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By Z. Jin, D. DePaoli, P. Zhang

"Phosphorite, or phosphate rock, is the most significant secondary rare-earth resource. It contains high amounts of phosphate-bearing minerals along with low contents of rare earth elements (REEs). In Florida, about 19 Mt of phosphate rock are mined annually and most are used to manufacture fertilizers using a wet process, in which sulfuric acid reacts with phosphates to produce phosphoric acid and phosphogypsum. In the wet process, REEs are also leached out into solution and eventually get lost in the leaching residue and phosphate fertilizer. Recovering REEs from Florida phosphate rock in the wet process will be beneficial to broadening rare-earth availability, improving the quality of phosphoric acid product and protecting the environment.This study focuses on the influences of wet-process operating conditions on REE leaching efficiency. The results indicate that REE leaching efficiency increases with phosphoric acid addition in the initial pulp. At a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2 SO4 ) to calcium oxide (CaO) of 1.05 and a weight ratio of liquid to solid of 3.5, REE leaching efficiency reached a relatively high value of 52.82 percent. The trends of REE leaching efficiency were similar to those for phosphoric acid (P2O5 ). Extensive tests on the leaching residue showed that during leaching, about 90 percent of the REEs were released from the phosphate rock but only 52.82 percent ended up in the leaching solution. This phenomenon can be attributed to two factors: (1) the effect of phosphate ions (PO4 3-) in the solution, which caused REE ions to form REE phosphates and be precipitated into the leaching residue, and (2) the influence of large amounts of anions such as sulfate (SO4 2-), dihydrogen phosphate (H2 PO4 -) and hydrogen phosphate (HPO4 2-) anions as well as the polar molecule H3 PO4 , which surrounded the REE cations and formed an ion atmosphere that prevented the PO4 3- from contacting and combining with REE cations. Interaction of these two opposite effects determined the REE distribution between leaching solution and residue."

Jan 1, 2017

By J. F. Neill, O&apos

[The Cartersville mining district is in Bartow County, Ga., about 40 miles northwest of Atlanta. Barite, limonite, ocher, amber, hematite, and, manganese oxide ores have been produced from the strict since about 1840. In the search for a possible source of manganese ore, Bureau of Mines engineers made a preliminary study of the district from September 1950 to January 1951. During this study 139 deposits were examined, and many mineral exposures were sampled. Manganese mineralization occurs as fine oxide and concretionary pellets in residual clays, as fine oxides in umberous clay, in brown-iron deposits, and in a limited quantity in mud ponds and Jig-tailing piles. The future supply of ferrograde manganese ore from the district, using current mining and benefication methods, appears limited to the recovery of the hard manganese ores deposits. Rough estimates indicate a reserve of manganese-bearing clays of about 8,000,000 long tons. This type of deposit has been extensively exploited and the larger deposits mined out to depths of from 50 to 200 feet. The remainder of these deposits are low grade, are covered with deep layers of colluvium, or lie below the ground-water table. Any future production from this source will require systematic prospecting, improved concentration, and an increase in the price of concentrate.]

Jan 1, 1954

By William Seymour

"INTRODUCTION Byproduct-coke manufacture is one of our country's most essential in¬dustries; its importance was strikingly accentuated by the demands of World War II. This paper reviews recent progress in various phases of byproduct-coke operations for the production of metallurgical coke particularly that used as blast-furnace fuel.In the early days of the by-product-coke industry in the United States high-grade bituminous coking coals, both high-volatile or gas coal and low-volatile Pocahontas coal, were plentiful, and the selection and mixing of coals for coke-oven use were minor problems.The demands of World War I for the production of iron, steel, and coke aroused and stimulated new interest in the investigation of the reserves, characteristics, and properties of our coking coals. During that war the increased demand for coke reached a critical stage, and the shortage of high-grade coking coals necessitated the use of cols of inferior quality and of different coking characteristics than those previously used.The period of prosperity following World War I brought much progress and development in the by-product-coke industry. Methods of testing coal and coke were improved. The search for satisfactory coking coals was continued, and construction and design of byproduct ovens were improved."

