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By Carvalho A. Felipe de

The search for environmentally friendly and cost-effective methods for gold extraction has been undertaken in order to provide alternatives to the use of cyanide leaching in the gold industry. Among such alternative reagents is the combination of chloride and hypochlorite ions due to their oxidation of metallic gold and its complexation. Therefore, the current work aims at investigating gold leaching from an oxidized material by means of a solution comprising calcium hypochlorite and sodium chlorite. The sample used in the current research contained 66.1% Fe2O3, 20.4%SiO2, and 35.7 g/t of Au. In addition, XRD and SEM-EDS analysis revealed iron oxide, quartz and muscovite as the main crystalline phases in the sample. For comparison purposes, cyanidation of the oxidized material resulted in 90% gold extraction in 24 h. The reference conditions for the leaching tests with the chlorite-hypochlorite system were: particle size −37 μm, solid/liquid ratio of 10% (w/v), 10 g/L NaCl, 10 g/L Ca (OCl)2, pH 5–6, 3 h of leaching. The effects of the: (i) Ca(OCl)2 concentration, (ii) NaCl concentration, (iii) pHrange and (iv) the effect of pulp density in the extraction of gold were assessed. In addition, the stability of the hypochlorite solutions (OCl−) was investigated. The ideal concentrations of Ca(OCl)2 and NaCl were determined as 25 g/L and 15 g/L, respectively, whereas the optimal pH range was 4–6. Under these conditions, the final gold extraction reached approximately 84%. By varying the solids content of the pulp (10%, 20% and 30%), it was observed that the lower solids value resulted in greater gold extraction (84%). The degradation of the hypochlorite solution and the possible catalytic effect of the presence of the solid were evidenced. To sumup, in the experiment, high gold extractions were achieved in shorter periods of time (3 h), as compared to the cyanidation of the same sample. On the other hand, itwas necessary to use significant amounts of the reagent due to hypochlorite instability at the pH conditions recommended for high gold extractions.

By Thomas Novak, Sampurna Arya

Controlling dust generation and keeping it below permissible limits to meet federal dust standards at the working face of a room-and-pillar coal mine is a challenge for a mine operator. With the recent changes in federal dust regulations requiring lower worker exposure, maintaining compliance has become increasingly difficult. The current most effective practice of dust control at a continuous miner face in an underground mine is the use of a flooded-bed scrubber. A study carried out by the U.S National Institute for Occupational Safety and Health (NIOSH) indicated that a flooded-bed scrubber could achieve cleaning efficiencies between 58 and 90 percent. But the operation of such a system is maintenance intensive. The flooded-bed scrubber screen becomes clogged with dust particles and requires frequent cleaning to maintain performance. However, the dust control issue is not solely a mining-industry problem. Other industries face similar issues. The University of Kentucky collaborated with Toyota Motor Manufacturing on the development of a novel wet scrubber, called the vortecone scrubber, for capturing over-sprayed paint particles in automotive paint booths. The vortecone scrubber achieved a cleaning efficiency of 99 percent and required minimal maintenance. This study aims to assess the ability of this vortecone scrubber to capture respirable dust in an underground coal mine. The paper presents the results of computational fluid dynamics (CFD) modeling of this vortecone scrubber. It discusses the effects of air quantity and dust particle size on the performance of the scrubber. 

By Gary L. Hundley

The Bureau of Mines has devised and demonstrated an ammoniacal sulfate leach process for recovering nickel and cobalt from low-grade domestic laterites. Solvent extraction of cobalt, one of the process steps, requires the reduction of hexammine complexes of C03+ to C02+ in an ammo-niacal leach solution. Previously, reduction was accomplished using cobalt metal shot in a column. This report presents experimental results and an economic evaluation comparing two alternate techniques with the shot column: (1) an electrolytic reduction cell with an extended surface area cathode and (2) direct electrowinning from purified leach solution using a cell with a fluid bed cathode. The second alternative eliminates the conventional solvent extraction-electrowinning steps. The costs of the three methods, based on the requirements of a pro-posed commercial-sized plant, including all unit operations, were deter-mined by the Bureau's process evaluation group. The operating costs for the shot column, $1.19/kg Co, and for electrolytic reduction, $1.20/kg, are essentially the same, but the cost of direct electrowinning, $3.77/ kg Co, would eliminate this method as a practical alternative. The cap-ital cost of approximately $14.4 million for reduction in a shot column is much higher than the approximately $4.4 million for electroreduction.

