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By J. W. Jensen

Alloys of manganese and copper containing from 65 to 80 percent manganese possess mechanical strength and vibration-damping capacity in an unusually high degree. The success of their use in reducing vibration in structures depends, to some extent, on their fatigue properties. This report describes the results of fatigue tests on alloys of four compositions. Three metallurgical conditions were investigated for each alloy. Or the basis of the data in this report, the general rule that vibration-damping manganese-copper alloys are comparable to mild steel in hardness and strength may be extended to include fatigue strength. Methods for casting and fabricating these alloys were described in a previous report,4 which contained data on the mechanical and damping properties of the solid-solution alloys, and on alloys aged for 2 hours at 450° C. The aging heat treatment of solution-treated alloys results in optimum mechanical and damping properties throughout the range of specified composition. However, in the present work, measurements also were made on alloys aged for 2 hours at 500° C., because it was theorized that the additional precipitation of a-manganese under these conditions might have a pronounced effect on the fatigue strength of the alloy.

Jan 1, 1961

By J. Kolacz

A new optical sorting system based on a complex image analysis and high definition imaging has been developed by Comex. The image analysis is based on high definition cameras of different types and advanced filtration tools for verification of waste particles. Different mineral properties are used to identify the processed material. The system is further combined with a high speed rejection mechanism based on FPGA technology and operating in real time conditions. This provides a minimal error when removing waste particles from the sorted material.

Jan 1, 2014

By T. G. Sitharam, P. B. Choudhury

Prediction of ground vibration (peak particle velocity, PPV) and frequency is an important task in geoscience. Till date, many empirical equations are derived from conducting trial blasts in the mines, to arrive at attenuation predictors. These predictors are usually site dependant and hold good for one particular type of rock/strata. These predictors cannot be used for geologically different rocks/strata. This paper presents the application of support vector machine (SVM) model, for predicting blast induced ground vibration and frequency, using a one comprehensive model for three different types of rock. Inputs to the SVM model formulation involve twenty one parameters consisting of geotechnical properties of the rock mass, blast design geometry and explosive properties, and the output of the formulated model is peak particle velocity and its associated frequency. The data has been acquired from eight limestone mine, five coal mine and two manganese mines. The comprehensive SVM model is formulated using 400 datasets and tested with 143 datasets. The performance indicators to the model not only justify its formulation but also the advantages it has over site specific predictor models. The SVM model not only predicts PPV, with higher correlation coefficients as compared to predictor equations, but also the associated frequency.

Jan 1, 2010

By L. D. Anderson

IN STUDYING Utah as a lead producing state one is immediately confronted by the fact that few, if any, of the ores of the state are valued for their lead contents alone. More correctly the ores from which this metal is recovered are characterized as silver lead. Even then the whole story is not told for many of these ores carry also gold, copper, zinc, bismuth, antimony, arsenic, tellurium, and other metals. It becomes apparent, therefore, that the production of lead i11 Utah is influenced by many factors. For example, i11 the early part of 1923 there was a marked increase in the production of the lead by reason of the efforts made by silver mines to produce as much silver as possible before the termination of purchases under the Pittinan Act in June, 1923. As nearly all silver ores carried more or less lead the production of that metal was increased with the increase in silver production. Very few, if any, ores of the State are mined for their lead contents alone. Important as Utah's contribution to the lead output of the country is nevertheless it is bound up to some extent with the production of gold, silver and copper.

Jan 1, 1925

By Henry A. Signore

The Appalachian coalfield, located in eastern Kentucky, Pennsylvania, Virginia and West Virginia, has been one of the most productive in the United States. Total production from the Appalachian coalfield during 1994 was 340.8 Mt (375.4 million st), or 37% of the 929 Mt (1 billion st) produced in the United States that year. This region contains various coal types from high- to mid-sulfur coal in Pennsylvania and northern West Virginia to low-sulfur, compliance steam coal and premium-grade metallurgical coal in eastern Kentucky, Virginia and southern West Virginia. The region's product is in high demand in domestic and export markets. Productivity continues to improve, resulting in the primary coal operators solidifying their market positions.