Jun 1, 1946

By E Jak, M Shevchenko, E Nekhoroshev, D Shishin

In the field of pyrometallurgy, the presence of multiple molten phases with distinct chemical compositions, such as slags, mattes, speiss liquids, metals and molten salts, is a well-known phenomenon. These phases exhibit strongly non-ideal solution behaviour and are mutually miscible to varying degrees. To describe these complex molten liquids, the Modified Quasichemical Model (MQM) has proven effective and has been applied to numerous binary, ternary and several higher-order multicomponent systems related to pyrometallurgy. In recent decades, the complexity of high-temperature processes has escalated due to increased impurity concentrations in primary ores, the incorporation of recycled consumer products and the integration of metallurgical plants through by-product and waste exchanges. To address these issues, PYROSEARCH laboratory has been developing large 20-component thermodynamic database using a generalised CALPHAD (CALculation of PHAse Diagrams) methodology integrated with experimental investigations. Over the past decade, strategic decisions were made balancing the ability to generate experimental data, prediction power, accuracy, stability of calculations, as well as computational time, which are discussed in the paper. Examples provided for issues of >3 liquid immiscibility, non-ionic behaviour and exaggerated ‘sharp’ enthalpies of mixing in silicate slags, dealing with multiple oxidation states, as well as comparative analysis of pair and quadruplet approximation in MQM.

Aug 21, 2024

By D. L. H. Forbes

(New York Meeting, February, 1912.) Introduction.. THE application of the cyanide process to complex sulphide ores for the extraction of their bold and silver is no longer a novelty, but, as an example showing modern tendencies in this direction, the following description of the new milling process at the Lucky-Tiger mine is offered: The extraordinary richness of the ore in the upper workings of this mine made any thought of milling in its early hays seen unnecessary. Its location in an almost inaccessible part of the rugged mountains just south of the Arizona boundary-line, and 60 miles from the town of Douglas, made the expense of bringing in machinery and supplies a very serious consideration. But, after the property had been shipping high-grade ore on mule-back for a few years, there remained in the mine a considerable tonnage of vein-matter that was too low in value to ship, but which it was thought could be milled near the mine at a profit. The first milling-experiment consisted in the installation of Nissen stamps in conjunction with concentrating-tables and Frue vanners, but, as the ore from the upper workings contained most of its silver in the form of cerargyrite, this type of mill was not successful. The proximity of the mine to the great copper-concentrating mills of Cananea and Moctezuma naturally made the influence of copper-milling, ideas felt in the company's next installation. At considerable expense a stage-crushing concentrating-mill, with a capacity of 100 tons per day, was built. This mill was modeled along the lines of the most approved practice in copper-concentrators at that time, the main idea being that crushing by stages in rolls was necessary in order to prevent losses from ?sliming." Largely owing to the fact that, when the mill

Aug 1, 1912

By Leonardo Araújo Peruch, José Fagundes, Henrique Carneiro Pinto, Marco Túlio Costa, Nayara Coutinho, José Fabiano Martins Assunção

The objective of this project was to increase the hot charge by reducing reheating energy consumption and raising the productivity of ArceloMittal Tubarão's hot strip mill by changing the HSM’s schedule process with optimization of the relocation process of slabs after HSM’s chance with focus on slab temperature in reheating time. The project began with the revision of metallurgical rules for the relocation of materials, definition of criteria temperature setting (hot / cold), definition of restrictions of the process and review of modus operandi scheduling process. With the implementation of the process / system it is expected to achieve a 10% increase in the hot charge index in slabs reheating furnaces and increase productivity of the ArcelorMittal Tubarão hot strip mill

Oct 3, 2019

By L. J. Kane

Applications are described of various methods for determining the weight concentration and physical properties of solid and liquid impurities of gases in connection with problems encountered in synthesis-gas production. Of special interest among these methods may be listed: 1. A method developed for determining, the weight concentration of solid and liquid impurities in. hot, crude synthesis gas containing a high concentration of moisture. 2. A method developed for the same purpose but for highly purified synthesis gas or atmospheric air. 3. A method for obtaining a uniform dispersion of dry duet or, a microscope slide for particle-size determination or other purposes.

