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By A. Ahmadieh, J. E. Dorn, Jack Mitchell

A detailed investigation of the disloccrtion mechanisms controlling prismatic, slip in a solid solutions of magnesium containing up to 15.9 at. pel Li revealed that low-temperature prismatic slip is controlled by the Peicrl's mechanism for all alloy compositions. At higher temperatures slip in the 7.9 at. pet Li alloy was found to follow the diclates of the cross-slip mechanism from basal to prism planes, while the higlier-lilhium alloys exhibited an athermal dejormation process which might be due COARSE-GRAINED polycrystalline aggregates of distilled magnesium exhibit very limited ductility at low temperatures.' The ductility of polycrystalline magnesium, however, is much improved by solid-solution additions in excess of about 8 at. pct to shot-range ordering. The major effect of lithium additions on the low-temperature Shear] stress. for prismatic slip appears to be due to its efftct in lowering the Peierl's stress whereas (1 increase in the shear stress with increased lithium conlent at higher temperatures might he due to short-range order strengthening. Additions rip to 7.9 (at. pel Li appear to have only minor effects on the slackiug-jaidt energy. Li.2 Although the relative amounts of basal slip and twinning are not materially altered by such alloying, a substantial change takes place in the relative amounts of prismatic slip. Whereas prismatic slip is negligible and limited to regions of high stress concentrations in the vicinity of the grain boundaries in pure magnesium, extensive prismatic slip over entire grains occurs in the higher lithium content alloys. Furthermore, as the lithium content is increased above 8 at. pct, the flow stress for polycrystalline aggregates decreases. Comparison of the single-crystal data on pure magnesium for basal slip by Sheely and Nash3 and those for prismatic slip by Flynn, Mote, and Dorn4 indicates that the critical resolved shear stress for prismatic slip is much above that for basal slip.

Jan 1, 1965

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

By Lee Nichols

The Oil Sand Industry in northern Alberta, Canada, disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called Consolidated Tailings or Composite Tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities. Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are long-term stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface. The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process.

May 1, 2004

By R. K. Mehta

A review of the literature reveals that methods for simulating the coupled behavior of size reduction and liberation are limited to binary mineral systems containing one composite particle class. The aim of this paper is to describe the development of a mathematical model to simulate such behavior for binary and ternary systems containing multiple classes of composite particles. A modified Levenberg-Marquardt algorithm and a finite difference Jacobian are used in conjunction with the developed model and a set of constrained equations to estimate all kinetic parameters. This estimation scheme is validated for a binary ore (sphalerite-dolomite) with five composite particle classes using experimental data.

Jan 1, 1989

By Tumilty JA, Douglas WD

With a view to characterising activated carbons with respect to their ability to adsorb gold from cyanide solutions, an attempt was made to establish correlations between the equilibrium capacity constant of the activated carbon for gold (k value) and five other parameters. These parameters were percentage ash content, iodine number, methylene blue value, surface area, and pH respectively. Twenty four different proprietary brand activated carbon products were examined, the correlations being established by means of linear regression analysis. It was shown that a significant correlation only existed between k and pH value. This was interpreted in terms of the presence of oxide complexes on the activated carbon surface. Further test specifications as developed at the Anglo American Research Laboratories are also outlined with a view to the selection of activated carbons suitable for use in' a carbon-in-pulp operation. Methods for assessing both the capacity and the kinetic response of carbons for gold adsorption are presented, while the measurement of attrition resistance, particle size distribution and moisture and solubles content is also outlined. The measurement of the capacity constant for gold adsorption together with attrition resistance are considered to be necessary in the initial selection of a suitable carbon.

Jan 1, 1982

By Karsten Hagenah, Tor Jensen, Jens Laugesen, Øyvind Fjukmoen, Lucy Brooks

"The methods and technologies to be used for environmental monitoring of seabed mining activities are a key issue. Due to the large water depths, there are special challenges with respect to the monitoring equipment that is suitable. DNV GL has built up substantial experience of environmental monitoring from oil & gas projects in deep waters in the Norwegian Sea.Monitoring equipment and experiences from the oil & gas sector can to a large extent be applied to seabed mining.BackgroundThe International Seabed Authority is currently developing an environmental management strategy for the Area (ISA, 2017) as a part of the work on the regulations for exploitation for mineral resources in the Area.The draft environment strategy contains provisions related to monitoring and reporting of the activities. An Annex (Annex III) of the draft document describes the format and content of the environmental management and monitoring plan.The monitoring plan should contain, inter alia: ?Technology to be deployed.?Monitoring frequency of respective elements/components of the Marine Environment.?Monitoring procedures required to implement the Monitoring programme.?Details of the environmental monitoring stations across the Environmental Impact Area.?Monitoring specifics e.g. water quality; sedimentation rates; sound; plume extent; etc., as well as relevant Environmental Targets.?Monitoring of Mining Discharges.?Processes for Monitoring reviews and Environmental audits."

