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By Junji Shibata

Extraction behavior of Ti(IV) and other metal ions, such as Fe(III), Fe(II), Cu(II), Zn(I1) and Co(I1) from acidic solutions like sulphuric acid and hydrochloric acid was studied in order to recover titanium from the waste solution in Ti02 production. Extractant used was tri-alkyl phosphine oxide whose trade name was Cyanex 923. Then, a study was made of the idea of simulating a countercurrent multistage extraction system, using the results of batch extraction. The simulation was camed out on extraction and saipping behavior for a Ti(1V)-H$O,-Cyanex 923 system. From the simulation result., the optimum operating condition of the system was considered.

Jan 1, 1994

By C. F. Cornell, R. C. Emmett, D. A. Dahlstrom

FOR many years the disk-type and cloth-covered drum filters have found widest application in liquid-solids separation, which uses continuous filters. The disk type is less expensive, occupies less floor space per square foot of filtration area, and requires negligible down time for filter media changing. However, because filter cloth is billowed out by the blowback in the cake discharge, it is very short-lived if the scraper blades are set too close. Consequently cake weight is very important in assisting cake discharge, which normally necessitates a minimum cake thickness of 3/8 to ½ in. Also, the vertical position of the disks eliminates the possibility of efficient cake washing for removal of soluble values. The disk-type filter is generally limited, therefore, to applications that require no cake washing and form relatively thick cakes within the normal range of filter cycle times. The conventional cloth-covered drum filter is a more flexible unit, permitting wider variation in the percentage of cycle time devoted to cake formation, dewatering, or washing, as required by the application. Thinner filter cakes can be discharged because a horizontal line across the filter medium at the location of the scraper blade is equidistant from the edge of the blade at all points. The scraper blade therefore may be set a short distance from the filter medium or, where wire winding is not used, a floating scraper can be utilized so that the contour of the cloth can be followed. The drum filter is generally employed when there are difficult filtering slurries with resultant thin cakes or when cake washing to recover soluble values must be practiced. Difficulties sometimes encountered in continuous filter operation can be summarized in the following four categories: 1) Low filtration and/or washing rates due to blinding of the filter medium. 2) Poor cake discharge resulting from sticky cakes, filter medium blinding, or too thin a cake for the particular type of filter. 3) High filter media costs caused by short life and frequent down times for cloth changing. This results from blinding or from abrasion by the scraper blade when cakes are thin. 4) Blowback of filtrate at cake discharge because not enough air passes through the cake to purge the drainage area and filtrate lines during dewatering. To reduce or eliminate blinding tendencies several modifications have been tried, for example, cover-cleaning showers, blowback under the feed slurry, and snap-blow cake discharge. In many cases, however, this simply retards the rate of blinding, since the filter medium is kept clean at its outer surface only by these methods. As blinding usually occurs within or on the back of the medium, the operator is finally forced either to remove the cloth and scrub the medium intensively with a cleaning solution or acid-rinse it on the filter—all resulting in down time, short cloth life, and additional costs.

Jan 1, 1959

By Matt Sotirin

The Santa Fe train station and passenger rail platform were constructed in the downtown district of Fort Madison, Iowa, over a century ago. This landmark building and rail platform were in need of major renovations and rehabilitation in order to restore the site to a functioning railway train station. A multitude of key players from various public and private parties were involved in the design and construction of this project site. Part of the project consisted of constructing the passenger platform. The original design included helical piles to provide foundational support for the platform. Challenges occurred during construction due to the presence of an obstruction in the form of a poured concrete slab in the immediate area where the helical piles were to be installed. The contractor worked with the engineer of record and other consulting parties to value engineer the helical pile design and utilize self- drilling micropiles as a replacement to the specified helical pile system.

Oct 1, 2022

By Matti Hämäläinen

Outokumpu has developed a new chloride leaching process, HydroCopper?, for copper concentrates. The process utilizes the cupric ion as oxidant, which is able to dissolve chalcopyrite. After solution purification monovalent copper is precipitated as cuprous oxide, Cu2O, using sodium hydroxide. Copper product is produced from Cu2O by reduction, melting and casting. An essential part of the new process is chlor-alkali electrolysis, which regenerates the reagents used. All impurity metals are removed before Cu2O precipitation, because otherwise they would report to the copper product, impairing its quality. A multistage solution purification scheme has been developed consisting of firstly, chemical precipitation of impurity metals by pH increase, secondly, cementation of silver and thirdly, removal of trace multivalent ions using ion exchange. This paper describes the characteristics of solution purification in the HydroCopper? process based on the laboratory tests and pilot runs made by Outokumpu Research Oy.

