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By G. E. Agar

This paper deals with the prediction of locked cycle flotation results from data developed from individual batch tests. A postulate is made that the distribution of material in a separation stage is determined by the chemical conditions and the flotation time and that this distribution can be characterized by split factors which are constants for a fixed set of conditions. With this premise, it is demonstrated that a steady-state balance can be calculated for a circuit. Although the necessary equations can be solved algebraically, a computer program was written that uses an iterative technique to arrive at the steady-state balance. The program is written so that a variety of circuits can readily be simulated. A number of examples are examined to demonstrate the validity of this simulation procedure. The sensitivity of the material balance to changes in the split factors was examined. Data developed from different flowsheets are presented on sulphide ores, on copper-nickel separation and on silver flotation.

Jan 1, 1978

By Wallace W. Roepke

Research on coal cutting at the Bureau of Mines Twin Cities Research Center (TCRC) has evolved from a purely mechanical approach, specifically to reduce dust or frictional methane ignitions, into an understanding of the complexity of the cutting system relationships. Achieving an understanding of these relationships requires a wide variety of testing techniques and equipment. Laboratory facilities and the associated equipment exist for shallow to deep cutting in both coal and coal-inclusive rock with any desired bit type. Research efforts with this equipment are providing insight for significant advances to help solve the problems of pneumoconiosis and frictional ignition. This effort will ultimately affect both respirable dust and methane ignitions at the face through better bit design and will increase the salable percent of run-of-mine (ROM) coal processed. It will also affect the design of rotary-drum cutting continuous mining machines (CMM) and longwall machines. This report describes the main features of the coal cutting research facilities at TCRC.

Jan 1, 1983

By E. G. Erspamer

Laboratory investigations were made by the Bureau of Mines on ore containing the sulfides of both mercury and antimony to develop a method or methods for the economic recovery of mercury metal and the concurrent recovery of antimony as metal or salts,. If standard mercury-recovery techniques are applied to such ores, the antimony content interferes with the effective production of mercury metal; further-more, the antimony is lost. This report presents the results of tests on a sample of cinnabar-stibnite ore from the Red Devil mine near Sleitmute, Alaska. Red Devil ore was chosen for the investigation because it is purported to be typical of ores of the Kuskokwim River area, which, in their aggregate, constitute large potential reserves of mercury and antimony. Studies included petrographic, spectrographic, and chemical analyses, gravity-separation tests, bulk flotation of mercury and antimony sulfides, differential flotation, leaching, and furnacing of crude ore and of flotation concentrate.

Jan 1, 1956

By David W. Evans

"Induced hydraulic fracture of strata during roof bolt installation is a potentially prevalent, but masked phenomenon within the underground coal industry. Previously reported resin testing programs (McTyer et al., 2014) examined the relationship between resin mixing effectiveness and varying bore hole diameter. The methodology employed within this earlier test program facilitated a further critical area of research – the measurement of back pressures generated within the bore hole during standard rock bolt installation practices. Experimental data has indicated that fluid resin can be pressurised to levels where it exceeds the compressive strength of the strata, inducing hydraulic fracture within the immediate area of the bolting horizon. The routine cycle of roof bolting serves to propagate this effect, progressively fracturing and delaminating the roof during mine advancement. This masked phenomenon can lead to a perception of difficult ground conditions - mining efficiencies and costs are therefore affected, with increased needs for additional support subsequently required to restabilise the inadvertently damaged roof.Further analysis of the parameters associated with resin bolt installation has now been conducted, assisting in the development of an empirical relationship between bore hole pressure, bore hole diameter and bolt insertion times. This relationship has been analysed for 15:1 ratio resins and 2:1 ratioresins, within 28mm and 30mm boreholes. Further to this, load transfer performance has been comparatively assessed for both 28mm and 30mm boreholes, suggesting that for 2:1 resins, acceptable resin mixing and load transfer can be obtained within a 30mm bore hole. The combination of 2:1 resins, utilised within a 30mm bore hole, may well provide the optimal solution to reduce the risk of hydraulic fracture in weaker strata during resin bolt installation.INTRODUCTIONA growing number of industry papers have previously investigated areas of concern associated with the performance of cartridge style resins in roof bolting, predominantly focussing on the effects of plastic film gloving, inadequate resin mixing and the pressurisation of resin within the bore hole. These three effects have a critical influence on the load transfer of the steel bolt element, through the cured resin and into the surrounding strata.Gloving occurs due to the plastic film of the resin cartridge partially encasing or wrapping around the steel roof bolt element – a known phenomenon over many years (Pettibone, 1987). The plastic film creates regions of discontinuity between the bolt, cured resin and borehole, reducing effective load transfer into the strata. Experimentation conducted into the effects of bolt ends fully encased by plastic film (Pastars and MacGregor, 2005) revealed that load transfer can be reduced by 85 to 90% in worstcase occurrences. It is also known that the aggregate filler size used within the resin can assist in shredding and breaking up the plastic film – this effect was observed in a previous study on resin mixing effectiveness (McTyer et al., 2014)."

