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By I. Gaballah

Spent hydrorefining catalysts may contain 4 to 6 % of COO and/or NiO, 8 to 16 % of Moo3 and up to 10 % V205 generally supported by alumina. Raw samples are roasted in order to eliminate carbon, sulfur and hydrocarbons contained in the spent catalysts. The roasting optimum temperature and time are 500 "C and 7 hours. Selective chlorination of roasted samples with Cl2 + air, Cl2 + N2 and Cl2 + CO is investigated in order to recover the valuable metals. Depending on the chlorination it is possible to recover more than 80 % of the Ni and Co about 95 % of the Mo and up to 80 % of vanadium compounds. Cobalt and nickel chlorides are obtained by leaching the chlorination residues' by acidified water. Molybdenum and vanadium chlorides and/or oxychlorides are obtained by selective condensation from the vapor phase. The chlorination of the catalyst support, Al2O3, can be limited to less than about 5 %. Besides the reaction temperature and time, the oxygen partial pressure of the chlorinating gas mixture appears to be the key factor for the reactions' selectivity.

Jan 1, 1993

By M. L. Liu

This work reports the results about the determination of mean activity coefficients and relative partial molar free energies for copper sulfide mineral bioleaching solutions by potentiometric method at 25ºC. The experimental potentiometric data were obtained by combining a solid state membrane-cupric ion selective electrode (Cu2+ ISE), containing a KNO3 filling solution, and an Ag/AgCl electrode. The measurements were performed in different series of copper sulfide mineral bioleaching solutions. The non-ideal behavior of the system was described on the base of the Pitzer ion-interaction model for mixed salts. Meanwhile, the relative partial molar free energies of bioleaching solution were investigated. The determination of the thermodynamic properties offers a basic data for the study of copper sulfide mineral bioleaching solutions.

Jan 1, 2014

By W. de Bruijn

Differential reduction and expansion or shrinkage of hematite under the influence of intimately associated foreign oxides may be a source of stress formation and sinter degradation during blast furnace reduction. To study specific effects, synthetically pre-pared hematite powder evenly doped with 1% by weight of several elements present as oxides, was pressed into tablets and sintered at high temperature prior to reduction. Continuous thermo-gravimetric and dilatometric analyses were per-formed on the sintered tablets as these were being subjected to reduction under simulated blast furnace time/temperature/gas composition conditions up to 1183 K. These findings were coupled with observations on the microstructure of tablets removed from various stages of the reduction process.

Jan 1, 1988

By B. Rai

Aluminum is produced by the Hall-Héroult process, which involves passing a current through a molten mixture of alumina dissolved in cryolite (Na3AlF6) to reduce the alumina to aluminum. This process occurs in an electrolytic cell comprising a steel shell lined with a carbon cathode and refractory bricks. After a certain period of operation, the carbon cathode deteriorates and is removed from the cell along with the refractory bricks. These removed materials are referred to as spent pot lining or ?SPL?. Typically, 30 Kg of SPL waste is generated for every ton of Aluminum produced. Globally aluminum smelters produce more than 500,000 tons of SPL each year. Even though SPL has a high fuel value (8000 to 9000 BTU/lb) and contains valuable metals, it is classified as a hazardous material due to its cyanide content and leachable fluorides. Various disposal/recycle techniques have been developed over the years for SPL but none of them is satisfactory. Thus, large quantities of SPL are still being dumped in landfills. In some countries, even the land filling of SPL is not permitted. The safe disposal of SPL thus remains a challenging problem to the aluminum industry and the search continues to find methods of converting SPL into a non-hazardous waste and/or recovering the valuable materials contained in the SPL. We have developed a process to produce hydraulic setting cements (eco-cement) containing a novel fluoride rich cementitious phase, from SPL by an energy efficient, low temperature clinkering route. A raw mix blend of SPL, lime/limestone, calcium sulfate and tailings sands based on a set of design criteria developed by us, is clinkered in a two stage process; 2 hours soak at 800 °C followed by clinkering at 1000 °C for another 2 hours, to produce a soft clinker. The SPL eco-cement is made by grinding the clinker to a fineness of 5000 cm2/g Blaine with 1% by weight borax as a set retarder. A good quality cement having as high as 20 % by weight of SPL in the raw mix (28 % by weight in the cement clinker) is thus produced. The physical properties of the SPL cements are found to be comparable to the Indian standard (IS) specifications for Ordinary Portland Cements (OPC). We have produced the cement in a few Kg batches and tested the reproducibility of results from batch to batch for further scale up. Once commercialized, this process has a potential of converting SPL into value-added cement products. Keywords: cement, spent pot lining, clinkering, fluoride, aluminum, ordinary portland cements

