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By AIME AIME

PLANS are now well advanced for the joint meeting of the Institute and over a dozen other engineering societies in Chicago during the week beginning June 26: Engineers' Week at A Century of Progress. All engineers planning to visit the Fair will find it to their advantage to be present at this time so far as the Chicago attractions are concerned, and Eastern members will also have the advantage of special transportation arrangements on June 24 and 25. The tentative program is given at the bottom of the next page. Monday morning, June 26, will be reserved for registration of members and guests and the Woman's Auxiliary at the Stevens Hotel, where special rooms will be provided. A luncheon will also be served there, and in the afternoon, a technical session on nonmetallics. Instead of having the big family dinner that evening at the Stevens, as at first proposed, the local committee has planned to have it at the Fair Grounds, where special facilities have been arranged. A meeting of the Board of Directors and a few invited guests will precede the dinner. All members and guests are likely to be interested in visiting the Museum of Science and Industry, so that will be the sole event on the program for Tuesday morning, June 27. The big attraction there at present is the model coal mine, the first operative coal mine ever built for exhibit purposes. It is based on the Deutsches Museum mine at Munich, but goes far beyond that in realism, and takes the visitor on an extended tour underground. It shows him in half an hour more types of modern mining machinery and coal geology than he would be likely to see in a week's underground study in the coal fields. The Institute members will be the first group to go through this mine.

Jan 1, 1933

By A. N. Chirico

This paper reviews the three major distillation processes: multiple effect (LTV) evaporation, multi-stage flash distillation and vapor-compression forced circulation evaporation. Scale preventative measures are discussed for all saline water applications. Operational data is presented on the Freeport, Texas, demonstration plant, which is the first government facility to produce one million gallons per day of fresh water for a municipality. There has been much publicity concerning the water crisis that confronts many peoples today. There is little doubt that the arid regions - which include the Middle East, parts of Africa and the Caribbean — have suffered to no slight extent for the lack of this most precious commodity. But what about our own country? Government experts have extrapolated demands and flatly predict that by 1980 we will be faced with a shortage of 80 billion gal per day. The validity of this prediction has been disputed by others; however, it appears certain that there will always be a natural abundance in some areas, a shortage of supply in other areas. Distributing our total natural water resource equitably would be impossible. Transmission of water by means of aqueducts can be an expensive undertaking. The controversial Feather River Project in Calif. is an example. The estimated cost for this venture is a staggering three billion dollars. As our population continues to increase and our standard of living rises, agricultural and industrial requirements will be proportionate. What can be done to avoid a crisis? We can conserve and use our water for industrial and irrigation purposes more judiciously: we can attempt to eliminate pollution of our natural resources from sewage and industrial wastes; we can develop, while there is time, saline water conversion processes for the massive production of low cost fresh water. The scope of this paper will be limited to only the distillation type processes that are commercially feasible. The first step in making potable water is to find a source of raw material. An inexhaustible supply is provided by oceans in coastal regions, but the supply of water is more critical in the inland communities of our country. The source of raw material in these. regions is brackish well water and this must be utilized. There is a significant process difference when handling brackish water compared to seawater and this brings out an important fact: No single conversion method can be universally applied to solve all the water problems. Composition of the raw water and degree of distillate purity are factors which must be considered before a particular process is selected. Local conditions at the plant site, fuel costs, labor costs, disposal facilities, etc. are other equally important factors which must be evaluated. WATER CONVERSION PROCESSES Conversion processes commercially feasible today are: 1) multiple effect evaporation, 2) multiple flash distillation, 3) vapor compression distillation and 4) electrodialysis. The first three are distillation processes which take potable water out of the raw water, while the fourth is a membrane process which takes out the salt. In addition to the above there are a good number of other promising methods for production of potable water, many of them in the basic research stage. Freezing is another promising process with commercial potential. This process hinges upon the formation of ice crystals which are free of salt occulsions. Separation and washing of the crystals are problems that must be solved before this process can be considered commercially feasible. Freezing processes have several advantages mostly attributable to the low temperature of operation. This low temperature reduces the scaling and corrosion problems encountered in higher temperature operations. Several different freezing processes are being considered and will be tested in the pilot plant at Wrightsville Beach. One process is a flash freeze process, a second uses a secondary refrigerant such as butane for freezing, and a third process employs a secondary refrigerant particularly controlled to produce large ice crystals. Of the above processes, only the distillation processes are reliable when water of high purity is re-

