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By O. L. Culberson, J. J. McKetta

Experimental and smoothed data are presented for the solubility of methane in water for temperatures of 77, 100, 160. 220. 280, and 340°F at prejsures to 10.000 psia. The minimum solubility phenomenon exists within this temperature range to pressures of 10.000 psia. INTRODUCTION The study of hydrocarhon-water systems has been extended to the determination of the solubility of methane in water at pressures to 10.000 psia. The experimental apparatus, and the technique. are the same as that previously reported.' - In the determination of the solubility of methane in water, only two phases were present at temperatures between 100 and 340°F. these being the vapor phase and the water-rich. liquid phase. The determinations involved the agitation of methane and water in an equilibrium cell. withdrawal of a sample from the liquid phase, and the analysis of the sample. The experimental value; determined in this manner are pre9ented in Table I and in Fig. 1. Since experimental and analytical techniques have improved since the initial experiments with this equipment, it was decided to repeat the 77°F isotherm determinations.' Fig. I shows that the individual results for this isotherm are much

Jan 1, 1951

By J. J. McKetta, O. L. Culberson

Experimental and smoothed data are presented for the solubility of methane in water for temperatures of 77, 100, 160. 220. 280, and 340°F at prejsures to 10.000 psia. The minimum solubility phenomenon exists within this temperature range to pressures of 10.000 psia. INTRODUCTION The study of hydrocarhon-water systems has been extended to the determination of the solubility of methane in water at pressures to 10.000 psia. The experimental apparatus, and the technique. are the same as that previously reported.' - In the determination of the solubility of methane in water, only two phases were present at temperatures between 100 and 340°F. these being the vapor phase and the water-rich. liquid phase. The determinations involved the agitation of methane and water in an equilibrium cell. withdrawal of a sample from the liquid phase, and the analysis of the sample. The experimental value; determined in this manner are pre9ented in Table I and in Fig. 1. Since experimental and analytical techniques have improved since the initial experiments with this equipment, it was decided to repeat the 77°F isotherm determinations.' Fig. I shows that the individual results for this isotherm are much

Jan 1, 1951

By M. Honarmand, Z. Moezifar, H. Ranjbar

Abstract - The Sar Cheshmeh area covers an area of 640 km2, and is located in the southern part of the Iranian Volcanic-Sedimentary Belt. ETM+ images have been used for alteration mapping. The Crosta method was found useful for enhancing exposed areas containing hydroxyl and iron oxide minerals. However, field checking has shown that this method is not able to identify all the known areas of hydrothermal alteration. Many of these altered areas are also not clearly resolved in the geophysical data. In order to improve resolution of such areas, integration of remote sensing and geophysical data may be helpful. The Darrehzar Cu deposit was chosen as a control area. The data have been divided into two sets: explanatory and target variables. The explanatory data are Landsat hydroxyl and iron oxide images and airborne geophysical data (K, U, and Th total counts, and total magnetics). The target variables are rock geochemistry and ground geophysics. Data analysis and integration of geophysical and remote sensing data were performed using directed principal components. This technique is found to be useful for the delineation of hydrothermally altered areas with more confidence.

Jan 1, 2002

By P. F. Mataich

When the subject of plant computers is brought up most people visualize the computer's con- trolling the entire plant with very little operator intervention. Actually, this picture is true today in only a limited number of cases and will certainly not be true in the minerals industries for many years to come. There are several ways in which a plant computer can significantly contribute to improving plant operation and closed loop control is only one of these. First of all, for good plant control, two basic requirements must be met. First, the operator must get good information feedback from the process and then he must know what action to take in response to this information. Control information can be obtained through instruments, laboratory analyses, or through simple visual observation. If it is timely and accurate and the operator knows how to use it, then we have the makings of a good plant control system. The computer can be of help in both these areas by getting good data back to the operator and in helping to develop a good control scheme for the plant.

Jan 12, 1966

By Glenn Keep

THIS paper is not an announcement of the successful conclusion of the Cerro de Pasco Copper Corporation's pacos-pyrite problems, but merely a description of the commercial-scale, intermittent-roasting operations conducted by the writer, J. H. Lucas and others of the staff. It was prepared by request, for presentation at the February meeting of the Institute. The results obtained in Peru confirm the 1-ton-a-day experiments completed about three years ago at Kearny, N. J. by C. C. Gordon and Mr. Lucas, where it was first demonstrated that a mixture of about 80 per cent. pacos ore with 10 per cent. pyrite ore and 10 per cent. salt could be roasted intermittently in a small 1-ton-a-day Holt-Dern furnace without extraneous fuel, producing porous calcine that could be leached rapidly. Mr. Keep and his staff, by successfully introducing improvements in the construction of the commercial furnace and in their handling of material, have established beyond doubt a low cost for roasting. The other steps in the process of treating pacos and pyrite ores have not as yet been demonstrated as sufficiently conclusive to warrant their acceptance for a permanent plant.