Jan 1, 1985

By Wm. I. Weisman

Sometimes in assessing where we are and where we are going it is informative to take a look at where we have been. Whether or not it adds to our understanding of the present, I think it may be interesting to review some of the past history of our industry. As a starting point I chose to use the famous Paley Commission Report, formally known as "The U. S. President's materials Policy Commission -Resources for Freedom."(l) The Paley Commission report said "Fluorspar is an essential raw material for the steel, aluminum, and chemical industries." Of course this statement is still true. It also said, "United States known reserves of fluorspar would be sufficient for some 15 years at present rates of consumption--about 426 000 short tons in 1960. Projected consumption for 1975, however, is several times as great, and reserves in other free countries do not appear adequate to supply United States deficiencies during the next 25 years." This simply demonstrates how even the most learned and competent people can observe all the facts avail-able to them at a given time and yet be unable to predict the future very accurately. We all know that reserves in other countries are more than adequate to supply the United States today, 25 years since the report was published. In fact, the report estimated free-world reserves at something over 36 million tonnes (40 million short tons). Contrast this with 246 million tonnes (271 million short tons) estimated as total world reserves from the section on fluorspar from Commodity Data Summaries of 1974, published by the Department of the Interior. (2) The Paley Report discusses other matters pertaining to fluorspar that are still of interest, such as improving mining methods. Furthermore, it certainly did a good forecasting job in noting that greater recycling should become possible in the aluminum industry in regard to fluorine lost in wastes and also concerning the substitution of fluorspar in the steel industry by other fluxing materials. It also suggested that non-fluorine containing propellants should be investigated as a replacement of those containing fluorine as a conservation matter. Some discussion was devoted to recovering the fluorine content of phosphate rock, which is being practiced today, but was in its infancy in 1950.

Jan 1, 1978

By Stephen M. Testa

Several methodologies are available for the remediation of contaminated soils including bioremediation, vapor extraction, chemical fixation, incineration and direct disposal. A proven innovative and cost effective alternative for the fixation of contaminated soils is via cold-mix Environmentally Processed Asphaltm (EPA"'). EPAm methodology utilizes contaminated soil as an ingredient in an industrial process to produce a commercially viable product. Petroleum hydrocarbon and metal affected soil is incorporated with a water-based asphalt emulsion and varying amounts of aggregate to produce a range of cold-mix asphaltic products that fulfills the requirements of a variety of end uses. This viable and creative use which is within the intent and spirit of current regulations in producing, in lieu of a landfill waste, an end product for use as a berm, road base, liner, or other site specific application. Consideration of certain engineering and environmental factors including durability, stability, chemical resistance and ageing, biological resistance, permeability, leachability and geochemical aspects suggests that cold-mix asphalt incorporation of affected soil will perform more than adequately under normal conditions for a long period of time.

