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By K. Pagalthivarthi, P. V. Desai

"During solidification of alloys, many inter-related physical processes, such as melt convection, mass diffusion, heat transport, macrosegregation and melt-undercooling occur. Several research workers have studied one or more of these effects separately. To answer important questions on solidification behavior, an overall approach interrelating the processes is necessaryAs a first step toward accomplishing the overall modeling, the freezing of a binary liquid metal is examined. The various stages during freezing of the alloy are critically described to build a continuum model for the entire process. Diffusive mixture theory is used to write the conservation equations for the liquid and the mushy zones. The concept of local thermodynamic equilibrium in the presence of curvature effects is used to restrict the number of degrees of freedom within the mushy zone. Constitutive equations relating flux quantities and affinities, the governing differential equations and boundary conditions are discussed briefly for the freezing process.IntroductionA solidification study encompasses such facets as solifidication time, microstructure, macrosegregation of the solute, shrinkage effects and soundness of the casting. Influence of one or more of the coupled heat and mass transfer phenomena such as local solute redistribution, thermosolutal convection, melt undercooling at dendrite tips and heat dissipation to the ambient have all been previously examined [1-3J. Several studies have examined the individual facets of alloy solidification as isolated processses. In fact, the transport processes occur simultaneously and a comprehensive model should include their inter-relationships. In particular, some of the existing studies of the mushy zone [4-6J do not emphasize thermodynamic completeness. This work represents an attempt to develop a thermodynamically consistent model of the entire solidification process on physical grounds."

Jan 1, 1986

The knowledge of aggregate size under various chemical and hydrodynamic conditions is very important for selective agglomeration, flotation and water clarification processes. Traditionally, aggregate size measurements are conducted using an ex-situ technique or in a diluted suspension. In either case, the measurement occurs in an environment that does not resemble the actual conditions under which the aggregates are formed. In this study, an on-line scanning laser microscope has been used to study the coagula size of micronized coal suspensions as a function of pH, solids concentration and agitation intensity. A maximum aggregate size of 310 µ m was obtained under relatively quiescent conditions and at pH values near the iso-electric point (iep) of the coal. The aggregate size results compare well with the coagulation efficiency measurements obtained under the same pH conditions.

Jan 1, 1994

By T. Sakai

Present authors have succeeded in single pass large draught rolling of AZ31 and ZK60A magnesium alloy sheets below 200 °C without heating rolls by raising rolling speed above 1000 m/min. Heavy reduction larger than 60% can be applied by single pass high speed rolling even at room temperature. The rolled sheets showed fine recrystallized microstructure by dynamic recrystallization. The improvement of workability at lower rolling temperature is due to temperature rise by plastic working. In high speed rolling, almost all of the work done by plastic deformation is converted into the heat that raises the temperature of the sheet during rolling because the heat did not flow out of the sheet by conduction and radiation within very short time.

Jan 1, 2006

By Jerald E. Harris

"Often taken for granted, drill accuracy plays a major role in the relative success or failure of a blast.Expensive technological advances in equipment capabilities, drilling tools, communications, explosives, and timing can quickly be nullified by poor drilling."