Jan 1, 1995

By Jue Kou, Hongda Xu, Tichang Sun, Shichao Wu, Wenli Han

To investigate the effect of simultaneous change in particle size of raw materials (including ore, reductant, and dephosphorization agent) on the direct reduction process of high-phosphorus oolitic hematite, the experimental research of method with direct reduction and magnetic separation was conducted to investigate the effect of simultaneous change in particle size of raw materials on the final reduction products in the form of mineral composition, reduction speed, metallic iron particle morphology, phosphorus distribution, and powdery reduction iron. The results revealed that under the same conditions of reduction temperature, the raw material particle size affects the mineral composition of the final reduction product, the coarser the raw material particle size, the slower the reduction speed, the lower the metallization rate, and the larger the final metallic iron particle size formed. Under the same conditions of raw material particle size, the reduction temperature affects the mineral composition of the final reduction product, the higher the reduction temperature, the faster the reduction speed, the higher the metallization rate, and the larger the size of metallic iron particles within a certain reduction time. Neither the raw material particle size nor reduction temperature affects the form of phosphorus present in the reduction product. Both the raw material particle size and reduction temperature affect the grade of powdery reduction iron to a less extent, but affect the recovery rate and phosphorus content significantly. At the same reduction temperature, the recovery of powdery reduction iron and phosphorus content gradually decreases with the increase in raw material particle size. For the same raw material particle size, the recovery of powdery reduction iron gradually increases, and the phosphorus content gradually decreases with the increase in the reduction temperature. The results identified the effect of simultaneous changes in particle size of raw materials on the direct reduction process of high-phosphorus oolitic hematite and provide a basis for the selection of raw material particle size for the industrial application.

Dec 20, 2022

By Mahdi Shevrini, Hamed Haghi

"In this research, the operation of screen classifying in silica processing circuits was investigated and modified by replacement of available trommel screens with teetered bed separator (TBS). In addition the effect of the mentioned replacement and addition of attrition scrubber on quality of final product, impurities removal, recovery and production rate were inspected. Considering screen efficiency problems to achieve certain particle size distribution, hydraulic classifying system was selected instead of trommel screens. Application of suggested plan improved quality and particle size distribution of produced silica significantly. Optimization of size classification in process circuit resulted in increase in production rate up to 21% (from 67% to 81%), silica recovery (from 68.35% up to 83.11%) and relative enhancement in removal of impurities such as Fe2O3 and TiO2. After optimization and stabilization of grinding and size classification section, industrial attrition scrubbing tests were carried out and the best solid percent and retention time were determined i.e. 70% and 6 minutes, respectively. Using sodium carbonate during attrition scrubbing, has major effect on removal of surface coating and staining especially sharp increase in clay removal; therefore 2 kg/t of sodium carbonate can be optimistic point of industrial procedure for this silica processing plant. It should be mentioned that application of attrition scrubbing which is followed by screw classifier for de-sliming were useful for better cumulating of particles in the range of appropriate liberation degree (+106-300µm) and efficient removal of metallic (iron and titanium oxides) and non-metallic (clays and feldspars) impurities."

Jan 1, 2014

By C. Coetzee

Additives are commonly used in copper electrowinning to improve cathode morphology. Polysaccharides such as guar are generally favoured as additives due to their compatibility with solvent extraction. Polyacrylamides are, however, being considered as possible alternatives. Understanding the influence of the structural chemistry of additives on electrowinning performance is critical to utilise them efficiently. This paper investigated polyacrylamide additives which are structurally different; their effects on copper electrodeposition were characterized and compared to that of guar. Electrochemical impedance spectroscopy (EIS) were used to characterize the effects of molecular weight and ionic charge of the polyacrylamides on electrodeposition. The findings were compared against results obtained with an industrially used guar product. Equivalent circuit modelling of EIS data indicated that an increase in polyacrylamide concentration and a decrease in additive molecular weight increased the overall system resistance.

By D. Beneteau, D. Milne

"Advances in technology provide educators with valuable tools to enhance their teaching and efficiently deliver content to larger audiences. University educators are often encouraged to become more “research intensive” and to increase student enrollment. Faced with these pressures, there is a tendency to use technology to improve teaching efficiencies rather than to enhance existing teaching approaches. Practical learning in applied engineering courses would suffer greatly if hands-on experience is not emphasized. This paper discusses advantages and limitations of new technologies applied to learning, and methods to incorporate more hands-on experiential teaching techniques to applied mining engineering courses.RÉSUMÉ Les avancées technologiques fournissent aux éducateurs des outils intéressants pour rehausser leur enseignement et livrer efficacement de la matière à de grands auditoires. Les éducateurs universitaires sont souvent encouragés à devenir plus « axés sur la recherche » et d’augmenter l’inscription d’étudiants. Face à ces pressions, il y a une tendance à utiliser la technologie pour améliorer l’efficacité d’enseignement plutôt que de rehausser les approches existantes d’enseignement. L’apprentissage concret dans les cours d’ingénierie appliquée souffrirait grandement si l’accent n’est pas mis sur l’expérience pratique. Le présent article discute des avantages et des limitations des nouvelles technologies appliquées à l’apprentissage et des méthodes pour incorporer plus de techniques expérimentales pratiques aux cours de génie minier appliqué."

