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By Brandon R. Ball

An investigation of the effects of ozone and ozone-induced hydroxyl radical on reducing whole effluent toxicity is described and discussed relative to the application of ozone for industrial water treatment. Results from operation of an ozone system treating industrial effluent from a lead and zinc mine in Colorado are presented. The mine discharges 1,000 gpm of wastewater into a tributary of the Arkansas River and has historically exceeded Whole Effluent Toxicity (WET) limits and on occasion has exceeded numeric limits for copper, ammonia, and cyanide. Based on results of a Toxicity Identification Evaluation (TIE) conducted on the effluent and individual process waste streams, the source of effluent toxicity is believed to be primarily associated with organic reagents used in the milling process. Based on test results, an applied ozone to COD ratio of 3: 1 by weight and a contact time of 30 minutes was found to be effective for reducing whole effluent toxicity at pH 11 but not at pH 7, indicating oxidation by hydroxyl radical to be the dominant mechanism responsible for toxic-ity reduction. At an applied ozone to COD ratio of 3:1 and a pH of 11, toxicity was improved from 0 percent survival to 100 percent survival for Ceriodaphnia dubia and fathead minnow (Pimephales promelas) based

Jan 1, 1996

By R. Jedrzejczak

Endako Mine is an open pit molybdenum mine located in the north central region of British Columbia, Canada, approximately 160 km. west of Prince George. Production for the latter part of 1992 is expected to average at 63,500 tonnes per day of which 27,000 tpd constitute the mill feed. This production is achieved with five 15 to 19 cu. yd. electric shovels, six Euclid R190 and two Unit Rig M120 diesel-electric haul trucks, and three 121;.1 inch electric rotary drills. There are three ore zones delineated into pit areas called the Endako, Denak East and Denak West. Present mill feed source is the South East stage of the Endako Pit while the stripping is carried out in the South Wall stage also of the Endako Pit. The mine high grade aggregate is reduced in the primary and secondary crushing circuits before processing in conventional RM/BM/flotation circuits. The majority of the Molybdenum Sulphide (MoS2) is roasted on site to produce technical grade Molybdenum Oxide (MoO3) while a portion is further refined and treated to yield a 99.9% pure Molybdenum Sulphide (MoS2) "Ultrapure" product.

Jan 1, 1993

By Zhiyang Long, Ruiling Xiao

"A mine shaft is one main development method of establishing access in an underground mine. The construction technology of the mine shaft sinking is complicated and large equipment setup on surface and in the mine shaft. The paper briefly reviews a single-line operation method, parallel operation method and mixed operation method as well as the features of the one operation method with the excavation, lining and installation. The special construction technology mainly would include ground freezing methods, full diameter shaft drilling methods, caisson methods, grouting technology and concrete curtain methods as well as other methods. The paper summarizes the shaft sinking numbers and effects by the special construction methods during different periods. The paper states the shaft sinking conditions and the each created record conditions in the coal, metallurgy, non-ferrous metal, hydropower, highway, railway, nonmetallic and other industries. The paper has a prediction on the shaft sinking requirements and development tendency in the future for China.INTRODUCTIONA mine shaft is one main development method of access in an underground mine. In recent years in China the new shaft mines represent 45% of the total number of new mines. With the development of new mining area under construction and the development of deeper mines, the ratio of the mine shaft as access for underground mines will increase. The construction technology of the mine shaft engineering will be complicated, the operation site footprint will be small and the working environment will be more difficult. The mine shaft sinking operation will often be varied by the geological conditions and affected by underground water inflows, seam gas outbursts, geothermal and other natural conditions. The safe construction of the mine shaft sinking will be challenged by all these conditions. Although the mine shaft engineering will only be about 5% of the total mine roadway engineering, the mine shaft construction period often will take over 40% of the total mine construction period. With the progress of modernized mine production technology and the construction of a high production and high efficient mine, the mine transportation roadways mostly would be set in the seam and the engineered amount of the mine rock roadways reduced year by year could cause more prominent long extensions of the mine shaft construction period. Therefore, in order to speed up the construction, to shorten the mine construction period and to realize the investment benefits as early as possible, the technical level of the mine shaft sinking should firstly be improved and the construction speed of the mine shaft engineering and sinking should be speeded up, which would have important significant benefits."

