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By N. V. Peterson, R. S. Mason

Pumice, pumicite, and cinders are all products of explosive volcanic eruptions. Pumice and pumicite are produced by the violent expansion of dissolved gases in a viscous silicic lava such as rhyolite or dacite. Pumice is a light-colored, cellular, almost frothy rock made up of glass-walled bubble casts. It may occur as coherent, massive blocks composed of highly vesicular glassy lava in either a flow or vent filling, or it may be more or less fragmented by violent eruption. Pumicite has the same origin, chemical composition, and glassy structure as pumice differing only in particle size. Particles less than 4 mm in diam are designated pumicite. Pumice is usually found relatively close to the vent from which it was erupted while pumicite may be carried by winds for great distances before settling as an accumulation of fine-grained ash or tuffaceous sediment. Volcanic cinders are the reddish to black vesicular fragments that pile up during explosive eruptions of volcanoes of basaltic composition. Most deposits of cinders occur as cones or mounds of stratified fragments that range in size from a fraction of an inch to several inches in diameter. Individual cones or mounds of cinders may be several hundreds of feet in diameter and as much as 500 ft high. Properties The properties that make pumice and pumicite useful in industrial applications include: low-bulk density, good heat and sound insulating properties, and excellent abrasive capability. Cinders, even though less cellular and somewhat heavier, also have a variety of industrial uses. Uses The main use of pumice and cinders continues to be in the construction industry as road-surfacing material, railroad ballast, building block aggregate, in lightweight structural concrete, and as plaster aggregate. Both pumice and pumicite continue to be used as abrasives for polishing glass, metal, leather, stone, and wood. Some scouring powders and soaps also contain pumicite. Minor uses include fillers, absorbents, carriers for insecticides, catalyst carriers, filters, and soil conditioners. Pumicite is also used in sizable quantities as a pozzolanic additive in monolithic concrete where it increases the workability, strength, and durability of the concrete and reduces the heat of hydration. Volcanic cinders are generally denser and more coarsely cellular than most pumice. Markets for cinders include aggregate for road construction and surfacing and in lightweight concretes, particularly blocks. Some producers having access to both pumice and cinders offer a variety of blends of the two materials to block manufacturers. Most pumice deposits are unconsolidated and usually have a minimum of overburden. Mining is by open pit and can be easily carried out with conventional loading equipment. Sometimes air-drying precedes hauling to a crushing and screening plant which yields the size product desired. Multiple bins at railroad hauling facilities permit blending if desired. Pumice for abrasive use may require more sophisticated processing by fine grinding and air classification before being bagged for market. Block pumice in economic quantity and quality is limited to a few geologically young

Jan 1, 1975

By Raymond B. Ladoo

The Paley report made little attempt to project future production and consumption for any industrial mineral except fluorspar and only about a dozen minerals were mentioned by name. Except for fluorspar the treatment consisted mainly of statistics of production, consumption, imports, and sometimes reserves up to 1950. FLUORSPAR In 1954 the author had occasion to evaluate the Paley fluorspar estimates. At that time a fairly detailed study of the world picture was made and bases for the Paley estimates were studied. Data for later years confirm, in the main, the conclusions reached in this earlier report and it will be drawn upon here.

