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By Henry Chumienski

Next to the paper industry, the steel industry is a major user of water. Without an adequate and reliable source of “good” water, steel cannot be produced. The use of water has a direct impact on steel quality and on our environment. Used improperly, water can also add unnecessary costs. Used properly, water can maintain and improve steel quality, enhance our environment and control or reduce the “total cost of operation”. Water needs to be more than just “wet and not lumpy”. Water quality needs to be based on the end use. This paper discusses ways to manage many of the water systems. With little or no capital investment it is possible to develop operating practices that protect your initial investment, ensure that the water systems do not have a negative impact on quality or your production costs and also minimize your chance of having an environmental incident.

Jul 30, 2018

The Australian coal industry has undergone sevenfold growth over the last 30 years and since 1985 has been the world's largest coal exporter. Three quarters of Australia's coal production is exported so its future is dependent on it remaining internationally competitive with other energy sources and other coal exporting countries. Coal is likely to increase its share of the energy market during the nine- ties as oil prices increase, new coal-fired capacity is commissioned and some form of nuclear energy is developed which is of acceptable safety standards to the community for use in the 21st century. Gas may take a part of coal's anticipated market share by the Year 2000. While coal exports will increase from China, Colombia, Indonesia and Venezuela and satisfy some of this additional coal demand Australia will also expand its export production, due to its existing advantages. The United States, Canada, South Africa, Poland and USSR seem unlikely to enjoy the same degrees of expansion and some, particularly Poland and USSR, will decline. Australia will always find it difficult to compete in the more distant markets due to levels of ocean freight, although its high quality coals will tend to partly offset such disadvantage.

Jan 1, 1988

By F. Rudloff, C. Karageorgos, J. Moyo, I. Boadi, M. Struble, B. Lumsden

Over it’s more than 100-year history, the Kennecott operation has often been at the forefront of innovation; driven by the demands of the lower grade ore-body and the higher costs of operating in the US where wages are generally higher and regulation more restrictive. One way of reducing operating costs in c/lb is to increase the lbs produced at minimal cost. Despite the relatively coarse grind at Kennecott - about 30% >150μm, approximately 20% of the Cu lost to tail is liberated chalcopyrite in the <20μm fraction, and about 30%-40% in the <37μm fraction. In 2020 Kennecott undertook a detailed plant scale test of the magnetic aggregation technology to increase copper recovery by reducing fine copper losses. A paired statistical plant test of magnetic conditioning on one rougher line showed a 1.12% increase in Cu recovery to 97% statistical confidence. The next challenge, unforeseen at the start of the project, was the fabrication and transportation to site of the equipment for the three remaining rougher rows, during the severe supply-chain constraints of the Covid pandemic in 2021. This resulted in delays and unforeseen costs as world-wide transportation became chaotic, particularly transportation via west coast USA. Nevertheless, the project was completed and commissioned, with only minor delays and cost increases, due to a flexible approach to overcoming the hurdles encountered.

Feb 1, 2023

By John D. Morgan

The United States is the world&apos;s most productive nation and its citizens enjoy one of the highest material standards of living of any people in the world. Materials and energy are the lifeblood of any industrialized economy. Annually the United States uses over 4 billion tons of mineral materials and fuels, or 40,000 pounds per person as detailed in Figure 1. Domestic processed materials of mineral origin and energy are valued at more than $150 billion annually, and they are derived largely from domestic sources, supplemented by imports, as detailed in Figure 2. In recent years the superior productivity of the United States has also enabled it to give food and manufactured articles to many other less fortunate nations and peoples of the earth. What then is our concern with materials at this time? Seeing the burgeoning increases in our mineral demand: from 2 billion tons in 1950, to over 4 billion tons today, and projected to 11 billion tons by 2000 - we are getting questions concerning our ability to continue to increase production sufficiently for the future.