Jan 1, 2016

By W. J. Bronkala

Dense-medium circuits have been installed in many mineral treatment plants since its, original development about thirty years ago. In the intervening, period the process has been thoroughly evaluated and many innovations have been introduced. The Heavy Density. Cyclone is one of the newer systems which has extended the operating range of this process to 65 mesh size. Several different finely divided materials have been used to produce the separating bath but nearly all new plants use a ferro-magnetic medium. The, advantages of magnetic medium include: 1. Smaller recovery plant 2. Lower cost recovery plant both in initial and operating cost 3. Excellent medium stability 4. Dependable medium supply at reasonable and stable cost. Magnetic separators are used to recover this magnetic medium and the smaller plants and lower operating costs are directly related to their use.

Jan 1, 1964

By Clark D. Harrison

This paper compares the ash slagging potential of Illinois No. 6 Seam coal: as raw coal; as commercially cleaned coal processed in a baum-jig plant; and as coal cleaned to a reduced ash specification at the Electric Power Research Institute's Coal Cleaning Test Facility. The comparison is based on: ? ASTM ash fusibility data ? A slagging index ? Gravity fractionation analyses of critical mineral matter compounds ? Comparative pilot combustion tests. The first three grounds of comparison are laboratory data; and the final comparison involves burning approximately 15 tons of each coal at CONOCO's 1.5 MBtu/hr (440 KW) test combustor. The evidence of these .four comparisons indicates that lowering the ash specification of coal before combustion can significantly improve the ash slagging characteristics of Illinois 90. 6 Seam coal.

Jan 1, 1984

SYMPOSIUM ON THE RECOVERY OF PYRITE The proceedings of the Symposium on the Recovery of Pyrite, held in Johannesburg in June 1969, may be ordered from the Secretary, S.A.I.M.M., P.O. Box 61019, Marshalltown, Transvaal, at the reduced price of R5.00. Papers and addresses presented at the Symposium were: Opening Address by Mr J. K. E. Douglas (President). "The world sulphur position," by W. C. J. van Rensburg (Member). "The South African sulphur position," by D. L. Taylor (Member). "The recovery of pyrite at Government Gold Mining Areas Limited," by R. J. Westwood (Member), G. S. Stander (Affiliate) and H. P. Carlisle (Member). "Recovery of pyrite concentrates from colliery-waste discards-A preliminary assessment," by W. A. Gilbert (Visitor) and E. A. Nugent (Member). "The role of pyrite in upgrading the uranium content of Witwatersrand conglomerate ores by means of the heavy-medium separation process," by D. J. Tutt (Associate Member). "Pyrite recovery by jigs at Durban Roodepoort Deep Limited," by E. J. Dominy (Affiliate), F. Diamond (Affiliate) and A. D. Graham (Affiliate). "The storage of pyrite concentrates," by Joan C. Campkin (Visitor) and P. J. Lloyd (Member). "The flotation plants of the Anglo-Transvaal Group," by L. A. Bushell (Member). "Pyrite flotation with amines and cyanidation of the products," by E. H. D. Carman (Member). "Gold recovery by cyanidation from mill products obtained after pyrite flotation," by P. G. Mrkusic (Graduate), M. Sciarone (Visitor) and H. E. Simonsen (Visitor). "The influence of sulphydryl and cationic flotation reagents on cyanidation of native gold," by K. G. Ashurst (Visitor) and W. P. Finkelstein (Member). "Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collector," by J. Levin (Member), and M. L. Veitch (Visitor). Closing Address, by Dr R. E. Robinson (Director, National Institute for Metallurgy). INCOME TAX: POST-GRADUATE STUDY COURSE CONCESSION As a result of representations made by the Associated Scientific and Technical Societies of S.A. and the Suid-Afrikaanse Akademie vir Wetenskap en Kuns, engineers and scientists will now be allowed to deduct expenses incurred on post-graduate study courses from their taxable income. The conditions of this concession are set out in section 16 of the Income Tax Act, 1969, which reads as follows: 16. (1) The following section is hereby substituted for section 16 of the principal Act: 16. "Notwithstanding the provisions of section 23(a) and (b), there shall be allowed to be deducted from the income of any person who is a dentist or medical practitioner or practises any profession referred to in paragraph (a), so much as the Secretary may allow of any expenditure incurred by such person in the circumstances contemplated in paragraph (c), if the Dental Association of South Africa in the case of a dentist, or the Medical Association of South Africa in the case of a medical practitioner, or the "Suid-Afrikaanse Akademie vir Wetenskap en Kuns" or the Associated Scientific and Technical Societies of South Africa in any other case, certifies in such form as the Secretary may prescribe that such person- (a) if he is not a dentist or medical practitioner, is the holder of a degree in engineering or allied technology or natural sciences awarded by a recognized university on completion of a prescribed minimum period of study of not less than four academic years or the equivalent thereof and enabling the holder thereof to practise the profession of an engineer or a profession for which advanced and specialised scientific knowledge is required which relates directly to- (i) the development or exploitation of natural resources; (ii) mining or prospecting for minerals; (iii) the production of pastoral, agricultural or forest produce ; (iv) the breeding or care of farm animals; (v) any industrial process; or (vi) the training of specialists in any branch of science or technology connected with any aforementioned profession; (b) has practised his profession for not less than three years; and (c) has incurred such expenditure during the year of assessment in respect of the attendance by him of any postgraduate study course approved by such body to improve his qualifications for carrying on his profession in the Republic". (2) The amendments effected by subsection (1) shall first take effect in respect of assessments for the year of assessment ending on the twenty-eighth day of February, 1970. From this section it is clear that the concession will only be granted if the application is accompanied by a certificate, which certificate must be either signed by the Chairman of Die Akademie or the President of the Associated Societies. In terms of the authority granted such certificates must certify that: (i) the taxpayer concerned has practised his profession for not less than three years; (ii) the expenditure was incurred by the taxpayer during the year of assessment indicated in the certificate; (iii) the expenditure was incurred by the taxpayer in respect of the attendance by him of a post-graduate study course approved by the Associated Scientific and Technical Societies of South Africa or Die Suid-Afrikaanse Akademie vir Wetenskap en Kuns, as the case may be, to improve his qualifications for carrying on his profession in South Africa; (iv) the taxpayer is the holder of a degree in engineering or allied technology or natural sciences, which degree was awarded by a recognized university,