Jan 1, 2015

By Ali Azizian, Brian Hall

"Driven piles were selected to support the Fraser Heights Bridge bents. Piles were a key component of the top-down construction approach, which was adopted for minimizing potential impacts on an environmentally sensitive wetland. Project requirements mandated verification of pile capacities using dynamic methods. More than 40 Pile Driving Analyzer (PDA) tests were performed. The subsurface conditions were highly variable. On the east side, piles extended through loose sands, soft silts/clays, and two peat layers and were founded in glacial till-like soils at about 45 m depth. However, on the west side, till-like materials were so shallow that it was difficult to drive the piles sufficiently deep to obtain the necessary lateral support. This paper provides an overview of the geotechnical considerations of the bridge design and top-down construction approach, and expands on the presentation of PDA results and how they compared to pile capacity estimation methods and parameters recommended in the applicable design codes.INTRODUCTIONThe Fraser Heights Bridge (FHB) was a component of the Fraser Heights Connector (FHC), a 2 km section of the South Fraser Perimeter Road (SFPR), constructed as part of the Port Mann/Highway 1 (PMH1) Improvement Project. The FHC is located in northeast Surrey BC (Fig. 1).Two major design and construction determinants were: 1) a mandated tight schedule to provide a non-tolled alternative to a new toll bridge; and, 2) an obligation that construction had to occur with minimal impact on the environmentally sensitive wetland the FHB crossed, including limiting the footprint of the permanent and temporary works to less than 45 m2, and prohibiting construction access onto the wetland. Construction equipment was only allowed on the wetland on temporary trestles or on the finished structure. This latter requirement resulted in the bridge being constructed span by span, using a top-down approach."

Jan 1, 2016

By Lv Guozhi, Ren Xiaodong, Liu Yan, Dou Zhihe

"This paper investigated a new desulfurizer, dolomite and ferrosilicon. Magnesium vapor produced by silicothermic reduction of dolomite and ferrosilicon in an immersion tube of molten iron was injected into the molten iron by carrier gas through the underpunch of the tube and desulfurization reaction occurred. In order to explore the desulfurization process of molten iron by the new desulfurizer, the thermodynamics, and experiments of magnesium vapor production and desulfurization have been studied. Through thermodynamic calculation, the reaction temperature of magnesium vapor production by 75ferrosilicon and light-burned dolomite is 1838K in the standard state and decreased with the decreasing partial pressure of magnesium vapor, PMg· When PMg=25kPa, the reaction happens at 1673K. From experiments of magnesium vapor production, reduction efficiency of Mg vapor is about 60 % in 15 minutes at 1673K. From hot metal experiments, the desulfurization efficiency is 89.35%, and the lowest sulfur concentration after desulfurization is 46ppm.IntroductionPretreatment desulfurization of hot metal has become a necessary step in modem optimizing steelmaking process for its cheap cost, which can not only liberate of blast furnace productivity and reduce the burden of produce steel, but also effectively improve overall economic efficiency of the iron and steel system[l-ZJ_ At present, injection magnesium particle is one of the two main methods of desulphurization in hot metal owing to its strong affinity for sulphur, low amount of slag produced, low iron loss in slag skimming and low equipment investment[3l. However, there are still some insufficiencies on the hot iron pretreatment with magnesium particles at present[4-5l"

Jan 1, 2013

By Edgar G. Tuttle

The accompanying figures show the arrangement of a twocompartment excentric jig fitted with adjustable and automatic discharges for drawing oft' the lower product obtained in jigging minerals, ores, coal, etc., which is designed to remove or separate more effectively the materials treated, as they travel over the jig from the receiving- to the discharge-points.