Jan 1, 1974

By T. Emery, D. Sweet, J. Bourgeois, B. Seymour, D. Porter

Cemented rockfill (CRF) is being used to backfill primary and secondary stopes at the Eagle Mine, an underground nickel and copper mine operated by Lundin Mining. National Institute for Occupational Safety and Health (NIOSH) researchers from the Spokane Mining Research Division (SMRD) are conducting cooperative research with the mine staff to determine if the size of a CRF sample affects its measured strength properties. Based on previous research by NIOSH, cylindrical samples of CRF ranging in size from six to eighteen inches in diameter were cast at the mine and cured underground. The samples were later transported to the SMRD laboratory and the Michigan Technological University where tests were conducted to determine the strength and elastic properties of the CRF. To further analyze the relationship between backfill density and compressive strength, different ASTM International compaction techniques were used to cast the samples. For comparison, tests were also conducted on in-situ core samples that were drilled from a stope which had been backfilled with the same CRF mix. The data collected from this study not only improves our understanding of CRF in-situ properties but also helps optimize Quality Assurance/Quality Control (QA/QC) methods for backfill preparation and testing.

Feb 1, 2023

By Liangying Wen, Zhehan Liao, Jian Xu, Chenguang Bai, Chengfeng Sun, Kaihui Ma, Yang Xu

The difference on particle density causes mass and size segregation in the blast furnace throat, causing poor permeability in radial and circumferential direction. Understanding the effect of density difference on particle spatial-temporal distribution helps stabilize smooth operation and improve energy ef ficiency of blast furnace iron-making process. Based on discrete element method simulation, the influence of density difference on particle segregation behaviors is quantitatively characterized by the proposed method when the binary-sized particles are charged from parallel-type hopper of blast furnace. The results show that increasing the 4 mm particle density aggravates the mass segregation in circumferential and radial direction, and the maximum standard deviation of each ring reaches as great as 0.415. For size segregation, the difference on average mass fraction of small particle between center and edge ring decreases from 0.373 to 0.301. When increasing the 6 mm particle density, the similar particle segregation behaviors could be obtained.

Mar 1, 2018

By H. J. White

The effect of alloying elements on the mechanical properties and weldability of wrought gamma prime strengthened nickel- base superalloys is well known. An understanding of the basic guidelines concerning alloying additions has led to the invention and development of HAYNES® 282® alloy for applications in aircraft and land base gas turbines and other high-performance high-temperature environments. The alloy combines exceptional high temperature properties with good weldability and fabricability. At high temperatures (~ 900 °C), the alloy is stronger in creep strength than Waspaloy alloy (UNS N07001) and it approaches the creep strength of R-41 alloy (UNS N07041). Because the alloy has better thermal stability, fabricability, and weldability than Waspaloy and R-41 alloys, it is currently being considered as a candidate universal consumable for welding/ repair welding of gamma prime strengthened nickel based superalloys and it is also being considered as a suitable replacement for applications where R- 41, Waspaloy, and 263 (UNS N07263) alloys are currently being used. The alloy was designed to have improved resistance to strain age cracking, a problem common to gamma prime strengthened nickel based superalloys. In this paper, we present (1) results from hot ductility testing of annealed and annealed/aged material; (2) results from Time Resolved X-ray Diffraction (TRXRD) studies during a welding thermal cycle of annealed and annealed/aged material, and (3) gas metal arc (GMA) and gas tungsten arc (GTA) welding of annealed and annealed/aged material.