Jan 1, 2019

By Ayman A. El‑Midany, Hassan E. El‑Shall, Kerri‑Ann A. Hue

Modification of clays is necessary for the zearalenone (ZEN), as long-chain mycotoxins, removal. The organic-cations were usually used to modify the clay hydrophobicity to accommodate the large mycotoxin molecules. In this study, tri capryl methylammonium (TCMA) chloride and common corn oil were used in clay modification. Several characterization techniques such as XRD, FTIR, and TGA were used to identify the d-spacing changes after modification either by TCMA or corn oil. The results of applying the TCMA-corn oil-modified clays in ZEN removal indicated a noticeable improvement where more than 90% of ZEN could be removed in vitro at acidic and neutral pH values. The success of eliminating a high percentage of ZEN molecules is due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clayforming layers. The removal percentage does not depend only on pH but also on the amount of clay used. In addition, the ZEN removal in the presence of corn oil is better at acidic pH and small clay amount where the ZEN can be fully removed.

Sep 27, 2021

By David R. Burkhard

"Comparative roof beam performance, as measured by delamination within the bolted horizon, was used to evaluate two types of roof bolt drill hole geometries in a development setting. Short encapsulation pull tests had demonstrated a higher grip factor in drill holes featuring helical grooves in the side walls in comparison to drill holes featuring continuous smooth to slightly rough walls. The study incorporated the two geometries during development mining in which fully grouted mechanically anchored bolts were installed as primary roof support.bolts were installed as primary roof support.The study site, in an entry adjacent to a longwall panel, was instrumented with extensometers and data collected during longwall retreat. Statistical analysis was conducted to validate null and alternative hypotheses used to compare drill hole geometries. Analysis yielded no statistically significant difference between drill hole geometries. Inspection of the data does reveal less delamination within the smooth walled site in comparison to the site containing grooved hole geometry.INTRODUCTIONFrom their introduction as a means of ground control over sixty years ago, roof bolts today are the primary mechanism of roof support utilized throughout mining. Whether through suspension, keying, or beam building, roof bolts are employed to reinforce the inherent strength of the strata comprising the immediate roof with the goal of creating a competent bolted horizon of sufficient load bearing capacity to be self-supporting for a given mine's design life, stress regime, and geomechanical properties.For grouted bolts in sedimentary strata, axial loading due to vertical rock movement and bending due to horizontal rock movement are the principal means of loading (Signer, 2000). Regardless of the type of bolt and extent of grouting employed, the success of any roof bolting design is determined, to a large extent, by the effectiveness of load transfer between the rock, grout, and bolt.At San Juan Mine, an underground longwall mine located in the northwestern corner of New Mexico, a number of different roof bolt types, grades, and lengths have been used over the years in an effort to optimize primary roof support. One common denominator shared throughout has been the use of full length grout. Load transfer for full length grout is achieved primarily through mechanical bonding between the grout and rock. It is this interaction that is the focus of the study described in this paper. The study assessed and compared two types of bolt hole geometries employed during gate road development at San Juan. Underground instrumentation and evaluation of the bolted roof provided the means of assessment and comparison."

Jan 1, 2016

By Lisa E. Helberg

"Titanium tetrachloride is produced through the chlorination of a variety of titanium bearing ores, some occurring in nature, and others enriched in titanium content by a variety of ""beneficiation"" processes. The chlorination step can produce a variety of metal chloride impurities, such as iron chlorides and vanadium chlorides, which must be removed from the TiC14 before it can be used to produce pigmentary TiO2, titanium metal or for any other commercial use. The requisite manipulations involve both physical and chemical separations in a multi-step process. The history of various purification strategies will be discussed.TextThere are a wide range of titanium-based products available, all of which start with titanoferrous ore of some type. Two main routes are used to convert ores into products, known as the sulfate and chloride processes. The sulfate process uses sulfuric acid to digest the ore, separate the impurities, and then precipitate titanium dioxide from the resulting titanyl sulfate (TiOSO4) via metatitanic acid. This process can also supply TiOS04 for other applications."