Jan 1, 1999

By J. C. Scully

In June, 1965, Sanderson and scully5 reported at the Conference on Environment Sensitive Mechanical Properties of Materials at the Research Institute for Advanced Studies at Baltimore that thin foils of titanium could be prepared by chemical polishing in a mixture of 44 pct HF and 73 pct HNO3 in the volumetric ratio 2:3. The technique is simpler than that since reported by Rice and Orava. As-received annealed titanium (containing 0.8 pct Fe and 30 ppm H) in the form of sheet 0.05 cm thick is placed in the solution and moved up and down. The reaction is violent but suitable foils are obtained very easily and consistently. A typical micrograph is shown in Fig. 3. The small precipitates were not identified. Yamane and ueda6 observed many spotlike features which they referred to as small dislocation loops. While their spots may be due to the reaction of the warm foil with the air as suggested by Rice and Orava, the precipitates in Fig. 3 are also found when foils of titanium are prepared by electro-polishing at low temperatures and subsequently examined in the electron microscope without any inter- mediate warming. Furthermore, they are not a surface effect. It is necessary to add that alloys of titanium cannot be so easily thinned by the chemical polishing solution described above since it contaminates the a, phase with hydrogen and produces y hydride. These matters are described at length in a paper7 and their relevance to stress corrosion is considered elsewhere.'-* Author's Reply The authors are grateful to Dr. Scully for bringing to our attention his hitherto unpublished technique for thinning unalloyed titanium, and deeply regret the unintended apparent duplication. The chemical thinning solution (7 parts HNO3 and 3 parts HF, by volume) reported by us is the same as that with which, for some period in the past, we had experienced success in the preparation of foils from single and polycrystalline niobium. Its subsequent effective application to titanium was a logical step, which, clearly independently of Scully, was conceived by Mr. Rice, to whom full credit is due. A few comments are warranted concerning some of the details of the preceding Discussion. It is evident to the discerning reader that the two thinning techniques under consideration are chemically almost identical, and in that sense are equally "simple". The chemical aspect is, of course, the one of primary importance in both communications. Thereafter, the relative simplicity is dictated by the mechanics of the actual thinning operation selected by the individual investigator. Our standard dimpling, or dishing, procedure was chosen with a view toward providing, for the electron transparent areas of the sample, the maximum protection from extraneous deformation during handling. That the long, straight dislocations visible in Scully's electron micrograph of a seemingly recovered structure closely resemble handling dislocations would tend to indicate the merit of our adopted technique. Features similar to those which Scully has attributed to precipitates, without any apparent diffraction contrast confirmation, were not observed in any of our clean foils taken from annealed or deformed specimens. This was admittedly somewhat surprising since the 3700 ppm (nominal) Fe in the A-70 commercial-grade titanium examined should have given rise to TiFe precipitates. Presumably these existed but were un-resolvable. Curiously, Scully's "precipitate1' density is fairly high although the iron content quoted was less than one-fourth of that in our material. One is forced to conclude from the evidence that prior thermal and mechanical treatments are responsible for the two different types of structure observed.

Jan 1, 1968

Analysis for pillar extraction potential (A-PEP) is an intelligent tool, which could be used as a preliminary output indicator when considering the secondary extraction of regional support pillars in the Witbank and Highveld coalfields of South Africa. The safe and economic extraction of underground coal pillars is of paramount significance and importance to the South African coalmining industry to ensure continuity of supply of this fossil fuel. Pillar extraction practices in South Africa have been responsible a significant proportion of safety and fatality statistics in relation to its relative output (less than 5 per cent of total South African coal production) and, as a result, research was undertaken in local pillar extraction operations and extended to similar operations in New South Wales, Australia to assess a way forward for pillar extraction in South Africa. It was found that, although little in the way of new technologies has emerged in this field in the recent past, significant contributions could be made in the field of risk analysis to obtain a generic design methodology for pillar extraction in South Africa. The resultant A-PEP tool to assess pillar extraction potential is based on certain physical, risk and economic factors, which combine to indicate operational success in terms of economic, health and safety attributes. At the time of A-PEP?s development there was alack of operating underground coal pillar extraction operations, which made it difficult to validate its applicability. Since then, however, A-PEP has been successfully tested and validated against two unique underground coal pillar operations, which is the discussion of this paper. One operation is situated in the Witbank coalfield and is extracting pillars, which are 20 years old and at a depth of 80 metres below surface, while the other operation is situated in the Highveld coalfield-which is extracting 6 month-old-pillars underneath a massive dolerite sill at a depth of 220 metres. A-PEP has shown that its predictive nature is consistent the workings at both operations, irrespective of their unique conditions, and as such it can be successfully used as a mine planning tool. The A-PEP mine planning tool thus represents a positive step toward an integrated approach to underground coal pillar extraction when considering legal and operational aspects, which could form the basis for legislative guidelines when considering the future of pillar extraction in South Africa.

Jan 1, 2005

By Felipe De Lucio Pezet

El presente texto señala las formas más eficaces de producción, donde no haya mayor consumo de mano de obra con menor incidencia directa en el tonelaje minado. Por ello, la modificación de las operaciones (mantenimiento de labores de acceso, avance en chimeneas; relleno; desarrollo de minas), conlleva un mejor productividad. Asimismo, la transferencia de tareas de operaciones no directamente ligadas a la producción hacia operaciones directamente productivas, permite un mejor uso de la fuerza laboral y reduce el costo de producción y aumenta la productividad.