Sep 1, 2012

By Gordon C. Petersen, Gary A. Almeraris

This paper describes the controlled blasting techniques required to mine a rock tunnel section of a main interceptor located in the Boston Metropolitan area. The 3m (10 ft) x 2.8m (9.25 ft) horseshoe shaped tunnel was driven 490m (1600 ft) by conventional drill and blast methods. The geology varied round by round and consisted of five highly faulted and jointed igneous rock types. The tunnel intersected numerous slickenslides and open mud seams which hampered both drilling and loading operations. Smooth blasting wee critical in order to keep overbreak tc a minimum in this extremely hard but blocky ground.

Jan 1, 1991

By Marcel Laflamme, Sebastián Ibarra‑Gutiérrez

Improvement on controlling the stope limits has enabled the assessment of technical performance in several underground mining operations. Technical performance, integrated to stope geotechnical and geomorphological parameters, constitutes the basis which guides mining engineers in the Mineral Reserves Estimation process. Moreover, there are established definitions to report this information in Canada, incorporated in NI 43–101, which stipulates that “A Mineral Reserve includes diluting materials and allowances for losses that may occur when the material is mined” [1]. However, some loopholes have been identified regarding practical standards followed to specify the way to include and report ore losses when the lost material was blasted and must be left behind unrecovered inside the stope. In fact, general efforts to estimate and quantify the negative effects of operational ore losses only consider under-break ore loss. However, mining engineers frequently confront situations requesting the anticipated closure of a stope. Therefore, reconciliation process should reflect the amount of unrecovered Mineral Reserve. This work presents a discussion of possible practices to integrate adequately operational ore losses consisting of blasted but not recovered material and focuses on how different approaches regarding the material constitution could severely affect the stope technical performance interpretation.

Aug 9, 2021

By M W. N Buxton, M S. Shishvan, J Benndorf

The flow of information, and consequently the decision-making along the chain of mining from exploration to beneficiation, typically occurs in a discontinuous fashion over long timespans. In addition, due to the uncertain nature of the knowledge about deposits and the inherent spatial distribution of material characteristics, actual production performance in terms of produced ore grades and quantity and extraction process efficiency often deviate from expectations. Reconciliation exercises to adjust mineral reserve models and planning assumptions are performed with timely lags of weeks, months or even years.With the development of modern information and communication technology over the last decade, a flood of data about different aspects of the production process is available in a real-time manner. For example, sensor technology enables online characterisation of geochemical, mineralogical and physical material characteristics on conveyor belts or at working faces. The ability to utilise this additional information and feed it back into reserve block models and planning assumptions opens up new opportunities to continuously control the decisions made in production planning to increase resource recovery and process efficiency. This leads to a change in paradigm from a discontinuous method to near real-time reserve reconciliation and model updating, which calls for suitable modelling and optimisation methodologies to quantify prior knowledge in the reserve model, process and integrate information from different sensor sources, back propagate the gain in information into reserve models and efficiently optimise operational decisions in real-time.This paper introduces the concept of an integrated closed-loop framework for real-time reserve management, incorporating sensor-based material characterisation, geostatistical modelling under uncertainty, modern data assimilation methods for sequential model updating and mining system simulation and optimisation. The effectiveness of the framework and the value added will be demonstrated in an illustrative case study.CITATION:Benndorf, J, Buxton, M W N and Shishvan, M S, 2014. Sensor-based real-time resource model reconciliation for improved mine production control – a conceptual framework, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 223–234 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By P Khalkho, M Singh