Jan 1, 2010

By E. V. Bratygin, S. P. Elnikova

"In the article carrying out technique of experiments for estimation of power efficiency of process of crushing in cone crushers «in a layer». The conformity of the granulometric characteristics of the crushed products obtained as a result of the tests, the theoretical equations for the size characteristics, and the choice of the optimal equation for the prediction of the granulometric characteristics of the final products obtained by crushing ""in a layer"". Optimization of granulometric composition of power of crushers working ""in a layer"" is carried out with the purpose of reduction of the electric power consumption at reception of a product of required quality. As a result of the experiments, dependencies are obtained, the relevance and applicability of the crushing process ""in the layer"" for obtaining crushed stone of improved quality is proved. INTRODUCTION A number of equations have been proposed for calculating the breakage energy. These include equations by Kirpichev and Kick, Rittinger and Bond (Bogdanov, Olevsky, 1982). Another equation for calculating the specific breakage work in breakage by impact and in stratum was proposed by Devyatkin (Boiko, 2003). In these equations, the breakage energy is proportional to the particle size raised to some power. In the equation proposed by Devyatkin, the ore piece thickness or the feed average diameter is used. The relationship between energy and breakage can be expressed as an equation (Lynch, 1981; Tikhonov, no. 3, 2008) where k is a coefficient characterizing the energy parameter depending on the strength of the feed, l is size in microns. The Rittinger formula is obtained for n = 2, the Kirpichev-Kick formula for n = 1, the Bond formula for n = 1.5. For n = 3 or higher, the equation describes fine and ultrafine grinding. R. Hookey proposed a formula (Lynch, 1981, Tikhonov, no. 3, 2008), where the size exponent n is substituted by a size function In all of the above equations, a single value of the feed and product size is used; for example, in the Bond equation, size is defined as the particle size of the 20% oversize (P80 and F80). However, a single size value can represent multiple distributions, making that the Bond method inappropriate for determining the size (Lynch, 1981). Describing an equation for estimating the grinding energy will allow to design the electric drive and ore preparation circuit for the given breakage method."

Jan 1, 2018

By S. K. Varma, Miriam Regalado, Daniel Salas, Erica Corral, Erika Esquivel

"Age hardenable 2014 aluminum alloys and composites containing 0.10 and 0.15 volume fractions of alumina particles (VFAP) have been solutionized at 540 and 550°C for up to 20 hours. The solutionized samples, heat treated for 5 and 20 hours, have been subjected to room temperature rolling until cracking develops. The work hardening curves have been compared to determine the effect of solutionizing time on the rolling characteristics from both hardness and the microstructural evolution points of view. Solutionizing at two different temperatures results in differences in the extent to which the composites can be rolled until fracture. The microstructural characterization by TEM has been performed to understand the room temperature rolling behavior.IntroductionThe effect of solutionizing on the age hardening response of 6061 and 2014 aluminum alloys and composites reinforced with 0.10, 0.15 and 0.20 volume fractions of alumina particles (VFAP) have been reported in the literature [1-4]. A comparison of the monolith and composites indicates that particles promote the aging process through differences in the microstructures in solutionized condition. The first effect of solutionizing is to produce a grain growth process which follows a grain growth law (square of grain diameter as a function of solutionizing time). It appears that it is possible for vacancies to be emitted during grain growth period as they try to minimize the total grain boundary surface area by increasing their diameter. This may be common to both the monolith and the composites. However, the second effect must be exclusively considered for the composites. The particles generate dislocations during the solutionizing process due to the differences in the values of the coefficient of thermal expansion (CTE) between the particles and aluminum base metal. It has been determined [1] that the dislocation density increases with increase in solutionizing time in the composites of 6061 aluminum alloys reinforced with 0.10, 0.15 and 0.20 VFAP. The improved bonding between particles and matrix can give rise to additional generation of dislocations due to curvature effects [1] with the result that the dislocation density continues to increase with increase in solutionizing time even after the CTE effect is considered to have been stabilized."

