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By F. F. Aplan, J. A. Gutierrez-Rodriguez

"Contact-angle and flotation techniques were used to evaluate the influence of oxygen - both that inherent in the coal and that introduced by ambient temperature, aqueous oxidation - on a wide range of coal ranks. Oxidation was found to decrease the hydrophobicity and floatability of coal; with the effect being minor for coals of high rank but becoming increasingly important as the rank of coal is reduced. As an approximation, oxidation makes a coal behave as if it were one of lower rank. Frother only flotation' of coal· correlates with the captive-bubble contact angle whereas when oil is used as a collector, the flotation appears to follow the pattern shown by the water sessile drop on a fresh, un-reagentized coal surface. Coal recovery lost through oxidation may often be recovered by use of a variety of collectors, of which No. 2 foe! oil is among the best of those reagents tested. A simple alkali-extraction test may be used to estimate the influence of oxidation on coal preparation processes and use.INTRODUCTIONThe hydrophobicity of coal is not only a function of its rank but also of the extent of oxidation of the coal during and subsequent to its formation. Weathering and oxidation processes may proceed in-situ for coal deposits that outcrop near the earth's surface, or the oxidation of the coal particles may occur during mining, stockpiling or processing. Such oxidation, whether it affects the bulk-coal sample or on1y a thin outer layer on the coal surface, can dramatically influence the wettability of the particle and hence such processes as flotation, filtration, flocculation and dispersion.Many of the studies made on the oxidation of coals ·were designed to study its effect on flotation, coking or pyrolysis. The. present study 'is directed exclusively toward the effect of oxidation on the hydrophobicity and floatability of the coal. One of the first studies of the effect of oxidation on coal flotation was that of Sun [l] who found that as oxidation proceeds, coal becomes progressively more hydrophilic. Low-temperature oxidation (100-150°C for 250 h) generally lowered the coal floatability with an oily collector only slightly, but more extensive oxidation (200- 3500 C for 250 h) reduced coal floatability seriously. Sun also found that cationic amines were effective collectors for the oxidized coal which infers that oxidation makes the coal more negative in solution. He attributed the loss of floatability to be due to the accumulation of water-insoluble oxidation products at the coal surface. Gayle et al. [2] found that oxidation adversely affected coal flotation when an aliphatic-alcohol frother was used, though a small amount of oxidation appeared to improve the floatability of some coals using a kerosene-pine oil, collector-frother mixture in pilot-plant testing. Prolonged oxidation adversely affected the flotation recovery of the coals tested, the effect being more pronounced when an alcoholic-type frother only was used. They also noted that the reduction in floatability of lower rank bituminous coals was more affected by oxidation than was that of higher rank bituminous coals."

Jan 1, 1989

"The development of non-destructive testing (NDT) methods for deep foundations occurred in several parts of the world, gradually coming together into the present state of the art. The compilation of this brief NDT history is the best effort of several knowledgeable members of the Deep Foundations Institute (DFI) Drilled Shaft Committee, coupled with the recollections of several historically important contributors to the science. It is not intended to be exhaustive, but rather concentrates on the origins of the methods in common use and on which this manual focuses.Modern NDT methods, and the spread of knowledge about them, have expanded through application to real foundations projects by the original researchers, sometimes inspired by their own curiosity, sometimes to respond to the cost and time limitations imposed by static testing, and sometimes to address the questions raised on research projects funded by large government agencies such as the Federal Highway Administration (FHWA) in the USA, and various European transportation agencies. Initial attempts were primitive by today’s standards, and equipment limitations often restricted successful application to relatively simple cases. As electronics improved and confidence in them increased, the early researchers began commercial promotion of their methods, published their findings in professional journals, and shared experiences at conferences held by such groups as the DFI, the International Association of Foundation Drilling (ADSC), the International Conferences on the Application of Stress-Wave Theory to Piles and other venues such as ASCE and Transportation Research Board (TRB) conferences.NDT methods were developed to fill a need to assess the quality assurance of deep foundation elements. New pile types and higher design loads prompted engineers to verify the safety of their foundations via additional testing during construction. Static load testing was the traditional method to assess performance, and this method has been used for centuries and perhaps even millennia.Relatively recent alternatives to static load testing for determining the capacity of drilled shafts include the bottom load test method. This method uses a jack embedded in the lower portion of the pile (bottom load test) and was first reported to be used from Canada in the early 1970’s (Gibson& Devenny 1973). The concept immediately caught on in Israel, where it was used as a quality control measure for small-diameter piles drilled in rock (then a new technology). The method was later patented in the US by Jorj Osterberg, and offered as a commercially available service in thelate 1980s (Osterberg, 1989)"