Jan 11, 1959

By J. Washburn, R. Drouard, E. R. Parker

Temperature dependence of the rate of recovery in zinc single crystals after a simple shear deformation at low temperature was investigated. Some tentative suggestions regarding the annealed and strain-hardened states of a crystal are discussed. RECOVERY may be defined as the gradual return of the mechanical and physical properties of strain-hardened metal to those characteristic of the annealed material; an increase in temperature increases the rate of recovery. The annealing process in strain-hardened polycrystalline metals is complicated by the inhomogeneity of strain which always exists in aggregates. Polygonization in bent regions of the crystals and growth of new almost strain-free grains starting at points of severe local distortion1-:' make it almost impossible to isolate and study the recovery process. Homogeneously strained single crystals, however, do not polygonize or re-crystallize and hence they can be used advantageously to study recovery. In such crystals strain hardening is completely removed by recovery alone. Since recovery is a process whereby certain lattice disturbances introduced by plastic flow are gradually reduced, a knowledge of the rate and temperature dependence of this process for various conditions of prestrain might be helpful in formulating a model of the strain-hardened state. For simplicity it seemed desirable to limit the type of prestrain to the simplest obtainable, i.e., simple shear strain. In the experiments to be described, recovery was studied by observing changes in the stress-strain curve of prestrained zinc single crystals held for various times at temperatures above that employed for straining. Single crystals were grown from the melt by a modified Bridgeman technique from Horse Head Special zinc 99.99 pct pure, and from spectrographically pure zinc 99.999 pct pure. They were grown as 1 in. diameter spheres and acid-machined' to the final specimen contour. The test section was a cylinder about 1/8 in. high and 3/4 in. in diameter. The conical sections adjacent to the test section were cemented into the grips so the load could be transmitted to the crystal as uniformly as possible. The specimens were oriented so that in testing the maximum shear stress was applied along one of the slip directions, [2110], in the (0001) plane. Details of the production and testing of such specimens have been presented.' Each test was carried out according to the following schedule: 1—The crystal was strained at — 50°C until it reached a maximum shear stress, ,,,. The strain rate was approximately 5 pct per min in all cases. 2—After straining, the crystal was unloaded before the temperature was changed. Unloading required about 3 min. 3—The temperature of the specimen was then increased from — 50°C to the temperature, T, of recovery. This change in temperature was completed in a time of less than 2 min. The specimen remained at temperature, T, for a time, t, which differed for the various specimens. 4—Thereafter the temperature was again reduced to — 50 °C in approximately 3 min. 5—While at —50°C, the stress-strain curve after recovery was obtained. 6—The specimen was then unloaded and annealed for 1 hr at 375 °C in a helium atmosphere to bring about complete recovery. Cooling to room temperature after anneal required 90 min. 7—The same crystal could be re-used for another test because the plastic properties after annealing closely duplicated those of the original crystal. The specimen was immersed during the test in a bath of methyl alcohol which, through a system of tubes, could be pumped through either of two heat exchangers to regulate the temperature; this was accomplished by circulating the liquid through coils immersed in a bath of acetone and dry ice for cooling or in a bath of warm water for heating. Test temperatures were thus maintained constant within ±1°C. The — 50°C temperature was low enough so that no measurable recovery occurred during unloading and reloading. The stress-strain curve continued after recovery along a path below, but approximately parallel to, the path of a curve obtained in an uninterrupted test. Fig. 1 shows some of the results from a specimen of 99.999 pct Zn. The amount of downward displacement of the curve due to recovery was a

Jan 1, 1954

By S. Chama, P. Chishimba, Tina Chanda Phiri, J. Machona, S. Parirenyatwa, G. Kaluba, Y. R. S. Hara, D. M. Musowoya

The investigation focuses on leaching of copper (2 wt%), cobalt (0.5 wt%) and iron (2.4 wt%) from complex tailings material from the Democratic Republic of Congo. The highest recovery of copper and cobalt into the leach solution were 78 and 10%, respectively, under direct leaching with sulphuric acid. Higher recoveries (90% for copper and 96% for cobalt) were attained when the material was pre-reduced with coal for 1.5 h in the temperature range of 700–950 °C. The increased recoveries were due to metallisation of all the copper and cobalt which is in the silicate matrix. The effects of pre-reduction temperature and sample to carbon weight ratios were analysed and found to be important in; (i) achieving high recoveries of copper and cobalt and (ii) decreasing the amount of iron in the leach solution. The samples were characterised by atomic absorption spectroscopy and scanning electron microscopy (SEM) techniques.

Mar 1, 2017

By J. S. Aronofsky, J. P. Heller

This paper presents a mathematical analysis of the fluid mixing which occurs during flow through porous media. The analysis is based on the well-known diffusion equation with mass transfer term. It is pointed out that the use of this equation is justified by a single general assumption which does not specify any particular mechanism for the mixing process. Formulas are given for tracer fluid concentrations for two different boundary and initial conditions. Calculated numerical values compare closely with some published results of experiments in which no viscosity or density difference existed between displaced and displacing fluids. INTRODUCTION A phenomenological theory of the mixing and diffusion process is presented for the flow in a porous medium of two miscible liquids of equal viscosity and density. This is based on the classical diffusion equation which has been used to explain such processes as Brownian motion and heat conduction. More recently, this same differential equation has been derived (in a manner analogous to the work in this paper) for the problem of heat transfer during fluid flow in porous media.' The purpose of this paper is to show that the available experimental evidence justifies the use of this simple diffusion equation. The recent data of Koch and Slobod' and of von Rosenberg' are used to test this diffusion model by comparing concentration curve shapes and calculating "effective diffusion coefficients". The same differential equation for miscible displacement, as well as some experimental confirmation, has been published in Japan by K. Yuhara,4 and recently in this country by Day.5 Yuhara arrives at his con-clusions through analogy with turbulent diffusion, de- scribing the microscopic velocities in terms of "eddy motion" — although unlike the ordinary eddies of hydraulics. Day proceeds directly from Scheidegger's6 concept of the dispersion of velocities. After a very clear description of Scheidegger's theory, he applies it to calculate the motion first of a drop and then of a thin layer of brine into a bed of sand. For the latter case, Day derives and solves the same differential equation as Eq. 1. In our presentation no detailed assumptions are made as to the mechanism of displacement. In fact, several microscopic processes may well be involved—the only general assumption made is that their cumulative microscopic effect may be described by the addition of a second-order term to the differentirl equation of continuity. DERIVATION OF EQUATIONS Let us consider the displacement in one spatial dimension of Liquid A from a sample of porous media by Liquid B. A and B are assumed completely miscible and of the same viscosity and density. Both fluids are also assumed to be incompressible and it is specified that the total flow is the same for any cross section. It is evident that the rate at which Liquid B would be carried across such a section would be given by the product of the fluid velocity, u, and the concentration, C, of B in the fluid mixture assuming the constancy of u and C over the cross section. Since the volume of Fluid B is conserved, this leads to the one-way wave equation - u ?C/?x = ? ?C/?l where x increases in the direction of u—the "Darcy velocity", Q/A (or velocity flux per unit area), and 9 is the fractional porosity. Consider the case where fluid B is displacing Fluid A and the concentration distribution is represented by a step funcLon (with a vertical discontinuity). The solution of Eq. 1 predicts no mixing