Rock masses when subjected to uniaxial or triaxial cyclic loading (eg in hydraulic running tunnels, during retrieval and injection of oil and gas from storage underground caverns and haulage roads), the material has a tendency to fail in fatigue. In order to design safe and reliable underground structures, the determination of brittleness under such loading conditions becomes a pre-requisite. Brittleness influences strongly the failure process and makes the rock mass behaviour complex under different tunnelling and mining activities. Brittleness Index is a term to quantify the brittleness feature of a specimen. In the present study, an attempt has been made to quantify the brittleness of jointed specimens using different brittleness criteria. The joints of the model jointed specimens were oriented at an angle of θ=15° normal to the loading direction, each having three different JRC’s=2–4, 12–14 and 14–16. The specimens were tested under triaxial conditions in incremental complete cyclic test scheme performed at displacement-controlled mode. Different brittleness criteria were used ie stress-strain dependent brittleness index, Young Modulus approach and energy-balance based mechanism. It was observed that energy-balance based mechanism which consider the post failure behaviour is more descriptive to reflect the whole variation of brittleness from sheer brittleness to ductility.

Nov 29, 2022

By Oliver Bowles

Since 1922 when the Bureau of Mines issued a report2 covering the slate industry in detail, changes in technology have taken place which have an important bearing on the industry. The present paper comprises a record of these changes. Though the value of slate, for roofing, structural, blackboard, sanitary, and electrical uses is generally recognized, it has many competitors. To meet this constantly increasing competition producers are promoting economies in manufacture, and improving processes, thereby lessening costs of production, and are placing on the market products of the highest possible quality, thus creating satisfaction and confidence on the part of the user. This endeavor to place the industry on a better basis, both as regards processes and products, is shown in the recent developments in technology which are presented herein. Valuable assistance in obtaining data for this paper was given by W. S. Hays, secretary of the National Slate Association, N. M. Male, president of the National Slate Association, and Robert Notvest, consulting engineer, Cleveland, O.

Jan 1, 1926

By T. Field, N. D. Nxumalo

Since the discovery of gold on the Witwatersrand in 1886, mining has been at the centre of South Africa’s development. Although mining continues to contribute significantly to the country’s economy, it is a temporary land-use activity, and mine closure is inevitable. This paper reviews mine closure planning at Tshikondeni coal mine, which commenced in 2014 with the initiation of mine closure. The review presents the mine closure processes undertaken at the Tshikondeni coal mine as regulated by South Africa’s principal mining legislation, the Mineral and Petroleum Resources Development Act 28 of 2002, and other relevant regulatory frameworks. To compile this review: (1) A desktop study was conducted; (2) empirical data was collected through one-on-one interviews with research participants at Tshikondeni coal mine; and 3) physical observations were made of the rehabilitation at various mine operations within the Tshikondeni coal mine complex. Research participants consisted of mine officials from different departments, i.e., human resources, and environmental, social, and business strategy, who were directly involved with the Tshikondeni coal mine closure. A questionnaire with semi-structured questions was developed. It was utilised to acquire a better understanding of mine closure planning at Tshikondeni coal mine and identify mine closure processes that aim to achieve post-mining land uses and align with Tshikondeni coal mine’s post-closure strategy, namely the Tshikondeni Legacy Project, with a post-closure strategy that has the potential to transition a mining economy to an eco-tourism economy that can preserve livelihoods and selfreliant communities.