Jan 1, 1963

By Charles Will Wright

The present struggle for economic and industrial supremacy by the Communist world is against the United States, its main target, and the other Free World nations. The basis of industrial power is minerals, so the Communist nations are building up mineral production within their borders, often regardless of costs, and are acquiring quantities of mineral products from Free World countries for future use. They are contracting for additional supplies and advancing funds for the development of these quantities. A number of the less developed mineral producing countries of the Free World are being infiltrated by Communists and Communistic influence. This situation is well known, but as yet little has been done to oppose these activities or to awaken the public to their seriousness. The Communist countries are still far behind the Free World Nations in production of many essential minerals. But, shortages are being made up from Free World nations in exchange for petroleum, manganese ore, chromite and other products. Restrictions on shipments of strategic materials to Communist countries have not been maintained.

Jan 1, 1964

By Francis X. McCullough

After OSHA published a Notice of Proposed Rulemaking on August 5, 1983, to revise its standards for Underground Construction, many contractors and their representative associations became concerned by the sweeping changes in the proposed rule. After reviewing all of the evidence and testimony on file with OSHA, the contractors presented extensive written and oral testimony to the Department of Labor in Washington, D. C. to help insure that the final published rule would be effective without jeopardizing the economic viability of the industry. The results of those efforts, the entire OSHA rulemaking process, and the opportunity for the construction industry to participate in that process will be discussed.

Jan 1, 1985

By Rimas Pakalnis, Andrea M. Ouchi, Thomas M. Brady, Mary M. MacLaughlin, Cristian Caceres, Paul Hughes

A major focus of ground control research presently being conducted by the Geomechanics Group at the University of British Columbia, Canada, in conjunction with the National Institute for Occupational Safety and Health’s (NIOSH) Spokane Research Laboratory, is the development of design guidelines for underground mining within weak rock masses. The study expands upon the span design curve for man-entry operations and the stability graph for nonentry operations developed at UBC by extending the application to weak rock masses. The original database has been augmented by weak rock mass information from mines throughout the United States, Canada, Australia, Indonesia, and Europe. The common factor in all of these mines is the presence of a weak back and/or walls. This paper expands on the North American database and how the design curves have been employed at mining operations throughout the world. The definition of a weak rock mass for this study has been defined as having an RMR76 under 45% and/or a Q-value under 1.0.

Jan 5, 2007

By John C. Edwards, Robert C. Bates

Modeling uranium mine radiation control methods and natural environmental radon variations is an extremely complex endeavor. A number of authors have examined particular facets of the problem and have proposed models for their area of interest. Bureau of Mines personnel brought together many of these individual studies, and from them have attempted to develop a coordinated plan for modeling radon daughter concentrations in the uranium mine environment. This approach is described.

Jan 1, 1981

By G. V. Krishnan, L. Adler

A rock classification for drilling and boring is presented covering most equipment types and providing an estimation of the key parameters for operation, such as thrust and speed, and of performance such as penetration rate and bit life. Drilling and boring are significant and integral aspects of both the mining and heavy construction industries. Together these constitute over 20% of the G.N.P. Drilling and boring represent the most arduous mechanical processes performed in industry. Their misapplication quickly leads to equipment destruction, hazards, and to major delays. The classification is unified in two ways: 1) for a particular rock class several parameters can be estimated, 2) the classification integrates most excavating activities (i.e. digging, ripping and even blasting), and is derived from ground control. The rock classification provides a job property, based on fundamental and index properties, which yields quick and rough estimates of vital information. However it does not obviate the need for a more thorough analysis, and maintaining field records. BACKGROUND In order to adequately describe a drilling operation the conditions, activity, and equipment must be characterized. Of these the major independent variables are the conditions. Conditions focus on the geologic mass and also consider whether the site is surface or underground. The primary component of the geologic mass is the rock type, detailed below in Rock Characteristics. The other components

