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By Ali Akbar Mottahedi

It is known for a long time that the reaction of oxygen with carbon, silicon, iron and many other elements is exothermic. The heat of released from these kind of reactions can decrease the time of fusion of iron and steel for metallurgical purposes in the electrical arc furnaces. By decreasing the time of fusion, we increase the rate of process and the amount of production. So, by blowing oxygen in to the furnace, we can reduce the consumption of electricity and save cost. There are many problems in the procedure of the oxygen blowing. In this project, the theoretical aspect of the oxygen blowing and its side effects into the arc electric furnaces are investigated. An oxygen blowing system into the arc electrical furnace of metallurgy department of Machine Sazi factory was also set up. This process reduced the consumption of electricity up to 22% and increases the rate of production, by reducing tap ? to ? tap time up to 15%. In this project; all oxygen blowing systems and its control were set up.

Jan 1, 2006

By Richard Birk

Rf sputtered quartz has been successfully used in multilayer interconnects for MOS devices. The target potential was 2000 v peak to peak with a frequency of 13.56 Mc per sec. The sputtering rate was approximately 60A per min with an operating pressure of argon gas at 10 to 15 p. The dielectric strength is 8.0 x 10' v per cm and the pinhole density is less than 2 x 10-2 per sq mm. Infrared absorption peaks for the Si-O vibrational bands we at 9.4, 12.4, and at 22.5 p. The etch rate of the sputtered SiO2 is 1200A per min. MOS devices have been fabricated using multilayer interconnects with no degradation of electrical characteristics. MULTILAYER interconnects require an insdating film between the metal layers which can be deposited below any potential eutectic temperature. Sputtered Si4, which can be deposited with substrate temperatures below 200°C, satisfactorily meets the multilayer insulation requirements and has been used to prepare MOS circuits with multilayer interconnects. The physical and electrical properties of rf sput-

Jan 1, 1969

By Restarick C, Jowett A

A cylinder-cyclone system, fitted with a flow control valve between the cylinder and cyclone plus in some tests a variable cyclone spigot, has been used to achieve classifier separations at unusually coarse sizes relative to the diameter of the units used. The method has proved to be useful for low tonnage flows at low pulp density and variable feed rate. The system relies on use of a cylinder unit to reject excess water and fine particles, the amount rejected being adjusted by the flow control valve. The valve also adjusts flow rate and pulp density of feed to the cyclone unit, and can be adjusted to give a separation at a coarse particle size. The system has been used in connection with experiments on the pilot plant at Mount Isa, where a 76 mm system was used to classify feed to the lead secondary rougher circuit at sizes as coarse as 52 micrametres galena equivalent for split conditioning tests. Further tests have been carried out with quartz to assess the range of size separations Possible.

Jan 1, 1978

By C. H. Elder, Fred N. Kissell, S. D. Maksimovic

The Bureau of Mines evaluated the hydraulic stimulation of a gob-degasification borehole to determine if this procedure would aid in degasifying a longwall panel. The stimulated borehole did not degasify the longwall panel as expected either before or after mining of the panel started. It reduced the underground methane emission only 11 pct, considerably less than the reductions effected by two unstimulated boreholes in the same panel. Some probable reasons for the reduced methane flow from the hydraulically stimulated borehole are very low reservoir gas pressure, location of hydraulically stimulated zones within the grouted casing, a casing break caused by lateral shifting, possible vertical movement of rock strata during caving, grouting of a 4-inch pipe blocking three stimulated zones, plasticity of shales, and possible hole damage by swelling of water-sensitive minerals. The borehole was also located between two second-mined areas, which may have allowed partial degasification of the overburden and the coalbed in advance of mining. Finally, a period of 3 months is probably not long enough for the borehole to degasify the overburden before mining.