Jan 1, 2004

By V Shrotri L Muhmood, P Gandhre

The current work deals with the measurement of some thermophysical properties of Ca(NO3)2 based ternary nitrate molten salts as HTF (heat transfer fluid) / TES (Thermal Energy Storage) material for CSP (Concentrating solar power) plants. The density and viscosity of different compositions of the ternary salt mixture containing Ca(NO3)2, NaNO3 and KNO3 close to the liquidus has been experimentally measured. An attempt has also been made to measure the melting point of the salt using the cooling curve technique as well as Differential Scanning Calorimetry (DSC). Thermogravimetric analysis has also been performed to estimate the peak operating temperature of the salt. Compatibility of suitable pipe material (SS304) with molten salt has also been discussed. The salt mixture proves to be a viable alternative to the already existing HTFs like Therminol VP-1 (organic oil) or Solar Salt® in regards to its lower melting point, wider operating range, low cost, nontoxicity, sufficiently high density and comparable viscosity.

Jun 19, 2024

By S. J. Schatzel, J. D. Addis, V. Gangrade, L. L. Chasko, C. A. Hollerich

A ventilation study was conducted at a western U.S. coal mine to evaluate the movement of longwall face air and exchanges between the face and worked-out areas to document the presence or absence of face airflow pathways between these locations. This field study was part of a project investigating the effect of longwall face length and caving characteristics on longwall face air behavior and its potential movement on and off of the face. Tracer gas experiments using sulfur hexafluoride (SF6) were done to describe air movement on the face and in the mined-portion of the active panel. Maintaining adequate ventilation air on longwall faces is important for worker safety and for the dilution of methane emitted from the face and caved gob.

By David Yang

Commercially available flotation technologies for recovery of mineral fines have remained essentially unchanged for several decades. Recent studies have focused simply on improving mechanical and open column cells. Such studies have explored different control strategies and have aimed to improve reagent selectivity, fine air bubble generation and particle-air contact. However, no study has questioned whether current techniques are the most efficient technology for recovering mineral fines. Given that both mechanical and open column cells have a widely accepted carrying capacity limitation, the lack of extensive research into an alternative technology is surprising. Most recently, open column flotation has become an entrenched technology, and it is undermining the efficient recovery of mineral fines worldwide. An alternative exists. Packed column flotation overcomes the above-stated problems as the technology surpasses the carrying capacity limitation of current means by several-fold and almost always achieves the best performance in many comparative pilot tests and full-scale plant operations. Filling a column with packing plates creates a network of sloped walls capable of supporting a froth bed many times deeper than conventional machines. Having froth up to 75 percent of the total column volume tolerates all feed changes encountered in the plant environment and permits maximum flexibility in concentrate quality control. Furthermore, its scale-up is straightforward by increasing column volume or the number of interconnected small cells. As the air breaks upon rising and is distributed horizontally through packing plates, the air spargers can be replaced with a simple blower, resulting in considerable savings in operation and maintenance costs. Packed flotation technology provides a break-through solution for the separation of fine and ultra-fine minerals. Its simplicity, superior performance, and low cost structure make it an appealing alternative to current technologies and allow greater flexibility in downstream processing. Future industrial applications include a wide variety of metallic and non-metallic ores. This paper focuses on some recent scale-up campaigns for nickel and copper sulphide flotation applications compared directly to conventional equipment.