Jan 1, 1983

By Leslie F. Sawatsky

Each potential oil sands developer deals with the question of optional sources of raw water to supply large water demands that range from 50 to 80 million cubic metres per year for each of six existing and planned developments. The Athabasca River currently supplies nearly all of the water to the existing mines via conventional bank intakes, which has resulted in some concern over the effects of reduced river flows. This paper describes the various water supply options, and the likely scenario for future oil sands water supply projects. Various water supply options have been suggested including Athabasca River water via infiltration galleries, groundwater, combined Athabasca River water and alluvial groundwater using wells (i.e. bank filtration systems), diversion of tributary rivers, utilization of large lakes in the region and pumping from other large rivers in the region. Investigations show that the size of river catchment needed to support raw water usage by a typical oil sands mines exceeds 5,000 km2 eliminating all tributary rivers that are located in the oil sands region except those rivers with large drainage areas like Firebag and MacKay Rivers. Lakes cannot be used as a source of supply due to large water deficits for smaller lakes and the large cost of sourcing water from a lake as large as Lake Athabasca. A groundwater source alone would not likely meet the large water demands. River intakes on the Athabasca River will likely continue to be the most practical water supply option for oil sands mines north of Fort McMurray, although various types of Athabasca River intakes are possible. Existing intake systems include screened riverbank intakes, forebay intakes, and river bottom intakes. Infiltration galleries are not feasible for most sites, though some bank-filtration-type systems using high capacity wells may be an option if there is sufficient thickness of high-permeability alluvium at a suitable location in the Athabasca River valley.

May 1, 2004

By Brian Hester

Many Third World African countries are well-endowed with minerals - especially gold and diamonds - while only a few have important base metal deposits. For decades since colonial rule, political and economic conditions discouraged interest by Western capital. Influence from Soviet Bloc countries, however, has declined with the move toward multi-party rule. And the left wing orientation, once widely favored by Third World African countries, has almost disappeared. With International Monetary Fund (IMF) encouragement, these Third World African countries now encourage representational government and solicit western finance to expand their industries. Mining is especially encouraged. The North American mining industry is following the same trail as other capital intensive industries and looking abroad for opportunities. The Prospectors and Developers Association of Canada released figures that show exploration expenditures in that country were halved between 1987 and 1990. Figures for the United States are not so easily found but every indication points to a downward trend. While total annual expenditures on US exploration by corporations as a group are either declining or remaining constant, expenditures away from North America is increasing. Gold exploration expenditures in 1991 by the major companies tracked by Minerals Economics Group were less in the United States than for Latin America and the Southwest Pacific combined. The same study showed as much was spent in the Republic of South Africa and "Other" areas combined as in the United States. Expenditures by major corporations in these "Other" areas amount to only 5.2% of their total budget. Third World Africa is a major component of these "Other" areas.

Jan 1, 1993

By Donald A. Deardorff

The capacity of a helical pile can be determined analytically using the individual bearing or cylindrical shear methods which are dependent on soil strength parameters and helical bearing area. The torque correlation method is widely used in the helical industry to determine the capacity during installation by monitoring torque during the final seating of the helicals. This method has been shown to be a better predictor of strength than the individual bearing or cylindrical shear methods. To determine capacity using the torque correlation method, the final average installation torque (ft-lbs) is multiplied by an empirical torque correlation factor (Kt, ft-1). Kt values have been well documented for square bar shaft helical products and can vary from about 3 to 20 ft-1 depending on pile geometry and soil type. A default value of 10 ft-1 is generally used for all square shaft sizes and soil conditions. Less research has been done on determination of Kt for round pipe shaft helical products. Studies have indicated that factors which affect Kt include soil type/strength, number of helical plates, helix spacing, helix pitch, depth of embedment, downward pressure (crowd), shaft diameter (round pipe) and load application direction while other studies have discounted some of these factors as inconsequential. This paper reviews past research findings regarding Kt determination for square and round pipe shaft helical products and presents a case history of round shaft helical pile installations in Chicago clay which resulted in much lower than expected Kt values.