Jan 1, 1977

By Ellery B. I

Field investigations recently undertaken by Utah Development Company (U.D.C.) have been developed to allow the assessment of ground conditions relevant to the use of large bucket wheel excavators for pre-stripping overburden. "Bucketwheel diggability" predictions were made on the basis of a wedge test which was perform- -ed in the field on nominal 150 mm diameter drill core samples. Specific separation force (calculated from the wedge test results) for different rock horizons were theoretically related to the excavation rates of various sized bucketwheels, i.e., "bucketwheel diggability". The specific separation force was shown to vary with lithology, structure, weathering and moisture changes. By correlating these features between boreholes, an overall assessment of bucketwheel diggability was then made. The approach adopted to assess bucket- wheel diggability incorporated various levels of investigation. Initially, a reconnaissance stage provided information from widely spaced 150 mm cored holes to compare and contrast areas with differing bucketwheel digging char- -acteristics. The following stages progressive -ly added to this information, until finally, between hole correlations, allowed calculations to be made of volumes of materials of similar

Jan 1, 1981

By Rick Deschamps, Amanda Blank, Matthew W. Drewek, Michael P. Walker

The Prairie du Sac Dam, located on the Wisconsin River, northwest of Madison, Wisconsin, was constructed 1912-1914. The spillway is an Ambursen-type, consisting of a series timber pile supported pier and buttress walls and rollway slab. The timber piles supporting the spillway, numbering approximately 5,000, have deteriorated, and the spillway structure was underpinned with over 700 micropiles as part of a design-build construction project. The underpinning micropiles needed to be arranged to avoid interferences with the existing timber piles, requiring the micropiles to be installed in the open spaces between the piers and buttresses. Inevitably, the installation of the new micropiles encountered obstructions, including existing timber piles out of alignment, as well as timber piles used to support the original construction activities and sheet pile used to control water during the original construction. This paper discusses using finite element analysis to model the spillway structure to estimate the vertical and horizontal stiffness with an extensive sensitivity analysis was performed during the design phase to account for anticipated construction challenges and potential variations in the underpinning performance. The inherent rigidity of the spillway structure allowed for load distribution to the underpinning system even when new micropiles needed to be re-located and aligned to avoid interferences with existing timber piles and other abandoned foundation elements dating back to original construction.

Sep 8, 2021

By James Ball

The paper describes a new type of pump and related apparatus specifically designed to dredge sea-floor minerals from very great depths. The principle of operation of the dredging system is explained, and the factors which determine the equipment size and the power required for varying mining rates and depths of water are discussed. An estimate of the capital and operating cost of a commercial-scale mining system is presented.

Jan 1, 1968

By J. J. Jakosky

"This report is the second of a series dealing with electrical methods of underground communication nd signalling, and is a discussion of some of the factors involved in -applying radio in mines.A previous report2 described the results obtained by the use of the ""T.P.S."" of ground-conduction method of signalling, and outlined in a general way the requirements for a practical mine communication apparatus.The popularity of radio, the development work on new apparatus, a desire to render humanitarian service to entombed miners, and an endeavor to find new uses and applications for radio stimulated many persons to attempt the application of radio to mine rescue purposes. A number of experiments on underground reception from surface broadcast stations have been conducted by different experimenters in various parts of the country and the widespread interest in the subject is shown by the fact that these tests have been con¬ducted in many States, The Bureau of Mines has received information regarding, underground tests in Illinois, Pennsylvania, Arizona, Utah, Idaho, Colorado, Michigan, Wyoming, Kentucky, New York, Connecticut, and in England, Germany, Italy, and Franc.From occasional press notices and illustrations in different papers it may appear that radio communication in mines and in tunnels being excavated is en established fact, and that the method is comparatively simple. As a matter of fact the reverse is the case."