Jan 1, 2017

By Charles A. Ramsey, Kathleen S. Smith, Philip L. Hageman

We developed a statistically based strategy for sampling the surficial material of mine-waste dumps for use in screening and prioritizing historic dumps on abandoned mine lands. This sampling strategy entails the collection of a representative composite sample from individual dumps and allows for regional or watershed-based assessments. One 30-inment dump-composite sample collected using this sampling strategy contains as much information, relative to average value, as 30 individual grab samples at 1/30 of the analytical cost.

Jan 1, 2000

By Henry J. Welge

The approximate methods which are now in use for calculating oil displacement from reservoirs by gas-cycling or gravity-drainage at constant gas pressure, or by water flooding, make use of fundamental relationships derived by Leverett' and Buckley and Leverett.2 The mathematical equations needed are derived by applying Darcy's law to the flowing phases, and by material balance considerations. ln general, any treatment of this type gives. for any particular exploitation time considered, a plot of oil saturation against distance in the reser-voir. The oil recovery must then be obtained by integrating in some manner the area under the plot. A useful analytical method has been derived for computing the average saturation, and hence the oil recovery. Use of this method simplifies the calculations because it makes unnecessary any numerical integrations. and even the saturation distribution plots are not needed. A further advantage of the method is that knowledge of the relative permeabilities is required only for a limited and intermediate saturation range. In both the Buckley and Leverett method and the method discussed here, a linear sand section is assumed, and in the case of gas drive the gas pressure is assumed sufficiently constant both with respect to reservoir position and time so that changes in gas density. solubility, or reservoir volume factor are negligiklle. Thus, the exploitation contemplates oil displacement as by an immiscible phase. Examples are given to illustrate how the new method can be used. INTRODUCTION AND THEORETICAL BACKGROUND This paper treats a simplified method for computing oil recovery when the oil is displaced, from the reservoir sand by a fluid which, within the limits of accuracy desired, can be assumed to be incompressible and immiscible with the oil. The method makes use of two basic relations originally developed for the case of water displacing oil. However, the case of gas displacing oil saturated with gas at a constant (or nearly constant) pressure may also be considered a displacement by an immiscible fluid. This is possible for the reason that the concentration of the gas in the oil never changes if tile pressure is fixed. consequently, any additional free gas must remain undissolved in the oil, and so must act essentially as an immiscible phase. For convenience, the cape of gas drive will be considered first. Both of the two basic relations needed refer to a linear reservoir, or one which may be somewhat idealized so that a constant cross-section is exposed to fluid flow. Further, the displacing phase is injected at one end, or face; of the reservoir, while the produced fluids are understood to emerge at one point only. which is the opposite face of the reservoir. As indicated in Fig. 1, the reservoir may he inclined by some angle 8. The first of the required equations may be derived by applying Darcy's law to both displacing and displaced phases, and subtracting the two equations. The result for water drive has been given previously, as Equation (13) of the reference by