Jan 1, 2007

By Thomas Oberndorfer

Recent publications indicate that there is a rising interest in the field of mining method selection, and increasing efforts are being undertaken to develop satisfying solutions. Yet, computer assistance for mining method selection (MMS), or in other, terms assistance in the (pre-)feasibility state of a project, still lags behind the computer application in other mining activities. This is true for research as well as for application. This paper is intended as a contribution to the development in computer-assisted mining method selection, and focuses especially on underground hard-rock mining. It is structured in four main parts. The first deals with general aspects of mining method. selection within the process of mine planning, and with problems and requirements which derive from this specific situation. In the second part some numerical MMS-approaches hitherto published are briefly introduced, and investigations on these approaches are discussed. Based on .these experiences, in the third part an analysis of the complex system MMS is presented. It focuses on heuristics, influencing factors, objectives, assessment-routines and mining methods, and emphasizes the essential necessity of a profound mining method description (MMD) specially developed for the requirements of MMS and numerical processing. Accordingly the fourth part of this paper presents a mining method description model developed at the Department of Mining Engineering, Montan-University Leoben (MUL), Austria. It describes the consequences of the investigation, in particular the new mining method description model, on 'the design of a MMS-system. The paper closes with a outlook on the possibilities of an successful MMS-system being realised.

Jan 1, 1992

By H. E. Peterson

A study was undertaken by the Bureau of Mines to develop a simple, reliable test for field detection of selenium in rocks and soils. Two methods are described for qualitative detection of selenium, dependent upon its form of occurrence and the presence of interfering constituents in the sample. Both methods involve fusion of the sample in a test tube to form elemental selenium that will volatilize and condense as a red deposit on the cooler upper portion of the test tube. The methods are sensitive to 10 parts per million, (p.p.m.) equivalent to 0.001 percent, and can be made semiquantitative by using suitable standard samples. INTRODUCTION Although selenium is widely distributed in the United States, the known deposits are either so small or so low grade that they cannot be processed economically for selenium alone-4/ At present, commercial production is a byproduct of the smelting and refining of base-metal ores, particularly copper.5/ About 0.75 pound of selenium is recovered per ton of electrolytic copper, and small amounts are recovered by special treatment of assorted smelter dusts and fume products. Since selenium is a strategic metal in short supply, new sources are being sought by both Government and private interests.

Jan 1, 1957

By Andrew Corry

GEOPHYSICAL investigations based on radioactivity have been applied to the earth's crust for the purpose of discovering bodies rich in radioactive substances, or for the location of solutions with high emanation or radioactive-salt content, or for the detection of oil, which, in virtue of colloidal properties, has strong powers of radioactive absorption. RADIOACTIVE SUBSTANCES Radioactive substances are distributed in all rocks, waters, and gases in the earth's crust in small quantities. Granites and similar acidic rocks are richest in uranium and thorium, two chief radioactive substances; yet the quantities present in such rocks are of the order 10-12g., this concentration being expressed in grams per gram of the whole substance per cubic centimeter. In granites the uranium yields, according to Haddock, 3 X 10-12 g. of radium per gram of rock. In basalts the uranium yields 1.19 X 10-12 g. per gram per cubic centimeter. Of thorium the granites yield -2 X 10-5 g. per gram of rock; the basalts, 0.77 X 10-5 g. per gram. Certain series of alkalis of low atomic weight, like potassium and rubidium, show weak radioactivity; this property has no significance so far for geological research. The uranium is esti-mated indirectly from the electrical properties of one of its derivatives as a -gas (emanation) into which it is transformed. The thorium is expressed directly, though it is measured as a derivative, thorium emana-tion. There is a measure for the gaseous radium emanation, the curie, which is that quantity of radium emanation, or radon, which stands in equilibrium with 1 g. of radium. The concentration of the emanation is the Mache unit corresponding to 3.64 X 10-10 curie per liter. When gases become permeated by alpha, beta, and gamma rays, plus and minus ions are produced in them by the decomposition of neutral gas molecules, and under the influence of an electrical field these ions are given opposite motions. The measurement of the alpha rays and the bisection thicknesses of the beta and gamma rays is a means of analyzing unknown radioactive substances. These rays accompany the disintegration of radioactive substances and arise from "spontaneous internal changes