Apr 1, 1924

By David A. Summers, Clark R. Barker

INTRODUCTION The use of high pressure water as a means of excavating valuable mineral from the earth dates back many hundreds of years, but is most familiar through its use in sluicing the gold bearing deposits of California and Alaska. Interestingly, that practice, which dates back from at least 1852, is now nearly defunct with only one known surviving hydraulicking operation.(l) In that particular development water under a relatively low, natural pressure head is carried to a nozzle and from the nozzle it is thrown a distance of perhaps 20 ft to wash the gold bearing material down into a channel from whence it's carried over some mineral collector, and the water is then recirculated. Development of this practice in coal mining began in Russia in 1915, and Dr. Muchnik established the criteria for hydraulic mining during the 1930's. The first water jet mine was established underground in 1939 and has been followed by several larger mines to the present day where there are at least 11 large mines producing about 10 million tons of coal per year in the Soviet Union.(2) Water jet mining has expanded from Russia through Japan, Germany, Poland, Czekoslovakia, and mainland China. The nearest location to the United States is currently at the Kaiser Mine in Sparwood, British Columbia, where a three-man crew has mined up to 3,400 tons of coal in a 6-hr shift. There are many advantages to this particular operation. It is one of the safest mining operations for coal in Canada and has won safety awards because of this. The process is relatively cheap since the cost of the equipment is much lower than that which would be required conventionally using either longwall or shortwall mining, and transportation is achieved by fluming the coal to a central station using a gravity feed and then pumping to the surface, (3) For this

Jan 1, 1976

By George J. Dvorznak, Robert W. Waytulonis

The Bureau of Mines is conducting a research project in cooperation with the Mine Safety and Health Administration (MSHA). Mining companies, and equipment manufacturers are also participating through the Colorado Mining Association (CMA). The objectives of this cooperative research project are to determine the practicality of coupling a dry exhaust conditioning system (dry system) and diesel particulate filter (DPF) to make an integrated control system, and to determine the effectiveness and durability of the integrated system in an underground coal mine. Diesel-powered mining machines must be equipped with control devices to reduce surface and exhaust temperatures to safe levels and prevent flames and sparks from being emitted to the mine atmosphere. Diesel exhaust-gas water scrubbers have been successfully used for many years but they have several disadvantages; they are large, consume large quantities of water, and require frequent maintenance to remain functional. Additionally, diesel exhaust is a source of noxious gases and particulate matter. Particulate emissions are composed primarily of small carbon particles with absorbed hydrocarbons and they are almost entirely respirable in size. Even an engine in good mechanical condition can emit up to 400 mg/cu m of respirable particulate matter. A dry system for control of diesel fire and explosion hazards, coupled to a DPF, promises to be a complete control system for diesel engines. The dry system cools the exhaust and suppresses sparks and flame with a heat exchanger and flame and spark traps. The conditioner is smaller, consumes no water, and requires less maintenance than a comparable water scrubber. The DPF uses a ceramic substrate as a wall-flow filter and is very efficient at collecting exhaust particles. Average particulate mass collection efficiency is 90%. This report describes a cooperative research project to combine the dry system with the DPF, conduct performance tests on the integrated system at Bureau and MSHA 1aboratory facilities, and conduct field tests of the system on a production machine in an underground coal mine.

Jan 1, 1987

By Louis Katona

The practical execution of the design for rolling-mills presented by the writer at the Paris meeting* of thc Iron and Steel Institute in 1900 involves the determination of some questions not yet discussed, among which is the determinatioir of the amount of power required to perform the rolling of pieces of iron and steel of given dimensions. It is necessary to know this factor if we would put motors of proper capacity to the respective pairs of rolls, or, rcciprocally, if, having standard motors at our disposal, we would design grooves to suit them. Moreover, this factor is involved in giving right dimensions to every part of the rolls and housings. Expert designers of engines for driving rolling-mills of the present type receive very indefinite directions, such as: that the motor is to drive a light, medium or heavy train; that it must work with fly-wheel or reversing gear; that the number of revolutions per minute should not exceed 40 or 60, and that at a given speed the power developed should be from 100 to 200 H. P., or from 1,000 to 2,500 13. P. It frequently happens, however, that an cngine of 200 H. P. is forced under the circumstances to press or develop as much as 300 H. P., while, on the other hand, the ,1,500-11. P. engine may be rolling-stock which could be worked with a maximum expenditure of 60 to 80 H. P. Of course such variatior~s as these do not permit the best adjustment of parts or the best economy of power and fuel. The design of roll-trains is even more vaguely limited. Every part of a train, from the point where it connects with the engine to the last groove in the rolls, bears evidence that there are no rules for calculating even approximately the dimensions of the main-shafts, couplings, pinions, gears, rolls, trunnions,