By Frank Woolley, John F. Elliott

The high-temperatzrre solulion calorimeter has been modified and an extension dynamic analysis of i/s transient behavior has provided an improved basis for interpretation of the experimental data. The partial molar heats of mixing, Him, of aluminum, copper, and silicon in the corresponding binary liquid-iron alloys haz,e been measured directly at 1600°C. The resulls in kcal per g-alom are: THE high-temperature1,2 solution calorimeter was planned and designed to obtain directly the partial molar heat of solution of solute elements in a variety of liquid metals that might serve as solvents. Results obtained in the temperature range of 1000° to 1200°C were described in the two earlier publications. However, a long-term goal in the program has been to obtain measurements at 1600°C of the heats of solution of elements in liquid iron. Hence, subsequent to the work last reported,2 and based on the experience of the first two studies, the calorimeter system has been modified and operated at 1600°C to obtain measurements on the Fe-Si, Fe-A1, and Fe-Cu systems. This paper reports the results of the work. THE MODIFIED SYSTEM It was clear from the earlier results that the most precise measurements can be obtained with the high-temperature solution calorimeter when the solution time is less than approximately 30 sec. This can be achieved only when the bath temperature, Tb, is above the melting (liquidus) temperature of the solute material being dropped. A second point of importance is that the refractories used earlier liberated considerable water so that, although the oxygen potential of the atmosphere in the system was satisfactory for work with nickel and copper, it was too high for work with iron, silicon, and so forth. Third, for work at 1550" to 1650°C, an improved temperature-sensing unit is needed. The modified calorimeter in its latest form is shown schematically in Fig. 1. The refractory brick and the Kanthal-Super heating elements which formed the furnace for heating the solute addition have been replaced by a smaller resistance-heated tube furnace which is insulated with bubble-grain alumina. A more elaborate gas purification system was installed to maintain a satisfactorily low oxygen potential in the atmosphere of the calorinieter chamber and of the solute addition furnace. As was the case in the earlier work, at the beginning of a run the calorimeter chamber is evacuated and then filled with purified argon so that a total pressure slightly in excess of 1 atm is maintained during the run. When either of the furnaces within the enclosure attains a red heat, 6 pct H2 is added to the atmosphere. Throughout the run, gas from the calorimeter is circulated through a de-oxidation system at the rate of approximately 5 standard liters per min; the changeover time for the gas within the calorimeter enclosure is approximately 1 hr. The essential stages of the deoxidation system are: a copper furnace at 600°C, a drying tube of anhydrite, and a titanium furnace at 800°C. The oxygen potential of the gas stream in the purification system can be monitored at several points by a stabilized zirconia oxygen cell. This cell is invaluable in detecting the development of leaks in the container vessel and the gas circulating system. The installation of the solute-addition furnace allowed either of two types of temperature-sensing units to be mounted on a water-cooled probe. The first was a small optical device using a silicon diode that was