Jan 1, 1958

By Raymond C. Voige

"The use of current electronic technology in the design of new underground mine communications equipment is providing improved and expanded voice communications which can, in turn, contribute to improved productivity and safety. A review of equipment that is now available or under development Includes the following categories:WIRED SYSTEMSI.Pager phones with selective calling, audible and visual alerting and message indicator.2. Mufti-conversation pager phones that use multiwire cable ormultiplexing techniques.WIRELESS SYSTEMSLow-and medium-frequency inductive systems utilizing ""near"" magnetic fields for both vehicular and personal communications.Wired SystemsCommunication systems in underground mines have evolved slowly in many parts of the world. For many years, magnetotype telephones were the only means of communication from one mine level to another and to the surface. These units were located near the shaft and communications to the working areas were limited."

Jan 1, 1981

By M. J. Saarivirta

A high-purity copper-zirconium alloy system was imesti-gated. The zirconium content of the alloys studied varied from 0.003 to 0.23 pet. The solid solubility of zirconium in copper and some physical and mechanical properties of the alloys have been determined. By proper heat treatment, Cu-Zr alloy can develop a high electrical conductivity and resistance to softening at temperatures up to 500°C (930°F). This combination of desirable properties makes this alloy superior, to other com-merzcrrl copper base alloys for- use in the electrical conductor field. DEMAND for high conductivity copper alloys that retain their mechanical properties at elevated temperatures is growing rapidly. At present, copper-base alloys such as copper-silver and copper-chromium are used where these characteristics are required. As an example, commutators in electric motors are often made of these alloys. However, the life at elevated temperature of commutators made of copper-silver alloys is much shorter than the life of the same part made of copper-chromium and copper-zirconium alloys. Copper-silver alloys are subject to creep and subsequent failure when the service temperature exceeds several hundred degrees centigrade. Use of copper-chromium alloys has been known for the past several years, but little information is available in the literature concerning the properties of alloys in the copper-zirconium alloy system. Some work had been directed toward determining the solubility of zirconium in copper as well as determining properties of the Cu-Zr alloys. These investigations have revealed the superior high-temperature and electrical conductivity properties of copper-zirconium alloys over copper-chromium alloys. The United States Metals Refining Co., Carteret, N. J. has recently produced OFHC R copper-zirconium alloys for experimentation and evaluation. Because OFHC R copper contains no appreciable oxygen, no harmful oxides are formed and the full benefit of Zr as an alloying addition is obtained. This paper describes the results of this work. It contains room-temperature and some high-temperature data which have been obtained after various processing techniaues. Actual elevated temperature properties are being determined and will be reported in a separate paper. Preliminary results obtained at elevated temperatures suggest that the Cu-Zr alloy is superior to other high conductivity copper-base alloys. WORK PROCEDURE The high-purity oxygen free (OFHC R) copper-zirconium alloys with zirconium content ranging from 0.003 to 0.23 pct were cast into 4-by 4-in. wirebars by both continuous casting and conventional casting methods. Zr was added in the form of a master alloy containing 30 pct Zr and 70 pct Cu. Castings were analyzed for zirconium and nine bars containing various amounts of zirconium were selected for this study. The results of analyses and the sample numbers are given in Table I. Typical analyses of OFHC R copper are also shown. The following properties were studied: A) Solid solubility of zirconium in copper. B) Effect of zirconium on properties of copper. C) Effect of combined working and heat treating on properties of Cu-Zr alloys. The solid solubility of zirconium in copper was determined by metallographic techniques. Specimens for this phase of the investigation were hot rolled at 900oC (1650oF) to 0.250-in. rod. The rolled rods were cut into 2/3-in. long specimens and solution annealed at 950 °C (1740°F), 980°C (1795 °F). and 1020 °C (1870 °F) for 6 hr and quenched in water. In order to find the solid solubility limits at lower temperatures, the homogenized specimens were reheated at various temperatures for 1 hr and quenched. The physical and mechanical properties were determined on 0.250 in. rod, 0.132- and 0.081-in. wires. The wires were cold drawn from the 0.250-in. rods after they were solution annealed at 980 °C (1795°F) and quenched in cold water. Mechanical and electrical properties were determined on cold drawn and