Jan 1, 1904

By Bilgehan Kekec, Sertac Dündar, Niyazi Bilim

"Knowledge of the abrasion resistance of aggregates is important when using them for asphalt and concrete mixes and highway construction materials. In this study, the usability of natural building stone waste as aggregates for different engineering applications was investigated. To this end, test samples were obtained from a number of natural stone quarries and stone cutting factories. The abrasion tests were carried out on the test samples and results were compared between samples. The abrasion strength values were determined with both the Micro-Deval (MDe) and the Los Angeles (LA) abrasion test methods. A correlation coefficient was also determined between the LA and MDe tests results using an appropriate statistical model.Introduction The rapid consumption of natural resources has led researchers to work on the efficient utilization of such resources. To this end one can convert waste into useful raw materials, or determine alternative uses of the industrial waste materials. This has become increasingly important as storing or dumping waste may result in environmental problems. In addition, the use of industrial waste in a different application of the construction industry prevents rapid consumption of limited natural resources and can mitigate environmental problems related to raw material production, Industrial waste such as blast furnace slag, fly ash, building demolition material, marble waste and dismantled asphalt have been used as highway and concrete materials (Ahmed 1993, Ramaswamy and Aziz 1992, Schroeder 1994, Ceylan and Manca 2013, Holtz and Eighmy 2000, Hebhoub et al 2011). It is very important to analyze whether these aggregates are of the required quality in terms of their application and their economic life. This analysis can be carried out using various tests such as the Micro-Deval and the Los Angeles abrasion tests, sieve analysis, durability chemical resistance, peeling and adhesion, and freezing-thawing tests (Erdem et al 1996). Specifications for aggregates also include terms that define the grain shape, cleanliness and surface textures."

Jan 1, 2017

By Luís Marcelo Tavares, Juliana Segura

Comminution is one of the most energy consuming stages in a mineral processing plant. This consumption is not only related to the power supplied to equipment, but also to the indirect or embodied energy, mainly associated to materials that are worn during operation, including grinding media and liners. Until recently, preparation of iron ores in Brazil did not use comminution intensively, given that plants mainly produced sinter feed, natural pellet fines, besides lump ore. However, with decreasing ore grades, size reduction now occupies a centre stage in nearly all new plants. Technologies used up to date for processing low-grade iron ores in Brazil, in particular itabirites, have consisted of three or four stages of crushing followed by ball milling. A number of new plants are either being built or are currently being designed that will process the same type of ore, so that engineers are investigating alternative comminution routes. The paper analyses comparatively four comminution routes for processing a particular itabirite ore, many of which using technologies and layouts that have not yet been used in such application. Using data from bench scale and/or pilot-plant tests, the different routes are compared on the basis of sustainability principles in accordance to the Brazilian energy matrix, which is quite particular. It is concluded that if the sustainability criterion is used, then the optimal route would correspond to a circuit that uses HPGR technology with truncated feed followed by ball milling. Given the particular case of itabirite iron ores and specially to the one in the present work and the source of Brazilian energy, it is evident that indirect energy expenditure in comminution plays a significant role in greenhouse gas emissions when compared to direct energy, being the reason for the great attractiveness of HPGR technology. Evidently that these will have to be balanced against CAPEX, OPEX, NPV and other qualitative criteria, which can certainly lead to a different optimal circuit.