Nov 1, 1972

In a previous paper the author showed that silver considerably delayed the recrystallisation of lead after cold work. The effect of antimony on the rate of recrystallisation of distorted lead was studied next, and the experiments performed, and the results obtained, are described in this paper. Electrolytic lead was used as a standard of comparison.It was also used to make the lead antimony alloys.This electrolytic lead contained 0.0005% total impurities.It was prepared from commercial lead by fire refining, followed by electrolysis and finally by vacuum casting. The process was described in the previous paper and the description need not be repeated here. PREPARATION OF LEAD - ANTIMONY ALLOYS.The steps taken to procure pure antimony are outlined in the appendix. To make the lead antimony alloys a mother alloy was prepared thus:-A quantity of the antimony (it was received in the powdered form) was placed in a pyrex glass tube, which was closed at one end. The antimony was washed with hot hydrochloric acid (1: 1), then with more dilute acid, then with distilled water, and finally with absolute alcohol; it was dried by warming and evacu,ating the tube. This should leave the antimony more nearly free from surface oxides.The amount of antimony was determined by weighing quickly; the appropriate amount of vacuum-cast electrolytic *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

By M. F. Chambers

The U.S. Bureau of Mines conducted experiments on electrowinning of neodymium metal by using a molten-metal cathode at 650° C and an electrolyte of 50 mol pct NdCl3 (neodymium chloride) and 50 mol pct KCI (potassium chloride). The molten-metal cathodes were alloys of magnesium and zinc or magnesium and cadmium. Current efficiencies were 90 pct with a Mg-Zn cathode and 80 pct with a Mg-Cd cathode; The Mg-Cd cathode was easily separated from the electrolyte. In contrast, the Mg-Zn cathode tended to mix with the electrolyte, making separation difficult. The cathode metals were separated from the neodymium by distillation at 1,100° C under a vacuum of 10-3 torr. Neodymium metal of 99.9+ purity was recovered from the Mg-Cd alloy cathode after 30 min distillation time. The neodymium recovered from the Mg-Zn system contained almost 2 pct Zn after vacuum distillation. Continuous operation using the Mg-Cd alloy cathode was demonstrated.

Jan 1, 2010

By Paul D. Tomlingson

Modern production equipment has been designed with greater productive capacity and higher reliability to meet the rigorous operating demands of the mining industry. These improvements have also made the equipment more complex and challenging to maintain. Whether these equipment enhancements contribute to more effective mining operations depends on the overall quality of maintenance. Maintenance is not a stand-alone activity. Although its quality depends primarily on maintenance, cooperation and support from other departments, coupled with the skillful guidance of mining managers, greatly influence maintenance success. Therefore, maintenance risk management must look beyond maintenance itself. Successful maintenance risk management begins with an assessment of the maintenance-related interactions of all mining departments within the mine’s stated operating strategy.

Jan 1, 2005

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By Lifeng Zhang

Printed circuited boards contain considerable quantities of valuable metal, while also containing many environmental pollutants making them unsuitable for landfill. In this study the decomposition of common plastics used in printed circuit boards were studied. Polytetrafluoroethylene (PTFE), polyvinyl chloride (PVC) and polyethylene (PE) were heated in both C02 and argon atmospheres using a thermo-gravimetric furnace (TG) coupled to a mass spectrometer (MS). Soda ash Na2C03 and baking soda NaHC03 were used as reactants. The degradation temperatures and evolved gases are presented for single plastics and mixtures. Mixed plastics are shown to behave as a sum of the individual plastics. The mass loss temperature is the same in CO2 and argon. However, less residue is formed when heated in CO2.

Jan 1, 2008

By A. T. Yu

The quest for ore in an open pit is fundamentally an earth moving proposition. This thesis is vividly underscored by the rapidly increasing volume of waste to be removed in newer mines, where in some instances waste to ore ratios have reached as high as 20 to 1. Continuing depletion of high grade reserves, greater demand for raw materials, coupled with ever climbing labor costs, have made the problem still more pronounced and the need for more effective means of earth moving in an open pit even more acute. A conservative approach to the problem has been to upgrade the sizes of conventional earth moving equipment such as shovels and trucks. In many open pits, particularly in the C.S., this has been responsible for the generally down- ward trend of earth moving costs. None the less, the investment costs of these machines are high, and their gigantic engines are seldom fully utilized. Moreover, a large number of operators are required and maintenance remains relatively high. Unfortunately most people have felt that no other viable alternative was in sight within today's technological capabilities.

