milling. Kalgoorlie Consolidated Gold Mines (KCGM) Fimiston operation is the largest gold mine in Australia, located in the heart of the Kalgoorlie Goldfields. Blast dilution has been reduced at KCGM by managing location of blast boundaries and by firing along strike to choked faces. Significant economies of scale have resulted from application of a bulk mining methods. The bench height of 10 m is the largest in the Western Australian Goldfields, and is typically mined in a single pass with large face shovels. Recent increases in production rates in both the mine and mill has been partly attributed to a 30 per cent increase in powder factor. KCGM then examined the benefit of a further 18 per cent increase in powder factor to 1.0 kg/BCM. A concern though was the impact of very high powder factors resulting in excessive blast movement and subsequently ore dilution. This was the subject of a project conducted with Orica Explosives. OricaÆsDMC(Distinct Motion Code) blast model was applied to understand the effect of not just further increases in powder factor but also blast geometry and explosive type. The modeling work demonstrated that high powder factors may be applied with minimal increase in ore dilution provided the combination of blast geometry and explosive type is optimised. These results are currently being implemented to achieve further reductions in total mining costs without a significant impact on recovery.

Jan 1, 2001

By L. Yuan, J. Soles, W. Tang, R. Thomas

Lithium-ion battery pack fires pose great hazards to the safety and health of miners. A detailed experimental study has been conducted at the National Institute for Occupational Safety and Health (NIOSH) Pittsburgh Mining Research Division (PMRD) to investigate the effectiveness of different fire suppression systems on Li-ion battery pack fire extinguishment. Tests were conducted in a well-ventilated container. Two sizes of battery packs (12V, 24V) were heated by heater strips to trigger thermal runaway and fire. Water mist with different flow rates, ABC powder, type D dry chemical, and water mist with F500 additives were used as the fire suppression agents. Multiple thermocouples were installed on the battery packs to measure the temperature evolution during the tests. The results indicated that the water mist with F500 additives is the most effective suppressant among the agents tested. Dry chemicals, however, do quench the fire for a moment, but cannot prevent re-ignition of the battery since they do not provide enough cooling. The findings of this paper can be used to develop safer battery fire suppression techniques in mining environments.

Feb 1, 2023

By S. K. M. Chao

The increasing demand for large volumes of relatively low-cost cement has resulted in the need for an equally low-cost high-volume means for transporting that cement. It has been estimated that 20% - 25% of the total cost of cement to the buyer represents delivery expenses from the mills. For instance, during the 1972 cement shortage in the Southeastern region of the U. S., bid prices for a ton of cement delivered increased to $45 compared to $20 average at mill price, i. e. , F. O. B. plant. Much of the increase was caused by the anticipated higher cement shipping costs for longer hauling distance. The exceptionally high bid price, of course, was not the price quoted by the successful bidder. Thus, clearly, cement is not a marketable commodity unless it can be economically transported to the consumer.

Jan 1, 1975

By Huang Kai

Uniform needle-like and spherical nickel oxalate particles were prepared by the chelating precipitation process, which was based on the reaction of oxalate acid and the solution of ammonia nickel chloride. The molar ratio of ammonia to nickel ion in the mixed solution is essential to determine whether the spherical or needle-like particles are formed, which means actually the concentration of ammonia is the key to determine the growth mechanism. When oxalate acid is added in the form of solid, it may act as the nucleation interface for the eariy-precipitated substance and so induce the formation of spherical particles. The PVP agent can improve the dispersing degree of the needle-like particles and higher reacting temperature leads to larger particles. The composition of the needle-like particle consists of ammonium and nickel oxalate instead of the pure nickel oxalate.