Dec 15, 2025

By Pingchao Ke

A crystalline polyferric sulfate (PFS) adsorbent was synthesized by oxidizing and precipitating ferrous ions under atmospheric conditions. The morphology, structure, composition and specific surface area (SSA) and adsorptive efficacy to As (III) of the adsorbent were characterized by SEM/EDS and TEM images, XRD patterns, FT-IR spectra, BET SSA analyses and adsorption experiments. The adsorbent presents as morphology of near-spherical aggregate and good crystallinity. A small amount of goethite co-precipitated with PFS in the case of the initial ferrous concentration of 1 mol/L and increased the SSA of the aggregates. The absorbent with co-precipitation of goethite showed good adsorption to As(III) and good filtering performance in the high As(III)-content solution of 10–100 mg/L under acidic, neutral and alkaline conditions (pH 2.09–9.01), and its maximal adsorption capacity and adsorption efficiency were 7911 μg/g and 96% separately. After Adsorption, the stability of the absorbents adsorbing As(III) were evaluated by TCLP tests, and the results indicated that the absorbents adsorbing As(III) were extremely stable, and the concentration of arsenic in all leaching solutions were less than 0.01 mg/L.

By J. N. Hartley

Uranium mill tailings, waste products of uranium extraction, contain hazardous constituents that if released into the atmosphere and groundwater could threaten our health and environment. To provide for safe disposal and control of these tailings, Congress enacted the Uranium Mill Tailings Radiation Control Act of 1978 (Public Law 95-604). Subsequently, the Environmental Protection Agency (EPA) established standards for tailings disposal that limit radon emission into the air to 20 pCi m-2s-1 on an annual average basis (EPA 1983). The design life of the impoundment is to be 1000 years where practicable, but 200 years at least. To facilitate the design of containment systems that will meet the EPA standards, the Nuclear Regulatory Commission (NRC) and the Department of Energy (DOE) are sponsoring research at the Pacific Northwest Laboratory (PNL)* to develop the necessary technology. Earthen and asphalt materials have been evaluated for use as radon barriers (Hartley 1983) and as liners to minimize leaching (Buelt 1983). Herbicide and rock barriers against biological intrusion have been evaluated (Cline 1982). Surface stabilization techniques have been investigated to maintain the long-term effectiveness of a containment system that must be protected from wind and water erosion, chemical and physical degradation, and biological disturbance.

Jan 1, 1984

In March 2003, Rio Tinto Coal AustraliaÆs (RTCA) new Hail Creek open cut coal mine commenced operations in the Bowen Basin. Hail Creek is a two-seam strip mining operation utilising two 90 m3 draglines and a fleet of excavators and trucks to remove the overburden. All overburden at Hail Creek is blasted prior to excavation. The mine conducts its own drill and blast operations while engaging Dyno Nobel for the provision of explosives supply and loading truck (bulk explosives vehicle û BEV) services. This arrangement was favoured over outsourcing the entire blasting function to a contractor. Subsequent to a value engineering review, the mine set about developing and implementing a blasting operation that did not rely on the need to store bulk quantities of ammonium nitrate on site. There were advantages identified in doing this, in particular the reduction of capital expenditure required and reduced exposure to a number of recently introduced security requirements. This approach also makes sense operationally. The establishment of reload facilities for the BEV close to the blasting location, where turnaround times are kept to a minimum, increases the productivity of the BEV. For this strategy to be successful the logistics of ammonium nitrate supply into the blasting operations has to be well planned and thoroughly executed. This means a robust planning and forecasting arrangement needs to be established with the supplier and transporters of the ammonium nitrate. To date, 80 million bcm of overburden has been blasted at Hail Creek and each year the quantity of overburden requiring blasting is increasing. The purpose of this paper is to present the findings of a study: evaluating the effectiveness to date of the strategy to conduct blasting operations without ammonium nitrate storage on site, and identifying whether there is a limit to which this strategy can operate after which the introduction of bulk ammonium nitrate storage facilities are necessary.

