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By N J. Welham

The Intec Copper Process is an environmentally advantageous hydrometallurgical process for the production of high purity copper and associated precious metals from copper sulphide concentrates. The process uses a mixed chloride-bromide lixiviant in an elegant cyclic circuit to leach the copper into solution, rejecting the iron as stable hematite rather than as unstable jarosite. After purification of the pregnant liquor, copper is electrowon at London Metal Exchange Grade A purity, while the anodic energy of the cell is stored as the soluble species, HalexTM, for recycle as the regenerated lixiviant to the leach circuit. Both gold and silver are leached and recovered directly from this cyclic process without resorting to cyanide leaching of the residue. No liquid emissions result from the Intec Copper Process, whilst spent air and water vapour from the leach are released to the atmosphere. The sulphur in the minerals reports to the solids residue in elemental form, without the need for expensive handling of voluminous gaseous sulphur dioxide streams found in smelters. A significant difference to competing smelting and hydrometallurgical processes is that any mercury entering the process from the sulphide concentrate feed is recovered rather than reporting directly to waste or polluting the environment. Outside the process circuit itself, the Intec Copper Process has several notable environmental advantages over competing technologies: Flexibility of scale with low capital and operating costs allow operation directly at the mill head at production rates as low as 15 000 tpa, significantly reducing environmental impacts from concentrates transport. The ability to handle low-grade and dirty concentrates often allows greater recoveries in the mill, improving both the economics and environmental acceptability of a mine by reducing metal losses to tailings. A comparison of the total energy requirements of the Intec Copper Process with those of competing technologies shows that the Intec Copper Process has the lowest energy consumption of any of the known hydrometallurgical processes, as well as improving upon pyrometallurgy under appropriate conditions.

Jan 1, 2002

By K. Gardner

"Many deposits have a geological model developed early in the project stages, which is not always reviewed or modified as the project matures and production commences. Conversely, ongoing pressures, due to a combination of declining head grades, a push for increased revenue and a multitude of other reasons, leads to processing plant modifications, with the primary aim being to increase production. Often, the ore deposit knowledge is not sustained or developed during the operational stages to the level carried out during the prefeasibility and feasibility study phases. This results in the variability within the deposit being poorly understood and a lack of data and knowledge being available to support (and ideally optimise) operations particularly in an environment where the flow sheet has changed and ore feed requirements are complex.INTRODUCTION This paper presents a case study of ore deposit knowledge development and corresponding process plant operating strategy at the Ladolam Gold Deposit, commonly referred to as the Lihir gold deposit in Papua New Guinea. The gold deposit is located in a tropical equatorial climate on the east side of Lihir Island in the New Ireland Province of Papua New Guinea. Gold mineralisation was discovered in 1982, and was followed by a major exploration campaign by a joint venture between Kennecott (Rio Tinto) and Nuigini Mining Limited. The first drillhole was drilled in 1983, and after an extensive period of drilling consisting of 343 holes for 83,500 m, the final Feasibility Study was completed in 1992. The feasibility study was based on a Reserve base of 37.9 Moz in refractory sulphide ore, with gold extraction proposed to occur via whole ore pressure oxidation due to the refractory nature of the mineralisation. The Lihir Special Mining Lease (SML) was granted in 1995 to a new PNG company – Lihir Gold Limited, and Rio Tinto established Lihir Management Company to develop and operate the mine on behalf of LGL. Mining and processing of the deposit commenced in 1997. Newcrest Mining Limited purchased Lihir Gold Limited in August 2010, and subsequently completed a major plant upgrade including the installation of additional grinding, autoclave and carbon-in-leach capacity. Post commissioning of the upgrade, Newcrest has continued to increase throughput and production. A reinvigorated ore body knowledge development program has significantly assisted this process in identifying operating strategies for the process plant and delivering recovery improvement projects to address declining head grade and recovery due to increased stockpile feed and flotation circuit use."