Jan 1, 1929

By A. F. Lucas

EACH day, the fact becomes more evident that the ever-growing demand for oil is farther outstripping production, regardless of the increase in output throughout the past twenty years. The development of known oil fields and the prospecting for new ones along present lines are not resulting, in, and cannot bring forth, supplies large enough adequately to meet the oil needs of the country. The usual methods of prospecting-for new supplies are insufficient to meet the exigencies of the situation which threatens, in the not distant future, to reach a critical stage. Were it not that within the last two years new and prolific oil fields have been discovered in northern Louisiana, central Texas, and California, this crisis would undoubtedly be now at our door. Stocks are being exhausted in spite of the rapid growth of imports. The time is therefore fast approaching when some radical departures must be made in the method of prospecting and developing old and new fields in order to increase our oil supplies. Methods and chances, that have seemed unwarranted will not only be given serious consideration, but, according to the results promised, will be put to the test. Meanwhile, however, nearly all the oil fields are responding to the stimulus of higher prices, whereby enormously growing capital is attracted to this important industry, both here and abroad; the increase in our petroleum production at the present time is due to this circumstance. Yet, although a most active search is being made for possible sources of additional supply, one section of our country is not yielding the results that, in my opinion, it is capable of producing: I allude to the coastal dome belt of Texas, Louisiana, and Mexico. The United States Geological Survey has estimated that three-fourths of a billion barrels are available in the ground in the Coastal Plain of the two states just mentioned. Numerous papers have been written on the subject of the salt domes of the Coastal Plain and more or less attractive theories have been advocated by leading geologists to account for their origin and the presence of the oil, sulfur, and salt associated in them. However, owing in part to the generally monotonously level country in which the coastal

Jan 9, 1920

By Warren A. Sinsheimer

ProbDly there has never been a year during which the petroleum industry expended so much effort as in 1929 in an attempt to rectify its ills. Eventually good will undoubtedly result, but as yet there have been no marked changes from the unhappy conditions familiar to all. Throughout the year remedies were sought that would cure the long-existing troubles of overproduction and waste. Proration of production and voluntary curtailment of output, for a short time considered the means for stability, not only failed but contributed to further waste and created a false sense of security. It encouraged a high rate of field development, weakened the economic structure by excessive development of newly discovered reserves and absorbed large sums of capital yielding meager or negative return. The manufacturing of gasoline by refiners without regard for market requirements furthered the unsatisfactory condition by falsely stimulating the demand for crude and placed on the market an oversupply of finished products, particularly gasoline. The marketing section of the industry has made progress by its adoption of the Code of Ethics as promulgated by the Federal Trade Commission and by the formation of an Export Association. The year 1929 opened not only with a current supply of oil exceeding demand but with an additional daily shut-in and potential supply variously estimated at from 3,000,000 to 5,000,000 bbl. This situation stimulated the industry, through the American Petroleum Institute, to attempt to work out an economically sound solution which would further conservation by bringing supply and demand into closer balance. Production Control After a thorough study of producing conditions, the committee of the American Petroleum Institute had for its recommendation that the production of crude oil in 1929 be held in check to an amount equal to that produced during the year 1928. The Federal Oil Conservation Board heard the appeal of the American Petroleum Institute and referred the matter to the Department of Justice. It was ruled that neither the Federal Oil Conservation Board nor the Department of Justice had the * Land and Oil Production Dept., Henry L. Doherty & Co.