Jan 1, 1952

By L. L. Handy

Two equations are compared for calculating imbibi-tion rates of water into porous media. A linear relation was found to apply when the square of the volume of water imbibed was plotted against time for water imbibing in natural rock materials. The effect of adsorbed organic materials on surface wettability was determined from measurements of rate of imbibition, water saturation and water permeability. INTRODUCTION An understanding of the mechanisms by which water displaces oil from porous media requires an understanding of the role of capillary forces in the displacement process. The capillary forces are determined by properties of the water-oil-solid surfaces. Consequently, some measure of the surface properties of reservoir rocks is necessary if displacement behavior in oil reservoirs is to be predicted from laboratory measurements. Several experimental procedures have been proposed to assign quantitative wettability indexes to reservoir rock surfaces. The most recent of these proposals are those of Bobek, Mattox and Denekas' and Amott.' These indexes are designed to show a continuous variation from the preferential oil-wet to the preferential water-wet systems. They require measuring some property of the rock which is a function of surface wettability. The quantities are measured on unaltered core material and compared with values obtained for known oil-wet and water-wet extremes on the same material. These methods are useful but are semi-empirical in nature. They have the disadvantage that the measured quantities may be functions of other variables in addition to surface wettability. Some understanding of the behavior of water-oil-rock systems may be obtained from studies of the simpler water-air-rock systems. Surfaces of a given wettability are more easily maintained for the latter. Also, certain approximations can be made for the flow of water and air which are not justified for water-oil flow. The theoretical and experimental work discussed in this paper is part of a study of the role of capillarity in the dynamic displacement of air by water. The expec- tation is that observations for the water-air system will lead to generalizations which are applicable to water-oil systems. THEORY Imbibition is defined as that process by which one fluid displaces another from a porous medium as a result of capillary forces only. Differential equations have been derived to describe the displacement of oil by water during imbibition, but these equations have not been solved.".' With certain assumptions, however, solutions are possible for water-air imbibition.

By Markus A. Reuter, Jacques J. Eksteen

"The modelling of bath type furnaces tends to be either fundamental in nature or total empirical ""black box models"". While models of the first kind are robust, they tend to lack accuracy, in cases where they are to be used for process control, and may take an overly long in development time. On the other hand, black box models tend to lack robustness of prediction for all circumstances and tend to be limited to interpolate based on historical data. While this may very often provide short-term accuracy, the models may have problems with stability in the long term. Moreover, the model structure may not reflect any of the fundamental properties of the system and remains opaque to fundamental analysis. The aim of the model development is in obtaining a model that have robustness, high accuracy, a short development time and which is adaptive to a changing environment. The models are specifically developed for on-line decision support or control of furnaces. The modelling approach is evaluated for a chromite bath smelting furnace. The role of systems analysis, mass balance smoothing, thermodynamic analysis are integrated into one generic algorithm for bath type furnaces. Not only are fundamental process relationships such the mass and energy balances satisfied through a scientific method of data reconciliation; the proposed modelling approach allows adaptive prediction, the first step towards predictive control or metallurgical decision support.It is shown that neither an ARMAX model only, nor a purely equilibrium model only, could predict the dynamics of the process very well. However, a combination of the two approaches more than doubled the accuracy as measured by the R2. It was noted for carbon dissolved in the alloy, that the improvement in R2 in using a hybrid modelling approach was more than the sum of the R2 of the individual traditional approaches. Similar improvements in modelling performance were noted for all other species.It shows further that process dynamics may totally overshadow the effect of thermochemical equilibrium (even when the thermochemical equilibrium prediction includes the recycled alloy and slag heels as additional feeds). The exclusion of process dynamics therefore leads to erroneous results."

Jan 1, 2003

By Ronald K. Frobel, Christopher J. Wienecke

Geomembrane systems and associated geosynthetics such as geotextiles, geonets, geogrids and geocomposites have been used in precious metal heap leach and tailings facilities for many years. Geomembranes have been used in the heap leach process in pad design and solution recovery ponds as well as associated collection channels as the primary liquid barrier to contain and collect metal bearing leach solution. Geomembrane systems offer an effective, low cost alternative to other containment methods such as compacted low permeability soils, asphalt or concrete. In the 19BO's, rigid High Density Polyethylene (HOPE) liners were used to a great extent with a gradual transition to the use of the more flexible Very Low Density Polyethylene (VLDPE) and Polyvinyl Chloride (PVC). These three geomembrane systems have been used successfully in precious metal heap leach solution containment. Predominant material thicknesses have been 30 and 40 mil for PVC, 40 and 60 mil for HOPE and VLDPE. Variants in recent years have included roughened HDPE and VLDPE to provide higher surface friction characteristics, as well as newer polymer materials such as polypropylene. In addition to providing an economical method for providing enhanced solution recovery, geomernbranes are also providing the primary liquid barrier for prevention of groundwater contamination. Because heap leach solution chemical components and dissolved metal constituents are classified as toxic substances, they are subject to environmental regulation. Many regulatory agencies are still developing guidelines for heap leach pad design, however a geomernbrane liner system is often used as a single liner or in conjunction with other materials to form composite double or even triple lined systems. "Other" materials can include alternate layers of drainage aggregate, geotextiles, clay layers and other geomembrane or geocomposite layers.