Jan 1, 1954

By Mario A. Terceros Herrera, Mario Terceros Arce, Antonio Marinucci

This paper describes the general principles of the expander body with post-grouting (EBI) system, and how it is similar in nature to a large-scale pressuremeter device. The results from the installation of an EBI can be used to provide information about the stress-strain characteristics of the soil adjacent to the device and to compute estimates of nominal axial resistance. As the EBI expands during grouting, pressure is applied to the in-situ soil surrounding the device thereby compacting/densifying the soil. The nominal axial resistance for small diameter piles/ground anchors can be increased due to the greater soil stiffness and shear strength around the device, larger surface and end area, and improved soil-to-EBI interaction in side resistance. The shape of the response curves depends on the geotechnical conditions of the soil (e.g., in-situ stress state, strength, and stiffness) and the installation method of the piling/ground anchor. This technique has been used successfully with different pile types and ground anchors in a wide range of conditions from very loose sands/silts to very dense sands and medium-dense gravels as well as in soft to stiff clays. This paper also describes a mini case history in which 80 piles were installed to support an office building, and the results of the static axial compression load tests performed on a production FDP+EBI pile is also included.

By R. D. Hossack

"The selection of a site for plant facilities is a function of several factors and has as its objective the maximization of profits, given fixed markets and sources of raw material locations. In practice there are several sites, any one of which or a combination of two or more would be suitable to meet the basic requirements of source of supply of raw material and labour and still fulfill market demands. The model used to select the optimum profit combination utilizes both computer programs and traditional financial analysis techniques. Of the three computer programs used in the mode), one is a linear program and another is a transportation simulator. Basic cost and price data are required. In examining costs, three levels are used: (a) distribution costs of raw material to the plant and finished goods to the market; (b) direct production costs at the plant, such as labour and locally supplied material; and (c) capital and overhead costs at the plant, such as construction costs, taxes, insurance, and federal and provincial cost allowances. The direct costs generally depend on the scale of operations, so that a large plant in one location may have a lower unit cost than two smaller plants. This, of course, must be balanced against distribution costs. In examining profit, it is necessary to think in terms of the price and volume of sales at each of the market locations. Given basic data and relationships, the model can be used to optimally locate production facilities or, alter-natively, optimally structure a transportation network given existing locations of plants and markets. It is dynamic to the extent that it can react to changes in volume, price and cost to optimally locate an additional plant, the expansion of existing plants, the shutting down or cutting back of plants, or the restructuring of distribution networks."

Jan 1, 1970

By Otto Ruhl

As the result of a study of an area comprising some 100 square miles in the Missouri-Kansas Zinc district known to have produced zinc Ore from horizons below the Grand Falls formation, it was concluded that these horizons could become an important future source of zinc. To test this conclusion and to ascertain the general conditions associated with these lower-horizon ore deposits, the Bureau of Mines undertook detailed drilling of localities thought to be favorable for deposition of ore in the Reeds Spring and. Fern Glen formations. Two sites in the Galena, Kans., mining camp were chosen for this purpose. Ninety churn-drill holes totaling 19,338 feet of bore were completed by the Bureau in two campaigns that extended from October 1944 to June 1946. Approximately 25 percent of the holes encountered ore and indicated three separate ore bodies containing substantial tonnages. Observations made during the course of the work revealed that certain structural conditions are common to ore deposits in the Reeds Spring and. Fern Glen formations.

Jan 1, 1949

By F. W. Bradley

GOLD is a large subject. One could talk about its geological or mineralogical occurrences, prospect- i11.g for it, mining of .it, its metallurgy or its marketing; but I have decided to limit my discussion to gold as a business-that is, to its production and marketing. In the production of gold, it is necessary to consider the many possible sources, the quantities available, the capital and operating costs and the chances of price-breaking competition. So in the following remarks I shall endeavour to point out that though gold is found in every formation constituting the earth's crust, though it is possible to-find it free in great concentrated placer deposits on the surface, though there are still large unprospected areas of both the surface and the crust, though it may be possible to produce it by the cheapest labor on earth, and by processes not as yet developed, it still has an unlimited market at a definite price. There is no reasonable fear of disturbance by the finding of bountiful deposits, or by cheapening the cost of production due to devaluation, or by the development of any easy processes for direct, or for by product, production.