Jan 1, 2014

"A carefully planned laboratory test program is the foundation for the successful development of a sulfide flotation process. In this paper, the development of a copper-molybdenum flotation process is described. However, the concepts discussed can be applied to most sulfide flotation systems and to many industrial minerals projects as well. Each step is examined, beginning with sample procurement and covering sample preparation, flotation test preparation grinding, scoping flotation tests for reagent scheme selection, rougher flotation parameter evaluation and cleaner circuit evaluation, through to locked-cycle testing and pilot plant design and operation. Ore variability and modeling to determine the response of various ore types to the optimum conditions established is also examined.IntroductionA carefully planned laboratory test program is essential for the successful development of any sulfide flotation process. These programs usually begin with a series of batch tests on several ore type composites to evaluate appropriate reagent schemes and delineate optimum rougher flotation conditions, such as primary grind size, flotation pulp density, flotation pulp pH and retention time. Cleaner parameters such as regrind size requirements, cleaner pH, pulp density and number of stages are then defined. Semicontinuous locked-cycle tests are performed using the parameters established in the batch tests to determine the effect of middling streams recirculation on flotation performance. The data generated and the experience gained in the locked-cycle tests may be used to design and operate a continuous pilot plant if relatively large amounts of concentrate are required for further process development, such as optimization of byproduct molybdenum production from bulk copper-molybdenum concentrate.A comprehensive ore variability program is undertaken to determine the response of various ore types to the optimum conditions established. These ore variability programs often test hundreds of samples in standardized batch rougher and cleaner tests to ensure that the orebody is well understood.This article describes the development of a copper-molybdenum flotation process, but the concepts discussed can be applied to most sulfide flotation systems and many industrial minerals projects. The block flow diagram in Fig. 1 provides an overview of the development process."

Jan 1, 2016

Formation of either sodium jarosite or lead jarosite from concentrated chloride solutions containing small concentrations of sulphate has been demonstrated. Sodium jarosite is precipitated at 95-100°C from FeC13-FeCI2-NaCI-PbCI2 solutions to which was added Na2SO4 or Li2SO4 in amounts greater than 0.05 M. In the absence of alkali metal ions capable of forming jarosites, lead jarosite was precipitated from either FeCI3-PbCI2 or FeCI3-FeCI2-LiCI-PbCI2 solutions to which had been added small amounts of sulphate. Many of the factors affecting jarosite precipitation from chloride solution have been elucidated, and the most critical were sulphate concentration and initial pH. Concentrations of HCI in excess of O. I M essentially suppressed the production of jarosite in chloride media. Alkali jarosite, precipitated in the presence of dissolved lead, incorporates a small amount of this metal into the alkali jarosite lattice. Small but significant amounts of copper can also be incorporated into alkali jarosite and the amount is further increased in the presence of lead. Other divalent base metals such as Zn, Cd or Ni are not significantly precipitated. Sulphate control in either FeCI3 or FeCl3-NaCI leaching systems could likely be maintained by jarosite precipitation provided that the acid concentration of the solution was low.