Jan 1, 2003

By V. Castranova, K. Van Dyke

"I. INTRODUCTIONA mechanism which is present in leukocytes and capable of releasing histamine from rabbit platelets was first described by Barbaro and Zvaitler in I966. A soluble mediator between rabbit leukocytes and platelets was also detected by Siraganian and Osier in 1971. This factor was isolated and characterized in 1971 by Benveniste et al. and named platelet activating factor i PAF). It was shown to be released from rabbit basophils through an antigen - IgE-dependent mechanism. The presence of PAF in human leukocytes' and its aggregation and releasing effects on human platelets were also demonstrated. Chemical analysis has shown that PAF is a glycerophospholipid with a choline polar head group. an ester-linked acyl chain at the second carbon and a nonester link at the first carbon.' The structure of the mediator was found to be 1-O-alky1-2-acetyl-sn-glyceryl-3-phosphoryl choline and it has been chemically synthesized.""' A variable portion exists in the alkyl group attached to the first carbon which can have a variety of molecular sizes such as C and C (where Cu is more abundant). Recent work by Pinckard et al."" has shown that there are at least five variations of the alkyl group.PAF has been shown to have a broad range of biological effects. Release of PAF from alveolar macrophages may be important in asthma, allergy, and shock states. In a rabbit model of antigen IgE anaphylaxsis. PAF can induce all of the effects of antigen challenge and. therefore is presumed to be a key mediator in production of anaphylaxsis. In addition to aggregating and degranulating platelets it is a potent chemoattractant."" and causes contraction of guinea pig ileum contraction of lung tissue and enhanced capillary permeability PAF has important effects in the kidney and is also known as the renal hypotensive factor proposed by Blank et al. who found the structure of PAF independently of Benveniste et al.' In producing these responses. PAF acts by a receptor-like mechanism. In platelets. PAF selectively desensitizes itself but not thrombin or collagen. In smooth muscle tissues a similar phenomenon occurs with anaphylatoxin or other stimuli.In vivo. PAF probably acts in concert with other agents in producing its various biological effects. It causes platelets to release histamine serotonin and RCS (rabbit-contractile substance formed from prostaglandins PPG2, PGH2 and TXA2) which contracts rabbit aorta. PAF can cause cells to release SRS-A and leukotriene B."

Jan 1, 1989

By J. -F. Blais, M. -O. Simonnot, J. Mocellin, G. Mercier, J. -L. Morel

Large quantities of ferromanganese sludge are generated as waste material by blast furnace during the manufacturing of ferromanganese. These slags are very rich in manganese, zinc and lead (5 to 40 %). These residues have been deposited in a pond in periphery of the steel industry. Considering the market value of the metals, these brownfield sites can now be considered as secondary resources. We have developed a hydrometallurgical process for selectively leaching Zn, Mn and Pb in order to produce compounds of Mn and Zn pure enough to be economically recoverable and a residue rich in Pb. Batch laboratory experiments were carried out to determine appropriate leaching conditions to maximize zinc extraction (100 %) and manganese extraction (90.0 %) with sulfuric acid and to generate a residue containing 15 to 30% of lead. This Pb residue is recyclable by another process.

Jan 1, 2015

By See G. T

Bentonites and fuller's earths from seven localities in N.S.W. have been analysed with respect to occurrence, mineralogy and physical properties and areas for future prospecting have been indicated.INTRODUCTIONThe rapid expansion of Australian industry in the postwar years has been accompanied by an ever increasing demand for fuller's earth and bentonite, but in New South Wales at least the demand has been met principally by imports. However, some local and generally inferior active earths have been won to blend with imported materials to reduce costs. The important discovery of the widespread distribution of bentonite clays in the Northern Coal Measures, made recently by Grim (Booker, 1956), has givenimpetus to the further search for material comparable in quality to the imported active earths.Bentonite may be defined as a highly plastic clay, generally possessing swelling properties, composed essentially of montmorillonite and derived from the alteration of volcanic ash. Fuller's earth refers to any clay which, with or without chemical treatment, is capable of decolourizing mineral or vegetable oils and is, therefore of economic value. Montmorillonite is the active component of most fuller's earths, though palygorskite-, halloysite- and even kaolinite-rich clays have been used.Previous literature related to the New South Wales deposits has been confined to general descriptions and little technical data beyond an occasional chemical analysIs have been available. Bentonites and fuller's earths from seven...

Jan 1, 1959

By Walter W. Focke, Zola Kwela, Willem van der Merwe, Arao Manhique

"The advantages of the de Wet zirconium process for the manufacture of AZST from zircon sand include: Fewer processing steps; removal of radioactivity by leaching rather than by precipitation; alkali reagent recovery in the form of a sodium silicate solution that is essentially free of radioactivity; fewer waste streams and less waste to discard.Here we report on our efforts at maximizing the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since they do not hydrolyse in water they limit the recovery of alkali. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed. Optimum process conditions, with respect to NaOH recovery, correspond to a 2:1 stoichiometry and fusing for 2-hour at 850°C. At these conditions the alkali recovery is ca. 78% and the zirconia yield is ca. 57%."

Jan 1, 2003