Jan 1, 1932

By B. D. Thomas

When the origin and early plans, of Battelle Memorial Institute were described in this journal in October 1929 by R. W. Gillett the first director, the doors of the laboratory had just been opened and the hope of the founder that the institution serve the world by research for industry still existed only as an ideal in the minds of the thirty or so employees who then constituted the staff. Since that time the country has experienced troublous times. A devastating depression plunged the entire world into an unprecedented period of financial and industrial inactivity; and the slow recovery of the late thirties was soon to be overtaken and overwhelmed in the violence of war. Through this time of stress Battelle has continued to grow. The staff has increased to almost 600; buildings and equipment have been added, until now it stands in a place of pre-eminence in the metallurgical and engineering world.

Jan 1, 1944

By Rob Boom, Yasuyuki Tozaki, Frank M. Wheeler

Selection of a suitable site for a metallurgical plant is crucial for the success of the business case. For a brownfield project, with the decision to locate the project on a site with existing production facilities and activities, the selection of the site has been made. For a greenfield project, important economic and logistical considerations include proximity to primary and secondary resources and/or to the market, infrastructure, and access to energy and water. National and regional aspects, including the social license to operate, can be decisive in final site selection. Key to recruiting and retaining a labour force are proximity to urban areas, along with weather and health conditions at the site. Risk factors include site geotechnical parameters and topography, contamination, as well as probability and types of potential natural disasters.

Jan 1, 2015

By S. G. Malghan

Flotation is the primary method for copper minerals separation from porphyry ores. The need to process difficult-to-float porphyry copper ores presents challenges to engineers and scientists in several areas. This paper is concerned with summarizing generalized problems faced in the processing of porphyry ores and treatment methods to overcome the specific problems. Though some of the problems are interrelated the problems have been classified into three broad catagories. The case studies of some of the successful applications of innovative methods to solve problems related to ore mineralogy, metallurgical aspects of ore treatment and process variables show that quite often the problems are solvable by a judicious choice of flotation variables.

Jan 1, 1984

By W. W. Adams

Because of insufficient funds for printing, the Bureau of Mines was unable to publish its annual bulletin covering accidents at metal mines in the United States for the year 1933. A brief mimeographed summary of the principal statistical data for that year was released to the public late in 1934. Since then reports for 1934 have been received from the mining companies, and in order to avoid further delay in releasing this information to the mining industry and others interested in the prevention of accidents in mining, statistics for both years are presented in this publication with a minimum of interpretation and comment. The fatal-accident rate for the metal and nonmetallic mines (excluding coal mines) of the United States was more favorable in 1933 than in any previous year since 1911, the first year for which the Bureau of Mines obtained reports from the operators. Further progress was made in 1934, when the fatality rate was even lower than that of 1933. On the other hand, the nonfatal-accident rate, which had reached its lowest level in 1932, increased in 1933 and increased further in 1934, although not to such an extent as to prevent the rate for either of those 2 years from being better than that for any year previous to r1931.

Jan 1, 1936

By I. Imris

The chemical industries are using different type of catalysts, which after application usually produced many tons heap of residues. One of them is cupric oxide catalyst with high content of copper and silica. The recovery of copper from the waste has become major interest from a viewpoint of environmental protection and recycling of resources. The thermodynamic analysis and experimental results suggest that the copper from cupric oxide catalyst can be extracted by plasma reduction process. By plasma reduction process the inert slag and copper with following chemical composition: 99.04 % Cu, 0,042 % Fe could be obtained.