Jan 1, 2017

By P. Abachi

Cemented carbides or hard metals that generally consist of hard tungsten carbide and a tough metal binder such as cobalt are important in many segments of the world economy, ranging from automobile related components to machining, cutting, and drilling tools. For metal cutting operations such as turning and milling, replaceable cemented carbide inserts are frequently used. The exposure of inserts to very severe conditions (e.g. temperatures as high as 1000°C) in combination with very high loads, limits their lifetime. When the tools and components are scrapped, they are collected with a view to recovering the tungsten carbide and cobalt due to both their environmental aspects and their strategic importance. In this work, a selective electrolysis process was used for recovery of WC powder particles from cemented carbide scraps. The WC-10Co and WC-10Co-VC up to 3 wt.% VC was produced using powder metallurgy route. The mean particle size of WC, Co and VC were selected as 2.5, l.5 and 2.2 µm respectively. Referring to electrochemical curves of WC-10Co cemented carbides in hydrochloric acid solutions with different concentrations, the recovery rate was enhanced in IN acid. Therefore, this solution was selected for recycling of all samples. The surfaces of as-produced and corroded specimens were investigated using a scanning electron microscopy (SEM). Detection of corrosion products was provided by energy dispersive spectrometry (EDS). According to results, the selective electrolysis process could be useful in the recycling of scrap carbide materials, although more studies should be undertaken on economical aspects of the process and the quality of samples produced using recovered powders.

Jan 1, 2005

By Cedric E. Gregory

"A study of model rectangular mine shafts has been made in the wind tunnel, with the aim of reducing air-flow resistance elements to a practicable minimum. An analysis of Table 7 shows an indicated average decrease in resistance of 28 per cent by adopting the over-all modifications involved in the configurations actually tested. Much greater reductions (up to 68 per cent) are indicated by extrapolating beyond the test results directly achieved. Intermediate partial reductions in aerodynamic resistance are shown for individual modifications, such as: (1) about 3 per cent for locating the lagging in the No. 4 (inside flush) position as against the No. 1 position - 8 per cent as against the No. 2 position - and 23 per cent as compared with position No. 3; (2) about 12 per cent for using lagging instead of steel meshwork along the divider separating the skipway from the service compartment; (3) about 14 per cent for using steel gridwork ladder stagings at 3-set intervals instead of similarly spaced wooden stagings; (4) about 12 per cent for using steel gridwork ladder stagings at 3-set instead of at 1-set intervals; (5) about 13 per cent for fitting a streamlined fairing (see Fig. 5) to the upstream face of the skipway divider. Contrary to expectations, an advantage of only 3 per cent is indicated for lagging in the inside flush (No. 4) position over the outside position (No. 1). This slight gain does not appear to warrant the cost of moving the lagging. However, if the lagging is already in the No. 2 or No. 3 position, there is an 8 and 23 per cent advantage respectively."

Jan 1, 1973

By N Petropoulos and M J Thurley, E Righetti, M Wimmer

Fragmentation in sublevel caving (SLC) is vitally important. Both gravity flow and any downstream processes are affected. Reasonably coarse fragmentation may lead to larger draw bodies (isolated extraction zones) and hence potentially higher primary ore recovery and depressed/delayed waste rock inflow from above. Fewer flow disturbances are expected by mitigating oversize. In addition, it requires less boulder handling and reduces wear and possible hang-up problems in orepasses. To assess the present-day functionality of large-scale SLC, a multiyear, comprehensive measurement program was initiated. It covers the main elements for SLC, namely blast function, fragmentation and gravity flow. The present paper focuses on fragmentation measurements. An image acquisition system was used to document the drawpoint and the load-haul-dump (LHD) bucket for each mucking cycle. At the beginning, four buckets (about 70 t total) were sieved to validate the results of both 2D and 3D image analysis techniques. The fundamental and specific problems are discussed herein. At the moment, fragmentation of the SLC rings is evaluated using a quick rating system and a 2D fragment delineation software. The results enable a description of fragmentation and its variation during mucking but also – combined with the gravity flow measurements – conclusions on the fragmentation for different parts of the SLC ring. Possible influences on flow disturbances and ore recovery/dilution are investigated. The recent findings allow a better understanding of breakage and flow and support future process improvements.CITATION:Wimmer, M, Nordqvist, A, Righetti, E, Petropoulos, N and Thurley, M J, 2015. Analysis of rock fragmentation and its effect on gravity flow at the Kiruna sublevel caving mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 775–792 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By J. Lindström, J. Hamuyuni, M. Lundström, J. Aromaa