Jan 1, 1981

By M Rattenbur, A B. Christie, S C. Cox

A new minerals initiative to increase the level of understanding of New Zealand's mineral resources and to promote the development of minerals began earlier in the year in a partnership pilot-project between Crown Minerals and the Institute for Geological and Nuclear Sciences (GNS). The project aims to gather a set of comprehensive geoscientific data and build a series of digital GIS packages to highlight New Zealand's mineral prospectivity. The pilot study was carried out at a regional scale, and is focussed on mesothermal gold mineralisation in the South Island. A significant amount of geological data and information was sourced from open file technical reports held by Crown Minerals and from various databases held by GNS and has now been compiled into a single GIS dataset, which will soon be made freely available to interested parties. In addition to this comprehensive data compilation, prospectivity modelling using Weights of Evidence techniques was undertaken to highlight those areas likely to contain ore deposits. It is clear from this study that the South Island of New Zealand remains highly prospective for mesothermal gold mineralisation. Many of the highly prospective areas, which also contain historic mine workings, remain open for exploration. The study not only highlights these areas, but also other areas where the potential for similar mineralisation exists, in all likelihood with no surface expression. The study has also highlighted the value of many of the open-file technical reports held by Crown Minerals and the need to carry out additional studies using this and other available data at a more detailed level, possibly as the basis for a web-based minerals information system.

Jan 1, 2002

By D. E. Wolfson

As part of its overall program of coal-carbonization research, the Bureau of Mines is studying the coking properties of coals from various fields of this country. Few of the coals included in this survey are used for the manufacture of metallurgical coke, although some well-known coking coals necessarily are tested to provide comparative data, particularly on blending properties. The overall objectives of the study were given in detail in a previous report.3/ The inherent suitability of coal for metallurgical purposes, as distinguished from economic considerations, depends primarily on (1) the available reserves, (2) chemical composition, (3) preparation characteristics, and (4) carbonization behavior. These items are considered in selecting coal for carbonization tests.

Jan 1, 1956

By Srinivasulu Tadisetty

The productivity and safety of Indian longwall operations are insignificant because of complex geomechanical conditions. Therefore, the continuous monitoring and forecasting of abnormalities is imperative. Authors developed an innovative real time system and implemented in one of the Indian longwall mines. The real time system was successfully acquired data from underground chock shields and classified the behaviour in real time as per the standard norms. Furthermore, it forecasted the abnormal behaviour of chock shields promptly. The management was implemented appropriate precautionary measures based on real time forecast. Subsequently, the longwall operations were successfully completed with enhanced productivity and safety. This paper discuss the impact of the innovative system on productivity of experimental longwall mine.

Jan 1, 2006

By D. M. Conner

An innovative patented process has been developed to convert high volume wastes--fly ash from coal-fired power plants, municipal solid waste (MSW) ash from incineration, solids from waste water treatment and paper mill sludge into a high value and environmentally benign product in the form of a lightweight aggregate. Lightweight Aggregate is widely used in the building construction industry in the United States, Europe and some Asian countries. This paper will present the development of the process, the process itself and details on the first commercial scale plant. The commercial plant is owned and operated by Wisconsin Electric Power (WEPCO).

Jan 1, 1997

By M. A. Kessick

Current treatment and disposal procedures are compared for clay slimes resulting from the extraction of Alberta oil sands, the extraction of Florida phosphate matrix, the recovery of diamonds from kimberlite deposits in South Africa, the recovery of kaolin from clay deposits in southwest England and the upgrading of bauxite ore. Published research in the area is reviewed, and common trends which are emerging in the disposal of clay slimes are discussed.

Jan 1, 1978

By P. C. Parsons, G. C. Milligan

"IN FIELD WORK in the Cape Breton Highlands, which are heavily covered with vegetation, it is necessary to run traverses along the valleys of small brooks. We encountered difficulty in closing such traverses, and the following technique was developed to solve this problem. It has been tested in the field for four seasons by several people, and found to be simple, efficient and more accurate than any other compass-and-pace system of which we are aware. So far as we can find, the technique has not been described previously. It may be of use to others.The Cape Breton Highlands of Nova Scotia consist of hills of old intrusive and metamorphosed sedimentary rocks protruding up to 1,000 feet above the general level of the younger sediments which underlie the valleys. The flat hill-tops are the remnants of a plateau; drainage off the edge of this plateau has produced many small steep brooks. They occupy valleys which are up to 800 feet deep, and V-shaped in cross section, with steep sides covered by mixed conifers and hardwoods. The stream at the bottom is rarely more than a few feet wide, with a negligible meander belt, but with many bends, rapids and falls. Visibility along the stream, in consequence, is rarely more than a few hundred feet, and in many places much less.It was found impractical to map the streams by the method of meander lines, as described in many standard surveying texts and hand-books. The limited visibility, and the numerous bends of the brooks, necessitated many corners. Every corner introduces errors. To 'close' a survey with 40 or 50 such corners proved either very time-consuming or impossible. In most cases, however, the general direction of a valley may be obtained from an aerial photograph, or by direct observation, and this became the basis of the method adopted."