Jan 1, 2011

By W Medina, G Angulo, A Anani

A current challenge faced by the mining industry is solving the integrated transition mine problem (TMP) that maximizes the net present value (NPV). This study aims to develop an optimization framework capable of solving the TMP. The problem is NP-hard and therefore computationally intractable. Three ad hoc approaches – Exact solution, Benders’ decomposition, and Benders’ decomposition with Bienstock-Zuckerberg (BZ) algorithm – are compared for different scheduling periods. The TMP is formulated as a mixed integer linear programming model, implemented in Python, and solved with the Gurobi optimizer. The results showed that Bender's decomposition with the BZ algorithm outperforms the other approaches in execution time, computational cost, and feasibility to address large problems in exchange for a marginal cost in the quality of the NPV obtained. In addition, the probability of finding the optimal point of transition is higher regardless of the number of feasible crown pillar locations evaluated. This is achieved through the optimality cuts proposed in the algorithm.

Jun 25, 2023

By Faidel VV, Yushina TI, Yagodkina NG, Yatsimirsky AK, Chanturiya VA

Among the problems of the flotation of sulphides by the thiol collectors is the dependence and varieties of the flotation starting with the time and oxygen contents in the slurry. For sulphides, the flotation stage follows after the electrocatalytic oxidation of the collector with oxygen on the surface of the conductor minerals. The necessity of the oxygen for sulphide flotation (Plaksin and Bessonov, 1957) is in accordance with a corrosion model of a collector surface sorption (Salamy and Nixon, 1954). As Golikov and Nagimyak (1961) showed, the sulphides possess catalytic activity which provides the autoxidation of the xanthates in the sluny to the dixanthogen. This stage can be rather protracted, which limits the speed of the total process. Disulphides constitute important collectors for the sulphide flotation and the optimal degree of the xanthate oxidation is about 20 per cent for different ores (Abramov, 1978) or, following Chanturiya and Nazarova (1977) the surface compositions for various sulphide ores are different and an optimal oxidation degree is variable from five to 25 per cent according to the ore nature. The optimisation of the surface composition is possible by application of the dixanthogens, or by a partial chemical, electrochemical, or catalytic oxidation of xanthates (Desains, 1847; Schall, 1896; Vigdergauz, 1989). According to Rand (1977) and Vigdergauz (1991) sulphides possess different catalytic activities for oxygen electroreduction. In neutral solutions, for example, the following decrease in the order: FeS2 (Fe,Ni)9S8 CuFeS2 FeS; Cu5FeS4 Cu2S; PbS (Vigdergauz, 1991). For the cases of low catalytic activities of the sulphides, the preflotation oxidation of xanthate could be useful to optimise the process kinetics.

Jan 1, 1993

By Nikhil Dhawan, Veeranjaneyulu Rayapudi, Singh Rahulkumar Sunil

The ever-increasing demand for steel and the subsequent depletion of high-grade ores requires the massive utilization of low-grade iron ores. In the present study, an iron ore slime sample containing 56.1% Fe was investigated using physical beneficiation, carbothermal reduction, and a microwave-assisted process; however, physical beneficiation and microwave exposure were found to be inefficient as they yielded lower iron recovery. Using coconut shell as an alternative reductant was found to be promising and does not lead to the formation of higher iron oxides, such as fayalite and wustite phases. The microwave-assisted carbothermal reduction was found at par with conventional reduction, saving time and heating. The optimum magnetic concentrate obtained in both carbothermal reduction routes (microwave and muffle furnace: Fe grade, Fe recovery, and yield of 64.3, 97, and 84%, and 67, 99, and 83%, respectively) are suitable for alternative iron-making or blast furnace units.