Jan 1, 1961

By M. Jarvis, D. B. Dreisinger, T. Hitchins

Mineral carbonation (MC) has been extensively researched all over the world since it was found as a natural exothermic process to permanently and safely sequester CO2. In order to accelerate the natural process, various methods for carbonation of Mg-/Ca-silicate minerals and other industrial wastes have been studied. It has been found that the MC efficiency will increase with an increase of CO2 pressure, retention time, temperature, mass ratio of Mg or Ca to Si in minerals, specific surface area, and the slurry concentration in a specific range, and with the introduction of an effective catalysts, for example, 1M NaCl and 0.64M NaHCO3 or carbonic anhydrase. However, there still is not a successful industrial application because of high economic cost and slow reaction rate. It is not economic to exploit Mg- and Ca-silicate minerals deposits or tailings to sequester CO2 by MC, due to the cost of grinding and heat pre-treatment and in some cases the whole sequestration process may result in more CO2 emissions than the amount of CO2 sequestered, due to the requirements of energy inputs. The process however, may be profitable as a whole (with carbon credits). It is suggested to combine MC with recovery of valuable metals from ore deposits in order to reduce the cost for MC by cost sharing for mineral recovery.

Jan 1, 2017

By M. M. Papic

"This paper describes the Sasol coal liquefaction process, as used in South Africa. It covers coal supply, coal gasification, gas purification, Fischer-Tropsch synthesis, the major utility systems involved and the economics of the process.IntroductionThe Sasol coal liquefaction process is based on Fischer-Tropsch synthesis of liquid fuels from carbon monoxide and hydrogen, which are in turn obtained by gasification of coal with steam and oxygen. The process is shown schematically in Figure I.The first step in the process is coal preparation, in which the coal is crushed and screened to a 3-50 mm size for gasification on one side and to -3 mm size for steam and power production on the other. Oxygen needed for coal gasificatoin is produced in the air separation plant.Coal is gasified under pressure by steam and oxygen in the Lurgi gasification plant, where raw, impure gas is produced . The raw gas is first washed in a scrubber with a circulating gas liquor, heat is then recovered from it in a waste heat recovery boiler and the gas is further cooled for purification. Water-insoluble materials (tar oils) in the gas liquor are separated from aqueous solution and sent to tar refining for the recovery of tar products. The aqueous portion of the gas liquor goes to a Phenosolvan solvent extraction process, where phenols and ammonia are recovered. Water then proceeds to the effluent treatment plant.The scrubbed and cooled raw gas goes to a Rectisol gas purification plant, where all components other than hydrogen, carbon monoxide and methane are removed as completely as possible by absorption in refrigerated methanol. The acid gases (CO2, H2S) stripped from the methanol in the Rectisol unit are processed in a Stretford plant for recovery of sulphur. Regenerated methanol is returned to the process. The purified synthesis gas is passed to the fluidized-bed Synthol reactors, where Fischer-Tropsch synthesis reactions take place.The synthesis products are recovered in a product recovery unit as separate streams of decant oil containing higher-molecular- weight hydrocarbons, light oil comprised of lower-molecular- weight species, the aqueous stream containing water solubles, a C3/C4 stream, a C2 stream , a methane stream and a hydrogen-rich stream. Most of the hydrogen is recycled to the Synthol reactors; a major portion of the methane is reformed to hydrogen and carbon monoxide for recycle; the C2 fraction goes to an ethylene plant; and liquid streams proceed to the product refinery.The product refinery is used to upgrade and purify the Synthol products to specification fuels and chemicals.Sasol l, the first coal liquefaction plant in South Africa , was built in 1955. It is still operating and has a product output of about half a million tonnes per year. The Sasol II plant is in a commissioning stage and will be in full operation in 1981. It is about five times the size of Sasoll. It uses over 12 million tonnes of coal and produces more than 2 million tonnes of saleable products annually (1,2,3). The Sasol llI plant, which is a mirror image of Sasol II, is under construction and scheduled for completion in 1983."