Jan 1, 1971

By Stephen J. Crittenden

Deep gas and oil production has been substantially increased over prolonged periods through the use of sintered bauxite propping agents. Since its inception in 1976, over 170,000,000 pounds of high strength ceramic proppants have been employed. Recent field evaluations and economic analysis demonstrate the superiority of sintered bauxite proppant over quartz sand. This paper describes the development, application, field results, and product evolution of sintered bauxite.

Jan 1, 1983

Considerable attention has been given to the restoration of low-level radioactive (<1000 pCl/g) sites contaminated during the early years of the atomic energy program. Current clean-up activities which involve the relocation of contaminated soils to licensed disposal sites have been shown to be very costly due to the large volumes of soils which must be excavated, transported and stored. Recent characterization studies conducted at Virginia Tech suggest that the volume of soil requiring disposal can be greatly reduced using mineral processing techniques such as classification, density separation and froth flotation. This article discusses the application of these technologies for soil remediation and describes a conceptual flowsheet for treating soil samples from two contaminated sites.

Jan 1, 1997

By H. F. Naldrett

"AbstractAt the end of May, 1950, Imperial Oil, Limited, had completed a total of 192 D-3 wells in the Leduc-Woodbend field, 62 of which lost circulation in the D-3 zone for periods ranging from two hours to fifty days. The majority of the remaining wells •lost some mud without actual loss of returns. In addition, independent operators completed 69 D-3 wells, of which 9 lost circulation. Included among the latter is the now well known Atlantic No. 3 well, which blew wild out of control for seven months. The well was finally brought under control through two directionally drilled wells, but not before the derrick fell and the well caught fire. Practically all known filler materials have been used in attempt3 to prevent or regain loss of circulation, but none has been successful, except in minor cases. Ordinary sawdust has come to be the most commonly used filler material and is added to the mud before the D-3 zone is contacted. In cases of serious loss of circulation, the on1y successful method of getting returns has been the use of a series of small cement plugs.IntroductionThe Leduc field is twenty miles southwest of Edmonton, Alberta. Geologically, it is on the east limb of the Alberta syncline, in the homoclinal belt. The main productive zones are in the Upper Devonian formation and are known locally as the D-2 zone and D-3 zone, respectively (see Figure 1).The D-3 zone is a dolomitized reef with fair average porosity and permeability, and shows considerable evidence of vertical fracturing. Porosity is mainly due to moderately uniform development of vugs which are interconnected by small crevices. However, the formation is known to be, locally, extremely vuggy and in places cavernous. These latter conditions create very serious drilling problems due to the hazard of loss of circulation, particularly in the gas cap, which has a maximum thickness of 200 feet. The D-3 zone is contacted at an average depth of 5,300 feet."