"The rising demand for metals today, coupled with the scarcity of primary sources for raw materials threatens both technological advancements and industrial manufacturing. In order to meet the demand, metals and other resources trapped in waste streams, have to be harnessed. This philosophy supports circular economy, where metals and other resources are kept in a closed loop. The pickling acid recovery system of most stainless steel production is one such example where the dissolved metals such as iron, nickel and chromium are currently not completely recovered due to the limitations of the current technologies. The aim of this study was to assess the available metals recovery methods from extremely concentrated acids. The main aim is to simultaneously recover metals and keep sulphuric acid reusable in acid circulation process. From the available literature, the most promising methods were chosen for laboratory experiments. Based on experimental work, the results and observations of electrodeposition, solvent extraction, and freeze crystallization are provided. KEYWORDS Pickling acid, metal recovery, solvent extraction, cathodic polarization, Freeze crystallization. INTRODUCTION Pickling in stainless steel production is an essential surface treatment process (Regel-Rosocka, M. (2010); Agrawal and Sahu, 2009). It is applied for removing surface films such as oxides and chromium-depleted layers to improve the corrosion resistance and surface finish of steel (Regel-Rosocka, 2010). Whilst the process greatly improves the surface finish of the stainless steel, it generates large amount of used acid, containing dissolved metals including chromium, iron, and nickel (Agrawal and Sahu, 2009). Recovery of acid is common practice for most steel producing industries (Nyman and Koivunen, 1986). In this work, acid regeneration process is investigated so as to simultaneously reusing sulfuric acid and recovering the dissolved metals. Recovery of valuable metals even in very small amounts would also bring additional revenue to the steel production industry. At a time when metal production has also been challenged by lack of natural resources for raw materials, secondary sources for metals such as the acid pickling process therefore, have greater potential as supplements. From earlier studies, electrodeposition (Giovanardi and Orlando, 2011; Kuznetsov et al., 200; Rögener et al., 2012; Surviliene et al., 2006), solvent extraction (Alguacil and López 1996; Haghshenas et al., 2009; Kesieme et al., 2013) and freeze crystallization (Beyer et al.,2003; Hasan et al.,2017; Van der Ham et al., 1999) are some of the most established potential methods. Earlier studies have also shown that simultaneous recovery of acid and metals would require combination of different methods. This is primarily due to the nature of very stable metal containing complex compounds formed during pickling. These complexes must be broken down to free the metals for further recovery processes."

Jan 1, 2018

By Kyle Bartholomew, Robert McIvor

"Functional performance analysis of closed circuit grinding provides valuable insight into the two components of ball mill circuit grinding efficiency: classification system efficiency and mill grinding efficiency. Classification system efficiency isolates the combined effect of classifier performance and circulating load ratio from other circuit variables, such as ore grindability and the mill grinding environment. Optimization of classification system efficiency ensures grinding energy is applied to particles needing further size reduction and not to overgrinding. Entirely based on size distribution data, classification system efficiency precisely distinguishes subtle changes in classification system performance. Use of the functional performance equation to isolate mill grinding efficiency allows for proper optimization of the mill grinding environment by isolating confounding effects of changes in classification and ore grindability. Variables such as mill percent solids and grinding media selection can be optimized using the mill grinding efficiency subcomponent of functional performance. First published by McIvor in 1988, the functional performance equation provides a set of standardized, quantitative optimization criteria, simple and powerful, which link circuit performance to plant design and operating variables that can be manipulated. Functional performance optimization has been applied in numerous mineral processing plants globally and continues to gain acceptance as a practical means for grinding circuit optimization. In this paper, examples of derivation and industrial application demonstrate the means by which functional performance analysis dissects grinding circuit efficiency into its subcomponents allowing the reader to apply this straightforward, powerful optimization methodology at their mineral processing operation."