Jan 1, 1897

By Joseph L. Uraco, Harry C. Verakis

The use of explosives in underground coal mines presents a potential risk for serious injuries and death to miners. Widespread disasters have occurred from the explosion of methane and/or coal dust initiated by blasting with explosives. Many of these disasters took place in the early 1900's when the use of black powder for blasting was prevalent. Historically, the investigations in the U.S.A. to develop and test safer explosives for blasting coal began in 1908 when a testing station was established in Pittsburgh, Pennsylvania. Since that time, great strides have been taken in the development of safer explosives. The use of safer explosives has significantly reduced blasting accidents in coal mines. Enactment of legislation, such as the Federal Coal Mine Health and Safety Act of 1969 and enforcement of regulations has also improved blasting safety. More recently, MSHA began a major revision of its regulations for blasting in coal mines. In 1988, MSHA published final rules for the approval and use of permissible explosives in coal mines. The approval requirements for explosives address testing and evaluation. The requirements include tests for sheathed explosives which represent a new technology. The use regulations provide increased safety protection for miners by including standards to address identified hazards. Major aspects of these standards, such as qualifications for blasters, multiple-shot blasting and the use of sheathed explosives are discussed.

Jan 1, 1992

By H. F. Yancey

Although a general relationship exists between the two criteria used to measure sharpness of separation -error area and probable error -they sometimes give quite different appraisals of a particular washing operation. Error area takes into account how the entire raw coal was treated, whereas probable error reflects only how the material of intermediate density was separated, ignoring completely the recovery of clean coal and the rejection of heavy impurity. Error area is thus more reliable for general use. In heavy-medium cleaning, sharpness of separation decreases with increase in separating density, but ordinarily the change is not great enough to affect the yield and ash content of washed coal measurably. Therefore, distribution curves for heavy-medium units can be transposed from one separating density to another, at least in the range of separating densities ordinarily used in the United States.

Jan 1, 1955

By D P. Blair

There are two major aspects to wall control blasting – the potential for any blasthole to cause wall damage and the potential for a delayed sequence of blastholes to cause damage. The damage potential of individual blastholes is governed by standoff distance and charge weight. However, for locations sufficiently close to a highwall, dynamic finite element models and field measurements show that there is also a critical nature to those blastholes very close to the wall, over and above standoff distance. At many mine sites, the charge weight/standoff-distance is set by trial and error. Thus, a significant aspect of the present work is the determination of dynamic stress radiating from a blasthole. Unfortunately, the modelling and measurement of this dynamic stress is still faced with many difficulties. Typical models have questionable aspects, which casts serious doubt over their predictions, and it is shown that the Hustrulid Bar experimental technique does not correctly account for stress wave attenuation in extended media. In an attempt to solve the dynamic stress problem, the present work describes a model based on an exact solution under the assumption of viscoelastic material. The model takes full account of the rock mass elastic/viscoelastic properties, the explosive type, geometry and primer location and predicts a dynamic stress for direct comparison with the unconfined compressive strength of the local rock mass. This model predicts the standoff distance required to avoid damage due to a single blasthole. The behaviour of a delayed sequence of blastholes is analysed using an upgraded waveform superposition model, covering a range of initiation delay combinations, which predicts the peak particle motion (PPM) induced in the wall for each combination. This approach shows that there is no need to fire dedicated trim shots close to walls; all that is required is a carefully modified production shot. The mechanism of vibration screening is discussed, and its use in a superposition model highlights the potential of reverse firing (shield blasting) to reduce wall PPM. A conceptual model is also introduced to give a further insight to vibration screening and damage (via ground heave). This model predicts that a centre-lift blast will have a central heave profile and that a reverse-fired shot will produce a smaller power trough than that produced by a standard shot. It is demonstrated that the mechanism of presplit formation is not well understood; nevertheless, experimental evidence shows that presplits can be an effective method for reducing wall vibrations.CITATION:Blair, D P, 2015. Wall control blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 13–26 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By NA NA

Listing safety award winners, £I43M has been added to proceeds from coal privatisation in the year to March 1997, bringing total revenues to over £1.3bn, some company news in brief.