Jan 1, 2007

By A. Cecala, J. Noll, J. Hummer

"NIOSH has observed that many control rooms and operator compartments in the US mining industry do not have filtration systems capable of maintaining low dust concentrations in these areas. In this study at a mineral processing plant, to reduce respirable dust concentrations in a control room which had no cleaning system for intake air, a filtration/pressurization system originally designed for enclosed cabs was modified and installed. Eighty-seven percent of submicron particles were reduced by the system at static conditions, meaning that greater than eighty-seven percent of respirable dust particles should be reduced. The particle size distribution for respirable dust particles are greater than for submicron particles, and filtration systems usually are more efficient in capturing the larger particles. A positive pressure near 0.02 inches of water gauge was produced which is an important component for an effective system and minimizes particles (e.g. dust) from entering into the room. The intake airflow was around 118 cfm, which is greater than the airflow suggested by ASHRAE for acceptable indoor air quality. INTRODUCTION Chronic overexposure to respirable silica dust (particle diameter < 10 microns) leads to a progressive lung disease known as silicosis. Workers who develop silicosis have an increased incidence of lung cancer and pulmonary disorders. In June 1997, the International Agency for Research on Cancer (1) found sufficient evidence to declare that inhaled crystalline silica in the form of quartz and cristobalite is carcinogenic. Mining is one of the leading industries for occupational exposure to silica dust (2-7). Control rooms located in dusty areas in some mines are of particular concern (8). Many mineral processing operations utilize operator’s compartments and/or control rooms to house workers who are performing particular job functions. Most industrial processing mills have rooms where a worker looks out over the facility and has direct control over the product flow throughout the entire building. In addition, primary crusher operators are often located in a compartment from which they are able to view the primary crushing function. Their job is to control when trucks dump into the primary jaw crusher and the rate of feed of the ore from the hopper into the crusher. Many of these control rooms and operator booths do not have filtration systems capable of cleaning air entering the control room or booth, which can result in elevated concentrations of dust in the room or booth. To reduce the dust concentrations in these rooms, it would make sense to clean the entering air with filtration/pressurization units similar to those proven to provide a clean environment in enclosed cabs."

Jan 1, 2016

By Theodore Ineich

The “BIOMOre” project aims to prove the technical feasibility of indirect in situ bioleaching of sulfide minerals contained in a deep underground deposit, by bringing together the disciplines required to make a success. The underground location in Poland was provided by project partner KGHM inside an operating copper mine. Key components of this project were the design and construction of a pilot plant, and its operation in an underground environment. This project also included a ∼250 t (100 m3) fragmented rock reactor hydraulically connected to the pilot plant. The pilot plant consisted of several tanks and pumps, a fluidised bed ferric iron generating bioreactor containing immobilised acidophilic iron oxidation biomass, and all the required instrumentation and utilities. Before the bioleaching phase could start, the rock reactor had to be flushed continuously firstly with water to remove chloride salts that are corrosive and also harmful for the bacteria used in the bioreactor, and secondly, with sulfuric acid solution to react with the carbonates present in the ore matrix. This paper summarizes the design, construction, commissioning, and operation of the pilot plant.

By Joe N. Magee

As part of the important program of promoting conservation and efficient utilization of petroleum, Bureau of Mines engineers are making studies of secondary oil-recovery projects throughout the United states and publishing reports setting forth the pertinent facts so that others may profit by the experience gained. This report presents the results of a study by engineers of the Bureau of Mines, stationed at Franklin, Pa., of secondary oil recovery in a part of the Cabin Creek field, Kanawha and Boone Counties, W. Va., where natural gas is injected into the reservoir to stimulate oil production. Most oil produced in the Appalachian region at present is obtained from stripper fields in which almost all natural energy has been dissipated. Secondary-recovery methods are used extensively in many oil-producing areas of New York, Pennsylvania, West Virginia, Ohio, and Kentucky for recovering oil not produced by primary-production methods. The part of the Cabin Creek field reported in this study is shown in figure 1 and has been designated by the operator as project 4. In 1944 the developed area of the entire field was approximately 4,200 acres, and the area of project 4 was about 600 acres. In the developed area of the project the oil reservoir is in the Berea sandstone and occurs at 2,914 to 3,410 feet.