Jan 1, 2014

By Björn Saxen

Outotec atmospheric Direct Leaching has so far been implemented for zinc production capacities of around 100,000 t/a. Lately, there has been growing interest for small scale direct leaching plants, producing circa 30,000 t/a of Zn. Such small leaching plants can provide extra front-end capacity in existing roaster-based plants and enable treatment of feed materials not suitable for roasting. In small scale plants the proven OKTOP® 9000 Direct Leaching reactors are not readily applicable, due the large size. For smaller installations a modular approach is proposed providing multiple advantages, such as reducing the construction time and amount of the site work required causing less disturbance to regular plant operation with reduced cost. In this paper, we present advantages that can be achieved by using modular OKTOP®C reactors and discuss also process design when connecting a small scale direct leaching process to an existing zinc plant. Also benefits of direct leaching expansion are presented.

Robert W. Hunt, Chicago, Ill.:—It has been my good fortune to know of this development of Mr. York's for some time, and I think he will permit me to say that this is not the first demonstration that he has made of his method for rolling difficult shapes, and which, as he has stated, had in the past been regarded as practically impossible. I have good reason to know that Mr. York has been successful on other lines, because I myself went through a period of professional disrepute for having reported favorably on his methods, which received discredit up to the time that it was practically demonstrated that his claims were true ones. Years ago Mr. York built a mill at Duluth, Minn., for the production of structural shapes, and notably of what might be called balanced beams—beams that did not have flanges of restricted width. His scheme was to produce beams with flanges so wide that they could be used in place of built-up beams. The mill, of course, went through the difficulties that such a mill would have to encounter. I mas called upon to make an examination of the property and report. These beams were rolled on a universal mill—a mill which would admit of various-sized sections without change of rolls. I was convinced that Mr. York could do it, and I so reported. Having received condemnation and ridicule for having taken that position, later on I was glad to find that Mr. John Fritz had come to the same conclusion, and had so reported. I concluded we both could rest content, while awaiting developments. Later still, as we all know, there was another difficulty that Mr. York met with—namely, that the architects or structural engineers would not accept his proposed sections. That is still a great difficulty in America. Later, the Grey mill came into successful operation in Luxemburg, producing such sections, which are being used in England and on the Continent. In fact, the whole process, both from a commercial and a mechanical point of view, is a success. The Bethlehem Steel Co., Bethlehem, Pa.,