Jan 1, 1993

By D. W. Dew, D. M. Miller, P. C. van Aswegen

The bacterial oxidation (BIOX®) process for pre-treatment of refractory ores for gold recovery is marketed by BIOMIN Technologies S.A. The process was originally developed by GENMIN who are still providing testwork, design and commissioning assistance to BIOMIN. This process offers an alternative to the more conventional roasting or pressure oxidation techniques with the following advantages: • Greatly reduced capital costs for small to medium size plants. • A relatively flexible and easily controllable process requiring relatively unskilled labour for operation. • Improved gold recovery. • A process that is environmentally friendly. The principal disadvantage of bacterial oxidation is the relatively slow kinetics compared to pressure oxidation and roasting, a plant residence time of 4 to 5 days typically being required to obtain complete liberation of gold from refractory sulphide minerals. Bacterial activity is also slow to recover from disruptions such as air supply failure or contamination by toxic species such as cyanide. Optimum plant performance depends on judicious management and sound training of operators.

Jan 1, 1993

By L. M. Klimov

In recent gears in the coal industry a great deal of attention is attached to the questions of elaborating and introducing the problems of planning and management and, first of all, in the sphere of mine production. The basis for planning of mi- ne production is complexes (sets) of problems for planning the development of mining operations based on different time periods, ensuring the follow-up of changes of mine productive capacities. Complexes of problems for planning, the development of mining operations at existing underground and surface mines within the OASUugol system (Coal Industry-wide Automatic System of Management) are aimed at ma- king decisions close to optimum, i.e. general lay-out of panels, blocks and pillars; transport and ventilation networks; schedules for working out parts of mine take; coordinated mining operations with limited labour and material resources; control of mining operations and ultimately maintaining productive capacities of existing mines at the required level.

Jan 1, 1979

By Edward Marszalek, Boleslaw Firganek

The paper deals with a computer method and algorithm of optimization of the rescue routes for the endangered staff in the case of fire in a given place of the mine. The adapted method is based on the objective function and realizes the algorithm of the shorest path with weighers assigned to it. The objective function is so defined that it reflects possibly all the hazards and difficulties arising during a fire in the mine. The algorithm is enhanced by an empirical formula for calculation of the smoke zone as result of a mine fire. The presented results of computations of optimal routes for several simple examples using the canonical scheme of the mine network and simulated fires are satisfying and prove the method, the algorithm and the coded program to be correct. The program will be a part of the software library of the mine ventilation engineer. The data for the program will be updated on-line from the fire detection systems.

Jan 1, 1989

By H. I-Lieh Huang, O. D. Sherby, J. E. Dorn

RECENT investigations1-4 have suggested that the total plastic strain, C, for high temperature creep under a given stress can be correlated by means of a temperature-compensated time, te- where t is the duration of test, e is the base of natural logarithms, aH is the activation energy for creep, R is the gas constant, and T is the absolute temperature. A typical set of data on which this deduction was based is given in Fig. la. Inasmuch as the e-in t curves for the various temperatures are identical except for their displacement along the In t axis where f and are appropriate functions. If the increase in creep rate with an increase in temperature is exclusively ascribable to a single process involv- ing thermal activation, (T) should equal RT and therefore it = constant [2] where ?= te Assuming the validity of this relationship, ? = ?2 at the same strain, or where the subscripts refer to two alternate test conditions.

Jan 1, 1957

By D Purdy, K Wilkinson, P Blake, M Fitzell, J McLellan, L Feltrin, O Dixon

The northern Drummond and Bowen basins region represents one of AustraliaÆs most prospective areas for epithermal vein and stockwork style gold deposits, with both low and high sulfidation epithermal mineralisation known in the region. 3D-GIS reconstructions, numerical and probabilistic modelling (UDEC, FLAC 3D and WofE) are used here to develop a better understanding of the controls operating on the mineral systems of the region and are aimed at enhancing predictive capabilities. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By R. Singh