By Andrew Meyer

As a producer of gold and platinum, Colombia is most emphatically an important country. Last year it produced 656,000 oz. of gold-twice as much as any other country in South America, in fact accounting for a third of the production of that continent. In platinum, world data for 1941 are not available, but in 1939 Colombia exported 39,000 oz., apparently ranking fourth among the world's producing countries, being exceeded only by Canada, Russia, and the Union of South Africa. Colombia was always a mining country. Centuries before the Conquest, Indians mined gold, copper, silver, salt, and emeralds. The Spaniards simply intensified mining. The Bank of the Republic states that from 1493 to 1940 52,177,427 oz. of gold was produced by Colombia, and official Chocó statistics show that about $60,000,000 worth of platinum was mined between 1908 and 1941. These figures are impressive indeed considering that only rich pockets and surface showings were mined by the ancients.

Jan 1, 1942

By Ankit Jha, RICHARD AMOAKO

In this paper, we examine the challenges associated with the use of empirical rock fragmentation models. We highlight key parameters omitted by these models, and propose a machine learning approach that incorporates these parameters, leading to a simple, yet more accurate approach to blast design.

Feb 1, 2020

By Victor Azbe

Azbe System of Controlled Calcination To obtain good and cheap lime there are certain fundamental requirements that need to be satisfied. These are : (1) Proper combustion of fuel and steady supply of heat to the kiln. (2) Proper heat distribution in the kiln. (3) Uniform drawing of lime through the several shaft sections. (4) Complete cooling of the lime and recovery of the heat. (5) Temperature control of the hot zone by economical means. (6) Ample draft to obtain high capacity. (7) Arrangements to facilitate operation. Figure 17 shows diagrammatically one of the smaller kilns, intended for large stone. Such a kiln can be supplied with gas from a centrally located automatic gas producer, or, as shown, from an integral producer located snugly against the kiln. These producers make very good gas and have a gasification capacity of either 10 or 15 tons of coal a day. The producers have water-sealed ash pits, a rather thick fuel bed that is conducive to the making of high-CO gas, and are under forced draft. No steam is used. Clinkering is prevented by admixing some spent gas from the kiln with the air. Coal feeding is from a coal bunker through spouts into the hoppers over the producer. This is done, at proper intervals, by manual operation of slides, but it is planned to install mechanical feeders. Central mechanical gas producers have the advantage of requiring little labour, but the blowing of soot is a problem, as also is the proper distribution of the gas among several kilns. In the case of integral gas producers, soot from the centre burner is blown back into the producer to be burned, and the supply of gas to the kiln is controlled by regulation of air to the producer. In large plants, the mechanical producer may be preferable, but in small ones, the integral producer is cheaper, better, and more reliable. The kiln shown in Figure 17 is suitable for both systems of gas supply. It will be noticed that there are no side gas burners. All gas enters the kiln through the centre burner in a manner that permits any desired amount of gas to be directed to any of the kiln sections by the aid of regulating slides.

Jan 1, 1946

By Nikolaos Petropoulos, Changping Yi, Daniel Johansson, Håkan Schunnesson

The effect of jointing on fragmentation by blasting was investigated experimentally and numerically. Firstly the experimental results were presented. Then the numerical modelling based on the experiments was performed. The same conclusions can be obtained based on both experiments and numerical modelling.

Feb 1, 2020

By B. Kolonja

A SIMAN and CINEMA PC-based simulation model was developed to simulate and animate the truck-shovel operations of surface mines. The model is capable of simulating one mathematical dispatching strategy using linear and dynamic programming and six heuristic dispatching strategies. Data were collected from an actual operating mine through time studies and analysis of historical records. The statistical analyses were performed and appropriate theoretical distributions were fitted for various time events in the truck-shovel work cycle. The model was then applied to study overall impact of these dispatching strategies on constrained and unconstrained mine productivity. The simulation/animation model developed in this study seems to be an efficient planning tool for choosing optimal fleets and finding an 'optimal" dispatching strategy to produce an equilibrium between "the quality and quantity of production.