Jan 1, 1907

By A. Kogelbauer, A. Stadtschnitzer, A. Boehm, F. Schillab

"The paper covers the design and implementation of an industrial dense medium cyclone plant for carbonaceous iron ore, the proving of efficiency as well as the development of a predictive model for plant control. The VA Erzberg GmbH mines about 12 Mio.t of carbonaceous rock ore at the “Steirische Erzberg”. Due to increased demand of the Austrian steel plants, the production of ore concentrate was raised by 30 % up to 3.0 Mio t/a during the last 5 years. One of the projects to realize the increase in capacity at improved concentrate quality was the implementation of a dense medium cyclone plant for the fine size fraction – 8 +1 mm replacing the former dry permanent magnetic drum separators. By physical separation the siderite variety “spateisenstein” (42% Fe) of a density of 3,8 g/cm³ is separated from ankerite (10 – 17% Fe), the second iron bearing carbonate with a density of 3,2 g/cm³, dolomite, calcite and silicate bearing schists. The feasibility of the process was proven by the test results obtained from a test rig, that was constructed and operated in close cooperation between the Chair of Mineral Processing, Montanuniversitaet Leoben and VA Erzberg GmbH. The density separation surpassed the efficiency of magnetic separation clearly shown by •- values. The plant performance tests (capacity 120 t/h) verify the cut densities defined by Tromp T50 -values and the assigned efficiency found in the pilot tests at varied settings of media density, pressure drop, cone angle and apex diameter. The test rig as well as the final process will be presented. In order to create a tool to predict the performance of the DMS in the centrifugal field at various settings for varying feed composition the experimental results from size and density testing are analyzed in a modified way to obtain physically justified, smooth approximations for the performance curves. Models developed on coal washing plants are checked for their validity at increased densities."

Jan 1, 2018

By A. R. Farkoosh

Al-Si based alloys have been recently used by automotive industry for highly stressed engine applications. Due to severe working conditions of the engine parts, existing alloys hardly endure high pressures at high temperatures. This necessitates alloy modifications to enhance the elevated temperature performance. In this study, the effects of trace nickel additions on the microstructural and mechanical properties of A356+0.5Cu alloy have been investigated at different aging conditions. Electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and X-ray diffraction (XRD) are used to study the microstructural changes. Aging curves have been obtained by hardness measurement. It was seen that the presence of additional nickel introduced many complex intermetallic phases within the microstructure which led to improved high temperature mechanical and aging response.

Jan 1, 2011

By Joseph L. Petrillo

In July 1997, Kvaerner Environmental signed a unique contract with Echo Bay Alaska called the Transfer Risk and Accelerate Closure (TRAC). The contract called for Kvaerner to assume the responsibilities and obligations associated with closeout of the Alaska-Juneau (A-J) Mine. Kvaerner is an international engineering and construction company with global interdisciplinary experience in the mining industry and environmental remediation. Echo Bay’s requirements called for Kvaerner to: •Provide a fixed price for closure with no change orders. •Negotiate, prepare and implement a final closeout plan as outlined by Echo Bay. •Complete a closure program that exceeded current regulatory requirements. •Improve, expand and maintain a proactive public and community relations program. •Hire Echo Bay employees where possible. •Provide adequate performance guarantees and judicial relief of environmental claims.

Jan 1, 1999

By Rubén Alvarado

The markets and environmental protection rules are more and more exacting, both of which have determined that copper smelters should look for technological development and global management to ensure their viability and competitivity in the short and long term. The main facilities of the present and future Smelting-Converting Process at Codelco's Caletones Smelter, is based on Teniente Converter reactors with a high operational availability that have reached concentrate processing capacities near 2,000 tpd. These reactors are in operation in most of the smelters in Chile as well as in Zambia, Peru, Mexico and, in ?the near future, in Thailand. Since 1993, the Smelting-Converting process of the Caletones Smelter of Codelco-Chile has been based on one Reverberatory furnace, two Teniente Converters and four Peirce-Smith Converters. These facilities, together with the operation of two Fluidized Bed Dryers, three Slag Cleaning Furnaces, and two Oxygen Plants have allowed the smelter to reach concentrate smelting capacities and copper productions of 1,215 kt/year and 360 kt/year, respectively. This transitional operating scheme, combining together traditional and advanced technological equipment, needs further modernization to successfully face the modern world challenges, especially with relation to the environmental commitment, production costs and wide satisfaction of customers. For this reason, for the period 1997-2000, a Modernization Plan has been worked out. This plan considers an increase of the present throughput, which will permit a significant increase in productivity, as well as finding a definitive solution for meeting the environmental regulations. Among these projects, we can point out the definitive shut down of the Reverberatory Furnace, which is a contaminating piece of equipment of low energetic efficiency. Additionally, it considers the installation of two new Slag Cleaning Furnaces, one additional Oxygen Plant, and the incorporation of two new Sulphuric Acid Plants with a production capacity of 4,500 T/D, that will recover over 92% of the sulphur content, of process off-gases.