Jan 1, 1981

By V. Koump, T. F. Perzak, R. H. Tien

A series of experiments were carried out in which the rates of propagation of the liquidus and the eutectic fronts Mere measured during essentially one-dimensional freezing of Al-Cu alloys. The dimensions of the ingots were 3 by 5 by 6 in. Three different alloys containing 0.1, 4.5, and 17 pct Cu were used in these experitments. For each alloy the rate of heat removal was varied to give a total jreezing time in the range 3 to 30 min. The results of these measurements cowlpared favorably with the theoretical model of freezing of binary alloys with time-dependent surface temperature. IN engineering analysis of solidification of commercia1 steels and nonferrous alloys it is a common practice to assume that an alloy freezes by propagation of an isothermal solidification front, i.e., essentially as a pure metal. In two recent theoretical investigations'j2 the present authors explored the possibility of a more realistic approach to the problem of solidification of alloys. In the proposed model the freezing of an alloy is assumed to take place by propagation of two isothermal fronts, i.e., the liquidus front and the solidus (or eutectic) front. The region between the two fronts contains both liquid and solid and is referred to as the solid-liquid region. The width and the solid content of the solid-liquid region vary with alloy type, solute concentration, and cooling rate. For a given alloy system, initial concentration of solute, and the mode of heat removal, the proposed model yields the temperature distribution within the solid skin, temperature, solid fraction, and concentration distributions with the solid-liquid region, and the rates of propagation of the liquidus and the solidus fronts. This model is obviously of considerable practical importance in engineering analysis of solidification processes, since it gives a more realistic estimate of skin strength during solidification and a better estimate of the total freezing time. Before the new model can be used with confidence, however, it is necessary to test this model experimentally. The experimental testing of the proposed model is a relatively simple matter since the effects to be measured are large and a relatively simple experiment will suffice. The theoretical model predicts, for example, that during freezing of an alloy containing substitutional type solute (negligible diffusion in the solid during freezing) the solid-liquid region occupies an appreciable portion of the ingot, even at low concentration of solute.' Another prediction of the theo- V. KOUMP, formerly with U. S. Steel Corp., is now with Research and Development Center, Systems and Process Division, Westinghouse Electric Corp., Pittsburgh, Pa. R. H. TlEN is Senior Scientist, Fundamental Research Laboratory, U. S. Steel Corp., Research Center, Monroe ville, Pa. T. F. PERZAK, formerly with U.S. Steel Corp., is now with Fiber Industries, Greenville, S. C. Manuscript submitted March 6, 1968. IMD retical model, easily verifiable by experiment, is that the rate of propagation of the solidus (or eutectic) front increases as the solidus front approaches the center of the slab. This prediction is contrary to well-known behavior of the solidification front during freezing of pure metals, where the rate of propagation of the solidification front decreases with time and freezing is completed at the lowest rate. A rather severe test of the proposed model is provided by comparison of theoretical predictions and experimental measurements of the effects of cooling rate and composition on the rates of propagation of the liquidus and the eutectic fronts. In order to test the soundness of the formulation and the method of solution of the problem of solidification of alloys a series of experiments were carried out in which the rates of propagation of the liquidus and the eutectic fronts were measured during essentially one-dimensional solidification of A1-Cu alloys. The A1-Cu system was chosen strictly as a matter of convenience. Three different alloys containing 0.1, 4.5, and 17 pct Cu were used in these experiments. For each alloy the rate of heat removal was varied to give the total freezing time in the range 3 to 30 min. The results of these measurements are compared with the predictions of the theoretical model of solidification of binary alloys, with time-dependent surface temperature.' Before the experiments described in this paper were undertaken, a serious attempt was made to utilize the measurements of previous investigators to test the theoretical model. In the course of this preliminary study a careful review was made of experiments of Pellini and coworkers3 and Doherty and Melf~rd.~ The measurements in Pellini's work were carried out using a steel containing at least four major components. Evaluation of the solid fraction-temperature relation for this steel (required in the theoretical model) is difficult and uncertain. Doherty and Melford, on the other hand, measured the solid fraction-temperature relation experimentally, but did not give sufficient data to explore the effects of composition and the cooling rates on solidification. Hence it was not possible to utilize these measurements to test our theoretical model. EXPERIMENTAL METHOD The experimental technique used in this investigation differs somewhat from the more conventional techniques employed in solidification studies. This technique was developed primarily to eliminate con-vective mixing in the molten metal caused by pouring of molten metal into the mold. In our experiments A1-Cu alloys were melted directly in the mold. The mold assembly used in solidification experiments is shown in Fig. 1. The mold was fabricated from *-in. stainless-steel sheet. The dimensions of