Jan 1, 1950

By Bill M. Stewart

To decrease the potential for fine coal waste slurry impoundment failures, the Bureau of Mines investigated a new disposal technique. The fine coal waste slurry is rapidly thickened (i.e., dewatered) and deposited on a slightly sloping surface. To accomplish rapid dewatering, a chemical flocculation system using polymers was developed to treat the fine coal waste slurry stream. The fine solids formed flocs, settled from suspension, and rapidly released excess water. During the last 5 days of the field test, slurry flowing at rates from 498 to 675 gal/min with a specific gravity range of 1.15 to 1.33 was successfully treated and dewatered. During this period, untreated slurry had an average moisture content of 227.4 pct (30.7 wt pct solids). The effectiveness of the dewatering system was determined by monitoring the moisture content of the deposited waste with respect to time. Sixty-five hours after ending the field test the average moisture content was 54.9 pct (64.5 wt pct solids); 68 days after the field test the average moisture content was 28.8 pct (78.0 wt pct solids).

Jan 1, 1986

By J. F. McMahon

Introduction The greater portion of the information presented in this paper was obtained in the course of an investigation on clay gathering and its cost in the provinces of Quebec and Ontario (1). For assistance in the preparation of the paper, the writer wishes to record his thanks to Mr. Howells Fréchette, Chief of the Ceramics and Road Materials Division of the Mines Branch. Clays are mineral substances consisting essentially of hydrous aluminium silicate which become plastic when wet, fairly hard when dry, and stony masses when burned to a sufficiently high temperature and re-cooled. Shales are clays which have been indurated by the processes of nature. Millions of tons of clays and shales are won yearly for the production of brick, tile, sewer pipe, drain tile, roofing tile, fire-brick, china-ware, wall and floor tile, cement, and a host of other products. There are certain types of clay which, due to their particular qualities and limited distribution, are mined entirely or in part for sale to manufacturers, and are even exported from one country to another, as for example china-clays or kaolins, utilized in the manufacture of white-wares and in the paper industry, due to their consistent whiteness; ball-clays, utilized in the white-ware industry, due to their bonding power and whiteness; slip-clays, used in the stone-ware industry because of their glazing properties, and in the grinding-wheel industry for their burned bonding properties; and suspension-clays, such as are used in the enamelling industry. However, the great bulk of clays and shales won are used in the production of heavy clay products, and the manufacturer of these generally owns and operates his own deposit of raw material.

Jan 1, 1933

By Roberto Pena, Cristhian Morales, Darwin Morales, Veronica Cambiaso

"This article makes evident the shortcomings of the current operation of oxygen pipes as well as the damages they cause and why they cause them. When focusing on the causes and effects of these drawbacks, it was possible to develop a new family of thermal lances that could pierce a taphole with the precision of a drill but with the capacity to complete the whole operation. Although efforts have been made to replace oxygen pipes since they are annoying, dangerous and inefficient, nobody had worked to improve the way the traditional oxygen pipe taps/perforates the furnaces and reactors tapholes. In fact, developments made in drills and robotic arms, have failed to replace the oxygen pipe, which despite their negative side effects have been used for more than a century. Observation and theory were key to radically transform this humble tool into a dependable and efficient support in the operation. A good news that it is worthwhile to share for the benefit of all of us, passionate about the world of pyro metallurgy.INTRODUCTION Normally, reports and papers prepared for conventions, symposia or other technical events related to metallurgy aim to relevant topics in the operational field, probably because in them lay the scale economies every company pursues. We intend to give relevance to a matter normally disregarded in operations, but that unmistakably vital: if the furnace or reactor cannot be bled, the pyrometallurgical process will not be completed. Besides, if the tapping task is difficult or is long delayed, the availability of the furnace will be reduced. Consequently, there will be a waste of energy and workers will be exposed to dangerous levels of radiation as well as to work overload and physical injuries Apart from these basic effects, in tapping operations where oxygen pipes are used, we can see serious damages in the smelting furnace, especially in the taphole components such as refractory bricks, taphole jackets and water cooled plates. This paper intends to show that taking care of the tapping task can significantly upgrade not only to the tapping operation itself, but also the whole plant productivity."

Jan 1, 2017

By S. V. Shiraishi, H. B. Bell

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J. Cahalan, President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C120-C127, with a contribution by Wright P.A. on the miscibility gap

Dec 1, 1971