Jan 1, 2003

The metallurgical works of the Electrolytic Zinc Company is situated on the Derwent Estuary, approximately five miles north of the city of Hobart and near a relatively dense housing area. Zinc concentrates, consisting chiefly of zinc and sulphur, have been roasted at Risdon for 53 years;- recently at rates of 1, 100 tons per day. The zinc content of the ores is converted to zinc calcine (ZnO), which is a dusty material. The calcine is leached with acid to form zinc sulphate, which is then electrolysed to make zinc. The sulphur is oxidised during roasting to sulphur dioxide, part of which is converted to sulphuric acid and part is dissolved in estuarine water which is then discharged to the Derwent Estuary. Photographic slides were exhibited showing the unaffected green flora of the nearby hills, of clear exit stacks, of green lawns, and of a w ll lrcnt nines hnlP anlf nniir.qa within the Wnrka hnnnrla_rv_

Jan 1, 1971

The Reconstruction and Research Division of the United States Council of National Defense has, up to date, prepared two reviews on the above subjects: one covers foreign countries and the other covers the activities in the States. These reviews contain information appearing in various Governmental and public periodicals. While the information on foreign countries is necessarily incomplete and fragmentary, its summation is perhaps the most complete work of this kind so far accomplished. The information from the states consists mainly of bills and ordinances introduced in the state legislature, municipal councils, legislature committee reports, programs suggested by governors, and other state and local officials and local organizations It is realized that a good deal of this information will be useful to engineers studying conditions in the various states, and especially to those who want an insight into the general condition in all the states. For instance, the reconstruction problem in each state involving highway, reclamation, buildings, etc., are covered in detail.

Jan 8, 1919

By Rodrigue Karam

An assessment of the geotechnical conditions at the Manhattan Cruise Terminals (Piers 88, 90, 92 & 94) was conducted after excessive settlement and structural distress was reported at Pier 92. The piers are located on the Hudson River along the west side of Manhattan, New York. The following paper focuses on the investigation and analysis performed on Pier 88 located at the western terminus of 48th Street. The pier is supported by approximately 2,500 timber piles bearing on soft organic silts and clays. The first portion of the analysis consisted of an offshore field investigation and laboratory testing to classify the subsurface soils within the project area and estimate the geotechnical capacities of the timber piles. Additionally, a settlement analysis including consolidation and negative skin friction analyses was performed to evaluate existing settlement levels. Axial and lateral analyses were performed to develop the soil springs (p-y, t-z, and q-z curves) necessary for the structural analysis.

By Anne Lemnitzer

Full-Scale cyclic field testing was performed on a 3x3 pile group consisting of nine cast-in-drilled-hole (CIDH) reinforced concrete shafts and a comparable single-shaft in order to investigate group interaction effects, derive p-y curves for reinforced concrete fixed head piles and to validate currently available p-multiplier models. The piles are identical in diameter of d=2 ft and were tested in similar soil conditions. The single pile as well as in three piles within the pile group were instrumented with internal sensor instrumentation to record pile curvatures. External instrumentation was used to control and measure the lateral displacement of the specimens. Experimental studies were supported with analytical models to enable comparisons and offer design recommendations. All test specimens were tested to structural failure and group interaction factors ranged between 0.8 at small displacement levels and increased towards unit near structural failure. A set of p-multipliers was found to reproduce an accurate fit to the available test data.

Jan 1, 2010

By Frigyes Egerer, Pál Bárczy

Introduction Charles III, Holy Roman Emperor and King of the Austro-Hungarian Monarchy, established one of the first mining schools in Europe on June 22, 1735, in Selmecbanya (Schemnitz in German and Banska Stiavmica in Slovakian). The old city, built around the ancient gold mines, is shown in a contemporary engraving in Fig. 1. Charles' historical decree consisted of 13 chapters and included: the deed of foundation, the definition of grants, instruction for educational policy and curriculum, disciplinary rules, and the appointment of personnel. The first professor of the school, Samuel Mikoviny, gave his first lecture the same year, in December 1735. The 250th anniversary of the establishment of the School of Mines was celebrated Sept. 2-4, 1985, in Miskolc. It was attended by representatives of other Hungarian and of several foreign technical universities. A silver medallion (Fig. 2) was issued to commemorate the occasion and a series of lectures