Jan 1, 1994

By M. B. Shongwe, R. K. K. Mbaya, C. K. Thubakgale, P. Mendonidis

"A low-grade nickel-bearing ore was pre-concentrated on a SB40 laboratory model Falcon Concentrator. Three size fractions, -212+125, -125+75 and -75 µm were tested with the intent to upgrade the nickel content by reducing their content of fine silica, which becomes amorphous during leaching. Separation of silica from nickel-bearing magnesium silicate minerals; hornblende, clinochlore and talc, was more efficient in the finer particle sizes, -125+75 and -75 µm, and at high G-forces. For these two size fractions, nickel was upgraded from 0.06 to 0.07%, with a reduction in silica content from 52.12 to 50.71%. Leaching of feed samples prior to pre-concentration resulted in the formation of amorphous silica, indicative of the presence of fine silica in the samples. Leaching of nickel from the -125+75 µm fraction increased with increasing G-force and feed pulp percent solids, while that of -75 µm was not influenced. The optimum nickel recovery was 15.68% to the Falcon underflow, using the feed size fraction of -75 µm, 30 G and a feed pulp solids content of 10% solids, after 120 minutes of treatment.INTRODUCTION A low-grade South African nickel-bearing ore with about 0.06% Ni was previously studied for atmospheric pressure acid leaching using sulphuric acid. The study was motivated by the continuing search for methods to treat of low-grade ores, which appear to be an increasingly important source of valuable metals as a result of a declining production from rich sulphide ores. Nickel is a base metal that is used as an alloy in steelmaking and chemical industries because of its resistance to corrosion (Haudet et al., 2015). Nickel laterite ores with grades lower than 1.50% Ni are considered to be complex ores, accounting for 70% of the global nickel reserves (MacCarthy et al., 2016). Their complex nature may be attributed to the indefinite mineralogy of these ores, in which nickel may occur in more than one mineral host. In some cases, nickel may be finely disseminated in the ore. The grade of such an ore and complex mineralogy do not justify the application of pyrometallurgical methods for extraction of nickel (Zhu et al., 2012). This suggests that there is a need for less expensive alternative methods of extraction. This study investigates the application of centrifugal gravity concentration, using the Falcon concentrator, followed by leaching to determine the effect of pre-concentration of the ore prior to extraction by atmospheric pressure leaching with sulphuric acid."

Jan 1, 2017

By Aleksandar D. Bugarski

Three types of uncatalyzed diesel particulate filter (DPF) systems, three types of high-temperature disposable filter elements (DFEs), and one diesel oxidation catalytic converter (DOC) were evaluated in underground mine conditions for their effects on the concentrations and size distributions of diesel aerosols. Those effects were compared with the effects of a standard muffler. The experimental work was conducted directly in an underground environment using a unique diesel laboratory developed in an underground experimental mine. The DPF systems reduced total mass of aerosols in the mine air approximately 10-fold for light-load and 20-fold or more for high-load test conditions. The DFEs offered similar reductions in aerosol mass concentrations. The efficiency of the new DFEs significantly increased with accumulation of operating time and buildup of diesel particulate matter in the porous structure of the filter elements. A single laundering process did not exhibit substantial effects on performance of the filter element. The effectiveness of DPFs and DFEs in removing aerosols by number was strongly influenced by engine operating mode. The concentrations of nucleation mode aerosols in the mine air were found to be substantially higher for both DPFs and DFEs when the engine was operated at high-load modes than at low-load modes. The effects of the DOC on mass and number concentrations of aerosols in mine air were relatively minor when compared to those of the DPF and DFE systems.

Jan 1, 2009

By Lowell B. Moon

Concern over possible wartime shortages finally resulted in passage of the Strategic Materials Act in 1939. As authorized by one section of this legislation, the Bureau of Mines proceeded to investigate deposits of seven strategic minerals with the objective of developing tonnages of low-grade material that could be mined in an emergency. During the war, the size of the program and the number of strategic minerals were increased, and the objective was the more immediate one of aiding production. Since the war, the size of the program has been reduced, but the number of minerals on the strategic list continues to be large. The objective has returned to that of 1939. In the course of the program, more than 10,000 examinations were made and about 1,300 projects were run on deposits of 33 different commodities. A considerable contribution to war production was made in six of the commodities investigated, and a minor contribution was made in twelve others. Substantial reserves have been indicated in 19 minerals. Private interest is currently active in some of the deposits developed in 14 commodities.