Jan 1, 1968

By John M. Arnold

Several years ago it became apparent to some of our people that; there was developing a very definite need for largee coal reserves in the West to satisfy- the need for fuel for the furnaces of electric generating plants with the rapid development of, the West, of both population and industry, it was impossible for hydro-electrics plants to keep up with the ever increasing demand for electricity. In 1960, Mr. E. R. Phelps, then associated with the engineering department of Peabody Coal Company, began a search for and development of coal deposits in the very remote northeast section of Arizona near the village of Kayenta. Travel to this section of the country was not easy even at this late date, and it was an eight hour drive from Farmington, New Mexico to Kayenta, Arizona, a distance of some 130 miles. The trip was over roads that even' a-horse and wagon had trouble negotiating and a four wheel drive vehicle was about the only type of transportation that could satisfactorily traverse these roads, as testify many badly beaten sedans and coupes that tried it. Since that time a very excellent road has been constructed from Shiprock; New Mexico to Cameron, Arizona where it junctions with another excellent road that runs north to Page, Arizona and the Lake. Powell area and south to Flagstaff, Arizona on highway 66. Kayenta is a small village nestled at the foot of the Black Mesa near its northeast extremities. The coal deposits of interest were on the surface of the mesa. This location presented another problem, as the only trail to the top of the mesa was intended for walking, horseback, or a brave soul In a horse and wagon. Once again the four wheel drive vehicle was about the only answer. To reach the coal deposits you must climb the mesa, which is vertical ascent of some 1,500 feet, and then proceed southward into the bowl of the mesa with an ensuing descent of some 1,000 feet, finally coming to an elevation of 6,500 feet, at which elevation the coal outcrops become apparent.

Jan 1, 1969

By S. D. Bearden

The world's reserve base is adequate for at least 100 years at the current consumption rate. China, India, and the U.S. are expected to remain the leading producing countries. The U.S. will continue to be the largest consumer of the production. None of the known substitutes for barium sulfate are expected to impact existing applications. World production in 1995 was 4,410Mt. This is about 50% of the projected capacity. Consumption is directly proportional to hydro-carbon well installation activity. Imports are expected to continue to supply more than half of the U.S. requirements.

Jan 1, 1997

By Manish Kumar Jain

The mineral industry in India is an important contributor to the country?s GDP and foreign trade, and also a significant source of employment generation. The industry is distributed almost all across the country and has operations in some of the remotest areas, where it has also served as a sole source of infrastructure development. India produces 89 minerals, out of which four are fuel minerals, 11 metallic, 52 non-metallic and 22 minor minerals. The mining leases are occupying about 0.21% of the total land mass of the country. Indian mining industry is characterized by a large number of small operational mines (approx 3000 mines). Appropriate systems have been put in place to ensure sustainable growth of the sector, which include formulation of procedures for scientific prospecting and mining and development of a mechanism of prior environmental and forest clearances for mining projects. Main emphasis is to protect the health and safety of mine workers, as well as to safeguard the interests of indigenous people through rehabilitation and resettlement packages. Efforts are under way to mainstream the artisanal and small-scale mining sector in order to promote equity in the mining industry. The issue of scientific closure and reclamation of the abandoned mine sites poses a major challenge. Present paper illustrated several initiatives have been taken in this direction along with case studies, which could be replicated in other parts of the country.