Jan 1, 1930

By Bockhorst R. W, Christopher D. A

Over the past fifteen years, horizontal drilling in coal seams for advance degasification has become an established practice in the United States of America. Consolidation Coal Company pioneered the development of the horizontal drilling system and licensed the technology in the U.S. A. and to Du Pont (Australia) for commercial production. This paper discusses the most recent developments in the equipment design, especially the borehole telemetry system, known as the Downhole Drill Monitor (DDM).

Jan 1, 1988

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

The Beloziminskoe deposit in Siberia is a large, potentially productive deposit of rare metals contained in ochreous apatite pyrochlore ores formed by weathering of a carbonatite. The ores are composed of pyrochlore, columbitized pyrochlore, monazite, apatite, magnetite, ferric and manganese hydroxide, titanic iron ore, zircon, hydromica, quartz, feldspar, and carbonates. A gravity-flotation enrichment flowsheet with application of cationic and anionic collectors has been developed. This flowsheet allows for obtaining a pyrochlore concentrate containing 44.3% Nb2O5 and 1.89% P2O5 with recovery of 55.83% Nb2O5 as well as an apatite concentrate containing 39.2% P2O5 and 1.05% TR2O3 with recovery of 62% P2O5 and 43.23% TR2O3 from ores containing 0.92% Nb2O5, 16.9% P2O5 and 0.6% TR2O3. Rare-earth concentrate containing 40% TR2O3 with recovery of approximately 10% TR2O3 was obtained at the same time. Major losses of valuable elements are related to slimes, which make up more than 50% of the ground ore. The niobium concentrate does not meet the phosphorus and radionuclide concentrations needed for the production of ferro-niobium. Acid leaching and sulfatization provided a high level of phosphorous and radionuclide removal. Conditions include hydrochloric acid pre-leaching at 75- 80°C with an 18% HCl solution for four hours and low-temperature sulfatization of acid-leached concentrate at 160-180°C for one hour followed by water leaching of the residue. The apatite concentrate could potentially be processed using nitric acid leaching. This technology is based on decomposition of apatite concentrate with 55-57% strength nitric acid with transfer of rare-earth metals into solution in the form of ammonium phosphate. This technology recovers a rare-earth concentrate containing 95% TR2O3 with extraction of 86%, and highly concentrated polynutrient fertilizer (ammophos) with phosphorus extraction of 95%. The completed research shows how complex multicomponent ores of residual soil may be processed for the extraction of niobium, phosphorus, and rare-earth products.

Jan 1, 2016

By E. I. Jurgens, K. E. Hanney, D. C. Comrie, R. H. Fletcher

Introduction The reclamation of mine/mill tailings areas is undertaken for a variety of objectives including safety, appearance, economical use of lands and forests and long term storage of a future resource. The establishing of criteria for these objectives at any site is a shared task of the government and mining company. Our attention in this paper is directed to uranium mine/ mill tailings as they are handled in the Canadian industry and in the unique Canadian climate. We focus our attention on the state of the art. Uranium is a ubiquitous mineral forming an average of 4 g per tonne of the Earth's crust. Ores are mined at about 500 g per tonne so that the residual content of uranium in tailings is comparable to average background levels. However, as in most mine/mill operations, the ore contains other minerals that become readily mobile after milling operations. Thus the main objective of tailings impoundment is the stability both physically and chemically of the mobile materials. Since the requirements for the operation and construction of tailings areas in Canada have changed considerably over the past decade, there exists a great many mine/mill tailings areas which while considered adequate in their day, would not meet modern criteria. However, most of these installations pose no concern or hazard to the public. The proximity of mine/mill development to inhabited land areas has necessitated more stringent modes of tailings operations and provisions for tailings site reclamation. The more important of these have been: 1) the prevention of dyke failure, with large liquid-solid outflows onto adjoining lands, and 2) the prevention of seepage from the tails of pollutants such as chlorides, sulphides, heavy metals and radionuclides. Uranium mill tailings are discharged as a slurry from the concentrator after the removal of generally only about 1000 g, or less, per tonne of uranium from the as-mined ore. As a consequence, a great volume of low level activity waste is generated. The amount of tailings is expected to grow in quantity in the future even faster than the increase in yellowcake production, as the demand for energy