Jan 1, 1998

By D. L. Yopps

In research conducted by the U.S. Bureau of Mines, platinum-group metal (PGM) flotation concentrate from the Stillwater Complex, MT, was subjected to biooxidation using Thiobacillus ferrooxidans in an effort to break down the sulfide minerals and liberate the associated PGM&apos;s for subsequent chemical leaching. Bacterial preleaching oxidized up to 94 pct of the sulfide present, destroyed the PGM-bearing pentlandite [(Ni,Fe)9S8] mineralization, and dissolved most of the nickel in the concentrate. Cyanidation at 80° C proved to be the most attractive chemical leachant, removing 34 pct of the platinum, 76 pct of the palladium, 94 pct of the rhodium, and 97 pct of the gold from the biooxidized concentrate. Research also indicated that increased sulfide oxidation during the preleach phase led to improved PGM recovery in the subsequent chemical leaching phase.

Jan 1, 2010

By Albert R. Ledoux

In Great Britain all analytical chemists are styled assayers, but in the United states a slight distinction is made, assayers being considered those analytical chemists who have chiefly to do with the determination of the precious metals. There have grown up around the assayers of precious metals a number of customs and traditions which, as a rule, do not fetter American chemists when called upon to determine the composition or constituents of any samples submitted to them for analysis. In Great Britain, on the other hand, trade-customs even go to the extent of enforcing the employment of an admittedly erroneous atomic weight in certain alkali-determinations. If the American chemist is asked to determine the amount of lime in a water, potash in an alkali, or silica in an ore, the owner of the sample does not presume to suggest what method he shall employ, nor does he question his report on the ground that he should employ another method. But even in America it is different with the assayer. Unfortunately for the guild, as well as for those who have to base business operations on the reports of assayers, customs and traditions as well as divergent interests seek to circumscribe him in his choice of method and sometimes dictate how he shall perform his operations. This was true at one time of copper, which to-day in England is still determined by the so-called Cornish fire-assay, an attempt to imitate in the laboratory the various metallurgical operations in the smelting-works; but nowhere in this country is the assayer forced to employ any particular method for determining copper so long as his certificate indicates the true total percentage of copper in the sample. It is true that both buyers and sellers demand use of the electrolytic method, but only because it is the most accurate. In America the trade accepts the assayer&apos;s statement as final, and makes

Jan 1, 1895

By Francesco Montanari, Gianni Schena

"Recent improvements in X-ray computed tomography allow investigation of objects several tens of millimetres in dimension with spatial resolutions in the order of a few microns. These improvements are made possible by coupling the micro-focus technology adopted by some of the latest cone-beam X-ray sources with an increase in the efficiency of the detectors. The micro-focus technology allows the production of clearer images at high magnification by reducing the penumbra (fuzziness) associated with larger focal spot size.Even higher resolutions can be expected in the next few years with the commercialisation of nano-focus X-ray tubes. In practice one can inspect a system of fine composite particles and analyze the different mineralogical phases in each individual particle. Computed tomography allows accurate liberation studies, e.g. providing liberation spectra or washability data in tens of minutes. However, on-line application of micro-focus computed tomography is unlikely in the foreseeable future, despite rapid development.Dual-energy (DE) radiography is another X-ray technique, which allows retrieval of the volumetric content of valuable components in two-phase particles in a fraction of a second. A digital radiograph of a single two-phase particle produces a grey level image, where the luminosity of the pixels is determined by the sum of the attenuation levels of all the structures. Thus morphological and compositional effects concur to produce the radiographic image, which does not allow retrieval of the composition of the particle, as the 3D-structure of the particle is compressed into a 2D-image, with an obvious loss of information. Thus, in principle it is not possible to discriminate between thick, comparatively penetrable, and thin, comparatively impenetrable mineralogical components."

Jan 1, 2003

By Alessandro Navarra, Aldo Quelopana

Sophisticated models have progressively been developed to address the challenges related to long-term, openpit mine planning under conditions of geological uncertainty. Prior research has acknowledged that strategies for mine planning and the design of mineral concentrators are interdependent; thus, it is highly desirable to optimize them together. However, achieving detailed holistic optimization of the mineral value chain remains unresolved because of the inherent limitations associated with mathematical formulations and computational processing capacity. This paper details a method that contributes to bridging these limitations by employing a novel parallelized variable neighborhood descent approach combined with an embedded mass–balance component using linear programming techniques refined through Dantzig– Wolfe decomposition. This approach is exemplified through a case study of a gold deposit, which illustrates the enhanced performance capabilities of the new algorithm. The findings demonstrate significant improvements in the optimization process for mine planning, providing a stronger link between the mine’s output and processing plant’s capabilities.