Jan 1, 2007

By P. B. Altringer

Searles Lake, CA, contains the largest known domestic tungsten resource. The brines in this near-dry lake bed, located in the Mojave Desert 130 mi northeast of Los Angeles, contain an estimated 135 MMlb of tungsten. However, the low concentration of tungsten (0.080 g/L W03) in the supersaturated brine makes selective tungsten extraction very difficult. Although many brine chemicals are extracted from the lake, tungsten recovery was an elusive goal prior to Bureau of Mines development of an ion-exchange technique. This publication describes the Bureau process. The following subjects are ad-dressed: ? The Searles Lake tungsten resource. ? General problems associated with tungsten recovery. ? Bureau research objectives. ? Synthesis of ion-exchange resins. ? Development of a two-stage ion-exchange tungsten extraction and concentration procedure. ? Product recovery and purification. ? Economic evaluation. Flowsheets for recovering three products (calcium tungstate, sodium tungstate, and tungstic oxide) are presented and evaluated, as well as a summary of the research effort and potential applications.

Jan 1, 1985

By Cleland N. Conwell

Intermittent coal mining has been conducted in Alaska for over a century. The first report of coal in Alaska was by the Veechy expedition of 1826 and 1827. Whaling ships used coal from Corwin Bluff near Cape Beaufort during the early and latter parts of the 19th century. The first coal mine in Alaska -- and probably the oldest in the Pacific coast of North America -- was opened by the Russians at Port Graham on the southwest tip of the Kenai Peninsula. The mine was operated from 1855 until 1867 when the United States took possession of Alaska. From 1880 to 1915 coal mining was carried on intermittently at several localities including Unga Island, Herendeen Bay, Chignik Bay, Kachemak Bay, and several points along the Yukon River. Small coal mines along the Yukon River provided fuel for the river steamers traveling from St. Michaels to Whitehorse. The area of sustained coal production began with the completion of the Alaskan Railroad from Anchorage to the Matanuska coal field in 1916 and to the Nenana field in 1918. Coal production continued to increase until 1953, at which time the oil and gas fields in Cook Inlet were developed. Oil and gas eventually replaced- the Matanuska coal as a means of providing heat and power. The military in the Anchorage area shifted from coal to oil in 1967 causing a decrease in production. The increased demand for electric power in the Fairbanks area offset the decline and coal production started to increase. In 1969-1970 the Golden Valley Electric Association constructed a mine-mouth power plant 70 miles southwest of Fairbanks near Healy and a power line to Fairbanks. LOCATION OF COALS IN ALASKA Coals are found in all geographical subdivisions of Alaska. Coal in Alaska ranges in age from Carboniferous to Tertiary, and grade from lignite through anthracite. Figure 1 shows the locations of Alaskan coal fields. The only fields that have been developed extensively are the Matanuska and Nenana. Figure 2

Jan 1, 1972

By A. Lebedev

Application of dynamic simulation for a base metal processing plant is discussed. The plant receives ore of variable quality from two pits and blending had to be applied to maximise recovery. The plant employs multiple stage crushing, screening, dense media separation, two-stage milling, flotation and further filtration. Stockpiles and bunkers are used in the plant to cater for breakdowns and operating delays, the latter being appropriately incorporated in the model. A detail dynamic simulation model was constructed from the rock face to the filtration plant to assist the plant design, notably with definition of the ore blending method, sizing storage capacity and in-plant conveyors. The plant model was broken down to capital equipment items and various feed types and mass balances were tested to ensure that the production target is met. The dynamic simulation tested the proposed blending method, identified bottlenecks, produced risk profiles for all strategic storage facilities and overall helped minimise the project risks and improve confidence in the plant design. Keywords: Dynamic simulation, ore grade, blending, capacity, risk profile, throughput, utilisation

Jan 1, 2020

By E. H. Smith

St. Joe Minerals Corp., a subsidiary of Fluor Corp., treats high-grade gold, silver, and copper ore at its El Indio plant at an altitude of 4 km in the Chilean Andes. The ore is complex, being a mixture of massive pyrite-enargite and quartz, both containing very fine gold and silver. Treatment produces a copper flotation concentrate containing high levels of gold, silver, and arsenic, and also dore bullion. Part of the flotation concentrate is roasted to remove the arsenic content, and arsenic trioxide is collected as a by-product.

Jan 1, 1987