Jan 8, 1997

By S Grimsey, E Janetzki, J Emery

Floor failure on the longwall face is a complex problem due to the dynamic interaction between the surrounding strata and powered roof supports involving multiple variables. It can also be highly problematic and costly when not well understood as there are significantly less remedies available post event. This was the early experience at the case study mine where significant lost time was incurred due to unplanned delays in the first two panels. To detect and prevent such occurrences is clearly the best approach, hence a tool to predict both floor failure occurrence and magnitude prior to mining was developed. Several parameters were determined as the key drivers for the failure events that had been experienced at this site. These parameters were, in list of influence from highest to lowest, material strength, retreat rate and the presence of water. The parameters were evaluated using a semi quantitative risk rating system ‘Heave Risk’ and given a weighting per their apparent influence. This ‘expert system’ methodology was selected as the use of risk rating systems in underground coal mining is well established. The heave risk model was first applied to previously mined panels. It accurately identified all areas of known major floor heave, with clearly defined areas of low and high risk apparent. The heave risk model was then used prior to mining and evaluated post mining based on observed conditions. It was found to also be highly accurate for prediction. The variability of each parameter and its influence on the overall risk rating is illustrated and discussed.

Nov 29, 2022

By E. Marburg

Most ingots complete solidification vertically rather than transversely. This conclusion is based on complete solidification patterns of big-end-up and big-end-down ingots developed from dumped and split ingots. New mechanisms for segregation in ingots are proposed. Internal soundness in ingots is found to depend upon adequate width of vertical core. A LTHOUGH it has long been recognized that the A internal soundness of ingots is principally been recognizedthatthedependent on the process of solidification, knowledge of this process is still only fragmentary. The mechanisms causing the several types of segregation in ingots, which mechanisms are necessarily related to the solidification process, are not well understood. In absence of a better conception of the solidification process, it seems hardly surprising that mold design varies widely. Guiding principles for mold design are needed. At stake in the improvement of ingot quality are not only improved properties of steel but also appreciably higher yields of sound steel, which would considerably decrease manufacturing costs. In the present study, following a general description of the several types of segregation in ingots, Fig. 1, complete solidification patterns of a big-endup and a big-end-down ingot, including the zones of accelerated solidification, have been reconstructed. In both ingots, a core of vertical solidification extends from the base cone to the hot-top junction. Based on the finding that ingots complete solidification vertically rather than transversely, as has been previously assumed, new mechanisms for segregation in ingots are proposed. Internal soundness in ingots is found to depend upon the width of the vertical core, which in turn depends principally upon the width to height (w/h) ratio of the ingot. Solidification patterns of ingots are of three general types: 1—those in which vertical solidification does not reach the top, 2—those in which vertical solidification just reaches the top of the ingot, and 3—those in which vertical solidification reaches the top some time before transverse solidification would reach the middle of the ingot, so that a vertical core of definite width at the top of the ingot is developed. Axial defects vary characteristically with the solidification pattern. Examples of ingots of each type are presented. Dumped ingot data reported by Nelson' have been used in developing families of curves of transverse and vertical solidification, and in deriving the effect of the w/h ratio upon the solidification pattern. Photographs of many ingots split at Homestead and at Duquesne Works, United States Steel CO., as well as those published by the British Iron and Steel Institute,' have been studied and analyzed. In the interest of brevity, only typical ingots of each type or classification from the above sources have been reproduced. Segregation in Ingots Segregation in ingots falls into three principal classifications: 1—lamellar segregation, as revealed in sulphur prints (Figs. 2 and 3); 2—zone segregation, or broad variations in composition; and 3— interdendritic, or microsegregation. The last class, of minor importance, is not considered here. When liquid metal cools, according to the theory of differential or selective solidification,2 metal of relatively high purity selectively solidifies first. Liquid segregates (principally carbon, phosphorus,