Mar 1, 2025

By E. P. Youngman

Before the World War the use of zirconium and its compounds was largely experimental and confined almost wholly to Germany and Austria . Occasionally small lots of zirconium ore had been produced in the United States ( 1,000 pounds in 1869 , 26 tons in 1883 , and 3,000 pounds in 1903 ) and used (with monazite ) in the manufacture of various lighting devices , especially incandescent gas mantles ; but it was not until 1906 that the discovery of the natural zirconium oxide in large quantities near Sao Paulo , Brazil , first gave promise that a zirconium industry eventually might be developed . Edward Rietz , who worked the Brazilian deposits , interested German chemists in extending the use of zirconium , and by 1911 trade journals were listing German firms as manufacturers of compounds or products derived therefrom . For a time zirconia was one of the various oxides used in the Nernst lamp . It was used also for crucibles and hearths as refractory material ; in the manufacture of chemical utensils ; in enamels ; in the place of bismuth subnitrate for defining Röntgenray pictures of the stomach ; as a pigment ; in medicine ; and in a number of other ways . The Germans were credited also with producing a remarkable zirconium steel , which , it was claimed , was much superior to other alloy steels . During the World War the United States Government investigated the possibilities of zirconium , as well as those of other steel -hardening elements , and a large automobile manufacturer actually purchased a substantial quantity of ore with the purpose of employing zirconium in automobile steels . Immediately after the armistice the Government ceased its investigations ; but despite the difficulties experienced by various investigators in reaching concordant results , interest in the use of zirconium as a steel -hardening agent , as well as in other uses of the element and its compounds , continued . In 1918 the Foote Mineral Co. , which had been interested in zirconium for several years , was exploiting the deposit in Brazil formerly worked by the Germans and was supplying zirconia in the form of ore , brick , and cement for refractory and other purposes . About the same time the Electro Metallurgical Co. , which before the entrance of the United States into the war was experimenting with zirconium alloys , supplied in tonnage quantities the demand for these alloys . In 1919 it was reported that American manufacturers , after several years of research, were producing in commercial quantities pure zirconium oxide , which was finding a place in the manufacture of small refractory articles , scorifying dishes , crucibles , tubes , and one- piece furnace linings . In 1920 the lowering of the price of zirconium metal powder ( because of improved metallurgical methods ) promised the production of the metal on a semicommercial scale . In 1924 the Titanium Alloy Manufacturing Co. introduced a new opacifying agent , " Opax , " made from zircon . A year or two later some of the large pottery manufacturers became interested in the use of zirconium oxide as an opacifying agent , the increased production of titanium pigments having resulted in the production of zirconium as a by-product at a price that could compete with tin oxide . In 1928 it was reported that the industrial use of zirconium oxide was increasing steadily in the manufacture of brick , crucibles , and other refractory products , such as high- temperature cements . However , the reluctance of producers to install additional and more suitable