The paper presents the results of characterization and beneficiation studies carried out on a lean grade tungsten ore sample from Degana, India. Basically, three different routes, involving gravity separation, magnetic separation, and froth flotation were studied for concentration of the sample by physical and physico-chemical methods. Considering the low recovery by physical methods, efforts were put in to produce a tungsten concentrate by physical methods suitable for subsequent hydrometallurgical recovery of tungsten as ammonium para-tungstate. This strategy proved quite helpful in minimizing the losses of tungsten in tailings. Based upon these studies a novel integrated technological process flow-sheet was developed for the exploitation of lean grade tungsten ore deposit of Degana, India. Keywords: lean tungsten ore, characterization, beneficiation, gravity and magnetic separation, hydrometallurgical extraction, integrated process route

Sep 1, 2012

Coal fly ash and flue gas desulfurization (FGD) sludges can be returned to mine pits, fills and revegetation zones in Virginia by regulation if (and only if) a positive beneficial use can be shown. Utilization of alkaline fly ash for control of acid drainage from pyritic coal processing waste piles, and use as a soil amendment for revegetation, are the two dominant beneficial uses proposed over time. Both applications must be controlled by the basic chemical properties of the ash proposed for utilization. Currently, public concerns over long-term As and Se leaching from various applications are increasingly driving regulatory options for mine site utilization. Many fly ash materials are relatively low in inherent alkalinity or neutralizing ability, and certain ashes are actually acidic. Failure to add sufficient total alkalinity will result in strong acidification of the ash utilization zones, stripping heavy metals like Mn, Zn and Cu from the fly ash matrix. Similarly, if alkaline ash is loaded into non-acid forming coal wastes at high rates such that leachate pH is > 9.5, significant leaching of As and Se has been documented in large scale laboratory leaching columns. Utilization of fly ash and FGD as a mine soil amendment for revegetation is based upon combined liming and water holding capacity benefits, however, levels of soluble salts (primarily sulfate and borates) limit one-time application rates to 100 Mg/ha or less.

Jan 1, 2006

By Ron M. Canon, John M. Begovich

Chromatography, ion exchange, and other techniques based on the interaction of solutes with solid phases offer versatility, high resolution capabilities, and near-universal potential applicability for the separation of valuable constituents in liquid solutions. The expense associated with obtaining reasonable throughput for these separations has been the only, albeit overwhelming, obstacle preventing widescale use of these methods. Attempts to devise continuous (cheaper) systems have previously resulted in moving, or simulated moving, beds of resin with complicated valving and timing sequences. These disadvantages, plus technical problems associated with the disturbing effects of non-plug flow and reduced resolution of moving versus packed beds, severely limit applicability of these systems. Over the past decade a new device has been developed that overcomes many of these problems. It utilizes a slowly (less than one revolution per hour) rotating annular bed of sorbent material with fixed-feed inlet and product withdrawal points. Numerous units of various diameters and lengths have been fabricated and operated, and a parallel effort has developed a satisfactory theoretical treatment of the device. Several simple control systems have been incorporated to thoroughly demonstrate the simplicity of operation, even for multiple products and multiplecarrier flows. This device has been developed using several metal solutions and has demonstrated its power with some of the most difficult, including the zirconium-hafnium, separations. Design equations are available for sizing units based on simple laboratory data and have been tested for units as large as 18 in. in diameter.

Jan 1, 1985

By K. Y. Haramy

This report describes the development of an equation for predicting the crushing strength of 2-inch (5.08-cm) cubes of coal from point load tests made on irregular lumps. The equation was developed from point load and cube crushing strength tests performed on coal samples from six Western U.S. coal seams. For the six coals tested, the means of the point loads [(P)] in kg at failure were approximately proportional to the deans it the distances [(V)], in cm between the platen points for lumps in the 2 to 10-cm size ramie. This finding is at variance with results of tests on other rock types reported in the literature, which tend to show that P is proportional to D2 , as is normally assumed (in theoretical grounds. [The average crushing strength of a 2-inch (5.08 cu) cane for each type of coal was plotted against the log 10 of the slope of the P vs D plots, AP/AID . A straight line was fitted to these plots. The equation of the fitted line is cr = 1.72 x 10 4 10gK -2.10 x 10 4, where Cr is re estimated 2-inch (5. 08-cu,) cube crushing strength of the coal in psi and K is the scope of the straight line fitted to a plat of P v D for the same coal.]

Jan 1, 1982