Jan 1, 1929

By William E. Bruce

This paper is intended to provide an improved understanding of natural draft (natural ventilating pressure) and the effect of natural draft on underground mine ventilation circuits. Attention is focused on measurement of natural draft pressures during ventilation surveys in mechanically ventilated mines and on different methods for modeling natural draft using the measured data. A number of examples are presented which utilize data collected during absolute air pressure surveys made by personnel of the Ventilation Division of the Mine Safety and Health Administration's Safety and Health Technology Center, Denver, Colorado. Examples are used to illustrate how the data from absolute air pressure surveys may be interpreted to determine whether natural draft pressure is present and what its magnitude is. In addition, two different methods are described for mathematically estimating the magnitude of the natural draft pressure. Comparisons are made of results obtained using the different methods. Different procedures are described for modeling natural draft using the MSHA-modified Penn State computer program. Use of the routines is described and illustrated relative to drafts that aid or oppose the mechanical ventilation system. Tabulations of results facilitate comparison of outcomes obtained using the different modeling procedures.

Jan 1, 1982

By Sergio Demetrio

Based on the current reality of the copper smelters industry, besides the advances that have been and are expected for the next few years, the authors present a futurist vision of the processing of copper concentrates and copper smelters in the years 2000. Outlined new development strategies and ways of improvement in this business, including research, development and management of the works that today posses characteristics of a profitable operation, as well as the changes expected with respect to the entry of new actors and the creation of new products The authors finally bet for small or tailor-made smelters with ad hoc technology for their raw materials and few units to coordinate -devoted to specific concentrates using high technology and low manpower. Considering the in-situ hydrometallurgical route, as well as the pyrometallurgical route in works or conversion facilities that buy or process white metal and produce copper and other metals associated with this such as gold and silver, besides sulfuric acid, plants which should be strategically located in zones with high sulfuric acid price to make this a product which contributes to the profitability of the business.

Jan 1, 1999

By Jorj Osterberg

550 load tests of up to 150 MN have been completed on driven and bored piles using the Osterberg Load Cell. Because the test measures side shear and end bearing separately, much can be learned about the forces on the pile as it is loaded to ultimate capacity. At working loads side shear almost always far exceeds end bearing, with the distribution of shear and bearing greatly affected by disturbance occurring during drilling operations. Since much less movement is required to mobilize side shear than end bearing, most of the bearing develops after the working load is exceeded. Thus with insufficient bottom cleaning, safety against excessive settlement can be considerably reduced. Improved methods of drilling, hole cleaning, rebar cage installation and concrete placement are discussed. For rock socket piles it has been found that the ultimate test load far exceeds the working loads in most cases. This is almost always due to greater penetration into the rock than is required for adequate safety against excessive settlement. Factors affecting rock socket capacity are discussed. Increase of side shear and ultimate capacity with time is discussed. Case histories for driven and bored piles in soil and rock sockets are described.

Jan 1, 2001

By R. L. Loofbourow

We are concerned with the destabilizing effects of water inflow and remedies which can be used to reduce that cause. The number of these remedies which have already been demonstrated in mining may be a surprise. Several possible remedies, well known in other work seem worth trial. In saw mines the destabilizing effect of inflow is negligible; in others it can be disaster. Inflow can reduce stability in mining for very nearly, if not all minerals, whether by open pit or under- ground methods. It might cause trouble in saw under water work. As examples of these effects consider hydrostatic pressure on the walls of fractures and ' lubrication' of clay seams. Skin protection by paint or gunite is not likely to help. It is generally necessary to go deeper, for example to drain the ground more effectively or to reduce inflow. The improvement of stability is but one of a score of possible advantages attainable with water control. Most of these advantages would help costs as wet mines go deeper for leaner ore while coping with more restraints and higher costs of per, labor and supplies. Investigation is promising!

Jan 1, 1983

By Louis B. Slichter

Prospecting is certainly the world's biggest and best gambling business. It is a game where the chips cost many thousands and where many millions, even billions, can be won. An attractive feature of this gamble is the fact that the players are free to rig the odds as favorably as possible. Only the limited bounty of nature, the restrictions of the laws of the land, the competition from other players, the limited sagacity of the player himself- only these, and other factors, restrict the possibilities for large winnings. Today probably about half the land surface of the earth remains to be searched for signs of ore visible at the surface. It is fortunate that so much land still remains for exploration by relatively economical methods. Looking to the future, it is a good guess that the costs of finding ore will increase in response to increasing technical difficulties. To continue to achieve profits from prospecting, it will become necessary to analyze the business more skillfully, in a more and more sophisticated manner. Whenever feasible, qualitative concepts must be replaced by their quantitative equivalents, improvements, and extensions.