Jan 1, 1980

By Russel Delmar, Rick Everdell, Harry Charalambu, John Tait

Award of the Design/Build Agreement for construction of Ontario Power Generation’s (OPG’s) Niagara Tunnel Project was made after an intensive 8-month international procurement process. The 14.4-m diameter × 10.4-km long rock tunnel will divert 500 m3/s of water from the Niagara River to the Sir Adam Beck hydroelectric generating complex. The procurement process and Design/Build Agreement included features to address the owner’s requirements regarding risk allocation and cost and schedule certainty, while encouraging innovative ideas from the industry, both technically and commercially. The process included an international expression of interest and prequalification, followed by an invitation for design/build proposals to qualified proponents, and comprehensive proposal evaluations and negotiations with several respondent proponents. An honorarium was provided to the unsuccessful participants in the proposal stage. The resultant negotiated Design/Build Agreement includes Owner’s Mandatory Requirements, negotiated contract terms and conditions, performanceincentive bonuses and liquidated damages for schedule and water delivery performance, a multistaged Geotechnical Baseline Report, joint risk management, references to preexisting community impact agreements and measures to reduce impact on tourism. It also addresses regulatory approvals and permits, an owner controlled insurance policy that required reference to the International Tunneling Insurance Group (ITIG) Code of Practice for Risk Management as a condition of coverage, site specific safety, security and environmental plans, formal team building, a dispute review board, and escrow documentation.

Jan 1, 2007

By G. Derge, W. Peifer, J. H. Richards

INTRODUCTION A WIDE variety of metallurgical defects in steel have commonly been attributed to the presence of excessive amounts of hydrogen. These defects include flakes in rails and forgings, cracks in welds, and blisters in enameled ware. They have been related to hydrogen largely by circumstantial evidence because the proper sampling and analysis of steel for hydrogen has been known to be difficult and because no general agreement has existed with regard to the relative suitability and accuracy of available methods. The need for a direct approach to these problems has been widely recognized. This general situation has been well described in the publications of the British Committee on the Heterogeneity of Steel Ingots,1 and current approaches to the problem were reviewed in a recent symposium of the AIME.12 The plans described by the present authors at that meeting have now matured satisfactorily and will form the basis of this paper. The principle object of this paper will be to describe the methods of sampling and analysis which have been developed and to illustrate the usefulness and limitations of these methods by citing their application to a specific problem. The first problem selected for investigation was the behavior of hydrogen in rail steel. This was chosen because the occurrence of shatter cracks in rails has received a great deal of study over a long period of time. The defect can be controlled by the expensive procedure of slow cooling. However, it may be hoped that a better understanding of the factors influencing the hydrogen content of rails will lead to a more efficient control of this problem. Rails provide a good starting point for a more general study of hydrogen in steel because they provide a cross section large enough to develop cracks, yet small enough for convenient handling and sampling. Rails were also selected because they are made from plain carbon steel and it was felt that the initial work should not be complicated by the effects introduced by alloying elements. The considerations which determined the original planning of this study should be reviewed. The inherently complex nature of most hydrogen problems requires that a large amount of data must be collected for any particular case. This in turn means that any analytical procedure should be as rapid and simple as possible. The same objective of speed is indicated by the fact that it may finally become desirable to use hydrogen analysis in process control. It is also known that hydrogen is highly fugitive and that any procedure which facilitates early analysis of the sample without prolonged or irregular storage has distinct advantages. The most important previously reported methods of analysis may be classified into three general groups: (I) Vacuum fusion. (2) Vacuum extraction (without melting). (3) Total combustion.

Jan 1, 1948