Jan 1, 1998

By Ming’an Wei, Qifu Duan, Jianmin Wu, Lusheng Zhou, HMR Group Limited / HMR Technology Canada Ltd., Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company Skega first introduced rubber magnetic liners, and then followed by the Chinese invention of metal magnetic liners. Traditionally, both liners were used in secondary ball mills and regrind ball mills for industrial applications, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged steel balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design. Due to the development of larger diameter ball mills and thus larger ball charge diameter (up to 80mm) especially in non-ferrous metal mining operations, the application of magnetic liners have been very limited. Based on “Magnetism theory” and the development of new materials, the HMR Group Limited has been conducting researches on examining the structures of magnetic liners, associated materials and magnetic circuits which led to the invention of the Nano Alloy Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5 m diameter × 6.5 m ball mill at the Erdenet Copper Mine in Mongolia. The NSML successfully handled a ball size up of to 80 mm, while achieving a service life of nearly 24 months, which is almost 3 times wear life of the original manganese steel liners.INTRODUCTIONDuring the development and utilization of mineral resources, mineral processing is an indispensably operation. The effective separation of various useful minerals depends on sufficient monomer dissociation of minerals in the ores. The crushing and grinding operation is prior operation of mineral processing. Ball mills are used in different concentrators. As the main consumption parts of mill, liners have been studied constantly. As a new kind of liners, magnetic liners besides can meet the requirement of production, and also have characteristics with maintenance-free, saving energy and increasing efficiency. So the magnetic liners are worth to be spread and applied world widely."

Jan 1, 2016

By J Crosbie, M Lord, R Bitencourt, P Defferrard

The MMG Century mine, which is the largest zinc/lead mine in Australia, began operating in 1999 and ceased mining from the open pit in July 2015, with processing completed in early 2016. Closure plans were developed from 2006, and detailed planning for closure commenced in early 2011 with the appointment of a dedicated closure planning resource. The site will continue to be managed during the active and passive closure phases to complete rehabilitation commitments and demonstrate that closure completion criteria have been achieved.Completion of the mining/processing phase of the project provides an opportunity to reflect on successes, missed opportunities and lessons learnt with respect to planning and execution of mine closure. This paper highlights examples of success at Century and also identifies key learnings and areas for improvement in progressive closure outcomes. Specific examples examine mine planning and execution involving bulk movement of waste rock and construction of permanent waste encapsulation landforms. The paper also provides recommendations for other sites that are planning for closure.Decisions made during the operational phase of the project life can result in a significant increase in closure liability and reduce the likelihood of achieving lease relinquishment. Likewise, it is of paramount importance to assess the consequences and thoroughly understand the risks associated with changes or deferral of closure plans, progressive rehabilitation targets and closure related key performance indicators.CITATION:Lord, M, Bitencourt, R, Crosbie, J and Defferrard, P, 2016. Closure planning lessons Learnt from the Century mine, in Proceedings International Mine Management Conference, pp 207-216 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By P C. Miclea