Jan 1, 2014

By J. V. Richards

The Altar district, State of Sonora, Mexico, is for the most part a desert with but little rain-fall and few running streams. On account of this scarcity of water it is necessary for the natives to " dry-wash" the placer-gravel, and the object of the present gaper is to describe some of the more commoil Mexican dry-mashing devices. My observations were confined to a property known as Las Palomas placers, 15 miles from the Gulf of California and about 150 miles south of the United States border; a brief description of which property may be of interest as illustrating what is, perhaps, a typical Sonora dry placer. It is said that as long as a century ago the Yaqui Indians discovered rich cement-gravel, known as argo masa, at Las Palomas, and that there has been a more or less steady production of gold from the property ever since. The argo masa, is a fairly-coarse gravel, the pebbles being quite firmly held together with a lime cement. Gold is scattered through this cement in particles ranging from fine specks to pieces several grams in weight, and occasional large nuggets are encountered. The contents vary so widely that it is difficult to estimate the average value, but returns of from $10 to $50 per cubic yard are common, and it is doubtful if the Indians considered anything less than from $4 to $5 a yard as "pay dirt.'' This ar-90 masa, occurs in channels varying in thickness from a few inches to several feet, and in width up to 300 ft. These channels are continuous and are probably ancient stream-beds. They are for the most part covered with an over-burden of a more recent gravel, varying from 30 to 50 ft. thick, and the fact that this over-burden contains values as high as $1.50 per cubic yard, and yet was not worked by the Indians, shows that their idea of what constituted mas high.

Jan 1, 1911

By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By B OÆNeil

The Trent-Severn Waterway is a 386 km long navigation route through central Ontario between Lake Ontario and Georgian Bay, and is operated by the Parks Canada Agency. Its primary focus is to pass recreational boats through a system of 44 locks. The Big Chute Marine Railway (BCMR) is one site in the system that provides transportation for boats. The BCMR carriage is used to transport boats and their passengers on the inclined railway a distance of 230 m over a natural barrier from one body of water to another, with an elevation difference of 18 m. The unique feature of the haulage system used in this application is the variable angle of the incline from about 20 per cent rise changing to horizontal and followed by 20 per cent decline. In such conditions, unlike as in standard incline haulage, special configuration of hoists and drives is required. On the uphill part of the track, there is a need to have a motoring mode, on the downhill part a regenerating mode and on the horizontal part a combination of motoring and regeneration is required. The original system was built in 1978 and employed four 100 hp dc drive mine hoists to haul the 100 tonne conveyance loaded with 90 tonnes of boats. Due to failures and operational problems with the original system, in 1999 Parks Canada awarded a turnkey contract to ABB for a new, modern system of four single drum hoists. The new system was put into operation in 2000, only six months after receiving the order. The hoists are controlled by digital drives and a digital control system. Due to dramatic changes in the load conditions for individual hoists involved, the new system features many interesting solutions like changing drive modes from speed to torque control and a multiple, regulated braking system. It is a unique hoisting system, which could be also used in mining applications.

Jan 1, 2005

By I Auranen, J Raatikainen

IMA Engineering (IMA) and Mine On-Line Service (MOLS) companies have used on-line sensors for analysing ore and waste rock in mining for more than 25 years. Today IMA on-line sensors are used in various stages of the mining process including on-line analysis of drill cores, drill chips, ore and waste in loader bucket, ROM ore analysis on belt conveyor belt and in bulk ore sorting and in slurry analysis in concentrators. During years of extensive field experience and testing we have found that the waste rock dilution and ore losses create much larger economic and environmental losses than has been previously recognized. According to our studies the main reason is limited number of analysis already in exploration when drill cores or drill cuttings are used in block modelling. The same happens in production because too few and biased samples from benches are used to estimate the ore grade. Much more than today estimated amount of waste enters the mill and considerable volumes of ore losses happen at the same time. The ore grade on the benches and in muck piles is averaged and “homogenized” with averaged and biased samples. These are the main root causes of waste rock dilution and ore losses. Sensor based preconcentration can be the remedy to waste rock dilution and ore losses. This presentation will show examples of the use of on-line sensors in preconcentration when analysing ore and waste rock in drill cores, drill cuttings, on conveyor belt and in bulk ore sorting. Waste rock removal in preconcentration has direct effect on energy consumption in crushing and grinding and chemicals in concentrator. In concentrator waste is separated and goes to tailings pond, however, preconcentration directly reduces the volume of the tailings. In our presentation we will cover cases in base metals and in gold mines.