Jan 1, 1973

By H. J. Glass, J. G. L. Bekkers

"In order to determine the feasibility of a hydraulic ore hoisting installation, the optimal operating conditions were calculated for applying such a system at the Detour Lake Mine of Placer Dome Ltd. Next, a financial analysis was conducted in order to estimate the cost per tonne for hydraulic hoisting of the ore. Subsequently, the cost per tonne was compared with the hoisting costs associated with a new borehole hoist. Installing a hydraulic ore hoist at Detour Lake Mine was found to be feasible with considerably lower costs per tonne of ore. The applied research method appears to be very functional and can be used to do similar research for other mining operations. IntroductionThe principle of hydraulic ore hoisting is well known, yet hardly accepted in hard rock mining. Application of the system would result in a smaller diameter shaft requirement and a flexible, easily expandable system. However, underground ore size reduction might be necessary and practical experience with the system is limited. Following recent innovations in the field of pumping hardware, e.g. new GeHo and Siemag Transplan equipment, hydraulic ore hoisting should be seriously considered for certain mining operations. As a case study, a design was made for the development of the newly found QK-Zone at Placer Dome Ltd.’s Detour Lake Mine. Hydraulic ore hoisting has been compared with conventional skip hoisting by establishing the optimal operating conditions and pumping equipment requirements for similar capacities at a selected mining operation. Generally accepted equations for slurry transport were used to predict the variation of pressure and power requirements as a function of hourly production and pipeline diameter. These data are used to select suitable equipment and estimate cost figures in order to make a financial assessment."

Jan 1, 1998

By Gary J. Massoth

Wherever hydrothermal fluids vent from the seafloor they will buoyantly rise (up to 100?s of meters) while mixing with seawater before attaining density equilibrium and dispersing laterally as neutrally buoyant plumes commonly 50 to several 100?s of meters in thickness and with order-of-magnitude or greater breadth. Although these plumes are typically >10,000-fold dilutions of vent fluids they can be reliably detected using sophisticated physical sensing and chemical techniques. Hence, hydrothermal plumes are spatially large targets compared to the actual sites of seafloor fluid discharge and resulting mineralization. For this reason plume prospecting techniques evolved over the past 20+ years have been widely used to systematically explore over 10% of the 60,000-km-long system of mid-ocean ridge (MOR) spreading centers for hydrothermal activity. While plume detection and gradient mapping can be used to home in on venting sites, plume chemical signatures provide additional insight regarding the nature of the fluids being discharged on the seafloor. We have applied the systematic plume prospecting techniques developed on MORs to the volcanic frontal arc setting as part of the NZAPLUME (New Zealand American PLUme Mapping Expedition) surveys. NZAPLUME I in March 1999 marked the first systematic reconnaissance of any intra-oceanic arc for submarine hydrothermal activity. Seven of thirteen previously mapped volcanoes that comprise a 260-km-long section of the southern Kermadec arc northeast of New Zealand were confirmed to be hydrothermally active. On average, one hydrothermally active volcano was found along each 35 km of arc front, a rate comparable to slow- and intermediate-rate spreading MORs. During NZAPLUME II in May 2002, thirteen previously unknown volcanoes and 8 satellite cones were first swath mapped for bathymetric detail and then surveyed using plume prospecting techniques. Three active venting sites were discovered along this 580 km-long arc section, bringing the total to 10, or 39% of 26 volcanoes surveyed overall, still an appreciable frequency rate for venting sites compared to MORs. While only chemical results for NZAPLUME I are available, the arc plumes characterized so far are chemically diverse and rich compared to MOR plumes. This diversity and enrichment was most evident as ultra-high concentrations of CO2, sulfur gases (St = SO2 + H2S), and Fe within plumes over several volcanoes. We suggest the fluids discharging from the seafloor at these sites are volcanic fluids, i.e., hybrid fluids comprised of MOR-like hydrothermal fluids evolved from seawater-rock reaction and fluids exsolved from magma as acid volatiles and liquid brines.