Jan 1, 1969

By S. D. Dahlgren

ORDERED G.P. zones having the cesium chloride structure were found to exist in the bcc iron-rich grains of an Fe-Au-Cu alloy that had been supersaturated with approximately equal atomic percentages of gold and copper, and aged at 400° and 350°C. Streaks and superlattice spots in electron diffraction patterns revealed the presence of the ordered zones in the aged material. The ordered Ll2 structure is commonly found for precipitates in fcc metals (e.g., Ni3A1 in nickelL7') but it is uncommon to find precipitates in bcc metals having the cesium chloride structure. The formation of the G.P. zones caused age hardening of the grains. Samples containing 3.8 at. pct each of gold and copper (with the remainder being iron) were annealed at 95@ or 1125°C in quartz capsules and were quenched by breaking the capsules under water. X-ray diffraction patterns revealed two solid solutions in the quenched samples. One solid solution was bcc and the other was fcc. The microstructure consisted of iron-rich grains of 0.3 mm diam surrounded by a yellow gold-copper-rich grain boundary network. The Au-Cu phase diagram %hows continuous solid solubility of gold and copper with ordered phases forming below 410°C. None of the ordered Au-Cu phases have the cesium chloride structure. Both Fe-Au and Fe-Cu phase diagrams3 show extended miscibility gaps and only terminal solid-solution phases. Consequently, it is reasonably certain the iron-rich grains consisted of an a-phase terminal solid solution, and the grain boundary network consisted of a gold-copper-rich terminal solid solution. Lattice parameters of the quenched solid solutions were consistent with the suggestion that the quenched phases were terminal solutions. The lattice parameter of the bcc phase (2.879A) obtained upon quenching from 950°C was higher than that (2.866A) for pure iron. The fcc phase in this sample had a lower lattice parameter than that for a 50 at. pct Au and 50 at. pci Cu solid solution, i.e., 3.866 compared to 3.877A. The lattice parameter for the 50 pct Au and 50 pct Cu solid solution was interpolated from data for Cu-Au solid solutions.4 More gold and copper were soluble in iron at 1125°C than at 950°C as indicated by a 0.012A increase in the bcc lattice parameter for a sample quenched from 1125°C. After the alloy had been quenched from 950° and 1125°C, the bcc lattice parameters were 2.879 and 2.891A1 respectively G.P. zones having the cesium chloride structure-which formed during low-temperature aging—were detected by electron diffraction and observed with electron transmission microscopy. In Fig. 1, the asymmetrical streaks parallel to ( 100) directions indicate that platelike G.P. zones had formed parallel to (100) planes of the matrix. The direction of streak asymmetry shows that the bcc unit cell of the G.P. zones was larger than the bcc cell of the matrix. The ordered cesium chloride structure is indicated by low-intensity superlattice spots at 010 positions which are nonallowed for bcc structures. The superlattice spots are streaked; therefore they are from the G.P. zones and are not caused by rel-rod effects of a thin matrix phase. The appearance and size of the zones observed in electron transmission microscopy and the appearance of the asymmetrical streaks in the electron diffraction patterns for the Fe-Au-Cu alloy were the same as those observed for a similarly treated Fe-Au alloy.' Ordered G.P. zones were detected also for an Fe-Au-Cu sample aged only at 400°C. The production of the ordered cesium chloride structure zones by low-temperature aging of super-

Jan 1, 1968

By K. H. Singh

The addition of new data and corrections can be made under the control of a simple editing session. All programs for this system are written in FORTRAN and executabe "MACROS".. After the addition of new data, the whole file Is reinitialized to update the binary file and cross-reference tables. Updating the binary file involves rerunning the initializing program. The creation of graphic plots like cross sections and plan views is menu-driven from a terminal and very user-friendly. Small files containing not more than 10,000 entries (survey and assay points) are suitable for this setup, particularly for computers with less than 2 Megabytes of real and virtual memory. The largest file processed contained 35,000 lines of survey and assay information and required 4 megabytes of virtual memory. Working with this size file slows down the time for the creation of plots and cross sections. Another independent system is more akin to a financial type of data base. It was installed in one Anaconda mine as part of the operation's inventory, warehouse, day-pay payroll, and purchasing data bases. It is a highly hardware-dependent system, in particular, IBM's CICS/VS (Customer Information Control System/Virtual Storage). This is a true relational data base that optimizes storage requirements, supports online inquiry, update, data entry, and data security. While this system has been tested and proven in accounting applications, it requires programming expertice in PL/I and other CICS utility programs. It is well suited for huge data bases (like the 35,000 lines of data), but cumbersome for small engineering files.