Jan 1, 1950

By G Mendoza, L Taddei, C Robertson

It is a well-known industry fact that many mine sites around the globe experience blast holes that have elevated temperatures due to reactive ground, geochemical reactions, geomorphic reactions, sub level open fires, etc. It has been reported in many previous industry publications (White, Saputra et al) that elevated blast hole temperatures are a norm at many mine sites and are dealt with on an ongoing basis while the drill and blast process continues under elevated states of alert. The choice of explosives products including the type of detonator, primer, accessory, and bulk product all must be taken into consideration when loading blast holes where there is a known potential for elevated temperature conditions. It should also be noted that these elevated temperatures inside blast holes can be consistent throughout the blast hole length or vary in position within the blast hole depending on the mine conditions mentioned in the opening statement above. The risks associated with the loading of primers and bulk explosives in holes where elevated temperatures are present include: the ejection of the bulk explosives product, deflagration of the explosives during initiation of the blast or premature and uncontrolled initiation of a blast hole(s). This paper describes a unique and novel approach to the active monitoring of the temperature within blast holes with the application of electronic detonators with integrated temperature measuring (ITM) capabilities, deployed and demonstrated at a mine site in Mexico during January 2023 to March 2023. The deployment of ITM capable electronic detonators allows a user to monitor and record the real time temperature at multiple locations (e.g., toe, middle and collar) at each electronic detonator’s position within the blast hole, with the ability to react instantaneously to elevations in temperature reported. The measurement of the temperature can be for a single ITM electronic detonator, or simultaneous for an array of ITM electronic detonators, allowing for the potential for the data to be represented by a time/temperature/hole depth three-dimensional heat map. Changes in temperature at different borehole positions can vary, however, often the collar position is expected to be the most reactive due the combination of bulk explosive product and oxygen exposure, which can be confirmed with the application of the ITM electronic detonators. A mine site’s reaction to a measured elevated temperature within a blast hole can vary depending on the temperature measured and the change in temperature from the last measurement made. The study was found to produce real-time in-hole temperature information which was previously unobtainable without the introduction of another device. New and adaptive elevated temperature hole policies can be created and adapted proactively as real time information is received, leading to a safer mining operation.

Jan 21, 2025

By L. T. Munn

"IT IS NOT necessary here to dwell on the fact that sulphur is currently in short supply. It may be well, however, to •point out that this •storage is not merely a temporary condition, but that, judging by trends in world consumption of sulphur, it may •be anticipated that requirements will double in the next ten years.Even with improved techniques for mining elemental sulphur in the United States and the new finds in Louisiana, there is much concern as to how these future sulphur requirements can be met. It appears necessary to .turn more and more to other sources than elemental sulphur for •additional production. The three major alternative sources were:(1) By-product sulphuric acid •from smelter gases.(2) Sulphur and sulphuric acid from iron sulphides.(3) Sulphur from hydrogen sulphide contained in natural gas. The Jumping Pound sulphur plant of the Shell Oil Company of Canada, Limited, is designed to produce sulphur by the •third of these methods.Jumping Pound is a natural gas field about 20 miles west of Calgary where Shell has a number of producing wells."

Jan 1, 1952

By Dan Wang, Qiuju Li, Xiao Guo

The chemical states and ions interaction were significant interest to understanding columbite mineral/acid solution interface dissolution and reaction. The present research work was focus to explore the specific cations ( Nb5+, Fe2+, Fe3+) distribution near the ferrocolumbite mineral/acid solution interface, and determine these cations leaching sequence in sulfuric acid solution. X-ray photoelectron spectroscopy had the potential to provide detailed dissolution information by resolving chemical state and ion distribution of ferrocolumbite during sulfuric acid leaching process. The binding energy decreased in sequence as Nb5+- O < Fe2+- O < Fe3+- O, and increased in sequence as Fe3+- SO4 < Fe2+- SO4 < Nb5+- SO4 which revealed Nb in ferrocolumbite mineral more easily leached comparing to Fe. The ratio of Fe2+- O/Fe3+-O on leaching residue decreased, and Fe2+- SO4/Fe3+-SO4 ratio increased as sulfuric acid contraction increasing suggested that the Fe2+ oxidized to Fe3+ and released Nb from mineral and dissolved into leaching solution. The ratio of Nb/Fe was lower 0.07 with sulfuric acid contraction increasing which meant Nb dissolution promoted by oxidation of iron. The dissolution mechanism of Fe element in ferrocolumbite mineral was Fe2+- O broken and generated Fe2+. Fe2+ was oxidized to Fe3+ in concentrated sulfuric acid leaching solution. The dissolution mechanism of Nb in ferrocolumbite was that Nb5+- O was directly digested by H+, and the released Nb5+ complex with SO4 2− ion formed cation − anion pairs. The coordination of formation Nb5+- SO4 pairs and oxidation Fe2+ in mineral could promote ferrocolumbite dissolution.