Aug 1, 2013

By I. A. Kovalevska

Considered problems: elaboration and implementation of resource-saving technologies, low-cost support systems improvement, openings security and support, based on wallrock condition control with supreme implication into the rock pressure occurrence counteraction work. Results of analytic and underground investigations using computer simulation of the finite elements in order to calculate stressstrain state of the multivariable geomechanical systems are presented. Solutions of concrete objectives are found using spatial geomechanical model of solid motion around openings, considering real geomechanical parameters formation of support forms with proper conditions of their contact and real mechanical characteristics. Ultimate solutions of resource-saving technologies implementation based on the analysis of multivariate vertical, horizontal, and reduced stresses components calculation and also near-contour rock, support bearing components and security constructions movements are found. Results of experimental investigations of combined supports and security constructions, which increase openings' stability in difficult conditions of flat coal seams are presented.

Aug 1, 2013

By M. Hayashi

The Bureau of Mines conducted laboratory studies on low-grade vanadiferous silicates from the Pumpkin Buttes and Nine Mile Lake deposits of Wyoming to examine techniques for extracting vanadium and uranium. Recovery from low-grade sources such as these could contribute to future vanadium production and reduce reliance on vanadium imports. The Pumpkin Buttes samples contained 0.03 to 0.04 pct V205 and 0.06 to 0.12 pct U308; the Nine Mile Lake samples contained 0.02 to 1.0 pct V205 and 0.06 to 0.19 pct U308" Leaching the Pumpkin Buttes samples for 18 h at 800 C with addition of 200 lb/ton H2S04 resulted in recoverey of 80 pct of the vanadium contained in the samples. The Nine Mile Lake samples were readily leached, yielding 78 to 94 pct of the vanadium after 3 h at 800 C with addition of 100 lb/ton H2S04, A solvent extraction procedure was used to selectively recover urani-um from Pumpkin Buttes and Nine Mile Lake leach solutions and to recover vanadium from the raffinates. In batch shakeout tests, Alamine 336 recovered over 95 pct of the uranium from leach solution adjusted to pH 1. Di-2-ethylhexyl phosphoric acid and Cyanex 272 recovered vanadium from the uranium raffinate after reduction and adjustment to pH 2; vanadium extractions of up to 96 pet and 92 pct, respectively, were achieved.

Jan 1, 1985

By K Mayank, A N. Mainza, I Govender, M Narasimha, A Mittal

In mineral processing industries grinding is the most energy-consuming process. A tumbling mill is an essential grinding equipment widely used for particle size reduction. Power consumption, impact forces and trajectory paths are critical parameters for characterising a tumbling mill to determine grinding efficiency. The effect of lifters and mill speed plays a vital role in such parameters. However, most of the studies ignore the impact of the lifter and do not investigate the effect of slurry dynamics on charge motion. The focus of the present work is to prepare a computational model that can accurately predict the complex multi-phase dynamics of charge particles, air and slurry inside the mill using a model that couples computational fluid dynamics (CFD) and the discrete element method (DEM). The details of impact forces with lifter profiles and mill speed variations will be refined even further using the CFD-DEM coupling approach. The slurry-air free surface is modelled using the volume of fluid (VOF) method, and the charge motion is modelled using the DEM. The phases are coupled using the interface momentum exchange between the charge and the fluid slurry. The coupled model is validated against experimental results from the positron-emitting particle tracking (PEPT) data. The validated model compares the effect of slurry content on charge dynamics with the dry DEM model. The presence of slurry is observed to dampen the tangential and shear contact forces.

Aug 24, 2022

By Robert van Hille, Alison Lewis

The precipitation of a selection of metals from both a synthetic and an actual metal-rich effluent was investigated. The experimental aspects of this study were carried out in a two-stage process consisting of a pre-treatment clarifier and a fluidised bed (pellet) reactor. Each unit operation in the two-stage process was investigated separately. The pre-treatment clarification stage at pH ˜ 5 resulted in a 99.9% removal of iron and 97.3% removal of aluminium. The pellet reactor was used to precipitate nickel as nickel carbonate from a pure stream and a removal efficiency of 99.6% was achieved. The high local supersaturation at the reagent inlet points caused the formation of a large amount of fines, but these agglomerated onto the pellets up the length of the bed. For copper precipitated as copper sulphide from a pure stream, a maximum removal efficiency of 92% was achieved. The high local supersaturation at the reagent inlets also caused the formation of a large amount of fines, but the extremely sparingly soluble nature of copper sulphide meant that the fines were not agglomerated up the length of the bed. For removal of cobalt as cobalt carbonate from an actual stream, a stable cobalt removal of only 60% was achieved. This was found to be due to the presence of magnesium, which reduced the cobalt precipitation efficiency through the formation of the magnesium bicarbonate ion.

Jan 1, 2003