Jan 1, 1985

By J. Gordon Parr, D. H. Polonis

High purity alloys of titanium and iron, made by a technique of levitation melting, have been investigated with particular reference to martensite formation and decomposition in the hypoeutectoid range. A preliminary study has been made of the occurrence of the phase corresponding to the structure Ti2Fe. MANY of the previous investigations of Fe-Ti alloys have been made using Kroll sponge as a source of titanium; and the subsequent heat treatments to which alloys have been subjected has, on occasion, led to further contamination. Worrier,',' who suggested a part of the equilibrium diagram for the binary system, and Wallbaum and coworkers,3-5 who worked largely with iron-rich alloys, all used Kroll sponge. Van Thyne, Kessler, and Hansen,6 in their determination of the equilibrium diagram, used iodide titanium for alloys up to 30 pct Fe. Duwez,7 who measured the M. temperature of titanium binary alloys with many solute elements, used iodide titanium in all cases except in his work on Ti-Fe alloys for which he used Kroll sponge. The investigation of the supposed phase Ti2Fe by Rostoker8 nvolved the use of iodide titanium. A section of the constitutional diagram, after Van Thyne et al., is reproduced in Fig. 1. Frequently too much stress is placed on the effect of contaminants in equilibrium and nonequilibrium systems, but there is no doubt that titanium alloys are extremely susceptible to interstitial atoms. Consequently, the main purpose of the work to be described was to determine those features of phase transformations in pure Ti-Fe alloys that were considered of importance in commercial heat treatments. For, although commercial alloys may not be of high purity, the investigation of a system uncomplicated by traces of impurity is a desirable starting point. Another incidental feature, the occurrence of Ti2Fe, was also investigated. The entire study was carried out using powders obtained from alloy ingots, for diffusion reactions are often more rapid in small particles than in bulk specimens. The frequently adopted practice of ascertaining phase constitutions by X-ray analysis of powders, and relating these to the microstructures and mechanical properties of bulk specimens, is considered by the authors to be open to criticism. In the martensite reactions in the Fe-Mn system, for example, it has been shown- hat similar phase distributions in solid and powder may result in different hardness values and appearance under the microscope; and it is possible that similar anomalies might occur in the Ti-Fe system. Consequently, in order to

Jan 1, 1955

ERRATA-AUTHOR'S REPLY IN SEPTEMBER, 1970, JOURNAL: PAGE 52 I. Left half of the page, 4th paragraph, fifth line from the bottom: for 22 / 5 1/2 %, read 22 / 5 1/2 %. 2. Right half of the page, fifth paragraph from the bottom, third line from the bottom: for N(l - p), read N(1 - p)x. 3. Right half of the page, fourth paragraph from the bottom, second line: for: at time t after time zero, read: at time x after time zero. NOTICE TO ALL STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY The Institute offers each year for competition among Student Members of the Institute a prize, or prizes, should entries so warrant it, of up to the value of R100 to be awarded to the Student Member or Members who submit the best paper or dissertation on a topic appropriate to the interests of the Institute. In the case of Student Members who are in full time study at a university the dissertation or thesis which they may have to write in part fulfilment of their university curriculum may be accepted provided it is presented in a manner and on a topic suitable for publication in the Journal. The closing date for the receipt of papers shall be 31st December each year.

By White B

A novel approach is suggested for the solution of planning and development problems in the coal, mining industry. The formation of coal measures depends to a significant extent on sequential geological processes and events which are probably best defined in a "system of processes and responses." The great number of variables in such a system is a characteristic feature of geological environments. Research work over the past two decades, in particular, has successfully established analytical procedures for the identification and definition of relevant and irrelevant variables for mining developments in specific geological situations. Such situations are typifiable within the regional geological setting of coal deposits. Scale gaps can be bridged by reliance on common symmetrical attributes and pervasive geometric features. Depositional processes and their resulting attributes are responsible for the development of mechanically significant rockmass "defects" and anisotropies; such features have to be identified and assessed for the selection of colliery design criteria. It is suggested that the procedural frame- work of systems engineering analysis is a most appropriate tool for the assessment of those geological features that can influence the mechanical behaviour of the "floor-seam-roof" system in "high technology" mining operations of the future. It is anticipated that the overall emphasis of future mining systems will be toward the use of larger scale more highly productive methods and machines, with higher capital outlay but

Jan 1, 1987

By T. Schmidt, H. Assadi, F. Gartner, H. Kreye

Among all spraying processes, cold spraying has attracted a special attention in recent years, both as a coating - and more recently - as a rapid manufacturing technique. The interest in this process is mainly because of the fact that the deposition of spray material takes place at moderately low temperatures, and thus, oxidation and unfavourable microstructural changes can be alleviated. In this process, a highly compressed gas, flowing through a de Laval nozzle, accelerates the particles of the spray powder to high velocities of up to 1200 m/s. Although there is no melting of particles prior to impact on the substrate, cold-sprayed deposits can be denser and more tightly bonded as compared to the equivalent deposits produced by conventional thermal spraying methods. The present contribution focuses on this unique aspect of cold spraying. Modelling of particle impact, combined with various experimental observations, is employed to illustrate that bonding of particles and hence material deposition occurs through shear instability - associated with severe plastic deformation and localized heat generation - at the interacting surfaces of particles and substrate. The results of modelling also provide an insight to the influence of material and process parameters on the critical velocity and on the microstructural properties of cold-sprayed deposits.