Transportation networks extend every day around the world, requiring safe and well-maintained structures for efficiency and for users’ safety. Due to specific features of the infrastructure, such as longer tunnels, increased traffic and marginal safety rules, fire safety in rail and road tunnels becomes more challenging.The situation becomes more critical due to the global economy and increasing worldwide tourism, with multi-national companies often involved in both design and construction of transportation routes or systems in other countries. Tourism brings the risk of visitors becoming victims in a foreign land; thus, international law becomes more and more applicable to transportation projects all over the world, requiring a consistent approach to safety (UN Economic and Social Council, 2001; US DOT Federal Highway Administration (FHWA) 2006; US Transportation Research Board, Committee on the Role of Public Transportation in Emergency Evacuation, 2008; UK Parliamentary Office of Science and Technology, 1997).There are significant differences between rail and road tunnels, both in their functionality and safety requirements. Most tunnels over a certain length are equipped with emergency ventilation systems capable to control the spread of smoke by creating an air stream in the desired direction. Besides ventilation, fire-life safety (FLS) includes smoke and heat detection by linear or spot detectors, closed-circuit television (CCTV) and public address systems with prerecorded announcements, as well as evacuation signage and monitoring capabilities (Vägverket – Swedish National Road Administration, 2004).There isn’t a consistent, worldwide approach to the design of emergency ventilation systems for tunnels, with significant differences from continent to continent (US DOT Federal Highway Administration (FHWA), 2004, US Federal Transit Administration, Transportation Research Board, 2006). In North America US NFPA 130 and 502 standards for rail and road tunnels, respectively, represent the main criteria, however, they are continually revised and new versions issued every three years. For road tunnels the World Road Association PIARC issues guidelines, but they are not truly enforceable. There are no similar international guidelines for rail tunnels, except general recommendations by the International Association of Public Transport (UITP) (IAPT, 2003).In Europe the Directive #54/EC adopted by European Community Parliament in 2004 requires a minimum level of safety for road tunnels users in all existing and proposed tunnels in the Trans-European road network that are greater than 500 m in length. Authorities having jurisdiction in many other individual countries, such as Australia, Austria, Germany, Japan and others, enforce specific safety regulations (Miclea et al, 2007). While it is impossible to summarise all aspects of this topic in a short paper, a review of the design approach, the existing differences in safety requirements, as well as applicable design solutions to meet safety codes for both rail and road tunnels are discussed below.

Mar 8, 2011

By Liang Zhen, Jian-Tang Jiang, Guo-Ai Li, Xiao-Ya Wang

"Deformation behavior of 2A97 aluminum alloy containing coarse secondary phases was studied using uniaxial hot compression (HC, 340–490°C, 0.4001–1 s-1). The flow stress could be described by a Zener-Hollomon parameter in hyperbolic sine function with the hot deformation activation energy of 237 kJ/mol. Based on the experimental data and dynamic materials model, processing maps were generated to demonstrate the hot workability of the alloy. The coarse secondary phases experienced dissolution by varying degree under different deformation temperature, which producing different effects on the microstructure evolution. When deformed at relatively low temperatures, a mass of fine grains shaped up in the original grains and grain boundaries, and the dominating deformation mechanism was believed to be dynamic recrystallization. As the deformation temperature rising to 490°C, most secondary phases disappeared and few recrystallized grains were observed, indicating that the secondary phases dissolved sufficiently along with dynamic recovery occurred during the hot deformation. Particle stimulated nucleation related to the coarse secondary phases was believed to promote the recrystallization and the recrystallization behavior was sensitive to deformation temperature.INTRODUCTION Al-Li alloys has received much attention as new promising structural materials in the aircraft and aerospace industries, due to their lower density, higher elastic modulus and improved fatigue crack growth resistance in comparison with the conventional commercial aluminum alloys (Ou Ling, 2015). 2A97 alloy is one of the 3rd generation Al-Li alloys targeting at comprehensive improvement of aviation aluminum alloy and applications for wing spars and ribs to other internal structures for transport aircraft. Al-Li alloys are usually formed by hot deformation, either by rolling or extruding. The deformation behavior and resulted microstructure evolution during the forming process mainly dominates the formability of the alloy and the serving performances as well. Therefore, the deformation behavior and microstructure evolution at elevated temperature need be made clear for optimizing the hot processing parameters and controlling microstructure evolution."