Jan 1, 2002

By Terrence R. Lejcher

Strip mining has played a key role in the production of coal used to produce energy in this country. About 56 percent of the 1.3 x 106 hectares (3.2 x 106 acres) that had been disturbed by surface mining as of 1965 can be attributed to stripping (Udall, 1967). The runoff from these stripped areas is usually heavily polluted with high concentrations of total dissolved solids, iron, aluminum, manganese, sulfates, and has low pH values with high acidity. Another problem of a most serious nature in our large cities is the volume of treated solids to be disposed of after sewage treatment. Chicago is presently producing about 664 metric tons/day of dry weight solids (Horn and Earles, 1968). Disposal methods most commonly used include lagooning, incineration, and landfilling. The high cost of land in an urban community is prohibitive of lagoon storage. Incineration and landfill disposal create air and water pollution problems. Many countries including Australia, England and Israel have long realized the value of sewage solids if they are recycled back to the land. In the United States, the value of such solids in reclaiming strip mined land has been recognized by relatively few people. This paper is concerned with the use of anaerobically digested sludge to reclaim strip mined land.

Jan 1, 1972

By Bernard G, Limpach R, Ulveling L

A major aspect in competitive ironmaking is to replace metallurgical coke by injecting alternative cheap fuels. Whereas in the past, heavy oil injection as well as on a lower scale natural gas injection have proved to be reliable, the progressing high price level of these fuels has prompted international interest in looking for alternative cheaper fuels, especially pulverized coal. Theoretical analysis and practical operations showed that for constant adiabatic flame temperature, potentially more coke may be replaced by injected coal than by heavy oil, because of less endothermic cracking of hydrogen components. Since about 1974, the ARBED-Group has been looking for alternative fuels and in 1976 came to conclusion to select for first trials pulverized lignite for the following reasons:

Jan 1, 1981

By M. R. Fletcher

Slags generated by the ferrous metals industry can he used to produce high-value ceramic materials. The properties of these ceramics can be controlled by judicious choices of composition, additives, and processing parameters. Standard methods of materials handling, such as comminution and mixing, are as applicable to slag as to any other mineralogic raw material. In this study, foundry slag was ground, homogenized, melted, and, formed to produce a glass, and then heat treated to crystallize it into a high-strength glass-ceramic. The product shows promise as a low-cost, wear-resistant tile material that (-an he custom cast. This and similar materials made from slags and natural rocks are candidates for use as construction materials, acid-resistant piping, shock-resistant sheathing, rot-proof pilings, and, when foamed, even as pontoons.

Jan 1, 1990

By Muhammet Mustafa Kahraman

Despite technological advancements and organizational adjustments, lost time accidents are major issues in occupational safety. However, there is very limited work that focuses on variables influencing days lost as a result of occupational accidents. In this study, decision tree and artificial neural network methods were used as machine learning techniques to investigate the impact of factors on accident lost day duration. Degree of injury, worker age, and worker activity were found to be the top three variables impacting loss of time from work. It was also identified that the mining method, location, and nature of injury had a moderate influence on duration lost due to occupational accidents. However, worker experience and ore type did not have any significant impact on the duration, which is an unexpected result. These results confirmed that some accident factors that might have a large influence on the number of mine accidents can be less critical when it comes to accident lost day duration.

Feb 3, 2021

By Felix Wolters, Michael Schütt

In over 40 years of operation, engineers at Aluminium Oxid Stade GmbH (AOS) have acquired a lot of experience whereby they have developed a series of optimizations regarding the specific primary energy consumption. The tube digester technology, invented by VAW in Germany and applied on an industrial scale for the first time in Stade, was brought to perfection by its innovative cleaning methods, which led to a constantly high heat transfer, low pressure loss and excellent availability of the digesters. Further improvements such as the heat recovery from the exhaust gas stream of the salt heater as well as the optimization of one of the fluid bed calciners and the installation of a combined heat and power generator (CHP) led AOS to where it is now—a leading alumina refinery with regard to the lowest energy consumption per ton of alumina.

Mar 1, 2017