Aug 5, 2023

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

By S. G. Kumar, R. G. Reddy

"Niobium aluminides offer the advantage of higher high temperature capability compared to other intermetallic aluminides due to the refractory nature of niobium. However, the reaction sequence in Nb-Al system is sluggish and currently there is a great interest in the processing aspects of these materials. In the present study, a systematic investigation was undertaken to compare the effect of different powder metallurgy processing routes on the phase relations and microstructure of 66Nb-22AH2Ti (in atom percent) alloy. The three different process routes adopted were: (i) cold pressing followed by reaction sintering; (ii) cold pressing and hot pressing followed by sintering; and (iii) arc melting, hydride-dehydride process to make the alloy powder followed by cold pressing and then sintering. The samples are analyzed by XRD, Optical Microscopy, SEM-EDS and EPMA. The analysis showed that alloy pellets made from pre-alloyed powders i.e., arc melting followed by hydride-dehydride process, gave good densification and more Nb3Al formation.1. IntroductionTo improve the performance standards of turbine engines, materials scientists are challenged to develop materials that have· high thrust-to-weight ratio with high specific strength, high specific modulus and good environmental properties at elevated temperatures. The conventional high temperature materials like nickel based superalloys are high in density and hence many of the high temperature materials scientists have focussed their attention on intermetallic aluminides like Fe-AI, Nb-AI, Ni-AI and Ti-AI in recent years. The phase relations and properties of alloys based on Fe-AI, Ni-AI and Ti-AI are fairly well known whereas little is known about the alloys based on niobium aluminides."

Jan 1, 1996

By Spencer Peng, Larry Wasik, Akram Alfantazi, Michael Mahon

A dynamic simulation of a zinc tankhouse is a potential tool to improve tankhouse production and cost efficiencies. A fully dynamic simulation has potential uses in the design of new tankhouses as well as in the optimization of existing facilities. Equations from previously validated models of a single cell have been adapted to the industrial dynamic process simulation software, CADSTM Plus. Based on the inlet concentration, current density, and electrode setup, the simulation can predict many parameters, including outlet concentrations, flow rates, current efficiency and energy consumption. Multiple cells have been simulated simultaneously, allowing for an entire hypothetical tankhouse to be modeled. The simulation can be used to dynamically predict the conditions in a zinc tankhouse throughout an operation time scale. Further applications of this model include, tracking impurity buildup, modeling of recycle streams and the development of new flow regimes within the tankhouse.

Jan 1, 2012

By S. K. Kawatra, S. J. Ripke

During 1998, 62 million tons of iron ore pellets valued at $1.7 billion were shipped from U.S. mines. These pellets are the primary source for domestic iron and steel production. During pelletization, binders are required to improve the green strength of the pellets. Each year, bentonite binder costs a typical plant from $3 million to $5 million. Reducing the bentonite dosage has the advantages of significant cost savings while producing higher quality, lower silica pellets. The authors have recently identified a new and important bentonite binding mechanism, the fiber theory. During this study, procedures were developed that took advantage of the ability of bentonite to form fibers, and resulted in a dramatic decrease in the necessary bentonite dosage. Acceptable quality pellets were produced with the bentonite dosages reduced in half from 14 lb/lt (0.66%) to 7 lb/lt (0.33%).