Jan 1, 1993

By S. C. Grund

In secondary copper smelting as it is performed at Hüttenwerke Kayser plant in Lünen, tin-and lead-containing flue dusts are produced as intermediate products. These flue dusts are further processed in a hearth furnace. Followed by certain refining operations a saleable tin-lead-alloy is produced. Even though the hearth furnace technology has been in use for this purpose for a long time still its performance undergoes changes in search for optimum processing conditions regarding to the increasing complexity of the raw materials and tightening economical and ecological boundaries. The use of modern statistical tools for the calculation of accurate mass balances is demonstrated for the tin-lead hearth furnace. These reliable mass balances are the basis for any further modelling of the process with the aim of optimization. Incorporating metallurgical knowledge and experience as well as different mathematical modelling techniques, further studies are planned in which the recoveries of valuable and minor elements and their dependency from various process parameters are examined. The aim of this modelling is to optimize the recoveries of the valuable elements, to minimize the energy consumption and the processing costs and thus to keep the process competitive in a harsher economical and ecological surrounding. The modelling principles are transferable to other metallurgical operations and are especially suited for ill-defined pyrometallurgical processes.

Jan 1, 1999

By S. Pule, Z. Ndabezimbi, A. Hefer, E. Cupido

This article outlines various projects implemented at Rand Refinery to reduce effluent generation and freshwater consumption. The refinery generates about 2800 m³ of effluent annually and has initiated projects such as granulation water recycle and silver leach optimisation to address these issues. The granulation water recycle project has successfully reduced effluent volumes, while the silver leach optimisation has further decreased effluent by implementing stoichiometric addition of HCl and NaClO3. The vibratory shear enhanced processing (VSEP) trial showed promising results for gold recovery from wastewater, though further trials are recommended. The water savings of the effluent reduction projects are monitored by measuring the amount of effluent pumped to service yard effluent storage facilities with the use of flow meters connected on SCADA. Since the effluent reduction initiative of granulation effluent recycle in FY23, the effluent reduced to 2676 m³. In FY24, the stoichiometric addition of HCl and NaClO3 was implemented in the silver leach process, further reducing the effluent to 2083 m³.

Mar 5, 2025

By M. A. Nagle

Various strategic projects were carried out in 2002 to increase the capacity of Teck Cominco's integrated zinc-lead smelter at the Trail operations site in British Columbia, Canada. The lead smelter treats the iron residue from the zinc plant and optimizes the overall zinc recovery. This paper summarizes two options that were considered to reduce the zinc content in the leaching iron residue. The first option involved increasing the capacity of an existing hot acid leach circuit up to the iron loading constraints of the circuit. The second sought to maximize the hot acid leach capability by separating the ferrite-rich solids, followed by aggressive hot acid leaching (>100°C) and subsequent iron precipitation. Different forms of iron precipitation were reviewed in order to determine the most effective and economical approach. Among these, was a novel high temperature ferrite conversion process. The technical results and selection criteria are presented together with possible ways to integrate the process concepts into the current sulphide leaching plant circuit. The first option was selected for implementation and is currently being operated successfully.

Jan 1, 2006

By Norman O. Lotter, Dominic Fragomeni, Lori J. Kormos, Guy Comeau, Antonio Di Feo