Nov 10, 2020

By Madan M. Singh

Section 516 of Public Law (PL) 95-87, commonly known as the Surface Mining Control and Reclamation Act of 1977 (SMCRA), requires that underground coal mine operators must "adopt measures consistent with known technology in order to prevent subsidence causing material damage to the extent technologically and economically feasible, maximize mine stability, and maintain the value and reasonable foreseeable use of such surface lands, except in those instances where the mining technology used requires planned subsidence in a predictable and controlled manner..." Implied in the constraints of Section 516(b)(1) of SMCRA is a determination of what constitutes "material damage" to surface structures, renewable resource lands, and the capacity for sequential land use following underground mining. The authors have already briefly addressed the subject of damage criteria in relation to surface structures (Bhattacharya et al, 1984). In this paper, an attempt is made to provide quantitative guidelines to ascertain material damage to renewable resource lands, although the data available to establish these criteria are considerably more limited than is the case for surface structures. Besides, many more variables influence the severity of the impact at a given site, making the task of assigning stringent ground movement limits even more complex. This often necessitated use of professional judgement and occasional reverting to a qualitative approach. Hence the reader is cautioned at the very outset that the quantitative limits presented herein are approximate and are primarily intended to serve as rough guides for ascertaining the extent of damage to the renewable resource lands under consideration, and that depending on site-specific conditions the actual damage incurred may differ significantly from that predicted by the proposed criteria. The authors, however, feel that the criteria suggested are somewhat conservative, but realistic. The actual damage observed should generally be less severe than predicted by these criteria. It may also be clarified here that the term "subsidence", as used in this paper, implies the total phenomenon of surface and subsurface effects associated with the mining of minerals and not only the vertical displacement of the surface as is sometimes inferred in the literature.

Jan 1, 1984

By Shi Guan-Yong, Niu Li-Ping, Dou Zhi-He

"In the preset work, the viscosity model (named modified KTH model) proposed by Sichen Du and S. Seetharaman et al and extended by Shu Qi-feng was applied to the ESR slag systems. A correlation to predict the viscosities of CaF 2-(CaO)-Al203 slags using interaction coefficients of different cations in the presence of oz-and viscosity interaction coefficients between oz-and F in the presence of different cations has been developed. The interaction coefficient between oz- and F- in the presence of Al3+ was determined from the experimental data as shown in known literatures. The good agreement between the calculated viscosities and the experimental data in the CaF2-(CaO)-Al203 systems has indicated that this approach can be successfully employed to predict the viscosities of ESR slags.IntroductionReliable viscosities data of high-temperature slag melts are important for the modeling and design of high temperature metallurgical processes. Although a number of experimental measurements have been carried out, the available viscosities data is still scarce compared to the needs of today's technology, especially in the case of complex melts. In process simulations, the needs of viscosity descriptions for complex systems which could enable the extrapolation of the data as functions of temperature and composition is strongly felt today."

Jan 1, 2013

By Georges Houlachi, Akram Alfantazi, Michael Mahon, Maysam Mohammadi

Corrosion resistance of the lead-based anodes directly influences the purity of the final product in the zinc electrowinning process. The anodic MnO2 layer that is electrodeposited on the anodes during this process can protect the anodes against corrosion. Sand-blasted anodes generate a uniform, adherent and shiny MnO2 layer, which gradually blisters and eventually sloughs off after several weeks. In this study, we attempted to develop a new method to stabilize the MnO2 protective layer on the anodes during the electrowinning process by providing suitable nucleation sites for electrodeposition of this layer. MnO2 particles (P80=40µm) were used as seed material for this purpose. Different techniques of galvanostatic and cyclic voltammetry polarizations, scanning electron microscopy (SEM) and atomic absorption spectroscopy (AAS) were employed to investigate the performances of the MnO2-seeded lead anodes. The experimental results showed that growth of the MnO2 layer is influenced by the MnO2 seed particles on the anode surface. The MnO2 layers electrodeposited on the MnO2-seeded lead anodes were uniform and strongly adherent to the substrate. This layer was more stable than those formed on the PbAg anode without MnO2 seeding. This could provide the anode with a higher level of corrosion protection. Moreover, formation of undesirable MnO2 mud in the electrolyte and the rate of manganese consumption were decreased when the MnO2-seeded lead anodes were polarized. These observations could be attributed to the different properties of the electrodeposited MnO2 layer on this anode in comparison with that formed on the PbAg anode.

Jan 1, 2016