Jan 1, 2001

By Thomas Kennedy, Michael Bennett

"History never repeats itself, but it often rhymes." The old aphorism reflects how the study of the past may, perhaps, be most widely valued when it can be used to improve current and future decision making. The education the authors received as geotechnical graduate students certainly impressed upon them the importance of recognizing that not all wisdom is necessarily new. Much of their graduate coursework involved reading technical papers that had introduced concepts of outstanding historical significance in the field, such as pore pressure coefficients, stress paths, and the stress history and nor- malized soil engineering model. These papers gave the authors both respect for and interest in the historical develop- ment of the field. After graduation, the authors furthered and deepened this interest by continuing to expand their knowledge of the profession through both experience in practice and the review of additional literature.

Jan 1, 2023

By M. S. Moats

As smelter feeds become more complex, the impurities that ultimately report to electrorefineries are changing. Many of these impurities collect in the electrolyte and must be controlled. As commercial copper electrorefineries look to expand their capacities by increasing their operating current density, the interaction between electrolyte composition and anode passivation can cause operational difficulties. To improve the industry&apos;s understanding of the passivation phenomena, the role of electrolyte composition was evaluated using commercial electrorefining anode samples. The electrolyte composition variables examined were copper, acid, nickel, arsenic, chloride, thiourea and glue. Finally, the role of non-commercially utilized additives, such as bromide and polyethylene glycol were studied. From this investigation, electrolyte parameters that inhibit copper dissolution through copper sulfate precipitation, copper oxide stabilization and/or absorbed species lead to accelerated passivation. Species that prevent passivation have the ability to complex cuprous ions. Possible mechanisms for the role of each.

Jan 1, 2007

By T. Cutard, E. Cailleux, F. Nazaret, G. Bernhart

This paper deals with the study of the mechanical behavior in the 20°C-900°C temperature range of refractory concretes reinforced with metallic fibers. Fibers are introduced to improve the damage resistance and to minimize the quasi-brittle behavior of refractory concretes. In some cases, a plastic or ductile like behavior can be obtained. Two approaches are considered in these studies. The first one is based on the micromechanical scale. Main objectives are to understand, quantify and predict the thermomechanical behavior of monofiber microcomposites. Such considerations are helpful to optimize the composite formulation for a better behavior. The second one is based on the macromechanical scale. Main objectives are to characterize and to model the macroscopic thermomechanical behavior of randomly reinforced refractory concretes. A particular attention is firstly paid to the relationships between the microstructural changes and the mechanical properties and secondly to the structural size effects.

Jan 1, 2004

By R M. Papini, A C. Araujo, A E. C Per

Flotation is an important process used in the concentration of iron ores. One of the challenges for process engineers is the low metallurgical recovery associated mainly with the fines fraction. In this work, the use of synthetic flocculants in iron ore reverse cationic flotation was investigated. The flocculants utilised were polyacrylamides of high molecular weight and different ionic degrees. Bench scale flotation tests were performed to compare the flotation performance with and without addition of polyacrylamides. It was observed that cationic and non-ionic polyacrylamides cause a significant increase in the metallurgical recovery. The anionic flocculant did not improve the flotation performance. An adverse effect was a slight increase in the silica content of the concentrate. Flotation with polyacrylamides was influenced by the hydrodynamic conditions of the pulp, such as agitation and the weight percentage of solids in the flocculant conditioning and flotation stages.

Jan 1, 2005

By F. Rojas, M. Sanchez, J. Palacios, O. Pavez

Copper sulfide is the main mining resources in Chile, and most of this metal is obtained via pyrometallurgical extraction in seven copper smelter plants, which extends from the northern Atacama desert to the central part of the country. In 2002, 1,522,000 metric tons of fine copper were produced, with a notorious environmental impact due to the large amount of slag generated, including transportation and disposing problems. Therefore, there is a great interest in finding alternative uses in order to give additional value to the slag. This is a total project development concept, which consider residues as new resources where new components could be obtained, improving sustainability in mining activities and also ensuring clean production processes. Thus, the present work shows a review of copper slag characterization as well as several ways of utilization, including compact material for road and railway installation, part of admixtures in concrete.

Jan 1, 2004