Jan 6, 1960

By Sarah Guzzelli, Enrigue Munaretti, Anneliese Botelho, Jair Koppe

Drill and Blast (D & B) is one of the main operations in the mining production cycle, which aims to fragment rock according to a pre-defined plan for proper loading, haulage and processing specifications. In this sense, data from a Brazilian iron ore mine was analyzed, given emphasis on blasthole length, subdrilling and stemming. The D & B report, including mining data such as number of blastholes, length, and diameter and stemming aspects, was analyzed in order to be able to compare these results with the blast design. The study showed significant differences between the designed blasting pattern and that one obtained by the operation. As a consequence, problems such as inadequate fragmentation, incorrect size distribution and loss of energy, were identified. For example, when stemming has a different length than it should have, noise and flyrock can occur, including inadequate fragmentation and vibration in both situations. Therefore, a comparison between the usual D & B procedures and recommended D & B design based on literature reveals the most important deviations and their consequences. The study intends to identify solutions for simple problems, improving D & B operations and safety practices.

Jan 1, 2014

By H. R. Quina

Phosphate is one of the most important minerals in our world today. It contains the life-giving element of phosphorus, which is essential to the growth of every living cell in plant, animal, and man. This vital mineral is found in twenty-three states of the United States; however, for more than 70 years, Florida has led the nation in phosphate-production and now produces 70% of the requirements of this country. Since the early 1880% when rich phosphate deposits were accidentally discovered in a river-bed in Central Florida, the industry has developed into a multi-million-dollar operation. Phosphate mining began in Florida in 1887 with very crude methods and equipment. The original process was necessarily slow and tedious, resulting in total production of 3000 tons in 1888. Progress was made in improved mining operations, and by 1894. Florida had grabbed the lead as the nation?s largest phosphate-producing area, and is still in the top position.

Jan 1, 1962

By K. A. Hildebrant, J. R. Norgate

"Synthetic lubricants have for many years documented extended service life and provided superior performance in temperature extremes. Increasing interest in synthetics' ability to reduce energy costs has resulted in laboratory and industry application evaluations. These tests have documented savings in functions such as worm gear drives, spur gears and in compressors. Energy savings data are presented as well as payback calculations as low as thirty days.The National Research Council of Canada has estimated that the Canadian economy loses over five billion dollars per year in friction and wear. Figures quoted were for 1986 during which it was estimated that nine hundred and forty million dollars were lost in the mining industry alone"" It has been further estimated that about 115 million dollars can be immediately recovered through improved tribology practices (Table I).The purpose of this paper is to present results and savings opportunities through the use of synthetic lubricants in various but common applications. Many other areas exist with the opportunity for energy savings such as in the use of more efficient drive equipment, reduced contact seals, spray mist lubrication systems and reduced friction coatings on rotating equipment such as pump impellers"

Jan 1, 1994

By Joseph E. Pogue

THAT the domestic consumption of gasoline displays a marked seasonal variation, with a low in the winter and a high in the summer, is well known. It is logical to expect that the nature of the variation has itself been undergoing a change as a result of improvement in roads, general employment of closed cars; and growth of mass haulage; but so far as I am aware the change in seasonal variation has never been investigated and measured. It is the purpose of this paper to present the method and results of such an investigation undertaken as a contribution to the technique of planning operating schedules now so prominent in connection with the functioning of the industry under a Federal quota system. For the method employed I am in-debted to the suggestions and help of Frederick R. Macaulay', who kindly looked over the work sheets; and credit is due Barnabas Bryan, Jr., for assisting in the computations and the graphic work. Ideas for the approach to the problem were also derived from an article by Aryness Joy, and Woodulief Thomas of the Division of Research and Statistics of the Federal Reserve Board*-.

Jan 1, 1934

The major incentives for developing continuous processes for the production of formcoke are to achieve a wider range of coals which can be used, greater operating flexibility enabling the production of various coke qualities, and environmental improvements. The characteristics of a formcoke which must be considered when assessing its performance in the blast furnace are compressive strength, abrasion resistance, volatile matter, reac- tivity, porosity, density, size, shape, ash yield and sulphur content. Lurgi's development work in attempting to pro- duce a formcoke which meets the specified requirements has resulted in most current efforts being concentrated on the Bergbauforschung/Lurgi hot briquetting process. This process blends hot char produced from a non-caking coal with small quantities of caking coal in a special mixer in the plastic range of the caking coal. The material is subsequently briquetted hot, then subjected to a thermal after-treatment to produce a strong abrasion resistant formcoke. A 650 tonne per day plant for British Steel Corporation is now under construction. A study of the equipment requirements and the operating costs indicate that the economics of large scale formcoke plants compare favourably with those of conventional coke-making plants.