Jan 1, 1952

By P. Rooney

In due course, new smelters will have to be installed in order to meet the increasing worldwide demand for copper. This paper presents the results of a study made for the purpose of identifying the most desirable countries in the world in which to locate a new smelter. Both sociopolitical and economic factors were taken into account. Criteria developed and methods used to assess each possible location are described. The study indicated that the most interesting potential locations are Canada, -Chile, Portugal and the USA for new copper smelting complexes.

Jan 1, 1983

By Avery H. Reed

[The Bureau of rides is making a general study of the occurrence of the Clinton red iron ores of Alabama. In the course of this study, it developed that the iron-ore seams of the Woodstock and Bucksville areas were virtually unexplored., and the nature and extent of the ore deposits were undetermined. As a part of the work of the project, the Bureau investigated the occurrence of red iron ore in the .areas. Eighty-four channel samples, representing 317.6 linear feet, were taken from l2 locations along the outcrop of the red iron-ore seams, Ten diamond-drill holes, amounting to 3915.5 linear feet, were drilled. In these areas, commercial- and marginal-grade ores of minable thickness have been shown. It is estimated that 4,500,000 tons of indicated ore and 6,700,000 tens of inferred commercial-grade ore averaging 5.1 feet thick, 47.6 percent Fe, 26.1 percent insoluble, 0.1 percent CaO, and 0.04 percent P; 7,200,000 tins of inferred marginal grade ore averaging 6.1 feet thick, 36.2 percent Fe, .35.0 percent insoluble, 3.9 percent CaO, and 0.14 percent P; and 18,500,000 tons of ferruginous sandstone averaging 12.2 feet thick, 19.2 percent re, 50.1 percent insoluble, 9.6 percent CaO, and 0.14 percent P are present in the areas.. All tonnages are estimated as gross tons of recoverable ore in place, based&apos; on 65-percent mining recovery. In accordance with established policy of the Bureau of Mines of publishing factual data as soon as possible after completion of field work, this description of the Woodstock and Bucksville areas is presented. As soon as work is completed in other areas additional reports will be prepared.]

Jan 1, 1953

By John W. Cole

Ore deposits in the? vicinity of Philipsburg, Mont., have been mined continuously since discovery of the Hope mine in 1865. Although originally famed chiefly for its silver production, since about 1917 the district has been the only important producer of battery-grade manganese ore in the United States. Also, it has produced substantial quantities of zinc ore and during World War I and World War II contributed notable amounts of manganese for metallurgical consumption. Nearly the entire production of base metal ores has been mined from the outcrop area of? a dolomitic limestone bed that plunges beneath overlying beds of limestone and shale northward from the outcrop area. The Hope silver mine, with a production record of over $4,000,000, was in one of the overlying limestone beds about 3,000 feet north of the base-metal producing area and about 1,000 feet vertically above the projected downward position of the dolomitic bed that has produced the base-metal ores. Furthermore, the Hope ore bodies were controlled, in part at least by east-west fractures similar to those that controlled the deposition of the base-metal ores.

Jan 1, 1949

By Joseph W. Mullan

The today status of air pollution control legislation and regulations can best be described as an exaggerated state of environmental limbo. The &apos;70&apos;s began but one and one-half months ago yet it already has been very appropriately named "the decade of the environment." This certainly will be the decade for new legislation - new regulations and hopefully "Clean Air." Already Washington is faced with legislators playing "pollution politics" to the crowds. Students have redirected their efforts from Vietnam to the cleansing of the environment and everyone including the man on the street has become an environ¬mental expert. This is the decade we all face, but where are we today? Pollution is not a new problem. It has been with us for centuries and while much is left to be done, much has already been accomplished. I will try to make some comparisons of what I believe to be the good and bad points in the national air pollution control picture and hopefully will generate within each of you sufficient concern as to which comparisons are sound.

Jan 1, 1970