Jun 1, 1931

By S. A. Kondratyev

"The present research work aims at disclosing the dependence of flotation concentrate recovery and its grade on the physically adsorbed collecting reagent properties, viz., surface pressure in the reagent film at gas-liquid interface, velocity of reagent species spreading over the said interface, relation between interaction energies of collector molecules within a film and with water dipoles.When using a single collecting reagent it is possible to improve the flotation concentrate grade in two ways, namely, by reducing collector consumption rate or using a weaker reagent. According to the proposed mechanism, a decrease in the physically sorbed species of the collector leads to a decrease in the rate of removal of the kinetic restriction of a flotation contact formation. As a result, the recovery of the useful component is reduced and the content of valuable components in the flotation concentrate is increased. The relationship between the spreading velocity of physically sorbed species at the gas-liquid interface and the recovery and quality of the flotation concentrate has been experimentally proved. Reduction in collector consumption lowered the valuable component recovery at a higher grade of the concentrate.The reasons were established for a rise of valuable content in the flotation concentrate if a weaker collector was used. It is justified that the use of a weaker collecting reagent with a shorter hydrocarbon fragment declines physically sorbed species of collector. The spreading velocity of collector derivatives at gas-liquid interface tends to lower along with less participation physically sorbed species of collector in formation of a flotation aggregate. The spreading velocity is determined for products of interaction between butyl-and ethyl-xanthates and lead nitrate at gas-liquid interface. It is found that the spreading velocity of butyl-xanthate derivatives is higher than that of ethylxanthate derivatives.The research work gets insight into the nature of relation between useful component content in the flotation concentrate and the useful component recovery. It is pointed out that adjusting the collecting activity of a collector makes it possible to influence a useful component content in the froth product thus gaining a compromise between wanted grade and recovery parameters."

Jan 1, 2018

By Egil Krystad, Merete Tangstad, Kai Tang, Gabriella Trenell

"A new UMG-Si refining concept has been proposed in this paper. Liquid Si and another liquid metal phase (Me) were separated by the molten slag spontaneously based on their different physicochemical properties. Two metal/slag distribution reactions are able to occur in the system simultaneously. Experimental investigation on the B and P distribution equilibria among Si/slag/Me was carried out in the graphite resistance furnace under the inert atmosphere. The B and P doped silicon was in equilibrium with either the SiO2-CaO or SiO2-CaO-l0%CaF2 slags at 1600 and 1650°C, respectively. The pure Fe and Cu metals were used in order to ""capture"" B and P in the slag phases. B and P in samples were determined by the ICP-MS. B and P distribution coefficients for the Si/slag/Me equilibria were compared with the theoretical calculations. The possible kinetic barriers for the Si/slag/Me three-layer equilibria have been analyzed. The metal contaminations in the three-layer equilibria were also examined. The present study provides a new approach for the refining of MG-Si.IntroductionMost of the impurities in the metallurgical silicon (MG-Si) are rather ""dilute'', ranging from few to several thousand ppms. However, the target impurity levels for upgrade metallurgical silicon (UMG-Si) feedstock are often far below the level of ppm. In such extreme case, the conventional refining technologies face the great technical challenges. B removal by slagging has already been implemented industrially. Removal of Pis frequently carried out by the vacuum distillation. The separating treatments for B and P removals lead to increase refining cost, total CO2 emission and longer pay-back time of solar cell module.It is well known that the phosphate capacities of slags in equilibrium with liquid silicon are extremely lower. However, if we introduce another phase that possesses high ""phosphor capacity"" into the Si/slag system, one would expect to continuously remove P from Si through molten slag to the new ""phosphor capturer"". The so-called three-layer refming concept is thus proposed in the present study. Liquid Si and another liquid phase (Me) are separated by the molten slag spontaneously based on their different physicochemical properties. Two metal/slag distribution reactions are able to occur in the system simultaneously."

Jan 1, 2013

By T. R. Ellis

The valuation of mineral properties in the U.S. is only partially regulated. The regulations which have jurisdiction or impact appear to have such mainly as a consequence of unintended fallout, since the regulations were designed for other purposes. Court case history can also be important. The combined results are a mixture of bad and good, with important lessons to be learned. Since 1981, the Securities and Exchange Commission has prohibited U.S. listed companies from reporting quantitative estimates of mineralization and the value of mineralization, other than proven and probable reserves. This results in the minerals appraiser (valuator) working with a shortage of data in his everyday work, both on the subject property and in sales analysis. Between 1989 and 1995, all 50 states and essentially all federal agencies adopted the Uniform Standards of Professional Appraisal Practice (USPAP) for real property appraisals (valuations). The major national appraisal societies also require their members to abide by USPAP. A significant portion of minerals appraisals must now follow these standards. This paper will discuss the content of USPAP. It provides a very good framework for the valuation of a minerals property or a mine, both as real property and as a business. However, the credentialing standards for real property appraisers are now prohibitive for minerals appraisers.