Jan 1, 1954

"It’s been 80 years since Charles Warman invented the iconic Warman slurry pump, a pump that revolutionized the mining industry and continues to push the boundaries of pump performance to this day.In honor of this legendary brand, Weir Minerals hosted an event at the end of May in Kalgoorlie, Western Australia. Throughout the evening, attendees relived Warman pumps’ history and gained an insight into some of the future innovations planned.“It was a privilege to share this special night with some of our key customers, past and present employees, and members of the Western Australian School of Mines,” said Ricardo Garib, divisional president of Weir Minerals. “Warman is one of our leading brands. It has truly shaped the mining industry over the past 80 years and is a product we are all very proud of. The Warman pump, invented to solve high wear issues in slurry pumping, created a thriving industrial business that is now the cornerstone of Weir Minerals with more than 8,000 people, and more than 150 manufacturing and service centers across the globe.”Always inventingCharles Warman invented the Warman slurry pump in Kalgoorlie in 1938. It was a hardwearing slurry pump that used replaceable liners and a replaceable impeller, something that had never been done before.“Charles Warman was a visionary and an innovator. The use of rubber lining in the pump was groundbreaking as it reduced total ownership costs, was safer to handle and offered extended wear life in many abrasive slurry applications. It is a great example of solving customer problems with material science, and is still taught in universities today,” said Marcus Lane, global product manager for centrifugal pumps at Weir Minerals.It was quickly adopted throughout the goldfields in Western Australia and by the 1950s, as customer demand rose, Warman expanded his business by opening offices in Sydney and Perth.During the 1960s the rapid growth of the business continued with manufacturing and sales outlets established around the world. The Warman Series ‘A’ pump was accepted and became a world leader in its field. Further work on the Warman AH pump resulted in the development of interchangeable metal and rubber wearing components."

Jan 9, 2018

By Alan H. Goode

Of the 15 million tons of glass discarded in municipal wastes annually, about 2 million tons pass through incinerators and can be recovered by ore processing techniques. Although the primary use for this recovered waste glass would be as cullet in the manufacture of new glass containers, this approach is not always practical because of long shipping distances, high freight costs, and high purity requirements. Alternatives to the use of waste glass as cullet would be either as landfill or in secondary products. Although glass is considered a good landfill material, it is still wasteful of potentially valuable raw materials. Secondary products that can be made from waste glass1 include a variety of industrial and construction items. As part of the Bureau of Mines' program in secondary materials recovery, the Tuscaloosa Metallurgy Research Laboratory has conducted research concerned with the development of ceramic building products from waste glass. Materials employed in this research were obtained from municipal incinerator residues fractionated in the Bureau's continuous residue processing plant, College Park Metallurgy Research center.' The studies reported herein3,4 present research results using waste glass in the formulation and production of clay bricks, not only to produce improved products, but to reduce production costs, conserve natural raw materials, and most important, to reduce manufacturing energy requirements.

Jan 1, 1974

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By Jane Li, Kevin Tom

"Research has shown that broken rock on conveyor transport systems can contribute upwards of 50% towards the overall heat load in underground mines. However, few studies have made significant efforts to predict the temperature distribution of the ore and air simultaneously, which can help implement heat management strategies. The present investigation explores a transient, analytical heat transfer model to track ore-pile temperature distributions, along conveyor systems in an example underground mine. Production rate, ambient conditions, ore pile thickness and belt velocity are adjusted to evaluate the effect on dry and wet bulb temperatures.INTRODUCTIONWith an ever increasing demand on Earth’s resources due to a multitude of factors like population growth and step changes in technology, pressure on the mining industry to bring out more ore with improved margins is a persistent challenge. Typically, high-volume producing mining methods (i.e., exceeding 5000 tons per day (tpd)) such as sublevel and block caving, room and pillar, and longwall shall utilize belt conveyors instead of trucks as the primary haulage method to surface to save on operational costs (de la Vergne, 2014). However, studies have shown that when such material transport systems are installed at mine depths with virgin rock temperatures (VRT) above 40oC, the heat dissipated by the conveyed ore can account for over 50% of the underground heat-load (Pareja, 2000; Bluhm, Jones, Moreby, & von Glehn, 2012; van den Berg, Moreby, & Kok, 2015).Unlike other types of heat sources encountered in underground mines, such as diesel machines, strata, electrical devices, and autocompression, heat transfer by conveyed broken rock is much more difficult to estimate. The seminal work of McPherson (1993) states that broken rock heat transfer is a function of its surface area, and the air’s psychrometric condition. It is additionally a function of the VRT, its specific heat, production rate, heat transfer coefficient and the residence time (Bossard, 1997; Ross, Tuck, Stokes, & Lowndes, 1997). Consequently, few studies have attempted to analytically quantify the significance of ore heat flow."