Jan 1, 1975

By K Thompson

The Diavik Diamond Mine is a world-class operation located in an extreme environment 220 km south of the Arctic Circle in CanadaÆs Northwest Territories. The mine has a number of distinctive characteristics û such as limited winter access via an ice road, mine infrastructure being located on an island, with mining taking place behind dykes holding back a lake, temperatures at the mine that get down to -45¦C in winter, and the presence of bears, wolves, foxes and wolverines! One thing that Diavik does have in common with other mines around the world is the need for reconciliation. In late 2005 Diavik implemented SnowdenÆs Reconcilor software system to facilitate the process of reconciling geological models, mine plans, production data and plant results. This paper provides a case study of the reconciliation system implementation. It outlines the migration of Diavik away from a comprehensive and effective spreadsheet-based reconciliation process to a commercial grade, automated and web-based information management system. This paper documents the reasons for moving away from the spreadsheet system, the key parameters used for reconciliation, and the benefits gained by closing the loop between reconciliation and ongoing process improvement.

Jan 1, 2006

By O. B. Bucklen, J. P. Matoney, P. G. Meikle, R. L. Terry

INTRODUCTION The trend in the coal industry for many years has been to make every- thing "bigger and faster." This also holds true for loading and storage facilities. Where once a 1 million st per yr (910,000 mt/yr) mine was rare, 3-5 million st per yr (2,730,000-4,550,000 mt/yr) mines are not uncommon today in the bituminous industry. This great increase in production, made possible through mechanization, requires greatly improved loading facilities just to get the coal away from the mine. Also, there is a trend to- ward combining production from more than one mine and cleaning it in a single preparation plant. In addition to increased loading capacity, this frequently necessitates raw-coal storage and blending facilities. The development of the unit train with its attendant economics has contributed more than any other factor to the widespread construction of storage and high-speed loading facilities. In the export market, the construction of ever larger coal colliers has added to the need for faster and larger loading facilities. In this climate of rapidly changing technology, any written ac-

Jan 1, 1979

By Van Barnefield J G

This paper is based on an evaluation project engaged upon jointly by Mount Isa Mines Limited nnd" IBM Austra]ia Limited. Mount Isa Mines Limited produces most of its copper from large underground open stopes within massive orebodies. Variations in the position and shapes of these stopes can result in improved metal recovery. An interactive graphics system has been developed to assist the mine design engineer optimise his design. The system can assist the engineer throughout the orebody visualis- ation, initial design and optimisation phases of his design. At any stage the engineer may call upon the display of gridded mesh data, digitized ore outlines or existing stopes or development (drives, cross-cuts). This information may be viewed in plan or any vertical section or in three dimensions with rotation. Tonnage and grade calculations may be quickly performed for initial stope outlines or for modifications to them during the optimisation phase. The system design is highly modular. An array of functions for the manipulation of coordinate and line information may be linked with the development or stope design functions in whichever way the designer desires.

Jan 1, 1977

By Martin H. Stanczyk

Under the Solid Waste Disposal Act, the Bureau of Mines initiated several accelerated in-house research programs to develop new and improved methods of proper and economic solid waste disposal. The program being conducted at the Bureau' College Park Metallurgy Research Center is concerned with eliminating the current waste of valuable materials in municipal refuse by developing low-cost methods for reclaiming and recycling the metal and mineral values contained in incinerator residues. Each year the United States must collect and dispose of in some manner or other, about 150 to 200 million tons of municipal solid wastes. The monetary output for this service ranks third among public services, exceeded only by the costs for schools and roads based on population growth projections and materials use patterns, the quantity of refuse generated by the early 1980's may approach 300 million tons annually. Currant estimates indicate that only 10 to 20 percent of the total municipal refuse generated is disposed of by incineration. If all refuse were properly incinerated the residues would contain more than 11 million tons of iron and nearly a million tons of mixed nonferrous metals including aluminum, copper, lend, zinc, and tin.

Jan 1, 1969

By Joseph Kelly

DEPLETION of anthracite resources in Lackawanna County, Pennsylvania, has forced the recovery of coal tracts formerly considered unminable. Chief among these are the large areas of outcrop coal lying on a heavy pitch on the mountain sides, abandoned thirty or forty years ago as too costly and too hazardous to mine. The old companies, in many instances, stopped their chambers 80 or 100 ft. hack from the actual outcrop, and then dropped back another 100 ft. before starting to rob the pillars, thus leaving large areas of coal. Recovery of this coal naturally leads to mining hazards not encountered years ago. The first step is to sink a slope from the surface with the pitch of the vein, and then drive counters across the pitch as close to the robbed area as proper protection for the lower side of the -counter will permit. Next, the old chambers are advanced or new ones driven in the solid, as the conditions require. As these chambers approach the outcrop the real safety work begins-that of preventing the miner from being buried or locked in by an avalanche of mud.

Jan 1, 1936