Jan 1, 2018

By R. Xie, J. Liu, Y. Zhu, Y. Li

The surface chemistry features of spodumene and feldspar were investigated by XPS, zeta potential measurements and first principle calculation. The results indicated that the zeta potential of feldspar was more negative than that of spodumene. The most possible active sites on spodumene and feldspar were Al sites and O sites. However, the number, type and activity of these sites were different. The flotation behaviour of five new collectors (cationic collector decyloxy-propyl-amine (DPA), anionic collector α-bromododecanoic acid (α-BDDA), N-Dodecyliminodiacetic acid (DIDA), and mixed collector DPA-BDDA and DPA-DIDA) were investigated through micro flotation experiments and analysed based on the surface chemistry features of spodumene and feldspar. The results revealed that cationic collector DPA processed a high collecting capacity for both minerals. The highest recovery of spodumene and feldspar was 91.60% and 95.30% respectively. The anionic collector α-BDDA and DIDA showed poor flotation behaviour. The recovery of spodumene and feldspar when using α-BDDA as collector was less than 5% and when using DIDA as collector was less than 1%. For the mixed collector DPA-BDDA, the recovery of spodumene and feldspar was 82.27% and 32.61% respectively at pH 4.5. For mixed collector DPA-DIDA, the recovery of spodumene and feldspar was 35.69% and 9.08% respectively at pH 5.8. The results indicated that the cationic collector had high collecting capacity, but low selectivity. The collecting capacity of anionic collector for spodumene and feldspar was poor at the same concentration compared with cationic collectors. Mixed collector DPA-BDDA showed good flotation behaviour and selectivity on spodumene. The ―COO- in mixed collector might improve the selectivity. However, too much ―COO- would increase the electrostatic repulsion, which might cause low selectively and poor recovery. Keywords: Spodumene, feldspar, surface chemistry features, mixed collector, flotation

Jan 1, 2020

By P. M. Solozhenkin, O. I. Solozhenkin

Currently lead nitrate is used as the recommended activator in Au-Sb flotation. However, due to high levels of hazard, the application of lead nitrate constitutes a potential risk for human health and ecosystems. To mitigate the harmful impact of activators on the environment, further research on activation by alternative reagents has been launched to promote the efficiency of antimony ores. In the present study, adsorption of lead, copper and zinc cations has been investigated by nuclear quadrupole resonance (NQR), which has revealed copper and zinc cations penetration into the mineral lattice, although lead cations remain adsorbed on the mineral surface. However, the combination of zinc and copper cations leads to preferential volumetric adsorption of zinc in the mineral lattice and further surface adsorption of copper which positively affects the activation process. It has been established that activation of stibnite can be achieved effectively with the mixture of Cu2+:Zn2+=1:1 as much as with lead cations in antimony ore flotation. As a part of this work, the computational modelling has been used in prognosis of reagent activity evaluation (PRAE) for stibnite and aurostibite flotation by sulfhydryl collectors. The lower PRAE value the stronger the ability of a collector to form a stable complex with a mineral. PRAE has shown a strong negative trend to complex formation on the mineral surface of aurostibite and stibnite. Based on these studies, several collectors have been proposed for effective flotation. To verify the feasibility of proposed collectors tetramethyl (ethyl) thiuram disulfides (TMTD and TETD) have been used for flotation of stibnite, sphalerite, pyrite and arsenopyrite. Flotation performance has been improved significantly with TMTD that allows the avoidance of lead nitrate application and increases the recovery of antimony by 8,16%. Keywords: Stibnite, aurostibite, activation, lead, copper, flotation reagents

Jan 1, 2020

By Elio Ferreira

This report describes the design, and development work performed to reduce the volume and weight of the miners caplamp battery, as well as a headpiece with a swivel mechanism containing a halogen bulb with two filaments. Work was also conducted in the development of a maintenance free battery. The design concept is based on non-sintered Ni-Cd technology, with an energy density of 22 Wh/lb. The cap lamp system developed has been approved by the Mine Safety and Health Administration (MSHA) and can be manufactured for mine use.

Jan 1, 1988