Jan 1, 2019

By Tony D. Canale, Anthony Mazzo

"Times Square, arguably one of the best-known destinations in the world, has undergone and continues to undergo a re-development aimed at attracting corporate tenants to the area. Mueser Rutledge Consulting Engineers (MRCE) was involved with the planning, design and construction of the foundations for the Conde Nast and 5 Times Square sites, as well as Times Square Tower. These sites are pictured in Figure 1.This paper will focus on the design and construction of the deep foundations for Times Square Tower that was developed by Boston Properties. PROJECT DESCRIPTIONTimes Square Tower is 47 stories tall, with no setbacks and an overall height to top of crown of 730 feet (222.5m). It has two basement levels extending 30 feet (9m) below grade over the full site. As shown in Figure 1, the structure occupies the entire site and has a footprint of 22,000 square feet (2,044 m2), with a total rentable area of about 1.2 million square feet (111,480 m2). The planned use for the building is office space with retail at the ground level. When completed, Times Square Tower was the final building constructed as part of the Revitalization of Times Square. Due to the site constraints, designing and constructing the foundations was akin to placing the final piece of a puzzle.Times Square Tower provided numerous design and construction challenges that were a result of tight working conditions, heavy column loads, and a compressed schedule.GEOLOGIC SETTING AND SITE HISTORYThe Times Square area is part of the Manhattan Prong called the Manhattan Ridge, a formation of old and durable metamorphosed and folded bedrock, now termed the Hartland Formation. The bedrock generally has a thin soil cover and uneven surface overlain in some areas with a thin mantle of decomposed and/or weathered rock. Overburden soils include glacial and post-glacial deposits and recent fills.Transit improvements have been made in and around the Times Square area since the early 1900’s. The 1, 2 and 3 Subway Lines that run below 7th Avenue were constructed circa 1915 using cut and cover techniques and extend about 28 feet (8.5m) below grade. The N, R, Q & W Subway Lines that run below Broadway were also constructed in 1915 using cut and cover techniques and extend about 38 feet (11.6m) below grade. The 7 Line that runs below 41st Street was constructed later, using both cut-and-cover and tunneling methods as it runs below the other subway structures at a depth of about 55 feet (16.8m) below grade."

Jan 1, 2005

By G. G. Oberfell

THOUGH the largest volume use of natural gas has been, is. and in all probability will continue to be as a fuel for domestic and industrial heating, it has various market outlets, both as a fuel and as a raw material for the chemical industry. Natural gas is a preferred type of fuel where ease of control, fuel uniformity, and freedom from ash are of primary importance. Other industrially important uses are as a source of carbon black and as a fuel in various low-cost heating operations. Many other uses are of varying importance and new potential uses are continually being uncovered, some being of economic importance to the gas indus¬try as a whole, but most of them involve such small volumes of gas that they are only of passing interest. Since various products extracted from natural gas and recovered as by-products from petroleum refining, such as liquefied petroleum gas and fuel oil, are being utilized in many industrial and domestic heating applications, some consideration will have to be given such materials in order to present a reasonably complete story of the importance of natural gas. Some of these materials may prove to be transient competitors and will not be available when more profitable uses are found for them. Meanwhile, however, the potential volumes of such materials available, the current volumes being marketed, and the nature of the utilization are considered as constituting an essential part of the over-all fuel picture.

Jan 1, 1946

By F. T. Principe

In order for solvent extraction technology to be acceptable as an alternative to existing jarosite precipitation circuits, iron must be cleanly separated and concentrated into a feed stream suitable for downstream iron by-product recovery which meets market specifications and economics. Ten years ago, significant progress was made in a joint McCill University/CANMET project that involved iron extraction with mono(2-ethylhexyl) phosphoric acid and stripping with HCI. Our iron solvent extraction research was reactivated recently by looking into this and other members of the organophosphorus extractant family. Our research focuses on the mechanisms and control of anion (SO42/CI) transport across the various phases (Rafinate/Organic/Strip), iron build-up in the strip liquor, and extractant stability/selectivity. In this paper, these issues along with some other performance parameters are discussed using data derived from an extensive search of the two commercially available and best known members of the organophosphorus family, di-2-ethylhexyl (D2EHPA) and mono-2-ethylhexyl (M2EHPA) phosphoric acid. Further in this discussion, the challenges lying ahead in the development of sx systems that overcome the deficiencies of D2EHPA and M2EHPA are outlined. In particular, the necessity of considering secondary separation technologies that can further concentrate iron values in the chloride strip liquor to levels economically attractive for the production of saleable iron oxide by pyrohydrolysis is addressed.

Jan 1, 1998