Jan 1, 2006

Vein swarms in metamorphic terranes such as the Otago Schist Belt, New Zealand provide evidence of past hydrothermal flow systems leading to fault initiation and reactivation. A major episode of hydrofracturing and fluid redistribution occurred during early Cretaceous exhumation of the schist belt. As a result, presently exposed lower greenschist facies greyschists in NW Otago are pervaded by abundant quartz-filled hydraulic extension fractures with associated normal faults hosting quartz¦scheelite¦gold mineralisation. Once the effects of Cenozoic folding have been removed, a regional subhorizontal schist foliation contains an aligned array of subvertical hydrofractures striking NNW, striking parallel to a set of low-slip conjugate normal faults; the array extends over an area >1500 km2 and over a depth interval >5 km. The hydrofracture array comprises a mesh of interlinked extensional-shear and pure extension veins. These veins show mutually cross-cutting relations. Extensional hydrofracturing apparently preceded the development of major throughgoing normal faults. Low-displacement normal faults are infilled with laminated quartz (¦ scheelite) veins (

Jan 1, 2002

By M. M. Fine

Development of a process for winning copper from pelletized chalcocite concentrate without matte smelting and converting is underway at the Twin Cities Metallurgy Research Center, Bureau of Mines. The new route from concentrate to metal includes 2-stage fluid-bed treatment; pelletized concentrate (33 percent Cu, 7 percent S) is first desulfurized (to about 0.5 percent S) in an oxidizing atmosphere, and in the second stage the calcine is metallized by reduction with hydrogen. Thereafter, the reduced product plus 10 percent CaO is routed to a smelting furnace to separate metallic copper from the gangue. Recovery and the Cu content of the product at this point are in the 97-98 percent range. The metal must be refined to remove sulfur and iron to make wirebar copper. An important feature of the process is the pelletizing of the fine concentrate into mini-pellets prior to fluid-bed treatment, which has permitted shorter reaction time, decreased dusting, and facilitated subsequent processing.

Jan 1, 1970

By William Watson

Coal production in the United States in 2010 increased to a level of 960 Mt (1,085.3 million st), according to preliminary data from the U.S. Energy Information Administration (EIA), an increase of 1 percent, or 9.43 Mt (10.4 million st) above the 2009 level of 975 Mt (1,074.9 million st) (Table 1). In 2010, U.S. coal consumption increased in all sectors except commercial and institutional, while total coal stocks fell slightly for the year. Coal consumption in the electric power sector in 2010 was higher by 4.5 percent, while coking coal consumption increased by 37.9 percent and the other industrial sector increased by 7.1 percent. The commercial and institutional sector, which prior to 2008 had been called the ?residential and commercial? sector and is the smallest of all the coal-consuming sectors, declined by 3.1 percent in 2010. (Note: All percentage change calculations are done at the short tons level.) U.S. coal exports increased from the 2009 levels due mostly to higher demand for metallurgical coal, while coal imports decreased for a third year in a row. The increase in coal consumption for electric generation during the year was the consequence of improving domestic economic conditions further bolstered by a cold winter and warm summer in important coal-consuming regions. Preliminary data show that total generation in the electric power sector (electric utilities and independent power producers, including useful thermal output) in the U.S. increased in 2010 by 4.2 percent. Coal-based generation also increased, resulting in a 38-Mt (42-million st) increase in coal consumed in the electric power sector. Coal use in all the sectors other than the electric power sector increased by 13.9 percent to a level of 65.9 Mt (72.7 million st).

Jan 1, 2011

By Zhanjun Wang, Yongqi Sun, Mei Zhang, Zuotai Zhang, Min Guo

The role of fluorine on the viscous and crystallization behavior of CaO-SiO2-MgO-Al2O3-FetO-P2O5-(CaF2) slags were explored using the rotating cylinder method, non-isothermal differential scanning calorimeter (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. It was found that the viscosity slightly decreased with increasing CaF2 content. It was also found that CaF2 addition can promote the primary phase transformed from MgFe2O4 spinel to Ca3(PO4)F, which was beneficial to the enrichment of phosphorus. Additionally, the structure of the slags explained by X-ray photoelectron spectroscopy (XPS) and magic angular spinning nuclear magnetic resonance (MAS-NMR) were further analyzed, which was well in accordance with the above analysis.

Jan 1, 2016