Jan 6, 1986

By P. Stantke

Glue, thiourea and chloride are the common reagents which are used in copper electrorefining to achieve fine-grained and smooth copper deposition. While thiourea and chloride are clearly defined chemical substances, glue is a natural product consisting of a mixture of amino acids in different constituent parts. The amino acids are continually degraded in the electrolyte by hydrolysis until they finally become completely inactive. This effect is well-known, largely constant and balanced by the continuous dosing of glue. In contrast, the behaviour of glue in the batch container is not always foreseeable. The glue can become partly or completely inactive by contamination with acid or bacteria, for instance. Usually this is not noticed, and partly or fully inactive glue is added to the electrolyte over a longish period, with the result that the copper growth is significantly impaired. Examples from operational practice show that, with the help of the CollaMat system, partly or fully inactive glue batches can be quickly detected.

Jan 1, 2007

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

The Lead-Line Update held in conjunction with the 1977 SME-AIME Fall Meeting in St. Louis provided sessions on mining, mineral processing, extractive metallurgy, and economies to brief the record on the industry's activities and developments since the 1970 World Symposium on Lead and Line convened, also in St. Louis. Changes in the industry since 1970 have not been profound, notes the program committee, consisting of D. O. Rausch, F. M. Stephens, and B.C. Mariacher, cochairmen; and H. L. Clifford, S. C. Fall), and M. Snedeker. However, various environmental and conservation factors have had a direct impact on process consideration and operating practice; the result has been new mines, improved technology, and changing market opportunities. The general consensus of the participants is that the future for the Lead-zinc industry looks promising as new applications are found and new products resulting from intensive research reach the marketplace. The highlights of the HS technical papers presented at the 1977 session follows.

Jan 11, 1977

By M. Giunti, R. Hampson, S. Gray, P. Kapoulitsas, J. Clark

In 1997 Pasminco's Port Pirie Lead Smelter began a modernisation of its lead and precious metals refinery operations. Driven by the anticipated closure of its Broken Hill mine, the new refining process replaced the locally developed continuous process, which had been in operation since the 1950's. Commissioning of the new plant was staged, beginning in late 1997, and finishing early in 1999. The new plant provides for batch refining of lead, and the use of vacuum induction retorting and bottom blown oxygen cupel technology in the silver refining area. The project has resulted in an increase of lead production capacity of 11% and allows the treatment of a wider range of concentrates than was formerly possible. The most significant change has been to double the smelter's silver capacity to over 400 tonnes per annum. This paper describes the successful implementation and optimisation of the new refinery, which is now consistently meeting design capacity.

Jan 1, 2000

By Nancy C. Shaver, Alan Tapp

Leach pads of 272,000 tonnes (300,000 st) and 910,000 tonnes (1,000,000 st) with associated operating ponds have recently been constructed on sidehill locations with up to 20 percent slopes. The larger pad was designed in anticipation of ore heights up to 30 meters (100 feet). This paper describes site investigations and civil engineering design as well as construction experience associated with development of these pads. The leach pads were underlain by a double liner system consisting of 2 mm (80- mil) HDPE over compacted fine-grained tailings, with an intermediate leak detection layer. Both sand and geotextile drainage layers were used. Pad slopes were limited by the factor of safety against sliding on the HDPE liner. The sites for the facilities had been substantially disturbed by prior mining and construction activities. Natural conditions included peat layers and locally swampy ground. Site preparation included french drains to lower the water table and stripping of unsuitable subgrade materials.

Jan 1, 1987

My paper presents a discussion of the legislative and departmental requirements in connection with the acquisition of exploration rights for minerals (other than petroleum and coal) in the Independant State of Papua New Guinea, the Solomon Islands and Queensland and he practical problems associated with land entry and land ownership associated therewith. In general there are many similarities in the methodology and philosophy behind the legislation in each country and the contractual requirements established thereby between the exploration company (the explorer) and the government and the mines department or equivalent in each place. There are also a number of differences. I have prepared the paper on the basis that my audience will largely consist of -experienced explorers and the paper is intended to act as a brief refresher and a guide to the philosophy and the practicalities behind the legislation and practices in ground entry in each case. I will deal in turn with New Guinea, the Solomon Islands and then Queensland.