Mar 1, 2002

By T. R. Ellis

"The valuation of mineral properties in the U.S. is only partially regulated. The regulations which have jurisdiction or impact appear to have such mainly as a consequence of unintended fallout, since the regulations were designed for other purposes. Court case history can also be important. The combined results are a mixture of bad and good, with important lessons to be learned.Since 1981, the Securities and ExchangeCommission has prohibited U.S. listed companies from reporting quantitative estimates of mineralization and the value of mineralization, other than proven and probable reserves. This results in the minerals appraiser (valuator) working with a shortage of data in his everyday work, both on the subject property and in sales analysis.Between 1989 and 1995, all 50 states and essentially all federal agencies adopted the Uniform Standards of Professional Appraisal Practice (USPAP) for real property appraisals (valuations). The major national appraisal societies also require their members to abide by USPAP. A significant portion of minerals appraisals must now follow these standards. This paper will discuss the content of USPAP. It provides a very good framework for the valuation of a minerals property or a mine, both as real property and as a business. However, the credentialing standards for real property appraisers are now prohibitive for minerals appraisers."

Jan 1, 2002

By Johan Richaud

Achieving high surface quality steel in the continuous casting process requires optimal mould level control. The design of the casting channel from the tundish to the mould is crucial to prevent formation of undesired instabilities or biased flows that can cause level fluctuation. With the aid of CFD and with physical water models, the geometry of the stopper nose and the nozzle seat have been studied and optimized to improve the overall mould flow stability. A special stopper nose; Ripple Stopper (RST), has been developed that reduces the formation of large and unwanted eddies in the liquid steel that destabilize the port exiting jets. Instead, the RST produces a fast release of turbulence in the form of a large number of small eddies. The large sudden fluctuations in the mould level are reduced, which in turn reduces the occurrence of surface defects. An additional benefit is derived from the local pressure around the stopper nose region being greater which reduces the refractory erosion. For a tundish gate type flow regulation, a new design encompasses an offset in the Tundish Well Nozzle (TWN) that realigns the flow and reduces the bias flow that is common to tundish gate regulation. The steel recirculation regions below the throttling gate are decreased reducing the risk of oxide depositions. The RST and the Offset bore casting channel have been applied successfully leading to a superior flow control performance between the tundish and the mould.

Jul 30, 2018

By Toshiaki Akahoshi

Keywords: Wasted catalyst, Hydrodesulfurization, Ammonium vanadate, Ammonium molyb-date, Hydrometallurgical process. The fundamental reactions have been investigated in order to develop a hydrometallurgical process for recovery of molybdenum and vanadium from wasted catalysts generated in the hy-drotreating desulfurization of heavy oil. The principal steps of the process are a mild oxidation roasting of the waste catalysts at temperature around 500°C, leaching of the target metal components with dilute ammoniacal aqueous leachates, selective precipitation of vanadic acid, and ammonium molybdate precipitation. The selective recovery of vanadium as vanadic acid is successfully performed using ammonium sulfate as a salting-out agent. Recovery of ammonium molybdate is based on large dependence of solubility of ammonium molybdate in ammoniacal solutions upon temperature and ammonium salt concentration. In this process, the solution after recovery of vanadium and molybdenum is recycled to the leaching stage of the roasted materials, and the ammonium salts in the process liquor is in the repeated use. Employment of am-moniacal system makes it possible to operate the roasting at much lower temperature than that for the currently operating process.

Jan 1, 2005