"A performance opportunity was identified for the Raglan concentrator operation by changing the selection of xanthate from Potassium Amyl Xanthate (PAX) to Potassium Isobutyl Xanthate (PIBX). This opportunity was identified by a Statistical Benchmark Survey of the operation and QEMSCAN measurement of these survey samples, in which fine liberated pentlandite was found in the final tailings. This was confirmed by some laboratory scale flotation testwork using High- Confidence Flotation Testing. A statistically designed plant trial was implemented in 2007 to measure and confirm the performance gain. This trial design used on-off switching following a three-month reference distribution of normal operations using PAX. This layout provided both external and internal reference distributions on PAX to be established. These were used to evaluate the internal reference distributions on PIBX. This trial format was deliberately designed so as to block out the effects of autocorrelation in the operations data. In this way, small but significant metal recovery gains may be measured and proven in a plant trial. The paper describes the case study to show that this approach successfully blocks out autocorrelation in time, which is an obstacle in analysing concentrator operations data. The results showed that the PIBX had produced clear and statistically significant recovery gains for Ni, Cu, Pt and Pd. Adjusted for feed and concentrate grades, these recovery gains were: Ni: 1.00, Cu: 0.96, Pt: 5.07 and Pd: 1.90%.INTRODUCTIONConcentrator OperationsMilling and flotation, sometimes accompanied by gravity separation, are well-established unit processes. These have traditionally been used to treat ore that has been mined, producing a lowbulk concentrate containing a high percentage of the paymetal(s) in the ore mined. These concentrates are more economically treated in subsequent beneficiation processes than the ore from which they were produced.This choice of a concentration process results in a significant and variable paymetal loss to the concentrator tailing. This tailing is discarded and disposed of in an impoundment area, and has no immediate business use. This paymetal loss forms the largest loss of paymetal in the entire flowsheet by which refined, or saleable, metal(s) are produced [Cramer, 2001]. The question arises as to whether any particular concentrator is performing at its full potential, and how this answer may be determined. In a concentrator operation, there is always an ongoing performance improvement programme for this reason."

Jan 1, 2009

By Marzio Piller, Girolamo Belardi, Jure Mencinger, Paolo Bozano, Gianni Schena

"The hydrodynamics of the Tri-Flo™, a two stage cylindrical cyclone used in dense media separation, is studied using Computational Fluid Dynamics. The flow field is simulated with an Euler-Euler Volume of Fluid two-phase approach and the Reynolds stress turbulence model.A unique feature of the device is that the separation medium suspension is pumped and introduced tangentially into the two cylindrical compartments while the raw feed is conveyed to the feed hopper and fed at the axial inlet. This feature allows to use less pumping energy and limits the unavoidable production of fines. The Tri-Flo™ complex flow pattern is little known but central to the efficiency of the separation.The velocity field is computed within the two compartments of the separator. The interface of the air-core that forms in the inner axial part of the cylindrical sections is identified and visualized. The numerical results for a reduced-size 100 mm ID Tri-Flo™ are compared against laser Doppler measurements on a transparent acrylic model (Chinè, 1995) operated with water. The robustness of the model and its prediction capability are verified.The possibility to accurately predict the velocity profiles within the vessel and their dependence on the main Tri-Flo™ operating and geometrical variables paves the way to a better understanding of the functioning of the separator, its design improvements and scale-up."

Jan 1, 2014

By K. J. Shoop

Coal-fired power plants in the U. S. produce approximately 20 million metric tons of Hue-gas desulfurization sludge every year. The sludge mainly consists of calcium sulfite and calcium sulfate. This can be converted to synthetic gypsum, which in principle could be a marketable commodity. However, many Hue-gas scrubbers produce sludges that do not meet the quality requirements of the gypsum industry, and so their sludges must be landfilled as a waste. If a suitable method can be developed for removing certain objectionable impurities from the sludge, it will then be possible to market the material instead of landfilling it. A sludge from a natural-oxidation scrubber was characterized, and the main contaminant was found to be calcium carbonate from unreacted limestone. Based on the particle size and the characteristics of the material, froth flotation was considered as a method for purifying the material. Since no flotation studies have ever been carried out to separate calcium carbonate particles from calcium sulfite or calcium sulfate particles, it was first necessary to select a suitable collecting reagent. Based on Zeta-potential studies, the most suitable reagent was found to be an octadecylamine-octadecylguanidine complex. Results are presented for flotation of calcium carbonate from scrubber sludge using this reagent, in a reverse-flotation process. The best results were obtained when the sludge was first pre-cleaned using a water-only cyclone to remove unfloatable coarse limestone, followed by froth flotation to remove fine limestone.

Jan 1, 1998