Jan 1, 1987

By M. Prasad, G. M. Rao, A. K. Majumder, T. C. Rao

Froth flotation was employed to beneficiate a lean-grade siliceous rock-phosphate ore containing fluorapatite, the phosphate-bearing mineral. The main gangue minerals were quartz, iron oxides and aluminum oxides. After the rougher stage, four cleaning stages were required to upgrade the ore. The liberation size of the phosphate mineral was below 200 mesh, The reagent scheme consisted of commercial-grade sodium silicate and sodium oleate. The effect of reagent dosages, number of cleaning stages and pulp density on the efficiences of separation were studied systematically. A flowsheet was proposed for the processing of low-grade siliceous phosphate ore containing 12.1% P2O5, 55.36% SiO2 and 15.45% CaO. The flowsheet provided a useable phosphate concentrate containing 34.18% P2O5 and 14.20% SiO2 with a P2O5 recovery of 70.4% (the weight yield was 25.0%).

Jan 1, 1999

By J. Donald Rimstidt, Jeanette K. Jerz

Acid mine drainage is a major environmental problem worldwide. A key to remediating this problem is understanding the rate and mechanisms of the complex, multistep pyrite oxidation reaction under geologically relevant conditions. Because many waste piles are not submerged, a large amount of pyrite oxidation actually occurs in air. We have designed a Barcroft-manometer reactor to measure the rate of pyrite oxidation in air as a function of relative humidity and oxygen partial pressure. The reactor consists of two chambers joined by a manometer. Each experiment occurs at constant temperature, initial oxygen partial pressure, and relative humidity, although these variable can be changed between runs. Oxygen consumption was measured and pyrite oxidation rates were calculated from those data. Initial data indicate that rate of pyrite oxidation by oxygen in humid air is much faster than the rate of oxidation by oxygen in solution. The rates determined by this study can be used to develop better remediation techniques for acidic mine waters.

Jan 1, 2000

By Reinhard Fischer

The consumption of lead for batteries in some western countries and Japan amounts to 870,000 T. annually. Battery life is 2-3 years. Therefore after a short time a considerable quantity of lead flows back to smelters. The production of lead from scrap batteries is discussed from the following points of view: 1. Separation of the acid contained in the batteries. 2. Separation of the components which are free of lead from the components containing lead, e.g. cases, separators. 3. Separation of metallic lead from lead compounds. 4. Avoidance of manual-work. A process has been developed and perfected at a plant, which began operation in 1965. The procedure consists essentially of the following steps: 1. Breaking the cases and removing the acid. 2. Crushing the batteries in an impact mill. 3. Screening off separators. 4. Separation of slurry. 5. Gravity separation of metal and organic material. The plant has a one-shift capacity of -24,000 T. batteries/year.

Jan 1, 1970

By Robert Longyear

IN, diamond-drill work, a true sample consists of all the material cut by the bit-both core and cuttings. As the recovery of this sample is the object of diamond drilling, the utmost care should be taken to secure it. Speed of drilling and low costs are of little value if an inaccurate sample is obtained. The engineer in charge must study his material and lay out the plan of sampling, and then see that the drill runner follows his instructions; for the runner may be more interested in obtaining a large footage than in developing accurate methods of sampling. FIG. 1.-CORE BOX. When the core has been removed from the core barrel, it should be placed in a core box in the exact order in which it is taken from the ground. This box, Fig. 1, is usually a shallow tray 4 or 5 ft. (1.2 or 1.5 m.) long, with partitions running lengthwise between which the core

Jan 12, 1921

By Toshihide Takenaka

Improvement of corrosion resistance of Mg metal by addition of rare earth metal (RE) was studied, and the effect of surface oxide layer with RE was investigated. The corrosion resistance of Mg was remarkably improved by adding a small amount of RE, and the suitable RE content was clarified. The corrosion resistance of Mg was particularly bettered by conversion coating using a solution including both RE(NO3)3 and Mg(NO3)2. This result indicates that the surface oxide layer consisting of both Mg and RE gives good corrosion resistance to Mg metal. In this study, direct electrodeposition of Mg metal containing RE was also tried in molten chloride with RE chloride, and it was shown that electrolysis could be performed stably. The RE content in the deposited Mg metal was depended on the concentration of RE chloride in the bath and the cathode potential, and Mg metal containing the suitable RE content for its corrosion protection was obtained easily by direct electrolysis.

Jan 1, 2006